Methyl-p-aminophenol And Dihydroxy Benzene Patents (Class 430/482)
  • Patent number: 9075051
    Abstract: The specification generally discloses systems and methods for mixing and delivering fluids in microfluidic systems. The fluids can contain, in some embodiments reagents that can participate in one or more chemical or biological reactions. Some embodiments relate to systems and methods employing one or more vent valves to controllably flow and/or mix portions of fluid within the microfluidic system. Advantageously, fluid control such as a sequence of fluid flow and/or a change in flow rate, can be achieved by opening and closing one or more vent valves and by applying a single source of fluid flow (e.g., a vacuum) operated at a substantially constant pressure. This can simplify the operation and use of the device by an intended user.
    Type: Grant
    Filed: April 22, 2013
    Date of Patent: July 7, 2015
    Assignee: OPKO Diagnostics, LLC
    Inventors: Enqing Tan, Vincent Linder
  • Patent number: 6770406
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a residue of removing a hydrogen from wherein X, Y, and Z represent substituents selected independently from the groups hydrogen, alkyl group of 1 to 6 carbon atoms, cyclopropyl, aryl, arylalkyl, and heterocyclic groups, wherein at least one of X, Y, and Z is an aryl group and one of X, Y, Z, which may or may not be an aryl group, is attached in the direction of the backbone, and the other substituents are as defined in the specification. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: August 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Douglas R. Robello, David H. Levy
  • Patent number: 6087078
    Abstract: Low silver black-and-white photographic silver halide elements, such as radiographic films, can be processed quickly using black-and-white developing and fixing compositions having reduced photoprocessing activity. The entire process is fairly rapid and effective despite the lowered concentrations of photographic developing and fixing agents.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: July 11, 2000
    Assignee: Eastman Kodak Company
    Inventors: Alan S. Fitterman, Robert E. Dickerson
  • Patent number: 5994040
    Abstract: A processing composition for silver halide photographic light-sensitive material, which comprises at least one compound represented by the following formula (A), (A-I) or (A-II) and at least one compound represented by the following formula (B): ##STR1## Also disclosed are a developer prepared from the processing composition, and a processing method using the developer.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinnichi Morishima, Kohzaburoh Yamada, Seiji Yamashita, Minoru Sakai, Kouta Fukui, Eiichi Okutsu
  • Patent number: 5840472
    Abstract: A developer for a silver halide photographic photosensitive material containing at least one of monocyclic dimercaptotriazine compounds, bis-type dimercaptotriazine compounds, mercapto-1,2,4-triazine compounds and dimercaptopyrimidine compounds, and a process for developing a silver halide photographic photosensitive material using the developer. The compounds of the present invention provides excellent effect in preventing silver stains without affecting the photographic properties of the photographic material.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirotomo Sasaki, Harumi Watanabe, Kohzaburoh Yamada
  • Patent number: 5830618
    Abstract: A silver halide photographic material is provided which comprises a support having thereon at least one light-sensitive silver halide emulsion layer wherein said light-sensitive layer or another hydrophilic colloidal layer provided on the support contains a compound represented by formula (I) and a hydrazine derivative represented by formula (II): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydroxyl, hydroxylamino, amino, alkylamino, arylamino, aralkylamino, alkoxy, phenoxy, alkyl, aryl, alkylthio, or phenylthio group, ##STR2## wherein R.sup.3 represents an aliphatic or aromatic group; R.sup.4 represents a hydrogen atom, or an alkyl, aryl, alkoxy, aryloxy, amino or hydrazino group; G.sup.1 represents a --CO--, --SO.sub.2 --, --SO--, --P(O)R.sup.4, --CO--CO--, thiocarbonyl or iminomethylene group; and A.sup.1 and A.sup.2 each represents a hydrogen atom, or one of A.sup.1 and A.sup.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 3, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Yamaguchi
  • Patent number: 5798204
    Abstract: A development processing method is described, which includes the steps of (a) exposing an ultrahigh-contrast silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and (b) developing the exposed silver halide photographic material with a developer while the developer is replenished with a development replenisher, wherein the developer and the development replenisher each contains a dihydroxybenzene developing agent and an auxiliary developing agent exhibiting a superadditive property to the dihydroxybenzene developing agent, and both the developer and the development replenisher have such a property that an increase of the pH is 0.25 or less when 0.1 mol of sodium hydroxide is added to 1 liter thereof; the developer has a pH from 9.5 up to but excluding 11.0; and the developer replenisher is added in an amount of 225 ml/m.sup.2 or less.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: August 25, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Mitsunori Hirano, Nobuaki Inoue
  • Patent number: 5770351
    Abstract: There is described a method of processing silver halide photographic material in a processing machine using a developing solution which comprises either a hydroquinone type developing agent or a reductone type developing agent, together with an electron transfer agent as an auxiliary developing agent, and with at least one basic compound the anion of which is carbonate, sulphite or hydroxide, where in the presence of a compound of formula (I), Ar is an aromatic ring or heterocyclic aromatic ring which is optionally substituted.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: June 23, 1998
    Assignee: Ilford Limited
    Inventors: William Edward Long, Michael John Parker
  • Patent number: 5766833
    Abstract: An image-forming process developing a previously image-exposed silver halide photographic material with an alkaline developer containing a reductone compound as a main developing agent in the presence of a 1,2,5-thiadiazole compound and/or a 2,1,3-benzothiadiazole compound, and the silver halide photographic material and the photographic developer being used for the process are disclosed. In this case, the 1,2,5-thuiadiazole compound and/or the 2,1,3-benzothiadiazole may be contained in the silver halide photographic material and/or the alkaline developer. Super high-contrast images for photomechanical process having a gamma of higher than 15 and having no pepper and less fog can be obtained.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: June 16, 1998
    Assignee: Dainippon Ink and Chemicals Inc.
    Inventors: Kiyoshi Suematsu, Hiroaki Muratake, Haruhiko Kaji, Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu
  • Patent number: 5545508
    Abstract: A process for forming a black-and-white high contrast negative photographic silver image by development of a silver halide photographic element with an aqueous alkaline photographic developer composition comprising a dihydroxybenzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant compound, a combination of buffering agents and a sequestering agent, characterized by the fact that: a) the auxiliary developing agent is an aminophenol compound, b) the combination of buffering agents comprises at least a first buffering agent represented by carbonate compounds and at least a second buffering agent represented by phosphate compounds, the total amount of said first buffering agent and said second buffering agent being at least 35 grams per liter, band c) the pH of said aqueous alkaline photographic developer composition is in the range 9.0 to 11.0.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: August 13, 1996
    Assignee: Minnesota Mining and Manufacturing
    Inventors: Carlo Marchesano, Elda Moizo, Filippo Faranda
  • Patent number: 5368983
    Abstract: A method for forming an image provides high sensitivity, high contrast, and reduced fluctuation in performance due to the deterioration of processing solutions. The method comprises processing a silver halide photographic material having on a support at least two silver halide emulsion layers having different sensitivities, with the emulsion layer closer to the support having a higher sensitivity, in a developing solution containing a di- or trihydroxybenzene compound and a 3-pyrazolidone compound or a developing solution containing a di- or trihydroxybenzene compound and an aminophenol compound in the absence of a hydrazine compound, wherein a characteristic curve obtained has a gradient (a .gamma. value) of 6.0 or more in the segment of the curve from D=0.1 to D=3.0 where D is the density.
    Type: Grant
    Filed: October 26, 1993
    Date of Patent: November 29, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Okamoto
  • Patent number: 5344741
    Abstract: The present invention provides a developer for silver halide photographic light-sensitive materials which provides super-high contrast and is improved in stability with time. This developer contains at least (1) a developing agent, (2) 10 g/l or more of a hydroquinonemonosulfonate, (3) 0.3 mol/l or more of a sulfite and (4) an amino compound in an amount necessary to accelerate enhancement of contrast and has a pH of 10.5-12.3.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: September 6, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Tamotu Iwata, Seiichi Sumi
  • Patent number: 5266442
    Abstract: A method for the production of a silver image with improved contrast by the development of an image-wise exposed photographic silver halide emulsion layer material with a developer liquid containing a hydroquinone in the presence of an auxiliary developing agent, wherein said developer liquid is applied to said photographic material containing silver halide grains that have been chemically sensitized with organic thiosulphonic acid anions in combination with a gold sensitizer in the absence of thiosulphate ions.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: November 30, 1993
    Assignee: Agfa-Gevaert N.V.
    Inventor: Richard A. Ooms
  • Patent number: 5210010
    Abstract: There is described a concentrated developer solution which comprises from about 20 to about 60 g/l of dihydroxybenzene developing agent, preferably hydroquinone, from about 0.5 to about 3.0 g/l of an auxiliary developing agent, preferably 1-phenyl-3 pyrazolidinone, from about 300 to about 500 g/l of potassium sulphite and which is buffered to a pH of from about 8 to about 10 with a buffering agent other than an alkanolamine and which comprises sufficient organic solvent other than an alkanolamine to dissolve the hydroquinone.Such a concentrated developing solution which contains a high concentration of potassium sulphite has when diluted a long useful life and produces images of low graininess.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: May 11, 1993
    Assignee: Ilford Limited
    Inventor: Ross Fielding
  • Patent number: 5206123
    Abstract: A method for high contrast development of an image-wise exposed photographic element comprising a support and at least one silver halide emulsion layer, which method comprises contacting said exposed element in the presence of a hydrazine compound with an aqueous alkaline developing solution which has a pH between 10 and 13 and contains a dihydroxybenzene developing agent a 3-pyrazolidinone or an aminophenol developing agent sulphite ions and a contrast promoting amount of an amino compound characterized in that said developing solution further contains an aprotic solvent corresponding to general formula (I) or (II) : ##STR1## wherein R.sub.1 represents alkyl, substituted alkyl, alkylamino or substituted alkylamino, andR.sub.2 and R.sub.3 each independently represent alkyl substituted alkyl orwherein R.sub.1 together with R.sub.2 represent the necessary atoms to form together with the carbon and the nitrogen atom respectively to which they are attached, a heterocyclic ring, and R.sub.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: April 27, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Richard A. Ooms, Piet Kok
  • Patent number: 5141843
    Abstract: A developer liquid suited for use in development of photographic silver halide emulsion layer materials which liquid contains:1) hydroquinone or a substituted hydroquinone as sole developing agent or said hydroquinone as main developing agent in combination with an auxiliary developing agent in an amount less than 10 mole % with respect to the main developing agent,2) an inorganic compound yielding free sulphite ions in an amount of at least 5 grams per liter,3) an organic anti-fogging agent corresponding to the following general formula (Z): ##STR1## wherein: X.sup.2 represents an alkyl group or an aryl group including said groups in substituted form or an amino group including said group in substituted form;the amount of anti-fogging agent being in the range of 50 mg to 1 g per liter,4) a polymer containing a plurality of alkylene oxide units, and5) the necessary alkaline material to have in said liquid a pH of at least 10.5. Optional additives can also be present in the developing liquid.
    Type: Grant
    Filed: March 27, 1991
    Date of Patent: August 25, 1992
    Assignee: AGFA-Gevaert N. V.
    Inventors: Richard A. Ooms, Piet Kok, Jean-Marie O. Dewanckele
  • Patent number: 4948713
    Abstract: There are disclosed a processing solution of a light-sensitive silver halide color photographic material, which comprises containing a compound represented by the formula (I) shown below, and a processing method of the same, which comprises subjecting a light-sensitive silver halide color photographic material having at least one layer of silver halide emulsion layer on a support to imagewise exposure and then applying processing including at least a color developing processing, characterized in that the color developing solution to be used in the color developing processing contains a compound represented by the formula (I) shown below: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.2 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.1 and R.sub.2 may be bonded with each other to form a ring containing an oxygen atom.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: August 14, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuhiro Kobayashi, Shigeharu Koboshi, Satoru Kuse, Masao Ishikawa
  • Patent number: 4740452
    Abstract: The present invention provides a process for preparing a negative image of high contrast comprising developing an exposed silver halide photographic material which is substantially a surface latent image-type material in the presence of a hydrazine derivative, wherein said material is processed with a water-soluble alkaline developer having a pH value of from 10.5 to 12.3 and at least comprising the following components (1) through (3):(1) a dihydroxybenzene-type developing agent;(2) 0.3 mole/liter (developer) or more of a sulfite preservative; and(3) from 0.01 to 0.30 mole/liter (developer) of a compound of formula (A) ##STR1## in which R.sub.2 represents an alkyl group having from 3 to 6 carbon atoms; R.sub.3 and R.sub.4 each represents an alkyl or hydroxyalkyl group having from 1 to 10 carbon atoms.The formed negative images are of high contrast and are almost free from silver stain. The sensitivity is high and the dot image quality is good.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Mitsunori Hirano
  • Patent number: 4668605
    Abstract: A silver halide photographic material containing a hydrazine derivative of the general formula (I):R.sub.1 --NHNHCHO (I)wherein R.sub.1 is a substituted or unsubstituted aryl group, is developed with high contrast by the use of an aqueous alkaline developer having a pH value of 10.5 to 12.3 and comprising the following components (1) through (5):(1) a dihydroxybenzene type developing agent;(2) a p-aminophenol type developing agent;(3) at least 0.3 mol/l of a sulfite preservative;(4) 0.05 to 0.30 mol/l of an alkanolamine of the general formula (II):(C.sub.2 H.sub.5).sub.2 N--R.sub.2 (II)wherein R.sub.2 is a hydroxyalkyl group having 2 to 10 carbon atoms; and(5) 10.sup.-4 to 10.sup.-2 mol/l of a mercapto compound of the general formula (III); ##STR1## where M.sub.1 and M.sub.2 are the same or different and each is a hydrogen atom, an alkali metal atom or an ammonium group;whereby a negative image of high contrast may be formed on said photographic material.
    Type: Grant
    Filed: June 5, 1985
    Date of Patent: May 26, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Mitsunori Hirano
  • Patent number: 4650746
    Abstract: This invention relates to a photographic element comprising a support, and coated on the support at least one negative-working photographic emulsion comprising radiation-sensitive silver halide grains capable of forming a surface latent image and a binder, and in the support or in a remaining hydrophilic colloid layer coated on the support in an amount sufficient to increase contrast, a hydrazine compound of the formula ##STR1## wherein R.sup.1 is a phenyl nucleus having a Hammet sigma value-derived electron withdrawing characteristic of less than +0.30.
    Type: Grant
    Filed: July 12, 1979
    Date of Patent: March 17, 1987
    Assignee: Eastman Kodak Company
    Inventors: Joseph M. Simson, Harold E. Jordan
  • Patent number: 4262086
    Abstract: A developer for black and white film comprising an active portion which includes from 16 percent to 23 percent by weight of hydroquinone, 23 percent to 30 percent by weight of a developer selected from the group consisting of Metol and Elon, 24 percent to 31 percent by weight potassium bromide and 24 percent to 32 percent by weight of sodium hydroxide such that the total percentage of these active ingredients comprises 100 percent of the active weight. Also included is a preservative portion such as sodium sulfite in amounts ranging from one-third to three times the weight of the active portion of the developer solution. Finally, sufficient water is present in the developer of this invention to provide an aqueous solution of the active portion of less than ten percent by weight active portion, based on the amount of water.
    Type: Grant
    Filed: June 22, 1978
    Date of Patent: April 14, 1981
    Assignee: F. F. D., Inc.
    Inventor: Richard P. Lindman
  • Patent number: 4224401
    Abstract: A negative image silver halide photographic emulsion comprising substantially surface latent image type monodispersed silver bromide or silver iodobromide grains containing up to about 10 mol% silver iodide, wherein the average grain size of the silver halide grains is about 0.7 micron or less, with the silver halide photographic emulsion containing a binder in an amount of about 250 g or less per mol of silver halide and a compound represented by the following general formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group and R.sup.
    Type: Grant
    Filed: December 7, 1978
    Date of Patent: September 23, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunji Takada, Yoshitaka Akimura, Hiroyuki Mifune, Nobuyuki Tsujino
  • Patent number: H2048
    Abstract: A non-hydroquinone photographic developer composition comprising: (a) a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, or alkali metal salts and mixtures thereof, in an amount of 0.1 to 0.4 mol/liter (mol/l); (b) an effective amount of an auxiliary developing agent comprising a 3-pyrazolidone compound, an aminophenol or a mixture thereof; (c) an alkali metal sulfite in an amount less than or equal to 0.32 mol/l; (d) an alkali metal carbonate in an amount of 0.1 to 0.4 mol/l; (e) an alkali metal hydroxide in an amount of from 0.08 to 2.0 mols/l; (f) with the developer composition having a pH of 11.8 or higher at 25° C.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: September 3, 2002
    Assignee: Fuji Hunt Photographic Chemicals, Inc.
    Inventors: Haixing Wan, Diane Zhang, David Carlson, Alan A. Bornstein