Containing At Least Three Aryl Groups Bonded To A Single Carbon Atom In Charge Transport Layer Patents (Class 430/58.3)
  • Patent number: 10599057
    Abstract: An electrophotographic photoreceptor that includes a conductive support; and at least a charge generation layer and a charge transport layer on the conductive support, where the charge transport layer includes at least two layers of a first charge transport layer which is an outermost layer and a second charge transport layer which is in contact with the first charge transport layer, such that the elastic deformation ratio of a binder resin A contained in the first charge transport layer is T1(%) and the elastic deformation ratio of a binder resin B contained in the second charge transport layer is T2(%) such that T1 and T2 satisfy a relationship of {0?(T1?T2)?4}, the first charge transport layer contains a charge transport material ? having a molecular weight of 600 or more, and the binder resin A and the binder resin B have different monomer units from each other.
    Type: Grant
    Filed: March 28, 2019
    Date of Patent: March 24, 2020
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Akiteru Fujii, Yuka Nagao, Wataru Miyashita
  • Patent number: 8859173
    Abstract: An electrophotographic photoreceptor is disclosed, in which an outermost surface layer of the electrophotographic photoreceptor is made of a cured film of a composition including a compound represented by the following Formula (M1) and a charge transporting material having a chain polymerizable functional group:
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: October 14, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Wataru Yamada, Katsumi Nukada, Takatsugu Doi, Tsuyoshi Miyamoto, Kenya Sonobe
  • Patent number: 8846280
    Abstract: Provided is a compound represented by the following General Formula (I): wherein in General Formula (I), F represents a charge transporting subunit, L represents a linking group having a valency of (n+1) that is formed by combining two or more kinds selected from a group consisting of an alkylene group, —C?C— (an alkenylene group), —C(?O)—, —N(R)—, —O—, and —S—, and R represents a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, m represents an integer of from 1 to 6, and n represents an integer of from 2 to 3.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: September 30, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Wataru Yamada, Katsumi Nukada, Yuko Iwadate, Tomoya Sasaki, Kenji Kajiwara
  • Patent number: 8785089
    Abstract: The present invention provides an electrophotographic photosensitive member, and a process cartridge and an electrophotographic apparatus, each of which has the electrophotographic photosensitive member. In the electrophotographic photosensitive member, a charge transport layer used as a surface layer contains a charge transport material, a polycarbonate resin A which has a specific amount of a specific repeating structural unit of a specific siloxane moiety, and a polyester resin C and/or a polycarbonate resin D, each of which has a specific repeating structural unit. In the charge transport layer, a matrix-domain structure is formed in which a matrix is formed from the charge transport material and the polyester resin C and/or the polycarbonate resin D, and domains are formed in the above matrix from the polycarbonate resin A.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: July 22, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Atsushi Okuda, Tsutomu Nishida
  • Patent number: 8669028
    Abstract: An electrophotographic photoreceptor is provided, which includes: a substrate; a photosensitive layer; and a surface protective layer, in this order, in which the protective layer contains a crosslinked product of a curable charge transporting material in a content of from about 90 to 98% by weight, and fluorinated resin particles in a content of from about 2 to 10% by weight, and the protective layer satisfies Formula (1): 0.5?b/a?1, wherein, “a” represents a ratio of fluorine atoms to the sum of carbon atoms, oxygen atoms, and fluorine atoms present in a region of the protective layer ranging from the photosensitive layer side surface thereof to a point corresponding to about ? of the thickness thereof, and “b” represents the ratio in a region of the protective layer ranging from the outer surface thereof to a point corresponding to about ? of the thickness thereof.
    Type: Grant
    Filed: March 21, 2011
    Date of Patent: March 11, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yukimi Kawabata, Yuko Yamano, Kazuyuki Tada, Kenji Ikeda, Mitsuhide Nakamura
  • Patent number: 8623577
    Abstract: To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming meth
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: January 7, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Horiuchi, Kazukiyo Nagai, Hongguo Li, Tetsuro Suzuki, Hiroshi Tamura
  • Patent number: 8609309
    Abstract: To provide an electrophotographic photoreceptor having a high sensitivity, a good balance of various electric properties such as chargeability and residual potential, a good stability of the coating solution, and an excellent light resistance. An electrophotographic photoreceptor comprising an electroconductive support having thereon a photosensitive layer, wherein the photosensitive layer contains a compound represented by the following formula (1): (wherein R1 represents a group having a chiral center, R2 represents a hydrogen atom, an alkyl group which may have a substituent, or an aryl group which may have a substituent, R3 and R4 each independently represents an alkylene group which may have a substituent, or an arylene group which may have a substituent, and R5, R6, R7 and R8 each independently represents an alkyl group which may have a substituent, or an aryl group which may have a substituent, and at least one member of R5 to R8 is an aryl group having a substituent).
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: December 17, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yuka Nagao, Teruyuki Mitsumori, Masayuki Hiroi
  • Patent number: 7544450
    Abstract: Polymers of naphthalene tetracarboxylic diimide dimmers are provided. The polymers are of the Formula I wherein the A units are selected from and Formula IX The polymers are suitable for use in the active layer of an imaging member and exhibit properties of both a binder and an electron-transporting material.
    Type: Grant
    Filed: March 19, 2008
    Date of Patent: June 9, 2009
    Assignee: Xerox Corporation
    Inventors: Timothy P. Bender, John Graham, James M. Duff
  • Patent number: 7449268
    Abstract: Polymers of naphthalene tetracarboxylic diimide dimmers are provided. The polymers are of the Formula I wherein the A units are selected from and Formula IX The polymers are suitable for use in the active layer of an imaging member and exhibit properties of both a binder and an electron-transporting material.
    Type: Grant
    Filed: May 27, 2005
    Date of Patent: November 11, 2008
    Assignee: Xerox Corporation
    Inventors: Timothy P. Bender, John Graham, James M. Duff
  • Patent number: 7291428
    Abstract: An electrophotographic imaging member having a charge generating layer and a charge transport layer overlayed thereon is provided. The charge transport layer has a lower surface and an upper surface, wherein the lower surface is in contiguous contact with the charge generating layer. The charge transport layer comprises a film forming polymer binder and a charge transport compound molecularly dispersed or dissolved therein to form a solid solution. The concentration of the charge transport compound in the charge transport layer decreases from the lower surface to the upper surface. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improved wear resistance, excellent imaging member electrical performance, and improved copy print out quality.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: November 6, 2007
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Anthony M. Horgan, Robert C. U. Yu, Dasarao K. Murti, Suresh K. Ahuja
  • Patent number: 7144607
    Abstract: A polyimide-containing liquid crystal alignment treating agent having a structure of the formula (I) incorporated therein, wherein Q is a single bond or a divalent organic group, R1 to R4 represent aromatic groups, and R1 to R4 may be the same as, or different from, one another.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: December 5, 2006
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Tomohisa Yamada, Hiroyoshi Fukuro, Hideyuki Endo
  • Patent number: 7125633
    Abstract: An imaging member having a charge transport layer with multiple regions or layers is provided. The charge transport layer includes at least two charge transport layers coated from solutions of different components and concentrations, wherein the second (top) transport layer comprises a lower concentration of different charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the second (top) charge transport layer is a high mobility hole transport compound. The charge transport compound in each layer is dissolved or molecularly dispersed in an electrically inactive film forming polymer to form a solid solution. In such a construction, the resulting dual charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: October 24, 2006
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Houy Jen Yuh, Anthony M. Horgan, Markus R. Silvestri, Robert C. Yu, Yuh Tong, Dale Renfer, Kenny-tuan Dinh, Geoff Foley, Jack Yanus, Timothy Fuller
  • Patent number: 7033714
    Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: April 25, 2006
    Assignee: Xerox Corporation
    Inventors: Anthony M. Horgan, Robert C Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
  • Patent number: 7005222
    Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: February 28, 2006
    Assignee: Xerox Corporation
    Inventors: Anthony M. Horgan, Satchidanand Mishra, Robert C. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
  • Patent number: 6946225
    Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: September 20, 2005
    Assignee: Eastman Kodak Company
    Inventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
  • Patent number: 6861188
    Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: March 1, 2005
    Assignee: Ricoh Company Limited
    Inventors: Takaaki Ikegami, Yasuo Suzuki, Tomoyuki Shimada, Nozomu Tamoto, Hidetoshi Kami
  • Patent number: 6794102
    Abstract: A compound having the Formula I wherein: R1 is independently selected from the group consisting of a hetero atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety; R2 and R3 are independently selected from the group consisting of hydrogen, a halogen, a hetero -atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety; and R4, R5, R6, R7, R8, R9, R10 and R11 are independently selected from the group consisting of a nitrogen containing group, a sulfur containing group, a hydroxyl group, a silicon containing group, hydrogen, a halogen, a hetero atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: September 21, 2004
    Assignee: Xerox Corporation
    Inventors: Timothy P. Bender, John F. Graham, James M. Duff
  • Publication number: 20040151999
    Abstract: An imaging member having a charge transport layer with multiple regions or layers is provided. The charge transport layer includes at least two charge transport layers coated from solutions of different components and concentrations, wherein the second (top) transport layer comprises a lower concentration of different charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the second (top) charge transport layer is a high mobility hole transport compound. The charge transport compound in each layer is dissolved or molecularly dispersed in an electrically inactive film forming polymer to form a solid solution. In such a construction, the resulting dual charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Application
    Filed: December 12, 2003
    Publication date: August 5, 2004
    Applicant: Xerox Corporation
    Inventors: Satchidanand Mishra, Houy Jen Yuh, Anthony M. Horgan, Markus R. Silvestri, Robert C.U. Yu, Yuhua Tong, Dale Renfer, Kenny-Tuan Dinh, Geoff Foley, Jack Yanus, Timothy Fuller
  • Publication number: 20040126685
    Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Application
    Filed: December 16, 2003
    Publication date: July 1, 2004
    Applicant: Xerox Corporation
    Inventors: Anthony M. Horgan, Satchidanand Mishra, Robert C.U. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
  • Publication number: 20040126684
    Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.
    Type: Application
    Filed: December 16, 2003
    Publication date: July 1, 2004
    Applicant: Xerox Corporation
    Inventors: Anthony M. Horgan, Robert C.U. Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
  • Publication number: 20030194627
    Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.
    Type: Application
    Filed: September 6, 2002
    Publication date: October 16, 2003
    Inventors: Takaaki Ikegami, Yasuo Suzuki, Tomoyuki Shimada, Nozomu Tamoto, Hidetoshi Kami
  • Publication number: 20030152854
    Abstract: An electrophotographic photoreceptor including a photosensitive layer on an electroconductive substrate, wherein nitrate ion is present on the surface of the photosensitive layer in an amount of from 50 to 300 &mgr;g per 1 m2 of the surface of the photosensitive layer when the nitrate ion is determined by an ion chromatographic method. Preferably a material having a fluorine atom and a carbon atom or a fatty acid metal salt such as zinc stearate is further present on the surface of the photosensitive layer such that the F/C ratio is from 0.05 to 0.5 or the Zn/C ratio is from 0.001 to 0.1. An image forming apparatus using the photoreceptor is also provided.
    Type: Application
    Filed: January 28, 2003
    Publication date: August 14, 2003
    Inventors: Narihito Kojima, Ryuta Takeichi, Akiyo Namiki, Hiroshi Nagame, Yohta Sakon
  • Publication number: 20030054270
    Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.
    Type: Application
    Filed: July 22, 2002
    Publication date: March 20, 2003
    Inventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
  • Patent number: 6361913
    Abstract: An electrophotographic imaging member comprising a substrate, a charge generating layer, a charge transport layer, and an overcoat layer comprising a small molecule hole transporting triphenylmethane having at least one hydroxy functional group and a polyamide film forming binder capable of forming hydrogen bonds with the hydroxy functional groups of the hydroxy triphenyl methane. This overcoat layer may be fabricated using an alcohol solvent. This electrophotographic imaging member may be utilized in an electrophotographic imaging process.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: March 26, 2002
    Assignee: Xerox Corporation
    Inventors: Damodar M. Pai, John F. Yanus
  • Patent number: 6331370
    Abstract: An imaging member includes a charge generation layer and a contiguous charge transport layer containing a diamine and a compound within the scope of formula (II): wherein each R1 and R2 is independently one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl, where the aryl is a phenyl group or a condensed ring group, and where the alkyl group of the alkaryl and aralkyl has 1 to 4 carbon atoms, R3 and R4 are independently hydrogen or CH3, and R5 is one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl as defined above, or a disubstituted aminophenyl group wherein each substituent is independently one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl as defined above. A electrophotographic system includes a cleaning blade and the above imaging member drum.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 18, 2001
    Assignee: Xerox Corporation
    Inventors: Richard L. Schank, William W. Limburg, Dale S. Renfer
  • Publication number: 20010031411
    Abstract: An electrophotographic photoreceptor including a photosensitive layer on an electroconductive substrate, wherein nitrate ion is present on the surface of the photosensitive layer in an amount of from 50 to 300 &mgr;g per 1 m2 of the surface of the photosensitive layer when the nitrate ion is determined by an ion chromatographic method. Preferably a material having a fluorine atom and a carbon atom or a fatty acid metal salt such as zinc stearate is further present on the surface of the photosensitive layer such that the F/C ratio is from 0.05 to 0.5 or the Zn/C ratio is from 0.001 to 0.1. An image forming apparatus using the photoreceptor is also provided.
    Type: Application
    Filed: March 2, 2001
    Publication date: October 18, 2001
    Applicant: Ricoh Company Limited
    Inventors: Narihito Kojima, Ryuta Takeichi, Akiyo Namiki, Hiroshi Nagame, Yohta Sakon