And Boron Patents (Class 501/65)
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Patent number: 11952307Abstract: A method for preparing a microstructure on the surface of glass by titanium oxide nanoparticle-assisted infrared nanosecond laser, including the following steps: (1) dropwise applying a titanium oxide nanoparticle hydrogel onto the surface of a glass sample; (2) pressing another piece of glass on the surface of the hydrogel, so the hydrogel is evenly distributed between the two pieces of glass, and allowing the two pieces of glass to stand horizontally for a period of time to air-dry the hydrogel; (3) separating the two pieces of glass to obtain a glass with a uniform titanium oxide nanoparticle coating; (4) forming a microstructure using an infrared nanosecond laser with a wavelength of 1064 nm; and (5) performing after-treatment, including ultrasonically cleaning the sample with acetone, absolute ethanol and deionized water respectively for 10 min to remove titanium oxide nanoparticles attached to the surface, to obtain a glass sample with the microstructure.Type: GrantFiled: December 28, 2019Date of Patent: April 9, 2024Assignee: SHANDONG UNIVERSITYInventors: Yukui Cai, Zhanqiang Liu, Xichun Luo, Yiping Tang, Yi Wan, Qinghua Song, Bing Wang
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Patent number: 11465937Abstract: A glass-based article may include from about 45 mol. % to about 80 mol. % SiO2; from about 0 mol. % to about 10 mol. % Na2O; less than about 5 mol. % K2O; a non-zero amount of Al2O; and an amorphous phase and a crystalline phase. The article may further in include a stress profile comprising a surface compressive stress (CS) and a maximum central tension (CT). A ratio of Li2O (mol. %) to R2O (mol. %) in the article is from about 0.5 to about 1, where R2O is the sum of Li2O, Na2O, and K2O in the article. CT may be greater than or equal to about 50 MPa and less than about 100 MPa. CS may be greater than 2.0·CT. A depth of compression (DOC) of the stress profile may be greater than or equal to 0.14·t and less than or equal to 0.25·t, where t is the thickness of the article.Type: GrantFiled: January 13, 2021Date of Patent: October 11, 2022Assignee: Corning IncorporatedInventors: Guangli Hu, Charlene Marie Smith, Zhongzhi Tang, Steven Alvin Tietje
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Patent number: 11453609Abstract: A method for producing a glass article having high hydrolytic resistance is provided. A glass tube consisting of borosilicate glass and having an Al2O3 content of less than 1 weight-%, a ZrO2 content of 2-12 weight-%, and a glass transition temperature Tg is reshaped into a glass article and is subsequently subjected to a thermal post-treatment. To reduce the alkali release of the glass article, the glass article is subjected to a treatment temperature of TB?Tg+5° K over a treatment time of tB?5 min and is subsequently cooled during the thermal post-treatment.Type: GrantFiled: April 9, 2019Date of Patent: September 27, 2022Assignee: Schott AGInventors: Malte Grimm, Christof Kass, Peter Nass
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Patent number: 11161768Abstract: A glass sheet having a composition which comprises total iron (expressed in terms of Fe2O3) from 0.002-0.06 wt %; chromium (expressed as Cr2O3) from 3-75 ppm; and manganese (expressed as MnO) from 50-1,000 ppm. The glass sheet has a LTD4 higher than 70%. Such a glass sheet exhibits at once a high luminous transmission, an increased transmission of infrared (IR) radiation and a pleasing slight color or an almost neutral to neutral color.Type: GrantFiled: July 18, 2017Date of Patent: November 2, 2021Assignee: AGC GLASS EUROPEInventors: Thomas Lambricht, Audrey Dogimont, Aline Degand, Michel Bogaerts
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Patent number: 10294151Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than 0.7·t, comprise a tangent that is less than about ?0.1 MPa/micrometers or greater than about 0.1 MPa/micrometers, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness.Type: GrantFiled: September 19, 2017Date of Patent: May 21, 2019Assignee: Corning IncorporatedInventors: Guangli Hu, Charlene Marie Smith, Zhongzhi Tang, Steven Alvin Tietje
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Patent number: 10266447Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than 0.7·t, comprise a tangent that is less than about ?0.1 MPa/micrometers or greater than about 0.1 MPa/micrometers, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness.Type: GrantFiled: September 19, 2017Date of Patent: April 23, 2019Assignee: Corning IncorporatedInventors: Guangli Hu, Charlene Marie Smith, Zhongzhi Tang, Steven Alvin Tietje
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Patent number: 10259746Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than 0.7·t, comprise a tangent that is less than about ?0.1 MPa/micrometers or greater than about 0.1 MPa/micrometers, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness.Type: GrantFiled: September 19, 2017Date of Patent: April 16, 2019Assignee: Corning IncorporatedInventors: Guangli Hu, Charlene Marie Smith, Zhongzhi Tang, Steven Alvin Tietje
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Patent number: 10167222Abstract: UV- and IR-absorbing materials with brown tint for sunglasses are described. The sunglass materials are prepared from a base glass through a post-fabrication process that includes ion exchange with silver. The tint of the sunglass material can be adjusted by controlling the level of ion exchange of the base glass with silver by varying the conditions of ion exchange. A wide range of tint is possible, including multiple shades of brown tint. In a typical process, a base glass having strong absorption in the UV and IR is fabricated and the resulting glass is subjected to a post-fabrication silver ion exchange process to control tint. The post-fabrication silver ion exchange process permits control of tint while maintaining strong UV and IR absorption and adequate transmittance in the visible.Type: GrantFiled: August 25, 2016Date of Patent: January 1, 2019Assignee: Corning IncorporatedInventors: Pierre-Jean Baron, Yves Andre Henri Brocheton
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Patent number: 10071442Abstract: A focusing unit of a laser processing apparatus includes: a focusing lens that focuses a laser beam oscillated from a laser beam oscillating unit; and a spherical aberration extending lens that extends the spherical aberration of the focusing lens. A pulsed laser beam is applied from the focusing unit to a workpiece held on a chuck table, to form shield tunnels each composed of a fine hole and an amorphous region shielding the fine hole, the shield tunnels extending from an upper surface toward a lower surface of the workpiece.Type: GrantFiled: April 5, 2016Date of Patent: September 11, 2018Assignee: DISCO CORPORATIONInventors: Hiroshi Morikazu, Noboru Takeda, Kazuya Hirata
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Patent number: 9556058Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.Type: GrantFiled: August 11, 2014Date of Patent: January 31, 2017Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
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Patent number: 9469564Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.Type: GrantFiled: May 13, 2014Date of Patent: October 18, 2016Assignee: AvanStrate Inc.Inventors: Akihiro Koyama, Satoshi Ami, Manabu Ichikawa
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Patent number: 9284215Abstract: There is provided a glass for chemical strengthening having a gray-based color tone and excelling in characteristics preferred for the purposes of housing or decoration of an electronic device, that is, bubble quality, strength, and light transmittance characteristics. A glass for chemical strengthening contains, in mole percentage based on following oxides, 55% to 80% of SiO2, 3% to 16% of Al2O3, 0% to 12% of B2O3, 5% to 16% of Na2O, 0% to 4% of K2O, 0% to 15% of MgO, 0% to 3% of CaO, 0% to 18% of ?RO (where R represents Mg, Ca, Sr, Ba or Zn), 0% to 1% of ZrO2, 0.01% to 0.2% of Co3O4, 0.05% to 1% of NiO, and 0.01% to 3% of Fe2O3.Type: GrantFiled: September 17, 2013Date of Patent: March 15, 2016Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Hiroyuki Yamamoto, Kazuhide Kuno
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Patent number: 9159467Abstract: In order to provide a dielectric ceramic composition capable of sintering at a low temperature, implementing a low relative dielectric constant, providing other excellent properties (such as a relative density and an insulation resistance), performing co-firing of different materials, and suppressing dispersion of Ag in the sintered body when the internal electrode is formed, the dielectric ceramic composition includes a main ingredient containing SiO2—K2O—B2O3-based glass of 40 to 65 weight %, quartz of 35 to 50 weight %, and amorphous silica of remaining weight %; and a subsidiary ingredient containing alumina of 1.5 to 4 weight %, K2O-MO—SiO2—B2O3-based glass (where “MO” denotes at least any one selected from a group consisting of CaO and SrO) of 5 to 20 weight % relative to the main ingredient of 100 weight %.Type: GrantFiled: January 28, 2014Date of Patent: October 13, 2015Assignee: TDK CORPORATIONInventors: Shusaku Umemoto, Takashi Suzuki, Hidekazu Sato, Masaki Takahashi, Shinichi Kondo
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Patent number: 9156725Abstract: Described herein are various glass compositions, glass articles, and information storage devices that comprise the glass articles as substrates therefor, along with methods for their manufacture and use.Type: GrantFiled: May 29, 2013Date of Patent: October 13, 2015Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, John Christopher Mauro, Morten Mattrup Smedskjaer
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Patent number: 9029278Abstract: An alumino-borosilicate glass for the confinement, isolation of a radioactive liquid effluent of medium activity, and a method for treating a radioactive liquid effluent of medium activity, wherein calcination of said effluent is carried out in order to obtain a calcinate, and a vitrification adjuvant is added to said calcinate.Type: GrantFiled: December 23, 2009Date of Patent: May 12, 2015Assignee: Areva NCInventors: Jean-Luc Dussossoy, Agnés Grandjean, Thierry Advocat, Nicolas Bousquet, Sophie Schuller
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Patent number: 9018115Abstract: Provided is a light-emitting glass which is applicable to, e.g., white illuminators including a light-emitting diode as a light source, and which emits light of a warm white color when irradiated with near ultraviolet light and combines long-term weatherability with high heat resistance; a light-emitting device containing same and a process for producing same. The light-emitting glass includes, as the base glass, borosilicate or silicate glass having a separated-phase structure, whereby the base glass is efficiently doped with, for example, transition metal ion clusters which emit light of a warm white color upon irradiation with near ultraviolet light. With this glass, it is possible to attain increases in excitation wavelength and emission wavelength. The glass thus emits, based on a multiple scattering effect, high-intensity light of a warm white color upon irradiation with near ultraviolet light.Type: GrantFiled: October 22, 2010Date of Patent: April 28, 2015Assignee: Tokyo University of Science Educational Foundation Administrative OrganizationInventors: Atsuo Yasumori, Tetsuo Kishi, Naoko Matsui
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Patent number: 8980139Abstract: A method of manufacturing a metal paste for an internal electrode according to the present invention includes preparing each of a metal powder and an organic vehicle; preparing a ceramic inhibitor powder in which a nano glass added with a rare-earth element is mixed; manufacturing a primary mixture by mixing the metal powder of 70 to 95 wt % and the ceramic inhibitor powder of 5 to 30 wt % when each of the metal powder, the organic vehicle, and the ceramic inhibitor powder in which the nano glass added with the rare-earth element is mixed is prepared; manufacturing a secondary mixture by mixing the primary mixture of 50 to 70 wt % and the organic vehicle of 30 to 50 wt % when the primary mixture is manufactured; and manufacturing the metal paste for the internal electrode by filtering the secondary mixture when the secondary mixture is manufactured.Type: GrantFiled: March 12, 2013Date of Patent: March 17, 2015Assignee: Samhwa Capacitor Co., Ltd.Inventors: Young Joo Oh, Jung Rag Yoon
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Publication number: 20150037552Abstract: High CTE glass compositions and laminated glass articles formed from the same are described. In one embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2, from about 0 mol. % to about 8 mol. % Al2O3, and from about 3 mol. % to about 10 mol. % B2O3 as glass formers. The glass composition may further include alkali oxides such as from about 0 mol. % to about 2 mol. % Na2O and from about 10 mol. % to about 15 mol. % K2O. In addition, the glass composition may include from about 5 mol. % to about 6 mol. % of alkaline earth oxide. The alkaline earth oxide may include at least one of CaO, SrO, and BaO. However, the glass composition may be substantially free from MgO. The glass composition may be used in a laminated glass article, such as a laminated glass article formed by a fusion laminate process.Type: ApplicationFiled: February 28, 2013Publication date: February 5, 2015Inventor: John Christopher Mauro
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Patent number: 8946102Abstract: This invention relates to lead free and cadmium free copper-containing glass fits that can be used as pigments to color other glass fits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.Type: GrantFiled: June 16, 2010Date of Patent: February 3, 2015Assignee: Ferro CorporationInventors: Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
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Patent number: 8937027Abstract: A glass composition and its use for producing glass tubes is provided. The glass tubes having the provided composition are particularly suitable for the outer tubes of fluorescent lamps in the case of which a phosphor layer is baked at temperatures of up to 700° C. The tubes composed of the glass of the provided composition have a lower tendency to deform or stick together when processed at high temperatures. To obtain the observed effects, the molar ratio of Na2O/(Na2O+K2O), inter alia, is greater than 0.4 and not more than 0.72.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Schott AGInventors: Erhard Dick, Joerg Hinrich Fechner
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Patent number: 8889575Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?X?20, 0?Z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.Type: GrantFiled: May 31, 2011Date of Patent: November 18, 2014Assignee: Corning IncorporatedInventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
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Publication number: 20140284577Abstract: Thin glasses having high refractive index (nd), a layer composite assembly made from these thin glasses, a method for the production of the thin glasses, and the uses of the thin glasses are provided. The thin glasses are processed in an in line manufacturing process and have the optical properties of a classical optical glass. The thin glasses are highly transparent, crystallization-resistant, chemically resistant and highly refractive. The viscosity/temperature behavior of the thin glasses is adjusted to the manufacturing process via in line flat glass methods.Type: ApplicationFiled: March 18, 2014Publication date: September 25, 2014Applicant: Schott AGInventors: Karl Mennemann, Uwe Kolberg, Holger Wegener, Monika Gierke, Ute Woelfel, Joerg Fechner
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Publication number: 20140247848Abstract: The invention relates to a Nd-doped, aluminate-based or silicate-based, laser glass having a peak emission wavelength that is longer than 1059.7 nm, an emission cross section (?em) of ?1.5×10?20 cm2, and/or an emission bandwidth (??eff) of ?28 nm, while maintaining properties that render the glass suitable for commercial use, such as low glass transition temperature Tg and low nonlinear index, n2.Type: ApplicationFiled: April 14, 2014Publication date: September 4, 2014Applicant: SCHOTT CORPORATIONInventors: Simi GEORGE, Nathan CARLIE, Sally PUCILOWSKI, Joseph HAYDEN
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Patent number: 8820119Abstract: To provide a vial with low alkali elution and a method for producing the same by removing a deteriorated region caused by processing on an internal surface of a vial. A vial with reduced alkali elution and a method for producing the same by forming vials from borosilicate glass tubes comprises a first step of forming a borosilicate glass tube into a cup-shaped body by formation of a bottom of a vial, and a second step of forming the cup-shaped body into the vial by formation of a mouth of the cup-shaped body.Type: GrantFiled: May 15, 2006Date of Patent: September 2, 2014Assignee: Nipro CorporationInventors: Hideo Kuwabara, Hideki Yamauchi, Yoshitaka Ishimi, Shinichiro Senga
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Patent number: 8795702Abstract: This invention relates to methods for producing a composite bone graft material that can regenerate bony defects in the body. The invention further relates to methods that allow for the production of bioactive glass particles used in the composite that have been surface treated to allow for the production of a highly porous composite that can hold significant amounts of body fluid or other molecules that will aid in the regenerative process. The method of surface treatment allows for the manufacture of a suitable implantable composite while retaining the unique osteostimulative properties that are associated with bioactive glass particles.Type: GrantFiled: March 3, 2011Date of Patent: August 5, 2014Assignee: Novabone Products, LLCInventors: David C. Greenspan, Srinivas Katta
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Patent number: 8785337Abstract: A glass container and related methods of manufacturing. The glass container has a glass composition including soda-lime base glass materials, and an oxide of vanadium for good ultraviolet light blocking properties and an oxide of selenium to decolor the glass for good clarity and decolorization. The glass composition of the glass container also may include an oxide of sulfur.Type: GrantFiled: July 8, 2011Date of Patent: July 22, 2014Assignee: Owens-Brockway Glass Container Inc.Inventors: Stephen D. Barton, Carol A. Click, Terence K. G. Howse
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Patent number: 8618005Abstract: Provided are a glass powder represented as aLi2O-bK2O-cBaO-dB2O3-eSiO2wherein a+b+c+d+e=1, and 0.01?a?0.1, 0.01?b?0.1, 0.01?c?0.1, 0.05?d?0.3, and 0.3?e?0.7 are satisfied in terms of mol %, a method of manufacturing the same, and a multi-layered ceramic material using the same. Therefore, a nano glass powder having an average particle size of 100nm or less and uniform particle size distribution can be manufactured using liquid phase deposition, specifically, a sol-gel method. In addition, the glass powder can be used as sintering additives to decrease a sintering temperature by about 100° C. in comparison with conventional glass upon manufacture of a ceramic material such as MLCC and MLCI, which can be sintered at a low temperature, contributing to improvement of dielectric capacity and inductance capacity of the parts and increasing quality coefficient.Type: GrantFiled: May 9, 2011Date of Patent: December 31, 2013Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Sungyong An, Jeongwook Kim, Sungbum Sohn, Jinwoo Hahn, Soonmo Song
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Patent number: 8609559Abstract: Disclosed are a glass composition and a dielectric composition enabling low temperature sintering, and a high capacitance multilayer ceramic capacitor using the same. In the glass composition used for sintering, the glass composition may be formed of a formula, aR2O-bCaO-cZnO-dBaO-eB2O3-fAl2O3-gSiO2, and the formula may satisfy a+b+c+d+e+f+g=100, 0?a?7, 1?b?3, 1?c?15, 10?d?20, 3?e?10, 0?f?3, and 55?g?72. Through this, when manufacturing the high capacity multilayer ceramic capacitor, the dielectric substance may enable the lower temperature sintering, thereby enhancing a capacitance and a reliability of the high capacitance multilayer ceramic capacitor.Type: GrantFiled: March 13, 2013Date of Patent: December 17, 2013Assignee: Samhwa Capacitor Co., Ltd.Inventors: Young Joo Oh, Jung Rag Yoon
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Patent number: 8541327Abstract: A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO2; one or more compounds from the group of compounds consisting of La2O3, Al2O3, B2O3, and Ni; the La2O3 less than about 20 mole percent; the Al2O3 less than about 25 mole percent; the B2O3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.Type: GrantFiled: October 21, 2011Date of Patent: September 24, 2013Assignee: U.S. Department of EnergyInventors: Peizhen Kathy Lu, Manoj Kumar Mahapatra
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Publication number: 20130230692Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0.1 to 60% of SiO2+Al2O3+B2O3, having a mass ratio (BaO+La2O3+Nb2O5+TiO2+ZrO2)/(SiO2+Al2O3+B2O3) of 0.1 to 50, amass ratio (MgO+CaO+SrO+BaO)/(BaO+La2O3+Nb2O5+TiO2+ZrO2) of 0 to 10, and a mass ratio (TiO2+ZrO2)/(BaO+La2O3+Nb2O5) of 0.001 to 40, and having a refractive index nd of 1.55 to 2.3.Type: ApplicationFiled: December 7, 2011Publication date: September 5, 2013Inventors: Tomoki Yanase, Takashi Murata
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Publication number: 20130210603Abstract: Provided are a glass powder represented as aLi2O-bK2O-cBaO-dB2O3-eSiO2 wherein a+b+c+d+e=1, and 0.01?a?0.1, 0.01?b?0.1, 0.01?c?0.1, 0.05?d?0.3, and 0.3?e?0.7 are satisfied in terms of mol %, a method of manufacturing the same, and a multi-layered ceramic material using the same. Therefore, a nano glass powder having an average particle size of 100 nm or less and uniform particle size distribution can be manufactured using liquid phase deposition, specifically, a sol-gel method. In addition, the glass powder can be used as sintering additives to decrease a sintering temperature by about 100° C. in comparison with conventional glass upon manufacture of a ceramic material such as MLCC and MLCI, which can be sintered at a low temperature, contributing to improvement of dielectric capacity and inductance capacity of the parts and increasing quality coefficient.Type: ApplicationFiled: March 15, 2013Publication date: August 15, 2013Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Sungyong AN, Jinwoo HAHN, Jeongwook KIM
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Publication number: 20130196159Abstract: Disclosed are a glass composition and a dielectric composition enabling low temperature sintering, and a high capacitance multilayer ceramic capacitor using the same. In the glass composition used for sintering, the glass composition may be formed of a formula, aR2O-bCaO-cZnO-dBaO-eB2O3-fAl2O3-gSiO2, and the formula may satisfy a+b+c+d+e+f+g=100, 0?a?7, 1?b?3, 1?c?15, 10?d?20, 3?e?10, 0?f?3, and 55?g?72. Through this, when manufacturing the high capacity multilayer ceramic capacitor, the dielectric substance may enable the lower temperature sintering, thereby enhancing a capacitance and a reliability of the high capacitance multilayer ceramic capacitor.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Applicant: SAMHWA CAPACITOR CO., LTD.Inventor: Samhwa Capacitor Co., Ltd.
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Patent number: 8492297Abstract: A device including a glass substrate made of a soda lime silica glass composition of: SiO2 (50˜75 wt %); Na2O (1˜8 wt %); K2O (1˜12 wt %); CaO (1˜12 wt %); ZrO2 (0˜8 wt %); SrO (0˜15 wt %); BaO (0˜12 wt %); MgO (0˜10 wt %); Al2O3 (0˜12 wt %); B2O3 (0˜3 wt %), wherein the total amount of Na2O and K2O is in the range of 5˜15 wt %, the total amount of CaO, MgO, SrO and BaO is in the range of 10˜25 wt %.Type: GrantFiled: August 31, 2010Date of Patent: July 23, 2013Assignee: SAGE Electrochromics, Inc.Inventors: Jun-Young Lee, Sei-Woong Yoo, Doo-Sang Ko, Marc Maurer
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Patent number: 8476353Abstract: Provided are an amorphous polyamide resin composition having high transparency, and is excellent in heat resistance and stiffness, and a molded product thereof. The glass filler contains, expressed in terms of oxides by mass %, 68 to 74% of silicon dioxide (SiO2), 2 to 5% of aluminum oxide (Al2O3), 2 to 5% of boron oxide (B2O3), 2 to 10% of calcium oxide (CaO), 0 to 5% of zinc oxide (ZnO), 0 to 5% of strontium oxide (SrO), 0 to 1% of barium oxide (BaO), 1 to 5% of magnesium oxide (MgO), 0 to 5% of lithium oxide (Li2O), 5 to 12% of sodium oxide (Na2O), and 0 to 10% of potassium oxide (K2O), where a total amount of lithium oxide (Li2O), sodium oxide (Na2O), and potassium oxide (K2O) is 8 to 12%.Type: GrantFiled: September 25, 2008Date of Patent: July 2, 2013Assignee: Asahi Fiber Glass Company, LimitedInventors: Hideyuki Higashiyama, Keiji Sekine
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Publication number: 20130116108Abstract: The invention relates to a silica glass compound having improved physical and chemical properties. In one embodiment, the present invention relates to a silica glass having a desirable brittleness in combination with a desirable density while still yielding a glass composition having a desired hardness and desired strength relative to other glasses. In another embodiment, the present invention relates to a silica glass composition that contains at least about 85 mole percent silicon dioxide and up to about 15 mole percent of one or more dopants selected from F, B, N, Al, Ge, one or more alkali metals (e.g., Li, Na, K, etc.), one or more alkaline earth metals (e.g., Mg, Ca, Sr, Ba, etc.), one or more transition metals (e.g., Ti, Zn, Y, Zr, Hf, etc.), one or more lanthanides (e.g., Ce, etc.), or combinations of any two or more thereof.Type: ApplicationFiled: July 2, 2012Publication date: May 9, 2013Applicant: MOMENTIVE PERFORMANCE MATERIALS, INC.Inventors: Nathan J. Cassingham, Ben Matthew Gauthier, Martin Panchula, Robert Stephen Pavlik, Yan Zhou, Konstantin S. Zuyev
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Publication number: 20130115422Abstract: Provided is a glass sheet, comprising, as a glass composition in terms of mass %, 40 to 80% of SiO2, 0 to 30% of Al2O3, 0 to 15% of B2O3, 0 to 25% of an alkali metal oxide (one kind or two or more kinds of Li2O, Na2O, and K2O), and 0 to 15% of an alkaline earth metal oxide (one kind or two or more kinds of MgO, CaO, SrO, and BaO), and being used as a viewing zone control member for covering partially or wholly a two-dimensional display.Type: ApplicationFiled: June 3, 2011Publication date: May 9, 2013Inventor: Takashi Murata
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Publication number: 20130040169Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 ?m?1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of ?5° C. or lower, of 7 ?m?1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R?2O in which R? is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R?2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.Type: ApplicationFiled: June 7, 2012Publication date: February 14, 2013Applicant: HOYA CORPORATIONInventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
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Publication number: 20130037105Abstract: A compositional range of high strain point and/or intermediate expansion coefficient alkali metal free aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates or superstrates for photovoltaic devices, for example, thin film photovoltaic devices such as CdTe or CIGS photovoltaic devices or crystalline silicon wafer devices. These glasses can be characterized as having strain points ?600° C., thermal expansion coefficient of from 35 to 50×10?7/° C.Type: ApplicationFiled: August 8, 2012Publication date: February 14, 2013Inventors: Bruce Gardiner Aitken, James Edward Dickinson, JR., Timothy James Kiczenski, John Christopher Mauro, Adama Tandia
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Patent number: 8367208Abstract: The invention is directed to a high strength, chemically toughened protective glass article, the glass article having a high damage tolerance threshold of at least 1500 g as measured by the lack of radial cracks when the load is applied to the glass using a Vickers indenter; preferably greater than 2000 g s measured by the lack of initiation of radial cracks when the load is applied to the glass using a Vickers indenter.Type: GrantFiled: February 6, 2009Date of Patent: February 5, 2013Assignee: Corning IncorporatedInventors: Gregory Scott Glaesemann, James Joseph Price, Robert Sabia, Nagaraja Shashidhar
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Publication number: 20130017387Abstract: Disclosed are a phase separable glass compositions used to produce chemically durable porous glass, e.g., porous glass powder, and the application of a sol gel coating to the glass to enhance chemical durability of the glass in alkaline solutions, and to the use of the glass, e.g., glass powder, as substrates for separation technology where harsh alkaline environments (pH?12 e.g., pH 12-14) are routinely prevalent.Type: ApplicationFiled: July 12, 2011Publication date: January 17, 2013Inventors: William H. JAMES, III, Sally Pucilowski, Eric H. Urruti, Matthias Bockmeyer
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Publication number: 20130011607Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0 to 10% of B2O2, 0.001 to 35% of SrO, 0.001 to 30% of ZrO2+TiO2, and 0 to 10% of La2O2+Nb2O5, having a mass ratio of BaO/SrO of 0 to 40 and a mass ratio of SiO2/SrO of 0.1 to 40, and having a refractive index nd of 1.55 to 2.3.Type: ApplicationFiled: May 18, 2012Publication date: January 10, 2013Inventors: Atsushi MUSHIAKE, Takashi MURATA, Tomoki YANASE
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Patent number: 8329602Abstract: An optical glass has a refractive index (nd) of 1.60 or over and excellent transmittance and internal quality. The optical glass comprises 0.1-4 mass % of Ta2O5 to total mass of glass calculated on oxide basis, has ratio of 0.95<Ta2O5/(Ta2O5+(ZrO2)+TiO2+Nb2O5+WO3)×5)?1.00, and further comprises SiO2+B2O3+Al2O3+BaO in a total amount of 81% or over.Type: GrantFiled: August 2, 2010Date of Patent: December 11, 2012Assignee: Ohara Inc.Inventor: Michiko Ogino
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Publication number: 20120308803Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.Type: ApplicationFiled: August 17, 2012Publication date: December 6, 2012Inventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
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Publication number: 20120308827Abstract: Ion exchangeable glass articles are disclosed. In one embodiment, a glass article formed from alkali aluminosilicate glass which may include Ga2O3, Al2O3, Na2O, SiO2, B2O3, P2O5 and various combinations thereof. The glass article may generally include about X mol % of Ga2O3 and about Z mol % of Al2O3, wherein 0?x?20, 0?z?25 and 10?(X+Z)?25. The glass article may also include from about 5 mol % to about 35 mol % Na2O, SiO2 may be present in an amount from about 40 mol % to about 70 mol % SiO2. The glass article may further include Y mol % B2O3 where Y is from 0 to about 10. The glass article may further include (10-Y) mol % of P2O5. Glass articles formed according to the present invention may be ion-exchange strengthened. In addition, the glass articles may have a low liquid CTE which enables the glass articles to be readily formed into complex shapes.Type: ApplicationFiled: May 31, 2011Publication date: December 6, 2012Inventors: Heather Debra Boek, Mark Owen Weller, Randall Eugene Youngman
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Patent number: 8318621Abstract: The invention relates to a glass sheet, the composition of which is of the soda-lime-silica type and comprises the following constituents in contents varying within the weight limits defined below: Fe2O3 (total iron) 0 to 0.02%; and WO3 0.1 to 2%.Type: GrantFiled: September 19, 2008Date of Patent: November 27, 2012Assignee: Saint-Gobain Glass FranceInventors: Dominique Sachot, Octavio Cintora-Gonzalez
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Publication number: 20120289394Abstract: To provide a colored glass plate, which uses sodium sulfate (Na2SO3) as a refining agent and which is capable of stably maintaining the mass percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 at a high level, while suppressing development of an amber color that is derived from sodium sulfate. A colored glass plate made of alkali-containing silica glass containing elements of iron, tin and sulfur, wherein the percentage of the total sulfur calculated as SO3 is at least 0.025% as represented by mass percentage based on oxides, the percentage of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 is from 60 to 80% as represented by mass percentage, and the percentage of divalent tin calculated as SnO2 in the total tin calculated as SnO2 is at least 0.1% as represented by mol percentage.Type: ApplicationFiled: July 12, 2012Publication date: November 15, 2012Applicant: Asahi Glass Company, LimitedInventors: Kensuke NAGAI, Yuichi Suzuki, Terutaka Maehara
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Publication number: 20120251743Abstract: A housing/enclosure/cover can include an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (6) a Young's Modulus ranging between about 50 to 100 GPa;; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.Type: ApplicationFiled: May 15, 2012Publication date: October 4, 2012Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
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Patent number: 8273671Abstract: A glass material for producing insulation layers is provided. The glass material can improve the radio-frequency properties of radio-frequency substrates or radio-frequency conductor arrangements. In one embodiment, the glass material for producing insulation layers for radio-frequency substrates or radio-frequency conductor arrangements is an applied layer with a layer thickness in the range between 0.05 ?m and 5?mm and has a loss factor tan ? of less than or equal to 70*10?4 in at least a frequency range above 1 GHz.Type: GrantFiled: May 23, 2003Date of Patent: September 25, 2012Assignee: Schott AGInventors: Jürgen Leib, Dietrich Mund
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Patent number: 8263230Abstract: A ceramic composition is prepared to contain a B2O3—SiO2—Al2O3-MO based glass composition (M: Ca, Mg, Sr and/or Ba, B2O3: 4 to 17.5 weight %, SiO2: 28 to 50 weight %, Al2O3: 0 to 20 weight %, and MO: 36 to 50 weight %): 24 to 40 weight %, SrTiO3 and/or CaTiO3: 46 to 75.4 weight %, CuO: 0.1 to 5.0 weight %, CaO: 0.5 to 7.0 weight %, and MnO, ZnO and/or CoO: 10 weight % or more (however, including 0% by weight). The ceramic composition is subjected to firing to produce a ceramic sintered body, and obtain a composite LC component including the ceramic sintered body. While suppressing the shrinkage behavior during firing, dielectric properties can be improved dramatically as compared with conventional cases, and moreover reliability can be ensured.Type: GrantFiled: May 17, 2011Date of Patent: September 11, 2012Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuhiro Kaneko, Satoshi Oga
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Patent number: RE44869Abstract: An alkali aluminosilicate glass that is chemically strengthened and has a down-drawable composition. The glass has a melting temperature less than about 1650° C. and a liquidus viscosity of at least 130 kpoise and, in one embodiment, greater than 250 kpoise. The glass undergoes ion exchange at relatively low temperatures to a depth of at least 30 ?m.Type: GrantFiled: February 23, 2012Date of Patent: April 29, 2014Assignee: Corning IncorporatedInventors: Adam James Ellison, Sinue Gomez