Silicide Formation Patents (Class 438/630)
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Patent number: 7754600Abstract: Various embodiments of the present invention are directed to methods of forming nanostructures on non-single crystal substrates, and resulting nanostructures and nanoscale functional devices. In one embodiment of the present invention, a method of forming nanostructures includes forming a multi-layer structure comprising a metallic layer and a silicon layer. The multi-layer structure is subjected to a thermal process to form metal-silicide crystallites. The nanostructures are grown on the metal-silicide crystallites. In another embodiment of the present invention, a structure includes a non-single-crystal substrate and a layer formed over the non-single-crystal substrate. The layer includes metal-silicide crystallites. A number of nanostructures may be formed on the metal-silicide crystallites. The disclosed structures may be used to form a number of different types of functional devices for use in electronics and/or optoelectronics devices.Type: GrantFiled: March 1, 2007Date of Patent: July 13, 2010Assignee: Hewlett-Packard Development Company, L.P.Inventors: Nobuhiko Kobayashi, Shih-Yuan Wang
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Patent number: 7723231Abstract: A semiconductor device including silicide layers with different thicknesses corresponding to diffusion layer junction depths, and a method of fabricating the same are provided. According to one aspect, there is provided a semiconductor device comprising a first semiconductor element device and a second semiconductor element device, wherein the first semiconductor element device includes a first gate electrode, first diffusion layers disposed to sandwich the first gate electrode, and having a first junction depth, and a first silicide layer disposed in the first diffusion layers and having a first thickness, and the second semiconductor element device includes a second gate electrode, second diffusion layers disposed to sandwich the second gate electrode, and having a second junction depth greater than the first junction depth, and a second silicide layer disposed in the second diffusion layers and having a second thickness greater than the first thickness.Type: GrantFiled: August 14, 2007Date of Patent: May 25, 2010Assignee: Kabushiki Kaisha ToshibaInventor: Hironobu Fukui
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Patent number: 7709369Abstract: A method for forming a contact in a semiconductor device includes opening a contact hole exposing a surface of a substrate, performing a first post treatment to form a rough portion at a bottom surface of the contact hole, and performing a second post treatment. The first post treatment includes using a fluorocarbon gas and the second post treatment includes using a nitrogen trifluoride (NF3) gas.Type: GrantFiled: February 26, 2007Date of Patent: May 4, 2010Assignee: Hynix Semiconductor Inc.Inventors: Jung-Seock Lee, Ky-Hyun Han
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Patent number: 7709372Abstract: A method of manufacturing a metal wiring in a semiconductor device includes: forming a via hole by selectively etching an interlayer insulating layer formed on a first metal layer; sequentially forming a first barrier metal layer and a second metal layer on the interlayer insulating layer; etching the first barrier metal layer and the second metal layer in the via hole to a predetermined depth together with selectively etching a surface of the second metal layer; forming a silicon layer on the first barrier metal and the second metal to a predetermined height; forming a second barrier metal layer on the interlayer insulating layer; forming a third metal layer on the second barrier metal layer; and forming a second barrier metal pattern and a third metal layer pattern by patterning the second barrier metal layer and the third metal layer.Type: GrantFiled: December 19, 2006Date of Patent: May 4, 2010Assignee: Dongbu Electronics Co., Ltd.Inventor: Keun Soo Park
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Patent number: 7692303Abstract: A semiconductor device includes: a P-type semiconductor layer formed in a surface region of a semiconductor substrate; a first gate insulating film formed on the P-type semiconductor layer; a first gate electrode; and a first source region and a first drain region formed in the P-type semiconductor layer to interpose a region under the first gate electrode in a direction of gate length. The first gate electrode includes: a first silicide film formed on the first gate insulating film and containing nickel silicide having a first composition ratio of nickel to silicon as a main component; a conductive film formed on the first silicide film; and a second silicide film formed on the conductive film and containing nickel silicide having a second composition ratio of nickel to silicon as a main component. The second composition ratio is larger than the first composition ratio.Type: GrantFiled: May 24, 2007Date of Patent: April 6, 2010Assignee: Kabushiki Kaisha ToshibaInventor: Takeshi Watanabe
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Patent number: 7662707Abstract: Methods of forming metal silicide layers in a semiconductor device are provided in which a first metal silicide layer may be formed on a substrate, where the first metal silicide layer comprises a plurality of fragments of a metal silicide that are separated by one or more gaps. A conductive material is selectively deposited into at least some of the gaps in the first metal silicide layer in order to electrically connect at least some of the plurality of fragments.Type: GrantFiled: October 11, 2005Date of Patent: February 16, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Sug-Woo Jung, Gil-Heyun Choi, Jong-Ho Yun, Hyun-Su Kim, Eun-Ji Jung
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Patent number: 7659160Abstract: The present invention relates to an field effect transistor (FET) comprising an inverted source/drain metallic contact that has a lower portion located in a first, lower dielectric layer and an upper portion located in a second, upper dielectric layer. The lower portion of the inverted source/drain metallic contact has a larger cross-sectional area than the upper portion. Preferably, the lower portion of the inverted source/drain metallic contact has a cross-sectional area ranging from about 0.03 ?m2 to about 3.15 ?m2, and such an inverted source/drain metallic contact is spaced apart from a gate electrode of the FET by a distance ranging from about 0.001 ?m to about 5 ?m.Type: GrantFiled: October 24, 2007Date of Patent: February 9, 2010Assignee: International Business Machines CorporationInventors: Michael P. Belyansky, Dureseti Chidambarrao, Lawrence A. Clevenger, Kaushik A. Kumar, Carl Radens
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Patent number: 7655557Abstract: The present invention provides a complementary metal oxide semiconductor integration process whereby a plurality of silicided metal gates are fabricated atop a gate dielectric. Each silicided metal gate that is formed using the integration scheme of the present invention has the same silicide metal phase and substantially the same height, regardless of the dimension of the silicide metal gate. The present invention also provides various methods of forming a CMOS structure having silicided contacts in which the polySi gate heights are substantially the same across the entire surface of a semiconductor structure.Type: GrantFiled: June 24, 2008Date of Patent: February 2, 2010Assignee: International Business Machines CorporationInventors: Ricky S. Amos, Diane C. Boyd, Cyril Cabral, Jr., Richard D. Kaplan, Jakub T. Kedzierski, Victor Ku, Woo-Hyeong Lee, Ying Li, Anda C. Mocuta, Vijay Narayanan, An L. Steegen, Maheswaren Surendra
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Patent number: 7655556Abstract: A cap layer for a copper interconnect structure formed in a first dielectric layer is provided. In an embodiment, the cap layer may be formed by an in-situ deposition process in which a process gas comprising germanium, arsenic, tungsten, or gallium is introduced, thereby forming a copper-metal cap layer. In another embodiment, a copper-metal silicide cap is provided. In this embodiment, silane is introduced before, during, or after a process gas is introduced, the process gas comprising germanium, arsenic, tungsten, or gallium. Thereafter, an optional etch stop layer may be formed, and a second dielectric layer may be formed over the etch stop layer or the first dielectric layer.Type: GrantFiled: April 23, 2007Date of Patent: February 2, 2010Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Hui-Lin Chang, Hung Chun Tsai, Yung-Cheng Lu, Syun-Ming Jang
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Patent number: 7655525Abstract: A semiconductor device that prevents gate spacer stress and physical and chemical damages on a silicide region, and a method of manufacturing the same, according to an exemplary embodiment of the present invention, includes a substrate, isolation regions formed in the substrate, a gate pattern formed between the isolation regions on the substrate, an L-type spacer adjacent to the sidewall of the gate pattern and extended to the surface of the substrate, source/drain silicide regions formed on the substrate between the end of the L-type spacer extended to the surface of the substrate and the isolation regions, via plugs electrically connected with the source/drain silicide regions, an interlayer dielectric layer which is adjacent to the L-type spacer and which fills the space between the via plugs layer formed on the gate pattern and the substrate, and a signal-transfer line formed on the interlayer dielectric layer.Type: GrantFiled: August 31, 2007Date of Patent: February 2, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Sun-jung Lee, Hong-jae Shin, Bong-seok Suh
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Patent number: 7648871Abstract: The present invention relates to an field effect transistor (FET) comprising an inverted source/drain metallic contact that has a lower portion located in a first, lower dielectric layer and an upper portion located in a second, upper dielectric layer. The lower portion of the inverted source/drain metallic contact has a larger cross-sectional area than the upper portion. Preferably, the lower portion of the inverted source/drain metallic contact has a cross-sectional area ranging from about 0.03 ?m2 to about 3.15 ?m2, and such an inverted source/drain metallic contact is spaced apart from a gate electrode of the FET by a distance ranging from about 0.001 ?m to about 5 ?m.Type: GrantFiled: October 21, 2005Date of Patent: January 19, 2010Assignee: International Business Machines CorporationInventors: Michael P. Belyansky, Dureseti Chidambarrao, Lawrence A. Clevenger, Kaushik A. Kumar, Carl Radens
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Patent number: 7638428Abstract: A method of forming a semiconductor structure comprises providing a semiconductor substrate comprising a layer of a dielectric material. A recess is provided in the layer of dielectric material. The recess is filled with a material comprising silver.Type: GrantFiled: July 11, 2007Date of Patent: December 29, 2009Assignee: GlobalFoundries, Inc.Inventors: Christof Streck, Volker Kahlert
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Publication number: 20090317973Abstract: Electronic devices and design structures of electronic devices containing metal silicide layers. The devices include: a thin silicide layer between two dielectric layers, at least one metal wire abutting a less than whole region of the silicide layer and in electrical contact with the silicide layer.Type: ApplicationFiled: June 20, 2008Publication date: December 24, 2009Inventors: Felix Patrick Anderson, Zhong-Xiang He, Thomas Leddy McDevitt, Eric Jeffrey White
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Publication number: 20090317972Abstract: Methods of forming metal silicide layers. The methods include: forming a silicon-rich layer between dielectric layers; contacting the silicon-rich layer with a metal layer and heating the silicon rich-layer and the metal layer to diffuse metal atoms from the metal layer into the silicon layer to form a metal silicide layer.Type: ApplicationFiled: June 20, 2008Publication date: December 24, 2009Inventors: Felix Patrick Anderson, Zhong-Xiang He, Thomas Leddy McDevin, Eric Jeffrey White
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Patent number: 7632744Abstract: Formation of an WNx film 24 constituting a barrier layer of a gate electrode 7A having a polymetal structure is effected in an atmosphere containing a high concentration nitrogen gas, whereby release of N (nitrogen) from the WNx film 24 is suppressed in the heat treatment step after the formation of the gate electrode 7A.Type: GrantFiled: April 14, 2008Date of Patent: December 15, 2009Assignee: Renesas Technology Corp.Inventors: Naoki Yamamoto, Yoshikazu Tanabe, Hiroshige Kogayu, Takehiko Yoshida
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Patent number: 7625819Abstract: An interconnection process is provided. The process includes the following steps. Firstly, a semiconductor base having at least a electrical conductive region is provided. Next, a dielectric layer with a contact hole is formed to cover the semiconductor base, wherein the contact hole exposes part of the electrical conductive region. Then, a thermal process is performed on the semiconductor base covered with the dielectric layer. Lastly, a conductive layer is formed on the dielectric layer, wherein the conductive layer is electrically connected to the electrical conductive region through the contact hole.Type: GrantFiled: June 1, 2007Date of Patent: December 1, 2009Assignee: Macronix International Co., Ltd.Inventors: Tuung Luoh, Ling-Wu Yang, Chin-Ta Su, Ta-Hung Yang, Kuang-Chao Chen
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Patent number: 7622381Abstract: The present invention provides a semiconductor structure and the forming method thereof. The structure includes a substrate having a plurality of stacks; a conformal layer on the substrate and a portion of sidewalls of the plurality of the stacks; and a plurality of plugs between the plurality of stacks. In addition, the present invention also provides a method of forming the semiconductor structure, comprising steps of providing a substrate; forming a plurality of stacks on the substrate; forming a conformal layer on the stacks and on the substrate; removing a portion of the conformal layer to expose a sidewall and a top surface of the plurality of stacks; and forming a plurality of plugs between the stacks.Type: GrantFiled: July 27, 2007Date of Patent: November 24, 2009Assignee: Nanya Technology Corp.Inventors: Jar-Ming Ho, Shian-Jyh Lin, Ming-Yuan Huang
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Patent number: 7622386Abstract: A method of forming silicide contacts for semiconductor devices includes subjecting a silicon containing semiconductor wafer to a degas treatment at an initial degas temperature of about 250 to about 400° C., transferring the semiconductor wafer from a degas chamber to a deposition chamber, depositing a nickel containing layer over the wafer following transfer of the wafer from the degas chamber to the deposition chamber, and annealing the semiconductor wafer so as to create silicide regions at portions on the wafer where nickel material is formed over silicon.Type: GrantFiled: December 6, 2006Date of Patent: November 24, 2009Assignees: International Business Machines Corporation, Samsung Electronics Co., Ltd.Inventors: Anita Madan, Robert J. Purtell, Keith Kwong Hon Wong, Jun-Keun Kwak
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Patent number: 7601634Abstract: A region is locally modified so as to create a zone that extends as far as at least part of the surface of the region and is formed from a material that can be removed selectively with respect to the material of the region. The region is then covered with an insulating material. An orifice is formed in the insulating material emerging at the surface of the zone. The selectively removable material is removed from the zone through the orifice so as to form a cavity in place of the zone. The cavity and the orifice are then filled with at least one electrically conducting material so as to form a contact pad.Type: GrantFiled: October 14, 2005Date of Patent: October 13, 2009Assignees: STMicroelectronics (Crolles 2) SAS, STMicroelectronics S.A.Inventors: Damien Lenoble, Philippe Coronel, Robin Cerutti
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Patent number: 7579231Abstract: Disclosed is a method of manufacturing a semiconductor device, comprising forming a metal compound film directly or indirectly on a semiconductor substrate, forming a metal-containing insulating film consisting of a metal oxide film or a metal silicate film by oxidizing the metal compound film, and forming an electrode on the metal-containing insulating film.Type: GrantFiled: April 2, 2004Date of Patent: August 25, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Kouji Matsuo, Tomohiro Saito, Kyoichi Suguro, Shinichi Nakamura
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Patent number: 7560379Abstract: In one aspect, the invention provides a method of fabricating a semiconductive device 200 that comprises forming a raised layer [510] adjacent a gate [340] and over a source/drain [415], depositing a silicidation layer [915] over the gate [340] and the raised layer [510], and moving at least a portion of the silicidation layer [915] into the source/drain [415] through the raised layer [510].Type: GrantFiled: February 7, 2006Date of Patent: July 14, 2009Assignee: Texas Instruments IncorporatedInventors: Puneet Kohli, Manfred B. Ramin
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Patent number: 7557032Abstract: Methods and structures are provided for full silicidation of recessed silicon. Silicon is provided within a trench. A mixture of metals is provided over the silicon in which one of the metals diffuses more readily in silicon than silicon does in the metal, and another of the metals diffuses less readily in silicon than silicon does in the metal. An exemplary mixture includes 80% nickel and 20% cobalt. The silicon within the trench is allowed to fully silicide without void formation, despite a relatively high aspect ratio for the trench. Among other devices, recessed access devices (RADs) can be formed by the method for memory arrays.Type: GrantFiled: September 1, 2005Date of Patent: July 7, 2009Assignee: Micron Technology, Inc.Inventors: Hasan Nejad, Thomas A. Figura, Gordon A. Haller, Ravi Iyer, John Mark Meldrim, Justin Harnish
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Patent number: 7553729Abstract: A method of manufacturing a non-volatile memory device includes the steps of forming gates respectively having a structure in which a gate insulating layer, a first conductive layer, a dielectric layer, a second conductive layer and a metal-silicide layer are laminated over a semiconductor substrate, annealing the metal-silicide layer at a temperature, which is the same as or lower than an annealing temperature of the dielectric layer, forming a buffer oxide layer on the entire surface, and forming a nitride layer on the buffer oxide layer.Type: GrantFiled: December 28, 2006Date of Patent: June 30, 2009Assignee: Hynix Semiconductor Inc.Inventor: Won Yeol Choi
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Patent number: 7550372Abstract: A method of fabricating conductive lines is described. A substrate having a polysilicon layer thereon is provided. A mask layer having an opening that exposes the polysilicon layer is formed on the polysilicon layer. Then, spacers are formed on the sidewalls of the mask layer. Using the mask layer and the spacers as a mask, a portion of the polysilicon layer is removed until the substrate is exposed. After that, an insulating layer that completely fills the opening is formed over the substrate. The insulating layer has an etching selectivity different from the mask layer. Thereafter, the mask layer is removed to expose the polysilicon layer and then a metal silicide layer is formed on the upper surface of the polysilicon layer.Type: GrantFiled: August 29, 2005Date of Patent: June 23, 2009Assignee: Powerchip Semiconductor Corp.Inventors: Su-Yuan Chang, Min-San Huang, Hann-Jye Hsu
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Patent number: 7544616Abstract: A method of forming word lines of a memory includes providing a substrate and forming a conductive layer on the substrate. A metal silicide layer is formed on the conductive layer, and a mask pattern is formed on the metal silicide layer. A mask liner covering the mask pattern and the surface of the metal silicide layer is formed on the substrate to shorten distances between the word line regions. An etching process is performed on the mask liner and the mask pattern until the partial surface of the metal silicide layer is exposed. The metal silicide layer and the conductive layer are etched to form word lines by utilizing the mask liner and the mask pattern as a mask. A silicon content of the metal silicide layer must be less than or equal to 2 for reducing a bridge failure rate between the word lines.Type: GrantFiled: October 17, 2007Date of Patent: June 9, 2009Assignee: MACRONIX International Co., Ltd.Inventors: Chi-Pin Lu, Ling-Wu Yang
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Patent number: 7534732Abstract: Cu interconnects are formed with composite capping layers for reduced electromigration, improved adhesion between Cu and the capping layer, and reduced charge loss in associated non-volatile transistors. Embodiments include depositing a first relatively thin silicon nitride layer having a relatively high concentration of Si—H bonds on the upper surface of a layer of Cu for improved adhesion and reduced electromigration, and depositing a second relatively thick silicon nitride layer having a relatively low concentration of Si—H bonds on the first silicon nitride layer for reduced charge loss.Type: GrantFiled: February 17, 2006Date of Patent: May 19, 2009Assignees: Spansion LLC, Advanced Micro Devices, Inc.Inventors: Minh Van Ngo, Erik Wilson, Hieu Pham, Robert Huertas, Lu You, Hirokazu Tokuno, Alexander Nickel, Minh Tran
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Patent number: 7528070Abstract: A sputtering apparatus for forming a low-resistance uniform metal silicide layer without additional heat treatment and a metal silicide layer forming method using the same are provided. The sputtering apparatus includes a sputtering chamber; a gas introduction port formed at an upper location of a lateral wall of the sputtering chamber; a gas exhaust port formed at a bottom wall of the sputtering chamber; a target located in an upper region of the sputtering chamber; a power source to supply the target with high-frequency electric power; a stage located in a bottom region of the sputtering chamber to heat the semiconductor substrate; and a sieve provided between the target and the semiconductor substrate to improve straightness of charged metal particles.Type: GrantFiled: December 28, 2005Date of Patent: May 5, 2009Assignee: Dongbu Electronics, Co., Ltd.Inventor: Jae Won Han
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Patent number: 7501317Abstract: A junction leak current of a transistor including a silicide layer provided on a source/drain region is to be suppressed. After forming a gate electrode over a chip-side surface of a silicon substrate, an insulating layer is formed over the gate electrode. The insulating layer is etched back so as to form a sidewall that covers the sidewall of the gate electrode, and a region adjacent to the sidewall on the chip-side surface of the silicon substrate, where a source/drain region is to be formed, is etched so as to form a generally horizontal scraped section on the chip-side surface. Then a dopant is implanted to the silicon substrate around the gate electrode, to thereby form the source/drain region. On the chip-side surface of the silicon substrate where the gate electrode is provided, a Ni layer is formed, so that the Ni layer is reacted with the silicon substrate thus to form a Ni-silicide layer.Type: GrantFiled: December 19, 2006Date of Patent: March 10, 2009Assignee: NEC Electronics CorporationInventors: Tomoko Matsuda, Hiroshi Kitajima
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Patent number: 7485572Abstract: A method of forming silicide contacts for semiconductor devices includes subjecting a silicon containing semiconductor wafer to a degas treatment at a temperature of about 400° C., transferring the semiconductor wafer from a degas chamber to a deposition chamber, depositing a cobalt layer over the wafer at a point in time when the semiconductor wafer has cooled to temperature range of about 275-300° C., depositing a cap layer over the cobalt layer, and annealing the semiconductor wafer so as to create silicide contacts at portions on the wafer where cobalt is formed over silicon.Type: GrantFiled: September 25, 2006Date of Patent: February 3, 2009Assignee: International Business Machines CorporationInventors: Anita Madan, Robert J. Purtell, Keith Kwong Hon Wong
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Patent number: 7473975Abstract: A method for forming a semiconductor device structure, comprising the steps of independently forming source/drain surface metal silicide layers and a fully silicided metal gate in a polysilicon gate stack. Specifically, one or more sets of spacer structures are provided along sidewalls of the polysilicon gate stack after formation of the source/drain surface metal silicide layers and before formation of the silicided metal gate, in order to prevent formation of additional metal silicide structures in the source/drain regions during the gate salicidation process. The resulting semiconductor device structure includes a fully silicide metal gate that either comprises a different metal silicide material from that in the source/drain surface metal silicide layers, or has a thickness that is larger than that of the source/drain surface metal silicide layers. The source/drain regions of the semiconductor device structure are devoid of other metal silicide structures besides the surface metal silicide layers.Type: GrantFiled: August 17, 2007Date of Patent: January 6, 2009Assignee: International Business Machines CorporationInventors: Glenn A. Biery, Ghavam Shahidi, Michelle L. Steen
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Patent number: 7456095Abstract: A method and apparatus are provided in which non-directional and directional metal (e.g. Ni) deposition steps are performed in the same process chamber. A first plasma is formed for removing material from a target; a secondary plasma for increasing ion density in the material is formed in the interior of an annular electrode (e.g. a Ni ring) connected to an RF generator. Material is deposited non-directionally on the substrate in the absence of the secondary plasma and electrical biasing of the substrate, and deposited directionally when the secondary plasma is present and the substrate is electrically biased. Nickel silicide formed from the deposited metal has a lower gate polysilicon sheet resistance and may have a lower density of pipe defects than NiSi formed from metal deposited in a solely directional process, and has a lower source/drain contact resistance than NiSi formed from metal deposited in a solely non-directional process.Type: GrantFiled: October 3, 2005Date of Patent: November 25, 2008Assignee: International Business Machines CorporationInventors: Keith Kwong Hon Wong, Robert J. Purtell
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Patent number: 7456096Abstract: It is made possible to reduce the interface resistance at the interface between the nickel silicide film and the silicon. A semiconductor manufacturing method includes: forming an impurity region on a silicon substrate, with impurities being introduced into the impurity region; depositing a Ni layer so as to cover the impurity region; changing the surface of the impurity region into a NiSi2 layer through annealing; forming a Ni layer on the NiSi2 layer; and silicidating the NiSi2 layer through annealing.Type: GrantFiled: September 11, 2006Date of Patent: November 25, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Takashi Yamauchi, Atsuhiro Kinoshita, Yoshinori Tsuchiya, Junji Koga, Koichi Kato, Nobutoshi Aoki, Kazuya Ohuchi
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Patent number: 7449410Abstract: The invention included to methods of forming CoSi2, methods of forming field effect transistors, and methods of forming conductive contacts. In one implementation, a method of forming CoSi2 includes forming a substantially amorphous layer comprising MSix over a silicon-containing substrate, where “M” comprises at least some metal other than cobalt. A layer comprising cobalt is deposited over the substantially amorphous MSix-comprising layer. The substrate is annealed effective to diffuse cobalt of the cobalt-comprising layer through the substantially amorphous MSix-comprising layer and combine with silicon of the silicon-containing substrate to form CoSi2 beneath the substantially amorphous MSix-comprising layer. Other aspects and implementations are contemplated.Type: GrantFiled: August 2, 2005Date of Patent: November 11, 2008Assignee: Micron Technology, Inc.Inventor: Yongjun Jeff Hu
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Patent number: 7432181Abstract: A method of forming self-aligned silicides is described and applied to a substrate having an isolation area, which divides the substrate into a first area and a second area. A resist protective oxide layer is formed on the substrate, and subsequently a mask layer is formed on the resist protective oxide layer. Further, the mask layer includes an opening on the first area and another opening on a contact hole of the second area. When a resist protective oxide process is performed, the mask layer protects the resist protective oxide layer underlying the same from being removed, whereas the resist protective oxide layer under the openings are removed. Therefore, silicides are controlled to form on the first area and the contact hole of the second area in a subsequent self-aligned silicidation process.Type: GrantFiled: December 7, 2004Date of Patent: October 7, 2008Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Yei-Hsiung Lin, Steven Huang
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Patent number: 7425482Abstract: A non-volatile memory device and a method for fabricating the same are provided. The method includes: forming a plurality of gate structures on a substrate, each gate structure including a first electrode layer for a floating gate; forming a first insulation layer covering the gate structures and active regions located at each side of the gate structures; forming a second electrode layer over the first insulation layer; and forming a plurality of control gates on the active regions located at each side of the gate structures by performing an etch-back process to the second electrode layer.Type: GrantFiled: October 12, 2005Date of Patent: September 16, 2008Assignee: Magna-Chip Semiconductor, Ltd.Inventor: Yong-Sik Jeong
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Patent number: 7422942Abstract: A semiconductor device having a self-aligned contact hole is formed by providing a side wall oxide film on a gate electrode, covering the gate electrode and the side wall oxide film by an oxide film and further covering the oxide film by a nitride film, wherein the oxide film is formed by a plasma CVD process with a reduced plasma power such that the H2O content in the oxide film is less than about 2.4 wt %.Type: GrantFiled: May 14, 2007Date of Patent: September 9, 2008Assignee: Fujitsu LimitedInventors: Kousuke Suzuki, Katsuyuki Karakawa
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Patent number: 7407880Abstract: A semiconductor device which can prevent a leak current between a silicide layer on a polysilicon and another part, as well as a manufacturing process therefor. The semiconductor device includes neighboring n- and p-type polysilicons; and a silicide layer thereon extending from the n-type polysilicon to the p-type polysilicon. The silicide layer is formed over the upper surfaces of the n- and p-type polysilicons except the periphery thereof.Type: GrantFiled: December 3, 2004Date of Patent: August 5, 2008Assignee: NEC Electronics CorporationInventor: Katsuya Izumi
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Patent number: 7405112Abstract: A low contact resistance CMOS integrated circuit and method for its fabrication are provided. The CMOS integrated circuit comprises a first transition metal electrically coupled to the N-type circuit regions and a second transition metal different than the first transition metal electrically coupled to the P-type circuit regions. A conductive barrier layer overlies each of the first transition metal and the second transition metal and a plug metal overlies the conductive barrier layer.Type: GrantFiled: June 15, 2006Date of Patent: July 29, 2008Assignee: Advanced Micro Devices, Inc.Inventor: Paul R. Besser
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Patent number: 7405154Abstract: A contact metallurgy structure comprising a patterned dielectric layer having cavities on a substrate; a silicide or germanide layer such as of cobalt and/or nickel located at the bottom of cavities; a contact layer comprising Ti or Ti/TiN located on top of the dielectric layer and inside the cavities and making contact to the silicide or germanide layer on the bottom; a diffusion barrier layer located on top of the contact layer and inside the cavities; optionally a seed layer for plating located on top of the barrier layer; a metal fill layer in vias is provided along with a method of fabrication. The metal fill layer is electrodeposited with at least one member selected from the group consisting of copper, rhodium, ruthenium, iridium, molybdenum, gold, silver, nickel, cobalt, silver, gold, cadmium and zinc and alloys thereof. When the metal fill layer is rhodium, ruthenium, or iridium, an effective diffusion barrier layer is not required between the fill metal and the dielectric.Type: GrantFiled: March 24, 2006Date of Patent: July 29, 2008Assignee: International Business Machines CorporationInventors: Cyril Cabral, Jr., Hariklia Deligianni, Randolph F. Knarr, Sandra G. Malhotra, Stephen Rossnagel, Xiaoyan Shao, Anna Topol, Philippe M. Vereecken
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Patent number: 7396570Abstract: Chemical vapor deposition methods of forming titanium silicide including layers on substrates are disclosed. TiCl4 and at least one silane are first fed to the chamber at or above a first volumetric ratio of TiCl4 to silane for a first period of time. The ratio is sufficiently high to avoid measurable deposition of titanium silicide on the substrate. Alternately, no measurable silane is fed to the chamber for a first period of time. Regardless, after the first period, TiCl4 and at least one silane are fed to the chamber at or below a second volumetric ratio of TiCl4 to silane for a second period of time. If at least one silane was fed during the first period of time, the second volumetric ratio is lower than the first volumetric ratio. Regardless, the second feeding is effective to plasma enhance chemical vapor deposit a titanium silicide including layer on the substrate.Type: GrantFiled: March 30, 2006Date of Patent: July 8, 2008Assignee: Micron Technology, Inc.Inventors: Cem Basceri, Irina Vasilyeva, Ammar Derraa, Philip H. Campbell, Gurtej S. Sandhu
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Patent number: 7396764Abstract: The technology which can improve the performance of a MOS transistor in which all the regions of the gate electrode were silicided is offered. A gate insulating film and a gate electrode of an nMOS transistor are laminated and formed in this order on a semiconductor substrate. A source/drain region of the nMOS transistor is formed in the upper surface of the semiconductor substrate. The source/drain region is silicided after siliciding all the regions of the gate electrode. Thus, silicide does not cohere in the source/drain region by the heat treatment at the silicidation of the gate electrode by siliciding the source/drain region after the silicidation of the gate electrode. Therefore, the electric resistance of the source/drain region is reduced and junction leak can be reduced. As a result, the performance of the nMOS transistor improves.Type: GrantFiled: May 4, 2006Date of Patent: July 8, 2008Assignee: Renesas Technology Corp.Inventor: Shigeki Komori
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Patent number: 7378344Abstract: A method for manufacturing a MOSFET equipped with a silicide layer over shallow source and drain junctions without leakage generation is provided. By restricting the temperature of manufacturing steps after the silicide formation below a critical temperature Tc, which is defined below as a function of a junction depth Dj from 20 nm to 60 nm, leakage generation is practically suppressed. Tc = a × Dj + b , ? where a = 6.11 ? ( 20 < Dj ? 26 ) = 1.60 ? ( 26 < Dj ? 60 ) , ? b = 290.74 ? ( 20 < Dj ? 26 ) = 408 ? ( 26 < Dj ? 60 ) , Dj is a junction depth (nm) measured from the lower surface of the silicide layer, and Tc is a critical temperature (° C.) during a heat treatment.Type: GrantFiled: August 21, 2006Date of Patent: May 27, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Masakatsu Tsuchiaki, Shoko Tomita
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Patent number: 7375013Abstract: Formation of an WNX film 24 constituting a barrier layer of a gate electrode 7A having a polymetal structure is effected in an atmosphere containing a high concentration nitrogen gas, whereby release of N (nitrogen) from the WNX film 24 is suppressed in the heat treatment step after the formation of the gate electrode 7A.Type: GrantFiled: April 3, 2006Date of Patent: May 20, 2008Assignee: Renesas Technology Corp.Inventors: Naoki Yamamoto, Yoshikazu Tanabe, Hiroshige Kogayu, Takehiko Yoshida
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Patent number: 7375025Abstract: On first and second regions of a substrate are formed a first gate structure including a first gate electrode and a first spacer, and a second gate structure including a second gate electrode and a second spacer, respectively. The first and second spacers are removed to different depths such that side portions of the first and second gate electrodes have different exposed thicknesses. A metal silicide layer is formed on the first and second regions including the first and second gate structures. The metal silicide layer formed on the second gate electrode has a second thickness that is greater than a first thickness of the metal silicide layer formed on the first gate electrode. The spacers in the gate structures of resulting N type and P type MOS transistors are removed to different thicknesses, thereby minimizing deformation in the gate structures and also improving electrical characteristics and thermal stability of the gate electrodes.Type: GrantFiled: November 16, 2005Date of Patent: May 20, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Eung-Joon Lee, In-Sun Park, Kwan-Jong Roh
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Patent number: 7361597Abstract: A semiconductor device incorporating an alloy layer formed on a substrate; a gate electrode, a source electrode, and a drain electrode formed on the alloy layer at predetermined intervals therebetween; a gate insulating layer formed on the gate electrode in a gate electrode region; a first conductive layer formed on the substrate, including the source electrode and the drain electrode; and a second conductive layer and a metal silicide layer sequentially stacked on the first conductive layer and gate insulating layer.Type: GrantFiled: June 23, 2006Date of Patent: April 22, 2008Assignee: Dongbu Hitek Co., Ltd.Inventor: Sang Hyun Ban
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Patent number: 7354854Abstract: Nickel silicide contact regions are formed on a source (2), drain (3) and polycrystalline silicon gate (5) of an integrated circuit transistor by annealing it after a nickel layer has been deposited on the source, drain, and gate, with no cap layer on the nickel layer. Nickel silicide bridging between the gate and source and/or drain is avoided or eliminated by using a chrome etching process to remove un-reacted nickel and nickel remnants from exposed surfaces of dielectric spacers (6A,B) located between the gate and source and between the gate and drain. The chrome etching process includes use of a solution including cerric ammonium nitrate, nitric acid, and acetic acid.Type: GrantFiled: May 24, 2005Date of Patent: April 8, 2008Assignee: Texas Instruments IncorporatedInventor: Rajneesh Jaiswal
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Patent number: 7348265Abstract: The present invention provides a semiconductor device, a method of manufacture therefor, and an integrated circuit including the semiconductor device. The semiconductor device (100), among other possible elements, includes a gate oxide (140) located over a substrate (110), and a silicided gate electrode (150) located over the gate oxide (140), wherein the silicided gate electrode (150) includes a first metal and a second metal.Type: GrantFiled: March 1, 2004Date of Patent: March 25, 2008Assignee: Texas Instruments IncorporatedInventor: Jiong-Ping Lu
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Patent number: 7338815Abstract: A semiconductor device manufacturing method, includes a step of forming refractory metal silicide layers 13a to 13c in a partial area of a semiconductor substrate 10, a step of forming an interlayer insulating film 21 on the refractory metal silicide layers 13a to 13c, a step of forming a first conductive film 31, a ferroelectric film 32, and a second conductive film 33 in sequence on the interlayer insulating film 21, a step of forming a capacitor Q consisting of a lower electrode 31a, a capacitor dielectric film 32a, and an upper electrode 33a by patterning the first conductive film 33, the ferroelectric film 32, and the second conductive film 31, and a step of performing an annealing for an annealing time to suppress a agglomeration area of the refractory metal silicide layers 13a to 13c within an upper limit area.Type: GrantFiled: September 27, 2005Date of Patent: March 4, 2008Assignee: Fujitsu LimitedInventors: Yukinobu Hikosaka, Hirotoshi Tachibana
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Patent number: 7326644Abstract: A method of fabricating a semiconductor device, includes (a) forming an oxide film entirely over a silicon substrate on which a MOS transistor is fabricated, (b) carrying out first thermal-annealing to the silicon substrate, (c) removing the oxide film in an area where later mentioned silicide is to be formed, (d) forming a metal film entirely over the silicide substrate, (e) carrying out second thermal-annealing to the silicon substrate to form silicide in the area, and (f) removing the metal film having been not reacted with the silicon substrate.Type: GrantFiled: January 23, 2004Date of Patent: February 5, 2008Assignee: NEC Electronics CorporationInventor: Shinya Ito
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Patent number: 7307017Abstract: Semiconductor devices and methods of fabricating semiconductor devices are disclosed. A disclosed semiconductor device includes a silicon substrate, a source region and a drain region. A gate electrode is formed on the silicon substrate. Also, a metal silicide layer is formed on each of the gate electrode, the source region, and the drain region. The metal silicide layer has a thickness uniformity of about 1˜20%. A disclosed fabrication method includes forming a metal layer on a silicon substrate having a gate electrode, a source region, and a drain region; performing a plasma treatment on the metal layer; forming a protective layer on the metal layer; and heat treating the silicon substrate on which the protective layer is formed to thereby form a metal silicide layer. A gas that includes nitrogen is used as a plasma gas during the plasma treatment.Type: GrantFiled: May 25, 2004Date of Patent: December 11, 2007Assignee: Dongbu Electronics Co., Ltd.Inventors: Han-Choon Lee, Jin-Woo Park