Nonsilica And Nonsilicate Crystalline Phase (e.g., Spinel, Barium Titanate, Etc.) Patents (Class 501/10)
-
Patent number: 6245700Abstract: Transparent solid microspheres that contain titania plus alumina, zirconia, and/or silica in a total content of at least about 75% by weight, based on the total weight of the solid microspheres, wherein the total content of alumina, zirconia, and titania is greater than the content of silica.Type: GrantFiled: July 27, 1999Date of Patent: June 12, 2001Assignee: 3M Innovative Properties CompanyInventors: Kenton D. Budd, Toshihiro Kasai, Stephen B. Roscoe, Chikafumi Yokoyama, John E. Bailey
-
Patent number: 6232251Abstract: Dielectric ceramics comprising a diopside oxide crystal phase, at least one kind of crystal phase selected from the group consisting of a quartz crystal phase and a composite oxide crystal phase containing Ti and Mg or Zn, and a glass phase of an amount of not larger than 30% by weight, said dielectric ceramics having a coefficient of thermal expansion of not smaller than 5.5 ppm/° C. at room temperature to 400° C. and a dielectric loss of not larger than 30×10−4 at 60 to 77 GHz. The ceramics can be obtained by the co-firing with a low-resistance metal such as copper or silver, and can be advantageously used for the production of wiring boards to which the signals of particularly high frequencies are applied. The ceramics has a large coefficient of thermal expansion which can be brought close to the coefficient of thermal expansion of the semiconductor element such as of GaAs or of the printed board.Type: GrantFiled: September 29, 1999Date of Patent: May 15, 2001Assignee: Kyocera CorporationInventors: Yoshitake Terashi, Shinya Kawai, Tetsuya Kimura, Hitoshi Kumatabara, Yasuhide Tami
-
Patent number: 6204211Abstract: A luminous glass ceramic comprising a main crystallized phase of spinel or a solid solution of spinel including the components in weight %: SiO2 30-65 Al2O3 5-35 MgO 1-20 BaO 3-4 ZnO 5-35 TiO2 1-15 As2O3 + Sb2O3 0-3 wherein one or more rare earth elements are added to the glass ceramic in an amount of 0.1-30 wt %.Type: GrantFiled: June 2, 2000Date of Patent: March 20, 2001Assignee: Kabushiki Kaisha OharaInventors: Kazuo {overscore (O)}hara, Satoru Matsumoto, Naoyuki Goto
-
Patent number: 6200137Abstract: An apatite glass ceramic is described which is characterized by good chemical stability, a low expansion coefficient and high translucence, and is particularly suitable, by itself or together with glasses or other glass ceramics, as a veneering material for ceramic dental restorations.Type: GrantFiled: June 12, 1998Date of Patent: March 13, 2001Assignee: Ivoclar AGInventors: Wolfram Höland, Martin Frank, Helga Drescher, Volker Rheinberger
-
Patent number: 6197429Abstract: A glass-ceramic material which exhibits extremely low (e.g. less than 100 ppm) shrinkage, when exposed to 900° C. for 6 hours, and methods for making such glass-ceramics. The glass-ceramic is cerammed at a sufficiently high temperature and then cooling in a controlled manner, preferably to below the strain point of the resultant material. Using this technique, glass-ceramic materials were fabricated which exhibited dimensional shrinkage comparable to and in some cases even less than that achieved by fused silica substrates, when exposed to high temperature poly-Si processing temperatures (e.g. 900° C. for 6 hours).Type: GrantFiled: February 26, 1998Date of Patent: March 6, 2001Assignee: Corning IncorporatedInventors: Josef C. Lapp, Chad B. Moore, Linda R. Pinckney
-
Patent number: 6184162Abstract: High E-moduli glasses and glass-ceramics are disclosed based on the SiO2—B2O3—RO—R2O—ZrO2—TiO2—Nb2O5—La2O3 system. The chemically pre-stressable glasses are lithium-poor or lithium-free. The glass-ceramics contain from 2 to 9 percent by weight lithium and the predominant crystalline phase is lithium titanate. These glasses and glass-ceramics particularly have a high specific E-modulus.Type: GrantFiled: August 18, 1999Date of Patent: February 6, 2001Assignee: Schott GlasInventors: Burkhard Speit, Silke Wolff, Peter Brix, Monika Gierke
-
Patent number: 6136459Abstract: A nonmagnetic substrate includes NiO, TiO.sub.2, ZnO, and CaO as major constituents, and major ilmenite and spinel structures, in which the percentage of the total area of the ilmenite and spinel crystalline domains occupied in the area of a given cross section of the nonmagnetic substrate is 20% or more. Preferably, the remainder of the area of the cross section, other than the ilmenite and spinel crystalline domain, contains a CaTiO.sub.3 phase and a TiO.sub.2 phase.Type: GrantFiled: November 16, 1998Date of Patent: October 24, 2000Assignee: Sony CorporationInventors: Yukari Nihei, Takashi Tamura
-
Patent number: 6124223Abstract: Nanocrystalline glass-ceramic materials based on .beta.-quartz solid solution Mg-rich phases formed in the system SiO.sub.2 --Al.sub.2 O.sub.3 --MgO--Li.sub.2 O--TiO.sub.2 (ZnO, BaO, ZrO.sub.2, P.sub.2 O.sub.5). Articles made from the glass-ceramic materials exhibit a crystal phase assemblage of a fine-grained, microstructure which is predominantly .beta.-quartz, and at least one additional phase selected from enstatite and spinel, and having a composition which consists essentially of, in weight percent on the oxide basis, 40-65% SiO.sub.2, 10-14% Al.sub.2 O.sub.3, 5-25% MgO, 0.5-4% Li.sub.2 O, 5-15% TiO.sub.2, and up to 5% ZrO.sub.2, such that the sum of (TiO.sub.2 +ZrO.sub.2) is at least 9% The glass-ceramide article is particularly useful for memory disk applications.Type: GrantFiled: April 9, 1999Date of Patent: September 26, 2000Assignee: Corning IncorporatedInventors: George H. Beall, Linda R. Pinckney
-
Patent number: 6121174Abstract: A dielectric material is disclosed which has a small absolute value of the temperature coefficient of resonance frequency and a high coefficient of unloaded quality. Also disclosed are a process for producing the dielectric material and multilayer and other circuit boards containing the dielectric material. The dielectric material is a highly densified material having a water absorption lower than 0.1%, which is obtained by mixing 95.5 to 99.5 percent by weight mixture of a glass frit and a strontium compound with 0.5 to 4.5 percent by weight titanium dioxide, compacting the resultant mixture, and sintering the compact at a relatively low temperature around 930.degree. C. This dielectric material is a glass ceramic containing strontium anorthite (SrAl.sub.2 Si.sub.2 O.sub.8) as the main crystalline phase, and may contain the TiO.sub.2, which remains unchanged after sintering. The absolute value of the temperature coefficient of resonance frequency of the dielectric material is 20 ppm/.degree. C.Type: GrantFiled: September 26, 1997Date of Patent: September 19, 2000Assignee: NGK Spark Plug Co., Ltd.Inventors: Hitoshi Yokoi, Hidetoshi Mizutani, Motohiko Sato, Kazushige Ohbayashi
-
Patent number: 6087280Abstract: An athermal optical device and a method for producing the device, such as an athermal optical fiber reflective grating, are described. The athermal optical fiber reflective grating device comprises a negative expansion substrate, an optical fiber mounted on the substrate surface, and a grating defined in the optical fiber. The method for producing the athermal optical fiber reflective grating device comprises providing a negative expansion substrate, mounting an optical fiber with at least one reflective grating defined therein onto the substrate upper surface, and affixing the optical fiber to the substrate at at least two spaced apart locations.Type: GrantFiled: January 16, 1997Date of Patent: July 11, 2000Assignee: Corning IncorporatedInventors: George H. Beall, Kenneth Chyung, Joseph E. Pierson
-
Patent number: 6030909Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %:______________________________________ P.sub.2 O.sub.5 35-40% SiO.sub.2 0-15% GeO.sub.2 + TiO.sub.2 25-50% in which GeO.sub.2 0 <-50% and TiO.sub.2 0-<50% ZrO.sub.2 0-10% M.sub.2 O.sub.3 (where M is one or 0.5-15% two selected from the group consisting of Al and Ga) Li.sub.2 O 10-25% ______________________________________and containing Li.sub.1+X M.sub.X (Ge.sub.1-Y Ti.sub.Y).sub.2-X (PO.sub.4).sub.3 (where 0<X<0.8 and 0<Y<1.0) as a main crystal phase. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol % ______________________________________ P.sub.2 O.sub.5 32-40% SiO.sub.2 7-14% TiO.sub.2 38-45% Li.sub.2 O 10-18% ______________________________________and containing Li.sub.1+X Ti.sub.2 Si.sub.X P.sub.3-X O .sub.12 (where X>0) as a main crystal phase.Type: GrantFiled: October 24, 1997Date of Patent: February 29, 2000Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
-
Patent number: 5998313Abstract: A cesium-lithium borate crystal, of which the chemical composition is expressed by any of the following formulae:Cs.sub.1-x Li.sub.1-y M.sub.x+y B.sub.6 O.sub.10,andCs.sub.2(1-z) Li.sub.2 L.sub.z B.sub.12 O.sub.20(where, M is an alkali metal element, and L is an alkali earth element), and in which an exotic element is doped or annealed.Type: GrantFiled: January 27, 1997Date of Patent: December 7, 1999Assignee: Japan Science and Technology CorporationInventors: Takatomo Sasaki, Yusuke Mori
-
Patent number: 5968857Abstract: A transparent glass-ceramic comprising the following composition, expressed in terms of weight percent on an oxide basis: 45-65 SiO.sub.2, 14-28 Al.sub.2 O.sub.3, 4-13 ZnO, 0-8 MgO, 0-10 TiO.sub.2, 0-6 ZrO.sub.2, 0-8 BaO, 0-15 Cs.sub.2 O, ZnO+MgO in combination being greater than or equal to about 8, and TiO.sub.2 +ZrO.sub.2 in combination being greater than about 4.Type: GrantFiled: February 26, 1998Date of Patent: October 19, 1999Assignee: Corning IncorporatedInventor: Linda R. Pinckney
-
Patent number: 5965284Abstract: Scandium-substituted thallium manganese pyrochlore compounds having increased magnetoresistance compared to unsubstituted compounds are disclosed. Such compounds are suitable for use in magnetic read heads and provide the choice of resistivity range.Type: GrantFiled: April 16, 1998Date of Patent: October 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventor: Munirpallam Appadorai Subramanian
-
Patent number: 5952253Abstract: The present invention relates to a transparent glass-ceramic article which includes a glass matrix and a crystalline phase of apatite crystals in the glass matrix. The present invention further relates to a method of producing the transparent glass-ceramic article.Type: GrantFiled: April 3, 1998Date of Patent: September 14, 1999Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Linda Ruth Pinckney
-
Patent number: 5925180Abstract: A ZrO.sub.2 -containing glass ceramic is described, the main crystalline phase of which is formed by ZrO.sub.2 and which has at least one further crystalline phase, and which can be used in particular in dentistry.Type: GrantFiled: September 3, 1997Date of Patent: July 20, 1999Assignee: Ivoclar AGInventors: Martin Frank, Volker Rheinberger, Wolfram Hoeland
-
Patent number: 5821182Abstract: A hermetic sealing composition comprising 100 parts by weight of a basic composition consisting of from 80 to 99.9 wt % of a crystalline low melting glass powder containing lead and boron and from 0.1 to 20 wt % of a low expansion ceramic filler, and from 0.001 to 1.0 part by weight, in total, of at least one of an .alpha.-4PbO.B.sub.2 O.sub.3 crystal powder and a Pb.sub.3 O.sub.4 powder, incorporated to the basic composition, the thermal expansion coefficient of the sealing composition after firing being from 80.times.10.sup.-7 to 105.times.10.sup.-7 /.degree.C. within a range of from room temperature to 300.degree. C.Type: GrantFiled: April 18, 1997Date of Patent: October 13, 1998Assignees: Asahi Glass Company Ltd., Iwaki Glass Company Ltd.Inventors: Ryuichi Tanabe, Satoshi Rokudai, Yuichi Kuroki, Akira Nakamura
-
Patent number: 5786287Abstract: A glass-ceramic article or composition which has better thermal and physical properties than the competing materials of zinc sulfide, spinel, or magnesium fluoride comprising 2-30 mole percent yttrium oxide and/or rare earth oxide, 25-80 mole percent germanium oxide, and 5-30 mole percent gallium oxide, based on the total moles of yttrium oxide and/or the rare earth oxide, germanium oxide, and gallium oxide; which article is over 80% by volume crystalline.Type: GrantFiled: November 15, 1996Date of Patent: July 28, 1998Inventors: Shyam S. Bayya, Barry B. Harbison, Jasbinder S. Sanghera, Ishwar D. Aggarwal
-
Patent number: 5776233Abstract: A bioactive ceramic material for dental fillings and crowns on the basis of calcium phosphate compounds contains crystallites of sparingly water-soluble calcium phosphate compounds in an amorphous, vitreous or polycrystalline matrix of readily water-soluble calcium phosphate compounds, the Ca/P-atomic ratio of the calcium phosphate compounds being altogether <1.65.Type: GrantFiled: May 13, 1994Date of Patent: July 7, 1998Assignee: BEGO Bremer Goldschlagerei Wilh. Herbst GmbH & Co.Inventors: Wolfgang Wiedemann, Hans Georg Klinger
-
Patent number: 5756408Abstract: A glass-ceramic sintered body containing Si, Al, Zn, element of Group 2a and Group 4a of the periodic table, and Boron and Oxygen, as constituent elements, and comprising a glass phase and crystalline phases, wherein the crystalline phase comprises a first crystalline phase of a composite oxide containing at least Si, Al and Ca or Sr, or, Si, Al, Ca and Sr, a second crystalline phase of ZrO.sub.2 crystalline and a third crystalline phase of spinel crystalline is presented. The glass-ceramic sintered body has a high dielectric constant of not smaller than 8.5 and have a fracture strength of not smaller than 20 kg/mm.sup.2 and preferred as an insulation substrate of a circuit board, a substrate board for mounting an integrated circuit or an electronic compornent part.Type: GrantFiled: October 30, 1996Date of Patent: May 26, 1998Assignee: Kyocera CorporationInventors: Yoshitake Terashi, Hideto Yonekura, Satoru Hamano
-
Patent number: 5753685Abstract: A ceramic enamel composition is described which contains a zinc-containing oxide frit, a zinc borate seed material, a pigment, and a vehicle. The zinc borate seed material is preferably crystalline in nature, and promotes crystal growth upon firing. A preferred crystalline zinc borate seed material is selected from the phases Zn.sub.3 B.sub.2 O.sub.6 and Zn(BO.sub.2).sub.2, and mixtures thereof. Upon firing and press-forming a glass substrate coated with the enamel, components of the enamel adhere to the substrate while reducing sticking of the coated region to the forming die. The ceramic enamel is particularly useful in providing a colored border around the periphery of automotive glass and is effective in improving appearance and reducing degradation of underlying adhesives by ultraviolet radiation.Type: GrantFiled: June 16, 1997Date of Patent: May 19, 1998Assignee: Cerdec CorporationInventor: George E. Sakoske
-
Patent number: 5726108Abstract: A glass-ceramic magnetic disk substrate which is prepared by forming, then heat treating, and then polishing a crystallizable glass composition comprising, expressed in terms of weight percent on the oxide basis: from 20 to 45% SiO.sub.2 ; from 25 to 45% Al.sub.2 O.sub.3 ; from 10 to 25% B.sub.2 O.sub.3 ; from 2 to 12% MgO; from 0.5 to 8% TiO.sub.2 ; from 0.5 to 5% P.sub.2 O.sub.5 ; from 0 to 2% Li.sub.2 O; from 0 to 2% Na.sub.2 O; from 0 to 3% K.sub.2 O; wherein, the total of the contents of Li.sub.2 O, Na.sub.2 O and K.sub.2 O is from 0 to 5%; and wherein the magnetic disk substrate comprises a main crystalline phase consisting of at least one member selected from the group consisting of mullite and aluminum borate crystals. The glass composition can easily be formed and the disk substrate can easily be polished, has excellent mechanical strength, surface flatness, surface smoothness, chemical durability, and heat resistance, and shows no deterioration of magnetic film characteristics by alkali migration.Type: GrantFiled: April 2, 1997Date of Patent: March 10, 1998Assignee: Yamamura Glass Co., Ltd.Inventors: Tomoyuki Taguchi, Hideki Kawai, Tohru Ohara, Ikuo Kuriyama, Hajimu Wakabayashi, Sadao Nakajima
-
Patent number: 5725808Abstract: A ceramic mixture of a crystallizable ZnO--MgO--B.sub.2 O.sub.3 --SiO.sub.2 glass mixed with a non-crystallizing lead-based glass and one or more oxide fillers forms a fired ceramic that has a TCE compatible with that of kovar. Green tapes made from the ceramic mixture aligned with a kovar support substrate when fired have excellent dielectric and low loss properties.Type: GrantFiled: May 23, 1996Date of Patent: March 10, 1998Assignees: David Sarnoff Research Center, Inc., Sharp K.K.Inventors: Ellen Schwartz Tormey, Ashok Naryan Prabhu
-
Patent number: 5702995Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %______________________________________ P.sub.2 O.sub.5 38-40% TiO.sub.2 25-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-15% Li.sub.2 O 10-20% ______________________________________and contain Li.sub.1+X (Al, Ga).sub.X Ti.sub.2-X (PO.sub.4).sub.3 (where X is 0 to 0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol % ______________________________________ P.sub.2 O.sub.5 26-40% SiO.sub.2 0.5-12% TiO.sub.2 30-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-10% Li.sub.2 O 10-18% ______________________________________and contain Li.sub.1+X+Y M.sub.X Ti.sub.2-X Si.sub.Y P.sub.3-Y O.sub.12 (where 0<X.ltoreq.0.4 and 0<Y.ltoreq.0.6) as a main crystal phase.Type: GrantFiled: October 31, 1996Date of Patent: December 30, 1997Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
-
Patent number: 5698019Abstract: A leucite-containing phosphosilicate glass-ceramic is described which, in addition to a leucite crystalline phase and at least one further crystalline phase, also contains one or more glass phases.Type: GrantFiled: June 30, 1995Date of Patent: December 16, 1997Assignee: Ivoclar AGInventors: Martin Frank, Marcel Schweiger, Volker Rheinberger, Wolfram Hoeland
-
Patent number: 5698482Abstract: A ZrO.sub.2 -containing glass ceramic is described, the main crystalline phase of which is formed by ZrO.sub.2 and which has at least one further crystalline phase, and which can be used in particular in dentistry.Type: GrantFiled: June 30, 1995Date of Patent: December 16, 1997Assignee: Ivoclar AGInventors: Martin Frank, Volker Rheinberger, Wolfram Hoeland
-
Patent number: 5691257Abstract: A cellulated, inorganic body, and a method of producing the body, the body having a very low bulk density and being resistant to aqueous and chemical attack, the cells being gas- or vacuum-filled, predominantly closed, and dispersed in a crystalline matrix.Type: GrantFiled: June 13, 1996Date of Patent: November 25, 1997Assignee: Corning IncorporatedInventor: Hermann L. Rittler
-
Patent number: 5683948Abstract: A hermetic sealing composition comprising 100 parts by weight of a basic composition consisting of from 80 to 99.9 wt % of a crystalline low melting glass powder containing lead and boron and from 0.1 to 20 wt % of a low expansion ceramic filler, and from 0.001 to 1.0 part by weight, in total, of at least one of an .alpha.-4PbO.B.sub.2 O.sub.3 crystal powder and a Pb.sub.3 O.sub.4 powder, incorporated to the basic composition, the thermal expansion coefficient of the sealing composition after firing being from 80.times.10.sup.-7 to 105.times.10.sup.-7 /.degree.C. within a range of from room temperature to 300.degree. C.Type: GrantFiled: July 30, 1996Date of Patent: November 4, 1997Assignees: Asahi Glass Company Ltd., Iwaki Glass Company Ltd.Inventors: Ryuichi Tanabe, Satoshi Rokudai, Yuichi Kuroki, Akira Nakamura
-
Patent number: 5677251Abstract: A ceramic enamel composition is described which contains a zinc-containing oxide frit, a zinc borate seed material, a pigment, and a vehicle. The zinc borate seed material is preferably crystalline in nature, and promotes crystal growth upon firing. A preferred crystalline zinc borate seed material is selected from the phases Zn.sub.3 B.sub.2 O.sub.6 and Zn(BO.sub.2).sub.2, and mixtures thereof. Upon firing and press-forming a glass substrate coated with the enamel, components of the enamel adhere to the substrate while reducing sticking of the coated region to the forming die. The ceramic enamel is particularly useful in providing a colored border around the periphery of automotive glass and is effective in improving appearance and reducing degradation of underlying adhesives by ultraviolet radiation.Type: GrantFiled: April 25, 1996Date of Patent: October 14, 1997Assignee: Cerdec CorporationInventor: George E. Sakoske
-
Patent number: 5658835Abstract: A glass-ceramic sintered body comprising an SiO.sub.2 --Al.sub.2 O.sub.3 --MgO--ZnO--B.sub.2 O.sub.3 type crystalline glass and alumina, said sintered body containing at least 10% by weight of a spinel crystalline phase; and a substrate composed of the sintered material. There is also provided a process for producing the glass-ceramic sintered body which comprises adding a binder to a mixed powder of an SiO.sub.2 --Al.sub.2 O.sub.3 --MgO--ZnO--B.sub.2 O.sub.3 type crystalline glass and alumina, molding the mixture into a predetermined shape, and firing the mixture into a predetermined shape, and firing the molded mixture at a temperature of 925.degree. to 1000.degree. C. in a non-oxidizable atmosphere. The glass-ceramic sintered body and the substrate composed of it in accordance with the present invention have excellent mechanical strength and thereby have markedly increased metallizing adhesion strength.Type: GrantFiled: June 6, 1995Date of Patent: August 19, 1997Assignee: Kyocera CorporationInventors: Masamitsu Onitani, Satoru Hamano, Takahiro Matsuoka, Hideto Yonekura
-
Patent number: 5612261Abstract: The present invention relates to a novel sealing glass composition, in particular, one which comprises solid PbO--ZnO--B.sub.2 O.sub.3 glass and natural garnet as a filler component. This composition has the advantage that thermal strain does not occur at the interface between the crystalline glass and filler because of the excellent chemical affinity. This prevents cracks from propagating at the interface between the main glass and filler, thereby improving the mechanical strength of the glass.Type: GrantFiled: June 23, 1995Date of Patent: March 18, 1997Assignee: Samsung Corning Co., LtdInventors: Byung C. Lim, Tae H. Park, Tae H. Park
-
Patent number: 5567217Abstract: A magnetic disk substrate is made of a glass-ceramic having crystal phases of lithium disilicate (Li.sub.2 O.2SiO.sub.2) and alpha-quartz (SiO.sub.2). The crystal phase of alpha-quartz is formed of grown crystal grains each having a globular grain structure made of aggregated particles. Each globular grain has a size within a range from 0.3 .mu.m to 3 .mu.m. Surface roughness (Ra) of a polished surface of the magnetic disk substrate is within a range from 15 .ANG. to 50 .ANG. which is an optimum range of surface roughness for the magnetic disk.Type: GrantFiled: May 16, 1995Date of Patent: October 22, 1996Assignee: Kabushiki Kaisya OharaInventors: Naoyuki Goto, Katsuhiko Yamaguchi
-
Patent number: 5561089Abstract: Glass-ceramic for information recording disks have a crystalline structure suitably used for substrate materials and the like for magnetic disks and magneto-optic disks as well as have improved surface characteristics obtained by polishing the glass, and besides the base glass thereof is excellent in melting properties and moldability thereof. The base glass composition consists essentially of ingredients of SiO.sub.2 -Al.sub.2 O.sub.3 -ZnO-MgO-CaO-SrO-BaO-TiO.sub.2 system. The main crystalline phase of the glass-ceramic produced by heat-treating the base glass having a viscosity of log .eta.=3.0 poise or less at 1250.degree. C. is gahnite, a size of the crystal grain is within a range of from 50 to 1000 Angstrom, and a degree of surface roughness (Ra) of the polished glass-ceramic is within a range of from 0.5 to 9.0 Angstrom.Type: GrantFiled: July 28, 1995Date of Patent: October 1, 1996Assignee: Kabushiki Kaisya OharaInventors: Futoshi Ishizaki, Naoyuki Goto, Masashi Maekawa
-
Patent number: 5534470Abstract: This invention is directed to the production of thermally crystallizable glasses which, upon heat treatment in contact with alumina particulates, will form a strong glass-ceramic-bonded composite body, the excellent bonding being attributed to the presence of lithium aluminoborate crystals. The glass-ceramic composition consists essentially, in weight percent, of______________________________________ SiO.sub.2 25-55 MgO 0-12 B.sub.2 O.sub.3 35-65 Li.sub.2 O + MgO 4-16. Li.sub.Type: GrantFiled: October 27, 1994Date of Patent: July 9, 1996Assignee: Corning IncorporatedInventors: Ronald l. Andrus, John F. MacDowell
-
Patent number: 5516733Abstract: A fusion seal between two surfaces, and a material to produce the seal, consist essentially of 60-90 percent by weight of a SnO--ZnO--P.sub.2 O.sub.5 glass frit and 10-40 percent by weight of a mill addition including alumina and, optionally, zircon, the alumina content being at least 10% when it constitutes the mill addition and not over 20% in conjunction with zircon, 0-15 % of a further additive that reduces the effective CTE of the seal, the mill addition being present in a sufficient amount to cause a substantial change in viscosity-temperature characteristics of the material after formation of a seal. The effect of the mill addition on viscosity in a fusion seal finds particular application in uniting the faceplate and funnel members to form a cathode ray tube envelope.Type: GrantFiled: August 8, 1995Date of Patent: May 14, 1996Assignee: Corning IncorporatedInventor: Robert Morena
-
Patent number: 5491116Abstract: A glass-ceramic article, such as an information disk substrate, and a method of making the article. The glass-ceramic has Mg-rich pyroxene and spinel-type predominate crystal phases and a composition at least 92% of which consists essentially of 35-60% SiO.sub.2, 10-30% Al.sub.2 O.sub.3, 12-30% MgO, 0-10% ZnO, 5-20% TiO.sub.2, and 0-8% NiO.Type: GrantFiled: April 3, 1995Date of Patent: February 13, 1996Assignee: Corning IncorporatedInventors: George H. Beall, Linda R. Pinckney
-
Patent number: 5488016Abstract: There is disclosed an amorphous, polymeric material that contains phosphorous, aluminum and carbon atoms, and that is the reaction product of a buffered liquid mixture of a source of phosphorous, such as 85% phosphoric acid, a source of aluminum, such as boehmite, and an organic liquid buffer, such as a carboxylic acid. The polymeric material may be converted to a glassy or crystalline solid by heating to a temperature of at least 150.degree. C., and may be cellulated.Type: GrantFiled: December 13, 1994Date of Patent: January 30, 1996Assignee: Corning IncorporatedInventor: Hermann L. Rittler
-
Patent number: 5486495Abstract: A germanate glass ceramic article which has better thermal and physical perties than the competing materials of zinc sulfide, spinel, and sapphire is made by mixing germanate ceramic glass components; melting the components to form a molten mass; cooling the molten mass to form a solid glass article; nucleating the solid article by heating it in the range of about 630.degree.-790.degree. C. for about 1-16 hours to develop nuclei in the article; and crystallizing the nucleated article by heating it, after nucleation, in the range of about 1/2 minute to about 8 hours to grow the nuclei to crystallites having an average diameter of less then about 1000 nanometer (nm); and cooling to form the glass ceramic.Type: GrantFiled: December 23, 1994Date of Patent: January 23, 1996Assignee: The United States of America as represented by the Secretary of the NavyInventors: John M. Jewell, Barry B. Harbison, Ishwar D. Aggarwal, Shyam S. Bayya
-
Patent number: 5476821Abstract: This invention is directed at glass-ceramic articles, and methods for producing such articles, exhibiting Young's modulus between about 14 to 24.times.10.sup.6 psi and a fracture toughness in excess of 1.0 MPa.sqroot. in. The crystal phase assemblage is comprised predominately of generally uniformly-sized spinel-type crystals which are uniformly dispersed within a highly siliceous residual glass matrix phase. The composition of these glass-ceramic articles is consists essentially, expressed in terms of weight percent on the oxide basis, of 35-60% SiO.sub.2, 20-35% Al.sub.2 O.sub.3, 0-25% MgO, 0-25% ZnO, at least about 10% MgO+ZnO, 0-20% TiO.sub.2, 0-10% ZrO.sub.2, 0-2% Li.sub.2 O and 0-8% NiO. However, if the Al.sub.2 O.sub.3 constituent is present in an amount less than about 25%, the TiO.sub.2 +ZrO.sub.2 +NiO amount should be at least 5%. The composition may also contain up to 5% of optional constituents selected from the group consisting of BaO, CaO, PbO, SrO, P.sub.2 O.sub.5, B.sub.2 O.sub.3, Ga.sub.2 O.Type: GrantFiled: November 1, 1994Date of Patent: December 19, 1995Assignee: Corning IncorporatedInventors: George H. Beall, Linda R. Pinckney
-
Patent number: 5476728Abstract: Non-magnetic ferrite composition used in the composite multilayer part of the invention is based on ferrite containing Fe.sub.2 O.sub.3 and CuO and/or ZnO and further contains 1 to 30% by weight of four oxide components of MgO, BaO, SiO.sub.2, and B.sub.2 O.sub.3 or five or six oxide components including the four oxide components plus at least one of SnO.sub.2 and CaO. Since the use of this non-magnetic ferrite minimizes the difference in coefficient of linear expansion between different materials used, the non-magnetic ferrite, when applied to composite multilayer parts such as shielded multilayer chip inductors, shielded multilayer transformers, and multilayer LC composite parts, prevents occurrence of cracks in the interior and avoids a lowering of circuit resistance due to precipitation of CuO, ZnO or the like at the interface between different materials. There result composite multilayer parts with improved characteristics.Type: GrantFiled: March 2, 1993Date of Patent: December 19, 1995Assignee: TDK CorporationInventors: Atsuyuki Nakano, Satoshi Saito, Takeshi Nomura
-
Patent number: 5472471Abstract: An optical fiber bundle for heat resistance and vacuum resistance which can be used even at a very high temperature or high vacuum is provided in economical manner. This is accomplished by a process for the production of an optical fiber bundle for heat resistance and vacuum resistance, which comprises making up optical fiber filaments each having a core part and a clad part into a bundle, closely fusion-bonding the end of the optical fiber bundle with a bonding glass and then subjecting the bonding glass to a crystallization treatment to increase the heat resistance.Type: GrantFiled: November 1, 1994Date of Patent: December 5, 1995Assignee: Sumita Optical Glass, Inc.Inventors: Nobuyoshi Baba, Shinobu Nagahama, Koji Moriya, Junya Yamauchi
-
Patent number: 5470804Abstract: A sealing glass material comprising a thermally crystallizable, PbO--ZnO--B.sub.2 O.sub.3 sealing glass flit and a mill addition selected from alumina, zircon, and manganese dioxide, the mill addition being in an amount sufficient to increase the mechanical strength in a fusion seal to at least 55.2 MPa(8000 psi), but the amount being not over about 5% by weight of the sealing material.Type: GrantFiled: August 3, 1994Date of Patent: November 28, 1995Assignee: Corning IncorporatedInventor: Robert Morena
-
Patent number: 5470506Abstract: A novel heat-generating composition comprises an electrically conductive powder, and a crystallizable glass frit which is alkaline-earth borate glass essentially containing at least one component of rare-earth metal oxides and Bi.sub.2 O.sub.3. A novel heat-generating composition comprises a molybdenum silicide as an electrically conductive powder, a glass frit, and an additive which is metal oxide powder and/or metal powder. A novel heat-generating composition comprises a combination of a molybdenum silicide and a nickel silicide as electrically conductive powder, a glass frit, and a nickel powder as an additive. The heat-generating composition is sintered in a nitrogen atmosphere or in air, to produce a heater, which has a low electrical-resistance value and a good heat-resistance.Type: GrantFiled: March 23, 1994Date of Patent: November 28, 1995Assignee: Yamamura Glass Co., Ltd.Inventors: Yoshinori Tanigami, Takahiro Tabata, Hidekazu Hashima, Akio Konishi
-
Patent number: 5449645Abstract: This invention is directed to the production of glass bodies containing crystallites of PbS and/or PbSe. The crystallite-containing bodies are formed by the thermal crystallization in situ of glass bodies having compositions essentially free from CdO and consisting essentially, expressed in terms of weight percent on the oxide basis except for fluorine, sulfur, and selenium which are expressed in terms of weight percent on the elemental basis, of______________________________________ SiO.sub.2 58-65 RO 0-15 Na.sub.2 O 10-15 F 1-3.5 ZnO 5-17 S 0-3 Al.sub.2 O.sub.3 0.5-5 Se 0-3 PbO 3-6 S + Se 1-3 ______________________________________wherein RO consists of at least one alkaline earth metal oxide in the indicated proportions selected from the group consisting of 0-5% BeO, 0-5% MgO, 0-15% CaO, 0-10% SrO, and 0-10% BaO.Type: GrantFiled: August 26, 1994Date of Patent: September 12, 1995Assignee: Corning IncorporatedInventors: Nicholas F. Borrelli, George B. Hares, Dennis W. Smith
-
Patent number: 5352638Abstract: This invention is directed to the production of thermally crystallizable glasses which can be crystallized in situ via heat treatment into glass-ceramic articles containing a nickel spinelloid as the predominant crystal phase. The glasses consist essentially, in weight percent, of 40-60% SiO.sub.2, 10-35% Al.sub.2 O.sub.3, 5-35% NiO, 0-20% MgO, and 0-15% total TiO.sub.2 and/or ZrO.sub.2. The preferred glasses contain at least 2% MgO.Type: GrantFiled: February 22, 1994Date of Patent: October 4, 1994Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson
-
Patent number: 5348918Abstract: This invention provides a continuous ceramic oxide fiber comprising Al, Y, and O. In another aspect, a method of making the same is taught. The continuous ceramic oxide fiber is useful, for example, as thermal insulation, as a filter component, and as a reinforcement for structural composites.Type: GrantFiled: April 8, 1993Date of Patent: September 20, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenton D. Budd, David M. Wilson
-
Patent number: 5346868Abstract: The invention relates to inorganic fibers, and a process for their production. The inorganic fibers lose their fiber form factor after a short contact period with water or a physiological body fluid, so that danger to health is not expected from such fibers remaining for a prolonged period of time in or on human tissue. The fiber of the invention is characterized by the fact that at least 90% of it comprises 20-50% by weight of CaO and 50-80% by weight of Al.sub.2 O.sub.3. The rest comprises a maximum of 10% by weight of typical impurity oxides.Type: GrantFiled: June 8, 1993Date of Patent: September 13, 1994Assignee: Didier-Werke AGInventor: Axel Eschner
-
Patent number: 5336642Abstract: A glass-ceramic biomaterial having high strength and toughness, a family of glasses from which the glass-ceramic biomaterial can be produced, and a method of production. The material has a primary crystal phase of F-canasite and a secondary crystal phase of F-apatite. The glass family is SiO.sub.2 --CaO--Na.sub.2 O--K.sub.2 O--P.sub.2 O.sub.5 --F. The method may be a single stage heat treatment, or a two stage involving an initial nucleation and a subsequent crystallization.Type: GrantFiled: September 1, 1993Date of Patent: August 9, 1994Assignee: Corning IncorporatedInventor: Christine C. Wolcott
-
Patent number: 5330939Abstract: A vitreous ceramic composition for coating ceramic articles with a zinc and alumina base capable of separating rapidly up to 50% of crystalline phase consisting essentially of gahnite. The percentages by weight of the principal ingredients of the composition are the following. SiO.sub.2 30-50%; Al.sub.2 O.sub.3 10-25%; ZnO 8-25%; B.sub.2 O.sub.3 5-20%; TiO.sub.2 0-7%; other selected oxides can be added to change the fusability characteristics and heat expansion coefficients on the basis of specific applications of the composition.Type: GrantFiled: November 23, 1993Date of Patent: July 19, 1994Assignee: Ceramica Filippo Marazzi S.p.A.Inventors: Filippo Marazzi, Mariano Paganelli
-
Patent number: 5318929Abstract: The invention relates to an apatite glass ceramic which can be used as a material in medicine and as an inorganic component of a glass ionomer cement. The apatite glass ceramic comprises in wt-%) 15-40% SiO.sub.2, 15-35% Al.sub.2 O.sub.3, 12-30% CaO, 6-25% P.sub.2 O.sub.5, 2.5-15% F.sup.-, 0-18% R.sub.2 O, wherein R.sub.2 O is an alkali oxide. The apatite glass ceramic comprises a crystal phase which contains apatite.Type: GrantFiled: October 10, 1991Date of Patent: June 7, 1994Assignee: Thera Patent GmbH & Co. KG Gesellschaft fur Industrielle SchutzrechteInventors: Carsten Jana, Wolfram Holand, Werner Vogel