And Boron Patents (Class 501/65)
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Patent number: 6512879Abstract: Phosphate free, Er/Yb co-doped borosilicate glass compositions and optical devices made from said compositions are disclosed; said compositions comprising, for 100 parts by weight of: 60 to 70 parts by weight SiO2 or SiO2+GeO2 with SiO2 always being greater than 40 parts by weight, 8 to 12 parts by weight of B2O3, 10 to 25 parts by weight M2O wherein M2O is an alkali metal oxide, 0 to 3 parts by weight of BaO, 0.1 to 5 parts by weight Er2O3, and from 0.1 to 12 parts by weight of Yb2O3 and from 0 to less than 5 parts by weight F; and within which, the boron atoms are of tetrahedral spatial coordination.Type: GrantFiled: November 3, 2000Date of Patent: January 28, 2003Assignee: Corning IncorporatedInventors: Alain Beguin, Patrice Camy, Pascale LaBorde, Christian Lerminiaux
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Patent number: 6503860Abstract: According to one aspect of the present invention an optically active glass contains Sb2O3, up to about 4 mole % of an oxide of a rare earth element, and 0-20 mole % of a metal halide selected from the group consisting of a metal fluoride, a metal bromide, a metal chloride, and mixtures thereof, wherein this metal is a trivalent metal, a divalent metal, a monovalent metal, and mixtures thereof. In addition, any of the glass compositions described herein may contain up to 15 mole % B2O3 substituted for an equivalent amount of Sb2O3.Type: GrantFiled: February 4, 2000Date of Patent: January 7, 2003Assignee: Corning IncorporatedInventors: James E. Dickinson, Adam J. G. Ellison, Alexandre M. Mayolet, Michel Prassas
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Patent number: 6444598Abstract: An insulator composition which can be sintered at a relatively low temperature and which exhibits a low dielectric constant and a thermal expansion coefficient suitable for forming an insulator layer of a laminated electronic part contains a crystallized glass composition containing SiO2, MgO and CaO as main components, and Al2O3, an amorphous silicate glass composition, and a ceramic composition. The composition ratio by weight % (SiO2, MgO, CaO) of the main components of the crystallized glass composition lies in a region surrounded by point A (30, 25, 45), point B (30, 5, 65), point C (45, 5, 50) and point D (45, 25, 30) shown in a ternary composition diagram thereof. The thermal expansion coefficient of the insulator composition after sintering can easily be changed by changing the content ratio of the crystallized glass composition, the amorphous silicate glass composition and the ceramic composition.Type: GrantFiled: September 6, 2000Date of Patent: September 3, 2002Assignee: Murata Manufacturing Co. LtdInventors: Hiromichi Kawakami, Toshiki Tanaka
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Patent number: 6429577Abstract: A discharge lamp comprising an arc tube containing a pair of electrodes in a light-emitting portion and an outer tube that envelops the light-emitting portion and is at least partly fused to the arc tube, wherein the outer tube comprises silicon dioxide in the range from 90 to 99.88 wt. % and boron in the range from 0.12 wt. % or more. The discharge lamp can inhibit the arc tube from deforming when the outer tube and arc tube are fused to each other by adjusting a softening temperature of the outer tube to an appropriate temperature and can realize a high accuracy of luminous intensity distribution.Type: GrantFiled: June 7, 1999Date of Patent: August 6, 2002Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hideaki Kiryu, Kazuhisa Tanaka, Takeshi Saitoh
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Patent number: 6420290Abstract: The object of the present invention is colorless inorganic glasses, as well as products manufactured from said glasses. Said glasses are of the type containing copper halides or copper cadmium halides and having a sharp optical absorption cutoff between 370 nm and 425 nm essentially having the composition below, expressed in cationic percentages: 23-73% SiO2 15-45% B2O3 0-24% Al2O3 0-12% Li2O 0-20% Na2O 0-12% K2O 0-5% CaO + BaO + SrO 0.125-1% Cu2O 0-1% CdO 0-5% ZrO2 with 0-1.75% Cl 0.Type: GrantFiled: February 11, 2000Date of Patent: July 16, 2002Assignee: Corning S.A.Inventors: Yves A. H. Brocheton, Christophe Remy
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Patent number: 6410467Abstract: A glass consisting essentially of antimony oxide. An optically active glass consisting essentially of antimony oxide and up to about 4 mole % of an oxide of a rare earth element. A rare earth-doped, antimony oxide-containing glass including 0-99 mole % SiO2, 0-99 mole % GeO2, 0-75 mole % (Al, Ga)2O3, 0.5-99 mole % Sb2O3, and up to about 4 mole % of an oxide of a rare earth element. The oxide of the rare earth element may comprise Er2O3. The glass of the invention further includes fluorine, expressed as a metal fluoride. An optical energy-producing or light-amplifying device, in particular, an optical amplifier, comprising the above-described glass. The optical amplifier can be either a fiber amplifier or a planar amplifier, either of which may have a hybrid composition. Embodiments of the glass of the invention can be formed by conventional glass making techniques, while some of the high content antimony oxide embodiments are formed by splat or roller quenching.Type: GrantFiled: April 8, 1999Date of Patent: June 25, 2002Assignee: Corning IncorporatedInventors: James E. Dickinson, Adam J G Ellison, Alexandre M. Mayolet, Michel Prassas
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Patent number: 6403509Abstract: A high LTa, low UV and IR transmittance grey glass employing as its colorant portion iron (Fe2O3/FeO), erbium (Er2O3) and, optionally, titanium (TiO2). Enhanced effects are achieved by forming separate prebatch mixes, one of which includes rouge, metallic Si (optional), SiO and sand, the other including the remainder of ingredients, which after separate formation are then admixed to form the final, overall batch.Type: GrantFiled: February 23, 2001Date of Patent: June 11, 2002Assignee: Guardian Industries Corp.Inventors: Gary Seldon Cochran, Anthony Vincent Longobardo, Ksenia Alexander Landa, Leonid Mendel Landa
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Publication number: 20020065187Abstract: The subject of the invention is a glass sheet intended to be thermally toughened, the matrix of which is of the silica-soda-lime type, having an expansion coefficient &agr; of greater than 100×10−7 K−1, a Young's modulus E of greater than 60 GPa and a thermal conductivity k of less than 0.9 W/m.K.Type: ApplicationFiled: November 26, 2001Publication date: May 30, 2002Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Frederic Bordeaux, Lucas Duffrene
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Publication number: 20020065186Abstract: A compositional range for a mother glass composition for graded index lenses which has a desired refractive index and is less apt to be devitrified and to develop cracks upon ion exchange was obtained by incorporating at least a given amount of one or more ingredients which are selected from oxides of metal elements ranging from yttrium, atomic number 39, to tantalum, atomic number 73, and which are less apt to cause glass coloration into a glass based on SiO2-TiO2-Li2O-Na2O and containing no lead oxide. In particular, a compositional range in which a large angular aperture is obtained and devitrification is less apt to occur was obtained by incorporating Ta2O5 and ZrO2 in a specific proportion and in specific amounts.Type: ApplicationFiled: October 11, 2001Publication date: May 30, 2002Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Tetsuro Yoshii, Jun Yamaguchi
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Patent number: 6395659Abstract: The ultraviolet/infrared transmittance glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % B2O3; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % total amount of MgO and CaO; and 0 to 20 wt. % total amount of Na2O and K2O, colorants including: equal to or more than 0.05 wt. % and less than 0.2 wt. % total iron oxide (T—Fe2O3) expressed as Fe2O3; 0.63 to 1.4 wt. % CeO2; 0.02 to 1.5 wt. % TiO2; 0.0005 to 0.005 wt. % CoO; and 0.0003 to 0.002 wt. % Se. FeO expressed as Fe2O3 is between 30 wt. % and 60 wt. % of T—Fe2O3.Type: GrantFiled: June 7, 2001Date of Patent: May 28, 2002Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Koichi Sakaguchi, Shigeki Nakagaki
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Patent number: 6372155Abstract: The object of the present invention is to provide an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by &ggr;-rays, X-rays, UV-rays, etc. and light emission can be continued for a long time even after stopping the excitation. That is, the present invention relates to an oxide glass capable of exhibiting a long lasting afterglow and photostimulated luminescence, characterized by a constitutional composition comprising, at least, terbium oxide (Tb2O3) or manganese oxide (MnO), gallium oxide (Ga2O3) or aluminum oxide (Al2O3), alkali metal oxide or alkaline earth metal oxide and boron oxide (B2O3) or silicon oxide (SiO2) or zinc oxide (ZnO).Type: GrantFiled: November 30, 1999Date of Patent: April 16, 2002Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 6365265Abstract: A photosensitive insulating paste including an insulating material containing a borosilicate glass powder. The insulating material is dispersed in a photosensitive organic vehicle, and the borosilicate glass powder contains SiO2, B2O3 and K2O such that the compositional proportions by weight of the three components represented by (SiO2, B2O3, K2O) fall within a region formed by connecting points A (65, 35, 0), B (65, 25, 10), C (85, 5, 10) and D (85, 15, 0) in a ternary diagram thereof. A thick-film multi-layer circuit substrate including the paste is also disclosed.Type: GrantFiled: January 3, 2000Date of Patent: April 2, 2002Assignee: Murata Manufacturing Co., Ltd.Inventors: Makoto Tose, Hiromichi Kawakami, Shizuharu Watanabe, Michiaki Iha
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Patent number: 6346493Abstract: The present invention provides a new and improved lead-free and cadmium-free glass enamel composition that displays good flow at traditional glass enamel firing temperatures and upon firing produces an enamel finish that displays no cracking, good chemical resistance, good weatherability, and improved color values. The glass enamel composition of the present invention includes a glass component, an oxidizer, a pigment system, and optional vehicles and fillers. The presence of the oxidizer in the composition, which can be included as part of the glass component, as a separately added material, or both, improves the color values of the fired enamel as compared to enamels formed using similar glass enamel compositions having no oxidizer present.Type: GrantFiled: October 27, 1999Date of Patent: February 12, 2002Assignee: Ferro CorporationInventors: Galina Kniajer, Jeffrey David Cosby, Ivan H. Joyce, Srinivasan Sridharan, John J. Maloney
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Publication number: 20020010065Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 4OO ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: ApplicationFiled: June 1, 2001Publication date: January 24, 2002Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 6326324Abstract: An ultraviolet and infrared radiation absorbing glass is disclosed, which has a bronze or neutral gray tint, a low ultraviolet transmission, and a low total solar energy transmission and is suitable for use as a window glass for motor vehicles or buildings. The glass comprises, in % by weight: basic glass components comprising 65 to 80% SiO2, 0 to 5% B2O3, 0 to 5% Al2O3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na2O, and 0 to 5% K2O, provided that the sum of MgO and CaO is 5 to 15% and the sum of Na2O and K2O is 10 to 20%; coloring components comprising 0.20 to 0.30% total iron oxide (T-Fe2O3) in terms of Fe2O3, 0.65 to 1.1% CeO2, 0.35 to 1.1% TiO2, 0.001 to 0.005% CoO, and 0.0003 to 0.0015% Se; and an additional component comprising 0.02 to 0.30% SO3, wherein 20.5 to 25% of said T-Fe2O3 is FeO in terms of Fe2O3.Type: GrantFiled: January 3, 2000Date of Patent: December 4, 2001Assignee: Nippon Sheet Glass Company, LimitedInventors: Koichi Sakaguchi, Shigeki Nakagaki
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Patent number: 6316374Abstract: A dielectric ceramic composition which can be sintered at low temperature and has a low dielectric constant, high Q value, and favorable temperature-dependent characteristic of capacitance (TCC) in the high-frequency region, can be used in a ceramic electronic element. The dielectric ceramic composition comprises glass and at least one of an Si—Mg—Al—O ceramic and TiO2. Preferably, the compositional proportions of the three components based on wt. % represented by (glass, Si—Mg—Al—O ceramic, TiO2) fall within a polygon formed by connecting points A(100, 0, 0), B(30, 70, 0), and C(30, 0, 70) in the ternary diagram of the three components.Type: GrantFiled: February 26, 1999Date of Patent: November 13, 2001Assignee: Murata Manufacturing Co., Ltd.Inventor: Hiromichi Kawakami
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Patent number: 6306785Abstract: A living tissue replacement of crystallized glass having bioaffinity and mechanical strength is briefly obtained simply by pressure molding or machining without using a special equipment. A glass material having a softening point below its crystallization temperature and exhibiting viscous flow at temperatures below its melting point is heated at a temperature above its Tg and pressed at the temperature to mold to a desired shape, thereby manufacturing a living tissue replacement such as a dental crown. Molding can be done under a pressure of up to 20 MPa.Type: GrantFiled: March 10, 1999Date of Patent: October 23, 2001Assignee: TDK CorporationInventors: Toru Nonami, Tatsuji Sano, Sadami Tsutsumi, Tetsuo Urabe, Masahiro Fukuma
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Publication number: 20010029753Abstract: The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods.Type: ApplicationFiled: May 8, 2001Publication date: October 18, 2001Inventors: Carol M. Jantzen, John B. Pickett, Connie A. Cicero-Herman, James C. Marra
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Patent number: 6271160Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of &ggr;-rays, X-rays or UV-rays images and further can be used as an optical recording material of such a type that can be read. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %): GeO2 21 to 80% ZnO 0 to 50% Ga2O2 0 to 55% (ZnO + Ga2O3 = 3 to 55%) Tb2O3 0 to 10% MnO 0 to 2% (Tb2O3 + MnO = 0.01 to 10%) R2O 0 to 45% (R: at least one atom selected from Li, Na, K and Cs) R′O 0 to 40% (R′: at least one atom selected from Mg, Ca, Sr and Ba) R2O + R′O 0.Type: GrantFiled: May 12, 1999Date of Patent: August 7, 2001Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Masaaki Yamazaki, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 6268304Abstract: A plate glass containing B2O3, having a total content of Li2O, Na2O and K2O of from 0 to 13 mol %, a content of BaO of from 0 to 0.8 mol % and a content of SiO2 of from 50 to 75 mol %, and having an average linear thermal expansion coefficient of from 75×10−7 to 120×10−7/° C. in a range of from 50 to 350° C., a strain point of at least 550° C., a density of at most 2.65 g/cm3 at 20° C. and an oxygen atom density of from 7.2×10−2 to 9.0×10−2 mol/cm3 at 20° C.Type: GrantFiled: April 28, 1999Date of Patent: July 31, 2001Assignee: Asahi Glass Company Ltd.Inventors: Kei Maeda, Seiki Ohara, Yasumasa Nakao
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Patent number: 6255598Abstract: A primarily polycrystalline but partially amorphous electrical insulator can hermetically seal first and second spaced electrical terminals, one made from an anodized aluminum and the second made from a beryllium copper or Kovar or an alloy of beryllium, copper, nickel and gold. Nickel may be diffused into the beryllium copper and a noble metal may be deposited on the nickel. The insulator provides a flat meniscus to abut a corresponding electrical insulator in a cable. The insulator may provide an electrical impedance of approximately 50 ohms, an electrical resistivity greater than approximately 1018 ohms and a dielectric constant of approximately 6.3. The insulator operates satisfactorily in a frequency range to approximately 40 gigahertz.Type: GrantFiled: July 15, 1999Date of Patent: July 3, 2001Inventor: James C. Kyle
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Patent number: 6255238Abstract: The object of the present invention is brown solar glasses, absorbing UV or IR radiation, as well as solar ophthalmic lenses in said glasses. Said glasses have the following composition, expressed in percentages by weight: SiO2: 64-71; B2O3: 2-8; Al2O3: 0-4; ZrO2: 0-2; Li2O: 0-4; Na2O: 6-10; K2O: 7-16; CaO: 0-5.5; ZnO: 0-5.5; TiO2; 0-2; Fe2O3: 3-9; Co3O4: 0-0.030; NiO: 0-0.2; SeO2: 0.0030-0.1; As2O3: 0-0.1; Sb2O3: 0-0.1; SnO2: 0-0.1; Cl: 0-2; Br: 0-2; F: 0-2.Type: GrantFiled: February 7, 2000Date of Patent: July 3, 2001Assignee: Corning S.A.Inventor: Yves A. H. Brocheton
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Publication number: 20010004138Abstract: The present invention relates to a molding composition based on sinterable materials, comprisingType: ApplicationFiled: December 15, 2000Publication date: June 21, 2001Applicant: Clariant GmbHInventor: DI. Michael Bayer
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Patent number: 6245733Abstract: A pre-glass agglomeration fragrance delivery system comprising fused microspheres and a fragrance incorporated therein. The pre-glass agglomeration has an extended fragrance release time exceeding a year and a half, and uses microcapillary action to quickly uptake oils and alcohols. The pre-glass agglomeration provides a slow release of fragrance without the escape of any residual liquid. The pre-glass agglomeration may be replenished, an unlimited number of times, with fragrance containing oils and alcohols after the odor fades. The pre-glass agglomerations can be molded and may be colored or dyed.Type: GrantFiled: April 30, 1999Date of Patent: June 12, 2001Inventor: James Mosbaugh
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Patent number: 6235666Abstract: A high LTa, low UV and IR transmittance grey glass employing as its colorant portion iron (Fe2O3/FeO), erbium (Er2O3) and, optionally, titanium (TiO2). Enhanced effects are achieved by forming separate prebatch mixes, one of which includes rouge, metallic Si (optional), SiO and sand, the other including the remainder of ingredients, which after separate formation are then admixed to form the final, overall batch.Type: GrantFiled: March 29, 1999Date of Patent: May 22, 2001Assignee: Guardian Industries CorporationInventors: Gary Seldon Cochran, Anthony Vincent Longobardo, Ksenia Alexander Landa, Leonid Mendel Landa
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Patent number: 6207905Abstract: In the glass-ceramic composition, a weight ratio of a glass and a ceramic is 40 to 60:60 to 40. The glass is composed of 40 to 60 wt % of SiO2, 5 to 9 wt % of Al2O3, 1 to 10 wt % of B2O3, 3 to 5 wt % of Na2O+K2O, 3 to 15 wt % of CaO+MgO+ZnO, and 15 to 40 wt % of PbO, and does not contain Li2O. A softening point of the glass is 650 to 780° C. The circuit substrate includes a laminate substrate formed by laminating insulating substrates, and a conductor circuit formed on a surface of each insulating substrate. The insulating substrate is formed of the glass-ceramic composition. A wiring layer and a via hole conductor are provided inside the laminate substrate.Type: GrantFiled: August 2, 1999Date of Patent: March 27, 2001Assignee: NGK Spark Plug Co., Ltd.Inventors: Shigeru Taga, Hiroyuki Takahashi, Yoshitaka Yoshida
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Patent number: 6184166Abstract: This invention relates to lead-free silicate glasses that find use in producing fine crystal glassware and in laminated ware applications. The glasses consist essentially, in weight percent, of: SiO2 52-66 ZnO 15-30 Al2O3 0-4 BaO 0-7 Li2O 0-4 MgO + CaO + SrO 0-4 Na2O 3-16 ZrO2 0-4 K2O 0-12 B2O3 0-4.Type: GrantFiled: July 16, 1999Date of Patent: February 6, 2001Assignee: Corning IncorporatedInventors: George B. Hares, Jeffrey T. Kohli, James E. Webb
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Patent number: 6180218Abstract: Radiation stable glass for space applications, especially glass in the form of thin sheet for cladding of spacecraft, is produced by including at least 5% by weight of barium oxide in a borosilicate glass composition. Because barium has a low absorption in the ultra violet, its use enables radiation stable glasses of low ultra violet absorption to be produced, alleviating problems of overheating when the glasses are used for cladding space craft. The glass is useful in the production of solar cell cover slips and second surface mirrors for cladding purposes, and space applications generally.Type: GrantFiled: January 26, 1999Date of Patent: January 30, 2001Assignee: Pilkington PLCInventors: Kenneth Melvin Fyles, Helen Louise Eaves, Peter Shorrock
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Patent number: 6165923Abstract: The present invention provides a coating layer of the coke oven having a high strength, high impact resistance and excellent smoothness to enable long term protection of the fire brick of the coke oven. Carbon adhered to the brick can be removed by spraying a coating agent with a glaze layer mainly composed of 18 to 70% by weight of SiO.sub.2 and 10 to 60% by weight of Na.sub.2 O and/or K.sub.2 O and containing one or a plurality of 2 to 14% by weight of P.sub.2 O.sub.5, 0.5 to 25% by weight of BaO, 0.5 to 25% by weight of SrO and 0.5 to 20% by weight of Fe.sub.2 O.sub.3 onto the surface of a high temperature firebrick, thereby obtaining an excellent coating layer.Type: GrantFiled: September 8, 1998Date of Patent: December 26, 2000Assignees: Kawasaki Steel Corporation, Taiho Industries Co., Ltd.Inventors: Takeshi Ando, Shizuki Kasaoka, Teruo Onozawa, Shigeru Nakai
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Patent number: 6123872Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by .gamma.-rays, X-rays, UV-rays, etc., light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for night illumination or night signal, but also as a material for confirming an infrared laser or controlling an optical axis because of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing of .gamma.-rays, X-rays or UV-rays images. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 1 to 55% B.sub.2 O.sub.3 1 to 50% (SiO.sub.2 + B.sub.2 O.Type: GrantFiled: December 16, 1998Date of Patent: September 26, 2000Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 6096432Abstract: Growth of scale on the wall surfaces of high-temperature furnaces is prevented, or the damaged portions are repaired. In addition, the inner wall surfaces of furnaces such as coke furnaces and carbon-firing furnaces, and attachments to furnaces (furnace lids and gas pipes) are protected from deposition of carbon.Glazing layers are formed by application to the refractory surfaces of furnaces of a glazing agent which comprises as a glaze, on an oxide basis, 0-10% by weight of Li.sub.2 O, 0-10% by weight of B.sub.2 O.sub.3, 10-40% by weight of R.sub.2 O (R represents Na or K) and SiO.sub.2 as the balance, wherein the glaze has a melting point of 900.degree. C. or below.Type: GrantFiled: November 15, 1996Date of Patent: August 1, 2000Assignee: Asahi Chemical Company, LimitedInventors: Seiichi Sakaguchi, Mitsutoshi Murase
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Patent number: 6017835Abstract: Compositions for producing irregularly-shaped dual-glass fibers include a first glass composition and a second glass composition, the first and second glass compositions having nonidentical coefficients of thermal expansion, the difference between the coefficients of thermal expansion being greater than about 2.0 ppm/.degree. C.Type: GrantFiled: November 5, 1993Date of Patent: January 25, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventor: Russell M. Potter
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Patent number: 6004894Abstract: The present invention provides a porcelain enamel coating composition for use in forming a coating composition upon a metal substrate having an infrared reflectivity of at least 50% at 2.5 .mu.-microns measured with a Perkin Elmer Lambda 19 UV/VIS/NIR spectrometer with a labsphere RSA-PE 19 reflectance spectroscopy accessory. The coating composition comprises a glass component and a separate and distinct addition of cerium oxide. Preferably, the coating composition comprises from about 0.20% to about 3.0% by weight of the cerium oxide.Type: GrantFiled: October 28, 1998Date of Patent: December 21, 1999Assignee: Ferro CorporationInventors: William D. Faust, Holger F. Evele
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Patent number: 5998314Abstract: Disclosed are a low-temperature sinterable ceramic composition comprising 100 parts by weight of an essential component composed of from about 60 to 85% by weight of cordierite and from about 15 to 40% by weight of glass, and not larger than about 25 parts by weight of TiO.sub.2, and a monolithic ceramic substrate comprising the composition. The composition can be sintered at relatively low temperatures, and the sintered substrate has a small thermal expansion coefficient and a small dielectric constant. The temperature-dependent variation in the electrostatic capacity of the substrate is small. Preferably, the glass component in the composition is composed of about 20 to 60% by weight of SiO.sub.2, about 30 to 50% by weight of B.sub.2 O.sub.3, about 5 to 30% by weight of MgO, 0 to about 15% by weight of Al.sub.2 O.sub.3, and about 1 to 5% by weight of R.sub.2 O in which R is an alkali metal.Type: GrantFiled: March 3, 1998Date of Patent: December 7, 1999Assignee: Murata Manufacturing Co., Ltd.Inventor: Yasutaka Sugimoto
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Patent number: 5994248Abstract: The invention relates to lenses such as aspherical lenses and to a process for their manufacture. According to the invention, the lens is composed of a glass matrix including the constituents below in the following weight proportions:______________________________________ SiO.sub.2 65-85% Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3 0-20% Li.sub.2 O + Na.sub.2 O + K.sub.2 O 3-20% CaO + MgO + BaO 1-15% FeO + Fe.sub.2 O.sub.3 0-0.1%, ______________________________________wherein the K.sub.2 O content is equal to or less than 1% and the BaO content is equal to or less than 1%.Type: GrantFiled: November 6, 1997Date of Patent: November 30, 1999Assignee: Saint-Gobain VitrageInventors: Jose Francisco Gandarillas-Lastra, Benoit Trouille
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Patent number: 5968858Abstract: An insulating paste comprises a glass component composed of SiO.sub.2, B.sub.2 O.sub.3 and K.sub.2 O as xSiO.sub.2 -yB.sub.2 O.sub.3 -zK.sub.2 O, where x, y and z (% by weight) fall within the area surrounded by points A (x=65, y=35, z=0), B (x=65, y=20, z=15), C (x=85, y=0, z=15) and D (x=85, y=15, z=0), and an organic vehicle. The insulating layer made of the paste has a low dielectric constant and excellent insulating properties.Type: GrantFiled: October 22, 1997Date of Patent: October 19, 1999Assignee: Murata Manufacturing Co., Ltd.Inventors: Hiromichi Kawakami, Hiroji Tani
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Patent number: 5961883Abstract: A glass material is provided which is capable of exhibiting fluorescence in the visible region by ultraviolet ray excitation. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 2 to 60%, B.sub.2 O.sub.3 5 to 70% (SiO.sub.2 + B.sub.2 O.sub.3 = 50 to 70%) RO 5 to 30% (R: at least one atom selected from Mg, Ca, Sr and Ba) ZnO 0 to 15% ZrO.sub.2 0 to 10%, Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3 2 to 15% (containing either of Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3) Ln.sub.2 O.sub.3 0 to 20% (Ln: at least one atom selected from Y, La, Gd, Yb, Lu, Sm, Dy and Tm) CeO.sub.2 0 to 1% Bi.sub.2 O.sub.3 0 to 2% Sb.sub.2 O.sub.3 0.01 to 0.5% and R'.sub.Type: GrantFiled: December 11, 1997Date of Patent: October 5, 1999Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Masaaki Otsuka, Hideaki Takaku, Naruhito Sawanobori
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Patent number: 5952256Abstract: An optical glass has a large negative anomalous dispersion value and optical constants of refractive index (nd) within a range of 1.65-1.80 and Abbe number (.nu.d) within a range of 28-42. The optical glass includes, as its essential ingredients, in weight percent, 20-50% SiO.sub.2, 6-20% B.sub.2 O.sub.3 where SiO.sub.2 /B.sub.2 O.sub.3 .ltoreq.6, 0.5-15% ZrO.sub.2 and 31-50% Nb.sub.2 O.sub.5.Type: GrantFiled: March 12, 1998Date of Patent: September 14, 1999Assignee: Kabushiki Kaisha OharaInventors: Michiko Morishita, Masahiro Onozawa
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Patent number: 5932501Abstract: The invention relates to glasses which absorb UV radiation and which have the following composition, in wt. %: SiO.sub.2 30-52; ZnO 0-8; B.sub.2 O.sub.3 12-22; PbO 0-2; ZrO.sub.2 5-14; Y.sub.2 O.sub.3 0-15; Al.sub.2 O.sub.3 0-12; La.sub.2 O.sub.3 5-25; Li.sub.2 O 1.5-3.5; TiO.sub.2 0-2; Na.sub.2 O 0-6; HfO.sub.2 0-2; K.sub.2 O 2-9; Nb.sub.2 O.sub.5 0-2; MgO 0-5; Ta.sub.2 O.sub.5 0-2; CaO 0-5; MoO.sub.3 0-2; SrO 0-9; WO.sub.3 0-2; BaO 0-14; SnO 0-4; Sb.sub.2 O.sub.3 0-4; SnO.sub.2 0-4; AS.sub.2 O.sub.3 0-4; CdO 0-1; CuO 0.15-1; F 0-2; Cl 0-3; Br 0-3; I 0-2 with the following conditions: Li.sub.2 O+Na.sub.2 O+K.sub.2 O (X.sub.2 O) 7-14; MgO+CaO+SrO+BaO (XO) 12-20; ZrO.sub.2 +Al.sub.2 O.sub.3 <15; F+Cl+Br+I 0.2-4.0; TiO.sub.2 +PbO+Nb.sub.2 O.sub.5 .ltoreq.2; AS.sub.2 O.sub.3 +Sb.sub.2 O.sub.3 +SnO.sub.2 +SnO 0.05-4.0 and a ratio R=(M.sub.2 O+2MO-Al.sub.2 O.sub.3 -ZrO.sub.2)/B.sub.2 O.sub.3 where M.sub.Type: GrantFiled: February 2, 1998Date of Patent: August 3, 1999Assignee: Corning IncorporatedInventor: Yves A. H. Brocheton
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Patent number: 5910707Abstract: A glass halogen lamp which exhibits improved short wavelength light transmission and emission having a glass envelope which is made of a glass composition of the aluminosilicate system in which the iron content of the composition is between 10 and 100 ppm. The glass envelope of the lamp may optionally contain an area of reduced wall thickness which further enhances short wavelength light transmission and emission.Type: GrantFiled: June 25, 1997Date of Patent: June 8, 1999Assignee: Welch Allyn, Inc.Inventor: Dean A. Bell
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Patent number: 5910461Abstract: The present invention relates to glass fibers, especially for reinforcing organic materials and having an alumino-silicate glass composition, containing one or more alkaline earth metal compounds and with a low content of alkali metal compounds, wherein the composition further contains a combination of coloring agents formed from iron oxides, cobalt oxide and, optionally, chromium oxide, which enable the fibers to be dyed in bulk and to have more neutral tones.Type: GrantFiled: November 28, 1997Date of Patent: June 8, 1999Assignee: Vetrotex FranceInventors: Jean-Philippe Gasca, Michel Arpin, Denis Malgrange, Daniel Caurant
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Patent number: 5902758Abstract: A low temperature firing glass-ceramic substrate comprising a borosilicate glass, .alpha.-alumina, .gamma.-alumina, and mullite crystals crystallized out in a dispersed form from the borosilicate glass and the .gamma.-alumina, and a production process of the substrate. It is an object of this invention to provide a glass-ceramic substrate, which is low in dielectric constant and dielectric loss and high in strength and is useful for multilayer wiring.Type: GrantFiled: March 12, 1998Date of Patent: May 11, 1999Assignee: Nec CorporationInventors: Ichiro Hazeyama, Kazuhiro Ikuina
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Patent number: 5900380Abstract: A conductive glass lining composition includes 100 parts by weight of a frit and 0.05 to 1.5 parts by weight of a metal fibers of 0.1 to 30 .mu.m in diameter, 1.5 to 10 mm in length and a length-to-diameter ratio of not less than 50.Type: GrantFiled: July 15, 1997Date of Patent: May 4, 1999Assignee: Ikebukuro Horo Kogyo Co., Ltd.Inventors: Yoshihiro Iizawa, Mitsuru Akazawa
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Patent number: 5897678Abstract: The invention provides a method by which a crystal glass composition which employs TiO.sub.2 as a raw material substituted for PbO can be produced while effectively preventing development of a yellowish color of the glass composition which is caused by TiO.sub.2. In the production method, to a batch composition which is composed of 50 to 60 percent by weight of SiO.sub.2, 4 to 14 percent by weight of K.sub.2 O, 10 to 20 percent by weight of BaO and 3 to 10 percent by weight of TiO.sub.2, NaNO.sub.3 (sodium nitrate) is added by 1.0 to 5.0 percent by weight or BaO.sub.2 (barium peroxide) is added by 0.3 to 2.0 percent by weight for elimination of development of a color which arises from the 3 to 10 percent by weight of TiO.sub.2, and also one of Sb.sub.2 O.sub.3 (antimony oxide) and As.sub.2 O.sub.3 (arsenious acid) is added by 0.2 to 1.0 percent by weight for defoaming. Instead, NaSb(OH).sub.6 (sodium antimonate) having color development elimination and defoaming actions may be added by 0.5 to 2.Type: GrantFiled: July 23, 1997Date of Patent: April 27, 1999Assignee: Toyo Glass Company LimitedInventors: Hidetoshi Komiya, Shizue Inaba
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Patent number: 5895719Abstract: Radiation stable glass for space applications, especially glass in the form of thin sheet for cladding of spacecraft, is produced by including at least 5% by weight of barium oxide in a borosilicate glass composition. Because barium has a low absorption in the ultra violet, its use enables radiation stable glasses of low ultra violet absorption to be produced, alleviating problems of overheating when the glasses are used for cladding space craft. The glass is useful in the production of solar cell cover slips and second surface mirrors for cladding purposes, and space applications generally.Type: GrantFiled: December 5, 1996Date of Patent: April 20, 1999Assignee: Pilkington plcInventors: Kenneth Melvin Fyles, Helen Louise Eaves, Peter Shorrock
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Patent number: 5876472Abstract: The invention is directed to a method of producing a chemically pretensioned glass body. In the method, a glass body is provided having a composition in percent by weight on oxide basis: SiO.sub.2 70-85; B.sub.2 O.sub.3 8-15; Na.sub.2 O 1-5; K.sub.2 O 1-<5; Al.sub.2 O.sub.3 1-5; MgO 0-3; SrO+BaO 0-2; CaO 0-3; ZnO 0-3; with CaO+ZnO 2-6; and, ZrO.sub.2 0-3.5. The glass body is placed in an ion exchange salt bath containing at least 90% by weight of potassium salts. The salt bath is maintained at a temperature below the transformation point Tg of the glass defined by the glass composition for a duration of at least 2.0 hr causing potassium ions from the salt bath to migrate into the surface region of the glass body to thereby produce the chemically pretensioned glass body.Type: GrantFiled: October 27, 1997Date of Patent: March 2, 1999Assignee: Schott GlaswerkeInventors: Oliver Gros, Sabine Melson, Roland Leroux, Otmar Becker, Dietrich Busch
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Patent number: 5866851Abstract: A hermetically sealed implantable medical device is provided with a multi-pin arrangement including selected glass to metal or ceramic to metal seals for a feedthrough of the compression seal or matched seal type.Type: GrantFiled: July 28, 1997Date of Patent: February 2, 1999Assignee: Medtronic Inc.Inventors: William J. Taylor, Lynn M. Seifried, Douglas Weiss, Joseph F. Lessar
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Patent number: 5849068Abstract: A shaped, high-strength dental ceramic prosthesis is made by pressing a molding composition including from about 1 to 50 percent by weight glass particles and from about 99 to about 50 percent by weight inorganic oxide particles at a pressure of from about 10 to about 40 MPa and a temperature of from about 1000.degree. to about 1200.degree. C. Dental prostheses prepared in accordance with the invention include crowns, bridges, inlays and onlays.Type: GrantFiled: May 1, 1997Date of Patent: December 15, 1998Assignee: Dentsply G.m.b.H.Inventors: Carmen Hofmann, geb. Roth, Ludwig J. Gauckler, Gerhard Bayer, Martin E. Hofmann, Atef Malash, Peter Scharer, Heinz Luthy, Klaus Krumbholz, Wigbert Hauner, Hansjorg Janssen, Ralf Janda
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Patent number: 5843855Abstract: The invention is a glass for electric lamps comprising SiO.sub.2, A1.sub.2 O.sub.3, Na.sub.2 O, K.sub.2 O, Li.sub.2 O, BaO, MgO, CaO, ZnO, B.sub.2 O.sub.3, TiO.sub.2, SbO.sub.3, MnO.sub.2 and one or more of the following Fe.sub.2 O.sub.3, As.sub.2 O.sub.3 and CeO.sub.2, whereZnO is 3 to 7 weight %,B.sub.2 O.sub.3 is 3 to 8 weight %,TiO.sub.2 is 0 to 1.5 weight %,Al.sub.2 O.sub.3 is 0.3 to 2.5 weight %,BaO is 1 to 4.5 weight %,CaO is 2 to 4.5 weight %,MgO is 0.5 to 3.7 weight %, andthe sum of ZnO and B.sub.2 O.sub.3 is equal to at least 8.6 weight % to provide stability of the glass.Type: GrantFiled: January 15, 1997Date of Patent: December 1, 1998Assignee: General Electric CompanyInventors: Zoltan Suha, Zsuzsanna Varga
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Patent number: 5843856Abstract: The invention relates to a glass composition for electric lamps which glass composition comprises SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O, K.sub.2 O and B.sub.2 O.sub.3 as well as optionally Li.sub.2 O, CaO, MgO, SrO, Sb.sub.2 O.sub.3, Fe.sub.2 O.sub.3, MnO.sub.2 and/or CeO.sub.2. The composition according to the invention is characterized in that it, in addition to the components listed, comprises ZnO and optionally TiO.sub.2 and/or P.sub.2 O.sub.5 as well, its Al.sub.2 O.sub.3 content is 0.3 to 2 mass %, ZnO content is 2.5 to 8 mass %, B.sub.2 O.sub.3 content is 1.5 to 7.5 mass % and the total amount of Al.sub.2 O.sub.3 and TiO.sub.2 is at least 1 mass %, while the total amount of MgO and ZnO is equal to or greater than the amount of B.sub.2 O.sub.3. The invention also relates to stems and bulbs made of the glass composition according to the invention.Type: GrantFiled: January 15, 1997Date of Patent: December 1, 1998Assignee: General Electric CompanyInventors: Zoltan Suha, Zsuzsanna Varga