And Inorganic Silver Compound Patents (Class 430/619)
  • Patent number: 6942960
    Abstract: Aqueous-based thermally sensitive emulsions and photothermographic imaging materials include photosensitive silver halide grains that comprise at least 15 mol % iodide based on total silver in the grains and are doped with bismuth (+3). These materials have increased photographic speed especially in the infrared region of the electromagnetic spectrum.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: September 13, 2005
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, David A. Dickinson, Victor P. Scaccia, Richard L. Gaines
  • Patent number: 6939667
    Abstract: A photo sensitive emulsion disclosed, comprising an organic silver salt, a photosensitive silver halide and a dispersing medium, wherein the organic silver salt is comprised of at least a first organic silver salt grains and a second organic silver salt grains which are different in average grain size from each other. A photothermographic material containing is also disclosed.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: September 6, 2005
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Yasuo Taima
  • Patent number: 6924089
    Abstract: An object of the present invention is to provide a novel heat-developable photosensitive material which hardly exerts an influence on the image color tone and exhibits high sensitivity. Disclosed is a heat-developable photosensitive material comprises, on the same surface of a substrate, at least (a) photosensitive silver halide, (b) a reducible silver salt, (c) a compound represented by the general formula (5), (d) a binder, (e) a compound represented by the general formula (6) or (7), and (f) a compound represented by the general formula (3).
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: August 2, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toyohisa Oya, Hirokazu Kyota, Kouta Fukui
  • Patent number: 6916599
    Abstract: A photothermographic material comprising: a support; and a photosensitive silver halide, a nonphotosensitive organic silver salt, a reducing agent and a binder, wherein the photosensitive silver halide comprises 90% by mole or more of a silver iodide and has a silver iodobromide structure having an average silver iodide content of 35% by mole or less in vicinity of a surface thereof.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: July 12, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fumito Nariyuki
  • Patent number: 6913876
    Abstract: A photothermographic material is disclosed, comprising a support, an organic silver salt, a light-sensitive silver halide, a reducing agent and a contrast-increasing agent, wherein the photothermographic material further comprises a secondary or tertiary amino group-containing alkoxysilane compound and a polyethyleneimine. A light-shielding package of the photothermographic material is also disclosed.
    Type: Grant
    Filed: July 24, 2003
    Date of Patent: July 5, 2005
    Assignee: Konica Corporation
    Inventor: Yasunobu Kobayashi
  • Patent number: 6890705
    Abstract: The second silver halide photosensitive material comprises a substrate and at least one photosensitive silver halide emulsion layer formed thereon, the silver halide photosensitive material comprising at least two types of silver halide grains with different projected areas having photosensitivity in the same spectral range; silver halide grains having a larger projected area having a refractive index n1 and an average thickness a, and silver halide grains having a smaller projected area having a refractive index n2 and an average thickness b; and the silver halide grains satisfying the conditions defined by the following equation (1): n2?n1, and a?b×(n2/n1)??(1).
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: May 10, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoteru Miyake, Masahiro Asami
  • Patent number: 6844129
    Abstract: The present invention provides a heat-developable photosensitive material having a substrate, an undercoat layer and photosensitive layer containing silver behenate in this order, wherein an adhesive roll having an adhesive force of at least 35 hPa is brought into contact with one face or both faces of the photosensitive material before the photosensitive layer is formed, and a method of producing the same.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: January 18, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshimitsu Ito
  • Publication number: 20040265757
    Abstract: A photo sensitive emulsion disclosed, comprising an organic silver salt, a photosensitive silver halide and a dispersing medium, wherein the organic silver salt is comprised of at least a first organic silver salt grains and a second organic silver salt grains which are different in average grain size from each other. A photothermographic material containing is also disclosed.
    Type: Application
    Filed: June 17, 2004
    Publication date: December 30, 2004
    Applicant: Konica Minolta Medical & Graphic, Inc.
    Inventor: Yasuo Taima
  • Publication number: 20040259044
    Abstract: A black and white photothermographic material is imaged and heat developed to provide an image that has an image tone that is characterized such that the value for b* at an optical density of 1.0 is greater than the value for b* at Dmin. This material is useful for recording medical images used for diagnosis, particularly those images which have been captured through computed radiography, digital radiography, or by digitally scanning a conventional wet-processed radiographic film.
    Type: Application
    Filed: October 16, 2003
    Publication date: December 23, 2004
    Applicant: Eastman Kodak Company
    Inventors: Bryan V. Hunt, Lilia P. Burleva, Mark C. Skinner
  • Patent number: 6830879
    Abstract: Disclosed is a photothermographic material having a support, at least one photosensitive layer containing a silver halide and a reducing agent and a non-photosensitive layer containing aggregates of a dye, wherein a transmission absorption spectrum of the aggregates has a maximum absorption wavelength within the range of 600-750 nm. The photothermographic material is easy to handle and provide an image having sufficient definition without residual color after development. The photothermographic material is suitable for light exposure with a red laser.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: December 14, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryo Suzuki, Keiichi Suzuki, Yoshiharu Yabuki
  • Patent number: 6828070
    Abstract: A photosensitive material comprising a substrate and a reversibly decolorable colored layer disposed thereon, wherein the reversibly decolorable colored layer is reversibly colored and decolored, the reversibly decolorable colored layer is in a colored state at 25 ° C., and a temperature at which the color density of the reversibly decolorable colored layer is reduced to 50% based on that at 25 ° C. is 50 to 120 ° C. A method for forming an image using the photosensitive material is also provided.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: December 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunichi Ishikawa, Yoshiharu Yabuki
  • Patent number: 6824962
    Abstract: Disclosed is a photothermographic material containing at least a photosensitive silver halide, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions and a binder on one surface of a support, wherein the material contains a compound producing imagewise a chemical species that can form development initiation points on and in the vicinity of the non-photosensitive silver salt of an organic acid or the like and an organic gold compound and the photosensitive silver halide has a mean grain size of 0.12 &mgr;m or less. This photothermographic material shows high sensitivity, low fog, high Dmax (maximum density), little increase of fog during storage and low temperature and humidity dependency during development.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: November 30, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tokuju Oikawa
  • Publication number: 20040234911
    Abstract: The present invention provides a ehat-developabel photosensitive material comprising a support having provided thereon an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, wherein a binder of an outermost layer at a side of the support at which the image forming layer is provided includes a latex polymer such as an ionomer type urethane polymer latex in an amount of 85 mass % or more, preferably 90 mass % or more, and more preferably 95 mass % or more. The heat-developable photosensitive material may also have a layer adjacent to the outermost layer which layer contains a binder that gels due to temperature reduction or contains a binder containing a water-soluble polymer derived from animal protein in an amount of 50 mass % or more.
    Type: Application
    Filed: April 7, 2004
    Publication date: November 25, 2004
    Inventor: Keiichi Suzuki
  • Patent number: 6821721
    Abstract: A photothermographic material comprising: a substrate; and a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, in a same region defined by the substrate, wherein the photothermographic material further comprises a fluorine compound which comprises at least one fluoroalkyl group having 2 or more of carbon atoms and not more than 13 of fluorine atoms and at least one of anionic and nonionic hydrophilic groups, and 40 to 98% by mol of the non-photosensitive organic silver salts are silver behenate.
    Type: Grant
    Filed: April 16, 2003
    Date of Patent: November 23, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Yoshioka
  • Patent number: 6821720
    Abstract: A method of producing a thermal-developable photosensitive material is provided, which prevents mixing of materials between layers to ensure that the coating surface is in a good condition. In this method, liquids for forming a photosensitive layer, an intermediate layer and a protective layer are simultaneously applied in a multilayer form on a substrate to produce a thermal-developable photosensitive material. A pH of the intermediate layer coating liquid is adjusted within a range from 5 to 10 and a viscosity of the intermediate layer coating liquid is adjusted within a range from 20 to 150 mPa·s. Moreover, a pH buffering salt is added to the intermediate layer coating liquid.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: November 23, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Junpei Iwado
  • Patent number: 6811964
    Abstract: A coating liquid for photothermographic materials excellent in photographing performance with high sensitivity and reduced fogging and having satisfactory surface conditions is produced. A silver halide particle feeding solution is added and mixed in a mother liquid of coating liquid during a time period between the instant 30 minutes before a substrate is coated with the produced coating liquid by a coating head and the instant just before the coating is started, and in addition, an in-plant mixer is configured such that a mixing container has an inner surface of a spherical shape, an oblate-spherical shape or a prolate-spherical shape so that a mixing blade forms a mixing area in proximity to any part of the inner surface of the mixing container when a rotation axis supporting the mixing blade is driven in a reciprocal manner, whereby the mixing performance of the in-plant mixer is significantly improved.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: November 2, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasushi Sano
  • Patent number: 6808872
    Abstract: A silver salt photothermographic material exhibiting enhanced image quality and superior uniformity without causing uneven density is disclosed, comprising on a support a light-sensitive layer comprising a light-sensitive emulsion containing organic silver salt grains and light-sensitive silver halide grains, a reducing agent and a binder and a conductive layer, wherein the conductive layer contains at least one of compounds represented by the following general formulas: (Rf2)—(A2)s LiO3S—(CF2)m—SO3Li MO3S—(CF2)t—SO3M L[O3S—(CF2)u—SO3]
    Type: Grant
    Filed: June 10, 2003
    Date of Patent: October 26, 2004
    Assignee: Konica Corporation
    Inventor: Shinji Kudo
  • Patent number: 6803177
    Abstract: Novel silver compounds can include a primary core of a photosensitive silver halide and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. Other novel silver compounds are homogeneous silver salts of organic silver coordinating ligands throughout (non-core-shell). Still other silver compounds can include a primary core of a non-photosensitive metal salt and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. These types of silver compounds can be used as sources of reducible silver ions in thermally developable imaging materials including thermographic and photothermographic materials.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: October 12, 2004
    Assignee: Eastman Kodak Company
    Inventors: Boris B. Bokhonov, Lilia P. Burleva, David R. Whitcomb, Nepal C. Howlader, Louis M. Leichter
  • Patent number: 6800430
    Abstract: A photothermographic material comprising a photosensitive silver halide, a reducible silver salt, a phenolic reducing agent, a binder and a compound represented by the following formula on the same surface of a support: wherein X1 is a substituent, X2 to X4 are a hydrogen atom or a substituent, and R1 is an alkyl group etc. The photothermographic material shows high sensitivity, high Dmax and low fog and can provide images suitable for use in photomechanical process.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: October 5, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirokazu Kyota, Toshihide Ezoe, Minoru Sakai, Toyohisa Oya
  • Patent number: 6800427
    Abstract: A heat-developable photosensitive material, which comprises a light-sensitive layer containing a light-sensitive silver halide, a light-insensitive organic silver salt, a thermal developer and a binder and a protective layer containing a fluorine compound having at least one fluorinated alkyl group having not less than 2 carbon atoms and not more than 13 fluorine atoms and at least one anionic or nonionic hydrophilic group, and is subjected to processing by a heat-developing machine having a stock tray for heat-developable photosensitive materials placed at the height of not more than 55 cm above the floor.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: October 5, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsutoshi Yamane
  • Patent number: 6800431
    Abstract: There is disclosed photothermographic material exhibiting superior photographic performance and having improved latitude for variation in thermal developing conditions, comprising on a support an organic silver salt, light-sensitive silver halide and a reducing agent for silver ions, wherein the reducing agent is represented by the following formula in which R1 through R4, L1, X1, X2 n and m have the meaning stated in the specification.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: October 5, 2004
    Assignee: Konica Corporation
    Inventors: Norio Miura, Ryohei Iwamoto, Kazuaki Nakamura, Hiroyuki Yasukawa, Kiyoshi Fukusaka
  • Patent number: 6794123
    Abstract: A preparation process for a first aqueous dispersion comprising an ex-situ photosensitive silver halide and a substantially light-insensitive silver salt of an organic carboxylic acid, comprising the steps of: separately preparing a second aqueous dispersion comprising the ex-situ photosensitive silver halide and a third aqueous dispersion comprising the substantially light-insensitive silver salt of an organic carboxylic acid; and mixing the second aqueous dispersion with the third aqueous dispersion to produce a mixture thereof, characterized in that the first aqueous dispersion thereby produced is substantially free of a water-soluble metal or ammonium salt of an aliphatic carboxylic acid with greater than 12 carbon atoms and the process further comprises a step selected from the group consisting of: increasing the pH of the second aqueous dispersion to a value of at least 8.0 prior to mixing with the third aqueous dispersion; increasing the pH of the third aqueous dispersion to a value of at least 8.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: September 21, 2004
    Assignee: AGFA-Gevaert
    Inventors: Herman Uytterhoeven, Luc Vissers
  • Publication number: 20040180301
    Abstract: A photothermographic material containing a photosensitive silver halide, a reducing agent, a binder having a glass-transition temperature of 70 to 110° C., and a non-photosensitive organic silver salt, wherein (i) the reducing agent is a compound represented by the following general formula (R), (ii) the photothermographic material comprises a development accelerator, or (iii) the non-photosensitive organic silver salt contains 50% by mole or more of silver behenate.
    Type: Application
    Filed: March 1, 2004
    Publication date: September 16, 2004
    Inventor: Hajime Nakagawa
  • Patent number: 6790569
    Abstract: A color photothermographic element comprising at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, and a blocked developer in the presence of a thermal solvent represented by the following structure: wherein the groups are as defined in the specification to promote the thermal development of the photothermographic element.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: September 14, 2004
    Assignee: Eastman Kodak Company
    Inventors: Xiqiang Yang, Zbyslaw R. Owczarczyk, David T. Southby, Mark E. Irving, Paul B. Merkel, Lyn M. Irving, David H. Levy
  • Patent number: 6787298
    Abstract: Disclosed is a highly sensitive photothermographic material containing on a support a silver salt of an organic acid, a photosensitive silver halide, a reducing agent, a binder and, for example, a compound of which one-electron oxidized derivative produced by one electron oxidation of the compound is capable of releasing two or more electrons with a bond cleavage.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: September 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Kohzaburoh Yamada, Tomoyuki Ohzeki, Eiichi Okutsu, Shoji Yasuda
  • Patent number: 6787299
    Abstract: A silver salt photothermographic imaging material is disclosed, comprising a light-sensitive aliphatic acid silver salt, a light-sensitive emulsion containing light-sensitive halide grains, a reducing agent for silver ions, a binder and a cross-linking agent, wherein the cross-linking agent is an aromatic polyisocyanate compound and the photothermographic material further comprises a compound selected from compounds represented by the following formulas.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: September 7, 2004
    Assignee: Konica Corporation
    Inventors: Hirobumi Yamashita, Toshihisa Takeyama
  • Patent number: 6783925
    Abstract: A thermally processed image forming material containing elsewhere on a support a reducing agent, a binder and non-photosensitive fatty silver salt grains was disclosed, in which (1) the non-photosensitive fatty acid silver salt grains are prepared by mixing and reacting a silver ion-containing solution, the solvent of which being water or a mixture of water and an organic solvent, with a solution of a fatty acid alkali metal salt, the solvent of which being water, an organic solvent, or a mixture of water and an organic solvent, in a closed mixing means, or (2) the non-photosensitive fatty acid silver salt grains are prepared by micro-dispersing the reaction mixture at an operating pressure of 1,800 kg/cm2 or above using a ultrahigh pressure dispersion apparatus. Such thermally processed image forming material is excellent in the coated surface quality, and can afford an image which is low in fog and high in Dmax (maximum density).
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: August 31, 2004
    Assignee: Fuji Photo Film Co., LTD
    Inventor: Shoji Yasuda
  • Patent number: 6783927
    Abstract: A photothermographic material is described which comprises a support having provided on one surface thereof at least one kind of a light-sensitive silver halide, a light-insensitive organic silver salt, a reducing agent for silver ions, and a binder, wherein the photothermographic material comprises the surface active agent represented by the following formula (F): wherein Rf represents a perfluoroalkyl group, Rc represents an alkylene group, Z represents a group having an anionic group, a cationic group, a betaine-series group, or a nonionic polar group necessary for imparting a surface activity, n represents an integer of 0 or 1, and m represents an integer of 1, 2 or 3. The photothermographic material can remarkably prevent attaching of dust, etc., which become the case of forming white spots after heat development.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: August 31, 2004
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventor: Yasuhiro Yoshioka
  • Patent number: 6780578
    Abstract: The thermally developable photosensitive material of the present invention has a support and including on at least one surface of the support a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development, a binder and a compound represented by the following general formula (1): wherein R1 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group; X represents a chalcogen atom; and Y represents an amino group, an N-alkylamino group, an N,N-dialkylamino group, an anilino group, a hydroxyl group, an alkoxy group, an aryloxy group, an acylamino group or a sulfonamide group, and wherein when Y represents an alkoxy group, an alkylamino group, a dialkylamino group, an acylamino group or a sulfonamide group, Y and R1 may be bonded to each other to form a 5- to 7-membered ring.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: August 24, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Yoshioka, Keiichi Suzuki
  • Publication number: 20040161714
    Abstract: A photothermographic material contains a support having thereon an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and a non-photosensitive outermost layer on a side of the support where the image forming layer is provided, The photosensitive silver halide contains silver iodide in an amount of from 40 to 100% by mole, and a binder contained in the outermost layer contains at least one of a latex polymer and a water soluble polymer that is not derived from an animal protein in an amount of 50% by mass or more.
    Type: Application
    Filed: December 30, 2003
    Publication date: August 19, 2004
    Inventor: Keiichi Suzuki
  • Publication number: 20040157177
    Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Application
    Filed: December 23, 2003
    Publication date: August 12, 2004
    Inventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
  • Publication number: 20040152023
    Abstract: The present invention provides an image forming method using an image recording apparatus that includes a laser irradiating means for laser scanning of a photothermographic material that has a support and includes on at least one surface thereof a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and a conveying means for guiding the photothermographic material in a sub-scanning direction to a thermal development unit, wherein the reducing agent is a specific bisphenol compound. The invention also provides another image forming method including carrying out thermal development, with an interval time equal to or less than 12 seconds, of the photothermographic material.
    Type: Application
    Filed: February 2, 2004
    Publication date: August 5, 2004
    Inventors: Eiichi Okutsu, Katsutoshi Yamane, Yasuhiro Yoshioka
  • Publication number: 20040152026
    Abstract: The present invention provides a photosensitive silver halide photographic emulsion comprising a silver iodide content of 41 mol % or more and 100 mol % or less and including a silver halide to which reduction sensitization is applied in the course of particle formation, and silver halide photographic emulsion comprising 41 mol % to 100 mol % of silver iodide and subjected to at least one of chalcogen sensitization and gold sensitization to the insides of particles.
    Type: Application
    Filed: January 16, 2004
    Publication date: August 5, 2004
    Inventor: Hiroyuki Mifune
  • Patent number: 6770430
    Abstract: A therally processed image forming material less causative of adhesion during storage in a form of commercial product is provided. The thermally processed image forming material has on only one side of a support an image forming layer, in which the outermost layer on the same side with the image forming layer contains a binder different from that contained in the outermost layer on the opposite side of the support.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: August 3, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Kubo
  • Patent number: 6770428
    Abstract: Aqueous-based thermally developable emulsions and photothermographic imaging materials include photosensitive silver halide core-shell grains that comprise at least 20 mol % iodide based on total silver, an amount of iodide in the core of the grains that can be up to the iodide saturation limit in silver iodobromide, and an amount of iodide in the shell of the grains that is at least 2 mol % less than the amount of iodide present in the core, and further provided that the total amount of silver in the shell is from about 10 to about 80 mol % of total silver in the grains. These materials provide desired Dmax and reduced image “print out”.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: August 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Victor P. Scaccia, David A. Dickinson
  • Patent number: 6770406
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a residue of removing a hydrogen from wherein X, Y, and Z represent substituents selected independently from the groups hydrogen, alkyl group of 1 to 6 carbon atoms, cyclopropyl, aryl, arylalkyl, and heterocyclic groups, wherein at least one of X, Y, and Z is an aryl group and one of X, Y, Z, which may or may not be an aryl group, is attached in the direction of the backbone, and the other substituents are as defined in the specification. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: August 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Douglas R. Robello, David H. Levy
  • Publication number: 20040146819
    Abstract: A photothermographic material, including a support; an image forming layer provided on the support and containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder; and a silver-saving agent. Silver iodide is contained in the photosensitive silver halide in an amount of 40 to 100 mol %.
    Type: Application
    Filed: January 14, 2004
    Publication date: July 29, 2004
    Inventor: Kouta Fukui
  • Publication number: 20040142255
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: 1
    Type: Application
    Filed: January 9, 2004
    Publication date: July 22, 2004
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Publication number: 20040142287
    Abstract: A photothermographic material including, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder on at least one side of a support, wherein a content of silver iodide in the photosensitive silver halide is 5% by mole or more, the binder contains polymer latex in an amount of 60% by weight or more, and the reducing agent is a compound represented by the following general formula (R): 1
    Type: Application
    Filed: January 6, 2004
    Publication date: July 22, 2004
    Inventors: Hajime Nakagawa, Yoshihisa Tsukada
  • Patent number: 6764816
    Abstract: The present invention provides a thermally developable photosensitive material including a support, the image-forming layer containing a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following formula (I), wherein after the material is exposed and thermally developed at 121° C.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: July 20, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tomoyuki Ohzeki
  • Patent number: 6764813
    Abstract: A photothermographic film and a method for making same is taught. The film includes a support, a photothermographic imaging layer coated on the support, and a complement film generally confining the photothermographic imaging layer between the support and the complement film. The complement film is applied to the photothermographic imaging layer prior to exposure of the photothermographic imaging layer. The complement film retains any volatile materials present in the photothermographic imaging layer generated when thermal energy is applied thereto to develop a latent image exposed on the photothermographic imaging layer.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: July 20, 2004
    Assignee: Eastman Kodak Company
    Inventors: Aparna V. Bhave, Karissa L. Eckert, Kenneth W. Metz, Lawrence B. Wallace, Mridula Nair, Thomas M. Smith, Barry M. Brown
  • Publication number: 20040137382
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain triazine-thione compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.
    Type: Application
    Filed: December 11, 2003
    Publication date: July 15, 2004
    Inventors: Doreen C. Lynch, Stacy M. Ulrich, Paul G. Skoug
  • Publication number: 20040137389
    Abstract: The invention is a heat-developable light-sensitive material having, on a face of a support thereof, a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder. In first and second aspects, the silver iodide content of the silver halide is from 5 mol % to 100 mol %, and the material contains a compound (eg. silver iodide complex-forming agent) capable of substantially lowering through heat development a spectral absorption intensity derived from the silver halide in visible and ultraviolet regions. In the first aspect, the silver halide is photosensitive silver halide grains having a mean diameter of 0.001 to 0.08 &mgr;m. In its second aspect, the material is exposed to light shorter than 700 nm.
    Type: Application
    Filed: December 16, 2003
    Publication date: July 15, 2004
    Inventors: Kouta Fukui, Toyohisa Oya
  • Publication number: 20040137381
    Abstract: An image forming method for forming an image by exposing a photothermographic material to a laser beam, the laser beam being a laser diode beam having a peak light-emission intensity at a wavelength of 350 nm to 450 nm. The photothermographic material comprises at least a non-photosensitive silver salt, a photosensitive silver halide, a binder and a reducing agent, wherein a silver iodide content of the photosensitive silver halide is 40% by mole or more.
    Type: Application
    Filed: November 12, 2003
    Publication date: July 15, 2004
    Inventors: Fumito Nariyuki, Shinichi Shikii, Tetsuya Kojima
  • Patent number: 6762013
    Abstract: Nonpolymeric fluorochemicals defined as by the following Structure I are useful in thermally developable materials. The fluorochemicals are defined as follows: Rf—R—N(R1)(R2)(R3)+X−  (I) wherein Rf is a straight or branched chain perfluoroalkyl group having 4 to 18 carbon atoms, R is a divalent linking group comprising at least 4 carbon atoms and a sulfide group in the chain, R1, R2, R3 are independently hydrogen or alkyl groups or any two of R1, R2, and R3 taken together can represent the carbon and nitrogen atoms necessary to provide a 5- to 7-membered heterocyclic ring with the cationic nitrogen atom, and X− is a monovalent anion.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: July 13, 2004
    Assignee: Eastman Kodak Company
    Inventors: Kumars Sakizadeh, Gary E. LaBelle, Aparna V. Bhave
  • Patent number: 6762016
    Abstract: A photothermographic material is described, which comprises a support having provided on at least one side thereof a photosensitive silver halide, a photo-insensitive organic silver salt, a reducing agent for silver ion and a binder, wherein at least one layer constituting the photothermographic material comprises an oxazoline compound, by which sufficiently high image density is developed within practically feasible reaction time and temperature, and sufficiently suppressed background coloration is exhibited when stored for a prolonged period after development processing.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: July 13, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Itsuo Fujiwara, Yoshihisa Tsukada, Yasuhiro Yoshioka, Hajime Nakagawa
  • Publication number: 20040131983
    Abstract: The invention provides a photothermographic material including: a support and an image-forming layer including a non-photosenisitive silver salt, a photosensitive silver halide, a binder, and a reduction agent disposed on the support, wherein a silver iodide content in the photosensitive silver halide is in a range from 40 mol % to 100 mol %; and an average sphere-equivalent diameter of the photosensitive silver halide is in a range from 0.3 &mgr;m to 5.0 &mgr;m. The photothermographic material may further include a silver iodide complex forming agent as a compound which substantially reduces visible light absorption caused by the photosenisitive silver halide after thermal development. At least 50%, in terms of a projected area, of the photosensitive silver halide may be occupied by tabular silver halide grains having an aspect ratio of from 2 to 50 and being deposited with a silver salt in an epitaxial growth manner.
    Type: Application
    Filed: December 17, 2003
    Publication date: July 8, 2004
    Inventors: Tomoyuki Ohzeki, Eiichi Okutsu
  • Patent number: 6759187
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: July 6, 2004
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Publication number: 20040126717
    Abstract: A photothermographic material comprising, on a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and a non-photosensitive outermost layer at a surface side of the support at which the image forming layer is provided, wherein:
    Type: Application
    Filed: December 15, 2003
    Publication date: July 1, 2004
    Inventors: Hajime Nakagawa, Yoshihisa Tsukada, Keiichi Suzuki
  • Publication number: 20040126718
    Abstract: Antistatic compositions include a fluorochemical that is a reaction product of RfCH2CH2—SO3H with an amine wherein Rf comprises 4 or more fully fluorinated carbon atoms. These antistatic compositions can be formulated in organic solvent-based conductive coating compositions, with or without hydrophobic binders, that can be used to form conductive layers in thermally developable materials including thermographic and photothermographic materials.
    Type: Application
    Filed: December 15, 2003
    Publication date: July 1, 2004
    Inventors: Kumars Sakizadeh, Gary E. LaBelle, Michael W. Orem, Aparna V. Bhave