Amino Substituent On Carbocyclic Ring Patents (Class 430/442)
  • Patent number: 5102778
    Abstract: A method for processing a silver halide light-sensitive material comprising subjecting an imagewise exposed silver halide color light-sensitive material having a silver chloride content substantially of 90 mol % or more to color developement in a color developing solution containing a hydrophilic p-phenylenediamine derivative and substantially no benzyl alcohol at a temperature of 30.degree. C. or higher for a period of 15 seconds or less and then subjecting the color developed material to bleach or bleach-fix, wherein the color development processed silver halide color light-sensitive material is introduced into a bleaching or bleach-fix bath with the amount of a color developing agent in the film of the light-sensitive material being controlled to 0.8 mmol/m.sup.2 or less, and wherein the desilvering is completed within 30 seconds.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: April 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koichi Nakamura
  • Patent number: 5098819
    Abstract: An environmentally-safe, non-toxic non-hydroquinone and non-alkali metal hydroxide containing photographic developer composition is provided comprising a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, stereoisomers and diastereoisomers of ascorbic acid and its sugar-type derivatives, their salts and mixtures thereof, together with a sulfite, an alkali metal carbonate, and a 3-pyrazolidone developer compound.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: March 24, 1992
    Inventor: Audenried W. Knapp
  • Patent number: 5093226
    Abstract: A method for forming an image of a silver halide color photograph, which comprises processing a silver halide color photographic material with a color developing solution containing at least one aromatic primary amine color developing agent, comprises: processing a silver halide color photographic material having at least one layer containing a compound represented by formula (S) and a silver halide emulsion comprising at least 80 mol % of silver chloride with a color developing solution containing chlorine ion in an amount of 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l and bromine ion in an amount of 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l: ##STR1## wherein Z.sub.1 represents a nitrogen atom, an oxygen atom, a sulfur atom or a selenium atom; Z.sub.2 represents an oxygen atom, a sulfur atom or a selenium atom; L.sub.1, L.sub.2, L.sub.3, L.sub.4 and L.sub.5 each represents a methine group which may be optionally substituted or may be combined together with another methine group to form a ring; R.
    Type: Grant
    Filed: October 3, 1989
    Date of Patent: March 3, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoto Ohshima
  • Patent number: 5041363
    Abstract: A method of processing a silver halide photographic material with a compact and high speed automatic processor is disclosed. The developing solution contains hydroquinone, 1-phenyl-4-methyl-3-pyrazolidone, and 1-phenyl-4,4-dimethyl-3-pyrazolidone or 1-phenyl-4-methyl-4-hydroxy-methyl-3-pyrazolidone. The method is suitable for an X-ray photographic material.
    Type: Grant
    Filed: May 9, 1990
    Date of Patent: August 20, 1991
    Assignee: Konica Corporation
    Inventor: Haruhiko Sakuma
  • Patent number: 5006439
    Abstract: A photographic reversal process for the production of positive photographic images by imagewise exposure of the photosensitive material containing at least one silver halide emulsion layer, black-and-white first development of the material, chemical fogging, color development and bleaching, fixing, washing or stabilizing and drying, in which the material is transferred from the first development to the color development without any intermediate steps, such as intermediate washing or diffuse second exposure, the first development bath exclusively contains one or more N,N-dialkyl-p-phenylenediamine derivatives as developer and a tin(II) complex compound and is adjusted to a pH value of <8 and the color development bath likewise exclusively contains one or more N,N-dialkyl-p-phenylenediamine derivatives as developer and is adjusted to a pH value >10, requires considerably less time than the conventional process but produces equivalent results.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: April 9, 1991
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Ubbo Wernicke, Herbert Mitzinger
  • Patent number: 4937160
    Abstract: Photographic silver halide elements containing aryl hydrazides as defined for the production of images with ultrahigh contrast and a new class of aryl hydrazides with a cationic group in the aryl radical as defined. The photographic silver halide elements can be developed at relatively low pH values and have low fog and low tendency to form black spots in unexposed or slightly exposed areas.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: June 26, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Reinhold Ruger
  • Patent number: 4927734
    Abstract: A silver halide photographic light-sensitive material contains at least one negative-working silver halide emulsion layer composed of substantially surface latent image type monodispersed silver halide grains. The emulsion layer or another hydrophilic colloidal layer contains a compound of general formula I or II: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a hydrogen atom, or a substituted or unsubstituted alkyl or aryl group, and if one of R.sub.3 and R.sub.4 is a hydrogen atom, the other thereof is not a hydrogen atom. Disclosed also is a process which forms a photographic image by employing the material as described above, or a developer containing the compound as shown above.
    Type: Grant
    Filed: November 21, 1988
    Date of Patent: May 22, 1990
    Assignee: Dainippon Ink. and Chemicals, Inc.
    Inventors: Shuji Rokutanda, Yasuo Higemitsu, Akiyoshi Tsuchida, Yukihiro Yamakoshi
  • Patent number: 4835092
    Abstract: A novel method for processing a silver halide color photographic material is provided, which comprises processing a silver halide color photographic material having at least one silver halide emulsion layer on a reflective support with a color-developing solution substantially free of benzyl alcohol and containing at least one compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, --CH.sub.2 COOH, or ##STR2## R.sub.2 represents a hydrogen atom or --COOH; n represents an integer of 0 or 1; and Z represents atoms necessary for the formation of an aromatic ring.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: May 30, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Toshio Koshimizu, Yoshihiro Fujita, Hiroshi Fujimoto
  • Patent number: 4772545
    Abstract: A silver halide photographic material in which a silver iodobromide emulsion having an iodide content of 2 mole % or more and an organometallic salt functioning as a development inhibitor are employed in combination, whereby an improvements in graininess and sharpness of a developed image are achieved and high photographic speed is retained.A process for producing silver images using the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shingo Nishiyama, Kiyoshi Kawai
  • Patent number: 4767692
    Abstract: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.
    Type: Grant
    Filed: January 5, 1987
    Date of Patent: August 30, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Morio Yagihara, Shigeo Hirano
  • Patent number: 4740452
    Abstract: The present invention provides a process for preparing a negative image of high contrast comprising developing an exposed silver halide photographic material which is substantially a surface latent image-type material in the presence of a hydrazine derivative, wherein said material is processed with a water-soluble alkaline developer having a pH value of from 10.5 to 12.3 and at least comprising the following components (1) through (3):(1) a dihydroxybenzene-type developing agent;(2) 0.3 mole/liter (developer) or more of a sulfite preservative; and(3) from 0.01 to 0.30 mole/liter (developer) of a compound of formula (A) ##STR1## in which R.sub.2 represents an alkyl group having from 3 to 6 carbon atoms; R.sub.3 and R.sub.4 each represents an alkyl or hydroxyalkyl group having from 1 to 10 carbon atoms.The formed negative images are of high contrast and are almost free from silver stain. The sensitivity is high and the dot image quality is good.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Mitsunori Hirano
  • Patent number: 4636460
    Abstract: Photographic recording materials which contain a developer substance or a precursor thereof produce better results if in addition they contain a sulphite, a disulphite or a compound capable of releasing sulphite in the photographic material.
    Type: Grant
    Filed: June 11, 1985
    Date of Patent: January 13, 1987
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Heinz Meckl, Helmut Kampfer, Helmut Haseler
  • Patent number: 4481286
    Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: November 6, 1984
    Assignee: Polaroid Corporation
    Inventors: Patrick F. King, Stephen G. Stroud
  • Patent number: 4481268
    Abstract: A method of forming a photographic azo or azamethine dye image in an exposed photographic silver halide element, the method of comprising the steps of (a) developing the imagewise exposed material to form an imagewise pattern of oxidized color developing agent, (b) reacting the oxidized color developing agent with a color coupler to produce an image dye, characterized in that at least one of the color developing agent and the color coupler possesses a metal chelating site such that the image dye is capable of forming a bi-, tri- or higher-dentate metallized dye, and (c) contacting the image dye with polyvalent metal ions to form a metallized dye image. Specified color developing agents include heterocyclic substituted hydrazides and specified couplers include benziso-oxazolones and 2H-pyrazolo-[3,4-b]pyridines in addition to more conventional compounds.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: November 6, 1984
    Assignee: Eastman Kodak Company
    Inventors: Joseph Bailey, David Clarke, Michael W. Crawley, Peter D. Marsden, Jasbir Sidhu
  • Patent number: 4473635
    Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## Wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, or R.sub.1 and R.sub.2 may be bonded to each other to form a heterocyclic ring together with the nitrogen atom; R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, an amino group, an alkoxy group, an acylamido group, a sulfonamido group, an alkylsulfonamido group or an alkyl group, or R.sub.1 and R.sub.6 or R.sub.2 and R.sub.3 may be bonded to each other to form a 5-membered or 6-membered ring; X represents HPF.sub.6 or HBF.sub.4 ; and n represents an integer from 1 to 3.
    Type: Grant
    Filed: May 18, 1983
    Date of Patent: September 25, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Katsusuke Endo, Sigeru Kuwazima, Eiichi Kato, Nobutaka Ohki
  • Patent number: 4439519
    Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms; R.sup.3 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; X represents a hydrogen atom or a group capable of being removed with alkali; Y represents ##STR2## and Z represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: March 27, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Ken Kawata, Isamu Itoh
  • Patent number: 4391900
    Abstract: A process for development-processing a silver halide photographic light-sensitive material is described, comprising processing with a developing solution containing 0.1 mol/liter or more of sulfite ion and at least one compound represented by formula (I) ##STR1## wherein n represents an integer of from 2 to 6; each of R.sub.1 and R.sub.2 represents hydrogen or an alkyl group having from 1 to 6 carbon atoms; and M represents hydrogen or an alkali metal atom.According to the process, the generation of silver sludge and the formation of fog are prevented when a black-and-white photographic light-sensitive material is processed with a developing solution containing sulfates in a high concentration.
    Type: Grant
    Filed: January 13, 1982
    Date of Patent: July 5, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Toyoda, Tadao Shishido, Teruaki Tsujikawa
  • Patent number: 4383023
    Abstract: A gelatino-silver halide film is exposed and then developed with a tanning developer bearing a positively or negatively charged substituent, e.g., a quaternary amine-substituted hydroquinone, to produce a charged matrix in the gelatin. To enhance the image the film is then processed to mordant an oppositely charged species, e.g., an anionic dye, to the charged matrix.
    Type: Grant
    Filed: October 1, 1981
    Date of Patent: May 10, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Frank L. Schadt, III
  • Patent number: 4377634
    Abstract: A method for forming a high contrast negative photographic image, which comprises imagewise exposing a photographic material comprising a support having thereon at least one photographic silver halide emulsion layer with the photographic silver halide emulsion layer or at least one hydrophilic colloid layer of the photographic material containing a compound of the general formula (I)R.sup.1 --NHNHCO--R.sup.2 (I)wherein R.sup.1 represents an aryl group, and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group containing 1 to 3 carbon atoms, and then developing the imagewise exposed material in the presence of a hydroquinone compound of the general formula (II) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a sulfo group, an alkyl group, an aryl group, an aralkyl group, a heterocyclic group, or a group of the formula --O--R.sup.7 or --S--R.sup.7 where R.sup.
    Type: Grant
    Filed: March 11, 1980
    Date of Patent: March 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4371603
    Abstract: This invention relates to amino hydroxy cyclohexenones of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each are alkyl, usually containing 1 to 20 carbon atoms.In another embodiment, the present invention is directed to the use of the above-denoted compounds as photographic silver halide developing agents and to photographic processes, products and compositions employing the same.
    Type: Grant
    Filed: December 30, 1980
    Date of Patent: February 1, 1983
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4365085
    Abstract: The present invention relates to novel bicyclic compounds useful as photographic silver halide developing agents, to the preparation of these compounds and to photographic products, processes and compositions employing the same. The subject compounds may be represented by the formula ##STR1## wherein R.sub.1 and R.sub.2, the same or different, each represents hydrogen, a hydrocarbon moiety, preferably an alkyl group, --COOH or --COOR.sup.1 wherein R.sup.1 is an alkyl group; R.sub.3 and R.sub.4, the same or different, each represent hydrogen or an alkyl group, R.sub.5 represents hydrogen or --COR.sup.2 wherein R.sup.2 is an alkyl group; R.sub.6 represents hydrogen when R.sub.5 is hydrogen and represents hydrogen or --OCOR.sup.3 wherein R.sup.3 is an alkyl group the same as R.sup.2 when R.sub.5 represents --COR.sup.2 ; X represents --OH, --NH.sub.2 or --NHCOR.sup.4 wherein R.sup.4 represents an alkyl group the same as R.sup.2 ; Y represents --OH or --OCOR.sup.5 wherein R.sup.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: December 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4348475
    Abstract: In a process for the production of photographic images exposed photographic materials are treated with a developer having an enhanced bromide ion concentration which is kept constant for the duration of the use of the developer. The advantage of the process is based on the technically uncomplicated regenerability of the developer.
    Type: Grant
    Filed: April 23, 1980
    Date of Patent: September 7, 1982
    Assignee: Agfa-Gevaert Aktiengesellschaft AG
    Inventors: Ubbo Wernicke, Heinz Meckl
  • Patent number: 4330616
    Abstract: A process of developing a color photographic material with a color developer, a diphosphonic acid and a water soluble metallic salt of magnesium, aluminum, zinc, barium or zirconium.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: May 18, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masayuki Kurematsu, Shigeharu Koboshi
  • Patent number: 4322492
    Abstract: The process for the development of color photographic images with an aqueous alkaline color developer mixture comprising methyl-p-dialkylaminoaniline derivates. The process provides brilliant color photographic images avoiding coloration of the support and color fog even when processing at high temperatures.
    Type: Grant
    Filed: April 23, 1981
    Date of Patent: March 30, 1982
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Friedrich-Wilhelm Kunitz, Walter Puschel, Karl W. Schranz
  • Patent number: 4318979
    Abstract: A light-sensitive silver halide photographic material comprising a combination of a salt of tetrazolium containing only a non-metallic anion and a salt of tetrazolium containing a metallic anion.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: March 9, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeshi Habu, Chika Honda
  • Patent number: 4282312
    Abstract: A multilayer color photographic material having at least one red sensitive silver halide emulsion layer containing a cyan coupler of the formula (I): ##STR1## wherein X represents a hydrogen atom or a chlorine atom and n is a positive integer of 8 to 20, is processed by a color developer containing a developing agent of the formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group or an ethoxy group; R.sub.5 represents an alkyl group having 1 to 4 carbon atoms, an alkoxyalkyl group wherein the number of carbon atoms in said alkyl moiety is 1 to 4, or a group of the formula --(CH.sub.2).sub.m R.sub.6 ; R.sub.6 represents a hydroxy group, a methylsulfonamido group, or an ethylsulfonamido group; and m represents a positive integer of 1 to 4.
    Type: Grant
    Filed: December 18, 1979
    Date of Patent: August 4, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Watanabe, Takeshi Hirose, Morio Yagihara, Yukio Yokota
  • Patent number: 4278750
    Abstract: Novel electron donor precursors have the structure: ##STR1## where: R is an alkali labile group;Y is an aliphatic or aromatic group; andZ is an electron withdrawing group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Eastman Kodak Company
    Inventor: Chung Y. Chen
  • Patent number: 4272606
    Abstract: A method of forming an extremely high-contrast negative photographic image which comprises image-wise exposing a photographic light-sensitive material comprising a support having thereon a mono-disperse silver halide emulsion layer containing surface latent image type silver halide grains and also containing a compound represented by the following general formula (1):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group, R.sup.2 represents a hydrogen atom, a phenyl group or an unsubstituted alkyl group having 1 to 3 carbon atoms, and then processing the exposed light-sensitive material in the presence of a compound having a thioamido moiety in the molecule thereof.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4264716
    Abstract: Photographic color developer compositions containing a primary aromatic amino color developing agent and an hydroxylamine are stabilized by incorporating therein a combination of sequestering agents, one of which is an aminopolyphosphonic acid compound and another of which is an aromatic polyhydroxy compound. Decomposition of the hydroxylamine, in the presence of heavy metals such as iron which act to catalyze the decomposition, and resultant formation of ammonia is effectively prevented by the presence in the developer composition of this combination of sequestering agents. Undesirable precipitate formation is also effectively avoided.
    Type: Grant
    Filed: September 10, 1979
    Date of Patent: April 28, 1981
    Assignee: Eastman Kodak Company
    Inventors: Sheridan E. Vincent, Michael D. Purol
  • Patent number: 4211835
    Abstract: A method of processing light-sensitive silver halide photographic material to be treated with a developing solution containing no hydroquinones developing agent, which material comprises a support, a silver halide emulsion layer coated thereon containing silver halide grains having an average grain size of 0.1 to 0.8.mu., at least 75% of said grains being within a range of 0.6 to 1.4 times the said average grain size, and a tetrazolium specified compound.
    Type: Grant
    Filed: January 16, 1978
    Date of Patent: July 8, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yoshio Nishina, Syunji Matsuo, Toshio Nagatani, Kazuo Takahashi, Takeshi Habu