Abstract: In the rotary drilling of oil wells a drilling mud is used both to transport the cuttings up to the surface and to impose an hydrostatic pressure on the walls of the borehole. For these functions the mud must for example have an acceptable viscosity and density. It is therefore important to monitor the characteristics of the mud, and to keep them within certain limits. Only recently, however, has drilling practice recognized the importance of monitoring the mud's ionic composition. The various techniques proposed involve separation of the mud into liquid and solid portions, and analysis of these. Though they have proven useful, yet there are a number of problems. For example, the separation has not always been easy, and the available techniques often may not satisfactorily remove the fines.

Abstract: Measuring of soil gas flux. Particularly a method of measuring soil gas concentration and emission flux during a period of post-compression of the earth's crust. The method includes observing gravitational acceleration on the surface of the earth, as defined by crustal tension and compression and as induced by the Sun and Moon, compensating for variation in acceleration due to geographic location of said observing, locating said crustal tension in the form of a bulge on the surface of the earth, then post-compression measuring of soil gas concentration and emission flux rate during both the long term (approximately 1 to 10 days) and short term (approximately 1 to 8 hours) of maximum soil gas emission.

Abstract: A sample of a fuel/oil/additive mixture is metered continuously to a channel-like, inclined test element along which there is an increasing temperature profile. Under the increasing action of heat on the flowing mixture, solid residual products form on the test element after a certain flow distance. Their weight and the flow distance are evaluated in order to evaluate the additive.

Abstract: A simple, on-site, field test method and kit for aromatic contamination in a water sample is provided. In the field test, the water sample is first extracted using an alkyl halide extractant, with a Friedel-Crafts Lewis acid catalyst being added to the resulting extractant phase. A reaction product is thereby produced having a characteristic color indicative of the amount and type of aromatic contamination.

Abstract: The invention in one aspect provides a method of testing drilling mud in use which comprises periodically sampling the circulating mud and analyzing its aqueous filtrate at the rig site by ion chromatography for selected positive and negative ions; one or more other parameters of the sampled mud and/or mud filtrate (e.g. pH, temperature) may also be measured; preferably the composition of the mud filtrate thus monitored is interpreted to indicate downhole interactions, with the composition of the mud supplied to the hole being adjusted to or towards the optimum as drilling proceeds. The invention also provides a method in which the solids of the periodically sampled mud are analyzed at the rig site, e.g. for sorbed ions and/or for cation exchange capacity; the values so obtained are preferably combined with those for the mud filtrate analysis and used in the diagnosis of downhole conditions for adjustment of the composition of freshly supplied mud.

Abstract: The concentration of unspent zinc-based hydrogen sulfide scavenger in an oil-based drilling fluid is controlled by selectively dissolving and extracting the unspent scavenger in a solvent, such as glacial acetic acid, separating the aqueous solution, measuring the concentration of dissolved zinc in the aqueous solution, for example, with an X-ray fluorescence spectrograph, and utilizing the results of the measurements to proportion the extent of changes in concentration of the scavenger in the drilling fluid.

Abstract: A continuous gas/steam ratio monitor is disclosed for use with a geothermal fluid source. A sample of the geothermal well steam flow is mechanically separated to eliminate condensate and treated with sulfuric acid to a pH between 3.0 and 5.0 to prevent H.sub.2 S and CO.sub.2 from dissolving into solution. Discharge of the steam occurs to a separating reservoir and then to a vertical condenser column having a lower condensate pool and an upper gas discharge outlet. The vertical condenser at its cooling fluid end is connected to an atmospheric heat exchanger to condense the steam close to the boiling temperature of water at the operating pressure (about 20-25 inches of mercury). Thus the condensate has the maximum tendency to liberate dissolved noncondensible gases. The upper discharge end of the column is cooled by a refrigeration unit and is kept close to the freezing point of water (about 33.degree. F.). Thus, most of the water vapor mixed in the gas is removed.

Abstract: The concentration of unspent zinc-based hydrogen sulfide scavenger in an aqueous drilling fluid is controlled by selectively extracting an unspent scavenger in a solvent, such as glacial acetic acid, measuring the concentration of dissolved zinc, for example, with an X-ray fluorescence spectrograph, and utilizing the results of the measurements to proportion the extent of changes to be made in the concentration of the scavenger.

Abstract: The invention relates to a method for indicating the presence of concealed minerals and/or deposits in prospecting or exploration operations. A flow of ascending free geogas is analyzed with respect to its content of entrained substances of exploration interest. The gas is suitably sampled at locations beneath or above the surface of the ground, and its content of carried substances caused to be released, and then collected and analyzed. The gas may suitably be caused to flow through a device in which solid substances of interest are collected for example by absorbtion and/or adsorbtion techniques. Electrically charged particles can also be collected with the aid of an electric field.

Abstract: An apparatus and method for detecting and mapping volatile species emanating from an underground source. A mass spectrometer is used for species identification and multivariate statistics are employed to determine the character of the source. The character is quantitatively defined and the volatile species emanating from unknown areas is compared to a known source.

Abstract: A method and apparatus has been provided to locate a subterranian precious ore and/or sulfide body from which mercury gas is emanating. The apparatus includes an inverted plastic drinking cup from which a mercury-free silver wire is suspended from its end. This is accomplished by inserting the end of the wire into a foam insulation disk located in the bottom of the inverted cup. Alternatively, wire may be attached within a cap of a storage vial. The cap has an adhesive on the outer surface which adheres it to the bottom of the cup, whereupon the vial is removed from the cap to expose the wire. A foil disk is placed on the outside of the bottom of the cup. A plurality of cups are buried in the ground forming a dead air space around the wire, for a period of weeks wherein any mercury-vapor in the ground in the area of the cup is adsorbed by the wire. These cups are arranged in a predetermined array and are subsequently located by means of a metal detector which can detect the metal foil on the cups.

Abstract: A well logging method is disclosed for identifying the presence of crude petroleum within subsurface earth formations by detecting electron spin resonance signals along a well bore and identifying crude petroleum as the source of those signals by enhancing and/or suppressing the signal by the presence of a chemical. Electron spin resonance signals from crude oil are enhanced by the presence of iodine and suppressed by the presence of ferric chloride.

Abstract: A dye adsorption procedure for determining clay type and amount in subterranean formation. The procedure can be carried out at a well-site, providing rapid, accurate information for treatment of the well penetrating the formation.

Abstract: A gaseous stream of steam is analyzed for hydrogen sulfide by keeping the gas stream above its dew point while withdrawing a representative sample, mixing the sample with a gas having a dew point lower than that of the gaseous stream to form a mixture with a dew point below that of the gaseous stream, and analyzing the mixture at a temperature above its dew point for hydrogen sulfide.

Abstract: A method of subterranean exploration which comprises locating areas of anomalously high concentrations of helium indicative of geothermal reservoirs, geopressurized zones, petroleum reservoirs and radioactive ore deposits. Also disclosed is a method of producing helium which comprises collecting gases from a geothermal source and separating helium from such gases.

Abstract: The concentration of unspent zinc-based hydrogen sulfide scavenger in an aqueous drilling fluid is controlled by selectively extracting the unspent scavenger in a solvent, such as glacial acetic acid, measuring the concentration of dissolved zinc, for example, with an X-ray fluorescence spectrograph, and utilizing the results of the measurements to proportion the extent of changes to be made in the concentration of the scavenger.