And Development Inhibitor Or Development Inhibitor Releasing Agent Patents (Class 430/544)
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Patent number: 4950584Abstract: The method of processing a heat-processable color photosensitive material is disclosed. The photosensitive material comprises a support, provided thereon, a photosensitive layer containing a photosensitive silver halide, a dye-donor, a reducing agent and a binder, and a non-photosensitive layer containing at least a binder, wherein a coupler capable of coupling with an oxydized product of the reducing agent to form a substantially colorless product is contained in at least one of the photosensitive layer and the non-photosensitive layer, and is represented by Formula (1); ##STR1## wherein R represents one selected from the group consisting of an alkyl group and an aryl group; and X represents a group of the atoms necessary to form a 5- or 6-membered heterocyclic ring containing at least one selected from the group consisting of nitrogen, sulfur and oxygen.Type: GrantFiled: November 29, 1988Date of Patent: August 21, 1990Assignee: Konica CorporationInventors: Tawara Komamura, Masaru Tsuchiya, Ken Okauchi
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Patent number: 4948712Abstract: The invention provides (1) direct positive photographic photosensitive materials in which at least one type of FR compound which releases fogging agent or development accelerator or a precursor thereof in accordance with the amount of silver developed when the silver halide is being developed is included in a direct positive photographic material comprising at least one layer of non-pre-fogged internal latent image type silver halide emulsion on a support, and (2) a method of forming direct positive images of which the distinguishing features are that in a method for the formation of direct positive images in which a direct positive photographic photosensitive material comprising at least one layer of non-pre-fogged internal latent image forming silver halide emulsion on a support is processed, after image exposure, in a surface developer, at least one type of FR compound which releases fogging agent or development accelerator or precursors thereof is included in the said photographic mateiral, and that the sType: GrantFiled: June 7, 1988Date of Patent: August 14, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Inoue, Tatsuo Heki, Hidetoshi Kobayashi, Naoyasu Deguchi, Shigeo Hirano
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Patent number: 4937179Abstract: A silver halide color photographic material comprising a support having thereon a silver halide emulsion layer, wherein the silver halide color photographic material contains a two-equivalent magenta polymer coupler which is capable of forming a color image upon coupling with an oxidation product of an aromatic primary amine developing agent and has an oil pKa' of 8.0 or more.The two-equivalent magenta polymer coupler has an excellent color forming property, an improved conversion efficiency to a dye and an improved resistivity to decreases in color forming property upon the attack of chemical substances and is free from the formation of undesirable fog when preserved under conditions of high temperature or of high temperature and high humidity.The silver halide color photographic material has a reduced layer thickness and an improved sharpness.Type: GrantFiled: May 27, 1986Date of Patent: June 26, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsumoru Hirano, Kei Sakanoue
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Patent number: 4929540Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide photographic emulsion layer on the support, said emulsion layer containing a 5-pyrazolone coupler having a coupling eliminable group of the following general formula (I) at the coupling site thereof: ##STR1## wherein L.sub.1 represents a substituted or an unsubstituted methylene or ethylene group; l represents 0 or 1; m represents 0 or an integer from 1 to 3; R.sub.1 represents a hydrogen atom, or a substituted or an unsubstituted alkyl, aryl or heterocyclic group; Y represents ##STR2## Q represents a single bond or nonmetal atoms necessary to complete a 5- to 8-membered ring together with ##STR3## said 5- to 8-membered ring may further have a saturated or an unsaturated ring condensed thereto; R.sub.Type: GrantFiled: July 17, 1989Date of Patent: May 29, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Furutachi, Takeshi Hirose
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Patent number: 4927743Abstract: A silver halide color photographic light-sensitive material comprising a support having provided thereon one or more blue-sensitive layers each containing a yellow coupler, one or more green-sensitive layer each containing a magenta coupler, one or more red-sensitive layers each containing a cyan coupler, and one or more protective layers provided on the side of the support and further from the support than the color-sensitive layer which is furthest away from the support, the thickness of the total photographic layers provided on the support from the color-sensitive layer located closest to the support to the protective layers, inclusive, being 18 .mu.Type: GrantFiled: February 26, 1988Date of Patent: May 22, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Koji Tamoto
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Patent number: 4916047Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.Type: GrantFiled: April 29, 1988Date of Patent: April 10, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
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Patent number: 4912025Abstract: A photographic recording material capable of accelerated development is described. The recording material comprises an image-forming coupler compound, a development inhibitor releasing compound and a compound capable of imagewise release of an electron transfer agent.Type: GrantFiled: June 21, 1988Date of Patent: March 27, 1990Assignee: Eastman Kodak CompanyInventors: Norma B. Platt, Drake M. Michno, David A. Steele, David T. Southby
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Patent number: 4912024Abstract: Photographic elements are disclosed having a first coupler represented by the formula:COUP.sub.1 --T--INH--CH.sub.2 --QwhereinCOUP.sub.1 is a coupler moiety,T is a timing group that is bonded to the coupler moiety at a coupling position and that is cleaved from --INH--CH.sub.2 --Q after it is released from the coupler moiety upon exposure and processing of the element, andINH--CH.sub.2 --Q is a development inhibitor moiety wherein Q is a ballasting group, anda second coupler represented by the formula:COUP.sub.2 --(TIME).sub.n --S--R.sub.1 --R.sub.2wherein COUP.sub.2 is a coupler moiety, TIME is a timing group, n is 0 or 1, R.sub.1 is a divalent linking group that does not include a heterocyclic ring attached directly to S, and R.sub.2 is a water solubilizing group.Type: GrantFiled: June 21, 1988Date of Patent: March 27, 1990Assignee: Eastman Kodak CompanyInventors: Drake M. Michno, Richard P. Szajewski, Stephen P. Singer
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Patent number: 4908302Abstract: Light-sensitive silver halide color photographic material comprising a support base having coated thereon at least one silver halide emulsion layer containing a diketomethylene yellow dye forming coupler having in the active coupling position thereof a group providing a compound with development inhibiting properties when the group is released from the active coupling position upon color development reaction, wherein said group corresponds to a 1-(fluoroalkylsubstituted-phenyl)- tetrazolyl-5-thio group.Type: GrantFiled: October 27, 1988Date of Patent: March 13, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventor: Ivano Delpato
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Patent number: 4900657Abstract: Pyrazolone magenta dye-forming couplers are described which provide excellent formaldehyde stability and which result in dyes having good stability to light, heat and moisture and which have higher .beta.max values as compared with dyes obtained from prior described pyrazolone couplers.Type: GrantFiled: May 30, 1989Date of Patent: February 13, 1990Assignee: Eastman Kodak CompanyInventors: Michael W. Crawley, Paul Louis R. Stanley
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Patent number: 4897341Abstract: Remarkably high inter-image and edge effects are obtained when DIR-Couplers corresponding to Formula I are added to multilayered color photographic recording materials, in particular to green sensitive or red sensitive layers. The sharpness and color reproduction may thereby be improved. ##STR1## R.sup.1 and R.sup.2 denote alkyl or an aromatic group, R.sup.3 denotes H, alkyl or acylamino,R.sup.4 denotes H or alkylR.sup.5 denotes alkyl, alkinyl, aryl, acyloxy, carbamoyl or a cyclic imido group andn has the value 0 or 1and the total number of carbon atoms in R.sup.3, R.sup.4 and R.sup.5 is greater than 3 but not greater than 11.Type: GrantFiled: October 19, 1987Date of Patent: January 30, 1990Assignee: Agfa-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Hans Ohlschlager, Friedrich-Wilhelm Kunitz, Dirk Hubner
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Patent number: 4891304Abstract: A silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing a compound represented by formula (I): ##STR1## wherein EAG represents an aromatic group bonding to N.sub.A and capable of accepting an electron;N.sub.A and N.sub.B each represents a nitrogen atom;R.sup.1 represents a lone pair, a .pi.-bond, a .sigma.-bond, or a substituent other than a hyudrogen atom;n represents 2 or 3;m represents 0 when n represents 2, or m represents 1 and N.sub.B has a positive charge when n represents 3;X.sup..crclbar. represents an anion;the groups or bonds represented by R.sup.1 may be combined with each other or may be combined with EAG to form a ring;R.sup.2 represents R.sup.3 --CO--, R.sup.3 --SO.sub.2 --, R.sup.3 --CO--N.dbd.CH--, or R.sup.3 --SO.sub.2 --N.dbd.CH--, wherein R.sup.3 represents an alkyl group, an aryl group, or a heterocyclic group;the group represented by R.sup.2 may be combined with at least one of R.sup.Type: GrantFiled: March 30, 1989Date of Patent: January 2, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Koki Nakamura
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Patent number: 4886736Abstract: A silver halide color photographic material comprising (1) at least one coupler and (2) at least one compound represented by formula (I) ##STR1## wherein EAG represents a group capable of accepting an electron from a reducing substance; R.sup.1 and R.sup.2 each represents a chemical bond or a divalent substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when linked with (Time).sub.t PUG; or R.sup.1 and R.sup.2 each represents a substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when not linked with (Time).sub.t PUG; Time represents a group capable of releasing PUG, which is released by the cleavage of the single bond between the oxygen atom and the nitrogen atom in the compound; t represents 0 or 1; PUG represents a photographically useful group; and the dotted lines mean that at least one of them forms a chemical bond, and a method for forming an image using the material.Type: GrantFiled: June 12, 1987Date of Patent: December 12, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Koki Nakamura, Kei Sakanoue, Seiji Ichijima
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Patent number: 4876182Abstract: A photographic element is described which contains a pyrazolone color coupler compound which provides a dye having improved fastness to light and improved resistance to yellowing when compared with prior known coupler compounds.Type: GrantFiled: May 30, 1989Date of Patent: October 24, 1989Assignee: Eastman Kodak COmpanyInventor: Paul R. Buckland
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Patent number: 4873179Abstract: A method for processing a silver halide color photographic material which comprises, after color development of a silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one compound capable of releasing, upon a reaction with an oxidation product of a developing agent, a compound which is capable of releasing a development inhibitor upon a reaction with another molecule of an oxidation product of a developing agent, treating said photographic material with a liquid having a fixing ability, followed by processing thereof while replenishing washing water or a stabilizing solution in an amount of from 2 to 50 times the amount carried over from the preceding bath per unit area of the silver halide color photographic material.Type: GrantFiled: May 20, 1987Date of Patent: October 10, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Abe, Keiji Mihayashi, Seiji Ichijima
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Patent number: 4870000Abstract: A color photographic recording material containing a coupler which releases a photographically active compound.Couplers corresponding to formula (I) couple with color developers to form yellow to yellow-orange dyes and, in doing so, release the residue X as a photographically active compounds. Where X is a development inhibitor, remarkably high inter-image and edge effects can be obtained. ##STR1## in which R.sup.1 represents alkyl, a heterocyclic or carbocyclic aromatic group or -NH-CO-R.sup.2 ;R.sup.2 represents alkyl, aryl or -NH-R.sup.3 ;R.sup.3 represents alkyl or aryl;Q represents the groups to complete a fused, optionally substituted benzene or heterocyclic ring;X represents the residue of a photographically active compound;TIME represents a bond which, on reaction of the coupler with the oxidation product of a color developer, is released together with the residue X attached thereto and, in turn, releases the residue X as a photographically active compound under the development conditions;n=0 or 1.Type: GrantFiled: March 21, 1988Date of Patent: September 26, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventors: Peter Bergthaller, Rudolf Stolzenburg, Dirk Hubner
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Patent number: 4865963Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] ##STR1## wherein, R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R.sup.1 and R.sup.2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R.sub.1 and R.sub.2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R.sup.1, R.sup.2 or X.By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.Type: GrantFiled: September 30, 1986Date of Patent: September 12, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Furutachi, Tadahisa Sato, Seiki Sakanoue, Akio Mitsui, Minoru Sakai, Masakazu Morigaki, Hidetoshi Kobayashi, Nobuo Sakai, Kiyoshi Nakazyo, Takeshi Hirose, Toshio Kawagishi
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Photographic element and process comprising a compound which comprises two timing groups in sequence
Patent number: 4861701Abstract: Photographic compounds capable of releasing a photographically useful group are more effective in photographic materials when the photographic compounds comprise at least two differing timing groups in sequence between a carrier moiety and the photographically useful group. The two timing groups in sequence enable improved timing and control of release of the photographically useful group.Type: GrantFiled: October 5, 1987Date of Patent: August 29, 1989Assignee: Eastman Kodak CompanyInventors: Paul A. Burns, Terry R. Taber -
Patent number: 4859578Abstract: A photographic recording material is disclosed which is capable of providing improved granularity properties without sacrifice in other desirable photographic properties. The recording material comprises an image dye-forming coupler compound, a development inhibitor releasing compound, a compound capable of imagewise release of a soluble mercaptan compound and a compound capable of imagewise release of an electron transfer agent.Type: GrantFiled: June 21, 1988Date of Patent: August 22, 1989Assignee: Eastman Kodak CompanyInventors: Drake M. Michno, Norma B. Platt, David A. Steele, David T. Southby
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Patent number: 4857448Abstract: An improved photographic silver halide element comprises a support, and an emulsion layer unit containing one or more photographic silver halide emulsions sensitized to the same spectral region and, adjacent each side of the emulsion layer unit, a layer substantially free of active silver halide containing an image modifier which is a compound capable of imagewise releasing an image-modifying compound on silver halide development wherein at least one of the layers contains a dye image-forming coupler. Such a layer arrangement enables greater control of the emulsion layer's response to oxidized developer generated upon processing.Type: GrantFiled: March 11, 1988Date of Patent: August 15, 1989Assignee: Eastman Kodak CompanyInventor: Michael J. Simons
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Patent number: 4857440Abstract: Photographic compound (A) capable of releasing a photographically useful group by means of intramolecular nucleophilic displacement exhibits increased resistance to hydrolysis when the compound contains in a coupling position a coupling-off group represented by the formula: ##STR1## wherein Q, R.sub.q, R.sub.1, R.sub.2, R.sub.3, n and PUG are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process.Type: GrantFiled: June 30, 1988Date of Patent: August 15, 1989Assignee: Eastman Kodak CompanyInventors: William J. Begley, Michael J. Carmody, John M. Buchanan
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Patent number: 4857447Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising (1) a coupler having a dye moiety, the maximum absorption wavelength of which is shifted to the shorter wavelength by a bond cleaving, directly or through a timing group, due to a coupling reaction with an oxidized product of an aromatic primary amine-based developing agent, and, as a result of the reaction, forming a compound having a dye portion which has the original maximum absorption wavelength before shifting; and (2) a compound releasing a development inhibitor directly or through a timing group upon reacting with the oxidized aromatic primary amine-based developing agent.Type: GrantFiled: May 28, 1986Date of Patent: August 15, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Koji Tamoto, Mitsunori Ono
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Patent number: 4855220Abstract: A photographic element is disclosed that comprises a support having thereon spectrally-sensitized light-sensitive silver halide, a color dye-forming coupler, a DIR compound capable of inhibiting development of the silver halide, and, between the silver halide layer and the source of the image exposure, a layer comprising a non-diffusible filter dye that absorbs light in the region of the spectrum to which the silver halide is sensitized.Type: GrantFiled: January 14, 1988Date of Patent: August 8, 1989Assignee: Eastman Kodak CompanyInventor: Richard P. Szajewski
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Patent number: 4853321Abstract: A method of forming a color image and a silver halide color photographic material comprising a reflective support having thereon at least one light-sensitive layer containing at least one coupler which forms a dye upon a coupling reaction with an oxidation product of an aromatic primary amine color developing agent and a silver halide emulsion which contains at least 80% by mol of silver chloride and substantially no silver iodide the method comprising processing with a color developing solution which contains not more than 0.002 mol of a bromine ion per liter and substantially no benzyl alcohol for a development time of not more than 2 minutes and 30 seconds in the presence of at least one compound represented by the following formulae (I), (II), or (III), as defined in the specification.The method of forming a color image and the silver halide color photographic material according to the present invention enable rapid processing to be conducted while controlling the fog formation with high sensitivity.Type: GrantFiled: May 19, 1987Date of Patent: August 1, 1989Assignee: Fuji Photo Film, Co., Ltd.Inventors: Yasuhito Momoki, Masahiro Asami, Nobuo Sakai, Shigeaki Otani
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Patent number: 4849325Abstract: A light-sensitive material package unit having an exposure function is disclosed, in which said light-sensitive material comprises a support having provided thereon at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, and at least one blue-sensitive silver halide emulsion layer containing a yellow coupler; at least one of said light-sensitive emulsion layers is composed of at least two layers being substantially the same in color sensitivity and different in sensitivity; and said light-sensitive emulsion layer composed of at least two layers contains a compound represented by formula (I)A--L.sub.1).sub.b Z.sub.1 (I)wherein A represents a component capable of releasing --(L.sub.1).sub.b Z.sub.1 upon reacting with an oxidation product of a color developing agent; L.sub.1 represents a timing group; Z.sub.Type: GrantFiled: June 30, 1987Date of Patent: July 18, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Noboru Sasaki, Keisuke Shiba
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Patent number: 4847185Abstract: Photographic compounds capable of releasing a photographically useful group (PUG) by means of an intramolecular nucleophilic displacement provide increased image acutance when a coupling-off group in the coupling position of the compound is a group of the formula: ##STR1## wherein PUG is a photographically useful group; Q is N or C--R where R is hydrogen or a substituent that does not adversely affect imaging; and Z represents atoms completing a non-aromatic, heterocyclic ring. The photographic compounds are useful in photographic materials and processes.Type: GrantFiled: June 30, 1988Date of Patent: July 11, 1989Assignee: Eastman Kodak CompanyInventors: William J. Begley, Michael J. Carmody, John M. Buchanan
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Patent number: 4845020Abstract: A method of processing a silver halide photographic material comprising processing the silver halide photographic material in the presence of an antifoggant which is an organic compound which loses its developing restraining function by a reduction oxidation reaction with oxidized developers. The method improves the discrimination between image and non-image areas of the silver halide photographic material by the novel antifoggant which restrains fog selectively in non-image areas without decreasing photographic sensitivity and image density. The organic compound can be an anti-foggant which possesses a moiety according to the Kendall-Pelz rule and either a mercapto group or a cyclic NH group.Type: GrantFiled: July 24, 1987Date of Patent: July 4, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Isamu Itoh, Keiji Mihayashi
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Patent number: 4840880Abstract: High interimage effects and edge effects can be obtained in multilayer color photographic recording materials if yellow DIR couplers of formula I are used therein, particularly if used in green sensitized or red sensitized layers. Sharpness and color reproduction are substantially improved. ##STR1## wherein R.sup.1 denotes a straight chained or branched alkyl group with up to 18 carbon atoms;R.sup.2, R.sup.3 denote identical or different alkyl groups with up to 18 carbon atoms;R.sup.4 denotes H, halogen, alkyl with up to 6 carbon atoms or alkoxy with up to 6 carbon atoms;R.sup.5 denotes H or alkyl with up to 9 carbon atoms; andR.sup.6 denotes a saturated or unsaturated aliphatic group with up to 10 carbon atoms,the total number of carbon atoms in R.sup.5 and R.sup.6 being not less than 5 and not greater than 10.Type: GrantFiled: July 20, 1987Date of Patent: June 20, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventors: Hans Ohlschlager, Gunter Renner, Friedrich-Wilhelm Kunitz, Heinrich Odenwalder, Dirk Hubner
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Patent number: 4840887Abstract: A silver halide photographic material is disclosed, which comprises a support having formed thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains, in the silver halide emulsion layer, other hydrophilic colloid layer(s), or both, a compound represented by formula (I) ##STR1## wherein EAG represents an electron accepting group, --SO.sub.2 -- represents a sulfonylene group; X represents an oxygen atom (--O--), a sulfur atom (--S--) or an atomic group (--N(R.sub.2)--) containing a nitrogen atom; the single bond between --SO.sub.2 and X being cleaved after EAG receives an electron, wherein R.sub.1 and R.sub.2 each represents a simple bond or a group other than a hydrogen atom; said R.sub.1, R.sub.2, EAG may be combined with each other to form a ring; (Time) represents a group capable of releasing a photographically useful group (PUG) upon the cleavage of the SO.sub.Type: GrantFiled: April 29, 1988Date of Patent: June 20, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Koki Nakamura
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Patent number: 4837136Abstract: A silver halide photographic material is described comprising a support having coated thereon at least one silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layer contains a nondiffusible photographically useful compound having a sulfo group and a group represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group having at least 2 carbon atoms and r represents 0 or 1.The compounds represented by the general formula (I) are photographically useful compounds which impart excellent photographic properties to silver halide photographic materials, including improved dispersibility.Type: GrantFiled: October 9, 1986Date of Patent: June 6, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Yasuhiro Shimada, Jun Arakawa
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Patent number: 4833070Abstract: Remarkably high interimage and Eberhard effects are obtained when yellow DIR couplers corresponding to formuls I are added to multilayered color photographic recording materials, in particular to the green-sensitive or red-sensitive layers. These couplers can improve the sharpness and color reproduction. ##STR1## R.sup.1 denoted alkyl or aryl, R.sup.2 denotes alkyl with up to 18 carbon atoms,R.sup.3 denotes halogen, SO.sub.2 --R.sup.6, SO.sub.2 --NR.sup.7 --R.sup.8 or NH--SO.sub.2 --R.sup.6,R.sup.4 denoted H, alkyl or aryl.R.sup.5 denotes alkyl, cycloalkyl, alkinyl, aralkyl or aryl,R.sup.6 denotes alkyl or aryl,R.sup.7 denotes H or alkyl andR.sup.8 denoted H, alkyl, aryl, CO--R.sup.6 or ##STR2## and the total number of carbon atoms in R.sup.4 and R.sup.5 is not greater than 11.Type: GrantFiled: August 28, 1987Date of Patent: May 23, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventors: Friedrich-Wilhelm Kunitz, Hans hlschlager, Heinrich Odenwalder, Dirk Hubner
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Patent number: 4830954Abstract: The sensitivity of color photographic negative films may be increased without loss of color quality or sharpness by applying at least one panchromatically sensitized, highly sensitive and black-coupling layer as uppermost, additional light sensitive and dye-forming layer on the side of the film facing the object and including in the negative material sufficient DIR-Coupler to produce an interimage effect of .gtoreq.10% in the yellow region, .gtoreq.25% in the magenta region and .gtoreq.15% in the cyan region.Type: GrantFiled: February 21, 1987Date of Patent: May 16, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventor: Reinhart Matejec
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Patent number: 4830955Abstract: The present invention relates to a silver halide photographic light-sensitive material comprising a support, at least one silver halide emulsion layer containing silver halide crystals, the silver chloride content of which being not less than 80 mol %, at least one compound which is represented by general formula [I], of which acid dissociation constant (Ka) and the solubility product (Ksp) with silver ion are not more than 1.times.10.sup.-8 and not more than 1.times.10.sup.-10, respectively; ##STR1## (wherein Z represents a group of atoms necessary to complete a heterocyclic ring) and at least one azaindene compound having at least one hydroxyl group.Type: GrantFiled: April 21, 1987Date of Patent: May 16, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Makoto Kajiwara, Kaoru Onodera
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Patent number: 4824772Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the material contains at least one compound represented by general formula (I) described below and at least one compound represented by general formula (II) described below.A--PDI (I)wherein A represents a group capable of releasing PDI upon reaction with an oxidation product of a developing agent; and PDI represents a group which forms a development inhibitor upon reaction with an oxidation product of a developing agent after being released from A; ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being released upon coupling; Za, Zb and Zc each represents a methane group, a substituted methine group, .dbd.N-- or --N--, wherein one of the Za--Zb bond and the Zb--Zc bond is a double bond and the other is a single bond; wherein R.sub.Type: GrantFiled: December 29, 1986Date of Patent: April 25, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Keiji Mihayashi
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Patent number: 4818670Abstract: A silver halide photographic material is disclosed, which has high image quality in addition to high sensitivity. The photographic material comprises a support and at least one silver halide light-sensitive emulsion layer containing a compound being capable of splitting off a diffusible development-inhibitor or a precursor thereof upon a reaction with an oxidized product of a color developing agent. At least one of the silver halide light-sensitive emulsion layer layer and a layer adjacent to the light-sensitive emulsion layer contains a silver halide emulsion comprising a silver halide grain having an internal fog nucleus.Type: GrantFiled: February 17, 1987Date of Patent: April 4, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshihiko Yagi, Hiroshi Shimazaki
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Patent number: 4814261Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer, the silver halide emulsion layer or a layer adjacent to the emulsion layer comprising a compound represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3, which may be the same or different, each represents a hydrogen atom or a group cleaved by an alkali; R.sub.4 represents an electron attracting group having .sigma..rho. value of Hammett's substituent constant of 0.3 or more; R.sub.5 represents a group substitutable on the benzene ring; n represents 0 or 1; and DI represents a development restrainer or a precursor thereof; and when any two of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are adjacent each other, each of the two groups may represent a divalent group and the two groups may be bonded to form a heterocyclic group.Type: GrantFiled: July 16, 1987Date of Patent: March 21, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Shigeo Hirano
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Patent number: 4806459Abstract: A color photographic material comprising a support having provided thereon a blue-sensitive silver halide emulsion layer containing at least one coupler capable of reacting with an oxidation product of an aromatic primary amine developing agent to form a yellow dye, at least one coupler capable of reacting with said oxidation product to form a cyan dye and not to produce a diffusible development inhibitor or a precursor thereof, and at least one compound capable of reacting with said oxidation product to produce a diffusible development inhibitor or a precursor thereof.Type: GrantFiled: May 6, 1987Date of Patent: February 21, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsumi Makino, Noboru Sasaki, Koji Takahashi
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Patent number: 4801520Abstract: A direct positive color light-sensitive material comprising a support having provided thereon at least one photographic emulsion layer containing unfogged internal latent image type silver halide particles and a color image forming coupler, wherein said color image forming coupler itself is substantially nondiffusible and produces or releases a dye upon oxidation coupling with a color developing agent, and said light-sensitive material contains at least one development inhibitor-releasing type coupler selected from the group consisting of compounds represented by formulae (D-I) and (D-II)Coup--Z (D-I)Coup--TIME--Z (D-II)wherein Coup represents a coupler residual group; Z represents a diffusible development inhibitor or a precursor thereof; and TIME represents a timing group.Type: GrantFiled: July 17, 1987Date of Patent: January 31, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Inoue, Tatsuo Heki
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Patent number: 4798784Abstract: A method for processing a silver halide color photographic material which comprises, after color development of an exposed silver halide color photographic material containing a hydrolyzable type DIR coupler, rapidly processing the developed silver halide color photographic material with a liquid having a bleaching ability and subsequently with a liquid having a bleach-fixing ability, to thereby form a color image.In accordance with the method for processing a silver halide color photographic material, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained.Type: GrantFiled: November 26, 1986Date of Patent: January 17, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinzo Kishimoto, Toshihiro Nishikawa, Akira Abe, Junya Nakajima
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Patent number: 4791049Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by the following general formula (I):A--Time).sub.t X (I)wherein A represents an oxidation reduction moiety comprising an atomic group which does not enable --Time).sub.t X to be released until the oxidation reduction moiety is oxidized during photographic development processing; Time represents a timing group which is connected to A through a sulfur atom, a nitrogen atom or an oxygen atom; t represents an integer of 0 or 1; and X represents a group represented by the following general formula (II): ##STR1## wherein R represents a straight chain or branched chain alkylene group, a straight chain or branched chain alkenylene group, a straight chain or branched chain aralkylene group or an arylene group; Z represents a polar substituent; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.Type: GrantFiled: April 23, 1987Date of Patent: December 13, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Shigeo Hirano, Hideo Usui
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Patent number: 4782012Abstract: Photographic elements and processes are described which employ compounds capable of releasing, as a function of silver halide development, a deactivatable development inhibitor to provide a combination of desirable sensitometric results. The deactivatable development inhibitor has the structure: ##STR1## wherein X is alkylene of 1 to 3 carbon atoms;R is alkyl of 1 to 4 carbon atoms; andthe sum of the carbon atoms in X and R is 5 or less.Type: GrantFiled: July 17, 1987Date of Patent: November 1, 1988Assignee: Eastman Kodak CompanyInventors: Roy C. DeSelms, Jon A. Kapecki
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Patent number: 4772546Abstract: A silver halide photographic material is described, having at least one light-sensitive silver halide emulsion layer containing an iodine-containing silver halide on a support and having one or more auxiliary layers on the outermost surface of a light-sensitive silver halide emulsion layer positioned farthest from the support, wherein at least one of the auxiliary layers contains a substantially non-light-sensitive silver halide emulsion or a silver halide emulsion containing grains whose inner part or surface part is fogged, and the material contains at least one compound represented by formula (I) ##STR1## wherein R, X, Y, Z, and n are described in the specification.Type: GrantFiled: October 10, 1986Date of Patent: September 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoyasu Deguchi, Tetsuro Kojima, Hideo Miyazaki, Shigeru Ohno, Koki Nakamura
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Patent number: 4770982Abstract: A silver halide photographic material is disclosed which contains a compound represented by formula (I)RED--L.sub.1).sub.v B--L.sub.2).sub.w PUG (I)wherein RED represents a group adapted to release the group (L.sub.1).sub.v B--L.sub.2).sub.w PUG upon oxidation: L.sub.1 represents a group adapted to release the group B--L.sub.2).sub.w PUG after cleavage from RED; B represents a group which, after cleavage of the bond with L.sub.1 or RED, releases the group (L.sub.2).sub.w PUG upon reaction with an oxidized developing agent; L.sub.2 represents a group which, after cleavage from B, releases PUG; PUG represents a photographically useful group; and v and w each represents 0 or 1.Type: GrantFiled: June 4, 1986Date of Patent: September 13, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Shigeo Hirano, Koki Nakamura, Keiji Mihayashi
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Patent number: 4762778Abstract: A silver halide color photographic light-sensitive material has a support and at least one silver halide emulsion layer. At least one of the silver halide emulsion layers has a group of substantially monodisperse core/shell type silver halide grains having a value of not greater than 0.15. This value is obtained by dividing a standard deviation value by the average grain size value. The substantially monodisperse core/shell-type silver halide grains have shells from 0.01 to 0.1 in thickness. The silver halide grains include a silver iodide in the core in an amount of less than 8 mole % and a silver iodide in the shell of from 0.1 mole % to 6 mole %. A development inhibitor releasing compound having a relative development inhibitability of not less than 1 is also present in the emulsion layer.Type: GrantFiled: June 10, 1987Date of Patent: August 9, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Katsumasa Yamazaki, Toshihiko Yagi, Kenji Michiue, Sohei Goto, Yoshiharu Mochizuki
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Patent number: 4760016Abstract: A silver halide color photographic light sensitive material is disclosed, which is excellent in the resistance to the back contamination of the processing liquid. The color photographic material comprises a support having thereon photographic component layers containing at least one silver halide emulsion layer. The emulsion containing at least one emulsion layer of the photographic component layers is a surface latent image forming type silver chloride or silver chloro-brobromide emulsion. And at least one of the photographic component layers contains at least one compound selected from the compounds represented by the formula [I]:A-(TIME)n-Z [I]in which A is a coupler component capable of coupling with the oxidized product of a color developing agent, Z is a component capable of releasing from A upon the coupling reaction of A with the oxidized product of the color developing agent and inhibiting the development of the silver halide, and Z has at least one hydrophilic group.Type: GrantFiled: October 14, 1986Date of Patent: July 26, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeto Hirabayashi, Kaoru Matsunaga
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Patent number: 4749644Abstract: In a light-sensitive direct posi silver halide color photographic material having photographic constituent layers comprising at least one silver halide emulsion layer containing latent image type silver halide grains not previously fogged, which is capable of giving a direct posi image by subjecting the whole surface to exposure or effecting surface development in the presence of a fogging agent, after image exposure, the improvement wherein said internal latent image type silver halide grains are composed of at least two groups of internal latent image type silver halide grains having average grain sizes different from each other, and at least one compound capable of releasing a development inhibiting substance or its precursor through the reaction with the oxidized product of a color developing agent is contained in at least one layer of said photographic constituent layers.Type: GrantFiled: June 18, 1986Date of Patent: June 7, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yasuo Tosaka, Keiji Ogi, Atsushi Kamitakahara
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Patent number: 4746600Abstract: Disclosed is a light-sensitive silver halide color photographic material in which a DIR compound capable of releasing a diffusible development inhibitor or precursor thereof by the reaction with an oxidized form of a color developing agent is employed in combination with a non-diffusible dye and which sastisfies Condition A and B recited in the specification.By using the color light-sensitive material according to the present invention, the sharpness, particularly the edge effect (including the fringe effect and the border effect) of a photographic image has been greatly improved.Type: GrantFiled: June 26, 1986Date of Patent: May 24, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yoshikazu Watanabe, Hiroshi Shimazaki, Toshifumi Iijima, Yoshiro Shigetomi, Toshihiko Yagi
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Patent number: 4745050Abstract: There is provided a silver halide color photographic material containing a 6-hydroxychroman derivative in, combination with a specific coupler, i.e., a 5-pyrazolone type magenta coupler having an --SR group at the coupling position or a 5-pyrazolone type magenta coupler having an anilino group at the 3-position. The photosensitive material provides photographic images, quality of which is prevented from deteriorating as time passes. The photographic color images are free from discoloration or fading and do not form yellow stains on a white background.Type: GrantFiled: January 28, 1986Date of Patent: May 17, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Seto, Masakazu Morigaki, Nobuo Sakai
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Patent number: 4745052Abstract: 2-equivalent magenta couplers with improved properties corresponding to the formula ##STR1## wherein X denotes O, S or NR.sub.9,R.sub.1 denotes hydrogen, halogen or alkoxy,R.sub.2 denotes halogen, alkoxy, acylamino, alkoxycarbonyl, aminocarbonyl which may be substituted on the nitrogen or aminosulphonyl which may be substituted on the nitrogen,R.sub.3 denotes hydrogen, halogen, alkoxy, alkyl, acylamino or alkoxycarbonyl,R.sub.4 denotes hydrogen or alkyl,R.sub.5 denotes a substituent having electron donor properties,R.sub.6 and R.sub.7 denote alkyl, acyl or sulphonyl,R.sub.8 denotes a substituent having electron acceptor properties,R.sub.9 denotes hydrogen or alkyl,m has a value from 1 to 5,n and o each have the value 0, 1 or 2 andp and q each have the value 0 or 1and the sum of p and q is 1 or 2.Type: GrantFiled: June 19, 1987Date of Patent: May 17, 1988Assignee: Agfa Gevaert AktiengesellschaftInventor: Gunter Renner
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Patent number: H817Abstract: A photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer, wherein said light-sensitive material contains:(1) a compound represented by formula (I):PWR--Time--.sub.t PUG (I)wherein PWR represents a group capable of releasing (Time--.sub.t PUG upon being reduced; PUG represents a photographically useful group; Time represents a group capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time--.sub.t PUG; and t represents 0 or 1, and(2) a polymer comprising at least 10 repeating units derived from the same monomer and having a molecular weight of 1000 or more. The photographic light-sensitive material exhibits both high activity of a compound capable of releasing a photographically useful group during development processing and preservation stability before development processing.Type: GrantFiled: April 29, 1988Date of Patent: September 4, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaharu Toriuchi, Keizo Koya