And Aluminum Or Beryllium Patents (Class 501/52)
  • Patent number: 4330596
    Abstract: In practice no sealing glasses are known with which glass or ceramic material having a coefficient of thermal expansion .alpha..sub.30.degree.-300.degree. C. in the range between 31 to 36.times.10.sup.-7 per .degree.C. can be sealed together.The invention provides bodies which are composed of at least two parts, these parts having been made from a material having a coefficient of expansion as mentioned above, the parts having been sealed together by means of a sealing glass containing 8-10 weight % vanadium pentoxide, 1.5-3.0 weight % copper (II) oxide, 1-3 weight % lead (II) oxide, 0-1 weight % silicon oxide, 0-5 weight % aluminium oxide, 26-28 weight % boron oxide and 58-61 weight % zinc oxide. The weight ratio of boron oxide to zinc oxide is in the range from 0.45 to 0.47.The body is composed of parts (1 and 3), which have been sealed together by means of the sealing glass (2).
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: May 18, 1982
    Assignee: U.S. Philips Corporation
    Inventor: Paul J. Van Assche
  • Patent number: 4311772
    Abstract: This invention is directed to the production of sealing glasses capable of forming strong, non-porous seals with glasses containing at least 10% by weight of an alkali metal oxide such as are used in the fabrication of the glass membranes utilized in sodium-sulfur and potassium-sulfur batteries. The inventive seals require an interdiffusion of ions to occur between the sealing glass and the glass being sealed. Glasses presently employed as membrane glasses for such batteries have base compositions within the Na.sub.2 O-B.sub.2 O.sub.3 and K.sub.2 O-B.sub.2 O.sub.3 systems. The inventive sealing glasses consist essentially, expressed in mole percent on the oxide basis, of about 3-30% R.sub.2 O and 60-95% B.sub.2 O.sub.3, wherein R.sub.2 O consists of K.sub.2 O, Rb.sub.2 O, Cs.sub.2 O, and mixtures thereof and, optionally, Al.sub.2 O.sub.3 is substituted for up to one-half the B.sub.2 O.sub.3 content on a molar basis.
    Type: Grant
    Filed: October 9, 1980
    Date of Patent: January 19, 1982
    Assignee: Corning Glass Works
    Inventor: Andrew Herczog
  • Patent number: 4308064
    Abstract: A strong and biocompatible sintered phosphate of calcium ceramics are obtained by sintering a powdery material substantially consisting of phosphate of calcium having a Ca/P ratio of 1.4-1.75, e.g. apatite group and/or tricalcium phosphate, and not exceeding 15% by weight of CaO-P.sub.2 O.sub.5 frit having a Ca/P ratio of 0.2-0.75. Y.sub.2 O.sub.3 incorporation therein improves the bending strength of the ceramics. Furthermore, a P.sub.2 O.sub.5 -metal oxide frit wherein metal oxide being one or more selected from BaO, CaO, MgO, ZnO, NaO and K.sub.2 O provides a more improved bending strength. The Y.sub.2 O.sub.3 incorporation herein still improves the strength of the sintered product.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: December 29, 1981
    Assignee: NGK Spark Plugs Co., Ltd.
    Inventors: Akio Takami, Kazuo Kondo
  • Patent number: 4291107
    Abstract: A glass for sealing a beta-alumina tube in a sodium-sulphur cell has a composition suitable to resist attack by sodium at elevated temperatures and a coefficient of thermal expansion suitable for use with beta-alumina. The glass consists essentially of 28-48 mol % B.sub.2 O.sub.3, 0-20 mol % SiO.sub.2, 16-28 mol % Al.sub.2 O.sub.3, together with 18-33 mol % of at least one alkaline earth oxide selected from the group consisting of BaO, SrO, CaO and MgO, the proportions of the constituents being such that the combined total of B.sub.2 O.sub.3 and SiO.sub.2 is 40 to 60 mol % and furthermore being such that 0.0517 A.sub.1 +0.0354 A.sub.2 -0.0063 A.sub.3 +0.168 A.sub.4 +0.1336 A.sub.5 +0.098 A.sub.6 +0.1597 A.sub.7, lies between 5.7 and 6.4 where A.sub.1, A.sub.2, A.sub.3, A.sub.4, A.sub.5, A.sub.6 and A.sub.7 are the respective molar percentages of B.sub.2 O.sub.3, SiO.sub.2, Al.sub.2 O.sub.3, BaO, CaO, MgO and SrO.A cell sealed with such a glass is described.
    Type: Grant
    Filed: April 15, 1980
    Date of Patent: September 22, 1981
    Assignee: Chloride Silent Power Limited
    Inventors: Thomas I. Barry, Gary S. Schajer, Francis M. Stackpool