And Development Inhibitor Or Development Inhibitor Releasing Agent Patents (Class 430/544)
  • Patent number: 4743533
    Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound represented by the formula ##STR1## wherein R is --OH, --OR.sub.4, --NH.sub.2 --NHR.sub.5 or --NR.sub.4 R.sub.6 ; R.sub.1 is hydrogen, --NH.sub.2, alkyl, substituted alkyl, aryl or substituted aryl; R.sub.2 and R.sub.3 each independently is hydrogen, alkyl, aralkyl or aryl; R.sub.4 is a protecting group which can be removed in the presence of a base; R.sub.5 is an activating group which can render the neighboring hydrogen atom acidic; R.sub.6 is an electron withdrawing group which is capable of stabilizing the negative charge on the nitrogen atom which is produced upon removal of R.sub.4 upon contact with alkali; and PHOTO is a photographically useful group.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: May 10, 1988
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, John B. Mahoney, Avinash C. Mehta, William C. Schwarzel, Lloyd D. Taylor
  • Patent number: 4737451
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said color photographic material containing a compound capable of releasing a group upon reaction with an oxidation product of a developing agent, the resulting group is oxidized and undergoes a ring cleavage reaction whereby a photograhically useful group is cleaved.The compound used in the present invention is capable of releasing a photograhically useful group through at least a two-step reaction, and the amount of the photographically useful group released is controlled depending on a concentration of the oxidation product of a developing agent. The silver halide color photographic material containing the compound either provides a color image having good image qualities such as sharpness, graininess, and color reproducibility, etc., or exhibits high sensitivity.
    Type: Grant
    Filed: October 7, 1986
    Date of Patent: April 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Seiji Ichijima
  • Patent number: 4728598
    Abstract: Novel photographic dye-forming couplers comprise an imidazo[1,2-b]pyrazole nucleus which reacts at its 3-position with an oxidized aromatic primary amino color developing agent. These couplers are monomeric or polymeric and are useful in photographic materials and processes and have improved absorption and solubility characteristics.
    Type: Grant
    Filed: May 1, 1986
    Date of Patent: March 1, 1988
    Assignee: Eastman Kodak Company
    Inventors: Joseph Bailey, David N. Rogers
  • Patent number: 4725530
    Abstract: A silver halide color photographic material comprising a support and at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer on the support, which contains at least one cyan dye forming coupler represented by the general formula (I) and at least one cyan dye forming coupler represented by the general formula (II): ##STR1## wherein R.sub.1 represents --CONR.sub.5 R.sub.6, --NHCORhd 5, --NHCOOR.sub.7, --NHSO.sub.2 R.sub.7, --NHCONR.sub.5 R.sub.6 or --NHSO.sub.2 NR.sub.5 R.sub.6, R.sub.2 represents a group which can be substituted in the naphthol ring, m represents 0 or an integer of 1 to 3, R.sub.3 represents a monovalent group, R.sub.4 represents an aromatic group, and X and Y each represents a hydrogen atom or a group capable of leaving through a coupling reaction with an oxidized product of aromatic primary amine developing agent; R.sub.5 and R.sub.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: February 16, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshihiro Nishikawa
  • Patent number: 4720451
    Abstract: A silver halide color reversal light-sensitive material comprising a support having thereon at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer, at least one layer of said light-sensitive material comprising (1) an emulsion containing tabular silver halide grains having a diameter/thickness ratio of at least of about 4 and (2) at least one compound represented by the following general formulae (I) to (IV), said tabular silver halide grains being present in amount of at least about 50% of the total projected area of silver halide grains present in the same layer: ##STR1## wherein M.sub.1 represents a hydrogen atom, a cation or a group cleavable in alkaline conditions, and Z represents an atomic group as defined in the specification; ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group, an aryl group or an aralkyl group as defined in the specification, X.sup..
    Type: Grant
    Filed: September 18, 1985
    Date of Patent: January 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Naoyasu Deguchi
  • Patent number: 4708927
    Abstract: A novel photographic element is disclosed. The element comprises a light-sensitive element including a light-sensitive silver halide emulsion layer coated on a support, wherein said silver halide emulsion layer or other photographic layers contain at least one development inhibitor precursor represented by formula (I) ##STR1## wherein A represents a phenyl group or a 5- or 6-membered nitrogen-containing heterocyclic ring group; L represents a chemical bond or divalent linking group; p and q each represents an integer of 1 or 2; and n represents 0 or 1.
    Type: Grant
    Filed: April 10, 1986
    Date of Patent: November 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hiroshi Kawamoto, Yoshio Sakakibara
  • Patent number: 4698297
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W and Z each represents an oxygen atom, a sulfur atom or a group of ##STR2## X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 each represents a hydrogen atom or an organic residue; PUG represents a photographically useful group; n represents 1 or 2; any two of X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and PUG each represents a divalent group and may be connected to each other to form a cyclic structure; and when n represents 2, two Z's, two X.sub.3 's and two X.sub.4 's may be the same or different.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: October 6, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Noboru Sasaki
  • Patent number: 4690885
    Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains at least one blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom, or a substituent group; and Z represents atoms necessary to form a carbocyclic ring or a heterocyclic ring (except for a heterocyclic ring which contains an NH group at the position adjacent to the carbon atom to which R.sup.1 is attached). The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing. The blocked photographic agent also exhibits its function to a substantial degree over a wide range of pH.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: September 1, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa
  • Patent number: 4686175
    Abstract: A silver halide multilayered color photographic light-sensitive material is disclosed. The material is comprised of a support basde having thereon a green-sensitive emulsion layer having a maximum sensitivity of from 535 nm to 555 nm, a blue-sensitive emulsion layer having a maximum sensitivity in the range of 80 to 110 nm shorter than that of the green-sensitive layer and a red-sensitive layer having a maximum sensitivity in the range of 75 to 95 nm longer than that of the green-sensitive layer. The material also contains a compound capable of releasing a diffusible development inhibitor or its precursor by a coupling reaction with the oxidation product of a color developing agent. This compound is present within one of the emulsion layers or a light-insensitive layer adjacent to one of the silver halide emulsion layers. The material undergoes less changes in color reproducibility due to changes in color temperature of a light source upon photographing.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: August 11, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ogawa, Masaki Okazaki
  • Patent number: 4684604
    Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.
    Type: Grant
    Filed: April 24, 1986
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4663272
    Abstract: A silver halide photographic material is described comprising at least one layer which contains at least(1) a polymer comprising as constitutional components thereof a repeating unit having a photographically useful group and at least one repeating unit having a sulfinic acid group or a sulfinate group, and(2) a compound having at least one functional group capable of reacting with at least one of a sulfinic acid group and sulfinate group and at least one functional group capable of reacting with at least one of a sulfinic acid group, a sulfinate group and a primary amino group.Said photographic group-containing polymer (1) may be fixed in a photographic layer according to the present photographic material, and does not substantially migrate therefrom during development or other photographic treatment, thus resulting in formation of color images of high density.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: May 5, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Taku Nakamura
  • Patent number: 4659651
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith at least one blocked photographic reagent represented by formula (I) or (II); ##STR1## wherein, A represents a moiety of a photographic reagent or a moiety of a precursor of a photographic reagent bonded to the ring containing Z through a hetero atom; Y.sup.1, and Y.sup.2 and Y.sup.3 each represents a hydrogen atom or a substituent, or Y.sup.1 and Y.sup.3 in formula (I) together form a ring; Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring; and n represents 1 or 2.The silver halide photographic material is stable under storage conditions.
    Type: Grant
    Filed: July 11, 1985
    Date of Patent: April 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa
  • Patent number: 4652516
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W represents an oxygen atom, a sulfur atom or a group ##STR2## (wherein R represents a hydrogen atom or an organic residue); X represents an electron withdrawing substituent; Y represents a hydrogen atom or a substituent; PUG represents a photographically useful group or a precursor thereof; X and Y each represents a divalent group and may be connected to each other to form a cyclic structure; and when W represents the group ##STR3## and R represents an organic residue, R and X or R and Y each represents a divalent group and may be connected to each other to form a cyclic structure.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: March 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shingo Sato, Mitsunori Ono, Noboru Sasaki
  • Patent number: 4652515
    Abstract: A silver halide color photographic material which comprises a support having thereon at least two silver halide light-sensitive layers having essentially the same color sensitivity but different speeds and a light-insensitive layer positioned adjacent to the highest-speed layer of said light-sensitive layers and containing a compound which reacts with the oxidation products of a color developing agent to form a diffusible development restraining compound or a precursor thereof. The photographic material provides a color image having excellent graininess and color reproduction and has excellent characteristics of development processing.
    Type: Grant
    Filed: August 5, 1985
    Date of Patent: March 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ogawa, Jun Arakawa, Satoshi Nagaoka, Yuichi Ohashi, Koji Tamoto
  • Patent number: 4636461
    Abstract: Photographic recording materials containing a silver halide emulsion in which the grains have zones of differing iodide content provide improved sensitometric results.
    Type: Grant
    Filed: January 31, 1985
    Date of Patent: January 13, 1987
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Manfred Becker, Reinhart Matejec, Lothar Endres
  • Patent number: 4610957
    Abstract: A heat-developable light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and an acid precursor having a structural moiety represented by the following formula (I) bonded to carbon atoms: ##STR1## The acid precursor is extremely stable at room temperature but when it is heated above a certain temperature, and the development proceeds to the desired appropriate condition, it releases an acid to neutralize a base, whereby the development is stopped. A heat-developable light-sensitive material containing the acid precursor provides color images having a high S/N ratio and a high image density.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: September 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Kato, Hiroshi Kitaguchi
  • Patent number: 4599301
    Abstract: A silver halide color photographic material is described, comprising a support having thereon at least a cyan-color-forming red-sensitive emulsion layer, a magenta-color-forming green-sensitive emulsion layer, and a yellow-color-forming blue-sensitive emulsion layer; the weight-averaged wavelength (.lambda.) on the spectral sensitivity distribution determined by equi-energy spectrum of said red-sensitive emulsion layer being less than 640 nm; the longest wavelength in the wavelengths having the sensitivity of 1/2 of the maximum value of the above-described equi-energy spectrum being in a range of from 30 nm to 55 nm longer than the weight-averaged wavelength and the minimum wavelength thereof being in a range of from 30 nm to 55 nm shorter than the weight-averaged wavelength; in the above-described equi-energy spectrum, values A and B defined below satisfying the relation of A/B.gtoreq.0.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: July 8, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuichi Ohashi, Tadashi Ogawa
  • Patent number: 4584257
    Abstract: A photographic element comprised of a support having provided thereon at least one silver halide emulsion layer, the element containing a development inhibitor precursor, is disclosed. The development inhibitor precursor is a compound represented by following general formula (I): ##STR1## wherein A represents an unsubstituted or substituted phenyl group or a 5-membered or 6-membered nitrogen-containing heterocyclic ring; Q represents a naphthalene skeleton; R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, independently represent a hydrogen atom or a monovalent substituent; and n represents 1 or 2. The photographic element gives improved image quality particularly in the low Dmin area. The element can be processed over a wide range of different processing temperatures and has improved preservability.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: April 22, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Yoshio Sakakibara
  • Patent number: 4579816
    Abstract: Yellow DIR couplers corresponding to formula I below are capable of producing remarkably powerful inhibitory effects on remote layers while their action on the layer containing them is comparatively slight: ##STR1## In the above formula, R.sup.1 represents straight-chained or branched alkyl, optionally substituted aryl or --NR.sup.5 R.sup.6,R.sup.2, R.sup.5 represent H or alkyl with 1 or 2 carbon atoms,R.sup.3, R.sup.6 represent alkyl with 1 to 18 carbon atoms or optionally substituted aryl,R.sup.4 represents alkyl with 5 to 12 carbon atoms, andFu represents a substituted or unsubstituted furyl group.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: April 1, 1986
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Hans Ohlschlager, Ulrich Griesel, Heinrich Odenwalder
  • Patent number: 4571378
    Abstract: Improved photographic recording materials containing at least one silver halide emulsion layer with comparatively high sensitivity and at least one silver halide emulsion layer with comparatively low sensitivity. Color couplers and DIR compounds of differing reactivities are associated with these layers.
    Type: Grant
    Filed: December 10, 1984
    Date of Patent: February 18, 1986
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Wolfgang Sauerteig, Erwin Ranz, Heinz Schutz
  • Patent number: 4565774
    Abstract: Method for forming a dye image comprising imagewise exposing and processing a silver halide light-sensitive color photographic material having a support and coated thereon a silver halide emulsion layer containing silver halide crystals, wherein said silver halide crystals consist essentially of crystals having at least 80 mole % of silver chloride, said developing taking place in a developer essentially free from bromide ion and having a pH value of at least 9.5, in the presence of a p-phenylenediamine color-developing agent and a compound of the formula ##STR1## having an acid dissociation constant of not more than 1.times.10.sup.-8 and a solubility product with silver ion of not more than 1.times.10.sup.-10, wherein Z, together with N forms a heterocyclic ring, said compound.
    Type: Grant
    Filed: October 18, 1984
    Date of Patent: January 21, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Makoto Kajiwara, Kaoru Onodera
  • Patent number: 4562138
    Abstract: This invention relates to nitrogen containing heterocyclic compounds represented by the general formula ##STR1## wherein Z is non-metallic atoms necessary to form a tetrazole, a benzotriazole or a benzothiazole, either substituted or unsubstituted, n is either 1 or 2 and R is alkyl or phenyl. The above mentioned compounds can be suitably used in a photographic material as a development inhibitor precursor.
    Type: Grant
    Filed: August 21, 1984
    Date of Patent: December 31, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Morito Uemura, Kaoru Onodera
  • Patent number: 4547458
    Abstract: A silver halide color photographic light-sensitive material comprising a support having at least one silver halide emulsion layer thereon, said silver halide emulsion layer having a sensitivity to a certain spectral region and at least one of said silver halide emulsion layers comprising a plurality of different-speed light-sensitive layers wherein the difference in speed between the fastest-speed layer and the second fastest-speed layer of said plurality of light-sensitive layers, in terms of log I.multidot.t, is 0.2 to 0.7, and each of at least said fastest-speed and said second fastest-speed layers contains at least one monodispersed silver halide emulsion, said monodispersed emulsion being light-sensitive and consisting essentially of silver halide particles having a granularity distribution represented by the formulaS/r.ltoreq.0.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: October 15, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshifumi Iijima, Kiyoshi Yamashita
  • Patent number: 4546073
    Abstract: Precursor compounds from which photographically-active compounds are released with a time delay correspond to the following general formula ##STR1## wherein A represents the residue of a compound which undergoes oxidative coupling;X represents --O--, --S-- or --NR.sup.1 --;Y represents a releasable group which may consist of or contain the residue of a photographically-active compound; andR represents a group for controlling the kinetics of release.Advantageous pictorial properties (inter-image effect, edge effect, modulation transfer function) are obtained with compounds according to the present invention if the photographically-active residue is the residue of a development inhibitor.
    Type: Grant
    Filed: May 16, 1984
    Date of Patent: October 8, 1985
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Peter Bergthaller, Heinrich Odenwalder, Reinhard Matejec
  • Patent number: 4528263
    Abstract: Disclosed is a light-sensitive silver halide color photographic material having at least one light-sensitive silver halide emulsion layer on a support, characterized in that said light-sensitive silver halide emulsion layer contains a cyan coupler represented by the formula [I] shown below, and said light-sensitive silver halide emulsion layer and/or a layer contiguous to said light-sensitive silver halide emulsion layer contains at least one of a timing DIR compound represented by the formula [II] shown below and a non-timing type DIR compound: ##STR1## wherein X, R.sub.1 and R.sub.2 are as defined in the specification; ##STR2## wherein Cp, TIME and Z are as defined in the specification.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: July 9, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Sugita, Yasuo Tsuda, Kenji Ito, Satoru Shimba
  • Patent number: 4524130
    Abstract: A silver halide color photographic light-sensitive material is disclosed. The material is comprised of a support base having a plurality of silver halide emulsion layers positioned thereon. The material includes at least one silver halide emulsion layer having a particular sensitivity and color sensitivity, and a second silver halide emulsion layer having the same color sensitivity but having a greater sensitivity with respect to light, the second layer including a silver halide having a silver iodide content in the range of 9% by mol to 15% by mol. The material includes a DIR compound in a layer other than the second silver halide emulsion layer. The DIR compound releases a diffusible development inhibitor or precursor thereof by a coupling reaction. The resulting material has greatly improved granularity and sharpness.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: June 18, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Iwasa, Shingo Ishimaru
  • Patent number: 4518685
    Abstract: A silver halide photographic light-sensitive material which comprises a support having thereon a light-sensitive silver halide emulsion layer, wherein the photographic light-sensitive material contains a blocked photographic agent therein represented by formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom or a group which is bonded to a blocking moiety through a hetero atom and capable of releasing a photographic agent upon a subsequent reaction after the group is released; Y represents a hydrogen atom or a substituent; and Z represents an atomic group necessary to form a carbocyclic ring or a heterocyclic ring.The precursor of photographic agent is completely stable during the preservation of the photographic light-sensitive material and releases a photographic agent at a desired time upon the processing of the photographic light-sensitive material.
    Type: Grant
    Filed: April 17, 1984
    Date of Patent: May 21, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa, Mitsunori Ono, Yuji Mihara
  • Patent number: 4511644
    Abstract: A photographic element comprised of a support having provided thereon at least one silver halide emulsion layer, the element containing a development inhibitor precursor. The development inhibitor precursor is represented by the following general formula (I): ##STR1## wherein A represents an unsubstituted or substituted phenyl group or a 5-membered or 6-membered nitrogen-containing heterocyclic ring; R.sup.1 represents a hydrogen atom or a monovalent substituent; and R.sup.2 represents an organic ballasting group. The element is capable of providing color images having improved image quality particularly with respect to having a low density in the Dmin areas. The photographic element can be processed over a wide range of processing temperatures. Further, the element can be preserved for long periods of time without having a reduction in the density in the Dmax areas.
    Type: Grant
    Filed: December 9, 1983
    Date of Patent: April 16, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Shinji Sakaguchi, Osamu Takahashi, Ashita Murai
  • Patent number: 4503139
    Abstract: There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: March 5, 1985
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Roger A. Boggs, Anthony J. Puttick, Nancy M. Sofen
  • Patent number: 4500633
    Abstract: A silver halide photographic material having formed on a support two or more layers that have different light sensitivities but have substantially the same color sensitivity is disclosed. In the material, the layer having the highest light sensitivity contains only a compound of formula (I) as a DIR compound and at least one of the remaining layers contains at least one compound of formula (II) as a DIR compound:A--TIME--Z (I)A--Z (II)wherein A is a coupling component capable of reaction with the oxidized product of a color developing agent to release the group TIME--Z (wherein TIME represents a timing group and Z represents a development retarder). The photographic material has improved sharpness and granularity and wide latitude for exposure.
    Type: Grant
    Filed: February 15, 1983
    Date of Patent: February 19, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Menjo, Yoshikazu Watanabe
  • Patent number: 4500634
    Abstract: A silver halide color photographic material in which both a coupler capable of releasing a diffusible development restrainer by coupling and a polymer coupler latex are present to increase visual sharpness.
    Type: Grant
    Filed: August 24, 1983
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kei Sakanoue, Morio Yagihara, Seigi Ichijima, Kimitoshi Nagao
  • Patent number: 4500636
    Abstract: A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi, Yukio Karino
  • Patent number: 4490459
    Abstract: The invention relates to multi-layered color photosensitive materials having a support, a red photosensitive silver halide emulsion layer containing a non-diffusible cyan coupler, a green photosensitive silver halide emulsion layer containing a non-diffusible yellow coupler and a blue photosensitive silver halide emulsion layer containing a non-diffusible magenta coupler coated on a support in the order recited and wherein the green photosensitive emulsion layer contains a compound capable of reacting with an oxidized color developing agent to release a development inhibiting substance.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: December 25, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshifumi Iijima, Kaoru Onodera, Wataru Fujimatsu
  • Patent number: 4482629
    Abstract: There is disclosed a light-sensitive silver halide photographic material containing a compound represented by the formula (I): ##STR1## wherein G, R.sub.1, R.sub.2 and X have the same meanings as defined in the specification.The 1-naphthol coupler which is contained in the light-sensitive silver halide photographic material is high in reactivity with an oxidized product of a color forming developing agent and can efficiently impart imagewise photographic effects to light-sensitive silver halide photographic materials.
    Type: Grant
    Filed: March 16, 1983
    Date of Patent: November 13, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoshi Nakagawa, Hiroshi Sugita, Shuzi Kida, Morito Uemura, Ken-ichi Kishi
  • Patent number: 4480028
    Abstract: Silver halide photographic material having at least one light sensitive silver halide emulsion layer, at least one non-light sensitive hydrophilic colloidal layer, and optionally a third type of layer, wherein at least one of said emulsion layers, colloid layers, or third type of layers has, in a single layer, both a magenta coupler of Formula I and a development inhibitor releasing compound having a development inhibitor radical of Formula II or III, said Formula is wherein R.sub.1 is selected from benzamido, anilino, and phenylureido, each having a sulfonamido group and R.sub.2 is selected from aryl and heterocyclic groups; said Formula II is ##STR1## wherein R.sub.3 is selected from hydrogen, halogen, acylamino, alkyl, benzothiazolinylidenamino and phenyl substituted alkoxy; said Formula III is ##STR2## wherein X is a group of non-metallic atoms necessary to complete, together with the C.dbd.N group, a five or six membered heterocyclic ring.
    Type: Grant
    Filed: January 28, 1983
    Date of Patent: October 30, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuo Kato, Yoshikazu Watanabe, Kenji Kumashiro, Satoru Shimba
  • Patent number: 4477563
    Abstract: A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a coupler having, at the coupling active position, a group which provides a compound having a development inhibiting property when the group is released from the coupling device position of the coupler upon the color development reaction and which is decomposed to a compound which does not substantially influence the photographic properties when the compound diffuses into a color developing solution.The silver halide color photographic light-sensitive material containing a novel class of development inhibitor releasing couplers provides color images of good sharpness and improved color reproduction without causing contamination of the processing solution.
    Type: Grant
    Filed: August 25, 1983
    Date of Patent: October 16, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Kei Sakanoue, Hidetoshi Kobayashi, Keiichi Adachi
  • Patent number: 4472493
    Abstract: A photographic element is disclosed which is comprised of a support having thereon a light-sensitive silver halide emulsion which is associated with a development inhibitor precursor. The precursor is represented by the general formula [I] ##STR1## the substituents within the general formula are defined within the specification. By utilizing the development inhibitor precursor of the invention the resulting photographic element provides images having high quality and excellent processing temperature characteristics.
    Type: Grant
    Filed: December 9, 1983
    Date of Patent: September 18, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Yukio Maekawa, Yukio Karino
  • Patent number: 4464463
    Abstract: A silver halide color photographic light-sensitive material comprises a support having thereon a light-sensitive silver halide emulsion layer and a light-insensitive layer is disclosed. The material contains within the light-sensitive layer or the light-insensitive layer a compound capable of reacting with and fixing formaldehyde gas, said compound being represented by the general formula (I) or (II): ##STR1## The compound capable of reacting with and fixing formaldehyde gas is loaded into an ultraviolet ray absorbing polymer latex comprised of a polymer having a repeating unit derived from a monomer represented by the general formula (III): ##STR2## The substituents within the above formulae are defined within the specification.
    Type: Grant
    Filed: July 26, 1983
    Date of Patent: August 7, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Hidetoshi Kobayashi
  • Patent number: 4461826
    Abstract: There is disclosed a silver halide light-sensitive color photographic material which comprises a support and coated thereon a light-sensitive layer containing a compound which, upon reaction with an oxidized color developing agent, is capable of releasing a diffusible development inhibitor and a negative type light-sensitive silver halide emulsion containing light-sensitive silver halide crystals essentially consisting of mono-dispersed silver halide crystals of which size distribution satisfies the following relation:S/r.ltoreq.0.15whereinS=.sqroot..SIGMA.(r-r.sub.i).sup.2 n.sub.i.sup.2 /.SIGMA.n.sub.i andr=.SIGMA.n.sub.i r.sub.i /.SIGMA.n.sub.i in which r.sub.i represents the crystal size of individual silver halide crystals and n.sub.i represents the number of crystals.The light-sensitive color photographic material of the present invention provides an image of remarkably improved sharpness.
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: July 24, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kiyoshi Yamashita, Toshifumi Iijima
  • Patent number: 4438193
    Abstract: There is disclosed a novel silver halide photosensitive color photographic material comprising a coupler which consists of a coupling component (A) which is capable of causing a coupling reaction with an oxidized color developing agent and a substituent component bonded at the coupling position of said coupling component (A), which substituent component is capable of being split off on coupling reaction, the improvement characterized in that said substituent comprises a coupling component (B) which can undergo coupling reaction with an oxidized color developing agent when released from said coupling component (A) and a photographically useful component which is capable of being released on coupling reaction of said coupling component (B).The color photographic material according to the present invention provides graininess, sharpness and color reproducibility which is sufficiently competent to the requirement of further miniturization of film size by use of a coupler having novel functions.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: March 20, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Morito Uemura, Kenichi Kishi, Satoshi Nakagawa, Shuji Kida
  • Patent number: 4434225
    Abstract: Disclosed is a light-sensitive silver halide color photographic material having at least one light-sensitive silver halide emulsion layer on a support, characterized in that said light-sensitive silver halide emulsion layer contains a cyan coupler represented by the formula [I] shown below, and said light-sensitive silver halide emulsion layer and/or a layer contiguous to said light-sensitive silver halide emulsion layer contains at least one of a timing DIR compound represented by the formula [II] shown below and a non-timing type DIR compound: ##STR1## wherein X, R.sub.1 and R.sub.2 are as defined in the specification; ##STR2## wherein Cp, TIME and Z are as defined in the specification.
    Type: Grant
    Filed: February 22, 1983
    Date of Patent: February 28, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Sugita, Yasuo Tsuda, Kenji Ito, Satoru Shimba
  • Patent number: 4431728
    Abstract: There is disclosed a silver halide photographic light-sensitive material which comprises a support, a combination of an unfogged surface latent image type silver halide photographic emulsion and a material which is non-diffusible under alkali conditions and which is capable of releasing a diffusible development inhibitor or a precursor thereof as a result of cross oxidation with an oxidized product of a photographic developing agent; and a combination of an internal latent image type silver halide photographic emulsion whose silver halide grains contain therein, prior to development, fog nuclei and a dye image-forming material which is initially non-diffusible under alkaline conditions but which is capable of releasing a diffusible dye or a precursor thereof as a result of being oxidized by the oxidized product of said photographic developing agent.
    Type: Grant
    Filed: June 9, 1982
    Date of Patent: February 14, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takao Abe, Tatsuhiko Kobayashi
  • Patent number: 4421845
    Abstract: A silver halide photographic light-sensitive material which comprises at least one of those pyrazole compounds represented by the following general formula: ##STR1## wherein A is a group which can be eliminated in a photographic process condition; X is ##STR2## wherein R.sub.5 is a hydrogen atom or an alkyl, an aryl, an acyl or a sulfone group, which R.sub.5 group may combine together with R.sub.1 to form a condensed ring; R.sub.1 is a hydrogen atom or an alkyl, an aryl, an acyl, a sulfone, an alkoxy, or a heterocyclic residue; R.sub.2 is a hydrogen atom or an alkyl, an aryl, an alkoxy, an amino, an acid amide, a sulfonamide, a carboxyl, an alkoxycarbonyl, a carbamoyl, a cyano, or a halogenated alkyl group, R.sub.3 and R.sub.
    Type: Grant
    Filed: March 11, 1982
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Morito Uemura, Kenichi Kishi, Satoshi Nakagawa, Shuji Kida, Hiroshi Sugita
  • Patent number: 4414308
    Abstract: In a silver halide color photographic photosensitive material, having a red, a green and a blue light-sensitive emulsion layer on a support, each emulsion containing a nondiffusible image forming coupler, improvement is attained by providing a layer structure in which at least one of the red, the green and the blue light-sensitive emulsion layer is separated into a high sensitivity silver halide emulsion layer and a low sensitivity silver halide emulsion layer, both layers having photosensitive regions in substantially the same spectral region, by an intermediate layer and incorporating at least one kind of DIR compounds represented by formula (I) defined in the specification in at least one layer of the high sensitivity silver halide emulsion layer, the low sensitivity silver halide emulsion and the intermediate layer.
    Type: Grant
    Filed: March 16, 1982
    Date of Patent: November 8, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventor: Fumio Hamada
  • Patent number: 4411987
    Abstract: A silver halide color photographic light-sensitive material containing an unsubstituted or substituted glycoluril as an aldehyde gas scavenger. The silver halide color photographic light-sensitive material of the present invention can avoid the decrease in color density and the formation of fog normally present when the silver halide color photographic light-sensitive material is stored for a long period of time in contact with formaldehyde gas. In addition, the silver halide color photographic light-sensitive material of the present invention has a reduced layer thickness and good film strength.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: October 25, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshiyuki Watanabe, Keiichi Adachi, Tadashi Ogawa
  • Patent number: 4410618
    Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.
    Type: Grant
    Filed: June 11, 1982
    Date of Patent: October 18, 1983
    Assignee: Eastman Kodak Company
    Inventors: James P. Vanmeter, Chin H. Chen
  • Patent number: 4409323
    Abstract: A silver halide photographic material containing a coupler capable of releasing a photographically useful group in a controllable timing.
    Type: Grant
    Filed: February 13, 1981
    Date of Patent: October 11, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Ryosuke Sato, Yuji Hotta, Katsumi Matsuura
  • Patent number: 4387159
    Abstract: A light-sensitive, color photographic silver halide multilayer material contains for the improvement of definition, grain and color rendition DIR-couplers which are substituted in coupling position by mercapto-azole-, mercaptobenz-azole- or mercapto-azine moieties, which themselves carry hydrophilic substituents. The DIR-couplers according to the invention may be used together with other couplers and additives or as sole color forming element and are noteworthy for their high color yields, inter- and intra-image effects. They may be added as well in hydrophobic state (in dispersed form) as in hydrophilic state (as alkaline solutions) and they may be used in single layers or as associated layers with a maximum three layers of a color forming unit and the layers may be arranged in any desired order within the whole combination of layers.
    Type: Grant
    Filed: May 8, 1981
    Date of Patent: June 7, 1983
    Assignee: VEB Filmfabrik Wolfen
    Inventors: Horst Engelmann, Rainer Redmann, Monika Bethke, Christa Melz, Gerd West, Jurgen Mistol, Udo Sydow
  • Patent number: 4368256
    Abstract: Production of masked positive color images by the silver dye bleach process, by exposure of a photographic material for the silver dye bleach process, silver developing, dye bleaching, silver bleaching and fixing, optionally the silver bleaching is carried out simultaneously with the dye bleaching and/or the fixing, in a single processing bath.
    Type: Grant
    Filed: July 13, 1981
    Date of Patent: January 11, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Herbert Mollet, Dieter Wyrsch
  • Patent number: RE31893
    Abstract: A color photographic material having a light-sensitive silver halide emulsion layer containing a DIR compound having an amino group and a DIR compound having no amino group.
    Type: Grant
    Filed: July 14, 1983
    Date of Patent: May 21, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Sugita, Shizuo Saito, Ryosuke Sato, Kiyoshi Yamashita