Thermal Imaging Composition Patents (Class 430/964)
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Patent number: 4540620Abstract: A method is described for producing electrically-conductive paths in poly(arylene sulfide) and other polymers exhibiting differing receptivity to chemical doping agents depending upon the crystallinity of the polymer structure. Conductivity is selectively induced in amorphous regions by contacting the amorphous regions with a doping agent in solution. Selected areas of crystalline polymers are made amorphous by heat or solvent treatment.Type: GrantFiled: August 17, 1984Date of Patent: September 10, 1985Assignee: Phillips Petroleum CompanyInventors: Timothy W. Johnson, Mark L. Stone
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Patent number: 4504565Abstract: A radiation imageable composition in which an image can be produced upon exposure to intense radiation is disclosed which comprises (a) hollow, ceramic microspheres, and (b) a binder material which will not be destroyed during exposure of the composition to intense radiation and will not mask the image produced upon exposure to intense radiation, wherein the binder material has an index of refraction greater than the index of refraction of the microspheres in the absence of any other dye or pigment.Type: GrantFiled: April 17, 1984Date of Patent: March 12, 1985Assignee: Markem CorporationInventors: Jon O. Baldvins, Joseph Puleo, Jr.
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Patent number: 4476214Abstract: An optical information disk in which information can be written and read optically and which has a substrate plate which on at least one side has a recording layer which satisfies the formula Te.sub.x Se.sub.y Sb.sub.z S.sub.q wherein x=55-85 at. %, y=13-30 at. % z=1-12 at. %, q=0-10 at. % and x+y+z+q=100. Suitable recording layers are Te.sub.60 Se.sub.25 Sb.sub.10 S.sub.5 and Te.sub.75 Se.sub.15 Sb.sub.5 S.sub.5.Type: GrantFiled: October 13, 1981Date of Patent: October 9, 1984Assignee: U.S. Philips CorporationInventors: Pieter Zalm, Bernardus A. J. Jacobs, Adriaan W. De Poorter
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Patent number: 4463089Abstract: An improved reflective silver laser recording and data storage medium for direct read after writing, having a protective gold plating on the silver particles of the reflective surface. The gold plating increases the recording sensitivity resulting in higher contrast ratios for the recorded data. Increased contrast ratios between recorded and non-recorded reflective areas are obtained by the gold plating allowing lower laser energy for readout of recorded data. The reflective silver surface is plated with gold by an electroless ion displacement procedure.Type: GrantFiled: December 20, 1982Date of Patent: July 31, 1984Assignee: Drexler Technology CorporationInventor: Eric W. Bouldin
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Patent number: 4463083Abstract: A thermal recording element comprising a support having formed thereon a recording layer, a first protective layer comprising an organic high molecular weight material having a softening point below about 70.degree. C. formed on the recording layer, and a second protective layer comprising an organic high molecular weight material having high mechanical strength.Type: GrantFiled: May 11, 1982Date of Patent: July 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Masao Kitajima, Osamu Seshimoto, Tomizo Namiki, Fumiaki Shinozaki, Tomoaki Ikeda, Yuzo Mizobuchi
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Patent number: 4460676Abstract: Method and apparatus are described for non-impact printing of single and multi-ply business form assemblies, utilizing an electromagnetic radiation reactant chemical mixture which is selectively coated in one or more plies of the assemblies causing the plies to form images when selectively heated by the action of a controlled source by passing the radiation, such as microwave energy, through the business form assemblies.Type: GrantFiled: February 21, 1980Date of Patent: July 17, 1984Inventor: Warren M. Fabel
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Patent number: 4435499Abstract: Photosensitive silver halide grains that are thin tabular grains having an average grain thickness of less than 0.3 microns provide advantages, including improved spectral sensitization and image tone, in a photothermographic material comprising photosensitive silver halide and a photosensitive silver halide processing agent. An image is developed in such an exposed photothermographic material by heating the material, such as to a temperature within the range of about 90.degree. C. to about 180.degree. C.Type: GrantFiled: January 31, 1983Date of Patent: March 6, 1984Assignee: Eastman Kodak CompanyInventor: John W. Reeves
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Patent number: 4430401Abstract: An optical recording medium for use with a recording apparatus of the type that focuses onto the medium, as the medium is moved in a prescribed fashion, a beam of light that is modulated in intensity in accordance with a data signal to be recorded. The recording medium includes a substrate having a smooth, planar upper surface, with a thin light-absorbing coating overlaying the surface, such coating including an explosive material such as nitrocellulose, and a light-absorbing dye. As the medium is moved with respect to the intensity-modulated beam, the explosive coating is selectively energized by the beam to induce spaced explosions threin, whereby corresponding optically readable irregularities, representative of the data signal, are formed in the outer surface of the coating.Type: GrantFiled: May 5, 1980Date of Patent: February 7, 1984Assignee: Discovision AssociatesInventor: Richard L. Wilkinson
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Patent number: 4400439Abstract: A recording medium is described comprising a recording layer having provided on a support, wherein the recording layer contains at least one chemically modified thermally coagulatable proteinaceous compound containing therein no intermolecular cross-linking bond.Type: GrantFiled: February 9, 1981Date of Patent: August 23, 1983Assignee: Process Shizai Co., Ltd.Inventors: Takashi Kashiwagi, Nobuyuki Inoue
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Patent number: 4396701Abstract: An underlayer for a laser recording and data storage medium with a light absorption characteristic suited to a recording laser. The underlayer is formed by creating a nuclei layer in a silver-halide photosensitive emulsion layer and then contacting the emulsion layer with a chromogenic reducing agent and a chromogenic dye coupler. The reflective layer may be formed prior to this step by subjecting the nuclei layer to a monobath having a silver-halide solvent and a silver reducing agent until a reflective surface layer of non-filamentary silver particles is formed, or after the step by chemical vapor deposition or sputtering of a reflective metal layer over the underlayer.Type: GrantFiled: September 11, 1981Date of Patent: August 2, 1983Assignee: Drexler Technology CorporationInventor: Eric W. Bouldin
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Patent number: 4363870Abstract: A method for making a laser recording and data storage medium by first exposing a Lippman emulsion to light in order to form a depthwise nuclei gradient, then physically developing the emulsion until a reflective surface layer of spheroid silver particles, having the desired degree of reflectivity, is attained and then chemically developing the remaining nuclei to form a dark underlayer of filamentary silver particles.Type: GrantFiled: September 11, 1981Date of Patent: December 14, 1982Assignee: Drexler Technology CorporationInventor: Eric W. Bouldin
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Patent number: 4349600Abstract: Disclosed is a color developer for a leuco pigment, which comprises an oligomer or polymer of a vinyl phenol. When this color developer is used for developing the color of a leuco pigment, a color having a high density is developed even if the leuco pigment concentration is low.Type: GrantFiled: October 28, 1980Date of Patent: September 14, 1982Assignee: Mita Industrial Co., Ltd.Inventor: Nobuhiro Miyakawa
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Patent number: 4316036Abstract: A benzopyranothiazole of the formula ##STR1## wherein each of R.sub.1 and R.sub.2 independently represents hydrogen, alkyl of not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or represents cycloalkyl, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl or lower alkoxy, or R.sub.1 and R.sub.2 together with the nitrogen atom to which they are attached represent a 5- or 6-membered heterocyclic radical or a N-carbazolyl radical, Q represents hydrogen, lower alkyl, benzyl or groups of the formulae (1a) or (1b) ##STR2## each of X, X.sub.1 and X.sub.2 represents hydrogen, halogen, lower alkyl or lower alkoxy, each of Y.sub.1, Y.sub.2, Y'.sub.1 and Y'.sub.Type: GrantFiled: September 11, 1978Date of Patent: February 16, 1982Assignee: Ciba-Geigy CorporationInventor: Jean C. Petitpierre
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Patent number: 4312938Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.Type: GrantFiled: October 17, 1980Date of Patent: January 26, 1982Assignee: Drexler Technology CorporationInventors: Jerome Drexler, Eric W. Bouldin
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Patent number: 4307898Abstract: 3-[(Alkoxy)(aryl or heteroaryl)methyl]-1H-indoles which are useful as color formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with alcohols in the presence of a base.Type: GrantFiled: March 6, 1980Date of Patent: December 29, 1981Assignee: Sterling Drug Inc.Inventors: Paul J. Schmidt, William M. Hung
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Patent number: 4298684Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion including silver precipitating nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric matrix which is highly reflective of light and electrically non-conducting.Type: GrantFiled: June 20, 1980Date of Patent: November 3, 1981Assignee: Drexler Technology CorporationInventors: Eric W. Bouldin, Jerome Drexler
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Patent number: 4291120Abstract: A heat developable photosensitive material having two or more layers superimposed on a support and containing at least (a) an organic silver salt, (b) a photocatalyst and (c) a reducing agent in one or more such layers, at least one said layers containing (d) a polymer having a repeating unit of the formula: ##STR1## wherein R is a hydrogen atom or a lower alkyl group; and X is a hydrogen atom, or one to three groups selected from the group consisting of a halogen atom, a nitro group, a cyano group, an alkyl group, an alkoxy group, an alkoxycarbonyl group, an alkylsulfonyl group, an aryloxy group, an acyl group, an acyloxy group and an acylamido group.Type: GrantFiled: February 15, 1980Date of Patent: September 22, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomoyuki Kobayashi, Toshimasa Usami, Hiroshi Misu, Hidefumi Sera
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Patent number: 4288510Abstract: This invention relates to the production of information carriers on which the information is recorded along a track; the process of making the information carrier comprises a first step of materializing the track itself before recording any information by forming a groove in an auxiliary layer, the track thus being capable of being optically detected, and a second step of recording the information in a photosensitive layer in contact with the auxiliary layer along the track previously formed.Type: GrantFiled: September 22, 1980Date of Patent: September 8, 1981Assignee: Thomson-BrandtInventors: Claude Tinet, Claire Lemonon
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Patent number: 4288509Abstract: A recording material comprising a transparent support having formed thereon a recording layer containing a thermally coagulatable proteinaceous compound, the recording layer having an average optical density throughout the wavelength region of about 350 mm to 450 nm of at least about 1.5 is disclosed, which is suitable for preparing a reprographic material such as a photmask by flash exposure in heat conducting relation with an original.Type: GrantFiled: July 20, 1979Date of Patent: September 8, 1981Assignee: Process Shizai Co., Ltd.Inventor: Takashi Kashiwagi
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Patent number: 4284716Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.Type: GrantFiled: April 14, 1980Date of Patent: August 18, 1981Assignee: Drexler Technology CorporationInventors: Jerome Drexler, Eric W. Bouldin
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Patent number: 4283077Abstract: Aldehyde or ketone 0-[(3-indolyl)(aryl or heteroaryl)methyl]oximes which are useful as color-formers in pressure-sensitive carbonless duplicating systems and thermal marking systems are prepared by reacting 3-[(arylsulfonyl)(aryl or heteroaryl)methyl]-1H-indoles with aldehyde or ketone oximes in the presence of a base.Type: GrantFiled: March 6, 1980Date of Patent: August 11, 1981Assignee: Sterling Drug Inc.Inventors: Paul J. Schmidt, William M. Hung
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Patent number: 4278756Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric matrix which is highly reflective of light and electrically non-conducting.Type: GrantFiled: July 6, 1979Date of Patent: July 14, 1981Assignee: Drexler Technology CorporationInventors: Eric W. Bouldin, Jerome Drexler
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Patent number: 4269917Abstract: A reflective laser recording and data storage medium, for direct reading after writing, formed from a photosensitive silver-halide emulsion wherein a surface latent image exposure on the recording area forms a depthwise gradient of silver nuclei. A single step negative silver diffusion transfer process is used to develop silver nuclei of the latent image and dissolve unexposed silver halide elsewhere, forming silver ion complexes. These complexes are transported by diffusion transfer to the developing silver nuclei sites where silver is precipitated and adsorbed to form a high concentration of non-filamentary particles at a surface of a low melting temperature dielectric colloid matrix which is highly reflective of light and electrically non-conducting.Type: GrantFiled: July 14, 1980Date of Patent: May 26, 1981Assignee: Drexler Technology CorporationInventors: Jerome Drexler, Eric W. Bouldin
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Patent number: 4230776Abstract: The thermosensitive recording paper comprising a support and, supported thereon, a combination of a colorless or slightly colored lactone compound color former and a phenolic compound capable of rendering said lactone compound to develop color, is improved in its printing quality in that said support is an undercoated paper.Type: GrantFiled: December 14, 1978Date of Patent: October 28, 1980Assignee: Mitsubishi Paper Mills, Ltd.Inventor: Takao Kosaka
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Patent number: 4211838Abstract: A dry process high sensitivity imaging film includes a solid, high optical density and substantially opaque film of dispersion imaging material deposited on a substrate. The film of dispersion imaging material comprises a plurality of separate layers of different and substantially mutually insoluble metal components having relatively high melting points and relatively low melting point eutectics, and interfaces between said layers having relatively low melting points.Type: GrantFiled: August 25, 1977Date of Patent: July 8, 1980Assignee: Energy Conversion Devices, Inc.Inventors: Masatsugu Izu, Vincent D. Cannella
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Patent number: 4208478Abstract: A Te(II) complex represented by the formula: RTeM(R').sub.3 wherein M is lead, tin, germanium or silicon; R and R' are alkyl or aryl is useful in an imaging material to provide a non-silver image. The imaging material can be a photographic material, especially a heat-developable photographic material containing, for example, a photosensitive metal salt other than the Te(II) material or other sources of developable nuclei.Type: GrantFiled: October 13, 1977Date of Patent: June 17, 1980Assignee: Eastman Kodak CompanyInventors: Sylvia A. Gardner, Henry J. Gysling
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Patent number: 4207392Abstract: An activator-stabilizer precursor which comprises a certain acylhydrazine which releases a base moiety upon being heated to a temperature above about 130.degree. C. provides improved heat developable and heat stabilizable photographic materials comprising, in binder, and in reactive association, (a) a photosensitive silver salt, (b) a photosensitive silver salt developing agent, and (c) a stabilizing concentration of the described activator-stabilizer precursor having an acid portion and a base portion. The heat developable and heat stabilizable photographic element provides essential freedom from visual crystal formation in the processed photographic element. After imagewise exposure, a developed and stabilized image can be produced in the photographic element by heating the element to processing temperature.Type: GrantFiled: October 30, 1978Date of Patent: June 10, 1980Assignee: Eastman Kodak CompanyInventors: Daniel D. Shiao, Lawrence R. Morrow
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Patent number: 4197131Abstract: Dry silver photo-sensitive compositions comprising an intimate mixture of a substantially light-insensitive silver compound which upon reduction gives a visible change and sufficient of a silver halide to catalyse said reduction to give a visible change in those areas where the silver halide has been exposed to light and when the mixture is heated in the presence of a reducing agent, and as a yellow acutance dye a 1-alkyl-4-nitro-methylene-quinolane, the alkyl substituent containing 1 to 4 carbon atoms.Type: GrantFiled: November 29, 1978Date of Patent: April 8, 1980Assignee: Minnesota Mining and Manufacturing CompanyInventors: Bernard D. Lea, Jack E. Reece