Gelatin Or Derivative Containing Patents (Class 430/640)
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Patent number: 5601971Abstract: An improved method of hardening a hydrophilic colloid is detailed. The hardening results in a stronger matrix and less water pickup. These and other advantages are obtained by hardening with a combination of at least one hardener chosen from Formula I either alone or in combination with at least one hardener chosen from Formula II: ##STR1## The substituents are defined.Type: GrantFiled: March 8, 1995Date of Patent: February 11, 1997Assignee: Sterling Diagnsotic Imaging, Inc.Inventors: Ludovic Fodor, Richard R. M. Jones, Reinhold R uger, Timothy D. Weatherill, Rolf T. Weberg
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Patent number: 5589322Abstract: A process for making a direct dispersion of a photographically useful material is disclosed comprising subjecting a mixture of an aqueous gelatin solution, a liquid organic phase comprising a photographically useful material, and an ionic polymer to conditions of high shear or turbulence to form a fine dispersion of the organic phase having an average particle size of less than 0.5 micron dispersed in the aqueous solution; wherein the ratio of the organic phase viscosity to the aqueous gelatin solution viscosity in the absence of the ionic polymer, measured at the temperature of the dispersion forming step, is greater than a value of 2.0, and the ionic polymer is a water soluble or dispersible substantially non-surface active polyelectrolyte which has a molecular weight of at least 10,000 selected from: i) synthetic polymers derived from at least 5 mole % of monomers which contain --OSO.sub.3 M, --SO.sub.3 M, --COOM, or ---OPO(OM).sub.Type: GrantFiled: December 12, 1995Date of Patent: December 31, 1996Assignee: Eastman Kodak CompanyInventors: Lloyd A. Lobo, Aileen M. Svereika
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Patent number: 5541048Abstract: This invention contemplates droplets of liquid lubricant, each droplet coated with colloidal particulate suspension stabilizing agent.The invention also contemplates a method of making size stable lubricant droplets by forming a discontinuous phase of lubricant droplets in a continuous aqueous phase containing a particulate suspension stabilizing agent, reducing the size of the lubricant droplets and limiting the coalescence of the lubricant droplets by action of the particulate suspension stabilizing agent.A third aspect of the invention is an imaging element comprising a support, at least one light-sensitive layer and a protective layer further removed from the support than the light-sensitive layer, at least one layer containing droplets of lubricant coated with colloidal particulate suspension stabilizing agent.Type: GrantFiled: May 12, 1995Date of Patent: July 30, 1996Assignee: Eastman Kodak CompanyInventors: Thomas H. Whitesides, Bonnie L. Howell, Ronda E. Factor
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Patent number: 5536630Abstract: The invention provides a method of nucleating silver halide particles wherein said nucleation is carried out in the presence of acid processed ossein (APO) gelatin or chain-extended acid processed ossein (CE-APO) gelatin and the composition formed therefrom.Type: GrantFiled: September 26, 1994Date of Patent: July 16, 1996Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Melvin D. Sterman, Jacob I. Cohen
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Patent number: 5529892Abstract: Light-sensitive silver halide photographic element comprising a support bearing at least a light-sensitive silver halide emulsion layer and at least a protective layer being further away from the support than every silver halide emulsion layer, said protective layer containing a gelatin having a viscosity lower than 20 milliPascal per seconds in 10 weight % aqueous solution at 40.degree. C., said gelatin being hardened with a carbamoyl pyridinium salt compound having the following formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group, an aryl group or an aralkyl group, or R.sub.1 and R.sub.2, together, constitute the atoms required to form a heterocyclic ring with the nitrogen atom to which they are bonded,R.sub.3 represents hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a carbamoyl group, or a ureido group, andR.sub.4 represents an alkylene group or a single chemical bond between the pyridinium nucleus and the --SO.sub.3 -- group.Type: GrantFiled: November 6, 1995Date of Patent: June 25, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sergio Massirio, Giovanni Giusto, Domenico Marinelli
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Patent number: 5514535Abstract: Hydrophilic colloids, such as gelatin, which are employed in the manufacture of photographic elements are commonly treated with a hardening composition, among the most useful of which are hardening compositions containing vinyl sulfone hardening agents such as bis(vinylsulfonyl)methane. In accordance with this invention, a sulfate, such as sodium sulfate, is utilized as both an effective conductivity marker and an effective inhibitor of homopolymerization in such hardening compositions.Type: GrantFiled: May 10, 1995Date of Patent: May 7, 1996Assignee: Eastman Kodak CompanyInventors: Lewis R. Hamilton, Peter A. Marr, Philip R. Martell, Kristine F. Ohman
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Patent number: 5508135Abstract: Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer comprising electrically-conductive metal-containing particles dispersed in a binder system comprising a blend of a film-forming polymer and an anionic polymer. The combination of electrically-conductive metal-containing particles, film-forming polymer and anionic polymer provides a controlled degree of electrical conductivity and excellent adhesion to gelatin-containing layers, such as silver halide emulsion layers of photographic elements, in adhering contact with the electrically-conductive layer.Type: GrantFiled: May 3, 1995Date of Patent: April 16, 1996Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Jehuda Greener
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Patent number: 5496691Abstract: A process for producing a silver halide photographic material comprising a polyester support having thereon at least one light-sensitive layer and at least one undercoat layer is described, wherein the undercoat layer is provided by coating a solution containing gelatin for an undercoating binder having a calcium ion (Ca.sup.++) content of from 10 to 2,500 ppm based on dry gelatin.Type: GrantFiled: February 6, 1995Date of Patent: March 5, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Hajime Miyamoto, Masahiko Murayama
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Patent number: 5482820Abstract: There is disclosed a light-sensitive silver halide photographic element comprising at least one hydrophilic colloid layer containing a dihalogenonitriloacylamino compound in combination with a phenolic biocide.Type: GrantFiled: February 3, 1995Date of Patent: January 9, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Luigi Cellone, Franco Leoncini
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Patent number: 5478710Abstract: New types of polymer latices and their use in photographic materials are disclosed. They are obtained by subjecting to radical emulsion polymerisation one or more radical-polymerisable monomers, whose emulsifier-free homopolymers or copolymers possess a glass transition temperature below 65.degree. C., preferably below 30.degree. C., in the presence of a water-soluble polymer of a particular chemical formula.These new types of latices are preferably used in graphic arts contact materials, e.g. daylight materials. They can be used in relative high amounts thus improving dimensional stability without deteriorating the scratch resistance too strongly.A preferred radical-polymerisable monomer mixture comprises n.-butyl acrylate, methyl methacrylate and acrylic acid.Type: GrantFiled: August 12, 1994Date of Patent: December 26, 1995Assignee: AGFA-Gevaert, N.V.Inventors: Michael Muller, Daniel M. Timmerman, Guido V. Desie, Stefaan F. Lingier, Gunter Stackmann
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Patent number: 5474889Abstract: A coating composition suitable for use in the preparation of a photographic material comprises an aqueous solution of a hydrophilic colloid and a surface active coating aid having the formulaCF.sub.3 (CF.sub.2).sub.n CH.sub.2 O(glycidyl).sub.m Hwhereinn is an integer from 4 to 7; and,m is an integer from 6 to 45.Type: GrantFiled: November 7, 1994Date of Patent: December 12, 1995Assignee: Eastman Kodak CompanyInventors: Alan R. Pitt, Bernard A. Clark, John F. Padday
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Patent number: 5470699Abstract: Gelatin hardeners, suitable for use in hardening gelatin-containing photographic layers, of the formula: ##STR1## wherein: X is a member selected from the group consisting of O and S or is absent,each Y independently is a member selected from the group consisting of O, S and a bond,each R.sup.1 independently represents an aliphatic group of up to 10 carbon atoms or the two R.sup.1 groups together represent the necessary atoms to complete a 5, 6 or 7-membered ring,--NR.sup.2 R.sup.3 contains not more than 12 skeletal atoms andR.sup.2 and R.sup.3 are independently members of the group consisting of hydrogen, cyclic groups and acyclic groups or R.sup.2 and R.sup.3 together represent the necessary atoms to complete a heterocyclic ring.Type: GrantFiled: July 8, 1994Date of Patent: November 28, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Anthony L. Beck, Julian M. Wallis, Martin D. Attwood, Stephen Newman
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Patent number: 5466567Abstract: Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer comprising a film-forming hydrophilic colloid having dispersed therein both electrically-conductive fine particles and pre-crosslinked gelatin particles. The combination of hydrophilic colloid, electrically-conductive fine particles and pre-crosslinked gelatin particles provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.Type: GrantFiled: October 28, 1994Date of Patent: November 14, 1995Assignee: Eastman Kodak CompanyInventors: Charles C. Anderson, Yongcai Wang, James L. Bello, Ibrahim M. Shalhoub, Douglas D. Corbin
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Patent number: 5457023Abstract: A water-soluble or water-dispersible, non-ionic surface active compound is provided having the formula ##STR1## wherein each Y independently is a hydrophilic polyhydroxyalkyl group;each X independently is ##STR2## each R independently is a hydrophobic substituted or unsubstituted alkyl group or a hydrophobic substituted or unsubstituted aryl group;each n independently is an integer from 2 to 6; and,each m is an integer from 2 to 4.Such surfactants can be used in hydrophilic colloid compositions in the manufacture of photographic materials.Type: GrantFiled: December 20, 1993Date of Patent: October 10, 1995Assignee: Eastman Kodak CompanyInventors: Catherine B. Briggs, Ian M. Newington, Alan R. Pitt
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Patent number: 5451497Abstract: The tendency of a photographically useful compound (PUC) to crystallize when dispersed in an aqueous medium is inhibited by codispersing with the PUC a non-color forming, oil-soluble, monomeric or oligomeric organic compound having a glass transition temperature between 0.degree. and 150.degree. C. Preferred organic compounds are oil-soluble sucrose esters, such as sucrose octaacetate, and rosin and derivatives thereof.Type: GrantFiled: December 30, 1993Date of Patent: September 19, 1995Assignee: Eastman Kodak CompanyInventors: David D. Miller, Krishnan Chari
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Patent number: 5445931Abstract: A silver halide photographic material comprising, on a support, at least one silver halide emulsion layer, which has at least one hydrophilic colloid layer (including the silver halide emulsion layer) containing a water-soluble polymer comprising a COOH-containing monomer or a salt thereof which is water-insoluble at a pH.ltoreq.6 and water-soluble at a pH.gtoreq.10. The photographic material is well processed by ultra-rapid processing system, displaying an excellent drying property.Type: GrantFiled: August 3, 1994Date of Patent: August 29, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Junichi Yamanouchi, Yutaka Tamura, Yasuyuki Takagi
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Patent number: 5391477Abstract: A photographic element comprising a modified gelatin whereby the modification results in carbamoyl groups by forming peptide bonds using fast-acting hardener. The derivatization involves initial reaction with a carboxyl activator followed by addition of a substituted amine thereby forming an amide linkage on the polypeptide chain. The resulting gelatin and photographic elements comprising such gelatin have a decreased propensity for water absorption without the loss of sensitometric properties.Type: GrantFiled: December 22, 1993Date of Patent: February 21, 1995Assignee: E. I. du Pont de Nemours and CompanyInventor: Timothy D. Weatherill
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Patent number: 5378598Abstract: The invention provides a method of nucleating silver halide particles wherein said nucleation is carried out in the presence of acid processed ossein (APO) gelatin or chain-extended acid processed ossein (CE-APO) gelatin and the composition formed therefrom.Type: GrantFiled: December 21, 1992Date of Patent: January 3, 1995Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Melvin D. Sterman, Jacob I. Cohen
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Patent number: 5370986Abstract: Polyhydroxyalkyl compounds and co-stabilizing agents are used to impart stabilizing or antifogging properties to photographic recording materials.Type: GrantFiled: November 3, 1992Date of Patent: December 6, 1994Assignee: Eastman Kodak CompanyInventors: Roger Lok, Arthur H. Herz
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Patent number: 5362626Abstract: Disclosed is a silver halide photographic light-sensitive material comprising a support and having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer contains a gelatin comprising an iron ion of 0.5 ppm to 5 ppm and .alpha.-constituent having weight-average molecular weight of 80,000 to 120,000 in an amount of not less than 40% by weight of the gelatin.Type: GrantFiled: September 29, 1993Date of Patent: November 8, 1994Assignee: Konica CorporationInventors: Takaaki Kojima, Mitsuhiro Okumura, Takahiko Nojima
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Patent number: 5352563Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide photographic emulsion layer and a protective layer in that order, wherein at least one layer of said emulsion layer and said protective layer contains a cyclodextrin compound and said emulsion layer contains a hydrazine derivative or a compound represented by the following formula (T): ##STR1##Type: GrantFiled: January 19, 1993Date of Patent: October 4, 1994Assignee: Konica CorporationInventors: Satomi Kawasaki, Shyouji Nishio, Hideki Komatsu
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Patent number: 5318889Abstract: This invention describes the advantages associated with the use of chain-extended acid processed ossein gelatin as the makeup gelatin, with emulsion precipitated in lime-processed ossein gelatin. Such photographic elements show a definite speed-fog advantage, compared to systems where standard lime-processed ossein gelatin is used solely.Type: GrantFiled: December 21, 1992Date of Patent: June 7, 1994Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Melvin Sterman, Jacob Cohen
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Patent number: 5316902Abstract: Hydrophilic organic colloids such as collagen or gelatin are modified for use in photographic elements such as film or paper, or for use as reagents in automated dry chemical analyzers. The modification comprises reaction of some of the carboxy groups attached to the polypeptide with (i) a amide bond forming agent, e.g. 1-pyrrolidinylcarbonylpyridinium chloride, and (ii) a di- or triamine, such as piperazine, diethylenetriamine or ethylenediamine. Such modification enables that colloid to react faster with a gelatin hardener such as bis(vinylsulfonyl)methane (BVSM). When coated over an equal amount of unmodified gelatin, and both layers imbibed with BVSM, a modified gelatin layer showed an enzyme resistance greater than that of the unmodified gelatin. This demonstrates that the modified gelatin hardened preferentially.Type: GrantFiled: January 4, 1993Date of Patent: May 31, 1994Assignee: Eastman Kodak CompanyInventors: Donald P. Specht, Kenneth G. Harbison
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Patent number: 5275793Abstract: The present invention describes a method and apparatus in which solid gelatin chunks are liquefied, tempered, and debubbled in a single operation. The debubbling step is accomplished by evacuating and sealing off the loaded solid reservoir and heat exchanger before initiating the liquefying step. After the vacuum is applied, the gelled chunks are pressed into the heat exchanger, where heat is applied to the gelled chunks of photographic material. This liquefies the gelled chunks of photographic material. When the liquefied product gives a positive pressure at the heat exchanger outlet, the liquefied product is allowed to flow from the heat exchanger. Liquefying and tempering are performed as the solid chunks are pushed through the heat exchanger by the reservoir piston.Type: GrantFiled: August 28, 1992Date of Patent: January 4, 1994Assignee: Eastman Kodak CompanyInventors: Walter Johannes, Daniel J. Wooster
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Patent number: 5272053Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support and a silver halide emulsion layer provided on the support, and the silver halide emulsion layer comprises a hydrogen peroxide-treated gelatin in a ratio of not lower than 20% by weight to the total amount of gelatin contained in the silver halide emulsion layer and silver halide grains composed of silver chlorobromide having a silver chloride content of not lower than 90 mol %. The light-sensitive material is improved in the stability of emulsion coating solutions.Type: GrantFiled: December 15, 1992Date of Patent: December 21, 1993Assignee: Konica CorporationInventors: Mitsuhiro Okumura, Shigeo Tanaka, Hirokazu Sato
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Patent number: 5238795Abstract: A light-sensitive silver halide photographic material is disclosed. The light-sensitive material comprises a support and two photographic layers each being provided on both sides, side A and side B, of the support and comprising a silver halide emulsion layer and a hydrophilic colloid layer wherein the light-sensitive material satisfies the relationship between sensitivities sA, sB and sA' thereof represented by the following expressions I and II, and an organic substance remained in the photographic layers after processing is an amount of not more than 90% by weight of the organic substance contained in the photographic layers before processing of the light-sensitive material;I: sA/sA'>4.0II: sA/sB=1.Type: GrantFiled: July 26, 1991Date of Patent: August 24, 1993Assignee: Konica CorporationInventor: Iku Metoki
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Patent number: 5229246Abstract: A diffusion transfer photographic material is disclosed, which comprises a support having thereon at least a photosensitive element comprising a photosensitive silver halide emulsion and a diffusible dye donating compound, and a dye fixing element which is placed upon the said photosensitive element at the time of image transfer, wherein a natural macromolecular polysaccharide originating from red algae is included in said photosensitive element and/or in said dye fixing element, and a process of producing a diffusion transfer photographic material is disclosed, which comprises the step of using a coating liquid which contains a water soluble polymer solution comprising a natural macromolecular polysaccharide, a hydrophilic organic solvent in which the said water soluble polymer is essentially insoluble and water.Type: GrantFiled: February 19, 1991Date of Patent: July 20, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Shibata, Takuya Yokokawa
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Patent number: 5198333Abstract: A new class of electron-accepting compounds for photographic emulsions is disclosed represented by following general formula (I): ##STR1## wherein: each of Z and Q which may be the same or different represents the atoms necessary to complete an unsubstituted or substituted nitrogen-containing heterocyclic ring;each of T.sub.1 and T.sub.2 which may be the same or different represents alkyl, cycloalkyl, alkoxy, aryl, aryloxy, halogen, cyano, hydroxy, carboxyl, sulfo, carbamoyl, acyl, acylamino, sulfamoyl, sulfonamido or a benzocondensed ring, each of which can be further substituted or not;q=1, 2 or 3, and p and r=0, 1 or 2.In this formula the nitro containing heterocyclic nucleus is preferably nitropyridine or nitrothiazole.In a preferred embodiment of the invention electron-accepting compounds are incorporated in negative or direct positive roomlight emulsions. In the latter case the emulsion layer preferably contains in addition a nitroindazole or nitrobenzimidazole derivative.Type: GrantFiled: March 13, 1991Date of Patent: March 30, 1993Assignee: Agfa-Gevaert, N.V.Inventors: Jean-Marie O. Dewanckele, Paul R. Callant, Marc H. Van Bockstaele, Marc B. Graindourze
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Patent number: 5187259Abstract: A soluble, chain extended gelatin having a high molecular weight and significantly higher viscosity at equivalent gelatin concentration compared to standard gelatin and significantly faster setting time is produced by preparing an aqueous gelatin composition containing from about 6% to about 18% dry weight of gelatin and from about 0.25 to about 5 millimoles of a bis-(vinyl sulfonyl) compound per 100 grams of gelatin, heating the composition at a temperature of from about 40 to about 60.degree.C. and at a pH of from about 4.5 to about 7 for from about one to about eight hours.Type: GrantFiled: November 14, 1990Date of Patent: February 16, 1993Assignee: Eastman Kodak CompanyInventors: Melvin D. Sterman, James L. Bello
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Patent number: 5185230Abstract: The invention creates a selective oxygen barrier around individual coupler or other photographically active particles by surrounding each particle with a layer of water applicable oxygen barrier polymer such as polyvinyl alcohol (PVA), which will also act as a steric barrier to coalescence of the particles. Photographic products formed with such materials are more dye stable.Type: GrantFiled: September 3, 1991Date of Patent: February 9, 1993Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James L. Edwards, Wendell F. Smith, Jr., Brian Thomas
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Patent number: 5135844Abstract: The invention is generally accomplished by utilization of a surfactant for very small particle photographic dispersions. Three types of such surfactants that have been identified are as follows:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycedyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A--B--A, B--A--B, A--B, (A--B).sub.n .tbd.G.tbd.(B--A), or (B--A).sub.n .tbd.G.tbd.(A--B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.Type: GrantFiled: February 12, 1991Date of Patent: August 4, 1992Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Gary J. McSweeney, Steven J. Sargeant
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Patent number: 5019494Abstract: A silver halide photographic material which comprises a support having thereon at least one hydrophilic colloid layer, wherein the hydrophilic colloid layer comprises (a) a binder comprising a dextran having a molecular weight of at least 100,000 and (b) an ionic polymer.Type: GrantFiled: February 27, 1989Date of Patent: May 28, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Ichizo Toya, Ryoichi Nemori
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Patent number: 5013640Abstract: The invention is generally accomplished by utilization of a surfactant for very small particle photographic dispersions. Three types of such surfactants that have been identified are as follows:Type A--Surfactant comprising 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic chains comprising at least 8 oxyethylene and/or glycedyl ether groups that may or may not be terminated with a negative charge such as a sulfate group.Type B--Block oligomeric surfactants comprising hydrophobic polyoxypropylene blocks (A) and hydrophilic polyoxyethylene blocks (B) joined in the manner of A-B-A, B-A-B, A-B, (A-B).sub.n .tbd.G.tbd.(B-A), or (B-A).sub.n .tbd.G.tbd.(A-B).sub.n, where G is a connective organic moiety and n is between 1 and 3.Type C--Sugar surfactants, comprising between one to three 6 to 22 carbon atom hydrophobic tail with one or more attached hydrophilic mono or oligosaccharidic chains that may or may not be terminated by a negatively charged group such as a sulfate group.Type: GrantFiled: June 15, 1989Date of Patent: May 7, 1991Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Gary J. McSweeney, Steven J. Sargeant
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Patent number: 4999282Abstract: An improved silver halide photographic material having at least one layer of a light-sensitive silver halide emulsion that is spectrally sensitized with a sensitizing dye of the following general formula (1) to light having a wavelength of 750 nm and above. Said silver halide emulsion is prepared by a process which comprises generating silver halide grains by adding a solution of a water-soluble silver salt and a solution of a water-soluble halide to a solution containing a protective colloid, aggregating the generated silver halide grains with a polymeric flocculating together with the protective colloid, and removing the dissolved matter; ##STR1## where Z.sub.1 and Z.sub.3 each represents the non-metallic atomic group necessary to form an optionally substituted benzothiazole, benzoxazole, naphthothiazole or naphthoxazole nucleus; R.sub.1 and R.sub.2 each represents a saturated or unsaturated aliphatic group; Z.sub.2 represents a 5- or 6-membered ring of carbon atoms; A represents a hydrogen atom when Z.sub.Type: GrantFiled: May 17, 1989Date of Patent: March 12, 1991Assignee: Konica CorporationInventors: Kiyoshi Sato, Kouji Ono
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Patent number: 4992362Abstract: The production of a photosensitive silver halide emulsion by precipitation of the silver halide in the presence of gelatine, flocculation and washing of the silver halide precipitated in the presence of the gelatine and redispersion with addition of more gelatine, precipitation being carried out in the presence of a gelatine having a gold number of at most 10 .mu.mol/g gelatine and a cysteine content of at most 6 ppm and redispersion being carried out with a gelatine having a gold number of at least 23 .mu.mol/g gelatine, leads to an emulsion of uniform grain distribution in which undesirably high fogging is avoided.Type: GrantFiled: August 4, 1989Date of Patent: February 12, 1991Assignee: AGFA Gevaert AktiengesellschaftInventors: Franz Moll, Bruno Mucke, Klaus Wagner, Herbert Gareis, Wolfgang Graesser, Peter Koepff
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Patent number: 4990440Abstract: The sensitivity/fog ratio can be improved by using photographic silver halide emulsions containing gelatine which has a cysteine content of less than 10 ppm and a gold number of .gtoreq.23 .mu.mol/g.Type: GrantFiled: August 4, 1989Date of Patent: February 5, 1991Assignee: Agfa-Gevaert AktiengessellschaftInventors: Franz Moll, Bruno Mucke, Walter Patzold, Klaus Wagner
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Patent number: 4946769Abstract: A silver halide photographic light-sensitive material, and a method of preparing the same and a method of image forming using the same photographic material. The photographic material comprises a support bearing, on one side thereof, a layer containing a light-sensitive silver halide emulsion comprised of silver halide grains having an average size of from 0.05 .mu.m to 0.3 .mu.m and gelatin and, on the other side thereof, a non-light-sensitive layer containing gelatin and at least one of the emulsion layer and the non-light-sensitive layer is brought into contact with air having a temperature of from 35.degree. C. to 80.degree. C. or relative humidity of from 5% to 25% for a period not shorter than 5 seconds to not longer than one minute, within 5 minutes from the point of time when the average surface temperature of said layer is raised up to a temperature 1.degree. C.Type: GrantFiled: November 15, 1988Date of Patent: August 7, 1990Assignee: Konica CorporationInventors: Takeo Arai, Toshiharu Nagashima
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Patent number: 4923790Abstract: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the material contains the combination of (i) at least one compound represented by formula (I) and (ii) and at least one compound represented by formulae (II) and/or (III): ##STR1## wherein R.sub.1 represents hydrogen, an alkyl group, an aryl group or an aralkyl group; X represents a halogen atom, a nitro group, a hydroxyl group, a cyano group, a lower alkyl group, a lower alkoxy group, --COR.sub.2, ##STR2## or --SO.sub.3 M; R.sub.2 represents hydrogen, --OM, a lower alkyl group, an aryl group, an aralkyl group, a lower alkoxy group, an aryloxy group, an aralkyloxy group or ##STR3## R.sub.3 and R.sub.4 each represents hydrogen, a lower alkyl group, an aryl group, an aralkyl group, --COR.sub.7 or --SO.sub.2 R.sub.7 ; R.sub.5 and R.sub.6 each represents hydrogen, a lower alkyl group, an aryl group or an aralkyl group; R.sub.Type: GrantFiled: September 22, 1988Date of Patent: May 8, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirohiko Kato, Keiji Mihayashi, Kazuhiro Aikawa
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Patent number: 4916049Abstract: A silver halide photographic material is disclosed, comprising a support having at least two hydrophilic colloid layers on one side of a support, at least one of said hydrophilic colloid layers containing dextran having an average molecular weight of at least 100,000, wherein at least one hydrophilic colloid layer containing substantially no dextran and having a dry thickness of at least 1.0 .mu.m exists between the hydrophilic colloid layer containing the dextran disposing nearest to the support and the support.Type: GrantFiled: December 12, 1988Date of Patent: April 10, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Ichizo Toya
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Patent number: 4898810Abstract: This invention relates to layers for photographic materials, which comprises a polysaccharide which is formed extracellularly by bacterial fermentation of glucose, maltose, sucrose or xylose, if appropriate in the presence of yeast, yeast hydrolysate or casein-hydrolysate, and with mono-, di- and/or tri-valent metal ions, forms gels having a solidification temperature between 24.degree. and 25.degree. C. Gellan gum has proved to be a particularly advantageous polysaccharide for use in the layers according to the invention.Type: GrantFiled: May 1, 1988Date of Patent: February 6, 1990Assignee: Ciba-Geigy AGInventors: Ute Eggert, Andreas Engel, Ekkehard Kramp
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Patent number: 4879209Abstract: The present invention provides a method of hardening a proteinaceous layer of a photographic silver halide element by incorporating a modified dextran in said proteinaceous layer, said modified dextran being the reaction product of dextran and an alkyl haloformate, a substituted alkyl haloformate, an aryl haloformate, or a substituted aryl haloformate. The invention also provides a photographic element comprising a said reaction product in at least one proteinaceous silver halide emulsion layer and/or in another proteinaceous layer coated thereon.Type: GrantFiled: December 15, 1987Date of Patent: November 7, 1989Assignee: AGFA-GEVAERT, N.V.Inventors: Joan T. Vermeersch, Daniel Timmerman, Hubert Vandenabeele, Jacques L. Vervecken
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Patent number: 4824774Abstract: A silver halide negative photographic material is described, comprising a support, at least one silver halide emulsion layer, and one or more light-insensitive hydrophilic colloid layers, wherein said silver halide emulsion layer or said light-insensitive hydrophilic colloid layer contains a hydrazine derivative, and the photographic material has a film surface pH not higher than 5.8 on the side of said emulsion layer inclusive of said light-insensitive hydrophilic colloid layer; in another aspect, this invention is directed to a method for forming an ultrahigh contrast negative image, comprising exposing said photographic material imagewise, followed by development processing of the same with a developer containing at least 0.15 mol/liter of sulfite ion and having a pH of from 10.5 to 12.3.Type: GrantFiled: September 14, 1987Date of Patent: April 25, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Senzo Sasaoka
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Patent number: 4714671Abstract: Polymer latices in which the dispersed particles consist of a soft core and a hard shell are suitable plasticizers for gelatine in photographic recording materials.Type: GrantFiled: April 25, 1986Date of Patent: December 22, 1987Assignee: Agfa Gevaert AktiengesellschaftInventors: Gunter Helling, Wolfgang Himmelmann
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Patent number: 4513080Abstract: A photographic recording material consisting of a layer support, at least one light-sensitive silver halide emulsion layer containing gelatine and optionally other gelatine-containing layers which are not light-sensitive contains in at least one of the layers a cross-linked polymer latex on the basis of a low molecular weight carboxylic acid amide. The latex may advantageously be used as a binding agent or for introducing residues of photographically active substances into a photographic layer.Type: GrantFiled: September 10, 1984Date of Patent: April 23, 1985Assignee: Agfa-Gevaert AGInventor: Gunter Helling
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Patent number: 4444926Abstract: A method of hardening gelatin is described which uses (1) a polymer containing at least 0.01 mol % of a repeating unit represented by formula (I) ##STR1## wherein R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or a halogen atom, M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or an organic base, X represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, an alkylamino group having from 1 to 6 carbon atoms, or a halogen atom, m represents 0, 1 or 2, and n represents 1 or 2, (2) a polyvalent alcohol having at least two hydroxy groups, and (3) a hardener having an active vinyl group.The method has advantages in that the rate of hardening the gelatin is fast, the so-called post hardening property is small, and the gelatin composition is hardely influenced by the conditions of temperature and humidity during storage.Type: GrantFiled: November 10, 1981Date of Patent: April 24, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Masasi Ogawa, Kunio Ishigaki, Kiyotaka Hori
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Patent number: 4433043Abstract: A water based photosensitive composition comprises a hydrolyzate of a mammal collagen and a photosensitizer serving to cross-link the hydrolyzate when exposed to an active light. The hydrolyzate has a number-average molecular weight, Mn, of 2,000 to 30,000 and an intrinsic viscosity, [.eta.], of 0.060 to 0.155 dl/g in a 0.15 mole citric acid buffer solution maintained at 40.degree.C. Also, the hydrolyzate is capable of maintaining the formability of the collagen fold. A photoresist pattern formed by using the composition exhibits a high resolution, a good dyeing property and a strong corrosion resistance.Type: GrantFiled: November 13, 1981Date of Patent: February 21, 1984Assignees: Toppan Printing Co., Ltd., Nippi, Inc.Inventors: Yoshikatu Sawada, Kazuo Shirakawa, Takeo Sugiura
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Patent number: 4315072Abstract: Artificial gelatins containing higher proportions of methionine than are found in natural gelatin are made by thermal polymerization of methionine with various proportions of other .alpha.-amino acids, including some proportion of aspartic acid, glutamic acid or lysine. Artificial gelatins containing as much as 40 mole percent methionine can be obtained. Proportions in the polymer can be adjusted by control of proportions in the reaction mixture. Photographic silver halide emulsions containing these artificial gelatins and photographic films employing the emulsions are also disclosed.Type: GrantFiled: March 11, 1980Date of Patent: February 9, 1982Assignee: PolymicroInventors: Sidney W. Fox, Arthur I. Holden
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Patent number: 4275145Abstract: A method for dispersing an oil-soluble photographic additive into a hydrophilic colloid composition is disclosed wherein a solution of an oil-soluble photographic additive in an organic solvent or the melted oil-soluble photographic additive is dispersed in a hydrophilic colloid containing an anionic surface active agent and lecithin together with a gelatin derivative.Type: GrantFiled: December 11, 1979Date of Patent: June 23, 1981Assignee: Fuji Photo Film Co., Ltd.Inventor: Takeshi Mikami
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Patent number: 4267212Abstract: A process for spin coating a substrate such as a semi-conductor wafer uniformly with a coating solution such as a photographic emulsion by rotating the substrate at a first speed while simultaneously applying the coating solution at a radially moving position. Once the substrate has been initially covered, the speed of rotation of the substrate is increased and rotation continues until a uniform coating is obtained.Type: GrantFiled: September 19, 1979Date of Patent: May 12, 1981Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinichi Sakawaki
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Patent number: 4224403Abstract: A method for preventing the degradation of a hydrophilic colloid solution for a silver halide photographic light-sensitive material of which the viscosity has been or is to be increased using an anionic polymer containing an acid group, which comprises incorporating into the hydrophilic colloid solution at least one compound represented by the formula (I): ##STR1## wherein R.sub. represents a hydrogen atom or an alkyl group; and R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group.Type: GrantFiled: August 3, 1978Date of Patent: September 23, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuzo Toda, Keiichi Adachi, Shoji Ishiguro, Yasuhiro Nakayama