And Zirconium, Titanium, Tantalum, Or Niobium Patents (Class 501/51)
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Patent number: 7141522Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) Y2O3, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.Type: GrantFiled: September 18, 2003Date of Patent: November 28, 2006Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Craig R. Schardt
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Patent number: 7141523Abstract: Ceramics comprising (i) at least one of Nb2O5 or Ta2O5 and (ii) at least two of (a) Al2O3, (b) REO, or (c) at least one of ZrO2 or HfO2. Embodiments of ceramics according to the present invention can be made, formed as, or converted into optical waveguides, glass beads, articles (e.g., plates), fibers, particles (e.g., abrasive particles), and thin coatings.Type: GrantFiled: September 18, 2003Date of Patent: November 28, 2006Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Craig R. Schardt
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Patent number: 7033966Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.Type: GrantFiled: May 19, 2004Date of Patent: April 25, 2006Assignee: Asahi Glass Company, LimitedInventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6977232Abstract: Provided is an optical glass that has high-refractivity and high-dispersion properties and can give preforms for press-molding, which are excellent in shapability at high temperatures and suitable for precision press-molding. The optical contains, as essential components, 25 to 45 mol % of B2O3, 2 to 20 mol % of SiO2, 5 to 22 mol % of La2O3, 2 to 20 mol % of Gd2O3, 15 to 29 mol % of ZnO, 1 to 10 mol % of Li2O and 0.5 to 8 mol % of ZrO2, the optical glass having a B2O3/SiO2 molar ratio of from 2 to 5.5 and having an La2O3 and Gd2O3 total content of 12 to 24 mol % and a ZnO and Li2O total content of 25 to 30 mol %, the optical glass having a refractive index (nd) of 1.75 to 1.85 and an Abbe's number (?d) of 40 to 55, or the optical glass contains, as essential components, B2O3, SiO2, La2O3, Gd2O3, ZnO, Li2O and ZrO2 and has a viscosity of at least 6 dPa·s at a liquidus temperature thereof, a glass transition temperature (Tg) of 600° C. or lower, a refractive index (nd) of 1.75 to 1.Type: GrantFiled: October 16, 2002Date of Patent: December 20, 2005Assignee: Hoya CorporationInventors: Kazutaka Hayashi, Xuelu Zou
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Patent number: 6875714Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.Type: GrantFiled: April 25, 2003Date of Patent: April 5, 2005Assignee: Minolta Co., Ltd.Inventor: Manabu Izuki
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Patent number: 6844279Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (?d) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa·s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (?d) of 45 to 55.Type: GrantFiled: February 20, 2002Date of Patent: January 18, 2005Assignee: Hoya CorporationInventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
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Patent number: 6841493Abstract: The present invention is directed to a glass composition comprising, based on mole %, 15-35% MO where M is selected from BaO, CaO, MgO, PbO, SrO and mixtures thereof, 30-60% TiO2, 10-30% B2O3, 1-7% P2O5, 0-3% Li2O and 2-16% Ln2O3 where Ln is selected from the group of rare earth elements and mixtures thereof. The invention is further directed to the glass composition incorporated in a thick film composition or a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 30-100 wt. % the glass composition; (b) 0-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition used in a method of forming a high K green tape by casting a thin layer of the castable dispersion onto a flexible sheet and heating the cast layer to remove the volatile organic solvent.Type: GrantFiled: March 17, 2003Date of Patent: January 11, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: Yong Cho, Kenneth Warren Hang
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Patent number: 6818578Abstract: An optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time. The optical glass has a refractive index nd of at least 1.875, an Abbe's number &ngr;d of at least 39.5 and a glass transition point Tg of 700° C. or lower, and contains at least one of La2O3, Gd2O3, Y2O3 or Yb2O3 and at least one of ZrO2, Ta2O5 or Nb2O5, with a weight ratio of the total content of La2O3, Gd2O3, Y2O3 and Yb2O3 to the total content of SiO2 and B2O3 of from 3.2 to 5 and the weight ratio of the total content of ZrO2, Ta2O5 and Nb2O5 to the total content of SiO2 and B2O3 is from 1.1 to 1.5.Type: GrantFiled: May 24, 2001Date of Patent: November 16, 2004Assignee: Hoya CorporationInventor: Kazuo Tachiwama
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Publication number: 20040180774Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.Type: ApplicationFiled: March 23, 2004Publication date: September 16, 2004Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
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Patent number: 6753278Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.Type: GrantFiled: May 2, 2002Date of Patent: June 22, 2004Assignee: Schott GlasInventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
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Patent number: 6656859Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: December 6, 2001Date of Patent: December 2, 2003Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
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Patent number: 6653251Abstract: An optical amplifying glass having Er doped in an amount of from 0.01 to 10% as represented by mass percentage to a matrix glass comprising, by mol %, BiO2: 20 to 80, B2O3+SiO2: 5 to 75, Ga2O3+WO3+TeO2: 0.1 to 35, Al2O3≦10, GeO2≦30, TiO2≦30, and SnO2≦30, and containing no CeO2.Type: GrantFiled: July 18, 2002Date of Patent: November 25, 2003Assignee: Asahi Glass Company, LimitedInventors: Naoki Sugimoto, Setsuro Ito
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Patent number: 6645894Abstract: An optical glass that substantially does not contain any Ta2O5 and has high-refractivity low-dispersion optical properties and various optical parts made of such optical glass are provided stably at a low cost, and an optical part made thereof is provided, the optical glass having a glass composition comprising, by weight %, 0 to 7% of SiO2, 18 to 30% of B2O3, provided that the total content of SiO2 and B2O3 is 23 to 35%, 2 to 10% of ZnO, 30 to 50% of La2O3, 0 to 20% of Gd2O3, 0 to 20% of Y2O3, provided that the total content of La2O3, Gd2O3 and Y2O3 is 45 to 60%, 3 to 8% of ZrO2 and 3 to 12% of Nb2O5, the total content of these components being at least 95% by weight, the optical glass having a refractive index [nd] and an Abbe's number [&ngr;d] which satisfy specified relational expressions.Type: GrantFiled: March 27, 2002Date of Patent: November 11, 2003Assignee: Hoya CorporationInventor: Michio Endo
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Publication number: 20030104919Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.Type: ApplicationFiled: May 2, 2002Publication date: June 5, 2003Inventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
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Patent number: 6558316Abstract: A composition has a durability to a sterilization treatment using vapor under high temperature and pressure and capable of transmitting or absorbing light. The composition comprises a group A including 15 to 23 mol % of lanthanum oxide, 3 to 8 mol % of gadolinium oxide, 3 to 8 mol % of tantalum oxide, and 8 mol % or less of yttrium oxide; a group B including 30 to 45 mol % of boron oxide, 20 mol % or less of silicon oxide, and 20 mol % or less of germanium oxide; zero mol % of alkaline metal oxide or alkaline earth metal oxide; and a group D including 0.3 to 15 mol % of niobium oxide and 3 to 15 mol % of zirconium oxide. A mol % ratio A/B between the group A and group B is 80% or more, and a dissolving-out rate of metal ion of the composition is 0.002×10−6 mol/hour or less per square centimeter.Type: GrantFiled: June 27, 2001Date of Patent: May 6, 2003Assignee: Olympus Optical Co., Ltd.Inventors: Akira Kikuchi, Sayaka Konno, Hiroaki Kinoshita
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Patent number: 6497962Abstract: A low melting point glass for covering electrodes, which contains Cu in a content as calculated as CuO within a range of from 0.1 to 0.9% by mass percentage and which contains neither Mo or Sb.Type: GrantFiled: November 1, 2000Date of Patent: December 24, 2002Assignee: Asahi Glass Company, LimitedInventors: Satoshi Fujimine, Yumiko Aoki, Tsuneo Manabe
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Patent number: 6495482Abstract: A glass composition well suited for use in optical amplification consists of an erbium-doped borate glass composition comprising at least 30 mole percent of B2O3, not over 30 mole percent of SiO2, preferably not over 5 mole percent of La2O3, a ratio of B2O3 to (&Sgr;X2O+&Sgr;YO) that is at least 3.5, preferably 4.5, where X2O represents monovalent metal oxides(s) and YO represents divalent metal oxides, the glass providing a wide useful bandwidth (50 nm and greater) for optical amplification around the 1545 nm region.Type: GrantFiled: May 5, 2000Date of Patent: December 17, 2002Assignee: Corning IncorporatedInventors: Jean-Philippe de Sandro, David Jacob, Michel Prassas
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Patent number: 6352950Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: May 31, 2000Date of Patent: March 5, 2002Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison
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Patent number: 6309989Abstract: A tin-borophosphate glass of the present invention has main components of SnO, B2O3, and P2O5, consists essentially of, by mole % representation, 30-70% SnO, 5-30% B2O3, and 24-45% (24% exclusive) P2O5, and satisfies a condition of B2O3/P2O5≧0.20 by mole ratio.Type: GrantFiled: November 29, 1999Date of Patent: October 30, 2001Assignee: Nippon Electric Glass Co., Ltd.Inventor: Takemi Kikutani
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Patent number: 6281151Abstract: The present invention relates to a transparent glass-ceramic material which includes a glass matrix and a crystalline phase of lanthanum fluoride crystals in the glass matrix, where the transparent glass-ceramic material contains no silica. The present invention further relates to a method of producing the transparent glass-ceramic material.Type: GrantFiled: January 24, 2000Date of Patent: August 28, 2001Assignee: Corning IncorporatedInventor: Paul A. Tick
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Patent number: 6153127Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.Type: GrantFiled: December 21, 1998Date of Patent: November 28, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichiro Nakamura, Koichi Maeda
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Patent number: 5747397Abstract: High rare-earth content glasses (Ln.sub.2 O.sub.3 .gtoreq.20 mol %) have applications as high optical density wavelength-selective filters, faraday rotators, scintillation glasses and high index glasses. New glasses are formed by adding TiO.sub.2 to the system SiO.sub.2 --B.sub.2 O.sub.3 --Al.sub.2 O.sub.3 --Ln.sub.2 O.sub.3. These glasses have improved optical properties, extended glass formation range and have superior resistance to devitrification. In some embodiments TiO.sub.2 can fully replace the Al.sub.2 O.sub.3. In additional embodiments, SiO.sub.2 can be completely removed from the glass.Type: GrantFiled: November 4, 1996Date of Patent: May 5, 1998Assignee: Bay Glass ResearchInventors: Donald M. McPherson, Steven C. Murray
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Patent number: 5693580Abstract: Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).Type: GrantFiled: September 13, 1996Date of Patent: December 2, 1997Assignee: Sandia CorporationInventors: Richard K. Brow, Howard L. McCollister, Carol C. Phifer, Delbert E. Day
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Patent number: 5665660Abstract: The object of the present invention is to provide a glass composition which has a sufficient bonding strength for bonding a fluorescent film with a glass tube, does not hinder decomposition of the binder and is effective as an adhesive material, and to provide a fluorescent lamp using the glass composition. The object can be achieved by a glass composition, represented by the general formula,xMO.yB.sub.2 O.sub.3.zM'.sub.2 O.sub.3.uM"O.sub.2.vM'".sub.2 O.sub.5in which M is at least one element of Mg, Ca, Sr, Ba and Zn, M' is at least one element of Al, Sc, Y and lanthanoid elements, M" is at least one element of Ti, Zr, Hf, Th and Si, M'" is at least one element of Nb and Ta, x, y, z, u and v satisfy the relationships of 0<x.ltoreq.70, 15.ltoreq.y.ltoreq.80, 0.ltoreq.z.ltoreq.50, 0.ltoreq.u.ltoreq.30, 0.ltoreq.v.ltoreq.30, 0.5.ltoreq.u+v.ltoreq.50 and x+y+z+u+v=100, represented by mol %, and by a fluorescent lamp, in which the glass composition is incorporated in a phosphor layer in a proportion of 0.Type: GrantFiled: January 2, 1996Date of Patent: September 9, 1997Assignee: Kasei Optnix, Ltd.Inventors: Hiroshi Yamawaki, Masahiko Yoshino, Yasuo Oguri, Masayuki Yamane
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Patent number: 5648302Abstract: Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C.Type: GrantFiled: September 13, 1996Date of Patent: July 15, 1997Assignee: Sandia CorporationInventors: Richard K. Brow, Howard L. McCollister, Carol C. Phifer, Delbert E. Day
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Patent number: 5643636Abstract: A ceramic color composition comprising from 5 to 34 wt % of a heat resistant color pigment powder, from 65 to 94 wt% of a bismuth type glass powder, from 0 to 10 wt % of a refractory filler powder, and from 0.1 to 20 wt % of at least one additive selected from the group consisting of borides and silicides, as inorganic components.Type: GrantFiled: January 24, 1996Date of Patent: July 1, 1997Assignee: Asahi Glass Company Ltd.Inventors: Hiroshi Usui, Hitoshi Onoda, Tsuneo Manabe
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Patent number: 5612154Abstract: A beta-alumina solid electrolyte for use in a sodium-sulfur battery is composed of beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 .mu.m or less, the proportion of the particles having a particle diameter of 5 .mu.m or less is 90% or more, and the maximum particle diameter is 300 .mu.m or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material, uses a magnesium-aluminum spinel as the magnesium source material and subjects all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination.Type: GrantFiled: March 2, 1995Date of Patent: March 18, 1997Assignee: NGK Insulators, Ltd.Inventors: Masaharu Kajita, Takehiro Kajihara, Takao Totoki
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Patent number: 5464674Abstract: A magnetic recording medium comprising a magnetic recording layer and at least one protective layer formed on the recording layer, wherein the outermost protective layer on the side exposed to air is made of an oxide film.Type: GrantFiled: January 12, 1993Date of Patent: November 7, 1995Assignee: Asahi Glass Company Ltd.Inventors: Ichiro Makino, Akira Mitsui, Mikio Takehara, Eiichi Ando, Junichi Ebisawa, Koichi Suzuki, Kiyoshi Matsumoto, Toru Iseda, Susumu Suzuki
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Patent number: 5461021Abstract: A novel composition comprises aluminum borate and zirconium borate. Preferably, the composition is prepared by coprecipitation. The composition is useful as a sorbent or as a catalyst material.Type: GrantFiled: October 17, 1994Date of Patent: October 24, 1995Assignee: Phillips Petroleum CompanyInventor: Lyle R. Kallenbach
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Patent number: 5252521Abstract: This invention relates to a lead-free glass coating made by firing a lead-free glass composition comprising in weight percent from about 35% to about 77% of bismuth oxide, from about 10% to about 33% of boron oxide, and from about 10% to about 32% of zinc oxide at a temperature sufficient to fuse and cure the glass composition. The invention also relates to lead-free glazes and enamels that exhibit excellent acid resistance, possess low coefficients of linear or thermal expansion, and moderate maturation temperatures.Type: GrantFiled: October 19, 1992Date of Patent: October 12, 1993Assignee: Ferro CorporationInventor: Gordon J. Roberts
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Patent number: 5245492Abstract: A magnetic head comprising magnetic core halves which are sealed with a sealing glass which consists essentially of 1 to 75 wt. % of TeO.sub.2, 1 to 30 wt. % of B.sub.2 O.sub.3, 1 to 75 wt. % of PbO, 1 to 25 wt. % of CdO, 0 to 15 wt. % of ZnO, 0 to 25 wt. % of Bi.sub.2 O.sub.3, 0 to 5 wt. % of A.sub.2 O wherein A is an alkali metal, 0 to 35 wt. % of ARO wherein AR is an alkaline earth metal, 0 to 35 wt. % of La.sub.2 O.sub.3, 0 to 5 wt. % of at least one oxide selected from the group consisting of Al.sub.2 O.sub.3, SiO.sub.2, TiO.sub.2 and ZrO.sub.2, 0 to 10 wt. % of at least one oxide selected from the group consisting of Ta.sub.2 O.sub.5, Nb.sub.2 O.sub.5, WO.sub.3 and MoO.sub.3, 0 to 30 wt. % of PbF.sub.2, and 0 to 2 wt. % of CoO, has a coefficient of thermal expansion of from 82.times.10.sup.-7 /.degree.C. to 137.times.10.sup.-7 /.degree.C. in a temperature range between 30.degree. C. and 300.degree. C., a working temperature of from 430.degree. to 620.degree. C.Type: GrantFiled: April 6, 1992Date of Patent: September 14, 1993Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Yasuo Mizuno, Masaki Ikeda, Akihiko Yoshida
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Patent number: 5226959Abstract: A ceramic composition for forming a ceramic dielectric body having a dielectric constant of less than about 5.5 and a TCE of less than about 4.5 ppm/.degree. C. The composition comprises a mixture of finely divided particles of 25-50 vol. % borosilicate glass 40-75 vol. % silica glass and 1-40 wt. % of a material selected from the group consisting of Ga.sub.2 O.sub.3, Ga.sub.2 SiO.sub.5, Ga.sub.2 TiO.sub.5, GaAs, GaPO.sub.4 and any gallium-contained compounds to inhibit the formation of crystalline forms of silica. The composition can be used with a polymeric binder to produce an unfired green tape which is co-fireable with high conductivity metallurgies such as gold, silver and silver/palladium.Type: GrantFiled: March 16, 1992Date of Patent: July 13, 1993Assignee: Aluminum Company of AmericaInventors: Jau-Ho Jean, Tapan K. Gupta
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Patent number: 5209835Abstract: A magnetic recording medium comprising a magnetic recording layer and at least one protective layer formed on the recording layer, wherein the outermost protective layer on the side exposed to air is made of an oxide film.Type: GrantFiled: March 7, 1990Date of Patent: May 11, 1993Assignee: Asahi Glass Company Ltd.Inventors: Ichiro Makino, Akira Mitsui, Mikio Takehara, Eiichi Ando, Junichi Ebisawa, Koichi Suzuki, Kiyoshi Matsumoto, Toru Iseda, Susumu Suzuki
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Patent number: 5137850Abstract: A chemically resistant glass which can be produced at relatively low melting temperatures and has anomalous negative partial dispersion P.sub.g,F, a refractive index n.sub.d of from 1.73 to 1.83 and an Abbe coefficient v.sub.d of from 31 to 38 preferably contains (in % by weight, based on oxides):______________________________________ 0-4 SiO.sub.2 + GeO.sub.2 0-2 GeO.sub.2 0-10 MgO 26-33 B.sub.2 O.sub.3 0-1 Li.sub.2 O 0-16 CaO 19-50 PbO 0-1 Na.sub.2 O 0-16 BaO 1-6 ZrO.sub.2 0-1 K.sub.2 O 0-16 SrO 4-16 Ta.sub.2 O.sub.5 0-2 .SIGMA. alkaline earth 0-6 Al.sub.2 O.sub.3 metal oxides 0-16 ZnO 0-4 TiO.sub.2 1.5-20 .SIGMA. alkaline earth metal oxides + ZnO 0-1 WO.sub.3 0-11 La.sub.2 O.sub.3 0-7 Nb.sub.2 O.sub.5 0-5.5 Y.sub.2 O.sub.3 0-5.5 Gd.sub.2 O.sub.3 4-11 .SIGMA. La.sub.2 O.sub.3 + Y.sub.2 O.sub.3 + Gd.sub.2 O.sub.3 ______________________________________with the proviso that the .SIGMA.(SiO.sub.2 +GeO.sub.2 +B.sub.2 O.sub.3)/.SIGMA.(ta.sub.2 O.sub.5 +ZrO.sub.2 +HfO.sub.2) ratio is less than 5 and the PbO/.Type: GrantFiled: January 16, 1991Date of Patent: August 11, 1992Assignee: Schott GlaswerkeInventors: Marc Clement, Volkmar Geiler, Danuta Grabowski
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Patent number: 5110637Abstract: An amorphous oxide film composed essentially of an oxide containing at least one member selected from the group consisting of Zr, Ti, Hf, Sn, Ta and In and at least one member selected from the group consisting of B and Si.Type: GrantFiled: March 3, 1989Date of Patent: May 5, 1992Assignee: Asahi Glass Company Ltd.Inventors: Eiichi Ando, Koichi Suzuki, Junichi Ebisawa, Susumu Suzuki
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Patent number: 5066621Abstract: Described is a sealing glass composition comprising, in wt. %, 13-50% lead oxide, 20-50% vanadium oxide, 2-40% tellurium oxide, up to 40% selenium oxide, up to 10% phosphorous oxide, up to 5% niobium oxide, up to 20% bismuth oxide, up to 5% copper oxide and up to 10% boron oxide and an electrically conductive formulation comprising, in wt. %, 50-77% silver, 8-34% of a sealing glass composition as described previously, 0.2-1.5% resin and thixotrope and 10-20% organic solvent.Type: GrantFiled: June 21, 1990Date of Patent: November 19, 1991Assignee: Johnson Matthey Inc.Inventor: Masyood Akhtar
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Patent number: 5006489Abstract: The soldering enamel is composed of a basic enamel consisting of aluminium oxide and a rare earth metal oxide and/or an alkali earth metal oxide and, in the given case, some other metallic or metalloid oxide, and of a ceramic filling material. The filling material is a zirconium-rare earth oxide of perovskite crystal structure. The quantity of the filling material amounts up to 5 mass % referred to the overall quantity of enamel.Type: GrantFiled: July 6, 1989Date of Patent: April 9, 1991Assignee: Tungsram ReszvenytarsasagInventors: Ferenc Nagel, Maria J. Farkasne
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Patent number: 4985377Abstract: The invention relates to glaze resistors which are used for electronic parts of hybrid integrated circuit devices, chip resistors, resistor network, etc. The glaze resistor comprises 4.0 to 70.0 wt % of a conductive component composed of a metal silicide and a metal boride and 30.0 to 96.0 wt % of glass in which a rate of said metal boride is 1.0 to 68.0 wt %. Thus, the glaze resistor can be formed by sintering in a non-oxidizing atmosphere and can provide a circuit, together with conductor pattern of base metals such as Cu.Type: GrantFiled: December 7, 1988Date of Patent: January 15, 1991Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Takeshi Iseki, Osamu Makino, Mitsuo Ioka, Hirotoshi Watanabe
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Patent number: 4732875Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.Type: GrantFiled: February 21, 1986Date of Patent: March 22, 1988Assignee: Hoya CorporationInventor: Koji Sagara
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Patent number: 4612295Abstract: A glass for an eye glass lens comprising a SiO.sub.2 (or B.sub.2 O.sub.3)-CaO-Nb.sub.2 O.sub.5 system as a basic system and having a refractive index of 1.79 or more, an Abbe number of 32 to 38 and a specific gravity of less than 3.6 is disclosed.Type: GrantFiled: April 26, 1984Date of Patent: September 16, 1986Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4469800Abstract: This invention is concerned with the preparation of moldable optical glasses having refractive indices of about 1.65-1.735, dispersions of about 38-58, transition temperatures lower than about 500.degree. C., softening points lower than about 600.degree. C., and satisfactory chemical durability consisting essentially, expressed in terms of parts by weight as calculated from the batch, of______________________________________ B.sub.2 O.sub.3 22-38 BaO 3-33 La.sub.2 O.sub.3 5-33 PbO 0-36 ZnO 0-14 CdO 0-12 SrO 0-10 BaO + La.sub.2 O.sub.3 + PbO + ZnO + CdO + SrO 55-68 Li.sub.2 O 0-4 Na.sub.2 O 0-4 Li.sub.2 O + Na.sub.2 O 1.5-4 F 1-8.Type: GrantFiled: July 28, 1983Date of Patent: September 4, 1984Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau
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Patent number: 4367919Abstract: Glass microspheres and other glass elements based on B.sub.2 O.sub.3, BaO, SiO.sub.2 and TiO.sub.2 have an improved combination of crushing strength, index of refraction, and, especially in some formulations, chemical resistance. The microspheres are especially adapted for use as retroreflective elements in pavement markings.Type: GrantFiled: March 19, 1981Date of Patent: January 11, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Chi F. Tung, Benjamin T. Fellows