Abstract: The present invention provides a method for pattering oriented materials to make organic electronic displays or devices. The method includes selective thermal transfer of an oriented electronically active or emissive material from a thermal transfer donor sheet to a receptor. The method can be used to make organic electroluminescent devices and displays that emit polarized light. The method can also be used to make organic electronic devices with enhanced charge mobility properties. The present invention also provides donor sheets for use with the method, and methods for making donor sheets that include transfer layers having oriented electronically active organic materials.

Abstract: A lithographic printing plate precursor comprising:

Abstract: This patent describes on-press ink and/or fountain solution development of lithographic plates having on a substrate a thermosensitive layer capable of hardening or solubilization upon exposure to an infrared laser radiation. The plate can be imagewise exposed with an infrared laser and then on-press developed with ink and/or fountain solution by rotating the plate cylinder and engaging ink and/or fountain solution roller. The developed plate can then directly print images to the receiving sheets. The imagewise exposure can be performed off the press or with the plate being mounted on the plate cylinder of a lithographic press.

Abstract: An image-forming material comprising: an image-receiving sheet; and a thermal transfer sheet comprising a first support, a photothermal converting layer and an image-forming layer, wherein the image-receiving sheet or each of the image-receiving sheet and the first support comprises a polyether sulfone layer comprising polyether sulfone and a method using the image-forming material.

Abstract: According to the present invention there is provided a method for obtaining a high quality printing plate by spraying a spray solution on a receiving surface, which is not a grained and anodized aluminum surface, characterized in that the pressure factor (PF) is lower than 200 mN/m, wherein PF=P/d×(&sgr;+&thgr; mN/m°) PF: Pressure Factor (mN/m) P: Spray Profile (mm) d: distance between spray head and receiving surface (mm) &sgr;: surface tension (mN/m). &thgr;: Dynamic contact angle of the receiving surface with water at 2 s, contact time, and wherein the spray solution comprises hydrophobic thermoplastic polymer particles and a compound capable of converting light into heat.

Abstract: A thermal mass transfer donor element is provided that includes a thermal transfer layer and a light-to-heat conversion layer, wherein the light-to-heat conversion layer has at least two regions exhibiting different absorption coefficients. The thermal transfer donor elements provided can improve imaging performance by increasing transfer sensitivity and decreasing imaging defects.

Abstract: The present invention provides a method for pattering oriented materials to make organic electronic displays or devices. The method includes selective thermal transfer of an oriented electronically active or emissive material from a thermal transfer donor sheet to a receptor. The method can be used to make organic electroluminescent devices and displays that emit polarized light. The method can also be used to make organic electronic devices with enhanced charge mobility properties. The present invention also provides donor sheets for use with the method, and methods for making donor sheets that include transfer layers having oriented electronically active organic materials.

Abstract: A photopolymerizable composition that is cured with visible light or an infrared laser and is used as a recording layer in a negative planographic printing plate precursor. The photopolymerizable composition is cured by exposure and includes (A) a polymerizable compound that is solid at 25° C. and has at least one radical-polymerizable ethylenically unsaturated double bond in a molecule, (B) a radical polymerization initiator, (C) a binder polymer and, as required, (D) a compound generating heat by infrared exposure.

Abstract: This invention relates to a photothermographic color element containing a mixture of blocked developers in the same emulsion layers. By having different blocked developers or mixtures of at least two blocked developers in different color layers, it is possible to manipulate the image discrimination (at the processing temperature) in each layer and to balance the density formation or color in the different color layers. Different mixtures of blocked developers can be used in different imaging layers, to balance the Gamma, the Dmin and the Latitude in different imaging layers or color units.

Abstract: Photothermally sensitive recording sheets for color imaging are disclosed comprising a transparent support sheet having a thermal slip layer disposed on one surface of the support and a heat sensitive image layer on the opposite surface of the support. A second opaque (paper) or transparent (plastic) sheet is laminated to the color-producing layer. The image layer comprises photohardenable microcapsules containing a photopolymerizable or photocrosslinkable compound, a photoinitiator and a dye precursor and a developer material external to the microcapsules. Image-wise exposure of the recording sheet to actinic radiation causes selective photohardening of microcapsules sensitive to that radiation. Heating the resultant exposed recording sheet to a temperature well above the developer melting point by for example a thermal head allows the developer to selectively permeate the non-photohardened capsules resulting in the development of an image, including full color images.

Abstract: A thermal mass transfer donor element is provided that includes a thermal transfer layer and a light-to-heat conversion layer, wherein the light-to-heat conversion layer has at least two regions exhibiting different absorption coefficients. The thermal transfer donor elements provided can improve imaging performance by increasing transfer sensitivity and decreasing imaging defects.

Abstract: A non-photosensitive core-shell silver salt can be used in thermographic and photothermographic imaging compositions and materials. This core-shell silver salt includes one or more silver salts in the core, at least one of which is different from the one or more silver salts used in the shell. The molar ratio of the different silver salts in the core and shell is from about 0.01:1 to about 100:1.

Abstract: According to the present invention there is provided a class of IR-sensitizing dyes, comprising two benzoindol rings and at least two sulphonic acid groups corresponding to the general formula I:

Abstract: A thermal transfer donor element is provided which comprises a support, a light-to-heat conversion layer, an interlayer, and a thermal transfer layer. When the above donor element is brought into contact with a receptor and imagewise irradiated, an image is obtained which is free from contamination by the light-to-heat conversion layer. The construction and process of this invention is useful in making colored images including applications such as color proofs and color filter elements.

Abstract: Phenolic resin compositions formulated for use in lithographic exposure processes are given a heat treatment at 40-90° C. for at least 4 hours shortly after their coating onto lithographic substrates, to produce lithographic printing forms. It is found that such a heat treatment improves later exposure processes, in particular by rendering the sensitivity of the compositions less variable, over time.

Abstract: A mass transfer imaging element comprising a substrate having a surface colorant layer containing a pigment to be imagewise transferred, wherein said colorant layer comprises a fluorocarbon additive in an amount to provide a fluorocarbon additive:pigment weight ratio of at least 1:20.

Abstract: In an image recording process comprising the steps of superposing a transfer film on an receiver film, said transfer film having an opto-thermal converting layer and a toner layer on a support and said receiver film having an image receiving layer on a support, said toner layer being opposed to said image forming layer, transferring said toner layer onto said image receiving layer by exposure of laser beam, and stripping said transfer film from said receiver film to form an image, the thickness of said opto-thermal converting layer is adjusted such that the distance from the position where a peak temperature occurs in the direction of thickness of the opto-thermal converting layer to said toner layer is within the range from zero to a third of the thickness of said opto-thermal converting layer. This design permits satisfactory image recording without undesired density drop.

Abstract: A process for producing a lithographic printing plate by on-press developing a heat-sensitive lithographic printing plate precursor having on a metallic base in this order (1) an ink-receptive layer, (2) a hydrophilic layer containing colloidal particles of an oxide or hydroxide of at least one element, e.g., silicon or aluminum, and (3) a hydrophilic overcoat layer capable of being removed on a printing machine, which includes: rotating a plate cylinder having attached thereto the heat-sensitive lithographic printing plate precursor which has been exposed; subsequently supplying an ink and a dampening water to the plate surface by simultaneously bringing a dampening roll and an inking roll into contact with the plate surface or by bringing a water-metering roll into contact with an inking roll and then bringing the inking roll, which functions also to dampen, into contact with the plate surface; and thereby removing the overcoat layer and the exposed parts of the hydrophilic layer.

Abstract: A negative photosensitive lithographic printing plate comprises: a support; and a photosensitive layer containing: i) a modified poly(vinyl alcohol) resin binder having a radical-polymerizable group and an acid group; and ii) at least one of a photo-polymerization initiator and a heat-polymerization initiator.

Abstract: A method for forming an image using a transfer material and an image-receiving material. The transfer material has at least a support, a light-heat exchange layer and a coloring material layer. The image-receiving material has at least an image-receiving layer. The coloring material layer is superposed on the image-receiving layer, and laser light is imagewasely irradiated onto this laminate from the transfer material side. An irradiated region of the coloring material layer transfers onto the image-receiving layer. The transfer material may include an electroconductive layer, and the surface of the coloring material layer may be charged by corona discharge before superposition. Moreover, yellow, magenta, cyan and black may be used one after another, The laser light may be irradiated from a multi-beam 2-dimensional laser array, The thickness of black coloring material layer is from 0.5 to 0.7 &mgr;m and is greater than the thickness of other coloring material layers.

Abstract: According to the present invention there is provided a method for the preparation of a lithographic printing plate comprising the steps of exposing with IR light an imaging element comprising on a lithographic base with a hydrophilic surface a first layer including a polymer, soluble in an aqueous alkaline solution and a top layer on the same side of the lithographic base as the first layer which top layer is IR-sensitive and unpenetratable for or insoluble in an alkaline developer wherein said first layer and said top layer may be one and the same layer, said imaging element comprising a siloxane surfactant; developing said exposed imaging element with an alkaline solution; rinsing said developed imaging element with water or an aqueous solution; gumming said developed imaging element with a baking gum solution; subjecting said gummed imaging element to a thermal treatment at a temperature above 50° C.

Abstract: A photosensitive lithographic printing plate comprising: a support; and a photosensitive layer, wherein the photosensitive layer comprises: a polyurethane resin binder comprising an aliphatic cyclic structure which has a carboxyl group as a substituent directly or indirectly attached to the structure; or a polyvinyl alcohol resin binder modified with an acetal skeleton comprising an aliphatic cyclic structure.

Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic image-receiving layer, and at least one antihalation layer or a filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising at least one dye and at least one hexaarylbiimidazole in the form of particles dispersed in a matrix comprising a hydrophilic or aqueous dispersible polymer.

Abstract: The present invention uses a thermal transfer film in combination with a thermally sensitive color developing paper. The hue of the thermal transfer ink layer or the hue of the developed color of the color developing paper can be recorded on the color developing paper when the applied energy is low, and a plurality of colors can be recorded on the color developing paper by color mixture of the transfer from the thermal transfer ink layer and the developed color of the color developing paper when the applied energy is high.

Abstract: According to the present invention there is provided a method for preparing a lithographic printing plate, the method including the steps of (1) providing an imaging element including on a lithographic hydrophilic support as contiguous top layer a heat-sensitive coating including a compound capable of converting light to heat and a compound, which becomes more hydrophilic under the action of heat; (2) imagewise exposing the imaging heat-sensitive composition with a high intensity laser emitting a laser beam with an intensity at the surface of the heat-sensitive composition of tat least 2 mW/&mgr;m2 thereby at least partially removing the heat-sensitive composition to expose at least partially the lithographic support.

Abstract: According to the present invention there is provided a method for the preparation of a lithographic printing plate comprising the steps of exposing with IR light an imaging element comprising on a lithographic base with a hydrophilic surface a first layer including a polymer, soluble in an aqueous alkaline solution and a top layer on the same side of the lithographic base as the first layer which top layer is IR-sensitive and unpenetratable for or insoluble in an alkaline developer wherein said first layer and said top layer may be one and the same layer, said imaging element comprising a siloxane surfactant; developing said exposed imaging element with an alkaline solution; gumming said developed imaging element with a baking gum solution; subjecting said gummed imaging element to a thermal treatment at a temperature above 50° C.

Abstract: According to the present invention there is provided a heat mode imaging element for making a lithographic printing plate having on a lithographic base with a hydrophilic surface a first layer including a polymer soluble in an aqueous alkaline solution, and a top layer on the same side of the lithographic base as the first layer that is IR-sensitive and unpenetrable for an aqueous alkaline developer wherein said first layer and said top layer may be one and the same layer; characterized in that the surface of said element upon exposure and treatment with an aqueous alkaline developer is such that a) the contact angle between the unexposed areas of the imaging element and the aqueous alkaline developer changes for at most 6° during the first minute of contact with said developer; b) the contact angle between the exposed areas of the imaging element and the aqueous alkaline developer changes more than 15° during the first minute of contact with said developer; c) the difference in contact angle betwe

Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.

Abstract: A planographic printing original plate which comprises an intermediate layer which contains a polymer including, as a monomer unit, at least a monomer having an acid group and a monomer having an onium group; and a photosensitive layer comprised of a positive-type photosensitive composition for an infrared laser which contains: (A) at least an alkali-soluble polymeric compound; (B) a compound which has a function to deteriorate the solubility of the alkali-soluble polymeric compound in an alkaline aqueous solution due to compatibility with the alkali-soluble polymeric compound, the function being deteriorated by compound (B) being heated; and (C) a compound which generates heat by absorbing light, the intermediate layer and the photosensitive layer being formed sequentially on a support which has been subjected to a hydrophilizing treatment.

Abstract: Multilayer thermographic materials have improved adhesion between a polymeric support and film-forming polymer-containing layers disposed thereon. This improved adhesion is provided by including in the adhesion-promoting layer next to the support two or more polymers having specific properties. At least one of the polymers adheres the layer to the support, and at least one other polymer is compatible or of the same class as the film-forming polymer in the upper layer, such as a thermographic imaging layer. This adhesion-promoting layer can be provided as a very thin “carrier” layer during coating operations so that desired imaging effects and functional properties are obtained.

Abstract: An image-forming system has an image-forming sheet, and a printer for forming an image on the sheet. The sheet has a sheet of paper, and a layer of microcapsule, coated over the paper sheet, that contains a plurality of microcapsules filled with a dye. A shell wall of each microcapsule is composed of a resin exhibiting a pressure/temperature characteristic such that, when each microcapsule is squashed under a predetermined pressure at a predetermined temperature, the dye seeps from the squashed microcapsule. The microcapsules are covered with an infrared absorbent coating that absorbs infrared rays having a specific wavelength. The printer has a transparent glass plate, and a roller platen elastically pressed against the plate at the predetermined pressure, with the sheet being interposed between the plate and the platen.

Abstract: A heat-developable light-sensitive material, which at least contains:

Abstract: A composition used as a resist in the manufacture of electronic parts, for example printed circuits, and which is rendered soluble in a developer by patternwise delivery of heat, comprises a polymer of general formula (I), wherein R1 represents a hydrogen atom or alkyl group, R2 represents a hydrogen atom or alkyl group, R3 represents a hydrogen atom or alkyl group, and R4 represents hydroxyalkyl group, and wherein the ratio n/m is in the range 10/1 to 1/10.

Abstract: Thermographic and photothermographic materials comprise a barrier layer to provide physical protection and to prevent migration of diffusible imaging components and by-products resulting from high temperature imaging and/or development. The barrier layer comprises a film-forming acrylic or methacrylic acid ester or amide polymer(s) that has a molecular weight of at least 8000 g/mole and comprises hydroxy functionality in from about 15 to 100 mole % of the acrylic or methacrylic acid ester or amide recurring units. This barrier layer is capable of retarding diffusion of mobile chemicals such as fatty carboxylic acids, developers, and toners. This barrier layer can also include at least one other film-forming polymer to provide a clear and scratch-resistant surface.

Abstract: A method of producing a lithographic printing plate which comprises subjecting a printing plate precursor comprising a support having a metallic compound layer which has a photo-catalytic property and a hydrophilic surface and bears light-heat convertible minute particles on the surface thereof to imagewise irradiation of heat mode to convert polarity of the metallic compound layer, thereby forming an imagewise hydrophobic region. The lithographic printing plate can be repeatedly employed.

Abstract: An image-forming system has an image-forming sheet, and a printer for forming an image on the sheet. The sheet has a sheet of paper, and a layer of microcapsule, coated over the paper sheet, that contains a plurality of microcapsules filled with a dye. A shell wall of each microcapsule is composed of a resin exhibiting a pressure/temperature characteristic such that, when each microcapsule is squashed under a predetermined pressure at a predetermined temperature, the dye seeps from the squashed microcapsule. The microcapsules are covered with an infrared absorbent coating that absorbs infrared rays having a specific wavelength. The printer has a transparent glass plate, and a roller platen elastically pressed against the plate at the predetermined pressure, with the sheet being interposed between the plate and the platen.

Abstract: A thermal transfer material includes a support. A release layer is overlaid on the support. A coloring transfer layer is overlaid on the release layer, has thermoplasticity, and is colorable by being exposed and then pressurized. In a printer for use with the thermal transfer material, an image is formed by exposing the coloring transfer layer. The coloring transfer layer is placed on image receiving material after the image is formed. The thermal transfer material is heated and pressurized while the coloring transfer layer is placed on, so as to color the image and transfer the coloring transfer layer to the image receiving material.

Abstract: A coated transfer sheet comprising a substrate having a first and second surface; optionally at least one barrier layer overlaying said first surface, at least one release layer overlaying said at least one barrier layer or, when the barrier layer is not present, said first surface of the substrate; and an optional image receiving layer comprising an ethylene acrylic acid co-polymer dispersion; wherein the coated transfer sheet exhibits cold peel and hot peel properties when transferred, and may be used in electrostatic printers and copiers or other devices in which toner particles are imagewise applied to a substrate. The addition of elastomeric polymers and polyurethanes help provide enhanced wash stability and chemical stability.

Abstract: Disclosed are thermal transfer elements and processes for patterning solvent-coated layers and solvent-susceptible layers onto the same receptor substrate. These donor elements and methods are particularly suited for making organic electroluminescent devices and displays. The donor elements can include a substrate, an optional light-to-heat conversion layer, and a single or multicomponent transfer layer that can be imagewise transferred to a receptor to form an organic electroluminescent device, portions thereof, or components therefor. The methods offer advantages over conventional patterning techniques such as photolithography, and make it possible to fabricate new organic electroluminescent device constructions.

Abstract: A lithographic printing plate comprises on a substrate a thermo-deactivatable photosensitive layer that is photohardenable before exposure to an infrared radiation and can be rendered incapable or having reduced rate of photohardening upon exposure to an infrared radiation. Optionally, an oleophobic top layer may be deposited on the photosensitive layer to form a waterless plate. Such a plate can be imagewise exposed with an infrared laser to thermally deactivate the photosensitive layer in the exposed areas, followed by overall actinic light exposure to harden the infrared laser non-exposed areas. The exposed plate can be developed with a suitable developer to remove the infrared laser exposed areas. A plate with an ink and/or fountain solution soluble or dispersible photosensitive layer of this invention can be developed on a printing press with ink and/or fountain solution during initial press operation.

Abstract: A method of making a lithographic printing master is disclosed which comprises the steps of

Abstract: A lithographic printing plate precursor comprises a grained and anodised aluminium substrate which has been treated with a solution of water-soluble salt of a Group IVa metal fluoride and over which is provided a metallic layer, preferably a silver layer. Imagewise exposure of the precursor by means of a high intensity laser beam allows for the direct provision of press ready plates showing high image quality and clean background, good press properties and high durability on press, without the requirement for the use of intermediate film and developer chemistry. The plate precursors show enhanced sensitivity on exposure, whereupon removal of the metallic layer occurs in the exposed areas.

Abstract: Multilayer thermographic materials have improved adhesion between a polymeric support and film-forming polymer-containing layers disposed thereon. This improved adhesion is provided by including in the adhesion-promoting layer next to the support two or more polymers having specific properties. At least one of the polymers adheres the layer to the support, and at least one other polymer is compatible or of the same class as the film-forming polymer in the upper layer, such as a thermographic imaging layer. This adhesion-promoting layer can be provided as a very thin “carrier” layer during coating operations so that desired imaging effects and functional properties are obtained.

Abstract: A laser thermal-transfer to transfer an ink image by being imagewise exposed with a laser beam, comprising: at a support; a photo-thermal conversion layer; and an ink layer having at least one kind of a thermoplastic resin and a pigment, wherein an average transmittance of the ink layer for a light having wavelength of 350 to 650 nm is not more than 70% and L* value of the ink layer is not less than 60.

Abstract: The present invention discloses an imaging element comprising on a hydrophilic surface of a lithographic base an image forming layer comprising hydrophobic thermoplastic polymer particles dispersed in a hydrophilic binder and (ii) a compound capable of converting light to heat, said compound being comprised in said image forming layer or a layer adjacent thereto, characterised in that said image forming layer further comprises a cross-linking agent capable of cross-linking said hydrophilic binder upon heating in a ratio between 1:100 and 200:1 by weight versus the hydrophilic binder. The present invention further provides a method for making a printing plate therewith. According to this method, the above imaging element is preferably exposed by means of a laser and is subsequently developed with plain water or an aqueous liquid.

Abstract: The present invention provides an active primer that includes an electronically active material dispersed in a binder. The active primer can be disposed between a thermal transfer donor sheet and a receptor to assist selective thermal transfer of a material from the donor sheet to the receptor to form at least a portion of an electronic device on the receptor. The binder of the active primer can be selected to improve adhesion of the transferred material to the receptor, or to enhance other transfer properties. The electronically active material of the active primer can be selected to maintain a desired level of functionality in the electronic device being patterned on the receptor.

Abstract: There is described a precursor for preparing a resist pattern, said precursor comprising an imageable layer which includes a relatively volatile compound that can be volatilised by application of heat, wherein imaging radiation can be applied to the precursor to heat areas thereof and volatilise said compound so that properties, for example, the ink accepting abilities of heated and non heated areas, are different.

Abstract: A non-photosensitive core-shell silver salt can be used in thermographic and photothermographic imaging compositions and materials. This core-shell silver salt includes one or more silver salts in the core, at least one of which is different from the one or more silver salts used in the shell. The molar ratio of the different silver salts in the core and shell is from about 0.01:1 to about 100:1.

Abstract: High contrast thermographic and photothermographic materials comprise a barrier layer to prevent migration of diffusible by-products resulting from high temperature development. The barrier layer comprises a film-forming polymer(s) that reacts with or acts as a physical barrier to diffusible by-products resulting from development including formic acid, hydrazo compounds, azo compounds, diimide compounds, hydrazine, and water.

Abstract: Thermographic and photothermographic materials comprise a barrier layer to provide physical protection and to prevent migration of diffusible imaging components and by-products resulting from high temperature development. The barrier layer comprises a film-forming, water-insoluble aromatic polyester that has a molecular weight of at least 10,000 g/mole and is capable of retarding diffusion of mobile chemicals such as fatty acids, developers and toners. This polymer can also be present in admixture with another film-forming polymer to provide a clear and scratch-resistance surface.