Abstract: A process for producing an optical glass fiber from crystal-glass phase material. In one embodiment, the process includes the step of providing a molten crystal-glass phase material in a container, wherein the temperature of the molten crystal-glass phase material is at or above the melting temperature of the molten crystal-glass phase material, Tm, to allow the molten crystal-glass phase material is in liquid phase. The process further includes the step of cooling the molten crystal-glass phase material such that the temperature of the molten crystal-glass phase material, T1, is reduced to below Tm to cause the molten crystal-glass phase material to be changed from the liquid phase to a viscous melt.

Abstract: Disclosed are glass-ceramics having predominantly Spinel-group crystal phases and methods of making the glass-ceramics. Disclosed are glass-ceramics harder than 10 GPa (Vickers) and methods of making the glass-ceramic. Disclosed are articles of manufacture made of the glass-ceramics. Disclosed is the use of the glass-ceramics in armor and related applications.

Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).

Abstract: There is provided a lithium ion conductive glass-ceramics which is dense, contains few microvoids causing the decrease in lithium ion conductivity, and achieves good lithium ion conductivity. A glass-ceramics which comprises at least crystallines having an LiTi2P3O12 structure, the crystallines satisfying 1<IA113/IA104?2, wherein IA104 is the peak intensity assigned to the plane index 104 (2?=20 to 21°), and IA113 is the peak intensity assigned to the plane index 113 (2?=24 to 25°) as determined by X-ray diffractometry.

Abstract: The invention provides an antimicrobial phosphate glass composition including, in weight percent based on oxide: greater than 45 to 90 of P2O5, 0 to 60 of B2O3, 0 to 40 of SiO2, 0 to 20 weight percent of Al2O3, 0 to 30 of SO3, 0 to 0.1 of Li2O, 0 to 0.1 of Na2O, 0 to 0.1 of K2O, 0 to 40 of CaO, 0 to 40 of MgO, 0 to 15 of SrO, 0 to 40 of BaO, 0 to 40 of ZnO, 0 to 5 of Ag2O, 0 to 15 of CuO, 0 to 10 of Cr2O3, 0 to 10 of I—, 0 to 10 of TeO2, 0 to 10 of GeO2, 0 to 10 of TiO2, 0 to 10 of ZrO2, 0 to 10 of La2O3, 0 to 5 of Nb2O3, 0 to 5 of CeO2, 0 to 5 of Fe2O3, 0 to 5 of WO3, 0 to 5 of Bi2O3, and 0 to 5 of MoO3.

Abstract: A glass composition consisting essentially of, based on mole percent, 46-56% B2O3, 0.5-8.5% P2O5, SiO2 and mixtures thereof, 20-50% CaO, 2-15% Ln2O3 where Ln is selected from the group consisting of rare earth elements and mixtures thereof; 0-6% M?2O where M? is selected from the group consisting of alkali elements; and 0-10% Al2O3, with the proviso that the composition is water millable.

Abstract: Ceramic fibers comprising glass, and composites comprising such fibers. The glass comprises at least 35 percent by weight Al2O3, based on the total metal oxide content of the glass, a first metal oxide other than Al2O3, and a second, different metal oxide other than Al2O3. The glass contains not more than 10 percent by weight collectively As2O3, B2O3, GeO2, P2O5, SiO2, TeO2, and V2O5, based on the total weight of the glass. The first and the second metal oxides are each selected from the group consisting of Y2O3, REO, MgO, TiO2, Cr2O3, CuO, NiO, Fe2O3, ZrO2, HfO2 and complex metal oxides thereof. At least a portion of the glass may be converted to crystals.

Abstract: Ceramic materials and articles comprising at least 35 percent by weight Al2O3, and a plurality of cells having an average cell size of less than 3 micrometers.

Abstract: A translucent piezoelectric glass ceramic is disclosed. The glass ceramic is prepared from a precursor glass by a ceraming process, using a temperature gradient to effect the precipitation of non-ferroelectric piezo-active crystallites from the precursor glass with a preferred direction of orientation and having an average crystal size of less than 1 micrometer. Alternatively, a translucent piezoelectric glass ceramic comprising ferroelectric crystallites may be prepared by poling. In this case the crystal size is controlled to be smaller than 90 nanometers but preferably larger than 10 nanometers.

Abstract: A glass ceramic is specified, with a crystalline phase consisting predominantly of BPO4, and preferably exclusively of BPO4. The glass ceramic contains 10 to 50 wt.-% SiO2, 5 to 40 B2O3, 25 to 75 wt.-% P2O5, up to 5 wt.-% refining agents, up to 1 wt.-% impurities, and 0.1 to 10 wt.-% of at least one constituent selected from the group of M32O3, M52O5 and M4O2, wherein M3 is an element selected from the group of the lanthanoids, yttrium, iron, aluminum, gallium, indium and thallium; wherein M5 is an element selected from the group of vanadium, niobium and tantalum and wherein M4 is an element selected from the group of titanium, zirconium, hafnium and cerium. The glass ceramic is advantageously suitable for being coated with semiconductor materials.

Abstract: The present disclosure relates to microspheres (i.e., beads) having a high index of refraction. The disclosure also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.

Abstract: The process of making the glass-ceramic includes ceramicizing a starting glass at a heating or cooling rate during the ceramicization of at least 10 K/min, so that the glass-ceramic contains at least 50% by volume of ferroelectric crystallites with a maximum diameter of from 20 to 100 nm and not more than 10% by volume of nonferroelectric crystallitesis. The glass ceramic produced by the process contains no pores or not more than 0.01% by volume of the pores and a value of e?·V2max of the glass-ceramic is at least 20 (MV/cm)2, wherein e? is the dielectric constant at 1 kHz and Vmax is the breakdown voltage per unit thickness. The ferroelectric crystallites preferably have a perovskite structure and are composed of substantially pure or doped BaTiO3 and/or BaTi2O5.

Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).

Abstract: The invention relates to vitreous compositions, in particular of the vitroceramic type, transparent to infrared, production and uses thereof. Said compositions comprise in mol. %: Ge 5-40, Ga<1, S+Se 40-85, Sb+As 4-40, MX 2-25, Ln 0-6, adjuncts 0-30, where M=at least one alkaline metal, selected from Rb, Cs, Na, K and Zn, X=at least one atom of chlorine, bromine or iodine, Ln=at least one rare earth and adjunct=at least one additive comprising at least one metal and/or at least one metal salt with the sum of all molar percentages of the components present in said composition being 100.

Abstract: A non-lead glass for forming a dielectric, which consists essentially of, as represented by mol %, from 20 to 39% of SiO2, from 5 to 35% of B2O3, from 2 to 15% of Al2O3, from 1 to 25% of CaO+SrO, from 5 to 25% of BaO, from 0 to 35% of ZnO, and from 0 to 10% of TiO2+ZrO2+SnO2, provided that B2O3+ZnO is from 15 to 45%, and which does not contain alkali metal oxides, or contains such oxides in a total amount within a range of less than 1%. Further, a glass ceramic composition for forming a dielectric, which consists essentially of a Ba-containing compound powder and a powder of the above mentioned non-lead glass for forming a dielectric. Further, a dielectric obtained by firing the above glass ceramic composition for forming a dielectric.

Abstract: The present invention relates to microspheres (i.e., beads) having a high index of refraction. The invention also relates to retroreflective articles, and in particular pavement markings, comprising such microspheres.

Abstract: Optical glass constituted by an amorphous matrix and crystal grains dispersed in the amorphous matrix, wherein the amorphous matrix comprises a first oxide of at least one of silicon oxide and phosphor oxide and a second oxide of at least one of titanium oxide and zirconium oxide, and wherein the crystal grains is at least one of titanium oxide, zirconium oxide and silicon, an average grain size of the titanium oxide grain being 3 nm to 20 nm, and the average grain size of the silicon crystal being 3 nm to 8 nm.

Abstract: A glass-ceramic material, particularly for elements in laser systems, and a method for preparing same. The glass-ceramic material may be used for an optical fiber for communication systems and laser systems. The glass-ceramic may include gahnite crystals and optionally ?-quartz-like solid solution, or a petalite-like crystals, spinel, and zirconia crystals. The elements may comprise a host material glass-ceramic, where the glass-ceramic is doped with appropriate ions.

Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).

Abstract: An internally nucleated, toughened cordierite glass-ceramic is disclosed. The cordierite glass-ceramic has good oxidation resistance and fracture toughness and coefficient of thermal expansion rivaling that of silicon nitride. The glass-ceramic may be cast as a liquid. Annealing produces a material of high crystallinity combining high hardness, high Young's modulus, good thermal stability, high strength, low density and good dielectric properties. The glass-ceramic comprises interlocking crystalline phases dominated by cordierite and a second phase having an elongated or acicular structure. A third phase may comprise a crystalline ceramic that promotes acicularity of the second phase. The third phase is preferably capable of twinning.

Abstract: Bi-containing glass-ceramic material, especially those containing ?-quartz and/or ?-spodumene solid solutions as the predominant crystalline phase, and the precursor glass material as well as process of making such glass-ceramic material and articles. The glass-ceramic can be made to have a dark color, and essentially to be free of V2O5, As2O3 and Sb2O3.

Abstract: Ceramic materials and articles comprising at least 35 percent by weight Al2O3, and a plurality of cells having an average cell size of less than 3 micrometers.

Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).

Abstract: The invention relates to an opaque dental ceramic for burning on a rack or implant of dental restoration at least comprising SiO2, Al2O3, B2O3, Na2O, K2O as well as TiO2. To cover the non-dental-coloured implant material sufficiently the invention provides that the opaque dental ceramic is clouded by precipitation of one or more crystalline TiO2 phases.

Abstract: To provide a process for producing CeO2 fine particles having high crystallinity, being excellent in uniformity of composition and particle size and having a small particle size, and a polishing slurry containing such fine particles. A process for producing CeO2 fine particles, which comprises a step of obtaining a melt containing, as represented by mol % based on oxides, from 5 to 50% of CeO2, from 10 to 50% of RO (wherein R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba) and from 30 to 75% of B2O3, a step of quenching the melt to obtain an amorphous material, a step of precipitating CeO2 crystals from the amorphous material, and a step of separating the CeO2 crystals from the obtained crystallized product, in this order. A polishing slurry containing from 0.1 to 20 mass % of such fine particles.

Abstract: Radio-opaque glass ceramics are described which have high chemical durability and adjustable translucency, brightness and coefficient of thermal expansion.

Abstract: Process for preparing nanocrystalline lithium titanate spinels by reacting lithium hydroxide and a titanium alkoxide at elevated temperature in a reaction mixture which forms water of reaction.

Abstract: Provided is a crystallized glass spacer for a field emission display resistant to charging with application of an electric field and resistant to chipping or cracking thanks to high fracture toughness. An SiO2—TiO2-based glass is subjected to a reduction and crystallization heat treatment at 600-900° C. in a hydrogen atmosphere or in a mixed atmosphere of hydrogen and nitrogen, to obtain a crystallized glass spacer for FED consisting essentially of, in molar percentage, SiO2: 20-50%, TiO2: 25-45%, MgO+CaO+SrO+BaO+ZnO: 20-50%, B2O3+Al2O3: 0-10% and ZrO2: 0-10%, and containing as a principal crystal at least one crystal selected from BaXTi8O16-based crystals (X=0.8-1.5), Ba2TiSi2O8-based crystals and TiO2-based crystals.

Abstract: Ceramics (including glasses and glass-ceramics) comprising nitrogen, and methods of making the same.

Abstract: A glass-ceramic material, particularly for elements in laser systems, and a method for preparing same. The glass-ceramic material may be used for an optical fiber for communication systems and laser systems. The glass-ceramic may include gahnite crystals and optionally ?-quartz-like solid solution, or a petalite-like crystals, spinel, and zirconia crystals. The elements may comprise a host material glass-ceramic, where the glass-ceramic is doped with appropriate ions.

Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.

Abstract: An internally nucleated, toughened cordierite glass-ceramic is disclosed. The cordierite glass-ceramic has good oxidation resistance and fracture toughness and coefficient of thermal expansion rivaling that of silicon nitride. The glass-ceramic may be cast as a liquid. Annealing produces a material of high crystallinity combining high hardness, high Young's modulus, good thermal stability, high strength, low density and good dielectric properties. The glass-ceramic comprises interlocking crystalline phases dominated by cordierite and a second phase having an elongated or acicular structure. A third phase may comprise a crystalline ceramic that promotes acicularity of the second phase. The third phase is preferably capable of twinning.

Abstract: A glass ceramic comprises (in wt.-% on oxide basis): SiO2 35 to 60, B2O3>4 to 10, P2O5 0 to 10, Al2O3 16.5 to 40, TiO2 1 to 10, Ta2O5 0 to 8, Y2O3 0 to 6, ZrO2 1 to 10, MgO 6 to 20, CaO 0 to 10, SrO 0 to 4, BaO 0 to 8, ZnO 0 to 4, SnO2+CeO2 0 to 4, SO42?+Cl? 0 to 4, wherein the total content (SnO2+CeO2+SO42?+Cl?) is between 0.01 and 4 wt.-%. The glass ceramic may be processed by the float glass method, may be transparent and is, inter alia, suitable as a substrate for thin film semiconductors, in particular for display applications, solar cells etc.

Abstract: A glass-ceramic and methods for making glass-ceramics that exhibit a combination of high hardness and high in-line transmission.

Abstract: Methods for making glass-ceramics comprising Al2O3, REO, at least one of ZrO2 or HfO2 and at least one of Nb2O5 or Ta2O5. Glass-ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. Some embodiments of glass-ceramic particles according to the present invention can be are particularly useful as abrasive particles.

Abstract: An opalescent glass-ceramic product, especially for use as a dental material or as an additive to or component of dental material, including SiO2, Al2O3, P2O5, Na2O, K2O, CaO and Me(IV))O2. In order to obtain improved opalescence with improved transparency, in addition to fluorescence, thermal expansion and a combustion temperature adapted to other materials, the opalescent ceramic product is completely or substantially devoid of ZrO2 and TiO2, such that the Me(II)O content in the glass ceramic is less than approximately 4 wt % and the Me(IV)O2 content amounts to approximately 0.5-3 wt %. The invention also relates to a method for the production of the opalescent glass-ceramic product.

Abstract: The invention relates to crystallizable aluminosilicate magnesium-containing glass which is used for producing extremely solid and break-resistant glass-ceramics having an easily polished surface. The inventive crystallizable glass contains 5-33 mass % of SiO2, 25-40 mass % of Al2O3, 5-25 mass % of MgO, 0-15 mass % of B2O3, 0.1-30 mass % of Y2O3, Ln2O3, As2O3 and/or Nb2O5 and 0.1-10 mass % of P2O5.

Abstract: A high-strength, low-temperature-sintered ceramic composition having a structure comprising a SrAl2Si2O8 crystal and an Al2O3 crystal, the SrAl2Si2O8 crystal being composed of hexagonal SrAl2Si2O8 alone or hexagonal SrAl2Si2O8 and monoclinic SrAl2Si2O8, and a peak intensity ratio represented by I101/(I101+I002)×100 being 5% or more in an X-ray diffraction measurement by a Cu—K? line, wherein I101 represents a peak intensity of a (101) plane of the hexagonal SrAl2Si2O8, and I002 represents a peak intensity of a (002) plane of the monoclinic SrAl2Si2O8.

Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) Y2O3, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.

Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 38–40% TiO2 25–45% M2O3 (where M is Al or Ga) ?5–15% Li2O 10–20% and contain Li1+X(Al, Ga)XTi2?X(PO4)3 (where 0<X<0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 ?26–40% SiO2 0.5–12% TiO2 ?30–45% M2O3 (where M is Al or Ga) ??5–10% Li2O ?10–18% and contain Li1+X+YMXTi2?XSiYP3?YO12 (where 0<X?0.4 and 0<Y?0.6) as a main crystal phase. There are also provided solid electrolytes for an electric cell and a gas sensor using alkali ion conductive glass-ceramics, and a solid electric cell and a gas sensor using alkali ion conductive glass-ceramics as a solid electrolyte.

Abstract: A dielectric ceramic obtained by firing a raw material comprising an alumina powder, a crystallizable glass powder mainly containing SiO2, CaO and MgO, and a noncrystallizable glass powder mainly containing SiO2, B2O3 and Na2O. After the firing, the dielectric ceramic contains an alumina crystal phase, a diopside crystal phase (Ca(Mg, Al)(Si, Al)2O6) and a magnesia-spinel crystal phase (MgAl2O4) and has a porosity of not higher than 2.2% when measured by a mercury penetration method.

Abstract: A dielectric ceramic material which is obtained by firing a raw material comprising an alumina powder and a glass powder containing at least SiO2 and MgO, the dielectric ceramic material being characterized in that a ratio (MgAl2O4 (311)/Al2O3 (116)) in X-ray diffraction peak intensity of an MgAl2O4 (311) to an Al2O3 (116) is at least 0.5.

Abstract: Radio-opaque glass ceramics are described which have high chemical durability and adjustable translucency, brightness and coefficient of thermal expansion.

Abstract: The disclosure relates to a leucite glass ceramic doped with nanoscale metal oxide, to a doped leucite glass ceramic powder suitable for its production, to a method for producing the doped leucite glass ceramic, to its use as dental material, to a dental product containing it and to the use of the nanoscale metal oxide powders for the production of the doped glass ceramic or of the doped leucite glass ceramic powder.

Abstract: Glass-ceramics and methods of making the same. Embodiments of the invention include abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.

Abstract: The present invention relates to the use of a magnesia-zirconia brick in regenerator chambers of glass troughs, which are at least partially operated using a reducing atmosphere.

Abstract: A multilayer composite includes an insulating substrate and patterned conductive layers and insulating layers alternately laminated on the insulating substrate. In a laminating process, a correcting insulating layer is formed on a laminate when a predetermined number of layers are laminated or when a predetermined degree of warpage of the laminate is detected by monitoring. The correcting insulating layer has a different composition from that of the other insulating layers to correct the warpage of the laminate.

Abstract: Alumina-zirconia materials and methods of making the same. Embodiments of the invention include abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.

Abstract: The invention relates to a bioactive rhenanite glass ceramic which is characterized by a high content of P2O5, CaO and Na2O and is particularly suitable as bone replacement material in dentistry.

Abstract: A glass ceramics having a chemical composition of aRO.bNb2.O5.cSiO2.dB2O3.eTeO2.fX (where R represents Ba and/or Sr, X represents one or more oxide selected from the group consisting of TiO2, ZrO2, P2O5 and ZnO, a>b?0.05, 0.60?c?0, 0.70?d?0, 0.70?e?0, c+d+e?0.175, a+b+c+d+e=1.0 and 0.10?f?0). The ratio dielectric constant at 1 kHz ?1 to dielectric constant at 100 kHz ?100 (?1/?100) is 10 or more.