And Inorganic Silver Compound Patents (Class 430/619)
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Patent number: 7125656Abstract: Organic silver salt particles are manufacture by mixing an aqueous solution containing silver ions with an aqueous solution containing an organic acid alkali salt to form organic silver salt particles, using a mixing device in which plural supply tubes are connected to a discharge tube so that an axis of the discharge tube and axes of the supply tubes coincide at a single point.Type: GrantFiled: November 24, 2004Date of Patent: October 24, 2006Assignee: Konica Minolta Medical & Graphic, Inc.Inventor: Satoshi Ito
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Patent number: 7125657Abstract: The present invention provides a photothermographic material including a support having disposed thereon an image-forming layer that contains at least a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent and a binder, and further including a compound represented by the following formula (I): A-(W)n-P??(I) wherein A represents an atomic group having at least two mercapto groups as the substituent; W represents a divalent linking group; n represents 0 or 1; and P represents a pyrazolidone group.Type: GrantFiled: December 16, 2003Date of Patent: October 24, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuyuki Watanabe, Hiroyuki Mifune
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Patent number: 7122300Abstract: A photothermographic material comprising a support, and an image-forming layer and a non-photosensitive layer provided on a surface of the support, wherein the image-forming layer and the non-photosensitive layer are adjacent to each other; the image-forming layer includes a photosensitive silver halide, a first non-photosensitive organic silver salt, a first reducing agent, a polyhalogen compound and a binder; and the non-photosensitive layer includes a second non-photosensitive organic silver salt.Type: GrantFiled: March 9, 2005Date of Patent: October 17, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuhiro Yoshioka
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Patent number: 7118851Abstract: A silver halide emulsion comprises at least a dispersion medium, water and a silver halide grain, wherein grains occupying from 40 to 100% of the total projected area of said gains have an AgI content of 85 to 100 mol %, a single kind of outer shape except for size and the equivalent-circle projected diameter of from 0.002 to 20 ?m.Type: GrantFiled: September 15, 2005Date of Patent: October 10, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuo Saitou, Satoshi Aiba, Sumito Yamada, Eiichi Okutsu
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Patent number: 7118849Abstract: Photothermographic materials are coated with imaging layers and an antihalation layer between the support and thermally developable imaging layers on one or both sides of the support. Such materials can be arranged in association with one or more phosphor intensifying screens capable of providing emission at a predetermined wavelength in imaging assemblies. These imaging assemblies can be exposed to X-radiation and thereby excited to form a latent image in the photothermographic material that can eventually be used for medical diagnosis. The antihalation layers contain radiation absorbing compounds (such as a UV-radiation absorbing compounds) that absorb radiation at the predetermined wavelength (for example at 300 to 450 nm) and have limited absorption at higher wavelengths.Type: GrantFiled: July 21, 2004Date of Patent: October 10, 2006Assignee: Eastman Kodak CompanyInventors: Robert E. Dickerson, Kurt M. Schroeder
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Patent number: 7115358Abstract: The present invention provides a black and white photothermographic material having, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, as well as an image forming method. The black and white photothermographic material is characterized in that 1) the non-photosensitive organic silver salt includes at least one compound selected from the group consisting of a silver salt of an azole compound and a silver salt of a mercapto compound, and 2) the photosensitive silver halide has a spectral sensitizing dye in the form of a multilayer adsorbed on its surface. According to the invention, an improved black and white photothermographic material and image forming method realizing high sensitivity, favorable gradation, and less dependence on developing process conditions are provided.Type: GrantFiled: May 20, 2005Date of Patent: October 3, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Funakubo, Takeshi Suzumoto
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Patent number: 7115359Abstract: A photothermographic material having a support provided on at least one side of the support light-sensitive silver halide particles, an organic silver salt and a reducing agent, as well as a leuco dye of a specific structure and a compound of a specific structure.Type: GrantFiled: July 15, 2004Date of Patent: October 3, 2006Assignee: Konica Minolta Medical & Graphic, Inc.Inventors: Yasushi Usagawa, Takeshi Habu
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Patent number: 7112401Abstract: A photothermographic material comprising a support body provided on or above at least one surface thereof with an image forming layer, containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and binder, and a non-photosensitive layer, wherein: 1) 50% or more of the binder in the image forming layer is hydrophilic binder; 2) a ratio of the non-photosensitive organic silver salt to the hydrophilic binder is from 0.6 to 1.4 by mass; and 3) 70% or more of binder in the non-photosensitive layer is hydrophilic binder.Type: GrantFiled: September 8, 2005Date of Patent: September 26, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Hajime Nakagawa
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Patent number: 7112402Abstract: A photothermographic material of the present invention contains a slipping agent. One slipping agent is a liquid at a ordinary temperature, and an volatile rate of the slipping agent at 120° C. for one hour is 0.5% by mass or less as measured by a thermo-balance. The other slipping agent is that a permeating rate to the transportation rollers, when the transportation rollers are immersed in the slipping agent at 120° C. for 2 hours, is 6% by mass or less.Type: GrantFiled: January 12, 2004Date of Patent: September 26, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Yoshioka, Yoshihisa Tsukada, Takayoshi Oyamada, Minoru Sakai
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Patent number: 7108965Abstract: A photothermographic material for blue light exposure that has a good coating surface condition and an image forming method for use with the photothermographic material are provided. The photothermographic material includes a support, and an image forming layer provided on at least one side of the support. The image forming layer contains at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder. The photothermographic material is characterized in that: (1) a silver iodide content of the photosensitive silver halide is not less than 40 mole %; (2) the binder is a hydrophilic binder; (3) the image forming layer contains a silver iodide complexing agent; and (4) the image forming layer contains, as a silver carrier, at least one compound represented by the following Formula (I) or (II): (wherein Q represents an atomic group that is necessary to form a 5 or 6-membered imide ring).Type: GrantFiled: September 12, 2005Date of Patent: September 19, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Takayoshi Mori, Kazutaka Takahashi
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Patent number: 7105282Abstract: An image forming method using a photothermographic material a photosensitive silver halide, a reducing agent, a binder and a non-photosensitive organic silver salt, wherein: the photothermographic material is discharged from a thermal developing device within 35 seconds after heating for thermal development is ceased.Type: GrantFiled: August 21, 2003Date of Patent: September 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsutoshi Yamane, Sumito Yamada, Eiichi Okutsu, Tomoyuki Ohzeki, Yutaka Oka
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Patent number: 7105283Abstract: The present invention provides a black and white photothermographic material having, on at least one surface of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, wherein 70% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having an aspect ratio of 2.5 or more, a mean projected area equivalent diameter of 0.5 ?m to 8 ?m, and a mean grain thickness of 0.02 ?m to 0.2 ?m, and a ratio of a number of sites capable of forming a development initiation point on a corner portion or a fringe portion of the photosensitive silver halide grain to all development initiation points is 50% or more. Also disclosed is an image forming method of forming a radiation image by using a fluorescent intensifying screen.Type: GrantFiled: December 10, 2004Date of Patent: September 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Tomoyuki Ohzeki
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Patent number: 7105288Abstract: A photothermographic material is disclosed, comprising on a support a light-sensitive emulsion containing a light-insensitive organic silver salt and a light-sensitive silver halide, a reducing agent for silver ions and a binder, wherein the photothermographic material further comprises a compound represented by the following formula (A-1) or (B) and a compound represented by the following formula (A-2)Type: GrantFiled: August 13, 2003Date of Patent: September 12, 2006Assignee: Konica CorporationInventors: Kiyokazu Morita, Ayumu Nishijima
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Patent number: 7097963Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.0002 mol/m2 of a halogen-substituted tetraazaindene compound.Type: GrantFiled: April 18, 2005Date of Patent: August 29, 2006Assignee: Eastman Kodak CompanyInventors: Chaofeng Zou, Kumars Sakizadeh, George J. Burgmaier, Roger L. Klaus
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Patent number: 7097962Abstract: A photothermographic imaging material containing a support having thereon light-insensitive organic silver salt grains, photosensitive silver halide grains, a reducing agent for silver ions and a binder, wherein, (i) each of the organic silver salt grains has a structure having different silver ion dissociation constants at a surface portion and at an inner portion of the grain; (ii) each of the silver halide grains produces a larger number of latent images in a surface portion than in an inner portion of the grain by exposure to light; (iii) each of the silver halide grains produces a larger number of latent images in the inner portion than in the surface portion of the grain after being subjected to a thermal development; and (iv) a surface photographic speed of each of the silver halide grains decreases after being subjected to the thermal development.Type: GrantFiled: October 19, 2004Date of Patent: August 29, 2006Assignee: Konica Minoltn Medical & Graphic, Inc.Inventors: Hideki Komatsu, Hideki Takiguchi
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Patent number: 7094524Abstract: Thermally developable photothermographic materials comprise a backside layer that includes a backside stabilizer to reduce fog formation in high humidity conditions, thereby providing improved shelf stability. Useful backside stabilizers include an amine organic base whose conjugate acid has a pKa greater than 5. These backside stabilizers can be provided particularly in non-photosensitive compositions that include an antihalation composition.Type: GrantFiled: October 15, 2003Date of Patent: August 22, 2006Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Kumars Sakizadeh, William D. Ramsden
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Patent number: 7094526Abstract: A photothermographic imaging material containing a support having thereon photosensitive silver halide grains, light-insensitive organic silver salt grains, a reducing agent for silver ions and polymer, wherein and average particle size of the photosensitive silver halide grains is 0.005 to 0.1 ?m, and the polymer dissolves both in water and in an organic solvent.Type: GrantFiled: October 28, 2004Date of Patent: August 22, 2006Assignee: Konica Minolta Medical & Graphic, IncInventors: Hiroaki Ando, Kazuhito Ihara, Shinichi Karakata, Kazuyoshi Shioiri
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Patent number: 7087367Abstract: A photothermographic material is disclosed, comprising on a support a light-sensitive layer comprising a light-insensitive silver salt of an aliphatic carboxylic acid, light-sensitive silver halide grains, a reducing agent for silver ions and a binder, wherein the light-sensitive layer further comprises nonaqueous dispersion particles insoluble in organic solvents.Type: GrantFiled: January 20, 2005Date of Patent: August 8, 2006Assignee: Konica Minolta Medical & Graphic, INCInventors: Takayuki Sasaki, Akihisa Nakajima, Kiyokazu Morita
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Patent number: 7087366Abstract: A photothermographic emulsion is prepared by chemically sensitizing silver halide grains formed by oxidative decomposition of a diphenylphosphine sulfide compound on or around the silver halide grains. This procedure uses a unique sequence of steps and provides increased photographic speed and manufacturing reproducibility.Type: GrantFiled: December 9, 2003Date of Patent: August 8, 2006Assignee: Eastman Kodak CompanyInventors: Lilia P. Burleva, Kumars Sakizadeh, David R. Whitcomb, Sharon M. Simpson
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Patent number: 7087368Abstract: A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more ?m and 0.04 ?m or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.Type: GrantFiled: October 31, 2005Date of Patent: August 8, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Hiroshi Kashiwagi, Narito Goto
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Patent number: 7083908Abstract: A photothermographic material including a substrate carrying on one surface thereof an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion, and a binder, wherein the photosensitive silver halide has a silver iodide content of 40 to 100 mol %, and an average particle size of 5 to 80 nm, and the photothermographic material contains a compound of the following general formula (1); Q-(Y)n—C(Z1)(Z2)X??General formula (1) wherein Q represents a heterocycle, Y represents a divalent connecting group, n represents 0 or 1, Z1 and Z1 each represent a halogen atom, and X represents a hydrogen atom or an electron withdrawing group.Type: GrantFiled: April 14, 2003Date of Patent: August 1, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiichi Yamamoto, Eiichi Okutsu, Tomoyuki Ohzeki
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Patent number: 7067243Abstract: A process for preparing a photothermographic material with increased photosensitivity, the photothermographic material comprising a support and a photo-addressable thermally developable element, exclusive of a compound R—S(M)n wherein R is an aliphatic hydrocarbon, aryl or heterocyclic group, M is a hydrogen atom, or cation, and letter n is a number determined so as to render the molecule neutral and also exclusive of a compound capable of releasing a mobile dye corresponding to or inversely corresponding to the reduction of silver halide to silver at elevated temperatures, the photo-addressable thermally developable element containing a photosensitive agent in catalytic association with a light-insensitive organic silver salt, a reducing agent for the light-insensitive organic silver salt in thermal working relationship therewith and a binder, comprising the steps of: (i) increasing the photosensitivity of a photosensitive silver halide by chemical sensitisation with a chemical sensitising merocyanine dye coType: GrantFiled: March 7, 2003Date of Patent: June 27, 2006Assignee: Agfa GevaertInventors: Herman Uytterhoeven, Paul Callant
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Patent number: 7067242Abstract: Backside conductive layers with increased conductive efficiency can be provided for thermally developable materials by formulating hydrophilic metal oxide clusters in a hydrophobic environment using low shear mixing conditions. The dry thickness and coating weight of the conductive layer are thereby reduced.Type: GrantFiled: October 29, 2004Date of Patent: June 27, 2006Assignee: Eastman Kodak CompanyInventors: Thomas J. Ludemann, Gary E. LaBelle, Roland J. Koestner, Samuel Chen
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Patent number: 7060423Abstract: The heat-developable photosensitive material of the present invention comprises a support, a photosensitive silver halide, a non-photosensitive organic silver salt, a heat developer and a binder, wherein the photosensitive silver halide is a specific photosensitive silver halide.Type: GrantFiled: July 10, 2002Date of Patent: June 13, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsutoshi Yamane, Yasuhiko Goto
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Patent number: 7056651Abstract: Thermally developable materials for thermography or photothermography have imaging layers on one or both sides of the support. Buried conductive underlayers are disposed under these imaging layers on one or both sides of the support, and these conductive underlayers include conductive metal oxide(s) and optionally a smectite clay or lithium salt.Type: GrantFiled: April 18, 2005Date of Patent: June 6, 2006Assignee: Eastman Kodak CompanyInventors: Sharon M. Simpson, Jon A. Hammerschmidt, Kumars Sakizadeh
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Patent number: 7056652Abstract: A silver salt photothermographic material is disclosed, comprising on a support a light-insensitive silver salt of an aliphatic carboxylic agent, light-sensitive silver halide grains, a reducing agent for silver ions and a binding agent, wherein the silver halide grains are those which are capable being converted from a surface latent image formation type to internal latent image formation type upon thermal development, and the photothermographic material further comprises a dye microcapsule dispersion or a dye compound containing at least two chromophores.Type: GrantFiled: October 22, 2004Date of Patent: June 6, 2006Assignee: Konica Minolta Medical & Graphic, Inc.Inventor: Hiroshi Kashiwagi
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Patent number: 7056650Abstract: Thermally developable imaging materials have an outermost protective layer that is composed of one or more hydrophilic film-forming components. The predominant film-forming component is a positively-charged latex polymer that has cationic groups. The charged latex polymer is present as latex particles that have prepared in the presence of a non-ionic or cationic stabilizer in an amount of at least 0.5% (by weight) that has an HLB value of 7 to 20. The nonionic or cationic stabilizer becomes associated with the latex polymer particles. Both thermographic and photothermographic materials can be prepared with such protective layers.Type: GrantFiled: September 7, 2004Date of Patent: June 6, 2006Assignee: Eastman Kodak CompanyInventors: Jon A. Hammerschmidt, Jeffrey W. Leon
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Patent number: 7052828Abstract: The present invention provides a photothermographic material including at least a photosensitive silver halide, a non-photosensitive silver-supplying compound, a reducing agent and a binder on at least one surface of a support. The photothermographic material further includes at least one kind of halogen releasing compound having a water-solubilizing group and at least one kind of halogen releasing compound having no water-solubilizing group, and a gradation of a characteristic curve is 2.5 to 4.0. The photothermographic material of the invention is excellent in storability, and particularly excellent in storability of high quality images used for image recording for medical diagnosis.Type: GrantFiled: September 14, 2004Date of Patent: May 30, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuhiro Yoshioka
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Patent number: 7052819Abstract: The addition of certain aliphatic and non-aromatic carbocyclic polycarboxylic acids provides an improvement in natural age keeping properties of organic-solvent based photothermographic materials. This improvement is particularly useful in organic-based photothermographic materials containing phosphors in the photothermographic emulsion layer. Phosphor-containing materials can be particularly useful for direct radiographic imaging using X-radiation.Type: GrantFiled: April 16, 2004Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventor: Sharon Mary Simpson
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Patent number: 7049054Abstract: Thermally developable imaging materials have an outermost protective layer that is composed of one or more hydrophilic film-forming components. Between the outermost protective layer and the underlying thermally developable imaging layers is an interlayer containing a film-forming ionic latex polymer other than a carboxy-containing latex polymer. This ionic polymer can be negatively-charged or positively-charged. The ionic latex polymer is present as latex particles that have been prepared in the presence of a stabilizer in an amount of at least 0.5% (by weight) that has an HLB value of 7 to 20. The stabilizer becomes associated with the latex polymer particles. Both thermographic and photothermographic materials can be prepared with such protective layers.Type: GrantFiled: September 7, 2004Date of Patent: May 23, 2006Assignee: Eastman Kodak CompanyInventors: Jon A. Hammerschmidt, Jeffrey W. Leon
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Patent number: 7049056Abstract: A method for wrapping a heat-developable photosensitive material, which comprises bending a wrapping material so that the wrapping material can bring into direct contact with at least a part of a heat-developable photosensitive material comprising a photosensitive silver halide, a reducing agent, a binder and a non-photosensitive organic silver salt having a silver behenate content of not lower than 53 mol % provided on one side of a support, wherein the wrapping material is a paper.Type: GrantFiled: February 6, 2003Date of Patent: May 23, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Takayoshi Oyamada, Yasuhiro Yoshioka, Eiichi Okutsu
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Patent number: 7026104Abstract: A heat-developable photosensitive material comprising on a support light-sensitive silver halide, a light-insensitive organic silver salt, a reducing agent and a binder, wherein at least 30 mole % of the total light-sensitive silver halide is silver halide of high silver iodide content having an average ?-phase proportion of from 5 to 70 mole %, and a method of forming images on the heat-developable photosensitive material with a semiconductor laser.Type: GrantFiled: February 27, 2003Date of Patent: April 11, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Fumito Nariyuki
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Patent number: 7026109Abstract: The present invention provides a photothermographic material, comprising a photosensitive silver halide, a non-photosensitive organic solvent salt, a reducing agent for a silver ion, and a binder on one face of a support, for being applied by using an organic solvent, the photothermographic material further comprising at least one compound selected from the group of compounds consisting of: a compound represented by the following general formula (1), a compound having a ?-lactam ring, a compound having a group that is adsorptive to a silver halide and a group that reduces a silver halide and a precursor thereof:Type: GrantFiled: August 4, 2003Date of Patent: April 11, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomoyuki Ohzeki, Hiroyuki Mifune, Tadashi Inaba, Kohzaburoh Yamada, Katsuyuki Watanabe
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Patent number: 7022470Abstract: A photothermographic imaging material having high sensitivity and superior temporal storage stability. The photothermographic imaging material includes silver halide on at least one side of a support, and includes at least one kind of the compounds represented by the following general formula (1).Type: GrantFiled: March 24, 2004Date of Patent: April 4, 2006Assignee: Konica Minolta Medical & Graphic, Inc.Inventors: Kiyoshi Fukusaka, Kazuaki Nakamura, Ryouhei Iwamoto, Norio Miura, Nobuaki Kagawa, Soc Man Ho Kimura
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Patent number: 7022467Abstract: Backside conductive layers with increased conductive efficiency can be provided for thermally developable materials by providing a buried conductive coating containing a lower molecular weight polyvinyl acetal binder (that is, a molecular weight of at least 8,000 and less than 30,000).Type: GrantFiled: November 30, 2004Date of Patent: April 4, 2006Assignee: Eastman Kodak CompanyInventors: Thomas J. Ludemann, Roland J. Koestner, Gary E. LaBelle, Darlene F. Philip
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Patent number: 7022471Abstract: An organic silver salt dispersion containing: light-insensitive organic silver salt grains; photosensitive silver halide grains; a solvent; and a binder for dispersion, wherein the organic silver salt is prepared by using: (i) an alkaline metal salt of an organic acid other than a sodium salt; and (ii) a water soluble silver compound, and the binder is a polyvinyl acetal resin having a polymerization degree of 250 to 1000 and prepared by acetal forming reaction of a polyvinylalcohol with an aldehyde.Type: GrantFiled: August 19, 2004Date of Patent: April 4, 2006Assignee: Konica Minolta Medical & Graphic Inc.Inventor: Kenji Ohnuma
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Patent number: 7018790Abstract: A photothermographic imaging material including a support; an image forming layer containing an organic silver salt, a photosensitive silver halide, a binder and a silver ion reducing agent, the image forming layer being provided on the support; and a cyan coloring leuco dye.Type: GrantFiled: December 2, 2003Date of Patent: March 28, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Hiroshi Kashiwagi, Narito Goto
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Patent number: 7018787Abstract: Thermally developable materials such as photothermographic and thermographic materials have a backside conductive layer with increased conductive efficiency. This backside conductive layer is a buried conductive coating and is overcoated with a layer that contains a smectite clay modified with a quaternary ammonium compound.Type: GrantFiled: November 30, 2004Date of Patent: March 28, 2006Assignee: Eastman Kodak CompanyInventors: Thomas J. Ludemann, Gary E. LaBelle, Darlene F. Philip, Thomas C. Geisler
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Patent number: 7018786Abstract: A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is represented by formula (I): wherein R1 is a hydrogen atom or an alkyl, an alkenyl, an alkynyl, a cycloalkyl, an alkaryl, an aryl, a heterocyclic or a heteroaryl group all of which may be optionally substituted; with the proviso that R1 may not be a hydrogen atom if both R2 and R3 are both hydrogen atoms; R2 and R3 are independently a hydrogen or a halogen atom or an amino, amide, ester, carboxy, carbonate, alkyl, alkenyl, alkynyl, cycloalkyl, alkaryl, aryl, heterocyclic or heteroaryl group all of which may be optionally substituted; R2 and R3 may together represent the atoms necessary to complete a heteroaromatic ring with no more than one nitrogType: GrantFiled: December 16, 2003Date of Patent: March 28, 2006Assignee: AGFA GevaertInventors: Ingrid Geuens, Johan Loccufier, Vera Drieghe
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Patent number: 7018770Abstract: A reflective radiographic material is useful to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support and a silver halide emulsion on one side of the support only. The material can be used with a single green- or blue-light emitting fluorescent intensifying screen as part of an imaging assembly. The reflective support enables the image in the radiographic material to be viewed without a light box and the speed of the material enables the use of low power X-radiation generating equipment.Type: GrantFiled: March 28, 2005Date of Patent: March 28, 2006Inventors: Robert E. Dickerson, Kenneth A. Duke, Phillip C. Bunch, Alan S. Fitterman
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Patent number: 7014989Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.00005 mol/m2 of a 4-substituted urazole.Type: GrantFiled: April 18, 2005Date of Patent: March 21, 2006Assignee: Eastman Kodak CompanyInventors: Sharon M. Simpson, Kumars Sakizadeh
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Patent number: 7014977Abstract: A reflective radiographic material (at least 200 system speed) is useful especially to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support, a silver halide emulsion on one side of the support only, and a photographic speed of at least 200. The reflective material also includes an incorporated black-and-white developing agent and a co-developing agent, and can be used with a single fluorescent intensifying screen as part of an imaging assembly. The reflective support enables viewing the resulting image without a light box and the high speed of the material enables the use of low power X-radiation generating equipment. The incorporated black-and-white developing agent and co-developing agent allow the radiographic material to be quickly processed after exposure using simplified processing chemistry.Type: GrantFiled: March 28, 2005Date of Patent: March 21, 2006Assignee: Eastman Kodak CompanyInventors: Robert E. Dickerson, Kenneth A. Duke, Alan S. Fitterman
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Patent number: 7008748Abstract: Thermally developable materials such as thermographic and photothermographic materials include a co-precipitate comprising first and second organic silver salts, the first organic silver salt comprising a silver salt of a nitrogen-containing heterocyclic compound containing an imino group, and the second organic silver salt comprising a silver salt of a mercaptotriazole. The first organic silver salt can be used in the imaging process as a source of reducible silver ions, and the second organic silver salt can be a source of a toning agent. The co-precipitate can be prepared using double-jet precipitation techniques to provide an aqueous dispersion that can be used in imaging formulations.Type: GrantFiled: September 7, 2004Date of Patent: March 7, 2006Assignee: Eastman Kodak CompanyInventors: Dirk J. Hasberg, Doreen C. Lynch, Kui Chen-Ho, Chaofeng Zou
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Patent number: 7005251Abstract: A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more ?m and 0.04 ?m or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.Type: GrantFiled: November 20, 2003Date of Patent: February 28, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Hiroshi Kashiwagi, Narito Goto
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Patent number: 6994952Abstract: A silver halide emulsion comprises at least a dispersion medium, water and a silver halide grain, wherein grains occupying from 40 to 100% of the total projected area of said gains have an AgI content of 85 to 100 mol %, a single kind of outer shape except for size and the equivalent-circle projected diameter of from 0.002 to 20 ?m.Type: GrantFiled: March 20, 2003Date of Patent: February 7, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuo Saitou, Satoshi Aiba, Sumito Yamada, Eiichi Okutsu
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Patent number: 6991894Abstract: Thermographic and photothermographic materials comprise a barrier layer to provide physical protection and to prevent migration of diffusible imaging components and by-products resulting from high temperature imaging and/or development. The barrier layer comprises a scavenger that is a metal hydroxide or ester. This barrier layer is capable of retarding diffusion of mobile chemicals such as organic carboxylic acids, developers, and toners.Type: GrantFiled: November 3, 2003Date of Patent: January 31, 2006Assignee: Eastman Kodak CompanyInventors: Kumars Sakizadeh, Karissa L. Eckert, Gary E. LaBelle, David R. Whitcomb
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Patent number: 6974662Abstract: Improved compounds and base precursors that undergo thermal decomposition are disclosed. Thermal base precursors, and in particular, a novel class of salts of arylsulfonylacetic acids as bleaching agents or promoting for photothermographic use are disclosed. Compositions employing these thermal base precursors are suitable for use in acutance and antihalation systems, bleachable filter dye materials, and in promoting unblocking of various components such as blocked developers, especially in photothermographic elements.Type: GrantFiled: August 4, 2003Date of Patent: December 13, 2005Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Wojciech K. Slusarek, David H. Levy
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Patent number: 6964842Abstract: Aqueous-based photothermographic materials comprise a hydrophilic binder, preformed silver halides, an organic silver salt, a reducing agent composition, and one or more benzothiazolium, benzoselenazolium, or benzotellurazolium salts as antifoggants. These photothermographic materials can be used in combination with phosphor intensifying screens for radiographic imaging.Type: GrantFiled: August 14, 2003Date of Patent: November 15, 2005Assignee: Eastman Kodak CompanyInventors: Chaofeng Zou, Roger L. Klaus
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Patent number: 6958209Abstract: A photothermographic material comprising a support and having thereon an image forming layer containing an organic silver salt, light-sensitive silver halide grains, binder and a reducing agent, wherein the reducing agent comprises: a reducing agent A containing at least a bisphenol derivative represented by following Formula (A-1); and a reducing agent B containing at least a bisphenol derivative not represented by the Formula (A-1), and the amount of reducing agent A is 5 to 45 weight % of the total weight of the reducing agent A and reducing agent B.Type: GrantFiled: December 27, 2002Date of Patent: October 25, 2005Assignee: Konica CorporationInventors: Kiyokazu Morita, Narito Goto, Ayumu Nishijima
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Patent number: 6949333Abstract: The present invention provides a photosensitive silver halide photographic emulsion comprising a silver iodide content of 41 mol % or more and 100 mol % or less and including a silver halide to which reduction sensitization is applied in the course of particle formation, and silver halide photographic emulsion comprising 41 mol % to 100 mol % of silver iodide and subjected to at least one of chalcogen sensitization and gold sensitization to the insides of particles.Type: GrantFiled: January 16, 2004Date of Patent: September 27, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Mifune