Amine Developer Patents (Class 430/484)
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Patent number: 5091292Abstract: There is disclosed a method for processing a silver halide color photographic material with a color developer and thereafter desilvering, wherein the silver halide color photographic material has a thickness of dried coatings of 15 .mu.m or less and the color developer comprises an anionic surface-active agent and a hydroxylamine compound. According to the disclosure staining in the unexposed part of the photographic material can be remarkably improved even in a continuous processing.Type: GrantFiled: August 1, 1990Date of Patent: February 25, 1992Assignee: Fuji Photo Film Co., LtdInventors: Hiroshi Fujimoto, Kiyoshi Morimoto, Takatoshi Ishikawa
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Patent number: 5066571Abstract: A method for processing a silver halide color photosensitive material is disclosed.The method comprises developing a color photographic light-sensitive material composed of a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide comprising at least 98 mol % silver chloride;in a color developer solution comprising a primary amine color developing agent, and having a chloride ion concentration of from 4.times.10.sup.-2 to 1.times.10.sup.-1 mol/l, and a bromide ion concentration of from 5.times.10.sup.-5 to 5.times.10.sup.-4 mol/l.When used in rapid processing methods, the method according to the invention prevents fogging streaks, and provides high maximum density and low minimum density images.Type: GrantFiled: October 3, 1989Date of Patent: November 19, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuaki Yoshida, Takatoshi Ishikawa
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Patent number: 5063144Abstract: Development of a color photographic material in which the emulsion layers contain silver halide grains with a chloride content of at least 80 mol % can be completed within 40 seconds by using a substantially bromide free color photographic developer solution containing, in 1 liter of aqueous solution ready for use, from 4 to 15 g of the developer corresponding to the following formula ##STR1## or a corresponding quantity of its salts, from 8 to 35 g of PO.sub.4.sup.3- ions, at least 0.2 g of antioxidant, from 0.5 to 5.0 g of KCl and other conventional components and adjusted to a pH of from 10.4 to 12.9.Type: GrantFiled: February 20, 1991Date of Patent: November 5, 1991Assignee: Agfa Gevaert AktiengesellschaftInventor: Ubbo Wernicke
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Patent number: 5043254Abstract: A method for forming an image comprises processing a silver halide color photosensitive material comprising a nondiffusible coupler and a nondiffusible color developing agent on a support with a color developer containing a diffusible color developing agent comprising an aromatic primary amine. By this method, it is possible to reduce the processing time required when a color developer containing an ordinary aromatic primary amine as the color developing agent is used and also to provide a stable image forming method having only a slight processing dependence.Type: GrantFiled: November 24, 1989Date of Patent: August 27, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Hajime Nakagawa, Yasuhiro Yoshioka, Takatoshi Ishikawa, Genichi Furusawa, Nobutaka Ohki
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Patent number: 5032494Abstract: Disclosed is a method of processing a light-sensitive silver halide color photographic material comprising; subjecting to exposure a light-sensitive silver halide color photographic material comprising a support; a light-sensitive silver halide emulsion layer containing at least one of a core/shell silver halide grain containing 3.0 mole % or more of silver iodide and a tabular silver halide grain containing 3.0 mole % or more of silver iodide; and a compound capable of releasing at a developing processing a restrainer or restrainer precursor which forms silver salt having the solubility product with a silver ion, of 1.times.10.sup.-9 or less, and thereafter; carrying out a color developing processing by using a color developing solution containing an aromatic primary amine type color developing agent, for a period of 120 seconds or less and so as to have a value of (developed silver amount at the maximum density portion)/(total silver amount), of 0.5 or less.Type: GrantFiled: August 17, 1990Date of Patent: July 16, 1991Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masayuki Kurematsu, Shigeharu Koboshi, Syozo Aoki, Masahiko Kon
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Patent number: 5028517Abstract: A method for processing a silver halide color photographic light-sensitive material is disclosed. Fogging caused by the color developer contaminated by heavy metal ions is surpressed by the processing method. The processing method is excellent in the point that stable photographic propertied can be obtained for long while of running. The processing method comprises a step for developing with a color developer an imagewise exposed light-sensitive material which comprises a support and a photographic layer being provided on the support and including at least one silver halide emulsion layer, wherein the photographic layer has a swelling ratio within the range of from 1.5 to 3.5 and the silver halide emulsion layer comprises a silver halide emulsion having a silver chloride content of not less than 90 mole %, and the developing step is performed for a time of not less than 90 seconds with a color developer containing a compound represented by the following Formula (1): ##STR1## wherein R.sub.1 and R.sub.Type: GrantFiled: May 18, 1989Date of Patent: July 2, 1991Assignee: Konica CorporationInventors: Satoru Kuse, Masao Ishikawa, Yoshimasa Komatsu, Shigeharu Koboshi
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Patent number: 5002862Abstract: A method for processing a silver halide color photographic material is described, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein after imagewise exposure, said silver halide color photographic material is processed with a color developer containing at least one aromatic primary amine developing agent and at least one compound capable of releasing the aromatic primary amine developing agent which has substantially no developing agent ability prior to the release of the aromatic primary amine developing agent.Type: GrantFiled: September 28, 1988Date of Patent: March 26, 1991Assignee: Fuji Photo Film Co.Inventors: Morio Yagihara, Takatoshi Ishikawa, Hiroshi Fujimoto
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Patent number: 4997749Abstract: True-to-type development without any overflow is achieved with a developer solution system of a refill solution and--replenished therewith--a ready-to-use developer solution which contains the following constituents in the quantities indicated per liter aqueous solution and, optionally, other typical consituents:3-15 g of the following color developer compound ##STR1## or a corresponding quantity of salts thereof, 8-35 g PO.sub.4.sup.3 ions,at least 0.2 g antioxidant and2.1-4.2 g KBrand which is adjusted to a pH value of 10.5 to 12.5, the regeneration quota amounting to between 50 and 120 ml/m.sup.2 developed material and the refill solution containing the individual constituents in a such a concentration that, for the above-mentioned regeneration quota, the in-use developer solution always contains the constituents shown above in the quantities indicated.Type: GrantFiled: December 27, 1988Date of Patent: March 5, 1991Assignee: Agfa-Gevaert AktiengesellschaftInventors: Ubbo Wernicke, Herbert Mitzinger
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Patent number: 4994345Abstract: A method for making a color proof in a photo-mechanical process. The method comprises a step for exposing a silver halide color photographic light-sensitive material to light through a black-and-white halftone dot image, and a step for developing said silver halide color photographic light-sensitive material with a color developer. The photographic material is comprised of at least three silver halide emulsion layers which are different from each other in spectral sensitivity thereof, and at least one of these silver halide emulsion layers contains a specific yellow coupler and the color developer contains a specific color developing agent. A halftone color image having a color tone similar to that of image printed with printing inks can be obtained by the simplified process.Type: GrantFiled: June 5, 1989Date of Patent: February 19, 1991Assignee: Konica CorporationInventors: Tomomi Yoshizawa, Keiji Ogi, Nariko Kimura
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Patent number: 4975357Abstract: Hydroxylamine compounds are commonly included in photographic color developing solutions to retard aerial oxidation. When the photographic element processed in the color developing solution is one which contains an aromatic polyhydroxy compound which serves as a stabilizing addendum, there will be a build-up of the level of such compound in the developing solution as seasoning occurs. Also, as a consequence of seasoning, there is a gradual build-up of the level of trace metal impurities in the solution. Interaction of a trace metal impurity with the aromatic polyhydroxy compound can form a metal-complex which catalyzes the oxidation of the hydroxylamine compound and thereby renders it ineffective for its intended purpose. In the improved method of this invention, the color developing solution is protected against the unwanted metal-complex catalyzed oxidation by incorporation therein of an aminopolycarboxylic acid sequestering agent.Type: GrantFiled: May 23, 1989Date of Patent: December 4, 1990Assignee: Eastman Kodak CompanyInventors: Jean M. Buongiorne, Janet M. Huston, Paul A. Schwartz, Sheridan E. Vincent
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Patent number: 4965175Abstract: A method for continuous processing of a silver halide color photosensitive material is disclosed. The process steps comprise developing a color photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide comprising at least 80 mol % silver chloride, in a color developer solution containing a chloride ion concentration of from 3.5.times.10.sup.-2 to 2.0.times.10.sup.-1 mol/l, said developing step being conducted in a developer bath having a bath opening ratio (S/V) of at most 0.015 cm.sup.-1 wherein S is air-contacting area of the bath in cm.sup.2 and V is a total volume of the bath in cm.sup.3.Type: GrantFiled: October 3, 1989Date of Patent: October 23, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Fujimoto, Kazuaki Yoshida
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Patent number: 4963475Abstract: A method of processing an imagewise exposed light-sensitive silver halide photographic material. The material contains a silver halide emulsion layer containing silver halide grains which are sensitized with a monomethine dye. The material is processed with a developer solution containing an aromatic primary amine color developing agent in the presence of at least one hydroxylamine derivative and at least one nitrogen containing heterocyclic mercapto compound.Type: GrantFiled: March 28, 1989Date of Patent: October 16, 1990Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kazuhiro Murai, Keiji Ohbayashi, Kaoru Onodera
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Patent number: 4948713Abstract: There are disclosed a processing solution of a light-sensitive silver halide color photographic material, which comprises containing a compound represented by the formula (I) shown below, and a processing method of the same, which comprises subjecting a light-sensitive silver halide color photographic material having at least one layer of silver halide emulsion layer on a support to imagewise exposure and then applying processing including at least a color developing processing, characterized in that the color developing solution to be used in the color developing processing contains a compound represented by the formula (I) shown below: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.2 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.1 and R.sub.2 may be bonded with each other to form a ring containing an oxygen atom.Type: GrantFiled: March 27, 1989Date of Patent: August 14, 1990Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kazuhiro Kobayashi, Shigeharu Koboshi, Satoru Kuse, Masao Ishikawa
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Patent number: 4937178Abstract: The present inventions relate to a processing method for processing, with a developing time of not more than 180 seconds, a silver halide color photographic light-sensitive material comprising a support, provided thereon, with at least one silver halide emulsion layer, and at least one emulsion layer containing silver iodo-bromide with not less than 0.5 mole% of silver iodine, in particular to an active processing method wherein, a light-sensitive material B not only containing silver iodo-bromide with an iodine content of not less than 0.5 mole% but also a magenta coupler and providing a maximum magenta density, after exposed, and being capable of only satisfying the maximum magenta dye density M of M<2.0 if exposed under specific conditions and then subjected to color developing of a duration of three minutes 15 seconds at 38.degree. C. with a specific developer solution, is capable of offering a maximum magenta density satisfying M.gtoreq.2.Type: GrantFiled: March 7, 1988Date of Patent: June 26, 1990Assignee: Konica CorporationInventors: Shigeharu Koboshi, Satoru Kuse, Masayuki Kurematsu, Moeko Hagiwara
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Patent number: 4920041Abstract: A method for processing a silver halide color photographic material comprising a reflective support having thereon at least one light-sensitive silver halide emulsion layer containing a color coupler or color couplers, which comprises the step of, after imagewise exposing, developing said silver halide color photographic material with a color developing solution which does not substantially contain benzyl alcohol and which contains an aromatic primary amine color developing agent represented by formula (A): ##STR1## wherein X represents a compound capable of forming a salt with a primary amine; and a compound represented by formula (I): ##STR2## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl, alkoxy, aryloxy or amino group; and R.sup.2 represents a hydrogen atom or a substituted or unsubstituted alkyl or aryl group; or R.sup.1 and R.sup.2 may be bonded to each other to form a carbon ring or a hetero-ring.Type: GrantFiled: January 12, 1989Date of Patent: April 24, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutaka Ohki, Kazuto Andoh, Takatoshi Ishikawa
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Patent number: 4906554Abstract: This invention relates to a color developing solution for processing of a light-sensitive silver halide color photographic material which comprises containing a compound represented by the following formula [I] and at least one compound selected from a compound represented by the following formula [II] and a compound represented by the following formula [III], and a processing method of a light-sensitive silver halide color photographic material, which comprises, after imagewise exposure of a light-sensitive silver halide color photographic material, carrying out processing including at least a color developing step, wherein the light-sensitive silver halide color photographic material has silver halide emulsion layers containing silver halide grains substantially comprised of silver chloride, and a color developing solution used in the color developing step contains the compound represented by the following formula [I] and at least one compound selected from the compound represented by the following formulaType: GrantFiled: December 11, 1987Date of Patent: March 6, 1990Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masao Ishikawa, Shigeharu Koboshi, Kazuhiro Kobayashi, Keiji Ohbayashi, Mitsuhiro Okumura, Shigeo Chino, Kaoru Onodera
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Patent number: 4900651Abstract: A method for processing a silver halide color photographic material is disclosed, which comprises developing a silver halide color photographic material with a color developer comprising:(a) an aromatic primary amine color developing agent;(b) at least one brightening agent represented by formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydroxyl group, an alkoxy group, an amino group, an alkylamino group, an aryloxy group or an arylamino group; provided that R.sub.1 is not the same as R.sub.3 when R.sub.2 is the same as R.sub.4, and R.sub.1 is not the same as R.sub.4 when R.sub.2 is the same as R.sub.3 ; and M represents a monovalent cation; and(c) at least one organic phosphonic acid series chelating agent.Type: GrantFiled: February 22, 1988Date of Patent: February 13, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Hiroshi Fujimoto
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Patent number: 4897339Abstract: A method for processing a silver halide color photographic material including a step of developing the material with a developer containing an aromatic primary amine color developing agent and at least one compounds represented by the following general formulae (Ia) and (Ib): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom or an unsubstituted alkyl group; R.sup.5, R.sup.6 and R.sup.7, which may be the same or different, each represents an unsubstituted alkylene group; X.sup.1 and X.sup.2, which may be the same or different, each represents ##STR2## --O--, --S--, --CO--, --SO.sub.2 or --SO--, or a combination thereof, and R.sup.8 represents a hydrogen atom or an unsubstituted alkyl group; and m and n, which may be the same or different, each is 0, 1, 2 or 3; and ##STR3## wherein R.sup.13 represents a substituted alkylene group; and R.sup.9, R.sup.10, R.sup.11 and R.sup.Type: GrantFiled: April 6, 1989Date of Patent: January 30, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuto Andoh, Takatoshi Ishikawa, Morio Yagihara
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Patent number: 4892804Abstract: Photographic color developing compositions which are especially useful in the processing of high chloride silver halide photographic elements are free, or at least substantially free, of bromides; optionally contain a small amount of sulfite; and comprise (1) a primary aromatic amino color developing agent, (2) an N,N-dialkylhydroxylamine, (3) at least one sequestering agent which functions to sequester iron and (4) at least one sequestering agent which functions to sequester calcium. The developing compositions exhibit excellent stability. They also provide minimal development restraint which permits the use of very short development times, as needed for rapid access processing.Type: GrantFiled: August 16, 1988Date of Patent: January 9, 1990Assignee: Eastman Kodak CompanyInventors: Sheridan E. Vincent, Richard W. Berls
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Patent number: 4882264Abstract: A color developer composition that maintains developer activity in all color forming layers and increases developer capacity is disclosed. The color developer composition allows use of reduced temperature, process time, replenishment rate, or concentration of developing agent without causing color imbalance. The composition employs two or more different color developing agents in combination. Each agent in a composition is selected from the group consisting of p-amino-N-dialkylanilines and the salts thereof. The composition of the present invention may be employed in conventional color developing processes without any significant change in conventional processing procedures and steps.Type: GrantFiled: January 20, 1984Date of Patent: November 21, 1989Assignee: Olin Hunt Specialty Products Inc.Inventors: Hongzoon Kim, Edward C. Saunders, Harris Miller
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Patent number: 4876174Abstract: The present invention relates to a method of processing a silver halide color photosensitive material. In particular, to a rapid processing method capable of reducing the development time. In the processing method, an exposed silver halide color photosensitive material having at least one emulsion layer containing a silver halide having a chlorine content of at least 80 molar % based on the total halogens is processed with a color developer containing an aromatic primary amine color developing agent and a dialkylhydroxylamine of the following general formula (I) but substantially free of benzyl alcohol: ##STR1## wherein R.sup.1 and R.sup.2 each represent an unsubstituted or substituted alkyl group or an unsubstituted or substituted alkenyl group or R.sup.1 and R.sup.2 may form a hetero ring together with nitrogen atom.Type: GrantFiled: June 18, 1987Date of Patent: October 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Morio Yagihara
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Patent number: 4873180Abstract: The addition to an aqueous alkaline developer composition for silver halide photographic materials of a dialkylaminomethane diphosphonic acid compound sequestering agent increases the resistance of the developer composition against aerial oxidation and inhibits calcareous deposit formation.Type: GrantFiled: April 6, 1988Date of Patent: October 10, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Carlo Marchesano, Franco Buriano, Enrico Furlanetto
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Patent number: 4851325Abstract: A process for processing silver halide color photographic materials, which comprises processing, after image-wise exposure, a silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a compound represented by the following general formula (I): ##STR1## wherein n represents an integer of at least 1; R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group or the n-valent groups corresponding to the groups when n represents an integer of at least 2; and A represents an organic group containing a carbon atom, an oxygen atom, a nitrogen atom, or a sulfur atom and forms a saturated or unsaturated 3- to 8-membered ring with the nitrogen atom, said A is substituted or unsubstituted and may be condensed with a benzene ring or a heterocyclic ring.Type: GrantFiled: December 30, 1988Date of Patent: July 25, 1989Assignee: Fuji Photo Film Co., Inc.Inventors: Kiyoshi Morimoto, Hideaki Naruse
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Patent number: 4849333Abstract: A method is disclosed for the processing of an imagewise exposed silver halide color photographic material, wherein at least one of wash water and a stabilizing solution used in a step subsequent to a bleach-fixing step or a fixing step following a bleaching step contains at least one compound represented by formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom, a halogen atom, an alkyl group, a substituted alkyl group, an acyl group, a hydroxy group, an amino group, a nitro group, a carboxy group, or a sulfo group.Type: GrantFiled: April 18, 1988Date of Patent: July 18, 1989Assignee: Fuji Photo Cilm Co., Ltd.Inventor: Yoshihiro Fujita
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Patent number: 4842993Abstract: A method for processing a silver halide color photographic material is described, which comprises treating said material after imagewise exposure with a color developer containing an aromatic primary amine developing agent and at least one compound represented by formula (I) ##STR1## in which X.sub.1 and X.sub.2 each represents a divalent organic group. In accordance with this method, the stability and color-forming capacity of the color developer are remarkably improved, the increment of fog during continuous processing of photographic material is greatly reduced, and the color developer need not substantially contain benzyl alcohol.Type: GrantFiled: March 4, 1988Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Hiroshi Fujimoto, Takatoshi Ishikawa, Kazuto Andoh
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Patent number: 4837132Abstract: A method is described for processing a silver halide color photographic material after imagewise exposure, comprising color developing, desilvering, and at least one of washing and stabilizing a silver halide color photographic material, wherein a color developer which does not substantially contain benzyl alcohol but comprises at least one compound represented by formula (I) ##STR1## wherein M.sup.1, M.sup.2, M.sup.3 and M.sup.4 each represents a hydrogen atom, an alkali metal ion, an ammonium ion, or 1/n of an n-valent cation is used for the color development.Type: GrantFiled: May 26, 1987Date of Patent: June 6, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Fujimoto, Takatoshi Ishikawa
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Patent number: 4833068Abstract: A developing solution composition for a silver halide color photographic material is described, comprising an aromatic primary amine color developing agent and a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different each represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sup.3 represents a substituted or unsubstituted alkylene group; and the total number of carbon atoms contained in R.sup.1, R.sup.2 and R.sup.3 is at least 3.The color developer composition has improved stability and color forming properties and remarkably limits fog formation during continuous processing.Type: GrantFiled: July 21, 1987Date of Patent: May 23, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutaka Ohki, Kazuto Andoh, Hiroshi Fujimoto
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Patent number: 4826757Abstract: A process for processing silver halide photographic materials by processing, after development and fixing, the silver halide photographic materials with wash water or a stabilizing solution using a replenisher thereof of not more than 2 liters (including 0) per square meter of the photographic material and drying using a roller transporting type automatic processor, wherein the swelling percentage of the silver halide photographic material is not more than 200% and the total processing time from development to drying is not longer than 70 seconds.Type: GrantFiled: March 18, 1988Date of Patent: May 2, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Minoru Yamada, Kunio Seto
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Patent number: 4818673Abstract: A method for processing a silver halide color photographic material is disclosed, which comprises processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer comprising silver chloride or silver chlorobromide containing at least 80 mol % of silver chloride with a color developing solution and thereafter processing the material with a bleach-fixing solution, wherein the bleach-fixing solution contains a ferric complex salt of an organic acid and from about 1.times.10.sup.-2 to about 2 mol of bromide ions and/or from about 5.times.10.sup.-4 to about 5.times.10.sup.-2 mol of iodide ions per liter.The method for processing a silver halide color photographic material according to the present invention is excellent in desilvering ability, and enables rapid processing to be conducted.Type: GrantFiled: August 5, 1987Date of Patent: April 4, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinji Ueda, Kazunori Hasebe, Junya Nakajima
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Patent number: 4810623Abstract: A process for developing a photographic material containing on a support an image-wise exposed silver halide emulsion layer of which the silver halide is substantially silver chloride and in which the photographic material before its exposure contains already at least one silver halide developing agent in a hydrophilic colloid binder in waterpermeable relationship with the silver halide, said process containing the step of contacting the exposed photographic material with an aqueous alkaline liquid, called activator liquid, being initially substantially free from developing agent(s), said contacting being not followed by a silver complex diffusion transfer processing, characterized in that said aqueous alkaline liquid contains a primary and/or secondary amine.Type: GrantFiled: February 18, 1988Date of Patent: March 7, 1989Assignee: Agfa-Gevaert N.V.Inventors: Hendrik E. Kokelenberg, Benedictus J. Jansen
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Patent number: 4801516Abstract: There is provided a method of processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific hydroxylamine compound. According to this method the stability of a color developer is improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened.Type: GrantFiled: June 24, 1987Date of Patent: January 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Morio Yagihara
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Patent number: 4800153Abstract: There is provided a method for processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific amino compound. According to this method the stability and color forming property of a color developer are improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened. There is also provided a color developer composition which can be used as the developer, as it is or after adjusting its composition.Type: GrantFiled: July 17, 1987Date of Patent: January 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyoshi Morimoto, Takatoshi Ishikawa
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Patent number: 4797350Abstract: A process for forming a dye image is disclosed, in which a silver halide photographic light-sensitive material having a silver halide emulsion layer is developed by a color developer comprising an aromatic primary amine and an N,N- dialkylhydroxylamine. The silver halide emulsion layer contains a hydrophobic dye-forming coupler and a compound selected from the group consisting of compounds having a sterically hindered phenol group and polyalkylpiperidine compounds or the water soluble acid salt thereof. The dye image having a high maximum density and a high light-fastness can be obtained when the color developer without benzyl alcohol is used.Type: GrantFiled: April 6, 1987Date of Patent: January 10, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Keiji Ohbayashi, Shigeo Chino, Mitsuhiro Okumura, Kaoru Onodera
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Patent number: 4774167Abstract: A method for processing a silver halide color photographic material is provided, which comprises subjecting an imagewise exposed silver halide color photographic material having at least one silver halide emulsion layer on a reflective support to color development for a period not exceeding 2 minutes and 30 seconds using a color-developing solution containing substantially no benzyl alcohol, a sulfite in a concentration of 8.times.10.sup.-3 mol/liter or less, and a hydroxylamine in a concentration of 1.5.times.10.sup.-2 mol/liter or less, thereby achieving high color densities of the developed images and reduced fog. The effects of this method are particularly significant in photographic paper containing a pyrazoloazole type magenta coupler.Type: GrantFiled: February 24, 1987Date of Patent: September 27, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Koshimizu, Takatoshi Ishikawa, Shinji Ueda
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Patent number: 4772531Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I) or (II): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent groups, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.Type: GrantFiled: March 9, 1987Date of Patent: September 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Jiro Tsukahara, Kozo Sato
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Patent number: 4767692Abstract: A novel silver halide photographic material is provided comprising a support and at least one silver halide photographic emulsion layer formed thereon and containing in said photographic emulsion layer or at least one hydrophilic colloid layer a compound represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom, an aliphatic residual group, an aromatic residual group, or a heterocyclic residual group; R.sup.3 represents a hydrogen atom or an aliphatic residual group; L.sub.1 represents a divalent aliphatic group, a divalent aromatic group, or a divalent heterocyclic group; L.sub.2 represents --O--, --CONR--, --NRCO--, --SO.sub.2 NR--, --NRSO.sub.2 --, --OCO--, --COO--, --S--, --NR--, --CO--, --SO--, --SO.sub.2 --, --OCOO--, --NRCONR'--, --NRCOO--, --OCONR--, or --NRSO.sub.Type: GrantFiled: January 5, 1987Date of Patent: August 30, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Morio Yagihara, Shigeo Hirano
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Photographic silver halide developer compositions and process for forming photographic silver images
Patent number: 4756997Abstract: An aqueous alkaline photographic silver halide developer composition comprising a dihydroxy benzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant and a buffering agent, characterized by the fact that the composition further comprises a stabilizing amount of an .alpha.-ketocarboxylic acid.The developer composition has a better resistance against air oxidation and can be left in continuous transport automatic processors for several days without undergoing any substantial decrease of its developing properties.The developer composition is particularly useful in a process for the formation of a high contrast silver image by developing silver halide photographic elements including at least a negative acting surface latent image type silver halide emulsion in the presence of a hydrazine compound, preferably in the additional presence of an effective amount of a contrast promoting agent.Type: GrantFiled: July 21, 1987Date of Patent: July 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano -
Patent number: 4738917Abstract: A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.Type: GrantFiled: May 15, 1986Date of Patent: April 19, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeharu Koboshi, Satoru Kuse, Kazuhiro Kobayashi, Masao Ishikawa, Masayuki Kurematsu
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Patent number: 4735884Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkynyl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent group, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.4 is a monovalent group selected from the group consisting of an aryl group, a heterocyclic group, hydrogen, an alkyl group, an alkoxycarbonyl group and carbamoyl, each of which may have one or more substituent groups.Type: GrantFiled: February 24, 1987Date of Patent: April 5, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Jiro Tsukahara, Taku Nakamura
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Patent number: 4699868Abstract: An alkaline aqueous tanning developing solution for photographic image development comprising at least one hydroxylamine derivative. Preferred formulations may also contain at least one water-miscible polyhydroxy aliphatic organic solvent and/or a developing agent which comprises a polyhydroxybenzene compound having at least two hydroxy groups and at least one electron withdrawing and good leaving group suitable for nucleophilic addition.Type: GrantFiled: August 18, 1986Date of Patent: October 13, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gebran J. Sabongi
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Patent number: 4629683Abstract: A method of processing a photographic material which contains a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent capable of releasing a photographically useful agent by ring cleavage of a 4- to 7-membered ring containing at least one carbonyl group in the presence of a hydroxylamine, whereby both high stability of the photographic material upon storage and timely release of the photographically useful agent upon processing are achieved.Type: GrantFiled: April 20, 1984Date of Patent: December 16, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Isamu Itoh, Mitsunori Ono, Keiji Mihayashi, Seiji Ichijima, Hidetoshi Kobayashi
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Patent number: 4596765Abstract: A photographic color forming agent composition comprising an aromatic primary amine color developing agent and materials (A), (B), and (C). Material A is a compound having an aromatic ring bearing two hydroxy groups in the ortho positions thereof. Material B is a hydroxyalkylidene-diphosphonic acid metal ion chelating agent. Material C is at least one metal salt selected from the group consisting of the water-soluble metal salts of magnesium, bismuth, aluminum, zinc, barium, or zirconium. The metal salt is present in an amount in mols equivalent to or more than the amount in mols of metal ion chelating agents of B.Type: GrantFiled: December 4, 1984Date of Patent: June 24, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masayuki Kurematsu, Shigeharu Koboshi
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Patent number: 4588677Abstract: A method for processing a silver halide color photosensitive material which comprises processing a silver halide color photosensitive material containing at least one 4-mercapto-5-pyrazolone type magenta coupler represented by formula (I) ##STR1## wherein W represents an aryl group; X represents an alkyl group, an aryl group or a heterocyclic ring group; and Y represents an acylamino group, a ureido group, or an anilino group; with a color developer containing at least one compound selected from a compound represented by formula (II) ##STR2## wherein R represents a lower alkyl group, and M.sub.1 and M.sub.2, which can be the same or different, each represents a hydrogen atom, and an alkali metal atom, or an ammonium group; a compound represented by formula (III) ##STR3## wherein M.sub.3, M.sub.4, M.sub.5, M.sub.6 and M.sub.Type: GrantFiled: December 28, 1984Date of Patent: May 13, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Junya Nakajima
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Patent number: 4543322Abstract: A process for processing a color photographic silver halide light-sensitive material comprising processing the color photographic silver halide light-sensitive material with a color developer containing at least one compound represented by the general formula (I): ##STR1## wherein X is a hydrogen atom, an alkali metal atom, an ammonium group, an alkyl group, or an aryl group; Y is a substituent on the phenyl group and is a halogen atom, an alkyl group, an alkoxy group, an amino group, a hydroxyl group, a nitro group, a sulfonic acid group or a carboxylic acid group; and n is 0, 1, 2, 3 or 4. Color developers containing the compounds of the general formula (I) have greatly increased stability and thus even after long-term storage, can be used to produce developed materials having superior photographic properties.Type: GrantFiled: March 30, 1984Date of Patent: September 24, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Junya Nakajima
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Patent number: 4501812Abstract: Color developer composition packaged in two or more concentrated parts, which on mixing with water give a ready-for-use silver halide developer solution, one part thereof comprising an aqueous concentrated solution containing a N-hydroxyalkylsubstituted p-phenylene diamine salt developing agent and a sulfite compound, said aqueous concentrated solution having a pH from 6 to 8. In particular, said N-hydroxyalkyl-substituted p-phenylene diamine developing agent is a 4-amino-3-methyl-N-ethyl-N-(.beta.-hydroxyethyl)-aniline and the molar ratio of the sulfite compound to the developing agent is higher than 1.5:1.Type: GrantFiled: February 2, 1984Date of Patent: February 26, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano
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Patent number: 4481286Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.Type: GrantFiled: October 29, 1982Date of Patent: November 6, 1984Assignee: Polaroid CorporationInventors: Patrick F. King, Stephen G. Stroud
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Patent number: 4481268Abstract: A method of forming a photographic azo or azamethine dye image in an exposed photographic silver halide element, the method of comprising the steps of (a) developing the imagewise exposed material to form an imagewise pattern of oxidized color developing agent, (b) reacting the oxidized color developing agent with a color coupler to produce an image dye, characterized in that at least one of the color developing agent and the color coupler possesses a metal chelating site such that the image dye is capable of forming a bi-, tri- or higher-dentate metallized dye, and (c) contacting the image dye with polyvalent metal ions to form a metallized dye image. Specified color developing agents include heterocyclic substituted hydrazides and specified couplers include benziso-oxazolones and 2H-pyrazolo-[3,4-b]pyridines in addition to more conventional compounds.Type: GrantFiled: April 29, 1983Date of Patent: November 6, 1984Assignee: Eastman Kodak CompanyInventors: Joseph Bailey, David Clarke, Michael W. Crawley, Peter D. Marsden, Jasbir Sidhu
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Patent number: 4439519Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein R.sup.1 and R.sup.2 independently represent an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms; R.sup.3 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; X represents a hydrogen atom or a group capable of being removed with alkali; Y represents ##STR2## and Z represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.Type: GrantFiled: May 5, 1983Date of Patent: March 27, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutaka Ohki, Ken Kawata, Isamu Itoh
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Patent number: 4426441Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.Type: GrantFiled: December 3, 1982Date of Patent: January 17, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Roy C. DeSelms
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Patent number: 4420557Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.Type: GrantFiled: October 25, 1982Date of Patent: December 13, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Paul Marx