And Divalent Metal Oxide (e.g., Oxides Of Zinc, Cadmium, Beryllium, Alkaline Earth Metal, Magnesium, Etc.) Patents (Class 501/72)
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Patent number: 6255238Abstract: The object of the present invention is brown solar glasses, absorbing UV or IR radiation, as well as solar ophthalmic lenses in said glasses. Said glasses have the following composition, expressed in percentages by weight: SiO2: 64-71; B2O3: 2-8; Al2O3: 0-4; ZrO2: 0-2; Li2O: 0-4; Na2O: 6-10; K2O: 7-16; CaO: 0-5.5; ZnO: 0-5.5; TiO2; 0-2; Fe2O3: 3-9; Co3O4: 0-0.030; NiO: 0-0.2; SeO2: 0.0030-0.1; As2O3: 0-0.1; Sb2O3: 0-0.1; SnO2: 0-0.1; Cl: 0-2; Br: 0-2; F: 0-2.Type: GrantFiled: February 7, 2000Date of Patent: July 3, 2001Assignee: Corning S.A.Inventor: Yves A. H. Brocheton
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Patent number: 6251812Abstract: A glass composition is disclosed which has a high modulus of elasticity (Young's modulus) and a high rigidity (modulus of elasticity/specific gravity) and is capable of being effectively inhibited from bending or vibrating. Also disclosed is a substrate for information recording media, which comprises the glass composition. The glass composition comprises the following components in terms of mol %: 50 to 64% SiO2, 6 to 18% Al2O3, 7 to 15% Li2O, 3 to 12% Na2O, 0 to 2% K2O, 0 to 10% TiO2, 0 to 4% ZrO2, 0 to 6% MgO, 0 to 9% CaO, and 0 to 6% SrO, provided at the content of RO (RO=MgO+CaO+SrO) is from 2 to 15%.Type: GrantFiled: April 19, 1999Date of Patent: June 26, 2001Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Akihiro Koyama, Shoichi Kishimoto, Junji Kurachi, Nobuyuki Yamamoto
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Patent number: 6251811Abstract: A funnel glass containing PbO for a cathode ray tube, wherein when the composition is represented by wt % based on oxides, the content of SrO is at least 1.0 wt %, the content of BaO is at least 1.0 wt %, and the ratio of the content of PbO to the total amount of PbO, SrO, BaO, CaO and MgO, is at most 0.69, and whereby the lead elution A of the glass as measured by the following method A is at most 1.0 &mgr;g/cm2, and the X-ray absorption coefficient at a wavelength of 0.6 Å is at least 40 cm−1: Method A: The glass is immersed in distilled and deionized water at 90° C. for 20 hours, whereupon the glass is taken out, and the amount of lead in the distilled and deionized water is measured by inductively coupled plasma emission spectrometry, and the measured value of the amount of lead is divided by the surface area of the glass, and the product is taken as the lead elution A.Type: GrantFiled: June 30, 1999Date of Patent: June 26, 2001Assignee: Asahi Glass Company Ltd.Inventors: Osamu Yanagisawa, Yuichi Kuroki, Ryousuke Akagi
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Patent number: 6235667Abstract: A lead-free glass, which is suitable for use as imitation lead crystal tableware and decorative crystal glassware, has a chemical composition as a percentage by weight within the following range: silica 50-58 zirconium oxide 0-5 potash (K2O) 0-13, e.g. 0-12 yttrium oxide 0-5 soda (Na2O) 0-9 alumina 0-3 lithium oxide 0-4 tin oxide 0-5 calcium oxide 0-3 lanthanum oxide 0-9 magnesium oxide 0-4 niobium oxide 0-9 boric anhydride (B2O3) 0-2 bismuth oxide 0-13, e.g. 0-12 zinc oxide 16-30 germanium oxide 0-5 barium oxide 0-13, e.g. 0-12 antimony oxide 0-1 titanium oxide 0-6.Type: GrantFiled: June 8, 1999Date of Patent: May 22, 2001Assignee: CALP Cristalleria Artistica la Piana S.p.A.Inventors: Fabio Paloschi, Giancarlo Boschi
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Patent number: 6206958Abstract: Porcelain compositions of the present invention comprises particulate of one or more glass or glass-ceramic powder components. Additionally, one or more opacifing agents, pigments, fluorescing agents and the like may be included in the composition. Based on volume percent, the particulate has a d10 of from about 1.1 and about 1.8 microns; a d50 of from about 3 to about 6 microns; a d90 of from about 8 to about 16 microns; and about 1.0 to about 4.0% by volume of the particulate has a particle size greater than or equal to about 20 microns. The mean particle size is preferably in the range of about 3.0 microns to about 7.5 microns.Type: GrantFiled: July 15, 1999Date of Patent: March 27, 2001Assignee: Jeneric/Pentron, IncorporatedInventors: Paul Panzera, Jana N. Pruden, Dmitri Brodkin, Lisa M. Kaiser, Richard A. Brightly, Carlino Panzera
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Patent number: 6207603Abstract: A borosilicate glass having properties that enable it to be drawn as microsheets for use as a solar cell cover glass, and a solar cell having such microsheet as a cover glass, the glass having a composition consisting essentially of, expressed in terms of weight percent on an oxide basis: SiO2 59-69 ZnO 6.5-8.5 B2O3 8.5-14 CeO2 0.25-3 Al2O3 2-2.5 TiO2 0-1 Na2O 5.5-12.5 CeO2 + TiO2 0.5-4 K2O 0-8 Sb2O3 0-0.5.Type: GrantFiled: April 23, 1999Date of Patent: March 27, 2001Assignee: Corning IncorporatedInventors: Paul S. Danielson, Ronald L. Stewart
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Patent number: 6200137Abstract: An apatite glass ceramic is described which is characterized by good chemical stability, a low expansion coefficient and high translucence, and is particularly suitable, by itself or together with glasses or other glass ceramics, as a veneering material for ceramic dental restorations.Type: GrantFiled: June 12, 1998Date of Patent: March 13, 2001Assignee: Ivoclar AGInventors: Wolfram Höland, Martin Frank, Helga Drescher, Volker Rheinberger
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Patent number: 6197429Abstract: A glass-ceramic material which exhibits extremely low (e.g. less than 100 ppm) shrinkage, when exposed to 900° C. for 6 hours, and methods for making such glass-ceramics. The glass-ceramic is cerammed at a sufficiently high temperature and then cooling in a controlled manner, preferably to below the strain point of the resultant material. Using this technique, glass-ceramic materials were fabricated which exhibited dimensional shrinkage comparable to and in some cases even less than that achieved by fused silica substrates, when exposed to high temperature poly-Si processing temperatures (e.g. 900° C. for 6 hours).Type: GrantFiled: February 26, 1998Date of Patent: March 6, 2001Assignee: Corning IncorporatedInventors: Josef C. Lapp, Chad B. Moore, Linda R. Pinckney
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Patent number: 6184166Abstract: This invention relates to lead-free silicate glasses that find use in producing fine crystal glassware and in laminated ware applications. The glasses consist essentially, in weight percent, of: SiO2 52-66 ZnO 15-30 Al2O3 0-4 BaO 0-7 Li2O 0-4 MgO + CaO + SrO 0-4 Na2O 3-16 ZrO2 0-4 K2O 0-12 B2O3 0-4.Type: GrantFiled: July 16, 1999Date of Patent: February 6, 2001Assignee: Corning IncorporatedInventors: George B. Hares, Jeffrey T. Kohli, James E. Webb
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Patent number: 6180218Abstract: Radiation stable glass for space applications, especially glass in the form of thin sheet for cladding of spacecraft, is produced by including at least 5% by weight of barium oxide in a borosilicate glass composition. Because barium has a low absorption in the ultra violet, its use enables radiation stable glasses of low ultra violet absorption to be produced, alleviating problems of overheating when the glasses are used for cladding space craft. The glass is useful in the production of solar cell cover slips and second surface mirrors for cladding purposes, and space applications generally.Type: GrantFiled: January 26, 1999Date of Patent: January 30, 2001Assignee: Pilkington PLCInventors: Kenneth Melvin Fyles, Helen Louise Eaves, Peter Shorrock
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Patent number: 6177169Abstract: A glass including SiO2, Na2O, MgO, Al2O3 and cobalt oxide, wherein the cobalt oxide is 4.5-85 wt % as an oxide of CoO or 4.9-91 wt % as an oxide of Co3O4.Type: GrantFiled: November 3, 1999Date of Patent: January 23, 2001Assignee: Hitachi, Ltd.Inventors: Hiroki Yamamoto, Takashi Naito, Takashi Namekawa, Yasutaka Suzuki, Ken Takahashi, Motoyasu Terao, Toshimichi Shintani
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Patent number: 6174828Abstract: A gradient-index optical element comprises SiO2, BaO, and TiO2 as essential components, and has a refractive index profile in its diametrical direction. The molar ratio of barium to silicon at the center of the element in its diametrical direction is limited to Ba/Si≧0.4. This gradient-index optical element has a small refractive index difference with reduced chromatic aberrations and, hence, is suitable for use with optical equipment.Type: GrantFiled: July 29, 1998Date of Patent: January 16, 2001Assignee: Olympus Optical Co., Ltd.Inventors: Yuko Morita, Satoshi Noda, Hiroaki Kinoshita
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Patent number: 6171988Abstract: The dielectric constant of low loss tangent glass-ceramic compositions, such as cordierite-based glass ceramics, is modified over a range by selective addition of high dielectric constant ceramics, such as titanates, tantalates and carbides and metals, such as copper. The low loss tangent is retained or improved over a range of frequencies, and the low CTE of the glass-ceramic is maintained. BaTiO3, SrTiO3 and Ta2O5 produce the most effective results.Type: GrantFiled: July 30, 1999Date of Patent: January 9, 2001Assignee: International Business Machines CorporationInventors: Benjamin V. Fasano, Robert A. Rita
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Patent number: 6153127Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.Type: GrantFiled: December 21, 1998Date of Patent: November 28, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichiro Nakamura, Koichi Maeda
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Patent number: 6133174Abstract: A method for producing a machinable feldspathic porcelain comprising leucite is presented. Machinability is imparted to feldspathic porcelains by achieving homogeneous distribution of fine crystalline constituent comprised of at least one of the following leucite phases: potassium tetragonal leucite, rubidium leucite, cesium stabilized cubic leucite, rubidium stabilized cubic leucite, and pollucite. The porcelains produced in accordance with the present invention are readily machinable by using available diamond tooling techniques. Furthermore, the porcelains are especially useful for the fabrication of dental restorations using CAD/CAM technology.Type: GrantFiled: October 9, 1998Date of Patent: October 17, 2000Assignee: Jeneric/Pentron IncorporatedInventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
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Patent number: 6127296Abstract: Disclosed is a novel ceramic-glass composite material useful as a material of electronic parts for attenuation of noise components in the GHz range. The composite material is a sintered body obtained by a heat treatment of a powder blend consisting of 35-55% by weight of a hexagonal ferrite of the formula Ba.sub.3 M.sub.2 Fe.sub.24 O.sub.41 (M.dbd.Co, Ni and/or Zn) and the balance of a glass material consisting of SiO.sub.2, Al.sub.2 O.sub.3, SrO, CaO, MgO and B.sub.2 O.sub.3, of which the content of SrO is 15-25% by moles, at a relatively low sintering temperature of 850-920 .degree. C. for 10-30 minutes.Type: GrantFiled: April 16, 1999Date of Patent: October 3, 2000Assignee: TDK CorporationInventor: Fumio Uchikoba
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Patent number: 6123872Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by .gamma.-rays, X-rays, UV-rays, etc., light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for night illumination or night signal, but also as a material for confirming an infrared laser or controlling an optical axis because of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing of .gamma.-rays, X-rays or UV-rays images. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 1 to 55% B.sub.2 O.sub.3 1 to 50% (SiO.sub.2 + B.sub.2 O.Type: GrantFiled: December 16, 1998Date of Patent: September 26, 2000Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 6121175Abstract: Alkali silicate glasses are described which, in view of their good chemical stability and their optical properties and processing properties, are particularly suitable as a coating or veneering material for ceramic dental frameworks and hence for the production of all-ceramic dental restorations such as crowns or bridges.Type: GrantFiled: June 12, 1998Date of Patent: September 19, 2000Assignee: Ivoclar AGInventors: Helga Drescher, Frank Martin, Volker Rheinberger, Wolfram Holand
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Patent number: 6120591Abstract: A dental porcelain composition, comprising a glassy matrix and leucite crystallites embedded therein, and having maturing temperatures in the range from about 600.degree. C. to about 885.degree. C. and CTEs in the range from about 11 to about 19, more preferably in the range from about 11.5 to about 18, and most preferably in the range from about 12 to about 17.5.times.10.sup.-6 /.degree.C. (measured from 25.degree. C. to 500.degree. C.). The tetragonal leucite is preferably both fine-grained (i.e, having average diameters of less than about 7 microns) and uniformly-sized. Preferably, the average diameters are less than about 1 to about 3 microns.Type: GrantFiled: August 13, 1998Date of Patent: September 19, 2000Assignee: Jeneric/Pentron IncorporatedInventors: Dmitri Brodkin, Carl Panzera, Paul Panzera, Jana N. Pruden, Lisa Kaiser, Richard Brightly
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Patent number: 6107224Abstract: Glass compositions displaying decreased far infrared radiation transmission, high biosolubility, and excellent moisture resistance are capable of fiberization by the rotary process, and may be used to prepare thermal insulation products exhibiting high thermal insulation efficiency as reflected by low thermal index values. The insulation products also exhibit excellent stiffness and recovery properties.Type: GrantFiled: November 19, 1998Date of Patent: August 22, 2000Assignee: Johns Manville International, Inc.Inventors: Xiaojie Xu, Foster Laverne Harding, Mark Alan Albers
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Patent number: 6087284Abstract: The invention relates to a solarization-stable aluminosilicate glass which has the following composition (in % by weight, based on oxide): SiO.sub.2 45-68; Al.sub.2 O.sub.3 >5-18; Na.sub.2 O 0-5; K.sub.2 O>9-15; where Na.sub.2 O+K.sub.2 O.gtoreq.10; CaO 0-10; SrO 0.5-18; BaO 0-10; where CaO+SrO+BaO 8-<17; ZrO.sub.2 1-6; TiO.sub.2 0.2-5. The glass is particularly suitable as substrate glass in display technology, in particular for plasma display panels.Type: GrantFiled: May 26, 1998Date of Patent: July 11, 2000Assignee: Schott GlasInventors: Peter Brix, Wilfried Linz
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Patent number: 6086662Abstract: A dental porcelain composition, comprising a glassy matrix and rubidium leucite crystallites embedded therein, and having maturing temperatures in the range from about 650.degree. C. to about 800.degree. C. and CTEs in the range from about 13 to about 17, more preferably in the range from about 13.5 to about 16, and most preferably in the range from about 14 to about 16.times.10.sup.-6 /.degree. C. (measured from 25.degree. C. to 400.degree. C.). The tetragonal rubidium leucite is preferably both fine-grained (i.e., having average diameters of less than about 5 microns) and uniformly sized. Preferably, the average diameters are less than about 1 to about 2 microns.Type: GrantFiled: October 8, 1998Date of Patent: July 11, 2000Assignee: Jeneric/Pentron IncorporatedInventors: Dmitri Brodkin, Carlino Panzera
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Patent number: 6087282Abstract: Porcelain compositions of the present invention possess non-greening properties and comprise one or more glass or glass-ceramic components. Additionally, an oxygen release agent is included in the compositions. The porcelain compositions may vary depending upon the specific thermal properties desired.The application temperature of the porcelain compositions ranges from about 600.degree. C. to about 930.degree. C. depending upon the method of application of the porcelain. The coefficient of thermal expansion is preferably in the range of about 11.times.10.sup.-6 /.degree. C. to about 16.times.10.sup.-6 /.degree. C. The porcelain is compatible with cores and/or substrates having coefficients of thermal expansion in the range of about 11 to about 20.times.10.sup.-6 /.degree. C.Type: GrantFiled: July 10, 1998Date of Patent: July 11, 2000Assignee: Jeneric/Pentron IncorporatedInventors: Carlino Panzera, Dmitri Brodkin, Paul Panzera
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Patent number: 6063718Abstract: The invention relates to a glass composition intended for the manufacture of thermally stable substrates or panes, which comprises the following constituents in the following proportions by weight:______________________________________ SiO.sub.2 55-70% Al.sub.2 O.sub.3 0-5% or 5-10% ZrO.sub.2 5-10% or 0-5% B.sub.2 O.sub.3 0-3% Na.sub.2 O 2-6% K.sub.2 O 5-11% MgO 0-6% CaO 2-11% SrO 4-12% BaO 0-2% ______________________________________with the following relationships:Na.sub.2 O+K.sub.2 O.gtoreq.8%MgO+CaO+SrO+BaO>10%the said composition having a strain point which is in excess of 600.degree. C.Type: GrantFiled: January 16, 1998Date of Patent: May 16, 2000Assignee: Saint-Gobain VitrageInventors: Nathalie El Khiati, Nathalie Dideron, Daniel Ricoult, Pascale Laborde
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Patent number: 6054401Abstract: The present invention relates to a fireproof sheet glass formed of glass composition which should be classified as a soda-lime glass. Thus far, there has been a demand for a fireproof sheet glass made of soda-lime glass which provides high productivity of sheet glass and which hardly reduces the life of glass melting furnace. However, there has existed none made of soda-lime glass which has high durability and hardly softens. Then, by preparing soda-lime glass in a predetermined glass composition and by using it to obtain a softening point of 780.degree. C. or higher, there has been provided a fireproof sheet glass made of soda-lime glass which provides high durability and which hardly softens.Type: GrantFiled: July 20, 1998Date of Patent: April 25, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Kiminari Sugiura, Akihiro Koyama, Tetsuro Yoshii
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Patent number: 6042806Abstract: Applicant has synthesized a family of novel non-pillared metal oxide compositions which have a triple layered perovskite structure and a surface area of at least 30 m.sup.2 /g. These compositions are described by the empirical formulaAB.sub.2 M.sub.3 O.sub.10-xwhere A is a monovalent exchangeable cation such as cesium, B is a divalent or trivalent cation such as strontium or lanthanum and M is a +2, +3, +4 or a +5 valent metal such as niobium, titanium, aluminum or copper.Type: GrantFiled: May 19, 1999Date of Patent: March 28, 2000Assignee: UOP LOCInventor: Robert L. Bedard
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Patent number: 6034011Abstract: A glass-ceramic substrate for a magnetic head has as its predominant crystal phase a mixed crystal of lithium disilicate (Li.sub.2 O.2SiO.sub.2) and either or both of .alpha.-quartz (.alpha.-SiO.sub.2) and .alpha.-cristobalite (.alpha.-SiO.sub.2), the .alpha.-quartz has a globular grain structure each globular crystral grain being made of aggregated particles and having a grain diameter within a range from 0.1 .mu.m to 3.0 .mu.m, the .alpha.-cristobalite has a globular grain structure each globular grain having a grain diamter within a range from 0.1 .mu.m to 1.0 .mu.m, and surface roughness (Ra) of the glass-ceramic substrate after polishing is within a range from 5 .ANG. to 50 .ANG..Type: GrantFiled: March 11, 1999Date of Patent: March 7, 2000Assignee: Kabushiki Kaisha OharaInventors: Katsuhiko Yamaguchi, Naoyuki Goto
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Patent number: 6022819Abstract: Porcelain compositions of the present invention comprise one or more glass or glass-ceramic powder components. Additionally, one or more opacifying agents, pigments, fluorescing agents and the like may be included in the composition. Based on volume percent, 10% of the particulate in the porcelain has a particle size of less than between about 1.1 microns and about 1.5 microns, 50% of the particulate in the porcelain has a particle size of less than between about 3 and about 6 microns, 90% of the particulate in the porcelain has a particle size of less than between about 8 and about 13.5 microns, and the maximum particle size of the particulate is greater than about 20 microns and less than about 60 microns. The mean particle size is preferably in the range of about 3.0 microns to about 6.5 microns.Type: GrantFiled: July 17, 1998Date of Patent: February 8, 2000Assignee: Jeneric/Pentron IncorporatedInventors: Paul Panzera, Jana Pruden, Dmitri Brodkin, Lisa M. Kaiser, Richard A. Brightly, Carlino Panzera
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Patent number: 6017835Abstract: Compositions for producing irregularly-shaped dual-glass fibers include a first glass composition and a second glass composition, the first and second glass compositions having nonidentical coefficients of thermal expansion, the difference between the coefficients of thermal expansion being greater than about 2.0 ppm/.degree. C.Type: GrantFiled: November 5, 1993Date of Patent: January 25, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventor: Russell M. Potter
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Patent number: 6004894Abstract: The present invention provides a porcelain enamel coating composition for use in forming a coating composition upon a metal substrate having an infrared reflectivity of at least 50% at 2.5 .mu.-microns measured with a Perkin Elmer Lambda 19 UV/VIS/NIR spectrometer with a labsphere RSA-PE 19 reflectance spectroscopy accessory. The coating composition comprises a glass component and a separate and distinct addition of cerium oxide. Preferably, the coating composition comprises from about 0.20% to about 3.0% by weight of the cerium oxide.Type: GrantFiled: October 28, 1998Date of Patent: December 21, 1999Assignee: Ferro CorporationInventors: William D. Faust, Holger F. Evele
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Patent number: 5994248Abstract: The invention relates to lenses such as aspherical lenses and to a process for their manufacture. According to the invention, the lens is composed of a glass matrix including the constituents below in the following weight proportions:______________________________________ SiO.sub.2 65-85% Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3 0-20% Li.sub.2 O + Na.sub.2 O + K.sub.2 O 3-20% CaO + MgO + BaO 1-15% FeO + Fe.sub.2 O.sub.3 0-0.1%, ______________________________________wherein the K.sub.2 O content is equal to or less than 1% and the BaO content is equal to or less than 1%.Type: GrantFiled: November 6, 1997Date of Patent: November 30, 1999Assignee: Saint-Gobain VitrageInventors: Jose Francisco Gandarillas-Lastra, Benoit Trouille
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Patent number: 5990023Abstract: Use is made, for the manufacture of fire-resistant glazings of the G fire-resistance classes, comprising panes made of glass toughened by the thermal route by means of a conventional toughening plant and possessing safety glass properties, of glasses which exhibit a thermal expansion coefficient .alpha..sub.20-300 of between 6 and 8.5.times.10.sup.-6 K.sup.-1, a thermal stress factor .phi. of between 0.5 and 0.8N/(mm.sup.2.K), a softening point of between 750 and 830.degree. C. and a transformation point of at the very most 1190.degree. C.Type: GrantFiled: March 11, 1998Date of Patent: November 23, 1999Assignee: Vetrotech Saint-Gobain International AGInventors: Horst Siedel, Claude Morin, Pierre Jeanvoine
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Patent number: 5985473Abstract: A barium/lead-free ceramic glaze includes by weight:(i) between about 44 and 50% SiO.sub.2 ;(ii) between about 7 and 13% Al.sub.2 O.sub.3 ;(iii) between about 22 and 26% B.sub.2 O.sub.3 ;(iv) between about 3 and 9% CaO;(v) between about 1 and 3% SrO;(vi) up to about 2% ZnO;(vii) between about 2 and 4% K.sub.2 O;(viii) up to about 2% Li.sub.2 O; and(ix) between about 5 and 9% Na.sub.2 O.This barium/lead-free glaze can be effectually applied to a ceramic substrate at firing temperatures on the order of 1550 to 1650.degree. F. (843 to 899.degree. C.).Type: GrantFiled: November 17, 1997Date of Patent: November 16, 1999Assignee: Cooper Automotive Products, Inc.Inventor: Randy Owen Knapp
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Patent number: 5981414Abstract: Described is an inorganic fiber comprising silica dioxide, calcium oxide, and alkali oxide having a free energy of hydration greater than (more positive than) -5.00 kcal/mol, an enthalpy of formation less than (more than negative than) -210.0 kcal/mol, a dissolution rate in simulated extra cellular fluid greater than 750 (calculated as nanograms of fiber/per square centimeter of fiber surface area/per hour) having an average fiber diameter not greater than 4.5 micrometers. Also described is a method of manufacturing the fibers.Type: GrantFiled: May 13, 1994Date of Patent: November 9, 1999Assignee: Johns Manville International, Inc.Inventors: Jon Frederick Bauer, Kevin Dean Schaal
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Patent number: 5981412Abstract: A bioactive ceramic composition including 47 to 51% SiO.sub.2, 23 to 25% CaO, 23 to 25% Na.sub.2 O and 0 to 6% P.sub.2 O.sub.5, the bioactive ceramic having a bioacitivity level such that the composition forms at least a thin layer of HCA within about 30 hours of implantation into a patient. The bioactive ceramic composition having a crystallinity of 34 to 60 volume percent and a crystalline phase of 1Na.sub.2 O.2CaO.3SiO.sub.2.Type: GrantFiled: May 1, 1997Date of Patent: November 9, 1999Assignee: University of Florida Research FoundationInventors: Larry L. Hench, Guy La Torre, Oscar P. Filho, Edgar Zanotto
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Patent number: 5977001Abstract: The invention relates to a glass composition for electric lamps which glass composition comprises SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O, K.sub.2 O, Li.sub.2 O, B.sub.2 O.sub.3, BaO and SrO and optionally CaO, MgO, ZnO, P.sub.2 O.sub.5, Sb.sub.2 O.sub.3, TiO.sub.2, MnO.sub.2, Fe.sub.2 O.sub.3 and/or CeO.sub.2. The composition according to the invention has a B.sub.2 O.sub.3 content of 1 to 2.8 mass %, a SrO content of 2.1 to 4.5 mass %, a BaO content of 3 to 6 mass % and of the components being present optionally, the amount of CaO is maximum 1 mass %, that of MgO is maximum 2.4 mass % and that of ZnO is maximum 3 mass %, on the condition that the total amount of SrO and B.sub.2 O.sub.3 is at least 3.6 mass %, the total amount of CaO and MgO is maximum 2.4 mass % and the total amount of MgO and ZnO is maximum 4.5 mass %.Type: GrantFiled: December 1, 1997Date of Patent: November 2, 1999Assignee: General Electric CompanyInventors: Zoltan Kamill Suha, Zsuzsanna Klara Varga, Zoltan Laszlo Bako
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Patent number: 5961883Abstract: A glass material is provided which is capable of exhibiting fluorescence in the visible region by ultraviolet ray excitation. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 2 to 60%, B.sub.2 O.sub.3 5 to 70% (SiO.sub.2 + B.sub.2 O.sub.3 = 50 to 70%) RO 5 to 30% (R: at least one atom selected from Mg, Ca, Sr and Ba) ZnO 0 to 15% ZrO.sub.2 0 to 10%, Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3 2 to 15% (containing either of Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3) Ln.sub.2 O.sub.3 0 to 20% (Ln: at least one atom selected from Y, La, Gd, Yb, Lu, Sm, Dy and Tm) CeO.sub.2 0 to 1% Bi.sub.2 O.sub.3 0 to 2% Sb.sub.2 O.sub.3 0.01 to 0.5% and R'.sub.Type: GrantFiled: December 11, 1997Date of Patent: October 5, 1999Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Masaaki Otsuka, Hideaki Takaku, Naruhito Sawanobori
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Patent number: 5958810Abstract: Optical glasses or lenses are described having a refractive index that varies as a function of at least one coordinate, which is made from a starting material with a constant refractive index by ion exchange. Greater index gradients than with the prior art are achieved by special compositions and ion exchange baths intended therefor. In addition, the stability of the glasses is increased.Type: GrantFiled: October 28, 1997Date of Patent: September 28, 1999Assignee: Optische Werke G. RodenstockInventors: Werner Mohr, Boris Goldenfang, Vladimir Il'Lin, Vladislav Lifschitz, Nikolai Remizov
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Patent number: 5958363Abstract: Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The containment vessel is enclosed within an aqueous atmosphere that is above the supercritical temperature and pressure of the solvent of the metal alkoxide solution.Type: GrantFiled: October 29, 1998Date of Patent: September 28, 1999Assignee: The Regents of the University of CaliforniaInventor: Paul R. Coronado
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Patent number: 5958812Abstract: This invention concerns a thermally stable glass composition, which comprises the following constituents in the following proportions by weight:______________________________________ SiO.sub.2 45 to 68% Al.sub.2 O.sub.3 0 to 20% ZrO.sub.2 0 to 20% B.sub.2 O.sub.3 0 to 10% Na.sub.2 O 2 to 12% K.sub.2 O 3.5 to 9% CaO 1 to 13% MgO 0 to 8% ______________________________________the sum of the contents of the oxides SiO.sub.2, Al.sub.2 O.sub.3 and ZrO.sub.2 remaining equal to or less than 70%, the sum of the oxides Al.sub.2 O.sub.3 and ZrO.sub.2 being equal to or greater than 2%, the sum of the alkaline oxides Na.sub.2 O and K.sub.2 O being equal to or greater than 8%, said composition comprising, if desired, the oxides BaO and/or SrO in proportions such that:11%.ltoreq.MgO+CaO--BaO+SrO>30%This glass composition may be used for the production of substrates for an emissive screen or for that of a fire-resistant pane.Type: GrantFiled: December 16, 1997Date of Patent: September 28, 1999Assignee: Saint-Gobain VitrageInventors: Stephanie Koch, Didier Jousse, Rene Gy, Gilles Courtemanche
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Patent number: 5945360Abstract: Glass compositions suitable for pot and marble fiberization display excellent chemical resistance to both acids and moisture while being highly biosoluble at the same time. The glass compositions are characterized by ratios of components which are reflective of acid resistance, biosolubility, and moisture resistance. Preferred glasses have a difference between HTV (10.sup.3 poise) and liquidus greater than 500.degree. F., and a biodissolution greater than about 350 ng/cm.sup.2 /hr.Type: GrantFiled: March 28, 1997Date of Patent: August 31, 1999Assignee: Johns Manville International, Inc.Inventors: Foster Laverne Harding, Jon Frederick Bauer, Harry Hand Russell, III, Xiaojie Xu
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Patent number: 5925583Abstract: A heat-resistant glass composition which comprises, in % by weight; 56 to 68% of SiO.sub.2, 0.2 to 5% of Al.sub.2 O.sub.3, 0 to 6.4% of ZrO.sub.2, 0 to 0.5% of Li.sub.2 O, 0.2 to 8% of Na.sub.2 O, 2.5 to 14% of K.sub.2 O, 1 to 7% of MgO, 2 to 12% of CaO, 0 to 12% of SrO, 0 to 13% of BaO, 0 to 2% of ZnO, 0 to 1% in total of SO.sub.3 and Sb.sub.2 O.sub.3, and 0 to 3% of TiO.sub.2, with the proviso of the total amount of Na.sub.2 O and K.sub.2 O being 7 to 17%, the total amount of MgO and CaO being 7 to 15%, the total amount of SrO and BaO being 4 to 18%, the total amount of MgO, CaO, SrO, and BaO being 15 to 27%, and the total amount of SiO.sub.2, Al.sub.2 O.sub.3, and ZrO.sub.2 being 58% or more, and which has an average thermal expansion coefficient of 75.times.10.sup.-7 to 100.times.10.sup.-7 /K at 50 to 350.degree. C. and a strain point of 530.degree. C. or more.Type: GrantFiled: September 11, 1997Date of Patent: July 20, 1999Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Tetsuro Yoshii, Akihiro Koyama, Hiroyuki Tanaka, Nobuyuki Yamamoto, Shigekazu Yoshii
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Patent number: 5925582Abstract: A novel type of glass having a low sodium content (<0.1 wt. % Na.sub.2 O), which can be used as a bulb glass (10) for "TL" lamps and for compact fluorescent lamps. Said glass is free of the toxic and/or corrosive components PbO, F, As.sub.2 0.sub.3 and Sb.sub.2 0.sub.3. Apart from favorable properties as regards phosphor poisoning and mercury absorption, resulting in a favorable maintenance of the lamp, said glass is characterized by a wide working range W.R. (=T.sub.work -T.sub.soft), so that glass tubing can be readily made of said glass. By virtue of the low liquidus temperature (T.sub.liq), the glass can be drawn into glass tubing which is free of crystals.Type: GrantFiled: May 12, 1997Date of Patent: July 20, 1999Assignee: U.S. Philips CorporationInventors: Bartholomeus Filmer, Gerardus H.A.M. Van Der Steen
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Patent number: 5914356Abstract: Novel fillers comprising combeite glass-ceramic are provided, along with filled polymerizable resin composites. Further provided are methods for making the combeite crystallite-containing novel fillers for use in hardenable, biocompatible bone restorations. Hard, shaped bodies or orthopaedic, dental and other uses are also provided.Type: GrantFiled: June 5, 1998Date of Patent: June 22, 1999Assignee: Orthovita, Inc.Inventor: Erik M. Erbe
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Patent number: 5908794Abstract: A glass composition for a substrate consisting essentially of from 56 to 72 wt % of SiO.sub.2, from 1 to less than 14 wt % of Al.sub.2 O.sub.3, from 0 to 9 wt % of MgO, from 0.5 to 11 wt % of CaO, from 0 to 4 wt % of SrO, from 0 to 3 wt % of BaO, from 6 to less than 14 wt % of MgO+CaO+SrO+BaO, from 0 to 9 wt % of Na.sub.2 O, from 6 to 20 wt % of K.sub.2 O, and from 6 to 20 wt % of Na.sub.2 O+K.sub.2 O.Type: GrantFiled: March 13, 1997Date of Patent: June 1, 1999Assignee: Asahi Glass Company Ltd.Inventors: Kei Maeda, Hitoshi Onoda, Yasumasa Nakao, Jeetendra Sehgal
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Patent number: 5900296Abstract: A glass substrate for magnetic disks, obtained by chemical strengthening treatment of a glass consisting essentially of from 50 to 65 wt % of SiO.sub.2, from 5 to 15 wt % of Al.sub.2 O.sub.3, from 2 to 7 wt % of Na.sub.2 O, from 4 to 9 wt % of K.sub.2 O, from 7 to 14 wt % of Na.sub.2 O+K.sub.2 O, from 12 to 25 wt % of MgO+CaO+SrO+BaO, and from 1 to 6 wt % of ZrO.sub.2.Type: GrantFiled: April 18, 1996Date of Patent: May 4, 1999Assignee: AG Technology Co., Ltd.Inventors: Ichiro Hayashi, Kei Maeda, Kazuo Mannami
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Patent number: 5900052Abstract: There is provided a belt coating material for a belt type continuous casting, which is capable of adsorbing the intermediate between a cast slab and the coating material to prevent the intermediate from remaining on the slab, and reducing the averaged heat flux during the casting to avoid an occurrence of cracking in a medium carbon steel. The belt coating material comprises: (1) a powder having a composition comprising 10 to 40 weight % of SiO.sub.2, 1 to 10 weight % of Al.sub.2 O.sub.3, 10 to 40 weight % of CaO, 10 to 30 weight % of Na.sub.2 O, 1 to 10 weight % of MgO, 10 to 20 weight % of F, and 1 to 5 weight % of LiO.sub.2, the powder being prepared by once melting the blended components, solidifying the melt, and crushing it into the powder to adjust the average grain diameter of the powder to be equal to or smaller than 10 .mu.m; (2) 0.1 to 10 weight % of graphite mixed into the powder to provide a mixture, the graphite having the same grain diameter with the powder; and (3) 0.Type: GrantFiled: April 11, 1997Date of Patent: May 4, 1999Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hiroshi Nakajima, Kouichi Hirata, Hironori Fujioka
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Patent number: 5900380Abstract: A conductive glass lining composition includes 100 parts by weight of a frit and 0.05 to 1.5 parts by weight of a metal fibers of 0.1 to 30 .mu.m in diameter, 1.5 to 10 mm in length and a length-to-diameter ratio of not less than 50.Type: GrantFiled: July 15, 1997Date of Patent: May 4, 1999Assignee: Ikebukuro Horo Kogyo Co., Ltd.Inventors: Yoshihiro Iizawa, Mitsuru Akazawa
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Patent number: 5897678Abstract: The invention provides a method by which a crystal glass composition which employs TiO.sub.2 as a raw material substituted for PbO can be produced while effectively preventing development of a yellowish color of the glass composition which is caused by TiO.sub.2. In the production method, to a batch composition which is composed of 50 to 60 percent by weight of SiO.sub.2, 4 to 14 percent by weight of K.sub.2 O, 10 to 20 percent by weight of BaO and 3 to 10 percent by weight of TiO.sub.2, NaNO.sub.3 (sodium nitrate) is added by 1.0 to 5.0 percent by weight or BaO.sub.2 (barium peroxide) is added by 0.3 to 2.0 percent by weight for elimination of development of a color which arises from the 3 to 10 percent by weight of TiO.sub.2, and also one of Sb.sub.2 O.sub.3 (antimony oxide) and As.sub.2 O.sub.3 (arsenious acid) is added by 0.2 to 1.0 percent by weight for defoaming. Instead, NaSb(OH).sub.6 (sodium antimonate) having color development elimination and defoaming actions may be added by 0.5 to 2.Type: GrantFiled: July 23, 1997Date of Patent: April 27, 1999Assignee: Toyo Glass Company LimitedInventors: Hidetoshi Komiya, Shizue Inaba
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Patent number: 5897956Abstract: Glass having low solar radiation and ultraviolet ray transmittance, which consists essentially of a soda lime-silica type matrix glass containing from 0.53 to 0.70 wt % of total iron calculated as Fe.sub.2 O.sub.3, from 0.2 to 0.4 wt % of TiO.sub.2 and from 0.5 to 0.8 wt % of total cerium calculated as CeO.sub.2, wherein the weight of FeO calculated as Fe.sub.2 O.sub.3 is from 30 to 40% of the weight of the total iron calculated as Fe.sub.2 O.sub.3.Type: GrantFiled: April 21, 1997Date of Patent: April 27, 1999Assignee: Asahi Glass Company Ltd.Inventors: Takashi Kijima, Toru Kudo, Mizuki Ito, Fumio Kamei, Akira Kondo