And Zirconium, Titanium, Tantalum, Or Niobium Patents (Class 501/51)
  • Patent number: 7141522
    Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) Y2O3, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: November 28, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Craig R. Schardt
  • Patent number: 7141523
    Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) REO, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: November 28, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Anatoly Z. Rosenflanz, Craig R. Schardt
  • Patent number: 7033966
    Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: April 25, 2006
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
  • Patent number: 6984261
    Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: January 10, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
  • Patent number: 6977232
    Abstract: Provided is an optical glass that has high-refractivity and high-dispersion properties and can give preforms for press-molding, which are excellent in shapability at high temperatures and suitable for precision press-molding. The optical contains, as essential components, 25 to 45 mol % of B2O3, 2 to 20 mol % of SiO2, 5 to 22 mol % of La2O3, 2 to 20 mol % of Gd2O3, 15 to 29 mol % of ZnO, 1 to 10 mol % of Li2O and 0.5 to 8 mol % of ZrO2, the optical glass having a B2O3/SiO2 molar ratio of from 2 to 5.5 and having an La2O3 and Gd2O3 total content of 12 to 24 mol % and a ZnO and Li2O total content of 25 to 30 mol %, the optical glass having a refractive index (nd) of 1.75 to 1.85 and an Abbe's number (?d) of 40 to 55, or the optical glass contains, as essential components, B2O3, SiO2, La2O3, Gd2O3, ZnO, Li2O and ZrO2 and has a viscosity of at least 6 dPa·s at a liquidus temperature thereof, a glass transition temperature (Tg) of 600° C. or lower, a refractive index (nd) of 1.75 to 1.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: December 20, 2005
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Xuelu Zou
  • Patent number: 6875714
    Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: April 5, 2005
    Assignee: Minolta Co., Ltd.
    Inventor: Manabu Izuki
  • Patent number: 6844279
    Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (?d) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa·s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (?d) of 45 to 55.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: January 18, 2005
    Assignee: Hoya Corporation
    Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
  • Patent number: 6841493
    Abstract: The present invention is directed to a glass composition comprising, based on mole %, 15-35% MO where M is selected from BaO, CaO, MgO, PbO, SrO and mixtures thereof, 30-60% TiO2, 10-30% B2O3, 1-7% P2O5, 0-3% Li2O and 2-16% Ln2O3 where Ln is selected from the group of rare earth elements and mixtures thereof. The invention is further directed to the glass composition incorporated in a thick film composition or a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 30-100 wt. % the glass composition; (b) 0-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition used in a method of forming a high K green tape by casting a thin layer of the castable dispersion onto a flexible sheet and heating the cast layer to remove the volatile organic solvent.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: January 11, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Patent number: 6818578
    Abstract: An optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time. The optical glass has a refractive index nd of at least 1.875, an Abbe's number &ngr;d of at least 39.5 and a glass transition point Tg of 700° C. or lower, and contains at least one of La2O3, Gd2O3, Y2O3 or Yb2O3 and at least one of ZrO2, Ta2O5 or Nb2O5, with a weight ratio of the total content of La2O3, Gd2O3, Y2O3 and Yb2O3 to the total content of SiO2 and B2O3 of from 3.2 to 5 and the weight ratio of the total content of ZrO2, Ta2O5 and Nb2O5 to the total content of SiO2 and B2O3 is from 1.1 to 1.5.
    Type: Grant
    Filed: May 24, 2001
    Date of Patent: November 16, 2004
    Assignee: Hoya Corporation
    Inventor: Kazuo Tachiwama
  • Publication number: 20040180774
    Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.
    Type: Application
    Filed: March 23, 2004
    Publication date: September 16, 2004
    Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
  • Patent number: 6753278
    Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: June 22, 2004
    Assignee: Schott Glas
    Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
  • Patent number: 6656859
    Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: December 2, 2003
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
  • Patent number: 6653251
    Abstract: An optical amplifying glass having Er doped in an amount of from 0.01 to 10% as represented by mass percentage to a matrix glass comprising, by mol %, BiO2: 20 to 80, B2O3+SiO2: 5 to 75, Ga2O3+WO3+TeO2: 0.1 to 35, Al2O3≦10, GeO2≦30, TiO2≦30, and SnO2≦30, and containing no CeO2.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: November 25, 2003
    Assignee: Asahi Glass Company, Limited
    Inventors: Naoki Sugimoto, Setsuro Ito
  • Patent number: 6645894
    Abstract: An optical glass that substantially does not contain any Ta2O5 and has high-refractivity low-dispersion optical properties and various optical parts made of such optical glass are provided stably at a low cost, and an optical part made thereof is provided, the optical glass having a glass composition comprising, by weight %, 0 to 7% of SiO2, 18 to 30% of B2O3, provided that the total content of SiO2 and B2O3 is 23 to 35%, 2 to 10% of ZnO, 30 to 50% of La2O3, 0 to 20% of Gd2O3, 0 to 20% of Y2O3, provided that the total content of La2O3, Gd2O3 and Y2O3 is 45 to 60%, 3 to 8% of ZrO2 and 3 to 12% of Nb2O5, the total content of these components being at least 95% by weight, the optical glass having a refractive index [nd] and an Abbe's number [&ngr;d] which satisfy specified relational expressions.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: November 11, 2003
    Assignee: Hoya Corporation
    Inventor: Michio Endo
  • Publication number: 20030104919
    Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.
    Type: Application
    Filed: May 2, 2002
    Publication date: June 5, 2003
    Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
  • Patent number: 6558316
    Abstract: A composition has a durability to a sterilization treatment using vapor under high temperature and pressure and capable of transmitting or absorbing light. The composition comprises a group A including 15 to 23 mol % of lanthanum oxide, 3 to 8 mol % of gadolinium oxide, 3 to 8 mol % of tantalum oxide, and 8 mol % or less of yttrium oxide; a group B including 30 to 45 mol % of boron oxide, 20 mol % or less of silicon oxide, and 20 mol % or less of germanium oxide; zero mol % of alkaline metal oxide or alkaline earth metal oxide; and a group D including 0.3 to 15 mol % of niobium oxide and 3 to 15 mol % of zirconium oxide. A mol % ratio A/B between the group A and group B is 80% or more, and a dissolving-out rate of metal ion of the composition is 0.002×10−6 mol/hour or less per square centimeter.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: May 6, 2003
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Akira Kikuchi, Sayaka Konno, Hiroaki Kinoshita
  • Patent number: 6497962
    Abstract: A low melting point glass for covering electrodes, which contains Cu in a content as calculated as CuO within a range of from 0.1 to 0.9% by mass percentage and which contains neither Mo or Sb.
    Type: Grant
    Filed: November 1, 2000
    Date of Patent: December 24, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Satoshi Fujimine, Yumiko Aoki, Tsuneo Manabe
  • Patent number: 6495482
    Abstract: A glass composition well suited for use in optical amplification consists of an erbium-doped borate glass composition comprising at least 30 mole percent of B2O3, not over 30 mole percent of SiO2, preferably not over 5 mole percent of La2O3, a ratio of B2O3 to (&Sgr;X2O+&Sgr;YO) that is at least 3.5, preferably 4.5, where X2O represents monovalent metal oxides(s) and YO represents divalent metal oxides, the glass providing a wide useful bandwidth (50 nm and greater) for optical amplification around the 1545 nm region.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: December 17, 2002
    Assignee: Corning Incorporated
    Inventors: Jean-Philippe de Sandro, David Jacob, Michel Prassas
  • Patent number: 6352950
    Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 5, 2002
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison
  • Patent number: 6309989
    Abstract: A tin-borophosphate glass of the present invention has main components of SnO, B2O3, and P2O5, consists essentially of, by mole % representation, 30-70% SnO, 5-30% B2O3, and 24-45% (24% exclusive) P2O5, and satisfies a condition of B2O3/P2O5≧0.20 by mole ratio.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: October 30, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takemi Kikutani
  • Patent number: 6281151
    Abstract: The present invention relates to a transparent glass-ceramic material which includes a glass matrix and a crystalline phase of lanthanum fluoride crystals in the glass matrix, where the transparent glass-ceramic material contains no silica. The present invention further relates to a method of producing the transparent glass-ceramic material.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: August 28, 2001
    Assignee: Corning Incorporated
    Inventor: Paul A. Tick
  • Patent number: 6153127
    Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 28, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichiro Nakamura, Koichi Maeda
  • Patent number: 5747397
    Abstract: High rare-earth content glasses (Ln.sub.2 O.sub.3 .gtoreq.20 mol %) have applications as high optical density wavelength-selective filters, faraday rotators, scintillation glasses and high index glasses. New glasses are formed by adding TiO.sub.2 to the system SiO.sub.2 --B.sub.2 O.sub.3 --Al.sub.2 O.sub.3 --Ln.sub.2 O.sub.3. These glasses have improved optical properties, extended glass formation range and have superior resistance to devitrification. In some embodiments TiO.sub.2 can fully replace the Al.sub.2 O.sub.3. In additional embodiments, SiO.sub.2 can be completely removed from the glass.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: May 5, 1998
    Assignee: Bay Glass Research
    Inventors: Donald M. McPherson, Steven C. Murray
  • Patent number: 5693580
    Abstract: Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: December 2, 1997
    Assignee: Sandia Corporation
    Inventors: Richard K. Brow, Howard L. McCollister, Carol C. Phifer, Delbert E. Day
  • Patent number: 5665660
    Abstract: The object of the present invention is to provide a glass composition which has a sufficient bonding strength for bonding a fluorescent film with a glass tube, does not hinder decomposition of the binder and is effective as an adhesive material, and to provide a fluorescent lamp using the glass composition. The object can be achieved by a glass composition, represented by the general formula,xMO.yB.sub.2 O.sub.3.zM'.sub.2 O.sub.3.uM"O.sub.2.vM'".sub.2 O.sub.5in which M is at least one element of Mg, Ca, Sr, Ba and Zn, M' is at least one element of Al, Sc, Y and lanthanoid elements, M" is at least one element of Ti, Zr, Hf, Th and Si, M'" is at least one element of Nb and Ta, x, y, z, u and v satisfy the relationships of 0<x.ltoreq.70, 15.ltoreq.y.ltoreq.80, 0.ltoreq.z.ltoreq.50, 0.ltoreq.u.ltoreq.30, 0.ltoreq.v.ltoreq.30, 0.5.ltoreq.u+v.ltoreq.50 and x+y+z+u+v=100, represented by mol %, and by a fluorescent lamp, in which the glass composition is incorporated in a phosphor layer in a proportion of 0.
    Type: Grant
    Filed: January 2, 1996
    Date of Patent: September 9, 1997
    Assignee: Kasei Optnix, Ltd.
    Inventors: Hiroshi Yamawaki, Masahiko Yoshino, Yasuo Oguri, Masayuki Yamane
  • Patent number: 5648302
    Abstract: Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: July 15, 1997
    Assignee: Sandia Corporation
    Inventors: Richard K. Brow, Howard L. McCollister, Carol C. Phifer, Delbert E. Day
  • Patent number: 5643636
    Abstract: A ceramic color composition comprising from 5 to 34 wt % of a heat resistant color pigment powder, from 65 to 94 wt% of a bismuth type glass powder, from 0 to 10 wt % of a refractory filler powder, and from 0.1 to 20 wt % of at least one additive selected from the group consisting of borides and silicides, as inorganic components.
    Type: Grant
    Filed: January 24, 1996
    Date of Patent: July 1, 1997
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroshi Usui, Hitoshi Onoda, Tsuneo Manabe
  • Patent number: 5612154
    Abstract: A beta-alumina solid electrolyte for use in a sodium-sulfur battery is composed of beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 .mu.m or less, the proportion of the particles having a particle diameter of 5 .mu.m or less is 90% or more, and the maximum particle diameter is 300 .mu.m or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material, uses a magnesium-aluminum spinel as the magnesium source material and subjects all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination.
    Type: Grant
    Filed: March 2, 1995
    Date of Patent: March 18, 1997
    Assignee: NGK Insulators, Ltd.
    Inventors: Masaharu Kajita, Takehiro Kajihara, Takao Totoki
  • Patent number: 5464674
    Abstract: A magnetic recording medium comprising a magnetic recording layer and at least one protective layer formed on the recording layer, wherein the outermost protective layer on the side exposed to air is made of an oxide film.
    Type: Grant
    Filed: January 12, 1993
    Date of Patent: November 7, 1995
    Assignee: Asahi Glass Company Ltd.
    Inventors: Ichiro Makino, Akira Mitsui, Mikio Takehara, Eiichi Ando, Junichi Ebisawa, Koichi Suzuki, Kiyoshi Matsumoto, Toru Iseda, Susumu Suzuki
  • Patent number: 5461021
    Abstract: A novel composition comprises aluminum borate and zirconium borate. Preferably, the composition is prepared by coprecipitation. The composition is useful as a sorbent or as a catalyst material.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: October 24, 1995
    Assignee: Phillips Petroleum Company
    Inventor: Lyle R. Kallenbach
  • Patent number: 5252521
    Abstract: This invention relates to a lead-free glass coating made by firing a lead-free glass composition comprising in weight percent from about 35% to about 77% of bismuth oxide, from about 10% to about 33% of boron oxide, and from about 10% to about 32% of zinc oxide at a temperature sufficient to fuse and cure the glass composition. The invention also relates to lead-free glazes and enamels that exhibit excellent acid resistance, possess low coefficients of linear or thermal expansion, and moderate maturation temperatures.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: October 12, 1993
    Assignee: Ferro Corporation
    Inventor: Gordon J. Roberts
  • Patent number: 5245492
    Abstract: A magnetic head comprising magnetic core halves which are sealed with a sealing glass which consists essentially of 1 to 75 wt. % of TeO.sub.2, 1 to 30 wt. % of B.sub.2 O.sub.3, 1 to 75 wt. % of PbO, 1 to 25 wt. % of CdO, 0 to 15 wt. % of ZnO, 0 to 25 wt. % of Bi.sub.2 O.sub.3, 0 to 5 wt. % of A.sub.2 O wherein A is an alkali metal, 0 to 35 wt. % of ARO wherein AR is an alkaline earth metal, 0 to 35 wt. % of La.sub.2 O.sub.3, 0 to 5 wt. % of at least one oxide selected from the group consisting of Al.sub.2 O.sub.3, SiO.sub.2, TiO.sub.2 and ZrO.sub.2, 0 to 10 wt. % of at least one oxide selected from the group consisting of Ta.sub.2 O.sub.5, Nb.sub.2 O.sub.5, WO.sub.3 and MoO.sub.3, 0 to 30 wt. % of PbF.sub.2, and 0 to 2 wt. % of CoO, has a coefficient of thermal expansion of from 82.times.10.sup.-7 /.degree.C. to 137.times.10.sup.-7 /.degree.C. in a temperature range between 30.degree. C. and 300.degree. C., a working temperature of from 430.degree. to 620.degree. C.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: September 14, 1993
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuo Mizuno, Masaki Ikeda, Akihiko Yoshida
  • Patent number: 5226959
    Abstract: A ceramic composition for forming a ceramic dielectric body having a dielectric constant of less than about 5.5 and a TCE of less than about 4.5 ppm/.degree. C. The composition comprises a mixture of finely divided particles of 25-50 vol. % borosilicate glass 40-75 vol. % silica glass and 1-40 wt. % of a material selected from the group consisting of Ga.sub.2 O.sub.3, Ga.sub.2 SiO.sub.5, Ga.sub.2 TiO.sub.5, GaAs, GaPO.sub.4 and any gallium-contained compounds to inhibit the formation of crystalline forms of silica. The composition can be used with a polymeric binder to produce an unfired green tape which is co-fireable with high conductivity metallurgies such as gold, silver and silver/palladium.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: July 13, 1993
    Assignee: Aluminum Company of America
    Inventors: Jau-Ho Jean, Tapan K. Gupta
  • Patent number: 5209835
    Abstract: A magnetic recording medium comprising a magnetic recording layer and at least one protective layer formed on the recording layer, wherein the outermost protective layer on the side exposed to air is made of an oxide film.
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: May 11, 1993
    Assignee: Asahi Glass Company Ltd.
    Inventors: Ichiro Makino, Akira Mitsui, Mikio Takehara, Eiichi Ando, Junichi Ebisawa, Koichi Suzuki, Kiyoshi Matsumoto, Toru Iseda, Susumu Suzuki
  • Patent number: 5137850
    Abstract: A chemically resistant glass which can be produced at relatively low melting temperatures and has anomalous negative partial dispersion P.sub.g,F, a refractive index n.sub.d of from 1.73 to 1.83 and an Abbe coefficient v.sub.d of from 31 to 38 preferably contains (in % by weight, based on oxides):______________________________________ 0-4 SiO.sub.2 + GeO.sub.2 0-2 GeO.sub.2 0-10 MgO 26-33 B.sub.2 O.sub.3 0-1 Li.sub.2 O 0-16 CaO 19-50 PbO 0-1 Na.sub.2 O 0-16 BaO 1-6 ZrO.sub.2 0-1 K.sub.2 O 0-16 SrO 4-16 Ta.sub.2 O.sub.5 0-2 .SIGMA. alkaline earth 0-6 Al.sub.2 O.sub.3 metal oxides 0-16 ZnO 0-4 TiO.sub.2 1.5-20 .SIGMA. alkaline earth metal oxides + ZnO 0-1 WO.sub.3 0-11 La.sub.2 O.sub.3 0-7 Nb.sub.2 O.sub.5 0-5.5 Y.sub.2 O.sub.3 0-5.5 Gd.sub.2 O.sub.3 4-11 .SIGMA. La.sub.2 O.sub.3 + Y.sub.2 O.sub.3 + Gd.sub.2 O.sub.3 ______________________________________with the proviso that the .SIGMA.(SiO.sub.2 +GeO.sub.2 +B.sub.2 O.sub.3)/.SIGMA.(ta.sub.2 O.sub.5 +ZrO.sub.2 +HfO.sub.2) ratio is less than 5 and the PbO/.
    Type: Grant
    Filed: January 16, 1991
    Date of Patent: August 11, 1992
    Assignee: Schott Glaswerke
    Inventors: Marc Clement, Volkmar Geiler, Danuta Grabowski
  • Patent number: 5110637
    Abstract: An amorphous oxide film composed essentially of an oxide containing at least one member selected from the group consisting of Zr, Ti, Hf, Sn, Ta and In and at least one member selected from the group consisting of B and Si.
    Type: Grant
    Filed: March 3, 1989
    Date of Patent: May 5, 1992
    Assignee: Asahi Glass Company Ltd.
    Inventors: Eiichi Ando, Koichi Suzuki, Junichi Ebisawa, Susumu Suzuki
  • Patent number: 5066621
    Abstract: Described is a sealing glass composition comprising, in wt. %, 13-50% lead oxide, 20-50% vanadium oxide, 2-40% tellurium oxide, up to 40% selenium oxide, up to 10% phosphorous oxide, up to 5% niobium oxide, up to 20% bismuth oxide, up to 5% copper oxide and up to 10% boron oxide and an electrically conductive formulation comprising, in wt. %, 50-77% silver, 8-34% of a sealing glass composition as described previously, 0.2-1.5% resin and thixotrope and 10-20% organic solvent.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: November 19, 1991
    Assignee: Johnson Matthey Inc.
    Inventor: Masyood Akhtar
  • Patent number: 5006489
    Abstract: The soldering enamel is composed of a basic enamel consisting of aluminium oxide and a rare earth metal oxide and/or an alkali earth metal oxide and, in the given case, some other metallic or metalloid oxide, and of a ceramic filling material. The filling material is a zirconium-rare earth oxide of perovskite crystal structure. The quantity of the filling material amounts up to 5 mass % referred to the overall quantity of enamel.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: April 9, 1991
    Assignee: Tungsram Reszvenytarsasag
    Inventors: Ferenc Nagel, Maria J. Farkasne
  • Patent number: 4985377
    Abstract: The invention relates to glaze resistors which are used for electronic parts of hybrid integrated circuit devices, chip resistors, resistor network, etc. The glaze resistor comprises 4.0 to 70.0 wt % of a conductive component composed of a metal silicide and a metal boride and 30.0 to 96.0 wt % of glass in which a rate of said metal boride is 1.0 to 68.0 wt %. Thus, the glaze resistor can be formed by sintering in a non-oxidizing atmosphere and can provide a circuit, together with conductor pattern of base metals such as Cu.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: January 15, 1991
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Takeshi Iseki, Osamu Makino, Mitsuo Ioka, Hirotoshi Watanabe
  • Patent number: 4732875
    Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: March 22, 1988
    Assignee: Hoya Corporation
    Inventor: Koji Sagara
  • Patent number: 4612295
    Abstract: A glass for an eye glass lens comprising a SiO.sub.2 (or B.sub.2 O.sub.3)-CaO-Nb.sub.2 O.sub.5 system as a basic system and having a refractive index of 1.79 or more, an Abbe number of 32 to 38 and a specific gravity of less than 3.6 is disclosed.
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: September 16, 1986
    Assignee: Hoya Corporation
    Inventor: Hiroji Sagara
  • Patent number: 4469800
    Abstract: This invention is concerned with the preparation of moldable optical glasses having refractive indices of about 1.65-1.735, dispersions of about 38-58, transition temperatures lower than about 500.degree. C., softening points lower than about 600.degree. C., and satisfactory chemical durability consisting essentially, expressed in terms of parts by weight as calculated from the batch, of______________________________________ B.sub.2 O.sub.3 22-38 BaO 3-33 La.sub.2 O.sub.3 5-33 PbO 0-36 ZnO 0-14 CdO 0-12 SrO 0-10 BaO + La.sub.2 O.sub.3 + PbO + ZnO + CdO + SrO 55-68 Li.sub.2 O 0-4 Na.sub.2 O 0-4 Li.sub.2 O + Na.sub.2 O 1.5-4 F 1-8.
    Type: Grant
    Filed: July 28, 1983
    Date of Patent: September 4, 1984
    Assignee: Corning Glass Works
    Inventors: Jean E. Boudot, Jean P. Mazeau
  • Patent number: 4367919
    Abstract: Glass microspheres and other glass elements based on B.sub.2 O.sub.3, BaO, SiO.sub.2 and TiO.sub.2 have an improved combination of crushing strength, index of refraction, and, especially in some formulations, chemical resistance. The microspheres are especially adapted for use as retroreflective elements in pavement markings.
    Type: Grant
    Filed: March 19, 1981
    Date of Patent: January 11, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Chi F. Tung, Benjamin T. Fellows