And Yttrium Or Rare Earth (i.e., Elements With Atomic Numbers 39, 57-71, Or 89+) Patents (Class 501/50)
  • Patent number: 8148280
    Abstract: An optical glass of the present invention has optical constants of a refractive index (nd) within a range from 1.75 to 1.85 and an Abbe number (?d) within a range from 35 to 45, comprises SiO2 and B2O3 as essential components and one or more components selected from the group consisting of ZrO2, Nb2O5, Ta2O5 and WO3, has a glass transition temperature (Tg) of 580° C. or below and has weathering resistance (surface method) of Class 1 or Class 2.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: April 3, 2012
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Susumu Uehara
  • Patent number: 8127570
    Abstract: A high-refractivity low-dispersion optical glass that can be stably supplied and has excellent glass stability and that has coloring reduced, comprises, by mass %, 5 to 32% of total of SiO2 and B2O3, 45 to 65% of total of La2O3, Gd2O3 and Y2O3, 0.5 to 10% of ZnO, 1 to 20% of total of TiO2 and Nb2O5, 0 to 15% of ZrO2, 0 to 2% of WO3, 0 to 20% of Yb2O3, 0 to 10% of total of Li2O, Na2O and K2O, 0 to 10% of total of MgO, CaO, SrO and BaO, 0 to 12% of Ta2O5, 0 to 5% of GeO2, 0 to 10% of Bi2O3, and 0 to 10% of Al2O3, wherein the mass ratio of the content of SiO2 to the content of B2O3, (SiO2/B2O3), is from 0.3 to 1.0, and the mass ratio of the total content of Gd2O3 and Y2O3 to the total content of La2O3, Gd2O3 and Y2O3, (Gd2O3+Y2O3)/(La2O3+Gd2O3+Y2O3), is from 0.05 to 0.6, the optical glass having a refractive index nd of 1.89 to 2.0 and an Abbe's number ?d of 32 to 38 and having a coloring degree ?70 of 430 nm or less.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: March 6, 2012
    Assignee: Hoya Corporation
    Inventors: Tomoaki Negishi, Xuelu Zou
  • Patent number: 8114796
    Abstract: The lead-free and fluorine-free optical glass has a refractive index of 1.60?nd?1.64 and an Abbe number of from 56?vd?64, a transformation temperature less than or equal to 590° C., can be precise pressed and is stable to cystallization. The glass has the following, composition (in weight-% based on oxide content. P2O5, 26-35; B2O3, 10-15; Al2O3, 5.5-10; BaO, 25-37; SrO, 0-6; CaO, 8-15; ZnO, 3-10; Bi2O3, 0-8; Na2O, 0-2; K2O, 0-2; WO3, 0-10; La2O3, 0-2; Nb2O5, 0-1; TiO2,0-<1; ? alkaline earth metal oxides ?40; ? alkali metal oxides, 0-2 and at least one fining agent, 0-0.5.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: February 14, 2012
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Ute Woelfel
  • Patent number: 8110514
    Abstract: An optical glass that is an oxide glass having a very high refractive index in spite of its low-dispersion property, having excellent glass stability and having less susceptibility to coloring.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: February 7, 2012
    Assignee: Hoya Corporation
    Inventors: Tomoaki Negishi, Xuelu Zou
  • Patent number: 8110515
    Abstract: A glass composition that simultaneously has a low temperature coefficient of refractive index and a good light transmittance, being suitable for use in environments of intense temperature change. There is provided an optical glass containing SiO2, B2O3 and La2O3, which has a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 10.0×10?6 (° C.?1) or below. Further, there is provided an optical glass mentioned above having a temperature coefficient (20° to 40° C.) of relative refractive index (546.07 nm) of 4.6×10?6 (° C.?1) or below. Still further, there is provided an optical glass mentioned above having an internal transmittance (?;10 mm) at 400 nm of 80% or higher.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: February 7, 2012
    Assignee: Ohara, Inc.
    Inventor: Koji Shimizu
  • Patent number: 8110513
    Abstract: A glass composition comprising: (A) TeO2 (50-95 mol %); (B) B2O3 (1-33 mol %); (C) ZnO (1-37 mol %); (D) Bi2O3 (1-18 mol %); (E) P2O5 (0-15 mol %); (F) R2O (0-13 mol %), where R represents at least one element selected from the group consisting of Li, Na, and K; (G) MO (0-13 mol %), where M represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba; (H) TiO2 (0-13 mol %); (I) Nb2O5 (0-10 mol %); (J) Ta2O5 (0-13 mol %); (K) L2O3 (0-11 mol %), where L represents at least one element selected from the group consisting of yttrium and lanthanoids; and (L) the total amount of P2O5, R2O, MO, TiO2, Nb2O5, Ta2O5, and L2O3 described in (E) to (K), respectively, is 0-15 mol %.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: February 7, 2012
    Assignee: Nikon Corporation
    Inventors: Motoi Ueda, Takashi Ozawa, Kiyoaki Shinohara
  • Patent number: 8080491
    Abstract: An optical glass having high refractive index and low dispersion properties. There is provided an optical glass having an Abbe number (?d) and a refractive index (nd) in a region indicated by a shape bound by connecting three points, A(53, 1.70), B(53, 1.87), and C(40, 1.87) with straight lines on an orthogonal xy-coordinate system with the x-axis designating the Abbe number and the y-axis designating the refractive index; and comprising no less than 25% and no more than 65% of a combination of a SiO2 component and a B2O3 component, no less than 20% and no more than 55% of a Ln2O3 component (Ln represents at least one species selected from the group consisting of La, Gd, Dy, Yb, and Lu), and a ratio of a La2O3 component to a Ln2O3 component being no more than 0.6, by mol % on the basis of oxides.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: December 20, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Patent number: 8053384
    Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising no less than 5 mol % and no more than 60 mol % of a B2O3 component, and no less than 0.2 mol % and no more than 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: November 8, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Patent number: 8053383
    Abstract: To provide a light-amplifying glass capable of increasing absorption of Yb3+. A light-amplifying glass to be used for amplifying light having a wavelength of 1.0 to 1.2 ?m, which comprises, as represented by mol % based on the following oxides, from 30 to 55% of Bi2O3, from 25 to 50% of either one, or both in total, of SiO2 and B2O3, from 12 to 27% of either one, or both in total, of Al2O3 and Ga2O3, from 0 to 4% of La2O3 and from 0.1 to 4% of Yb2O3 and which contains substantially no Er2O3. An optical waveguide having such a light-amplifying glass as a core.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: November 8, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Seiki Ohara, Yuki Kondo
  • Patent number: 8039408
    Abstract: The optical glass of the present invention has a refractive index nd of 1.70 or greater and an Abbé number of 50 or greater. Given as mole percentages, it comprises: B2O3 20 to 80 percent, SiO2 0 to 30 percent, Li2O 1 to 25 percent; ZnO 0 to 20 percent, La2O3 4 to 30 percent, Gd2O3 1 to 25 percent, Y2O3 0 to 20 percent, ZrO2 0 to 5 percent, MgO 0 to 25 percent, CaO 0 to 15 percent, SrO 0 to 10 percent, with the combined quantity of the above components being 97 percent or greater. The molar ratio of {ZnO/(La2O3+Gd2O3+Y2O3)} is 0.8 or less and the molar ratio of {(CaO +SrO+BaO)/(La2O3+Gd2O3+Y2O3)} is 0.8 or less. Ta2O5 may be incorporated as an optional component, with the molar ratio {(ZrO2+Ta2O5)/(La2O3+Gd2O3+Y2O3)}being 0.4 or less. The present invention further relates to a preform for precision press molding comprised of this glass, an optical element comprised of this glass, and methods of manufacturing the same.
    Type: Grant
    Filed: March 28, 2007
    Date of Patent: October 18, 2011
    Assignee: Hoya Corporation
    Inventor: Yasuhiro Fujiwara
  • Patent number: 8034733
    Abstract: An optical glass comprises, denoted as weight percentages, SiO2-2-22%, B2O3: 3-24%, ZnO:>8% and ?30%, CaO+BaO+ZnO: 10-50%, MgO: 0-3%, La2O3+Y2O3+Gd2O3+Yb2O3: 1-33%, TiO2: 2-20%, ZrO2: 0-10%, Nb2O5: 2-32%, Li2O: 0-5%, Na2O: 0-8%, K2O: 0-10%, WO3: 0-20%. The ratio by weight of La2O3 to the combined contents of La2O3, Y2O3, Gd2O3, and Yb2O3 (La2O3/(La2O3+Y2O3+Gd2O3+Yb2O3)) falls within a range of 0.7 to 1.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: October 11, 2011
    Assignee: Hoya Corporation
    Inventors: Yuta Kobayashi, Yoichi Hachitani
  • Patent number: 7998891
    Abstract: Optical glass having a refractive index (nd) of 1.85 or greater, and an Abbe number (?d) falling within the range of 10 to 30, which is suited for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 3 to 60%, Bi2O3 in an amount of 25 to 80%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole percentage, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 480° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 600 nm for a thickness of 10 mm.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: August 16, 2011
    Assignee: Ohara Inc.
    Inventor: Jie Fu
  • Publication number: 20110172076
    Abstract: To provide a light-amplifying glass capable of increasing absorption of Yb3+. A light-amplifying glass to be used for amplifying light having a wavelength of 1.0 to 1.2 ?m, which comprises, as represented by mol % based on the following oxides, from 30 to 55% of Bi2O3, from 25 to 50% of either one, or both in total, of SiO2 and B2O3, from 12 to 27% of either one, or both in total, of Al2O3 and Ga2O3, from 0 to 4% of La2O3 and from 0.1 to 4% of Yb2O3 and which contains substantially no Er2O3. An optical waveguide having such a light-amplifying glass as a core.
    Type: Application
    Filed: March 25, 2011
    Publication date: July 14, 2011
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Seiki OHARA, Yuki Kondo
  • Publication number: 20110160032
    Abstract: An object of the present invention is to provide optical glass having improved glass-devitrification resistance and moldability without causing reduction in refractive index, and also provide an optical element using the optical glass as a raw material. Specifically, the present invention provides an optical glass containing components of, by mol %: B2O3: over 60% through 75%; Bi2O3: 24% to 39%; La2O3: 7% or lower; Gd2O3: 7% or lower; and ZrO2: 7% or lower.
    Type: Application
    Filed: December 22, 2010
    Publication date: June 30, 2011
    Inventor: Yoshinori Yamamoto
  • Publication number: 20110135931
    Abstract: Provided is a glass composition for electrode formation including, as a glass composition expressed in terms of oxides by mass %, 73.1 to 90% of Bi2O3, 2 to 14.5% of B2O3, 0 to 25% of ZnO, 0.2 to 20% of MgO+CaO+SrO+BaO (total content of MgO, CaO, SrO, and BaO) , and 0 to 8.5% of SiO2+Al2O3 (total content of SiO2 and Al2O3).
    Type: Application
    Filed: September 1, 2009
    Publication date: June 9, 2011
    Inventor: Kentaro Ishihara
  • Patent number: 7955998
    Abstract: A high-refractivity optical glass which has both a low-temperature softening property suitable for precision press-molding and glass stability suitable for hot-shaping of a preform, which contains, by mass %, 13 to 30% of B2O3, 0.1 to 4% of Li2O, 17 to 35% of ZnO, 15 to 45% of La2O3, 4 to 15% of Ta2O5 exclusive of 15%, 0 to 10% of ZrO2, 0 to 10% of Nb2O5 provided that Ta2O5/(Ta2O5+ZrO2+Nb2O5)>0.3, 0 to 20% of WO3 and 0 to 1% of Sb2O3 and which has a refractive index (nd) of 1.80 to 1.84 and an Abbe's number (?d) of 40.0 to 45.0.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: June 7, 2011
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara
  • Publication number: 20110124485
    Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising 5 mol % to 60 mol % of a B2O3 component, and 0.2 mol % to 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.
    Type: Application
    Filed: January 19, 2011
    Publication date: May 26, 2011
    Applicant: OHARA INC.
    Inventor: Jie FU
  • Patent number: 7943540
    Abstract: An optical glass for precision molding having a high refractive index (nd) and a low yield temperature (At). The optical glass comprises, as glass components in wt %, 64 to 83% of Bi2O3; 4 to 17% of B2O3; 0 to 12% of GeO2 (wherein the total of B2O3 and GeO2 is 10 to 20%); 0 to 7% of La2O3; 0 to 7% of Gd2O3 (wherein the total of La2O3 and Gd2O3 is 1 to 13%); 0 to 4% of ZrO2; 0 to 5% of Ta2O5; 0 to 15% of ZnO; 0 to 2% of Sb2O3; and 0 to 1% of In2O3. The optical glass has optical constants, that is, a refractive index (nd) of 2.05 to 2.25 and an Abbe number (vd) of 15 to 22, and a yield temperature (At) of 510° C. or less.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: May 17, 2011
    Assignee: Sumita Optical Glass, Inc.
    Inventor: Yoshinori Yamamoto
  • Patent number: 7932197
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (?d) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: April 26, 2011
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7867934
    Abstract: Optical glass containing bismuth oxide having good defoamability. The Optical glass contains, as % by mass, from 10 to less than 90% of a Bi2O3 component and at least 0.1% of a TeO2 and/or SeO2 component. The optical glass is on Grade 4 to Grade 1 in “JOGIS12-1994, Method for Measuring Bubbles in Optical Glass”. By controlling the amount of RO component (R is at least one selected from a group consisting of Zn, Ba, Sr, Ca, Mg) and Rn2O component (Rn?Li, Na, K, Cs), the clarifying time may be shortened.
    Type: Grant
    Filed: October 22, 2007
    Date of Patent: January 11, 2011
    Assignee: Ohara, Inc.
    Inventor: Atsushi Nagaoka
  • Publication number: 20100317503
    Abstract: Embodiments of compositions comprising materials satisfying the general formula AM1?xM?xM?yO3+y are disclosed, along with methods of making the materials and compositions. In some embodiments, M and M? are +3 cations, at least a portion of the M cations and the M? cations are bound to oxygen in trigonal bipyramidal coordination, and the material is chromophoric. In some embodiments, the material forms a crystal structure having a hexagonal unit cell wherein edge a has a length of 3.50-3.70 ? and edge c has a length of 10-13 ?. In other embodiments, edge a has a length of 5.5-7.0 ?. In particular embodiments, M? is Mn, and Mn is bonded to oxygen with an apical Mn—O bond length of 1.80 ? to 1.95 ?. In some embodiments, the material is YIn1?xMnxO3, x is greater than 0.0 and less than 0.75, and the material exhibits a surprisingly intense blue color.
    Type: Application
    Filed: June 10, 2010
    Publication date: December 16, 2010
    Inventors: Munirpallam A. Subramanian, Arthur W. Sleight, Andrew E. Smith
  • Publication number: 20100255979
    Abstract: An optical Glass characterized by comprising, denoted as molar percentages: B2O3 5 to 45 percent; Li2O 0 to 3 percent; ZnO 10 to 40 percent; La2O3 5 to 30 percent; Gd2O3 0 to 20 percent; and at least one from among TiO2, Nb2O5, WO3, and Bi2O3; in that the total content X of Ti, Nb, W, and Bi, denoted as a cation percentage, is 3 to 35 percent; in that the Abbé number v(nu)d and refractive index nd fall within the range delimited by sequentially connecting with straight lines points A, B, C, D and A in FIG. 1; and in that the glass transition temperature Tg satisfies relation (1) below: Tg[° C.]?655° C.?5×X??(1). An optical Glass characterized by comprising, denoted as molar percentages: B2O5 5 to 45 percent; SiO2 0 to 6 percent (excluding 6 percent); Li2O, Na2O, K2O in total 0 to 3 percent; ZnO 10 to 40 percent; La2O3 5 to 30 percent; Gd2O3 0 to 20 percent; and ZrO2, TaO2, TiO2, Nb2O5, 12.
    Type: Application
    Filed: May 28, 2009
    Publication date: October 7, 2010
    Applicant: Hoya Corporation
    Inventor: Yasuhiro Fujiwara
  • Patent number: 7749929
    Abstract: Glass for covering electrodes, which consists essentially of, as represented by mol % based on the following oxides, from 25 to 60% of B2O3, from 0 to 18% of SiO2, from 0 to 60% of ZnO, from 0 to 18% of BaO, from 3 to 15% of Bi2O3 and from 0 to 10% of Al2O3, and contains no PbO.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 6, 2010
    Assignee: Asahi Glass Company, Limited
    Inventors: Masamichi Tanida, Tomoyuki Fukahori
  • Patent number: 7704904
    Abstract: An optical glass contains as glass ingredients, by weight: 0-8% SiO2; 34.5-46% B2O3; 2.6-6% Li2O; 21-38% ZnO; 0-40% La2O3; 0-35% Gd2O3; and 0-15% Y2O3, with the total content of La2O3+Gd2O3+Y2O3 accounting for 10-40%. The optical glass also has a predetermined index of refraction and a predetermined dispersion.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: April 27, 2010
    Assignee: Konica Minolta Opto, Inc.
    Inventor: Akio Oogaki
  • Patent number: 7687417
    Abstract: A glass composition consisting essentially of, based on mole percent, 46-56% B2O3, 0.5-8.5% P2O5, SiO2 and mixtures thereof, 20-50% CaO, 2-15% Ln2O3 where Ln is selected from the group consisting of rare earth elements and mixtures thereof; 0-6% M?2O where M? is selected from the group consisting of alkali elements; and 0-10% Al2O3, with the proviso that the composition is water millable.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: March 30, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Kenneth Warren Hang, Kumaran Manikantan Nair, Mark Frederick McCombs
  • Patent number: 7655585
    Abstract: Provided is a precision press-molding optical glass that is not easily degraded in quality by the occurrence of an altered layer such as fogging or yellowing on a surface and that comprises B2O3, ZnO, La2O3 and ZrO2 and contains, by mol %, 0 to less than 0.5% of Li2O, 20 to 50% of B2O3, 0 to 20% of SiO2, 22 to 42% of ZnO, 5 to 24% of La2O3, 0 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 10 to 24%, 0.5 to 10% of ZrO2, 0 to 15% of Ta2O5, 0 to 20% of WO3, 0 to 15% of Nb2O5, 0 to 20% of TiO2, 0 to 10% of Bi2O3, 0 to 10% of GeO2, 0 to 10% of Ga2O3, 0 to 10% of Al2O3, 0 to 10% of BaO, 0 to 10% of Y2O3 and 0 to 10% of Yb2O3, the optical glass having an Abbe's number (?d) of at least 35 but less than 40.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: February 2, 2010
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7638449
    Abstract: This invention provides an optical glass including, by mass %: 30 to 40% of B2O3; 2.5 to 6% of Li2O; 10 to 17% of ZnO; 12 to 22% of La2O3; 15 to 25% of Gd2O3; 0 to 5% of SiO2; 0 to 5% of Bi2O3; 0 to 15% of Al2O3; 0 to 3% of ZrO2; 0 to 5% of WO3; 0 to 5% of Ta2O5; 0 to 3% of TiO2; 0 to 5% of Y2O3; and 0 to 5% of MgO+CaO+SrO+BaO.
    Type: Grant
    Filed: August 15, 2008
    Date of Patent: December 29, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Kenji Imakita, Jun Sasai, Naoki Sugimoto
  • Patent number: 7638450
    Abstract: The lead-free, fluorine-free and arsenic-free optical glass, which is useful in mapping, projection, telecommunication, optical communication engineering, and mobile drive and laser technology, has a refractive index of 1.75?nd?1.83, an Abbe number of 34?Vd?44, and Tg?560° C. The glass is free of WO3 and TeO2and has a composition in percent by weight based on oxide content of: SiO2, 0.5-8; B2O3, 10-25; ZnO, 10-22; La2O3, 23-34; Ta2O5, >15-25; Nb2O5, 0.5-15; Al2O3, 0-2; and can include optional ingredients, e.g. alkali and/or alkaline-earth oxides. In addition, a sum of B2O3 and ZnO is 33 to 41% by weight and preferably a sum of La2O3+Ta2O5+Nb2O5+Y2O3+ZrO2 is greater than 50% by weight.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: December 29, 2009
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Ute Woelfel, Stefanie Hansen
  • Publication number: 20090309125
    Abstract: A glass for encapsulating an optical element that can seal the optical element at a temperature in the vicinity of 500° C., and a glass-encapsulated light-emitting device encapsulated with the glass, are provided. A glass for encapsulating an optical element, which is a glass consisting essentially of, in terms of mol % of oxide, from 35 to 55% of TeO2, from 20 to 50% of B2O3, from 10 to 30% of ZnO, and from 0.1 to 5% of one type or a combination of at least two types selected from the group consisting of Y2O3, La2O3, Gd2O3 and Bi2O3, wherein the value of (B2O3+ZnO)/TeO2 is at least 0.9, the glass contains substantially no fluorine, and when the content of ZnO is at most 15%, the content of TeO2 is at most 46%.
    Type: Application
    Filed: August 6, 2009
    Publication date: December 17, 2009
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Syuji MATSUMOTO, Nobuhiro Nakamura
  • Patent number: 7622409
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: November 24, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7615507
    Abstract: An optical glass having a remarkably high refractive index and excellent stability can be give without being based on PbO, and the optical glass contains, as essential components, at least one oxide selected from La2O3, Gd2O3, Y2O3, Yb2O3, TiO2, Nb2O5 or WO3, at least one oxide selected from MgO, CaO, SrO or BaO and B2O3 and optionally containing SiO2, wherein on the basis of mass, the total content of B2O3 and SiO2 is from 1 to 25%, the ratio of (B2O3+SiO2)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.05 to 0.3 and the ratio of (MgO+CaO+SrO+BaO)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.1 to 0.4, the optical glass having a refractive index (nd) of 2.000 or more and an Abbe's number (vd) of 27 or less.
    Type: Grant
    Filed: July 10, 2006
    Date of Patent: November 10, 2009
    Assignee: Hoya Corporation
    Inventor: Michio Endo
  • Patent number: 7582580
    Abstract: The present invention provides an optical glass including, by mass %: 46 to 70 of B2O3; 3 to 10 of Li2O; 5 to 15 of Y2O3; 0 to 46 of SiO2: 0 to 20 of Al2O3: 0 to 40 of MgO+CaO+SrO+BaO; 0 to 30 of La2O3; and 0 to 10 of ZrO2+TiO2+Gd2O3.
    Type: Grant
    Filed: August 21, 2008
    Date of Patent: September 1, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroyuki Ohkawa, Jun Sasai, Naoki Sugimoto
  • Patent number: 7576020
    Abstract: Provided is an optical glass for precision press-molding is free from degradations in product quality caused by a surface altered layer such as fogging, browning, etc., and a precision press-molding preform and an optical element provided are formed of the above glass. The optical glass is a glass which contains B2O3, La2O3 and ZnO and is used as a glass material for precision press-molding, and contains, by mol %, 20 to 60% of B2O3, 0 to 20% of SiO2, 22 to 42% of ZnO, 5 to 24% of La2O3, 0 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 10 to 24%, 0 to 10% of ZrO2, 0 to 10% of Ta2O5, 0 to 10% of WO3, 0 to 10% of Nb2O5, 0 to 10% of TiO2, 0 to 10% of Bi2O3, 0 to 10% of GeO2, 0 to 10% of Ga2O3, 0 to 10% of Al2O3, 0 to 10% of BaO, 0 to 10% of Y2O3 and 0 to 10% of Yb2O3, has an Abbe's number (?d) of 40 or more and is substantially free of lithium.
    Type: Grant
    Filed: October 11, 2005
    Date of Patent: August 18, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7572747
    Abstract: An optical glass consisting essentially of B2O3 in an amount of 10-40 wt %, SiO2 in an amount less than or equal to 5 wt %, ZnO in an amount less than or equal to 15 wt %, SrO in an amount less than or equal to 9 wt %, ZrO2 in an amount less than or equal to 9 wt %, La2O3 in an amount of 15 to 45 wt %, BaF2 in an amount of 1 to 10 wt %, BaO in an amount less than or equal to 5 wt %, HfO2 in an amount of 0.1 to 7.5 wt %, Gd2O3 in an amount less than or equal to 16 wt %, CaO in an amount less than or equal to 7 wt %, ZrF4 in an amount less than or equal to 5 wt %, Na2O in an amount less than or equal to 2 wt % and Y2O3 in an amount less than or equal to 16 wt %. The optical glass has a glass transition temperature in a range of 500-670° C. and a refractive index (nd) in a range of 1.60 to 2.00.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: August 11, 2009
    Assignees: Alfred University, Kyocera Corporation
    Inventors: Alexis G. Clare, Tatsuji Furuse, Matthew Hall
  • Patent number: 7563736
    Abstract: An optical glass which has an internal transmittance to a light having a wavelength of 400 nm being at least 90% as calculated in a thickness of 1 mm and which contains at least 25 mol % of B2O3 and from 0.1 to 20 mol % of TeO2. The above optical glass which contains La2O3. The above optical glass wherein the glass transition point ?650° C. and the refractive index at 633 nm?1.70. A process for producing an optical element made of the above optical glass, which comprises dropping the optical glass in a molten state from a flow outlet of a flow out pipe made of a platinum alloy to form a preform and subjecting it to precision press-molding.
    Type: Grant
    Filed: April 26, 2006
    Date of Patent: July 21, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Kobayashi, Jun Sasai, Syuji Matsumoto, Naoki Sugimoto
  • Patent number: 7524781
    Abstract: A non-lead optical glass consisting essentially of, as represented by mol %, from 45 to 75% of Bi2O3, from 12 to 45% of B2O3, from 1 to 20% of Ga2O3, from 1 to 20% of In2O3, from 0 to 20% of ZnO, from 0 to 15% of BaO, from 0 to 15% of SiO2+Al2O3+GeO2, from 0 to 15% of MgO+CaO+SrO, from 0 to 10% of SnO2+TeO2+TiO2+ZrO2+Ta2O3+Y2O3+WO3 and from 0 to 5% of CeO2, wherein Ga2O3+In2O3+ZnO?5%. An optical fiber comprising the above non-lead optical glass as a core.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: April 28, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Tatsuo Nagashima, Naoki Sugimoto, Seiki Ohara, Tomoharu Hasegawa
  • Publication number: 20090105060
    Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).
    Type: Application
    Filed: October 10, 2008
    Publication date: April 23, 2009
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventors: Takahiro Takada, Hirobumi Yamamoto, Keisuke Kageyama
  • Patent number: 7514381
    Abstract: To provide an optical glass which has a high transmittance and a high refractive index and shows little decrease in the transmitted light intensity when continuously irradiated with a blue-violet laser diode light, and which is less prone to a higher melting temperature and exhibits chemical durability being not low. An optical glass consisting essentially of, as represented by mol %, from 35 to 54% of TeO2, from 0 to 10% of GeO2, from 5 to 30% of B2O3, from 0 to 15% of Ga2O3, from 0 to 8% of Bi2O3, from 3 to 20% of ZnO, from 0 to 10% of MgO+CaO+SrO+BaO, from 1 to 10% of Y2O3+La2O3+Gd2O3, from 0 to 5% of Ta2O5+Nb2O5, from 0 to 1.8% of TiO2, and from 0 to 6% of Li2O+Na2O+K2O+Rb2O+Cs2O. A lens made of such an optical glass.
    Type: Grant
    Filed: December 26, 2006
    Date of Patent: April 7, 2009
    Assignee: Asahi Glass Company, Limited
    Inventors: Syuji Matsumoto, Jun Sasai, Naoki Sugimoto
  • Patent number: 7491667
    Abstract: Provided are optical glasses having a refractive index (nd) of over 1.82 but not more than 1.86 and an Abbe's number (?d) of 30 to 39.5 and having the property of low-temperature softening that permits precision press-molding, one is an optical glass comprising B2O3, La2O5, Gd2O3 and ZnO as essential components, comprising Li2O and SiO2 as optional components, provided that the content of SiO2 is less than 2% by weight when Li2O is contained, having a refractive index (nd) of over 1.82 but not more than 1.86 and an Abbe's number (?d) of 30 to 39.5 and having a glass transition temperature (Tg) of 630° C. or lower, and the other is an optical glass comprising, by % by weight, 14 to 30% of B2O3, 10 to 40% of La2O3, 1 to 30% of Gd2O3 and 6 to 26% of ZnO as essential components, and comprising, as optional components, predetermined amounts of WO3, Ta2O5, Nb2O5, TiO2, SiO2, Li2O, Na2O, K2O, MgO, CaO, SrO, BaO, Y2O3, Yb2O3, ZrO2, Bi2O3 and Sb2O3 and having a refractive index (nd) of over 1.82 but not more than 1.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: February 17, 2009
    Assignee: Hoya Corporation
    Inventor: Kazutaka Hayashi
  • Patent number: 7482292
    Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: January 27, 2009
    Assignee: Murata Manufacturing Co., Ltd
    Inventors: Takahiro Takada, Hirofumi Yamamoto, Keisuke Kageyama
  • Publication number: 20090018006
    Abstract: A glass composition satisfying the following conditions (A) to (L), the conditions are: (A) a content ratio of TeO2 is in a range from 50 to 95 mol %; (B) a content ratio of B2O3 is in a range from 1 to 33 mol %; (C) a content ratio of ZnO is in a range from 1 to 37 mol %; (D) a content ratio of Bi2O3 is in a range from 1 to 18 mol %; (E) a content ratio of P2O5 is in a range from 0 to 15 mol %; (F) a content ratio of R2O (where R represents at least one element selected from the group consisting of Li, Na, and K) is in a range from 0 to 13 mol %; (G) a content ratio of MO (where M represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba) is in a range from 0 to 13 mol %; (H) a content ratio of TiO2 is in a range from 0 to 13 mol %; (I) a content ratio of Nb2O5 is in a range from 0 to 10 mol %; (J) a content ratio of Ta2O5 is in a range from 0 to 13 mol %; (K) a content ratio of L2O3 (where L represents at least one element selected from the group consisting of yttrium and lant
    Type: Application
    Filed: June 24, 2008
    Publication date: January 15, 2009
    Applicant: NIKON CORPORATION
    Inventors: Motoi Ueda, Takashi Ozawa, Kiyoaki Shinohara
  • Publication number: 20080318758
    Abstract: This invention provides an optical glass including, by mass %: 30 to 40% of B2O3; 2.5 to 6% of Li2O; 10 to 17% of ZnO; 12 to 22% of La2O3; 15 to 25% of Gd2O3; 0 to 5% of SiO2; 0 to 5% of Bi2O3; 0 to 15% of Al2O3; 0 to 3% of ZrO2; 0 to 5% of WO3; 0 to 5% of Ta2O5; 0 to 3% of TiO2; 0 to 5% of Y2O3; and 0 to 5% of MgO+CaO+SrO+BaO.
    Type: Application
    Filed: August 15, 2008
    Publication date: December 25, 2008
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Kenji IMAKITA, Jun Sasai, Naoki Sugimoto
  • Patent number: 7468338
    Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (?d) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa·s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (?d) of 45 to 55.
    Type: Grant
    Filed: September 21, 2007
    Date of Patent: December 23, 2008
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
  • Publication number: 20080312063
    Abstract: The present invention provides an optical glass including, by mass %: 46 to 70 of B2O3; 3 to 10 of Li2O; 5 to 15 of Y2O3; 0 to 46 of SiO2: 0 to 20 of Al2O3: 0 to 40 of MgO+CaO+SrO+BaO; 0 to 30 of La2O3; and 0 to 10 of ZrO2+TiO2+Gd2O3.
    Type: Application
    Filed: August 21, 2008
    Publication date: December 18, 2008
    Applicant: ASAHI GLASS CO., LTD.
    Inventors: Hiroyuki OHKAWA, Jun Sasai, Naoki Sugimoto
  • Publication number: 20080312062
    Abstract: The invention provides an optical glass comprising, by mass % on the oxide basis; 25 to 50% of B2O3; 5 to 25% of ZnO: 13 to 25% of La2O3; 10 to 28% of Gd2O3; and 1.5 to 4% of Li2O, the optical glass having: a refractive index (nd) of 1.65 to 1.76; an Abbe number (?d) of 45 to 60; and a molding temperature (Tp), as defined with the glass transition temperature (Tg) and the yield point (At) by the expression At+(At?Tg)/2, of 650° C. or less; the optical glass substantially containing neither an arsenic nor a lead nor a fluorine.
    Type: Application
    Filed: August 21, 2008
    Publication date: December 18, 2008
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Jun SASAI, Naoki Sugimoto
  • Publication number: 20080248941
    Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising no less than 5 mol % and no more than 60 mol % of a B2O3 component, and no less than 0.2 mol % and no more than 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.
    Type: Application
    Filed: April 2, 2008
    Publication date: October 9, 2008
    Inventor: Jie Fu
  • Publication number: 20080167172
    Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.
    Type: Application
    Filed: January 7, 2008
    Publication date: July 10, 2008
    Applicant: HOYA CORPORATION
    Inventor: Kazutaka Hayashi
  • Patent number: 7396785
    Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: July 8, 2008
    Assignee: Murata Manufacturing Co. Ltd
    Inventors: Takahiro Takada, Hirobumi Yamamoto, Keisuke Kageyama
  • Publication number: 20080119345
    Abstract: A ceramic substrate composition is provided which can be co-fired with a low-melting metal and exhibits excellent dielectric characteristics at high frequencies, particularly tens of gigahertz. The ceramic substrate composition mainly contains a glass represented by aB2O3-bRe2O3-cZnO, wherein the molar ratios (a, b, and c) fall within a region defined in a ternary composition diagram by Point A (0.4, 0.595, 0.005), Point B (0.4, 0.25, 0.35), Point C (0.52, 0.01, 0.47), Point D (0.9, 0.005, 0.095), and Point E (0.9, 0.09, 0.01).
    Type: Application
    Filed: December 12, 2007
    Publication date: May 22, 2008
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventors: Takahiro Takada, Hirobumi Yamamoto, Keisuke Kageyama
  • Patent number: 7358462
    Abstract: A method and apparatus for heating semiconductor wafers in thermal processing chambers is disclosed. The apparatus includes a non-contact temperature measurement system that utilizes radiation sensing devices, such as pyrometers, to determine the temperature of the wafer during processing. The radiation sensing devices determine the temperature of the wafer by monitoring the amount of radiation being emitted by the wafer at a particular wavelength. In accordance with the present invention, a spectral filter is included in the apparatus for filtering light being emitted by lamps used to heat the wafer at the wavelength at which the radiation sensing devices operate. The spectral filter includes a light absorbing agent such as a rare earth element, an oxide of a rare earth element, a light absorbing dye, a metal, or a semiconductor material.
    Type: Grant
    Filed: August 1, 2006
    Date of Patent: April 15, 2008
    Assignee: Mattson Technology, Inc.
    Inventor: Paul Janis Timans