Boron Containing Patents (Class 501/49)
  • Patent number: 4732875
    Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: March 22, 1988
    Assignee: Hoya Corporation
    Inventor: Koji Sagara
  • Patent number: 4725383
    Abstract: A process is disclosed for volume reduction and solidification of a radioactive waste solution mainly composed of sodium borate and discharged from a pressurized water reactor. The process comprises adding to said radioactive waste solution, ZnO or a mixture of ZnO with Al.sub.2 O.sub.3 and/or CaO, and then subjecting the resulting mixture to dehydration and melting to produce a vitrified solid solution. Said process is safe and reliable. A vitrified solid solution produced by said process is safe and stable.
    Type: Grant
    Filed: October 27, 1986
    Date of Patent: February 16, 1988
    Assignee: Ebara Corporation
    Inventors: Tadamasa Hayashi, Toyoshi Mizushima
  • Patent number: 4717690
    Abstract: An overglaze ink comprising(a) 55 to 70 weight % of a glass composition, the glass composition comprising(1) 15 to 43 weight % of a main glass component selected from the group consisting of BaO, SrO and SrO+BaO,(2) a glass forming component comprising34 to 45 weight % B.sub.2 O.sub.3 and0 to 6 weight % SiO.sub.2(3) 0 to 2 weight % of a colorant selected from the group consisting of Cr.sub.2 O.sub.3, CoO and NiO,(4) 7 to 20 weight % of a thermal expansion modifier selected from the group consisting of ZnO, Al.sub.2 O.sub.3, TiO.sub.2 and mixtures thereof, and(5) 1 to 7 weight % of a dopant comprising one or more of the following:ZnF.sub.2 having a weight % of 0 to 5,Li.sub.2 O having a weight % of 0 to 2,Na.sub.2 O having a weight % of 0 to 2,K.sub.2 O having a weight % of 0 to 2,LiF having a weight % of 0 to 2,NaF having a weight % of 0 to 2,KF having a weight % of 0 to 2,BaF.sub.2 having a weight % of 0 to 2,Na.sub.2 SiF.sub.6 having a weight % of 0 to 2,PbO having a weight % of 0 to 3,V.sub.2 O.sub.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: January 5, 1988
    Assignee: Heraeus, Inc. Cermalloy Division
    Inventors: Dana L. Hankey, Robert C. Sutterlin
  • Patent number: 4703019
    Abstract: The invention relates to a photosensitive and heat-sensitive glass which is composed of 25-70 mol % of Al.sub.2 O.sub.3 and/or Ga.sub.2 O.sub.3, 30-75 mol % of at least one of CaO, BaO, SrO and MgO and 0-40 mol % of an auxiliary component which is at least one of SiO.sub.2, GeO.sub.2, B.sub.2 O.sub.3 and P.sub.2 O.sub.5. The glass is produced by melting a batch mixture of powdery raw materials. By exposure to UV rays the glass colors in yellowish brown, and the color does not fade by termination of the exposure. Bleaching of the colored glass is accomplished by heating for a short time at about 150.degree.-300.degree. C. Coloration and bleaching can be repeated without deterioration. The same glass turns into an opaline foam glass, which presents a very attractive appearance, by heat treatment at a temperature above the softening temperature. This change is irreversible. The foams created in the glass matrix are usually tens of microns in diameter.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: October 27, 1987
    Assignee: Central Glass Company, Limited
    Inventors: Yoshihiro Abe, Hideo Hosono
  • Patent number: 4684616
    Abstract: Use of borax in the removal of and/or to prevent the build-up of slag on heat transfer surfaces in glass manufacture and allied industries. The borax may be used in association with a minor amount of a transition metal acetylacetonate. The borax is preferably applied directly onto the heat recuperator tubes.
    Type: Grant
    Filed: February 24, 1986
    Date of Patent: August 4, 1987
    Inventor: Patrick J. Trears
  • Patent number: 4649126
    Abstract: The invention relates to halide-containing glass. Glass with anionic conductivity for fluorine comprises PbO, F, and a glass-forming agent. As the glass-forming agent boron oxide (B.sub.2 O.sub.3) is used, with the following proportions of the components, per cent by mass:PbO: 86.0 to 87.0F: 3.5 to 0.5B.sub.2 O.sub.3 : 10.5 to 12.5Glass with anionic conductivity for fluorine is intended, mainly, for making dividers of electric signals.
    Type: Grant
    Filed: June 7, 1985
    Date of Patent: March 10, 1987
    Assignee: Institut Kibernetiki Akademii Nauk Gruzinskoi SSR
    Inventors: Khanzerifa I. Gaprindashvili, Vadim E. Kogan, Dzhemal I. Kekelia, Alexei A. Pronkin, Nana A. Salukvadze, Georgy V. Bakuradze, Konstantin K. Evstropiev, deceased
  • Patent number: 4612295
    Abstract: A glass for an eye glass lens comprising a SiO.sub.2 (or B.sub.2 O.sub.3)-CaO-Nb.sub.2 O.sub.5 system as a basic system and having a refractive index of 1.79 or more, an Abbe number of 32 to 38 and a specific gravity of less than 3.6 is disclosed.
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: September 16, 1986
    Assignee: Hoya Corporation
    Inventor: Hiroji Sagara
  • Patent number: 4595528
    Abstract: A method of immobilizing boric acid liquid wastes containing radionuclides by neutralizing the solution and evaporating the resulting precipitate to near dryness. The dry residue is then fused into a reduced volume, insoluble, inert, solid form containing substantially all the radionuclides.
    Type: Grant
    Filed: May 10, 1984
    Date of Patent: June 17, 1986
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Wilbur O. Greenhalgh
  • Patent number: 4539509
    Abstract: A lead-free sealing glass consisting essentially of, in parts by weight, 8-25 BaO, 20-35 B.sub.2 O.sub.3, and 45-72 Sb.sub.2 O.sub.3 except for incidental impurities, residual fluxes and refining agents provides an improved molten sealing action especially useful for high temperature electric lamp envelopes and other electrical devices. More particularly, a protective molten seal utilizing said sealing glass is formed between a refractory metal inlead which extends into a larger sized opening of a fused quartz member by filling the free space between said opening in the fused quartz member and the refractory metal inlead with the aforementioned sealing glass composition and thereafter converting the sealing glass to a molten condition during device operation.
    Type: Grant
    Filed: December 17, 1982
    Date of Patent: September 3, 1985
    Assignee: General Electric Company
    Inventor: Arun K. Varshneya
  • Patent number: 4521641
    Abstract: A solder glass comprised of about 65 weight percent Sb.sub.2 O.sub.3 ; about 30 weight percent B.sub.2 O.sub.3 and about 5 weight percent V.sub.2 O.sub.5. The glass is black and extremely visible when employed as a molten seal in electrical devices such as tungsten-halogen lamps.
    Type: Grant
    Filed: January 4, 1984
    Date of Patent: June 4, 1985
    Assignee: GTE Products Corporation
    Inventors: Richard G. Snell, Fredrick A. Loughridge
  • Patent number: 4513070
    Abstract: Electrochemical devices use a vitreous material having a general formulaxAaR.sub.b --yNmRc--zN.sub.n Y.sub.pwherein A is Si, Ge, P, S, B, Nb, As, V, Cr or Mo; R is O, S or Se; N is Li, Na, K or Ag and Y is I, Br, Cl, F, ClO.sub.4, CF.sub.3, SO.sub.3, SCN or SO.sub.4 with the proviso that the material contain at least two salts NY. Such materials have increased cationic conductivity.
    Type: Grant
    Filed: February 8, 1983
    Date of Patent: April 23, 1985
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Brigitte Carette, Ali Kone, Jean-Louis Souquet, Michel Ribes, Maurice Maurin
  • Patent number: 4493944
    Abstract: A solder glass comprising, by weight, about 65% Sb.sub.2 O.sub.3 ; about 30% B.sub.2 O.sub.3 ; and about 5% PbO. The glass is molten at about 350.degree. C. and can be employed as a molten seal in electrical devices such as tungsten-halogen lamps.
    Type: Grant
    Filed: January 4, 1984
    Date of Patent: January 15, 1985
    Assignee: GTE Products Corporation
    Inventors: Richard G. Snell, Fredrick A. Loughridge
  • Patent number: 4492814
    Abstract: A solder glass comprising, by weight, about 65% Sb.sub.2 O.sub.3 ; about 30% B.sub.2 O.sub.3 ; and about 5% Bi.sub.2 O.sub.3. The glass is molten at about 350.degree. C. and can be employed as a molten seal in electrical devices such as tungsten-halogen lamps.
    Type: Grant
    Filed: January 4, 1984
    Date of Patent: January 8, 1985
    Assignee: GTE Products Corporation
    Inventors: Richard G. Snell, Fredrick A. Loughridge
  • Patent number: 4352889
    Abstract: A powder having a negative coefficient of linear thermal expansion and sealing compositions containing the same are disclosed wherein the powder is a .beta.-eucryptite particle having on the surface thereof a layer of tin oxide, titanium oxide, and/or zirconium oxide.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: October 5, 1982
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Akio Takami, Kazuo Kondo
  • Patent number: 4342943
    Abstract: A glass composition is disclosed that is useful as a solder glass for sealing components together. However, the glass is also especially adapted for use as an electric resistance film for coating the inner neck or funnel portions of a cathode ray tube to reduce arcing. The glass composition includes primarily the oxides of vanadium and phosphorous with the preferred addition of either zinc oxide or lead oxide. Still other metal oxides may be optionally included such as oxides of barium, antimony, lithium, manganese, silicon, boron, molybdenum and mixtures thereof.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: August 3, 1982
    Assignee: Owens-Illinois, Inc.
    Inventor: Edward A. Weaver
  • Patent number: 4340693
    Abstract: A range of titano-borate glass compositions e.g. for use as cross linking agents in the preparation of polycarboxylic acid cements. The glass may contain one or more further metal oxides, for example calcium and/or zinc, and typically comprises 25-40 mole % calcium, 45-65 mole % boric oxide and up to 15 mole % titanium dioxide. The specification also describes the preparation of polycarboxylic acid, typically polyacrylic acid, cements incorporating the glasses.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: July 20, 1982
    Assignee: International Standard Electric Corporation
    Inventors: Cyril F. Drake, Francesca M. Shreeve
  • Patent number: 4330596
    Abstract: In practice no sealing glasses are known with which glass or ceramic material having a coefficient of thermal expansion .alpha..sub.30.degree.-300.degree. C. in the range between 31 to 36.times.10.sup.-7 per .degree.C. can be sealed together.The invention provides bodies which are composed of at least two parts, these parts having been made from a material having a coefficient of expansion as mentioned above, the parts having been sealed together by means of a sealing glass containing 8-10 weight % vanadium pentoxide, 1.5-3.0 weight % copper (II) oxide, 1-3 weight % lead (II) oxide, 0-1 weight % silicon oxide, 0-5 weight % aluminium oxide, 26-28 weight % boron oxide and 58-61 weight % zinc oxide. The weight ratio of boron oxide to zinc oxide is in the range from 0.45 to 0.47.The body is composed of parts (1 and 3), which have been sealed together by means of the sealing glass (2).
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: May 18, 1982
    Assignee: U.S. Philips Corporation
    Inventor: Paul J. Van Assche
  • Patent number: 4311772
    Abstract: This invention is directed to the production of sealing glasses capable of forming strong, non-porous seals with glasses containing at least 10% by weight of an alkali metal oxide such as are used in the fabrication of the glass membranes utilized in sodium-sulfur and potassium-sulfur batteries. The inventive seals require an interdiffusion of ions to occur between the sealing glass and the glass being sealed. Glasses presently employed as membrane glasses for such batteries have base compositions within the Na.sub.2 O-B.sub.2 O.sub.3 and K.sub.2 O-B.sub.2 O.sub.3 systems. The inventive sealing glasses consist essentially, expressed in mole percent on the oxide basis, of about 3-30% R.sub.2 O and 60-95% B.sub.2 O.sub.3, wherein R.sub.2 O consists of K.sub.2 O, Rb.sub.2 O, Cs.sub.2 O, and mixtures thereof and, optionally, Al.sub.2 O.sub.3 is substituted for up to one-half the B.sub.2 O.sub.3 content on a molar basis.
    Type: Grant
    Filed: October 9, 1980
    Date of Patent: January 19, 1982
    Assignee: Corning Glass Works
    Inventor: Andrew Herczog
  • Patent number: 4293439
    Abstract: A solder glass suspension for sealing glass or other ceramic parts is provided having the characteristics of a reversible gel, exhibiting high viscosity during storage and after extrusion onto a sealing surface, but relatively low viscosity under shear stress during extrusion. The use of the suspension for sealing glass or ceramic parts is also described.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: October 6, 1981
    Assignee: Corning Glass Works
    Inventors: Daniel W. Corbett, Donald L. Guile