Phosphorus Containing Patents (Class 501/45)
  • Publication number: 20090023574
    Abstract: The invention relates to dental glass-ceramics and a process for producing them and their use, with these comprising at least one crystal phase containing xenotime or monazite or mixtures thereof.
    Type: Application
    Filed: May 31, 2006
    Publication date: January 22, 2009
    Applicant: Ivoclar Vivadent AG
    Inventors: Wolfram Holand, Christian Ritzberger, Volker Rheinberger, Elke Apel
  • Patent number: 7456142
    Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: November 25, 2008
    Assignee: Reckitt Benckiser N.V.
    Inventor: Karlheinz Ulrich Gerhard Hahn
  • Patent number: 7439201
    Abstract: The invention is directed to lead-free glass frit compositions that can be used as sealing frits, the compositions being a blend of: (1) at least one of two glass families which are SnO—ZnO—P2O5 and alkali-ZnO—P2O5 glasses; and (2) at least one cerammed filler material having a crystalline phase selected from the group consisting of beta-quartz, beta-eucryptite, cordierite, and beta-spodumene. The blends of the invention have flow characteristics that enable them to be used at sealing temperatures in the range of 450-550° C., and a CTE value in the range of 60-90×10?7/° C.
    Type: Grant
    Filed: August 29, 2006
    Date of Patent: October 21, 2008
    Assignee: Corning Incorporation
    Inventors: Melinda Ann Drake, Sasha Marjanovic, Lisa A. Lamberson, Robert Michael Morena
  • Patent number: 7435695
    Abstract: Disclosed are zinc niobium phosphate glasses consisting essentially, expressed in terms of mole percent on the oxide basis of, 40-65% P2O5, 25-37% ZnO, 0.1-15% Nb2O5, 0-6% Al2O3, 0-5% Bi2O3, 0-3% Na2O and 0-5% B2O3, said glass exhibiting glass transition temperature below 450° C., a dilatometer softening point below 500° C., coefficient of expansion in the range of 80-120×10?7° C.?1, good chemical durability and blue color. The glass of the present invention is useful for sealing optical fiber to ferrule by local heating.
    Type: Grant
    Filed: December 9, 2004
    Date of Patent: October 14, 2008
    Assignee: B.G. Negev Technologies and Applications Ltd.
    Inventor: Jacob Hormadaly
  • Patent number: 7396786
    Abstract: A glass containing 5 to 25 mass % of P2O5, 0 to 15 mass % of B2O3, 0 to 5 mass % of SiO2+GeO2, 21 to 50 mass % of BaO+SrO, 0 to 3 mass % of Li2O+Na2O+K2O, and 35 to 65 mass % of Nb2O5, not substantially containing PbO, satisfying Nb2O5/(BaO+SrO)=0.85 to 2.20, having a dielectric constant of 15 or greater, a dielectric loss of 10.0×10?4 or less, and a resistivity of 1.0×1016 ?·cm or more.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: July 8, 2008
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Masaaki Miyata, Kazuo Ohara
  • Patent number: 7396787
    Abstract: The lead-free, preferably lithium-free, optical glass is useful in imaging, projection, telecommunications, optical communication and/or laser technology, particularly for making precise-pressed optical elements. It has a refractive index nd of 1.50 to 1.57, an Abbé number ?d of 61 to 70. It also has a low transformation temperature of about or below 400° C., good production and processing properties and crystallization resistance. It has a composition, in percent by weight, based on oxide content of P2O5, 40 to 60; Al2O3, 1 to 20; B2O3, 0 to <5; Na2O, 0 to 30; K2O, 0 to 30; Li2O, 0 to <1; ?M2O, >15 to 40; BaO, 1 to 20; ZnO, 1 to 20; SrO, 0 to 5; CaO, 0 to 5; MgO, 0 to 5; and ?MO, 5 to 25. In addition, it may contain standard refining agents, although it is preferably free of arsenic and fluorine.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: July 8, 2008
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Ute Woelfel, Silke Wolff
  • Publication number: 20080132399
    Abstract: Disclosed are glass materials generally belonging to the P2O5—ZnO—TeO2 system and process for making the same. The glass may comprise Bi2O3 as well. The high refractive index and low Tg materials are particularly suitable for refractive lens elements for use in portable optical devices. The process involves the use of P2O5 source materials with reduced amounts of reducing agents or a step of removing the reducing agents from such source materials by an oxidizing step such as calcination.
    Type: Application
    Filed: February 7, 2007
    Publication date: June 5, 2008
    Inventors: Bruce Gardiner Aitken, James Edward Dickinson, Sinue Gomez
  • Patent number: 7371703
    Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: May 13, 2008
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Patent number: 7361632
    Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: April 22, 2008
    Assignee: Reckitt Benckiser N.V.
    Inventor: Karlheinz Ulrich Gerhard Hahn
  • Patent number: 7326367
    Abstract: This invention is related to thick film conductor compositions comprising electrically conductive gold powder, one or more glass frit or ceramic oxide compositions and an organic vehicle. It is further directed to the composition's uses for LTCC (low temperature co-fired ceramic) tape, for fabrication of multilayer electronic circuits and in high frequency microelectronic applications.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: February 5, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Patricia J. Ollivier, Kenneth Warren Hang
  • Patent number: 7312169
    Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature, a refractive index (nd) of at least 1.83 and an Abbe number (?d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 15 to 29% B2O3 ?0 to 2% GeO2 ?0 to 14% Sum of P2O5 + B2O3 + GeO2 20 to 35% Li2O ?0 to 5% Na2O ?3 to 14% K2O ?0 to 9% Sum of Li2O + Na2O + K2O ?5 to 15% Nb2O5 ?2 to less than 22% Bi2O3 34 to 60% WO3 ?0 to 5% BaO ?0 to 5% In2O3 ??0 to 7%.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: December 25, 2007
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 7309670
    Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: December 18, 2007
    Assignee: Hoya Corporation
    Inventors: Yasuhiro Fujiwara, Xuelu Zou
  • Publication number: 20070243991
    Abstract: A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 18, 2007
    Inventors: Richard K. Brow, Signo T. Reis, Mariano Velez, Delbert E. Day
  • Publication number: 20070225146
    Abstract: Optical glasses are described, which are useful for imaging, sensors, microscopy, medical technology, digital protection, photolithography, laser technology, wafer/chip technology, as well as telecommunication, optical communications engineering and optics/lighting in the automotive sector, with a refractive index of 1.80?nd?1.95 and an Abbe value from 19??d?28 with excellent chemical resistance and stability to crystallization. These optical glasses have a composition, in weight % based on oxide content, of: P2O5, 14-35; Nb2O5, 45-50; Li2O, 0-4; Na2O, 0-4; K2O, 0.5-5; BaO, 17-23; ZnO, 0.1-5; TiO2, 1-<5; ZrO2, 06; and Sb2O3, 0.1-2.
    Type: Application
    Filed: March 16, 2007
    Publication date: September 27, 2007
    Inventors: Silke Wolff, Stefanie Hansen, Ute Woelfel
  • Patent number: 7192897
    Abstract: Provided are near-infrared light-absorbing glass in which good color compensating characteristics are maintained even without containing harmful arsenic, permitting the thinning of the glass, and having good weatherability and forming properties; a near-infrared light-absorbing element comprised of such glass; a near-infrared light-absorbing filter employing such glass. Also provided, at low cost, are near-infrared light-absorbing glass permitting good color compensating, a near-infrared light-absorbing element comprised of such glass, and a near-infrared light-absorbing filter comprising such elements. The glass comprises cationic components with a certain composition as well as F? and O2? as anionic components. Alternatively, the glass is near-infrared light-absorbing glass, wherein the glass exhibits properties, based on a thickness of 0.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: March 20, 2007
    Assignee: Hoya Corporation
    Inventors: Rie Yamane, Youichi Hachitani, Xuelu Zou
  • Patent number: 7157391
    Abstract: An optical glass being free of lead and fluorine, having a low glass transition temperature permitting press-molding with a mold formed of stainless steel and having high climate resistance includes an optical glass comprising, by mol %, 25 to 44% of P2O5, 10 to 40% of a total of Li2O, Na2O and K2O, 5 to 40% of ZnO, 1 to 35% of BaO and at least one components selected from Nb2O5, Bi2O3 and WO3, having a glass transition temperature (Tg) of 370° C. or lower and being free of lead and fluorine and an optical glass which is free of lead and fluorine, has a mass loss ratio of less than 0.25% when immersed in pure water, and has a glass transition temperature (Tg) of 370° C. or lower.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: January 2, 2007
    Assignee: Hoya Corporation
    Inventors: Yoshiko Kasuga, Xuelu Zou
  • Patent number: 7148165
    Abstract: Disclosed is a lead-free low softening point glass whose composition lies within the system SnO—P2O5 and containing over 5 to 30 mol % of MnO. The addition of MnO allows the water resistance and coefficient of thermal expansion of the glass to be improved without spoiling its feature of a low softening point. The lead-free low softening point glass can be prepared through a simplified production process.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: December 12, 2006
    Assignee: Tokan Material Technology Co., Ltd.
    Inventor: Hirohisa Masuda
  • Patent number: 7141524
    Abstract: The lead-free, Li2O-free, CuO-free and preferably arsenic-free optical glass is suitable for applications in the fields of imaging, projection, telecommunications, optical communication technology and/or laser technology, and has a refractive index nd of 1.55?nd?1.60, an Abbe number Vd of 54?Vd?63 and a transformation temperature Tg?500° C. This optical glass has good production and processing properties and crystallization stability, and, at the same time, advantageously does not contain PbO and As2O3. These glasses contain, in percent by weight based on oxide content: P205, 43-56; ZnQ, 21-36; Al2O3, 0-6; Na2O, 0-16; K2O, 0-8; ?M2O ?16; MgO, 0-5; CaO, 0-5; BaO, 3-14; B2O3, 0-8; La2O3, 0-7. In addition, it may also contain standard refining agents.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: November 28, 2006
    Assignee: Schott AG
    Inventors: Silke Wolff, Ute Woelfel
  • Patent number: 7141525
    Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature (At), i.e. at most 580° C., a refractive index (nd) of at least 1.89 and an Abbe number (?d) of at most 23.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 3 to 20% B2O3 0 to 5% GeO2 more than 14 to 37% Sum of P2O5 + B2O3 + GeO2 24 to 43% Li2O 0 to 5% Na2O 0 to 8% K2O 0 to 10% Sum of Li2O + Na2O + K2O 1 to 10% Nb2O5 0 to 50% Bi2O3 12 to 67% BaO 0 to 5% WO3 0 to 12%.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: November 28, 2006
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 7115536
    Abstract: A rare earth containing glass nominally based on the ternary P2O5—WO3—Na2O-Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: October 3, 2006
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
  • Patent number: 7060640
    Abstract: An optical glass comprises, in mass percent, 15–35% of P2O5, 40–60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (?d) within a range from 18 to 27.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: June 13, 2006
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
  • Patent number: 7033966
    Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: April 25, 2006
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
  • Patent number: 6995101
    Abstract: An optical glass having a high refractive index and high dispersion characteristics suitable for application to precision press molding to precisely mold final products without requiring grinding or polishing. An optical glass can be prepared exhibiting a refractive index in the range of from 1.75 to 2.0, and an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials. A suitable optical glass is composed of the following in molar percent: 15–30% P2O5; 0.5–15% B2O3; 5–25% Nb2O5; 6–40% WO3; 4–45% of at least one of Li2O, Na2O or K2O; 1–5% K2O; 2–9% TiO2; and 0–30% (excluding 30%) of at least one RO selected from among BaO, ZnO, and SrO; with the total content of the above-stated components being equal to or more than 95 percent.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: February 7, 2006
    Assignee: Hoya Corporation
    Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
  • Patent number: 6989340
    Abstract: Disclosed is a lead-free low softening point glass whose composition lies within the system SnO—P2O5 and containing over 5 to 30 mol % of MnO. The addition of MnO allows the water resistance and coefficient of thermal expansion of the glass to be improved without spoiling its feature of a low softening point. The lead-free low softening point glass can be prepared through a simplified production process.
    Type: Grant
    Filed: May 11, 2004
    Date of Patent: January 24, 2006
    Assignee: Tokan Material Technology Co., Ltd.
    Inventor: Hirohisa Masuda
  • Patent number: 6984261
    Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: January 10, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
  • Patent number: 6939820
    Abstract: The present invention provides an antibacterial glass composition exhibiting high antibacterial performance with sufficiently sustaining antibacterial performance by adding a small amount of the antibacterial component, and an antibacterial polymer composition using the antibacterial glass composition. The present invention provides an antibacterial glass composition containing 0.1 to 5.0% by weight of Ag2O in a glass composition containing 30 to 60 mol % of P2O5, 1 to 15 mol % of one or more compounds selected from the group consisting of K2O, Na2O and Li2O, 35 to 55 mol % of one or more compounds selected from the group consisting of MgO, CaO and ZnO, and 0.01 to 3 mol % of one or more compounds selected from the group consisting of La2O3 and Y2O3.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: September 6, 2005
    Assignee: Ishisuka Garasu Kabushiki Kaisha
    Inventors: Minoru Numaguchi, Makio Nomura
  • Patent number: 6878765
    Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 12, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventors: Robert Greiner, Angelo Polese
  • Patent number: 6875714
    Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: April 5, 2005
    Assignee: Minolta Co., Ltd.
    Inventor: Manabu Izuki
  • Patent number: 6865318
    Abstract: Athermal optical components comprise cubic crystalline materials including silver chloride and cesium bromide, or comprise composites of at least two layers of different compositions wherein the total optical pathlength, nL, across said layers is essentially independent of temperature.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: March 8, 2005
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Joseph Hayden, Samuel David Conzone, Alexander J. Marker, III
  • Publication number: 20040259714
    Abstract: The present invention relates to low-dispersion optical glass having a low glass-transition temperature suited to precision press molding, a press molding preform comprised of this glass, a method of manufacturing the same, an optical element, and a method of manufacturing the same. The optical glass comprises, given as molar percentages, 28 to 50 percent of P2O5; more than 20 percent but not more than 50 percent of BaO; 1 to 20 percent MgO; a sum of Li2O, Na2O, and K2O exceeding 3 percent (with 0 to 25 percent of Li2O, greater than or equal to 0 percent and less than 10 percent of Na2O, and 0 to 12 percent of K2O); more than 0 percent but not more than 15 percent of ZnO; 0 to 25 percent of B2O3; 0 to 5 percent of Al2O3; 0 to 8 percent of Gd2O3; 0 to 20 percent of CaO; 0 to 15 percent of SrO; and 0 to 1 percent of Sb2O3; with a sum of oxide contents of P, Ba, Mg, Li, Na, K, Zn, B, Al, Gd, Ca, Sr, and Sb being greater than or equal to 98 percent. The press molding preform is comprised of the optical glass.
    Type: Application
    Filed: April 16, 2004
    Publication date: December 23, 2004
    Applicant: HOYA CORPORATION
    Inventors: Yasuhiro Fujiwara, Xuelu Zou
  • Patent number: 6809049
    Abstract: The present invention provides glass compositions that can be used instead of known glass compositions containing a large amount of PbO in applications such as coating ceramic substrates, e.g., alumina, or sealing fluorescent tubes or the like. The invention also provides glass forming materials containing the glass compositions as a primary component for glass formation. Glass compositions provided by the present invention are comprises essentially of primary oxide components. The primary oxide components include ZnO, B2O3 and P2O5 as essential components and Al2O3, MgO, CaO and BaO as optional components. The amount of the primary oxide components is 85 wt % or more (preferably 90 wt % or more) of the total weight of the glass composition. Typically, the primary oxide components include 45 to 80% of ZnO, 5 to 45% of B2O3, 1 to 35% of P2O5, 0 to 10% of Al2O3, 0 to 15% of MgO, 0 to 10% of CaO, and 0 to 5% of BaO.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: October 26, 2004
    Assignee: Noritake Co., Ltd.
    Inventor: Jun Hirose
  • Publication number: 20040182285
    Abstract: A modified alkali silicate composition for forming an inorganic polymer matrix having improved mechanical properties. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), a non-silicate network former and/or reactive glass, water and optionally one or more multivalent cation(s) selected from Groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 of the periodic table such as an alkaline earth salt, water and optional processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and curing the composite at a temperature from about 15° C. up to 1000° C. and a pressure of up to 20,000 psi for typical high-performance organic polymer processing (temperatures about 15° C. to about 200° C. and pressures <200 psi).
    Type: Application
    Filed: February 12, 2004
    Publication date: September 23, 2004
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Publication number: 20040170700
    Abstract: The present invention provides an antibacterial glass composition exhibiting high antibacterial performance with sufficiently sustaining antibacterial performance by adding a small amount of the antibacterial component, and an antibacterial polymer composition using the antibacterial glass composition. The present invention provides an antibacterial glass composition containing 0.1 to 5.0% by weight of Ag2O in a glass composition containing 30 to 60 mol % of P2O5, 1 to 15 mol % of one or more compounds selected from the group consisting of K2O, Na2O and Li2O, 35 to 55 mol % of one or more compounds selected from the group consisting of MgO, CaO and ZnO, and 0.01 to 3 mol % of one or more compounds selected from the group consisting of La2O3 and Y2O3.
    Type: Application
    Filed: November 26, 2003
    Publication date: September 2, 2004
    Applicant: ISHIZUKA GARASU KABUSHIKI KAISHA
    Inventors: Minoru Numaguchi, Makio Nomura
  • Patent number: 6784128
    Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %): P2O5   32 to 40% Li2O   6 to 21% Na2O   8 to 31% K2O   4 to 22% Al2O3  7.4 to 16% ZnO   0 to 19.6% BaO   0 to 12% and Sum of Li2O + Na2O + K2O 35.1 to 49%.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: August 31, 2004
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Otsuka, Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
  • Publication number: 20040162210
    Abstract: A lightweight aggregate for use in concrete exhibiting a high weight to strength ratio comprising a mixture of hydrated cement and a low sodium closed-cell foamed glass comprised of between 51 and 65 weight percent silica, between 8 and 14 weight percent alumina, between 2 and 5 weight percent soda, between 18 and 26 weight percent calcia, between 2 and 5 weight percent iron oxide, and up to 8 percent lithium oxide.
    Type: Application
    Filed: February 18, 2003
    Publication date: August 19, 2004
    Inventor: Robert Dejaiffe
  • Publication number: 20040138043
    Abstract: An optical glass being free of lead and fluorine, having a low glass transition temperature permitting press-molding with a mold formed of stainless steel and having high climate resistance includes an optical glass comprising, by mol %, 25 to 44% of P2O5, 10 to 40% of a total of Li2O, Na2O and K2O, 5 to 40% of ZnO, 1 to 35% of BaO and at least one components selected from Nb2O5, Bi2O3 and WO3, having a glass transition temperature (Tg) of 370° C. or lower and being free of lead and fluorine and an optical glass which is free of lead and fluorine, has a mass loss ratio of less than 0.25% when immersed in pure water, and has a glass transition temperature (Tg) of 370° C. or lower.
    Type: Application
    Filed: December 24, 2003
    Publication date: July 15, 2004
    Inventors: Yoshiko Kasuga, Xuelu Zou
  • Patent number: 6757474
    Abstract: A co-doped silicate optical waveguide having a core including silica, and oxides of aluminum, germanium, erbium and thulium. The composition concentrations are: Er from 15 ppm to 3000 ppm; Al from 0.5 mol % to 12 mol %; Tm from 15 ppm to 10000 ppm; and Ge from 1 mol % to 20 mol %. In a specific embodiment, the concentration of Er is from 150 ppm to 1500 ppm; Al is from 2 mol % to 8 mol %; and Tm is from 15 ppm to 3000 ppm. A boron-less cladding surrounds the core.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: June 29, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Mark T. Anderson, Craig R. Schardt, James R. Onstott, Kenton D. Budd
  • Patent number: 6743743
    Abstract: Optical glasses and optical articles comprised of the optical glass are disclosed. One of which comprises, by means of weight percentages, more than 32 percent and not more than 45 percent P2O5, more than 0.5 percent and not more than 6 percent Li2O, more than 5 percent and not more than 22 percent Na2O, 6-30 percent Nb2O5, 0.5-10 percent B2O3, 0-35 percent WO3, 0-14 percent K2O, and 10-24 percent Na2O+K2O, and the total of all the above components is not less than 80 percent.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: June 1, 2004
    Assignee: Hoya Corporation
    Inventor: Koichi Sato
  • Patent number: 6737375
    Abstract: Glass frit compositions, calculated in mole percent on an oxide basis, consisting essentially of 24.5 to 29.0% P2O5; 1.0 to 5.0% B2O3; 1.0 to 2.0% Al2O3; and sufficient amounts of SnO and ZnO (51.5 to 66.5% SnO, and 5.0-12.0% ZnO), wherein the molar ratio of SnO:ZnO is in the range of about 5.0:1 to 12:1, and 0.0 to 2.0% SiO2. The glass compositions exhibit, under NMR spectroscopic analysis of 11B nuclei, a signal containing at least two peaks at a chemical shift in the range of approximately −18 to −25 ppm. The frit compositions exhibit long term stability, durability, and resistance to attack against moisture in high temperature and humidity conditions and are capable of attaching optical fiber Bragg gratings without the use of a hermetic chamber and the like. An optoelectronic device that employs a sealing material that comprises a frit made from the glass compositions.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: May 18, 2004
    Assignee: Corning Incorporated
    Inventors: Carol L. Buhrmaster, Robert Morena, Kamjula P. Reddy, Randall E. Youngman
  • Publication number: 20040092378
    Abstract: The lead-free and preferably arsenic-free optical glass is suitable for applications in the fields of imaging, projection, telecommunications, optical communication technology and/or laser technology, and has a refractive index nd of 1.55≦nd≦1.60, an Abbe number vd of 54≦vd≦63 and a transformation temperature Tg≦500° C. This optical glass has good production and processing properties and crystallization stability, and, at the same time, advantageously does not contain PbO and As2O3. These glasses contain, in percent by weight based on oxide content: P2O5, 43-56; ZnO, 21-36; Al2O3, 0-6; Na2O, 0-16; K2O, 0-8; &Sgr;M2O≦16; MgO, 0-5; CaO, 0-5; BaO, 3-14; B2O3, 0-8; La2O3, 0-7. In addition, it may also contain standard refining agents.
    Type: Application
    Filed: August 19, 2003
    Publication date: May 13, 2004
    Inventors: Silke Wolff, Ute Woelfel
  • Patent number: 6734243
    Abstract: A component (1) which includes a material formed from a glass/polymer mixture. The component has first regions, in which the glass is present substantially in the form of spherical particles (2) and second regions, in which the glass is present in the form of fibre-type particles (3). A component of this type advantageously provides both mechanical stability and dimensional consistency in separate areas within the same component.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: May 11, 2004
    Assignee: Siemens Aktiengesellschaft
    Inventors: Robert Greiner, Angelo Polese
  • Publication number: 20040063563
    Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Application
    Filed: September 18, 2003
    Publication date: April 1, 2004
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Publication number: 20040018933
    Abstract: An optical glass comprises, in mass percent, 15-35% of P2O5, 40-60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (&ngr;d) within a range from 18 to 27.
    Type: Application
    Filed: July 10, 2003
    Publication date: January 29, 2004
    Inventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
  • Publication number: 20040002416
    Abstract: There is provided an antibacterial fiber, an antibacterial twisted yarn and an antibacterial cloth which exhibits high durability to post-processing with water, detergent, staining or the like at a small added amount.
    Type: Application
    Filed: April 11, 2003
    Publication date: January 1, 2004
    Applicant: Ishizuka Garasu Kabushiki Kaisha
    Inventor: Makio Nomura
  • Publication number: 20040002417
    Abstract: There is provided an antibacterial fiber, an antibacterial twisted yarn and an antibacterial cloth which exhibits high durability to post-processing with water, detergent, staining or the like at a small added amount.
    Type: Application
    Filed: April 11, 2003
    Publication date: January 1, 2004
    Applicant: Ishizuka Garasu Kabushiki Kaisha
    Inventor: Makio Nomura
  • Patent number: 6667258
    Abstract: Disclosed is a zinc phosphate glass consisting essentially, expressed in terms of mole percent on the oxide basis, of 31-34% P2O5, 0-2% Al2O3, 5-11% Li2O, 5-13% Na2O, 3-7% K2O, with Li2O+Na2O+K2O being 10-28%, 20-45% ZnO, 0-10% CaO, 0-10% BaO, 0-10% SrO, with CaO+BaO+SrO being 3-12%, and 0-2% SiO2, said glass exhibiting a stable glass transition temperature below 450° C., a working temperature below 500° C., and a water durability of no more than 5×10−7 g/cm2/min after immersion in water at 95° C. for 24 hours. The low-temperature glass of the present invention is particularly useful for producing glass/polymer blends. Glass/polymer blends containing the glass of the present invention are also disclosed.
    Type: Grant
    Filed: January 4, 2002
    Date of Patent: December 23, 2003
    Assignee: Corning Incorporated
    Inventor: Candace Jo Quinn
  • Patent number: 6656859
    Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: December 2, 2003
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
  • Publication number: 20030181307
    Abstract: A high-gain phosphate glass composition, which can be used to produce ultra-short gain length lasers and optical amplifiers is described wherein the composition of the glass in addition to exhibiting high gain for lasers and amplifiers, also exhibits high thermal shock resistance, high cross section, insignificant concentration quenching, and high solubility for rare earth ions and other properties which enable the material to be fabricated into a new class of ultra-short length micro-laser, fiber laser and amplifier configurations and designs.
    Type: Application
    Filed: March 21, 2003
    Publication date: September 25, 2003
    Inventors: John D. Myers, Michael J. Myers
  • Publication number: 20030105200
    Abstract: The invention relates to machine elements such as bearings and toothed wheels, which consist of a thermoplastic-based glass/plastic compound containing a sulfophosphate glass with a low melting point and with the following composition: 4 to 10% Li2O, 4 to 10% Na2O, 4 to 8% K2O, 1 to 2% CaO, 35 to 37% ZnO, 0 to 3% La2O3, 19 to 22% P2O5 and 19 to 22% SO3; and a high performance thermoplastic.
    Type: Application
    Filed: October 2, 2002
    Publication date: June 5, 2003
    Inventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn
  • Patent number: 6560009
    Abstract: The specification describes rare earth doped fiber amplifier devices for operation in the extended L-band, i.e. at wavelengths from 1565 nm to above 1610 nm. High efficiency and flat gain spectra are obtained using a high silica based fiber codoped with Er, Al, Ge, and P and an NA of at least 0.15.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: May 6, 2003
    Assignee: Lucent Technologies Inc.
    Inventors: Matthew Julius Andrejco, Inger Pihl Byriel, Bera Palsdottir