Thermal Imaging Composition Patents (Class 430/964)
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Patent number: 4837134Abstract: A data card for optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular oblong silver particles within the top 0.5 micron of the gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The strip is laminated into a wallet-size card and may be pre-patterned during formation of the crust with control indicia or pre-recorded data. User data may be recorded by modifying the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface metallic layer underlying the gelatin layer which can be observed in the recorded spots.Type: GrantFiled: April 16, 1987Date of Patent: June 6, 1989Assignee: Drexler Technology CorporationInventors: Eric W. Bouldin, Jerome Drexler
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Patent number: 4818666Abstract: Erasable optical recording element according to FIG. 1 having a substrate 1 and a recording layer 4 which is provided thereon and which satisfies the formula (QSb).sub.100-x M.sub.x, wherein Q is the element Ga or In, M is a metal or chalcogenide element and x has the value 2-15, as well as a method of optically recording and erasing information in which under the influence of pulsated laser light amorphous info areas 10 are formed in the recording layer 4, which areas can be reverted by laser light to the crystalline phase and can be erased.Type: GrantFiled: June 2, 1986Date of Patent: April 4, 1989Assignee: U.S. Philips CorporationInventors: Dirk J. Gravesteijn, Carlus J. Van Der Poel
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Patent number: 4816385Abstract: According to the method a rotating recording element 23 (FIG. 3) having a crystalline recording layer 28 of the composition Q.sub.x Sb.sub.y Te.sub.z, wherein Q=In, Ga; X=34-44 at. %; y=51-62 at. %; Z=2-9 at. %; is exposed to a pulsated laser light spot 29 (FIG. ) in which amorphous information bits are formed which are read by means of weak laser light 30 and which can be erased in real time during one revolution of the element 23 by means of a laser light erasing spot 33 (FIG. 4) and be returned to the crystalline state.Type: GrantFiled: May 4, 1987Date of Patent: March 28, 1989Assignee: U.S. Philips CorporationInventors: Dirk J. Gravesteijn, Carolus J. Van Der Poel
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Patent number: 4816386Abstract: A novel near-infrared sensitive phthalocyanine-polymer composition comprises a substituted aluminum phthalocyanine and a polymer wherein substituted aluminum phthalocyanine dimers and/or dimer aggregates which are responsible to the near-infrared sensitivity, are included.The near-infrared sensitive phthalocyanine-polymer composition has useful characteristics:(A) when the near-infrared sensitive phthalocynaine-polymer composition is heated above the T.sub.g (Glass Transition Temperature) of the polymer either by direct heating and by absorbing irradiated light energy, optical properties of said near-infrared sensitive phthalocyanine-polymer composition; absorbance and/or reflectivity, are capable of being changed,(B) the thermal change of optical properties of the near-infrared sensitive phthalocyanine-polymer composition can be fixed by further heating above the T.sub.f (Thermal Fixation Temperature) higher than the T.sub.Type: GrantFiled: January 5, 1987Date of Patent: March 28, 1989Assignee: Toray Industries, Inc.Inventors: Tetsuya Gotoh, Tosiyuki Kondoh, Mutsuo Aoyagi
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Patent number: 4816374Abstract: An opacifier substance is added to a plastic material which is naturally transparent to laser radiation. The opacifier substance is added in powder form as a concentration of 2% to 6% by weight of the plastic material. The opacifier substance is preferably antimony oxide and the resulting plastic material is capable of being permanently marked by a laser beam and is suitable for providing animal ear tags. These tags may be marked with an automatically readable bar code and this code continues to be automatically readable over a period of several years use on the animal.Type: GrantFiled: April 9, 1986Date of Patent: March 28, 1989Assignee: Societe d'Applications Plastiques Rhone-Alpes (SAPRA)Inventor: Gilbert Lecomte
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Patent number: 4812385Abstract: Optical recording and record elements are provided. The elements comprise a write-once amorphous thin-film optical recording layer of an alloy having a composition within a polygon in a ternary composition diagram of antimony, zinc, and tin; wherein(a) the composition diagram is according to FIG.Type: GrantFiled: May 23, 1988Date of Patent: March 14, 1989Assignee: Eastman Kodak CompanyInventors: Kee-Chuan Pan, Yuan-Sheng Tyan, Donald R. Preuss
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Patent number: 4812386Abstract: Recording and record elements are disclosed. The elements have thin film optical recording layers of a SbSnGe alloy. The alloy has a composition within a polygon ABCDEF in a ternary SbSnGe composition diagram as shown in FIG. 5 herein.Type: GrantFiled: May 23, 1988Date of Patent: March 14, 1989Assignee: Eastman Kodak CompanyInventors: Kee-Chuan Pan, Yuan-Sheng Tyan, Salvatore J. Marino
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Patent number: 4808514Abstract: A method is provided for the optical recording of information in which an amorphous recording layer 4 having a composition according to formula (1) provided on a synthetic resin substrate (2) (FIG. 1) in a maximum layer thickness of 150 nm is exposed of infrared laser light having a wavelength of 750-900 nm and pulsed in accordance with the binary information to be recorded with a pulse time of at most 200 ns. A crystalline area 6 (bit) having maximum dimensions of a few micrometers is formed in the amorphous layer in the exposed places. As optical recording element is also provided for use in the method.Type: GrantFiled: December 17, 1986Date of Patent: February 28, 1989Assignee: U.S. Philips CorporationInventors: Dirk J. Gravesteijn, Carolus J. van der Poel
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Patent number: 4798785Abstract: Optical recording and record elements are provided. The elements comprise a write-once amorphous thin-film optical recording layer of an alloy having a composition within a polygon in a ternary composition diagram of antimony, aluminum, and tin; wherein(a) the composition diagram is according to FIG.Type: GrantFiled: June 5, 1987Date of Patent: January 17, 1989Assignee: Eastman Kodak CompanyInventors: Kee-Chuan Pan, Yuan-Sheng Tyan, Fridrich Vazan
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Patent number: 4795695Abstract: Recording and record elements are disclosed. The elements have thin film optical recording layers of a SbSnGe alloy. The alloy has a composition within a polygon ABCDEF in a ternary SbSnGe composition diagram as shown in FIG. 5 herein.Type: GrantFiled: February 13, 1987Date of Patent: January 3, 1989Assignee: Eastman Kodak CompanyInventors: Kee-Chuan Pan, Yuan-Sheng Tyan, Salvatore J. Marino
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Patent number: 4795697Abstract: Alkyl ketazine dyes are stabilized by the presence of poly(vinyl chloride) and/or poly(vinylidene chloride) binders in photothermographic emulsions.Type: GrantFiled: December 29, 1986Date of Patent: January 3, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kim M. Vogel, David C. Weigel, Roger A. Mader
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Patent number: 4794069Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.Type: GrantFiled: July 14, 1987Date of Patent: December 27, 1988Assignee: Shin Nisso Kako Co., Ltd.Inventors: Yutaka Ohnishi, Shinji Yoshinaka, Toshiyuki Tanaka, Minoru Koguchi, Takeo Obitsu
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Patent number: 4792514Abstract: A light-sensitive material is described, comprising a support having provided thereon a light-sensitive layer containing at least a light-sensitive silver halide, a polymerizable compound, a color image forming substance, and a hydrazine derivative represented by formula (I): ##STR1## wherein R.sub.1 represents a monovalent group derived from a substituted or unsubstituted aromatic ring or aromatic heterocyclic ring; R.sub.2 and R.sub.3 each represents a substituted or unsubstituted aryl group; and R.sub.4 represents a hydrogen atom or a substituted or unsubstituted alkyl, aryl, alkoxycarbonyl, or carbamoyl group,in which the color image forming substance is immobilized by imagewise exposure to light followed by heat development under conditions substantially not containing water. The material exhibits high sensitivity and provides a color image through a simple, easy, and rapid dry processing step, with a reduced exposure time.Type: GrantFiled: October 10, 1986Date of Patent: December 20, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Taku Nakamura, Kozo Sato
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Patent number: 4782010Abstract: The use of phenazine, phenoxazine and phenothiazine color forming developers in photothermographic dry silver emulsions provides a stable imaging system under both light and dark storage.Type: GrantFiled: December 29, 1986Date of Patent: November 1, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger A. Mader, David C. Weigel, Louis M. Leichter, Kristen A. Hoff
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Patent number: 4774170Abstract: Optical recording and record elements are provided. The elements comprise a write-once amorphous thin-film optical recording layer of an alloy having a composition within a polygon in a ternary composition diagram of antimony, zinc, and tin; wherein(a) the composition diagram is according to FIG.Type: GrantFiled: June 5, 1987Date of Patent: September 27, 1988Assignee: Eastman Kodak CompanyInventors: Kee-Chuan Pan, Yuan-Sheng Tyan, Donald R. Preuss
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Patent number: 4770981Abstract: There is provided a multi-layer heat-developement-type color light-sensitive material comprising a support having thereon a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a yellow dye donator substance and a binder, e.g. gelatin, a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a magenta dye donator substance and a binder, and a layer containing light-sensitive silver halide grains, an organic silver salt, a reducing agent, a cyan dye donator substance and a binder, the binder of the respective layers amounting in total to from 3 g to 10 g per m.sup.2 of said support; preferably at least one layer of the light-sensitive material contains a heat solvent.Type: GrantFiled: June 17, 1987Date of Patent: September 13, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Tawara Komamura, Masaru Iwagaki, Toyoaki Masukawa
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Patent number: 4769311Abstract: In a data recording member having a data recording film which is formed on a substrate either directly or via at least one of inorganic and organic protective layers and which causes the change of atomic arrangement upon being irradiated by recording beam, the improvement wherein said data recording film has an average composition in a direction of the film thickness expressed by the following formulas:M.sub.x Te.sub.y Se.sub.z O.sub..alpha.wherein x, y, z and .alpha. are values within the ranges of 2.ltoreq.x.ltoreq.40, 30.ltoreq.y.ltoreq.95, 3.ltoreq.z.ltoreq.45, 0.ltoreq..alpha..ltoreq.20, and M is at least one element selected from the group consisting of As, Sb, Bi, S, Si, Ge, Sn, Pb, Al, Ga, In, Tl, Zn, Cd, Au, Ag, Cu, Ni, Pd, Rh, Cr, Mo, W and Ta.Type: GrantFiled: July 10, 1986Date of Patent: September 6, 1988Assignee: Hitachi, Ltd.Inventors: Motoyasu Terao, Yasushi Miyauchi, Kazuo Shigematsu, Shinkichi Horigome
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Patent number: 4769310Abstract: A method of laser marking ceramic materials, glazes, glass ceramics and glasses that contain at least one radiation-sensitive additive, utilizing a laser beam as radiation energy source which is either applied to, or focused on, the surface of the material to be marked in accordance with the form of the graphic symbols to be reproduced, such that a change in color is induced at the irradiated areas, wherein the wavelength of said laser beam used as energy source is in the near UV and/or visible range and/or infra-red range, and the radiation-sensitive additive is an inorganic pigment.Type: GrantFiled: January 30, 1987Date of Patent: September 6, 1988Assignee: Ciba-Geigy CorporationInventors: Heinrich Gugger, Fritz Herren, Manfred Hofmann, Andre Pugin
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Patent number: 4764458Abstract: A heat developable light-sensitive material is disclosed. The material comprises a support having provided thereon at least a light-sensitive silver halide, a reducing agent, a binder and an organic silver salt of the formula: ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group; R.sub.2 represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3 represents a halogen atom, a substituted or unsubstituted alkyl, alkoxy, amino, alkylsulfonyl, arylsulfonyl, carbamoyl, sulfamoyl or alkoxycarbonyl group or a cyano group; X represents ##STR2## wherein R.sub.4 represents a hydrogen atom or a substituted or unsubstituted alkyl group, --SO.sub.2 --, ##STR3## wherein R.sub.5 represents a substituted or unsubstituted alkyl group, and ##STR4## and l represents 0 or an integer of from 1 to 3; and when l is 2 or 3, the groups R.sub.3 may be the same or different.Type: GrantFiled: April 4, 1986Date of Patent: August 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Hiroshi Hara, Ken Kawata
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Patent number: 4762770Abstract: An optical memory disk for laser recorded optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular oblong silver particles within the top 0.5 micron of a gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The disk may be pre-patterned during formation of the crust with control indicia, such as servo track guides or timing marks. User data may be recorded by modification of the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface and the reflective metallic layer underlying the gelatin layer which can be observed in the recorded spots.Type: GrantFiled: April 16, 1987Date of Patent: August 9, 1988Assignee: Drexler Technology CorporationInventors: Eric W. Bouldin, Jerome Drexler
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Patent number: 4758499Abstract: This invention relates to an optical information recording medium, characterized by having an organic thin film recording layer containing at least one of triaryl methane type coloring matters expressed by the general formula (1), (2) or (3): ##STR1## (wherein, in the above formulas (1) and (2), Ar.sub.1, Ar.sub.2 and Ar.sub.3 may be the same or different and represent a substituted or non-substituted arylene group, at least one pair of optical two nitrogen atoms bonded with said arylene groups being connected by an atomic chain having at least ten carbon atoms in total number in the shortest way; R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.Type: GrantFiled: September 5, 1986Date of Patent: July 19, 1988Assignee: Ricoh Co., Ltd.Inventors: Michiharu Abe, Tsutomu Sato, Hideaki Oba, Masaakira Umehara, Yutaka Ueda, Tetsu Yamamuro
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Patent number: 4755831Abstract: A multi- and full-color thermosensitive recording method of recording multi- or full-color images on a multi-color thermosensitive recording sheet capable of forming 2 to 4 different colors by use of a thermal head is disclosed, with the improvement that the picture elements of a thermal head are grouped so as to be operative in the form of a matrix consisting of n picture elements in the main scanning direction and m picture elements in the sub-scanning direction, each matrix is assigned to 2 to 4 alternatively independent colorings and thermal recording is performed in such a manner that, of the n.times.m picture elements in each matrix, the number of the picture elements for each color formation is changed, whereby multi- and full-color recording with a multi-step pseudo density gradation is attained.Type: GrantFiled: June 30, 1986Date of Patent: July 5, 1988Assignee: Ricoh Company, Ltd.Inventor: Hiroshi Sakamoto
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Patent number: 4753864Abstract: A medium in tape form for laser recorded optical information featuring a gelatin layer having a thin black crust at the top of the layer. The crust is formed by developed black irregular silver particles within the top 0.5 micron of a gelatin colloid matrix. The remainder of the colloid matrix is substantially clear gelatin and a reflective metallic layer is disposed below the gelatin. The tape may be disposed on reels and may be pre-patterned during formation of the crust with indicia, such as servo track guides or timing marks. User data may be recorded by modification of the black silver particles in the crust with a laser to expose the reflective underlayer. A laser or other light source is used to read data on the medium with optical contrast between the black surface and the reflective metallic layer underlying the gelatin layer which can be observed in the recorded spots.Type: GrantFiled: April 16, 1987Date of Patent: June 28, 1988Assignee: Drexler Technology CorporationInventors: Eric W. Bouldin, Jerome Drexler
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Patent number: 4745046Abstract: A thermal imaging method is provided which employs as color-forming co-reactants, (a) a substantially colorless di- or triarylmethane compound possessing on the meso carbon atom within its triarylmethane structure an aryl group substituted in the ortho position with a nucleophilic moiety which is ring-closed on the meso carbon atom and (b) an electrophilic reagent which upon heating and contacting said di- or triarylmethane compound undergoes a bimolecular nucleophilic substitution reaction with the nucleophilic moiety to form a colored, ring-opened di- or triarylmethane compound.Type: GrantFiled: May 14, 1986Date of Patent: May 17, 1988Assignee: Polaroid CorporationInventors: Alan L. Borror, Ernest W. Ellis
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Alloy having variable spectral reflectance and information recording material making use of the same
Patent number: 4743526Abstract: An alloy having variable spectral reflectance having a composition which essentially consists of Ag, 30 to 46 wt % of Zn and 0.1 to 15 wt % in total of at least one element selected from elements of groups Ia, IIa, Iva, Va, VIa, VIIa, VIII, Ib to Vb and rare earth elements, the alloy being able to have different crystal structures, one of which is obtained when it is held in solid state at a first temperature above the room temperature, another of which is obtained when the same is held in the solid state at a second temperture lower than said first temperature. Disclosed also is an information recording medium made of the alloy. The alloy exhibits a reversible change in color or spectral reflectance as a result of change between two crystal phases, so that the information recording medium produced from this alloy can be used effectively as the medium for recording, regeneration and erasion of the informations.Type: GrantFiled: December 2, 1985Date of Patent: May 10, 1988Assignee: Hitachi, Ltd.Inventors: Hisashi Ando, Tetsuro Minemura, Isao Ikuta, Yosimi Katou, Mituo Nakamura -
Patent number: 4738908Abstract: A photothermal transducing type of recording medium comprises at least one azulenium salt represented by the general formula [I], [II], [III], or [IV].Type: GrantFiled: July 11, 1985Date of Patent: April 19, 1988Assignee: Canon Kabushiki KaishaInventors: Yoshihiro Oguchi, Kazuharu Katagiri, Yoshio Takasu
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Patent number: 4735888Abstract: A disk-shaped recording medium of the invention has a photosensitive recording layer formed on a substrate. Tellurium oxide clusters are dispersed in a hydrocarbon matrix of the recording layer so as to thermally stabilize the matrix. Tellurium clusters are dispersed in the matrix which is thermally stabilized by dispersion of the tellurium oxide clusters. The recording layer has excellent oxidation and heat resistance. The recording medium is manufactured by a plasma sputtering technique.Type: GrantFiled: January 30, 1986Date of Patent: April 5, 1988Assignee: Kabushiki Kaisha ToshibaInventors: Yoshikatsu Takeoka, Norio Ozawa, Nobuaki Yasuda
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Patent number: 4725525Abstract: Provided is an information recording medium and a method for recording information thereon. The information layer of the recording medium comprises a naphthalocyanine chromophore, e.g., a sulfonamidonaphthalocyanine having silicon or germanium as the central hetero atom. Information can thereby be readily recorded via a thermal deformation technique due to the effective absorption by the dye of light in the wavelength range of about 760-850 nm. The naphthalocyanine chromophores exhibit excellent chemical and photolytic stability, their use thereby increasing the useful life of the recording medium.Provided herein are also novel naphthalocyanine chromophore compounds which are useful in optical recording media, and which exhibit exceptional solubility characteristics. Such chromophores are thereby readily applied as a film in the formulation of an information recording medium.Type: GrantFiled: July 7, 1986Date of Patent: February 16, 1988Assignee: Hoebbst Celanese CorporationInventors: Malcolm E. Kenney, R. Sidney Jones, Jr., James E. Kuder, David E. Nikles
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Patent number: 4720450Abstract: A method of thermal imaging is provided which comprises heating imagewise a layer of a colored di- or triarylmethane compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho-position to the meso carbon atom with a group comprising a thermally unstable urea moiety which fragments upon heating to provide a new group that bonds to the meso carbon atom whereby the di- or triarylmethane compound is rendered ring-closed and colorless in an imagewise pattern corresponding to said imagewise heating.Type: GrantFiled: May 15, 1986Date of Patent: January 19, 1988Assignee: Polaroid CorporationInventor: Ernest W. Ellis
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Patent number: 4720449Abstract: A thermal imaging method is provided which comprises heating imagewise a di- or triarylmethane compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho position to the meso carbon atom with a moiety ring-closed on the meso carbon atom directly through a nitrogen atom, which nitrogen atom is also bound to a group with a masked acyl substituent that undergoes fragmentation upon heating to liberate the acyl group for effecting intramolecular acylation of said nitrogen atom to form a new group in the ortho position whereby the di- or triarylmethane compound is rendered colored in an imagewise pattern corresponding to said imagewise heating.Type: GrantFiled: May 14, 1986Date of Patent: January 19, 1988Assignee: Polaroid CorporationInventors: Alan L. Borror, Ernest W. Ellis
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Patent number: 4713314Abstract: The invention relates to an optical recording medium for effecting writing of information by means of recording light such as laser and reproduction or reading of the recorded information by means of reproduction or reading light, and provides an optical recording medium designed to prevent any degradation of the properties by the reading light and any lowering of writing sensitivity and reading S/N ratios. The optical recording medium including a recording layer 2 on a substrate 1 is characterized in that the recording layer 2 contains a mixture of a cyanine dye with a combination of cyanine dye cation with quencher anion.Type: GrantFiled: February 4, 1986Date of Patent: December 15, 1987Assignee: TDK CorporationInventors: Kenryo Namba, Shigeru Asami, Toshiki Aoi, Kazuo Takahashi, Akihiko Kuroiwa
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Patent number: 4711834Abstract: A laser-imageable assembly comprising a transparent substrate and an associated energy absorbent transfer layer comprising particles which absorb laser energy dispersed in a resin, the assembly comprising at least one further layer selected from(a) an intermediate priming layer,(b) a protective coating layer, and(c) a lubricant coating layer.The transfer layer is preferably rendered heterogeneous - for example, by appropriately drying the coated substrate.A preferred substrate is a polyester film.Type: GrantFiled: April 8, 1985Date of Patent: December 8, 1987Assignee: Imperial Chemical Industries PLCInventors: Alan Butters, Roger N. Barker, Stuart C. Rennison
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Patent number: 4710452Abstract: A recording element comprising, as the optical recording layer, an amorphous thin film of an alloy having the formula:(Ge.sub.x Te.sub.1-x).sub.1-z Ti.sub.zwherein, on an atom-to-atom basis,x is from 0.33 to 0.55, andz is greater than zero up to 0.30 is disclosed.Type: GrantFiled: September 15, 1986Date of Patent: December 1, 1987Assignee: Eastman Kodak CompanyInventor: Pranab K. Raychaudhuri
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Patent number: 4702991Abstract: In an optical disk, a single recording layer is formed on a transparent substrate. The recording layer has an insulative base layer in which metal clusters and organic clusters are uniformly contained. When radiation is incident on the recording layer such that the intensity of the radiation is changed in accordance with the type of recording information, the metal clusters absorb radiation energy. The organic clusters produce a gas component in accordance with a level of the radiation energy absorbed by the metal clusters, thereby causing the base layer to incur a local projection by a pressure of the gas component such that a protuberance is formed on the base layer.Type: GrantFiled: June 20, 1986Date of Patent: October 27, 1987Assignee: Kabushiki Kaisha ToshibaInventors: Yoshikatsu Takeoka, Norio Ozawa, Nobuaki Yasuda
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Patent number: 4683191Abstract: An imageable toner powder comprising a solid material capable of existing as a supercooled liquid after being heated above its melting temperature and subsequently cooled and a colorant.Type: GrantFiled: June 9, 1986Date of Patent: July 28, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas C. Geisler
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Patent number: 4652514Abstract: An optical information recording medium which comprises the provision of a thin film (recording layer) formed of a cyanine coloring matter and a transition metal complex being superior in long wavelength range light absorbability to said coloring matter on a transparent or opaque substrate and which permits writing and reading by using laser beam.Type: GrantFiled: September 20, 1984Date of Patent: March 24, 1987Assignee: Ricoh Co., Ltd.Inventors: Michiharu Abe, Hideaki Oba
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Patent number: 4637976Abstract: In a data recording member having a data recording film which is formed on a substrate either directly or via at least one of inorganic and organic protective layers and which causes the change of atomic arrangement upon being irradiated by recording beam, the improvement wherein said data recording film has an average composition in a direction of the film thickness expressed by the following formulas:M.sub.x Te.sub.y Se.sub.z O.sub..alpha.wherein x, y, z and .alpha. are values within the ranges of 2.ltoreq.x.ltoreq.40, 30.ltoreq.y.ltoreq.95, 3.ltoreq.z.ltoreq.45, 0.ltoreq..alpha..ltoreq.20, and M is at least one element selected from the group consisting of As, Sb, Bi, S, Si, Ge, Sn, Pb, Al, Ga, In, Tl, Zn, Cd, Au, Ag, Cu, Ni, Pd, Rh, Cr, Mo, W and Ta.Type: GrantFiled: August 20, 1984Date of Patent: January 20, 1987Assignee: Hitachi, Ltd.Inventors: Motoyasu Terao, Yasushi Miyauchi, Kazuo Shigematsu, Shinkichi Horigome
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Patent number: 4636462Abstract: A heat-developable photosensitive material which contains a compound of the general formula: ##STR1## wherein F and F' each represents an atomic group necessary for the formation of a 5- or 6-membered rings which may have condensed rings; n represents an integer of 0 or 1; R.sup.1 and R.sup.2 which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxyl group, a cyano group, or a substituted or unsubstituted alkyl group, cycloalkyl group, alkenyl group, alkynyl group, aryl group, heterocyclic residual group, aralkyl group, alkoxy group, aryloxy group, acylamino group, acyloxy group, acyl group, carbamoyl group, sulfamoyl group, sulfamoylamino group, ureido group, alkylsulfonyl group, arylsulfonyl group, alkylsulfonylamino group, arylsulfonylamino group, alkoxycarbonyl group or alkoxycarbonylamino group, or --CO.sub.2 M; and R.sup.1 and R.sup.2 may be combine and form a ring, M is an alkali metal or H.Type: GrantFiled: August 26, 1985Date of Patent: January 13, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
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Patent number: 4626493Abstract: A laser-imageable assembly comprising a transparent substrate having on a surface thereof an energy absorbent transfer layer comprising particles which absorb laser energy dispersed in a heterogeneous resin layer. Heterogeneity may be achieved by appropriately drying the coated substrate.The assembly may also comprise one or more additional layers of primer, protective and lubricant coatings.A preferred assembly comprises a polyester substrate with a graphite-containing heterogeneous transfer layer.Type: GrantFiled: April 8, 1985Date of Patent: December 2, 1986Assignee: Imperial Chemical Industries PLCInventors: Alan Butters, Roger N. Barker, Stuart C. Rennison
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Patent number: 4624914Abstract: An optical information recording medium comprising a substrate and a photosensitive thin layer consisting of Te, O and Pd. When exposed to optical energy, this thin layer is capable of undergoing a phase change by which an optical transmittance is changed. The addition of Pd results in an improvement of a response time to a great extent. This optical information recording medium is preferably made by a method using a Pd evaporation source and another source for Te+TeO.sub.2.Type: GrantFiled: September 12, 1985Date of Patent: November 25, 1986Inventors: Kunio Kimura, Masatoshi Takao, Nobuo Akahira, Mutsuo Takenaga
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Patent number: 4614521Abstract: The transfer recording method which comprises heating a transfer sheet having a color material layer containing a sublimable dye on a base according to the image information received, thereby subliming said sublimable dye and transfer recording it on an image receiving layer of a recording sheet, a transfer recording method which is characterized by that the image receiving layer of the recording sheet contains a compound capable of reacting with the sublimable dye contained in the color material layer of the transfer sheet.Type: GrantFiled: May 10, 1985Date of Patent: September 30, 1986Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Yukichi Murata, Shuichi Maeda
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Patent number: 4613553Abstract: Metallic salts of organic charge-transfer agents, such as TCNQ, TNAP, TCNE and DDQ and their derivatives, can be processed by an electron beam for a variety of useful electronic and optical applications. The metallic charge transfer salts can be used to deposit high resolution conductive lines directly without developing solutions or subsequent metallization steps. The compounds can also be employed in the conventional manner as resists for doping (i.e., ion diffusion or implantation) and to diffuse metals into substrates. In particular, electronic devices, optical devices and image-storage devices are disclosed which can be formed by simple electron beam processed of metal charge-transfer salt films deposited on substrates.Type: GrantFiled: May 31, 1985Date of Patent: September 23, 1986Assignee: Brown University Research FoundationInventors: William M. Risen, Jr., Efstratios I. Kamitsos
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Patent number: 4608329Abstract: An imageable toner powder comprising a solid material capable of existing as a supercooled liquid after being heated above its melting temperature and subsequently cooled and a colorant.Type: GrantFiled: January 8, 1985Date of Patent: August 26, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas C. Geisler
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Patent number: 4605607Abstract: Provided is an optical data storage medium comprising a chromophore/polymer composition information layer, wherein the chromophore is chemically bound or coordinated with the polymer. The chromophore is an organo macrocyclic chromophore containing a constituent metal atom, and preferably a central metal atom, with the chromophore being coordinated to the polymer through the metal atom. As a result, the chromophore/polymer material has excellent film-forming properties so that the medium can be readily and efficiently manufactured. As well, the resulting information layer offers excellent thermomechanical properties and exhibits excellent absorption properties, all in a single component material. By utilizing a single component material, the problem of dye/polymer phase separation frequently encountered in conventional dye/polymer mixtures is also overcome.Type: GrantFiled: April 8, 1985Date of Patent: August 12, 1986Assignee: Celanese CorporationInventors: David E. Nikles, R. Sidney Jones, Jr., James E. Kuder
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Patent number: 4602263Abstract: A thermal imaging method for forming color images is provided which relies upon the irreversible unimolecular fragmentation of one or more thermally unstable carbamate moieties of an organic compound to effect a visually discernible color shift from colorless to colored, from colored to colorless or from one color to another.Type: GrantFiled: September 4, 1984Date of Patent: July 22, 1986Assignee: Polaroid CorporationInventors: Alan L. Borror, Ernest W. Ellis, Donald A. McGowan
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Patent number: 4599298Abstract: A radiation-sensitive, imageable article comprises in sequence a substrate, a vapor-deposited colorant layer capable of providing an optical density of at least 0.3 to 10 nm band of the electromagnetic spectrum between 280 and 900 nm, and a vapor-deposited graded metal/metal oxide or metal sulfide layer.Type: GrantFiled: July 16, 1984Date of Patent: July 8, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard S. Fisch
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Patent number: 4588674Abstract: The laser imaging material comprises a laser-transparent support layer of, for example, polyester. A first overlying layer is laser-transparent and formed from a binder that is instantaneously thermally-chemically-decomposable with the production of a gas, for example, an acrylic or methacrylic homopolymer or copolymer, a cellulosic polymer, or a homopolymer or copolymer of stryene. A second overlying layer is formed from such a material, the same as or different from that of the first overlying layer, pigmented with carbon black. Upon laser irradiation through the support layer 10, selected portions of the carbon black are transferred to a suitable receptor surface such as paper or a lithographic plate.Type: GrantFiled: October 13, 1983Date of Patent: May 13, 1986Inventors: Malcolm J. Stewart, Andrew Hudson, Peter W. Griffiths
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Patent number: 4587209Abstract: Disclosed is an optical information recording member which permits recording of optical information at a high speed and high density by means of energy of light or heat, as well as a high speed reproduction of the recorded information. The optical information recording member has a thin film formed on a substrate which thin film is made of TeOx constituted by a mixture of Te and TeO.sub.2 with a small amount of Au being added such that the contents of Te, O and Au in the thin film falls within a predetermined region limited in terms of atomic percent. The optical information recording member of the invention having the thin film of Te-O-Au system permits the information to be recorded in quite a short time thus allowing quite high speed of recording and reproduction as compared with the conventional recording film of TeOx system. The optical information recording member of the invention also brings about a higher recording sensitivity and a higher C/N ratio.Type: GrantFiled: March 25, 1985Date of Patent: May 6, 1986Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Eiji Ohno, Kunio Kimura, Noboru Yamada, Nobuo Akahira
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Patent number: 4585722Abstract: Optical recording medium includes a substrate, a coloring agent layer formed on the substrate, a light absorber layer formed on the coloring agent layer and a developer layer formed on the light absorber layer. The coloring agent layer is separated from the developer layer by the light absorber layer and the lamination layer composed of these layers has a uniform thickness. The optical recording medium is produced by vacuum depositing a coloring agent, a light absorber and a developer successively on the substrate to form a multi-layer construction, the substrate being capable of transmitting visible light and near infrared light. Alternatively, the optical recording medium contains a plurality of lamination layers mentioned above. The optical recording medium has a high contrast and achieves a high speed multi-color recording.Type: GrantFiled: February 20, 1985Date of Patent: April 29, 1986Assignee: Nippon Telegraph & Telephone Public CorporationInventors: Akira Morinaka, Shigeru Oikawa, Hirotsugu Sato
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Patent number: 4554239Abstract: A recording material comprising a transparent support having formed thereon a recording layer containing a thermally coagulatable proteinaceous compound, the recording layer having an average optical density throughout the wavelength region of about 350 nm to 450 nm of at least about 1.5 is disclosed, which is suitable for preparing a reprographic material such as a photomask by flash exposure in heat conducting relation with an original.Type: GrantFiled: February 11, 1985Date of Patent: November 19, 1985Assignee: Process Shizai Co., Ltd.Inventor: Takashi Kashiwagi