Organic Compound Containing The Heavy Metal Or Aluminum Patents (Class 44/358)
  • Patent number: 11014045
    Abstract: The present invention describes a fluid which is suitable for the decontamination of heat engines which can carry out both, at the same time, the catalytic reduction of oxides of nitrogen (NOx) contained in exhaust gases and assist in the regeneration of the particulate filter (PF). The invention also describes several embodiments of said fluid.
    Type: Grant
    Filed: October 20, 2016
    Date of Patent: May 25, 2021
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Serge Gonzalez, Jacques Vallet, David Pasquier
  • Patent number: 9409861
    Abstract: The present invention provides a photocurable composition prepared using mercapto benzophenone compounds as key raw materials. The present invention aims to solve the problems existing in the prior photo-curing technology that low-molecular photoinitiators are easy to remain and migrate, while macromolecular photoinitiators has low initiation efficiency due to a low content of effective components and also has the problem of certain migration. The photocurable composition in the present invention can be easily prepared and has high addition efficiency with ethylenically unsaturated compounds, and the photocurable composition obtained by addition has no residual mercapto and has features of high initiation activity and zero migration rates when it is used in photocurable coatings, binder and ink formula.
    Type: Grant
    Filed: May 14, 2015
    Date of Patent: August 9, 2016
    Assignee: Insight High Technology (Beijing) Co. Ltd.
    Inventors: Wenchao Zhao, Zhongli Ma, Jiaqi Li, Lixiu Yao, Jue Zhang, Weijing Hu, Jing Li, Yonglin Wang
  • Patent number: 9061979
    Abstract: The present invention provides a photocurable composition prepared using mercapto benzophenone compounds as key raw materials. The present invention aims to solve the problems existing in the prior photo-curing technology that low-molecular photoinitiators are easy to remain and migrate, while macromolecular photoinitiators has low initiation efficiency due to a low content of effective components and also has the problem of certain migration. The photocurable composition in the present invention can be easily prepared and has high addition efficiency with ethylenically unsaturated compounds, and the photocurable composition obtained by addition has no residual mercapto and has features of high initiation activity and zero migration rates when it is used in photocurable coatings, binder and ink formula.
    Type: Grant
    Filed: February 7, 2013
    Date of Patent: June 23, 2015
    Assignee: Insight High Technology (Beijing) Co. Ltd.
    Inventors: Wenchao Zhao, Zhongli Ma, Jiaqi Li, Lixiu Yao, Jue Zhang, Weijing Hu, Jing Li, Yonglin Wang
  • Patent number: 8945244
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: February 3, 2015
    Inventors: Robert W. Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 8870981
    Abstract: An additive composition for a fuel comprises: (i) a metal compound selected from an iron compound, a manganese compound, a calcium compound, a cerium compound and mixtures thereof; (ii) an organic compound selected from a bicyclic monoterpene, substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof; and (iii) a stabilizer. The additive composition allows fuels which are prone to separation, for example blended fuels or fuels having a high content of asphaltenes, to be used successfully.
    Type: Grant
    Filed: November 14, 2012
    Date of Patent: October 28, 2014
    Assignee: Innospec Limited
    Inventors: Miltiades Papachristos, Ian Malcolm McRobbie, Deepak Kamran
  • Patent number: 8852299
    Abstract: There is disclosed a method for combusting a secondary organometallic compound in an engine including (a) combining a secondary organometallic compound and methylcyclopentadienyl manganese tricarbonyl, (b) introducing the combination from (a) into a fuel, and (c) causing the fuel from (b) to be combusted in the engine.
    Type: Grant
    Filed: June 30, 2006
    Date of Patent: October 7, 2014
    Assignee: Afton Chemical Corporation
    Inventor: Allen A. Aradi
  • Patent number: 8852298
    Abstract: There is disclosed a method of reducing the conductivity of deposits formed from the combustion of a fuel comprising an iron-containing compound, said method comprising adding a manganese-containing compound to the fuel.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: October 7, 2014
    Assignee: Afton Chemical Corporation
    Inventors: Lawrence J. Cunningham, Allen A. Aradi
  • Publication number: 20140202069
    Abstract: A fuel additive concentrate comprising at least one aryl amine; and at least one metal-containing compound is disclosed. In an aspect, the fuel additive concentrate can be synergistic. Fuel composition comprising the fuel additive concentration and methods of combusting the fuel composition are also disclosed. Moreover, methods of enhancing research octane number, increasing fuel economy, and reducing the carbon footprint of a vehicle are also disclosed.
    Type: Application
    Filed: March 20, 2014
    Publication date: July 24, 2014
    Applicant: Afton Chemical Corporation
    Inventors: Allen A. Aradi, May Duffield Thomas
  • Patent number: 8734540
    Abstract: A fuel additive concentrate comprising at least one aryl amine; and at least one metal-containing compound is disclosed. In an aspect, the fuel additive concentrate can be synergistic. Fuel composition comprising the fuel additive concentration and methods of combusting the fuel composition are also disclosed. Moreover, methods of enhancing research octane number, increasing fuel economy, and reducing the carbon footprint of a vehicle are also disclosed.
    Type: Grant
    Filed: October 1, 2012
    Date of Patent: May 27, 2014
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, May Duffield Thomas
  • Patent number: 8715373
    Abstract: A fuel additive concentrate comprising at least one aryl amine; and at least one metal-containing compound is disclosed. In an aspect, the fuel additive concentrate can be synergistic. Fuel composition comprising the fuel additive concentration and methods of combusting the fuel composition are also disclosed. Moreover, methods of enhancing research octane number, increasing fuel economy, and reducing the carbon footprint of a vehicle are also disclosed.
    Type: Grant
    Filed: July 10, 2007
    Date of Patent: May 6, 2014
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, May Duffield Thomas
  • Patent number: 8715375
    Abstract: A diesel fuel composition comprising a performance enhancing additive, wherein the performance enhancing additive is the product of a Mannich reaction between: (a) an aldehyde; (b) a polyamine; and (c) an optionally substituted phenol; wherein the molar ratio of component (c) to component (b) in the reaction mixture used to prepare the performance enhancing additive is at least 1.5:1.
    Type: Grant
    Filed: September 25, 2008
    Date of Patent: May 6, 2014
    Assignee: Innospec Limited
    Inventor: Jacqueline Reid
  • Patent number: 8641791
    Abstract: The invention concerns a method for supplying iron, via the fuel, to the particulate trap of a diesel engine exhaust in a form suitable for promoting trap regeneration. The method involves the addition to the fuel of a defined colloid of iron oxide. Combustion of this colloid produces iron-containing compounds, especially iron oxides, which collect in association with carbonaceous particulate matter in the particulate trap, and function to promote the combustion of this matter. The colloid in particular shows a lower level of associated deposit formation on the fuel injectors than the iron additives of the prior art. The method is thus particularly suitable for modern engines showing increased susceptibility to fuel injector deposits. The colloid also shows a balance of properties providing excellent suitability for use as an additive in fuels, and especially in diesel engine on-board dosing devices.
    Type: Grant
    Filed: March 7, 2008
    Date of Patent: February 4, 2014
    Assignee: Infineum International Limited
    Inventor: Russell M. Thompson
  • Publication number: 20130185990
    Abstract: A composition for improving the combustion efficiency of an internal combustion engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.
    Type: Application
    Filed: December 5, 2012
    Publication date: July 25, 2013
    Inventor: Stephen C. Perry
  • Publication number: 20130111805
    Abstract: A high octane non-leaded gasoline meeting ASTM D910 LL standard is provided that includes a base gasoline fuel having a minimum MON of 96.5 and meeting the ASTM D910 standard. An octane-boosting component is mixed with the base gasoline fuel that raises the MON above 99.6 and the blended fuel complies with ASTM D910. The octane-boosting component is selected from a group including an additive, TEL only and a TEL containing gasoline.
    Type: Application
    Filed: August 29, 2012
    Publication date: May 9, 2013
    Inventors: Indresh Mathur, Jarvis J. Brown
  • Publication number: 20130031826
    Abstract: A fuel additive concentrate comprising at least one aryl amine; and at least one metal-containing compound is disclosed. In an aspect, the fuel additive concentrate can be synergistic. Fuel composition comprising the fuel additive concentration and methods of combusting the fuel composition are also disclosed. Moreover, methods of enhancing research octane number, increasing fuel economy, and reducing the carbon footprint of a vehicle are also disclosed.
    Type: Application
    Filed: October 1, 2012
    Publication date: February 7, 2013
    Applicant: Afton Chemical Corporation
    Inventors: Allen A. Aradi, May Duffield
  • Publication number: 20130025513
    Abstract: A fuel additive concentrate comprising at least one aryl amine; and at least one metal-containing compound is disclosed. In an aspect, the fuel additive concentrate can be synergistic. Fuel composition comprising the fuel additive concentration and methods of combusting the fuel composition are also disclosed. Moreover, methods of enhancing research octane number, increasing fuel economy, and reducing the carbon footprint of a vehicle are also disclosed.
    Type: Application
    Filed: October 1, 2012
    Publication date: January 31, 2013
    Applicant: Afton Chemical Corporation
    Inventors: Allen A. Aradi, May Duffield
  • Patent number: 8323362
    Abstract: A composition for improving the combustion efficiency of an internal combustion engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.
    Type: Grant
    Filed: March 7, 2011
    Date of Patent: December 4, 2012
    Inventor: Stephen C. Perry
  • Patent number: 8287607
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: October 16, 2012
    Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 8211190
    Abstract: This invention relates to fuel oil, especially middle distillate fuel oil, compositions comprising middle distillate fuel oil and incorporated therein an incorporated therein an additive composition comprising (a) at least one fuel-soluble or fuel-dispersible neutral alkaline earth metal compound and/or at least one fuel-soluble or fuel-dispersible neutral alkali metal compound, and (b) at least one fuel-soluble or fuel-dispersible transition metal compound, characterized in that the fuel oil composition contains at most 0.05 mass % of sulfur, the total metal content derived from (a) and (b) in the fuel oil composition is at most 50 ppm by mass, and the mass proportion of (a) to (b), based on metal content, is in the range of from 1:99 to 99:1.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: July 3, 2012
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Brid Dilworth, Carlo S. Fava, Philip Collier
  • Publication number: 20120102822
    Abstract: A fuel additive comprising a sol containing particles of at least one inorganic-metallic component and at least one organo-metallic component stabilized in a suitable hydrocarbon medium. The components are formed as a metal complex wherein the metallic element comprises at least one metal selected from the elements of Groups VIII to XI in the Periodic Table, preferably platinum, cobalt, nickel, copper, gold, rhodium or, most preferably, palladium. The organo component is an alkyl carboxylate, preferably acetate, and the inorganic component is derived from silicon, titanium, aluminum, and preferably silicate. The additive is preferably formed by (a) forming an aqueous solution of at least one metallic component; (b) forming a colloid of organo-metallic and inorganic-metallic components from said solution; and (c) extracting at least some of the metallic colloidal components from the aqueous solution using a suitable hydrocarbon medium under controlled PH, temperature and time.
    Type: Application
    Filed: March 16, 2006
    Publication date: May 3, 2012
    Inventors: Robert R. Holcomb, Lou Basenese
  • Patent number: 8163042
    Abstract: The present invention relates to a hydrocarbon fuel composition comprising (i) at least 99% by weight of a base gas; and (ii) additives comprising (a) 2 to 50 ppm organometallic compound; and (b) 100 to 5000 ppm aniline or substituted aniline and 100 to 5000 ppm toluidine. The present invention discloses addition of an additive or additive mixture to base fuel preferably, liquefied petroleum gas. The addition of additive mixture not only improves the properties of the base fuel for use as torch gas for cutting and welding application, but also reduces the consumption of both fuel and oxygen for cutting applications.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: April 24, 2012
    Assignee: Bharat Petroleum Corporation Limited
    Inventors: Peddy Venkat Chalapathi Rao, Sudha Tyagi, Rajiv Kumar Brahma, Nettem Venkateswarlu Choudary, Puthiyaveetil Padmanabhan, Mohammad Amir Siddiqui
  • Patent number: 8147568
    Abstract: A diesel fuel composition containing metallic additives that are stabilized against phase separation. The diesel fuel contains a colloidally dispersed or solubilized metal catalyst compound, which can be used for diesel particulate trap regeneration and, as a stabilizer, 5-1,000 ppm (weight) of an oil-soluble or oil-dispersible organic compound having a lipophilic hydrocarbyl chain having attached directly thereto at least two contiguous polar head functional groups, i.e., the functional groups are separated by no more than three carbon atoms. The diesel fuel composition is particularly suitable for use with diesel engines fitted with a particulate trap for emissions control.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: April 3, 2012
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Russell M. Thompson
  • Publication number: 20110154726
    Abstract: A composition for improving the combustion efficiency of an internal combustion engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.
    Type: Application
    Filed: March 7, 2011
    Publication date: June 30, 2011
    Applicant: CONSEAL INTERNATIONAL INCORPORATED
    Inventor: Stephen C. Perry
  • Patent number: 7967876
    Abstract: There is disclosed a composition comprising an alloy represented by the following generic formula (Aa)n(Bb)n(Cc)n(Dd)n( . . . )n; wherein each capital letter and ( . . . ) is a metal; wherein A is a combustion modifier; B is a deposit modifier; C is a corrosion inhibitor; and D is a combustion co-modifier/electrostatic precipitator enhancer; wherein each subscript letter represents compositional stoichiometry; wherein n is greater than or equal to zero; and wherein the alloy comprises at least two different metals; and with the proviso that if the metal is cerium, then its compositional stoichiometry is less than about 0.7. There is also disclosed a fuel additive comprising an alloy; a fuel composition comprising the fuel additive composition; methods of making the fuel additive composition; and methods of using the disclosed alloy.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: June 28, 2011
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, Carl K. Esche, Jr., Katrina McIntosh, Tze-Chi Jao
  • Patent number: 7901472
    Abstract: A composition for improving the combustion efficiency of an internal combustion Engine. The composition includes a mixture of a hydrocarbon fuel and an organometallic soap selected from among several cerium-containing and ferric compounds. The cerium-containing compound or compounds increase the energy released during combustion of the fuel. The ferric compound or compounds coat an interior wall of a combustion chamber of the internal combustion engine to increase the power output of the engine by reducing the accumulation of residues deposited on the interior wall which interfere with the combustion of fuel.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: March 8, 2011
    Assignee: ConSeal International Incorporated
    Inventor: Stephen C. Perry
  • Publication number: 20110034357
    Abstract: To provide a novel composition useful as lubricant composition or the like. It is disclosed a composition comprising an oily medium and at least one compound represented by following formula (Z). A-L-{D1-(E)q-D2-(B)m—Z1—R}p??(Z) A represents a p-valent chain or cyclic residue; L represents a single bond or a divalent linking group; p represents an integer of 2 or more; D1 represents a carbonyl group (—C(?O)—) or a sulfonyl group (—S(?O)2—); D2 represents a carbonyl group (—C(?O)—), a sulfonyl group (—S(?O)2—), a carboxyl group (—C(?O)O—), a sulfonyloxyl group (—S(?O)2O—), a carbamoyl group (—C(?O)N(Alk) or a sulfamoyl group (—S(?O)2N(Alk)-); E represents a divalent group; R represents a hydrogen atom, a substituted or non-substituted C8 or longer alkyl group, a perfluoroalkyl group or a trialkylsilyl group; B represents an oxyethylene group or the like; and Z1 represents a single bond or a divalent group.
    Type: Application
    Filed: March 27, 2009
    Publication date: February 10, 2011
    Inventors: Ken Kawata, Saisuke Watanabe
  • Publication number: 20110021396
    Abstract: A composition and method for improving the performance, and thus, also the fuel economy, of an internal combustion engine by introducing a fuel additive into the engine's fuel supply to enhance fuel lubricity. The composition can feature a mixture of esters, glycol ether, and a solvent. The mixture of esters can include adipate esters, azelate esters, dodecanedioate esters, sebacate esters, or phthalate esters. Esters that may be used to create the composition can include a mixture of two or more adipate esters such as, for example, an adipic acid ester, a glutaric acid ester, and a succinic acid ester. The composition can further feature a smoke suppressant that can be an organometallic soap. The organometallic soap can be an iron salt of a fatty acid such as, for example, ferrocene. The composition can be used as a combustion modifier fuel additive and as a lubricating oil.
    Type: Application
    Filed: October 1, 2010
    Publication date: January 27, 2011
    Inventor: Stephen C. Perry
  • Patent number: 7862628
    Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.
    Type: Grant
    Filed: August 14, 2007
    Date of Patent: January 4, 2011
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: Stephen A. Factor, Joseph W. Roos, Allen A. Aradi
  • Patent number: 7794512
    Abstract: The present invention relates to an apparatus and method for delivering tungsten from a to a fuel combustion system or to the exhaust therefrom. By the present invention, tungsten from the lubricant or the fuel will interact with iron from the combustion process. In this manner, the tungsten scavenges or inactivates iron that can otherwise poison catalytic converters, sensors and/or automotive on-board diagnostic devices and/or reduce the operation of spark plugs. The present invention can also lead to improved durability of exhaust after treatment systems. Supplying tungsten acts to change the characteristics of iron deposits formed by combusting a fuel with iron.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: September 14, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Allen A. Aradi, Joseph W. Roos, Dennis H. Rainear
  • Publication number: 20090282730
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Application
    Filed: February 4, 2009
    Publication date: November 19, 2009
    Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 7618725
    Abstract: A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.
    Type: Grant
    Filed: March 14, 2005
    Date of Patent: November 17, 2009
    Assignee: The Board of Trustees of the University of Illinois
    Inventors: Richard I. Masel, Yimin Zhu, Zakia Kahn, Malcolm Man
  • Patent number: 7585336
    Abstract: A fuel additive composition comprising a solution or dispersion of an oil soluble metal carboxylate or metal complex derived from a compound of the formula: where R1, R2, R3 and R4 represent hydrogen or a hydrocarbyl having 1-30 carbon atoms (C1-C30), but at least two of R1, R2, R3 or R4 are C1-C30 hydrocarbyl; R5 is a hydrocarbyl having 1 to 120 carbon atoms and m and n may each be zero or an integer such that the total number of carbon atoms in the carboxylate is not more than 125.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: September 8, 2009
    Assignee: Infineum International Limited
    Inventors: Philip E. Collier, Rinaldo Caprotti
  • Patent number: 7524338
    Abstract: An additive composition for fuels such as diesel oil and fuel oil, used respectively for diesel engines and boilers of various types, containing a metal oxidation catalyst, in which the metal is iron, cerium, calcium, or their binary or ternary mixtures, an organic nitrate and a dispersing agent. The additive composition is able to reduce the formation of particulate emitted by diesel engines and boilers.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: April 28, 2009
    Inventor: Cesare Pedrazzini
  • Publication number: 20090013588
    Abstract: The burn properties of hydrocarbon fuels are improved by incorporating bimetallic fuel additives. The fuel additives include oil-soluble iron as a primary metal component and an oil-soluble platinum-group metal as a secondary metal component. The concentration of the platinum-group metal in the fuel additive is significantly less (e.g., an order of magnitude less) than the concentration of iron. The minute amount of platinum-group metal in combination with 1 to 100 ppm iron synergistically improves smoke point and/or utilizes less iron to achieve the same improvement in smoke point as compared to iron-based fuel additives without a platinum-group metal. The additives can also include one or more oil-soluble metal compound including an alkali metal, alkaline earth metal, lanthanide metal, actinide metal, or base transition metal such as manganese.
    Type: Application
    Filed: July 13, 2007
    Publication date: January 15, 2009
    Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLC
    Inventors: Zhenhua Zhou, Zhihua Wu, Bing Zhou
  • Patent number: 7452388
    Abstract: The present invention relates to iron-organo compounds and the use of such compounds in the regeneration of particulate filter traps in combustion systems such as high-compression spontaneous ignition engines. The iron-organo compounds have the formula X-Y where X represents the group of formula Y represents the formula each A and B is independently an unsubstituted or substituted aromatic carbon ring or an unsubstituted or substituted aromatic heterocyclic ring; the or each Z is independently an unsubstituted or substituted divalent hydrocarbyl group; n is 0 or an integer of from 1 to 10.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: November 18, 2008
    Assignee: Innospec Limited
    Inventors: Stephen Leonard Cook, Werner Kalischewski, Gabriele Lohmann, Armin Marschewski
  • Patent number: 7332001
    Abstract: A method of enhancing the operation of diesel fuel combustion systems in a combustion system includes supplying a fuel and additive that includes a manganese compound to a diesel fuel combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The diesel fuel combustion system operation is enhanced by improving the attributes of lubricating oil loaded with the combustion byproduct soot particles.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: February 19, 2008
    Assignee: Afton Chemical Corporation
    Inventors: Gregory H. Guinther, Mark T. Devlin, Joseph W. Roos, David M. Human
  • Publication number: 20080000149
    Abstract: There is disclosed a method for combusting a secondary organometallic compound in an engine including (a) combining a secondary organometallic compound and methylcyclopentadienyl manganese tricarbonyl, (b) introducing the combination from (a) into a fuel, and (c) causing the fuel from (b) to be combusted in the engine.
    Type: Application
    Filed: June 30, 2006
    Publication date: January 3, 2008
    Inventor: Allen A. ARADI
  • Patent number: 7306634
    Abstract: A fuel additive iron salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm iron in the fuel which comprises an oil soluble or oil dispersible neutral or overbased iron salt of an acidic organic compound, 50-99 mole % of the total iron present in the composition being in the ferric form, the balance being the ferrous form.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: December 11, 2007
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Robert J. Pilling
  • Publication number: 20070277431
    Abstract: An additive for engine oil of the present invention comprises: a compound containing a metallic element, wherein a metal oxide obtained by oxidizing the metallic element has a catalytic action which promotes burning of a particulate matter contained in exhaust gases discharged from an internal combustion engine.
    Type: Application
    Filed: August 1, 2006
    Publication date: December 6, 2007
    Inventors: Kazushige Ohno, Tomokazu Oya, Hiroshi Sasaki
  • Patent number: 7300477
    Abstract: A combustion additive is used for protecting and improving the operation of diesel fuel combustion systems. The additive contains one or more iron-containing compounds. The additive can be added to the fuel prior to introduction into a combustion chamber or to the exhaust after the combustion chamber. The additive will then enhance the operation of diesel fuel combustions systems by improving, for example, exhaust aftertreatment performance.
    Type: Grant
    Filed: August 14, 2003
    Date of Patent: November 27, 2007
    Assignee: Afton Chemical Corporation
    Inventors: Timothy J. Brennan, Scott D. Schwab
  • Patent number: 7288506
    Abstract: Aluminum carboxylate drag reducing agents are described herein. These materials are useful to reduce drag in hydrocarbon fluids and multiphase fluids of hydrocarbon(s) and water. No injection probes or other special equipment is expected to be required to introduce the drag reducing agent into the liquid stream. The drag reducing additives of the invention are not subject to shear degradation and do not cause undesirable changes in the emulsion or fluid quality of the fluid being treated, or undesirable foaming. In one non-limiting embodiment, an aluminum monocarboxylate is reacted with at least one carboxylic acid in situ. In another non-limiting embodiment, the aluminum carboxylate is introduced as a dispersion in a solvent such as paraffin oil. The drag reducing additives include aluminum dicarboxylates such as aluminum dioctoate, aluminum distearate, aluminum octoateoleate, aluminum octoatestearate, aluminum stearateoleate, hydroxyaluminum bis(2-ethylhexanoate) and mixtures thereof.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: October 30, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: Vladimir Jovancicevic, Samuel Campbell, Sunder Ramachandran, Paul Hammonds, Steven J. Weghorn
  • Patent number: 7285140
    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: October 23, 2007
    Assignee: Clean Diesel Technologies, Inc.
    Inventor: James M. Valentine
  • Patent number: 7276094
    Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: October 2, 2007
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: Stephen A. Factor, Joseph W. Roos, Allen A. Aradi
  • Patent number: 7063729
    Abstract: A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50–300 ppm detergent, 25–500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1–2.0 ppm platinum COD and 5–20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOx and the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: June 20, 2006
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: James M. Valentine, Barry N. Sprague, Jeremy D. Peter-Hoblyn
  • Patent number: 6941743
    Abstract: A method, apparatus, and fuel composition for the protection of a catalytic after treatment system and a method for protecting a catalytic after treatment system in a lean burn system are disclosed. A scavenging agent is introduced into the combustion chamber in an amount effective to complex with catalytic poisoning combustion byproducts and improve emissions system durability. In a preferred embodiment, the scavenger is an organometallic compound which also imparts additional desirable properties to the fuel.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: September 13, 2005
    Assignee: Ethyl Corporation
    Inventors: Joseph W. Roos, Martin J. Openshaw, Herbert M. Scull
  • Publication number: 20040237384
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Application
    Filed: November 24, 2003
    Publication date: December 2, 2004
    Inventor: William C. Orr
  • Publication number: 20040211112
    Abstract: A fuel composition, and a method and an apparatus for combusting it in a two-stroke engine, in which molybdenum introduced from the fuel will interact with alkaline earth metal originating from a detergent or other co-ingredient of the fuel in the combustion products to increase detergency without increasing the level of alkaline earth metal or compounds present in the fuel or combustion products thereof. In this manner, the engine operates more cleanly and efficiently without increasing the risk of harmful alkaline earth materials and compounds thereof blocking and poisoning catalysts, sensors and/or automotive on-board diagnostic devices, and it can lead to improved durability of exhaust after treatment systems.
    Type: Application
    Filed: March 29, 2004
    Publication date: October 28, 2004
    Inventors: Nicholas P. Clague, Michael A. Haynes, Peter Growcott
  • Publication number: 20040172876
    Abstract: Delivery of metallic combustion catalysts to internal combustion engines and other combustion devices is improved by dosing units that have the ability to effect the slow and positive supply of metallic additives, including platinum and/or cerium containing catalyst compositions, to fuel. The invention provides additive dosing materials and methods for simply and effectively supplying catalytic metal fuel additives to fuel in suitable low concentrations as are effective. The dosing units can be used with devices made to contact diesel fuel. In one approach, a catalytic metal additive concentrate (CMAC) is prepared in normally solid, semisolid or viscous form. The CMAC will preferably be encapsulated with a solid polymer. The encapsulation can be accomplished by embedding or dispersing the CMAC in a suitable polymer. If desired, the CMAC can be dispersed in one polymer and then the resulting composite can be embedded in the same or a different polymer.
    Type: Application
    Filed: March 21, 2003
    Publication date: September 9, 2004
    Inventors: Barry N. Sprague, James M. Valentine
  • Publication number: 20040118032
    Abstract: The present invention relates to the reduction or inhibition of corrosion in an atmospheric burner unit by adding to a combustion system an effective amount of manganese, or a manganese precursor source, or derivative. The system may further include a catalyst package that may be composed of one or more individual organometallic compounds of Li, Na, K, Mg, Ca, Sr, Ba, Mo, Fe, Co, Pt, Ce, and combinations, mixtures or precursors thereof. The manganese component of the catalyst package of the present invention reduces or eliminates the poisoning of the combustion system, whereby improved combustion and reduced emissions result. In addition, this invention inhibits both high- and low-temperature corrosion that occurs on the hot surfaces of burner furnace walls and tubes, and on cooler surfaces of the burner unit exhaust stack.
    Type: Application
    Filed: December 18, 2002
    Publication date: June 24, 2004
    Inventors: Allen A. Aradi, Michael Wayne Adams, Stephen Alan Factor
  • Patent number: 6725653
    Abstract: This invention relates to a process for reducing the level of pollutants in the exhaust of a diesel engine, comprising: operating said diesel engine using as the fuel a water-diesel fuel emulsion; and contacting the exhaust gas from said diesel engine with an after-treatment such as a filter.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: April 27, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Kevin F. Brown, Ted N. Tadrous, Deborah A. Langer, David A. Duncan