Phosphorus Containing Patents (Class 501/45)
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Publication number: 20090023574Abstract: The invention relates to dental glass-ceramics and a process for producing them and their use, with these comprising at least one crystal phase containing xenotime or monazite or mixtures thereof.Type: ApplicationFiled: May 31, 2006Publication date: January 22, 2009Applicant: Ivoclar Vivadent AGInventors: Wolfram Holand, Christian Ritzberger, Volker Rheinberger, Elke Apel
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Patent number: 7456142Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.Type: GrantFiled: July 11, 2007Date of Patent: November 25, 2008Assignee: Reckitt Benckiser N.V.Inventor: Karlheinz Ulrich Gerhard Hahn
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Patent number: 7439201Abstract: The invention is directed to lead-free glass frit compositions that can be used as sealing frits, the compositions being a blend of: (1) at least one of two glass families which are SnO—ZnO—P2O5 and alkali-ZnO—P2O5 glasses; and (2) at least one cerammed filler material having a crystalline phase selected from the group consisting of beta-quartz, beta-eucryptite, cordierite, and beta-spodumene. The blends of the invention have flow characteristics that enable them to be used at sealing temperatures in the range of 450-550° C., and a CTE value in the range of 60-90×10?7/° C.Type: GrantFiled: August 29, 2006Date of Patent: October 21, 2008Assignee: Corning IncorporationInventors: Melinda Ann Drake, Sasha Marjanovic, Lisa A. Lamberson, Robert Michael Morena
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Patent number: 7435695Abstract: Disclosed are zinc niobium phosphate glasses consisting essentially, expressed in terms of mole percent on the oxide basis of, 40-65% P2O5, 25-37% ZnO, 0.1-15% Nb2O5, 0-6% Al2O3, 0-5% Bi2O3, 0-3% Na2O and 0-5% B2O3, said glass exhibiting glass transition temperature below 450° C., a dilatometer softening point below 500° C., coefficient of expansion in the range of 80-120×10?7° C.?1, good chemical durability and blue color. The glass of the present invention is useful for sealing optical fiber to ferrule by local heating.Type: GrantFiled: December 9, 2004Date of Patent: October 14, 2008Assignee: B.G. Negev Technologies and Applications Ltd.Inventor: Jacob Hormadaly
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Patent number: 7396786Abstract: A glass containing 5 to 25 mass % of P2O5, 0 to 15 mass % of B2O3, 0 to 5 mass % of SiO2+GeO2, 21 to 50 mass % of BaO+SrO, 0 to 3 mass % of Li2O+Na2O+K2O, and 35 to 65 mass % of Nb2O5, not substantially containing PbO, satisfying Nb2O5/(BaO+SrO)=0.85 to 2.20, having a dielectric constant of 15 or greater, a dielectric loss of 10.0×10?4 or less, and a resistivity of 1.0×1016 ?·cm or more.Type: GrantFiled: January 22, 2003Date of Patent: July 8, 2008Assignee: Kabushiki Kaisha OharaInventors: Masaaki Miyata, Kazuo Ohara
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Patent number: 7396787Abstract: The lead-free, preferably lithium-free, optical glass is useful in imaging, projection, telecommunications, optical communication and/or laser technology, particularly for making precise-pressed optical elements. It has a refractive index nd of 1.50 to 1.57, an Abbé number ?d of 61 to 70. It also has a low transformation temperature of about or below 400° C., good production and processing properties and crystallization resistance. It has a composition, in percent by weight, based on oxide content of P2O5, 40 to 60; Al2O3, 1 to 20; B2O3, 0 to <5; Na2O, 0 to 30; K2O, 0 to 30; Li2O, 0 to <1; ?M2O, >15 to 40; BaO, 1 to 20; ZnO, 1 to 20; SrO, 0 to 5; CaO, 0 to 5; MgO, 0 to 5; and ?MO, 5 to 25. In addition, it may contain standard refining agents, although it is preferably free of arsenic and fluorine.Type: GrantFiled: January 13, 2005Date of Patent: July 8, 2008Assignee: Schott AGInventors: Simone Monika Ritter, Ute Woelfel, Silke Wolff
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Publication number: 20080132399Abstract: Disclosed are glass materials generally belonging to the P2O5—ZnO—TeO2 system and process for making the same. The glass may comprise Bi2O3 as well. The high refractive index and low Tg materials are particularly suitable for refractive lens elements for use in portable optical devices. The process involves the use of P2O5 source materials with reduced amounts of reducing agents or a step of removing the reducing agents from such source materials by an oxidizing step such as calcination.Type: ApplicationFiled: February 7, 2007Publication date: June 5, 2008Inventors: Bruce Gardiner Aitken, James Edward Dickinson, Sinue Gomez
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Patent number: 7371703Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: GrantFiled: September 18, 2003Date of Patent: May 13, 2008Assignee: Kabushiki Kaisha OharaInventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 7361632Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.Type: GrantFiled: July 25, 2005Date of Patent: April 22, 2008Assignee: Reckitt Benckiser N.V.Inventor: Karlheinz Ulrich Gerhard Hahn
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Patent number: 7326367Abstract: This invention is related to thick film conductor compositions comprising electrically conductive gold powder, one or more glass frit or ceramic oxide compositions and an organic vehicle. It is further directed to the composition's uses for LTCC (low temperature co-fired ceramic) tape, for fabrication of multilayer electronic circuits and in high frequency microelectronic applications.Type: GrantFiled: April 5, 2006Date of Patent: February 5, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Patricia J. Ollivier, Kenneth Warren Hang
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Patent number: 7312169Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature, a refractive index (nd) of at least 1.83 and an Abbe number (?d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 15 to 29% B2O3 ?0 to 2% GeO2 ?0 to 14% Sum of P2O5 + B2O3 + GeO2 20 to 35% Li2O ?0 to 5% Na2O ?3 to 14% K2O ?0 to 9% Sum of Li2O + Na2O + K2O ?5 to 15% Nb2O5 ?2 to less than 22% Bi2O3 34 to 60% WO3 ?0 to 5% BaO ?0 to 5% In2O3 ??0 to 7%.Type: GrantFiled: November 4, 2004Date of Patent: December 25, 2007Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 7309670Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.Type: GrantFiled: April 19, 2004Date of Patent: December 18, 2007Assignee: Hoya CorporationInventors: Yasuhiro Fujiwara, Xuelu Zou
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Publication number: 20070243991Abstract: A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.Type: ApplicationFiled: March 30, 2007Publication date: October 18, 2007Inventors: Richard K. Brow, Signo T. Reis, Mariano Velez, Delbert E. Day
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Publication number: 20070225146Abstract: Optical glasses are described, which are useful for imaging, sensors, microscopy, medical technology, digital protection, photolithography, laser technology, wafer/chip technology, as well as telecommunication, optical communications engineering and optics/lighting in the automotive sector, with a refractive index of 1.80?nd?1.95 and an Abbe value from 19??d?28 with excellent chemical resistance and stability to crystallization. These optical glasses have a composition, in weight % based on oxide content, of: P2O5, 14-35; Nb2O5, 45-50; Li2O, 0-4; Na2O, 0-4; K2O, 0.5-5; BaO, 17-23; ZnO, 0.1-5; TiO2, 1-<5; ZrO2, 06; and Sb2O3, 0.1-2.Type: ApplicationFiled: March 16, 2007Publication date: September 27, 2007Inventors: Silke Wolff, Stefanie Hansen, Ute Woelfel
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Patent number: 7192897Abstract: Provided are near-infrared light-absorbing glass in which good color compensating characteristics are maintained even without containing harmful arsenic, permitting the thinning of the glass, and having good weatherability and forming properties; a near-infrared light-absorbing element comprised of such glass; a near-infrared light-absorbing filter employing such glass. Also provided, at low cost, are near-infrared light-absorbing glass permitting good color compensating, a near-infrared light-absorbing element comprised of such glass, and a near-infrared light-absorbing filter comprising such elements. The glass comprises cationic components with a certain composition as well as F? and O2? as anionic components. Alternatively, the glass is near-infrared light-absorbing glass, wherein the glass exhibits properties, based on a thickness of 0.Type: GrantFiled: July 3, 2003Date of Patent: March 20, 2007Assignee: Hoya CorporationInventors: Rie Yamane, Youichi Hachitani, Xuelu Zou
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Patent number: 7157391Abstract: An optical glass being free of lead and fluorine, having a low glass transition temperature permitting press-molding with a mold formed of stainless steel and having high climate resistance includes an optical glass comprising, by mol %, 25 to 44% of P2O5, 10 to 40% of a total of Li2O, Na2O and K2O, 5 to 40% of ZnO, 1 to 35% of BaO and at least one components selected from Nb2O5, Bi2O3 and WO3, having a glass transition temperature (Tg) of 370° C. or lower and being free of lead and fluorine and an optical glass which is free of lead and fluorine, has a mass loss ratio of less than 0.25% when immersed in pure water, and has a glass transition temperature (Tg) of 370° C. or lower.Type: GrantFiled: December 24, 2003Date of Patent: January 2, 2007Assignee: Hoya CorporationInventors: Yoshiko Kasuga, Xuelu Zou
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Patent number: 7148165Abstract: Disclosed is a lead-free low softening point glass whose composition lies within the system SnO—P2O5 and containing over 5 to 30 mol % of MnO. The addition of MnO allows the water resistance and coefficient of thermal expansion of the glass to be improved without spoiling its feature of a low softening point. The lead-free low softening point glass can be prepared through a simplified production process.Type: GrantFiled: September 22, 2005Date of Patent: December 12, 2006Assignee: Tokan Material Technology Co., Ltd.Inventor: Hirohisa Masuda
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Patent number: 7141524Abstract: The lead-free, Li2O-free, CuO-free and preferably arsenic-free optical glass is suitable for applications in the fields of imaging, projection, telecommunications, optical communication technology and/or laser technology, and has a refractive index nd of 1.55?nd?1.60, an Abbe number Vd of 54?Vd?63 and a transformation temperature Tg?500° C. This optical glass has good production and processing properties and crystallization stability, and, at the same time, advantageously does not contain PbO and As2O3. These glasses contain, in percent by weight based on oxide content: P205, 43-56; ZnQ, 21-36; Al2O3, 0-6; Na2O, 0-16; K2O, 0-8; ?M2O ?16; MgO, 0-5; CaO, 0-5; BaO, 3-14; B2O3, 0-8; La2O3, 0-7. In addition, it may also contain standard refining agents.Type: GrantFiled: August 19, 2003Date of Patent: November 28, 2006Assignee: Schott AGInventors: Silke Wolff, Ute Woelfel
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Patent number: 7141525Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature (At), i.e. at most 580° C., a refractive index (nd) of at least 1.89 and an Abbe number (?d) of at most 23.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 3 to 20% B2O3 0 to 5% GeO2 more than 14 to 37% Sum of P2O5 + B2O3 + GeO2 24 to 43% Li2O 0 to 5% Na2O 0 to 8% K2O 0 to 10% Sum of Li2O + Na2O + K2O 1 to 10% Nb2O5 0 to 50% Bi2O3 12 to 67% BaO 0 to 5% WO3 0 to 12%.Type: GrantFiled: November 4, 2004Date of Patent: November 28, 2006Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 7115536Abstract: A rare earth containing glass nominally based on the ternary P2O5—WO3—Na2O-Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.Type: GrantFiled: March 5, 2003Date of Patent: October 3, 2006Assignee: Schott Glass Technologies, Inc.Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
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Patent number: 7060640Abstract: An optical glass comprises, in mass percent, 15–35% of P2O5, 40–60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (?d) within a range from 18 to 27.Type: GrantFiled: July 10, 2003Date of Patent: June 13, 2006Assignee: Kabushiki Kaisha OharaInventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
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Patent number: 7033966Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.Type: GrantFiled: May 19, 2004Date of Patent: April 25, 2006Assignee: Asahi Glass Company, LimitedInventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
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Patent number: 6995101Abstract: An optical glass having a high refractive index and high dispersion characteristics suitable for application to precision press molding to precisely mold final products without requiring grinding or polishing. An optical glass can be prepared exhibiting a refractive index in the range of from 1.75 to 2.0, and an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials. A suitable optical glass is composed of the following in molar percent: 15–30% P2O5; 0.5–15% B2O3; 5–25% Nb2O5; 6–40% WO3; 4–45% of at least one of Li2O, Na2O or K2O; 1–5% K2O; 2–9% TiO2; and 0–30% (excluding 30%) of at least one RO selected from among BaO, ZnO, and SrO; with the total content of the above-stated components being equal to or more than 95 percent.Type: GrantFiled: June 29, 2001Date of Patent: February 7, 2006Assignee: Hoya CorporationInventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
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Patent number: 6989340Abstract: Disclosed is a lead-free low softening point glass whose composition lies within the system SnO—P2O5 and containing over 5 to 30 mol % of MnO. The addition of MnO allows the water resistance and coefficient of thermal expansion of the glass to be improved without spoiling its feature of a low softening point. The lead-free low softening point glass can be prepared through a simplified production process.Type: GrantFiled: May 11, 2004Date of Patent: January 24, 2006Assignee: Tokan Material Technology Co., Ltd.Inventor: Hirohisa Masuda
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6939820Abstract: The present invention provides an antibacterial glass composition exhibiting high antibacterial performance with sufficiently sustaining antibacterial performance by adding a small amount of the antibacterial component, and an antibacterial polymer composition using the antibacterial glass composition. The present invention provides an antibacterial glass composition containing 0.1 to 5.0% by weight of Ag2O in a glass composition containing 30 to 60 mol % of P2O5, 1 to 15 mol % of one or more compounds selected from the group consisting of K2O, Na2O and Li2O, 35 to 55 mol % of one or more compounds selected from the group consisting of MgO, CaO and ZnO, and 0.01 to 3 mol % of one or more compounds selected from the group consisting of La2O3 and Y2O3.Type: GrantFiled: November 26, 2003Date of Patent: September 6, 2005Assignee: Ishisuka Garasu Kabushiki KaishaInventors: Minoru Numaguchi, Makio Nomura
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Patent number: 6878765Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.Type: GrantFiled: December 13, 2000Date of Patent: April 12, 2005Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Angelo Polese
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Patent number: 6875714Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.Type: GrantFiled: April 25, 2003Date of Patent: April 5, 2005Assignee: Minolta Co., Ltd.Inventor: Manabu Izuki
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Patent number: 6865318Abstract: Athermal optical components comprise cubic crystalline materials including silver chloride and cesium bromide, or comprise composites of at least two layers of different compositions wherein the total optical pathlength, nL, across said layers is essentially independent of temperature.Type: GrantFiled: March 28, 2000Date of Patent: March 8, 2005Assignee: Schott Glass Technologies, Inc.Inventors: Joseph Hayden, Samuel David Conzone, Alexander J. Marker, III
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Publication number: 20040259714Abstract: The present invention relates to low-dispersion optical glass having a low glass-transition temperature suited to precision press molding, a press molding preform comprised of this glass, a method of manufacturing the same, an optical element, and a method of manufacturing the same. The optical glass comprises, given as molar percentages, 28 to 50 percent of P2O5; more than 20 percent but not more than 50 percent of BaO; 1 to 20 percent MgO; a sum of Li2O, Na2O, and K2O exceeding 3 percent (with 0 to 25 percent of Li2O, greater than or equal to 0 percent and less than 10 percent of Na2O, and 0 to 12 percent of K2O); more than 0 percent but not more than 15 percent of ZnO; 0 to 25 percent of B2O3; 0 to 5 percent of Al2O3; 0 to 8 percent of Gd2O3; 0 to 20 percent of CaO; 0 to 15 percent of SrO; and 0 to 1 percent of Sb2O3; with a sum of oxide contents of P, Ba, Mg, Li, Na, K, Zn, B, Al, Gd, Ca, Sr, and Sb being greater than or equal to 98 percent. The press molding preform is comprised of the optical glass.Type: ApplicationFiled: April 16, 2004Publication date: December 23, 2004Applicant: HOYA CORPORATIONInventors: Yasuhiro Fujiwara, Xuelu Zou
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Patent number: 6809049Abstract: The present invention provides glass compositions that can be used instead of known glass compositions containing a large amount of PbO in applications such as coating ceramic substrates, e.g., alumina, or sealing fluorescent tubes or the like. The invention also provides glass forming materials containing the glass compositions as a primary component for glass formation. Glass compositions provided by the present invention are comprises essentially of primary oxide components. The primary oxide components include ZnO, B2O3 and P2O5 as essential components and Al2O3, MgO, CaO and BaO as optional components. The amount of the primary oxide components is 85 wt % or more (preferably 90 wt % or more) of the total weight of the glass composition. Typically, the primary oxide components include 45 to 80% of ZnO, 5 to 45% of B2O3, 1 to 35% of P2O5, 0 to 10% of Al2O3, 0 to 15% of MgO, 0 to 10% of CaO, and 0 to 5% of BaO.Type: GrantFiled: November 21, 2002Date of Patent: October 26, 2004Assignee: Noritake Co., Ltd.Inventor: Jun Hirose
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Publication number: 20040182285Abstract: A modified alkali silicate composition for forming an inorganic polymer matrix having improved mechanical properties. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), a non-silicate network former and/or reactive glass, water and optionally one or more multivalent cation(s) selected from Groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 of the periodic table such as an alkaline earth salt, water and optional processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and curing the composite at a temperature from about 15° C. up to 1000° C. and a pressure of up to 20,000 psi for typical high-performance organic polymer processing (temperatures about 15° C. to about 200° C. and pressures <200 psi).Type: ApplicationFiled: February 12, 2004Publication date: September 23, 2004Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
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Publication number: 20040170700Abstract: The present invention provides an antibacterial glass composition exhibiting high antibacterial performance with sufficiently sustaining antibacterial performance by adding a small amount of the antibacterial component, and an antibacterial polymer composition using the antibacterial glass composition. The present invention provides an antibacterial glass composition containing 0.1 to 5.0% by weight of Ag2O in a glass composition containing 30 to 60 mol % of P2O5, 1 to 15 mol % of one or more compounds selected from the group consisting of K2O, Na2O and Li2O, 35 to 55 mol % of one or more compounds selected from the group consisting of MgO, CaO and ZnO, and 0.01 to 3 mol % of one or more compounds selected from the group consisting of La2O3 and Y2O3.Type: ApplicationFiled: November 26, 2003Publication date: September 2, 2004Applicant: ISHIZUKA GARASU KABUSHIKI KAISHAInventors: Minoru Numaguchi, Makio Nomura
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Patent number: 6784128Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %): P2O5 32 to 40% Li2O 6 to 21% Na2O 8 to 31% K2O 4 to 22% Al2O3 7.4 to 16% ZnO 0 to 19.6% BaO 0 to 12% and Sum of Li2O + Na2O + K2O 35.1 to 49%.Type: GrantFiled: July 12, 2002Date of Patent: August 31, 2004Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Otsuka, Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
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Publication number: 20040162210Abstract: A lightweight aggregate for use in concrete exhibiting a high weight to strength ratio comprising a mixture of hydrated cement and a low sodium closed-cell foamed glass comprised of between 51 and 65 weight percent silica, between 8 and 14 weight percent alumina, between 2 and 5 weight percent soda, between 18 and 26 weight percent calcia, between 2 and 5 weight percent iron oxide, and up to 8 percent lithium oxide.Type: ApplicationFiled: February 18, 2003Publication date: August 19, 2004Inventor: Robert Dejaiffe
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Publication number: 20040138043Abstract: An optical glass being free of lead and fluorine, having a low glass transition temperature permitting press-molding with a mold formed of stainless steel and having high climate resistance includes an optical glass comprising, by mol %, 25 to 44% of P2O5, 10 to 40% of a total of Li2O, Na2O and K2O, 5 to 40% of ZnO, 1 to 35% of BaO and at least one components selected from Nb2O5, Bi2O3 and WO3, having a glass transition temperature (Tg) of 370° C. or lower and being free of lead and fluorine and an optical glass which is free of lead and fluorine, has a mass loss ratio of less than 0.25% when immersed in pure water, and has a glass transition temperature (Tg) of 370° C. or lower.Type: ApplicationFiled: December 24, 2003Publication date: July 15, 2004Inventors: Yoshiko Kasuga, Xuelu Zou
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Patent number: 6757474Abstract: A co-doped silicate optical waveguide having a core including silica, and oxides of aluminum, germanium, erbium and thulium. The composition concentrations are: Er from 15 ppm to 3000 ppm; Al from 0.5 mol % to 12 mol %; Tm from 15 ppm to 10000 ppm; and Ge from 1 mol % to 20 mol %. In a specific embodiment, the concentration of Er is from 150 ppm to 1500 ppm; Al is from 2 mol % to 8 mol %; and Tm is from 15 ppm to 3000 ppm. A boron-less cladding surrounds the core.Type: GrantFiled: November 19, 2002Date of Patent: June 29, 2004Assignee: 3M Innovative Properties CompanyInventors: Mark T. Anderson, Craig R. Schardt, James R. Onstott, Kenton D. Budd
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Patent number: 6743743Abstract: Optical glasses and optical articles comprised of the optical glass are disclosed. One of which comprises, by means of weight percentages, more than 32 percent and not more than 45 percent P2O5, more than 0.5 percent and not more than 6 percent Li2O, more than 5 percent and not more than 22 percent Na2O, 6-30 percent Nb2O5, 0.5-10 percent B2O3, 0-35 percent WO3, 0-14 percent K2O, and 10-24 percent Na2O+K2O, and the total of all the above components is not less than 80 percent.Type: GrantFiled: January 29, 2002Date of Patent: June 1, 2004Assignee: Hoya CorporationInventor: Koichi Sato
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Patent number: 6737375Abstract: Glass frit compositions, calculated in mole percent on an oxide basis, consisting essentially of 24.5 to 29.0% P2O5; 1.0 to 5.0% B2O3; 1.0 to 2.0% Al2O3; and sufficient amounts of SnO and ZnO (51.5 to 66.5% SnO, and 5.0-12.0% ZnO), wherein the molar ratio of SnO:ZnO is in the range of about 5.0:1 to 12:1, and 0.0 to 2.0% SiO2. The glass compositions exhibit, under NMR spectroscopic analysis of 11B nuclei, a signal containing at least two peaks at a chemical shift in the range of approximately −18 to −25 ppm. The frit compositions exhibit long term stability, durability, and resistance to attack against moisture in high temperature and humidity conditions and are capable of attaching optical fiber Bragg gratings without the use of a hermetic chamber and the like. An optoelectronic device that employs a sealing material that comprises a frit made from the glass compositions.Type: GrantFiled: March 16, 2001Date of Patent: May 18, 2004Assignee: Corning IncorporatedInventors: Carol L. Buhrmaster, Robert Morena, Kamjula P. Reddy, Randall E. Youngman
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Publication number: 20040092378Abstract: The lead-free and preferably arsenic-free optical glass is suitable for applications in the fields of imaging, projection, telecommunications, optical communication technology and/or laser technology, and has a refractive index nd of 1.55≦nd≦1.60, an Abbe number vd of 54≦vd≦63 and a transformation temperature Tg≦500° C. This optical glass has good production and processing properties and crystallization stability, and, at the same time, advantageously does not contain PbO and As2O3. These glasses contain, in percent by weight based on oxide content: P2O5, 43-56; ZnO, 21-36; Al2O3, 0-6; Na2O, 0-16; K2O, 0-8; &Sgr;M2O≦16; MgO, 0-5; CaO, 0-5; BaO, 3-14; B2O3, 0-8; La2O3, 0-7. In addition, it may also contain standard refining agents.Type: ApplicationFiled: August 19, 2003Publication date: May 13, 2004Inventors: Silke Wolff, Ute Woelfel
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Patent number: 6734243Abstract: A component (1) which includes a material formed from a glass/polymer mixture. The component has first regions, in which the glass is present substantially in the form of spherical particles (2) and second regions, in which the glass is present in the form of fibre-type particles (3). A component of this type advantageously provides both mechanical stability and dimensional consistency in separate areas within the same component.Type: GrantFiled: November 1, 2002Date of Patent: May 11, 2004Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Angelo Polese
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Publication number: 20040063563Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: ApplicationFiled: September 18, 2003Publication date: April 1, 2004Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Publication number: 20040018933Abstract: An optical glass comprises, in mass percent, 15-35% of P2O5, 40-60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (&ngr;d) within a range from 18 to 27.Type: ApplicationFiled: July 10, 2003Publication date: January 29, 2004Inventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
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Publication number: 20040002416Abstract: There is provided an antibacterial fiber, an antibacterial twisted yarn and an antibacterial cloth which exhibits high durability to post-processing with water, detergent, staining or the like at a small added amount.Type: ApplicationFiled: April 11, 2003Publication date: January 1, 2004Applicant: Ishizuka Garasu Kabushiki KaishaInventor: Makio Nomura
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Publication number: 20040002417Abstract: There is provided an antibacterial fiber, an antibacterial twisted yarn and an antibacterial cloth which exhibits high durability to post-processing with water, detergent, staining or the like at a small added amount.Type: ApplicationFiled: April 11, 2003Publication date: January 1, 2004Applicant: Ishizuka Garasu Kabushiki KaishaInventor: Makio Nomura
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Patent number: 6667258Abstract: Disclosed is a zinc phosphate glass consisting essentially, expressed in terms of mole percent on the oxide basis, of 31-34% P2O5, 0-2% Al2O3, 5-11% Li2O, 5-13% Na2O, 3-7% K2O, with Li2O+Na2O+K2O being 10-28%, 20-45% ZnO, 0-10% CaO, 0-10% BaO, 0-10% SrO, with CaO+BaO+SrO being 3-12%, and 0-2% SiO2, said glass exhibiting a stable glass transition temperature below 450° C., a working temperature below 500° C., and a water durability of no more than 5×10−7 g/cm2/min after immersion in water at 95° C. for 24 hours. The low-temperature glass of the present invention is particularly useful for producing glass/polymer blends. Glass/polymer blends containing the glass of the present invention are also disclosed.Type: GrantFiled: January 4, 2002Date of Patent: December 23, 2003Assignee: Corning IncorporatedInventor: Candace Jo Quinn
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Patent number: 6656859Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: December 6, 2001Date of Patent: December 2, 2003Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
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Publication number: 20030181307Abstract: A high-gain phosphate glass composition, which can be used to produce ultra-short gain length lasers and optical amplifiers is described wherein the composition of the glass in addition to exhibiting high gain for lasers and amplifiers, also exhibits high thermal shock resistance, high cross section, insignificant concentration quenching, and high solubility for rare earth ions and other properties which enable the material to be fabricated into a new class of ultra-short length micro-laser, fiber laser and amplifier configurations and designs.Type: ApplicationFiled: March 21, 2003Publication date: September 25, 2003Inventors: John D. Myers, Michael J. Myers
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Publication number: 20030105200Abstract: The invention relates to machine elements such as bearings and toothed wheels, which consist of a thermoplastic-based glass/plastic compound containing a sulfophosphate glass with a low melting point and with the following composition: 4 to 10% Li2O, 4 to 10% Na2O, 4 to 8% K2O, 1 to 2% CaO, 35 to 37% ZnO, 0 to 3% La2O3, 19 to 22% P2O5 and 19 to 22% SO3; and a high performance thermoplastic.Type: ApplicationFiled: October 2, 2002Publication date: June 5, 2003Inventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn
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Patent number: 6560009Abstract: The specification describes rare earth doped fiber amplifier devices for operation in the extended L-band, i.e. at wavelengths from 1565 nm to above 1610 nm. High efficiency and flat gain spectra are obtained using a high silica based fiber codoped with Er, Al, Ge, and P and an NA of at least 0.15.Type: GrantFiled: August 21, 2001Date of Patent: May 6, 2003Assignee: Lucent Technologies Inc.Inventors: Matthew Julius Andrejco, Inger Pihl Byriel, Bera Palsdottir