Containing At Least Three Aryl Groups Bonded To A Single Carbon Atom In Charge Transport Layer Patents (Class 430/58.3)
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Patent number: 10599057Abstract: An electrophotographic photoreceptor that includes a conductive support; and at least a charge generation layer and a charge transport layer on the conductive support, where the charge transport layer includes at least two layers of a first charge transport layer which is an outermost layer and a second charge transport layer which is in contact with the first charge transport layer, such that the elastic deformation ratio of a binder resin A contained in the first charge transport layer is T1(%) and the elastic deformation ratio of a binder resin B contained in the second charge transport layer is T2(%) such that T1 and T2 satisfy a relationship of {0?(T1?T2)?4}, the first charge transport layer contains a charge transport material ? having a molecular weight of 600 or more, and the binder resin A and the binder resin B have different monomer units from each other.Type: GrantFiled: March 28, 2019Date of Patent: March 24, 2020Assignee: Mitsubishi Chemical CorporationInventors: Akiteru Fujii, Yuka Nagao, Wataru Miyashita
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Patent number: 8859173Abstract: An electrophotographic photoreceptor is disclosed, in which an outermost surface layer of the electrophotographic photoreceptor is made of a cured film of a composition including a compound represented by the following Formula (M1) and a charge transporting material having a chain polymerizable functional group:Type: GrantFiled: August 16, 2010Date of Patent: October 14, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Wataru Yamada, Katsumi Nukada, Takatsugu Doi, Tsuyoshi Miyamoto, Kenya Sonobe
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Patent number: 8846280Abstract: Provided is a compound represented by the following General Formula (I): wherein in General Formula (I), F represents a charge transporting subunit, L represents a linking group having a valency of (n+1) that is formed by combining two or more kinds selected from a group consisting of an alkylene group, —C?C— (an alkenylene group), —C(?O)—, —N(R)—, —O—, and —S—, and R represents a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, m represents an integer of from 1 to 6, and n represents an integer of from 2 to 3.Type: GrantFiled: February 16, 2012Date of Patent: September 30, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Wataru Yamada, Katsumi Nukada, Yuko Iwadate, Tomoya Sasaki, Kenji Kajiwara
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Patent number: 8785089Abstract: The present invention provides an electrophotographic photosensitive member, and a process cartridge and an electrophotographic apparatus, each of which has the electrophotographic photosensitive member. In the electrophotographic photosensitive member, a charge transport layer used as a surface layer contains a charge transport material, a polycarbonate resin A which has a specific amount of a specific repeating structural unit of a specific siloxane moiety, and a polyester resin C and/or a polycarbonate resin D, each of which has a specific repeating structural unit. In the charge transport layer, a matrix-domain structure is formed in which a matrix is formed from the charge transport material and the polyester resin C and/or the polycarbonate resin D, and domains are formed in the above matrix from the polycarbonate resin A.Type: GrantFiled: December 2, 2010Date of Patent: July 22, 2014Assignee: Canon Kabushiki KaishaInventors: Atsushi Okuda, Tsutomu Nishida
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Patent number: 8669028Abstract: An electrophotographic photoreceptor is provided, which includes: a substrate; a photosensitive layer; and a surface protective layer, in this order, in which the protective layer contains a crosslinked product of a curable charge transporting material in a content of from about 90 to 98% by weight, and fluorinated resin particles in a content of from about 2 to 10% by weight, and the protective layer satisfies Formula (1): 0.5?b/a?1, wherein, “a” represents a ratio of fluorine atoms to the sum of carbon atoms, oxygen atoms, and fluorine atoms present in a region of the protective layer ranging from the photosensitive layer side surface thereof to a point corresponding to about ? of the thickness thereof, and “b” represents the ratio in a region of the protective layer ranging from the outer surface thereof to a point corresponding to about ? of the thickness thereof.Type: GrantFiled: March 21, 2011Date of Patent: March 11, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yukimi Kawabata, Yuko Yamano, Kazuyuki Tada, Kenji Ikeda, Mitsuhide Nakamura
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Patent number: 8623577Abstract: To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming methType: GrantFiled: November 9, 2007Date of Patent: January 7, 2014Assignee: Ricoh Company, Ltd.Inventors: Tamotsu Horiuchi, Kazukiyo Nagai, Hongguo Li, Tetsuro Suzuki, Hiroshi Tamura
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Patent number: 8609309Abstract: To provide an electrophotographic photoreceptor having a high sensitivity, a good balance of various electric properties such as chargeability and residual potential, a good stability of the coating solution, and an excellent light resistance. An electrophotographic photoreceptor comprising an electroconductive support having thereon a photosensitive layer, wherein the photosensitive layer contains a compound represented by the following formula (1): (wherein R1 represents a group having a chiral center, R2 represents a hydrogen atom, an alkyl group which may have a substituent, or an aryl group which may have a substituent, R3 and R4 each independently represents an alkylene group which may have a substituent, or an arylene group which may have a substituent, and R5, R6, R7 and R8 each independently represents an alkyl group which may have a substituent, or an aryl group which may have a substituent, and at least one member of R5 to R8 is an aryl group having a substituent).Type: GrantFiled: August 16, 2010Date of Patent: December 17, 2013Assignee: Mitsubishi Chemical CorporationInventors: Yuka Nagao, Teruyuki Mitsumori, Masayuki Hiroi
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Patent number: 7544450Abstract: Polymers of naphthalene tetracarboxylic diimide dimmers are provided. The polymers are of the Formula I wherein the A units are selected from and Formula IX The polymers are suitable for use in the active layer of an imaging member and exhibit properties of both a binder and an electron-transporting material.Type: GrantFiled: March 19, 2008Date of Patent: June 9, 2009Assignee: Xerox CorporationInventors: Timothy P. Bender, John Graham, James M. Duff
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Patent number: 7449268Abstract: Polymers of naphthalene tetracarboxylic diimide dimmers are provided. The polymers are of the Formula I wherein the A units are selected from and Formula IX The polymers are suitable for use in the active layer of an imaging member and exhibit properties of both a binder and an electron-transporting material.Type: GrantFiled: May 27, 2005Date of Patent: November 11, 2008Assignee: Xerox CorporationInventors: Timothy P. Bender, John Graham, James M. Duff
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Patent number: 7291428Abstract: An electrophotographic imaging member having a charge generating layer and a charge transport layer overlayed thereon is provided. The charge transport layer has a lower surface and an upper surface, wherein the lower surface is in contiguous contact with the charge generating layer. The charge transport layer comprises a film forming polymer binder and a charge transport compound molecularly dispersed or dissolved therein to form a solid solution. The concentration of the charge transport compound in the charge transport layer decreases from the lower surface to the upper surface. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improved wear resistance, excellent imaging member electrical performance, and improved copy print out quality.Type: GrantFiled: December 15, 2006Date of Patent: November 6, 2007Assignee: Xerox CorporationInventors: Satchidanand Mishra, Anthony M. Horgan, Robert C. U. Yu, Dasarao K. Murti, Suresh K. Ahuja
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Patent number: 7144607Abstract: A polyimide-containing liquid crystal alignment treating agent having a structure of the formula (I) incorporated therein, wherein Q is a single bond or a divalent organic group, R1 to R4 represent aromatic groups, and R1 to R4 may be the same as, or different from, one another.Type: GrantFiled: June 11, 2002Date of Patent: December 5, 2006Assignee: Nissan Chemical Industries, Ltd.Inventors: Tomohisa Yamada, Hiroyoshi Fukuro, Hideyuki Endo
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Patent number: 7125633Abstract: An imaging member having a charge transport layer with multiple regions or layers is provided. The charge transport layer includes at least two charge transport layers coated from solutions of different components and concentrations, wherein the second (top) transport layer comprises a lower concentration of different charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the second (top) charge transport layer is a high mobility hole transport compound. The charge transport compound in each layer is dissolved or molecularly dispersed in an electrically inactive film forming polymer to form a solid solution. In such a construction, the resulting dual charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 12, 2003Date of Patent: October 24, 2006Assignee: Xerox CorporationInventors: Satchidanand Mishra, Houy Jen Yuh, Anthony M. Horgan, Markus R. Silvestri, Robert C. Yu, Yuh Tong, Dale Renfer, Kenny-tuan Dinh, Geoff Foley, Jack Yanus, Timothy Fuller
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Patent number: 7033714Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 16, 2003Date of Patent: April 25, 2006Assignee: Xerox CorporationInventors: Anthony M. Horgan, Robert C Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Patent number: 7005222Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 16, 2003Date of Patent: February 28, 2006Assignee: Xerox CorporationInventors: Anthony M. Horgan, Satchidanand Mishra, Robert C. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Patent number: 6946225Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.Type: GrantFiled: July 22, 2002Date of Patent: September 20, 2005Assignee: Eastman Kodak CompanyInventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
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Patent number: 6861188Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.Type: GrantFiled: September 6, 2002Date of Patent: March 1, 2005Assignee: Ricoh Company LimitedInventors: Takaaki Ikegami, Yasuo Suzuki, Tomoyuki Shimada, Nozomu Tamoto, Hidetoshi Kami
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Patent number: 6794102Abstract: A compound having the Formula I wherein: R1 is independently selected from the group consisting of a hetero atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety; R2 and R3 are independently selected from the group consisting of hydrogen, a halogen, a hetero -atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety; and R4, R5, R6, R7, R8, R9, R10 and R11 are independently selected from the group consisting of a nitrogen containing group, a sulfur containing group, a hydroxyl group, a silicon containing group, hydrogen, a halogen, a hetero atom containing group and a hydrocarbon group that is optionally substituted at least once with a hetero atom moiety.Type: GrantFiled: July 17, 2002Date of Patent: September 21, 2004Assignee: Xerox CorporationInventors: Timothy P. Bender, John F. Graham, James M. Duff
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Publication number: 20040151999Abstract: An imaging member having a charge transport layer with multiple regions or layers is provided. The charge transport layer includes at least two charge transport layers coated from solutions of different components and concentrations, wherein the second (top) transport layer comprises a lower concentration of different charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the second (top) charge transport layer is a high mobility hole transport compound. The charge transport compound in each layer is dissolved or molecularly dispersed in an electrically inactive film forming polymer to form a solid solution. In such a construction, the resulting dual charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: ApplicationFiled: December 12, 2003Publication date: August 5, 2004Applicant: Xerox CorporationInventors: Satchidanand Mishra, Houy Jen Yuh, Anthony M. Horgan, Markus R. Silvestri, Robert C.U. Yu, Yuhua Tong, Dale Renfer, Kenny-Tuan Dinh, Geoff Foley, Jack Yanus, Timothy Fuller
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Publication number: 20040126685Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: ApplicationFiled: December 16, 2003Publication date: July 1, 2004Applicant: Xerox CorporationInventors: Anthony M. Horgan, Satchidanand Mishra, Robert C.U. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Publication number: 20040126684Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: ApplicationFiled: December 16, 2003Publication date: July 1, 2004Applicant: Xerox CorporationInventors: Anthony M. Horgan, Robert C.U. Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Publication number: 20030194627Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.Type: ApplicationFiled: September 6, 2002Publication date: October 16, 2003Inventors: Takaaki Ikegami, Yasuo Suzuki, Tomoyuki Shimada, Nozomu Tamoto, Hidetoshi Kami
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Publication number: 20030152854Abstract: An electrophotographic photoreceptor including a photosensitive layer on an electroconductive substrate, wherein nitrate ion is present on the surface of the photosensitive layer in an amount of from 50 to 300 &mgr;g per 1 m2 of the surface of the photosensitive layer when the nitrate ion is determined by an ion chromatographic method. Preferably a material having a fluorine atom and a carbon atom or a fatty acid metal salt such as zinc stearate is further present on the surface of the photosensitive layer such that the F/C ratio is from 0.05 to 0.5 or the Zn/C ratio is from 0.001 to 0.1. An image forming apparatus using the photoreceptor is also provided.Type: ApplicationFiled: January 28, 2003Publication date: August 14, 2003Inventors: Narihito Kojima, Ryuta Takeichi, Akiyo Namiki, Hiroshi Nagame, Yohta Sakon
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Publication number: 20030054270Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.Type: ApplicationFiled: July 22, 2002Publication date: March 20, 2003Inventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
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Patent number: 6361913Abstract: An electrophotographic imaging member comprising a substrate, a charge generating layer, a charge transport layer, and an overcoat layer comprising a small molecule hole transporting triphenylmethane having at least one hydroxy functional group and a polyamide film forming binder capable of forming hydrogen bonds with the hydroxy functional groups of the hydroxy triphenyl methane. This overcoat layer may be fabricated using an alcohol solvent. This electrophotographic imaging member may be utilized in an electrophotographic imaging process.Type: GrantFiled: December 21, 1993Date of Patent: March 26, 2002Assignee: Xerox CorporationInventors: Damodar M. Pai, John F. Yanus
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Patent number: 6331370Abstract: An imaging member includes a charge generation layer and a contiguous charge transport layer containing a diamine and a compound within the scope of formula (II): wherein each R1 and R2 is independently one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl, where the aryl is a phenyl group or a condensed ring group, and where the alkyl group of the alkaryl and aralkyl has 1 to 4 carbon atoms, R3 and R4 are independently hydrogen or CH3, and R5 is one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl as defined above, or a disubstituted aminophenyl group wherein each substituent is independently one of an alkyl having 1 to 8 carbon atoms, aryl, alkaryl and aralkyl as defined above. A electrophotographic system includes a cleaning blade and the above imaging member drum.Type: GrantFiled: June 7, 1995Date of Patent: December 18, 2001Assignee: Xerox CorporationInventors: Richard L. Schank, William W. Limburg, Dale S. Renfer
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Publication number: 20010031411Abstract: An electrophotographic photoreceptor including a photosensitive layer on an electroconductive substrate, wherein nitrate ion is present on the surface of the photosensitive layer in an amount of from 50 to 300 &mgr;g per 1 m2 of the surface of the photosensitive layer when the nitrate ion is determined by an ion chromatographic method. Preferably a material having a fluorine atom and a carbon atom or a fatty acid metal salt such as zinc stearate is further present on the surface of the photosensitive layer such that the F/C ratio is from 0.05 to 0.5 or the Zn/C ratio is from 0.001 to 0.1. An image forming apparatus using the photoreceptor is also provided.Type: ApplicationFiled: March 2, 2001Publication date: October 18, 2001Applicant: Ricoh Company LimitedInventors: Narihito Kojima, Ryuta Takeichi, Akiyo Namiki, Hiroshi Nagame, Yohta Sakon