And Divalent Metal Oxide (e.g., Oxides Of Zinc, Cadmium, Beryllium, Alkaline Earth Metal, Magnesium, Etc.) Patents (Class 501/72)
  • Patent number: 6255238
    Abstract: The object of the present invention is brown solar glasses, absorbing UV or IR radiation, as well as solar ophthalmic lenses in said glasses. Said glasses have the following composition, expressed in percentages by weight: SiO2: 64-71; B2O3: 2-8; Al2O3: 0-4; ZrO2: 0-2; Li2O: 0-4; Na2O: 6-10; K2O: 7-16; CaO: 0-5.5; ZnO: 0-5.5; TiO2; 0-2; Fe2O3: 3-9; Co3O4: 0-0.030; NiO: 0-0.2; SeO2: 0.0030-0.1; As2O3: 0-0.1; Sb2O3: 0-0.1; SnO2: 0-0.1; Cl: 0-2; Br: 0-2; F: 0-2.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: July 3, 2001
    Assignee: Corning S.A.
    Inventor: Yves A. H. Brocheton
  • Patent number: 6251812
    Abstract: A glass composition is disclosed which has a high modulus of elasticity (Young's modulus) and a high rigidity (modulus of elasticity/specific gravity) and is capable of being effectively inhibited from bending or vibrating. Also disclosed is a substrate for information recording media, which comprises the glass composition. The glass composition comprises the following components in terms of mol %: 50 to 64% SiO2, 6 to 18% Al2O3, 7 to 15% Li2O, 3 to 12% Na2O, 0 to 2% K2O, 0 to 10% TiO2, 0 to 4% ZrO2, 0 to 6% MgO, 0 to 9% CaO, and 0 to 6% SrO, provided at the content of RO (RO=MgO+CaO+SrO) is from 2 to 15%.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: June 26, 2001
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Akihiro Koyama, Shoichi Kishimoto, Junji Kurachi, Nobuyuki Yamamoto
  • Patent number: 6251811
    Abstract: A funnel glass containing PbO for a cathode ray tube, wherein when the composition is represented by wt % based on oxides, the content of SrO is at least 1.0 wt %, the content of BaO is at least 1.0 wt %, and the ratio of the content of PbO to the total amount of PbO, SrO, BaO, CaO and MgO, is at most 0.69, and whereby the lead elution A of the glass as measured by the following method A is at most 1.0 &mgr;g/cm2, and the X-ray absorption coefficient at a wavelength of 0.6 Å is at least 40 cm−1: Method A: The glass is immersed in distilled and deionized water at 90° C. for 20 hours, whereupon the glass is taken out, and the amount of lead in the distilled and deionized water is measured by inductively coupled plasma emission spectrometry, and the measured value of the amount of lead is divided by the surface area of the glass, and the product is taken as the lead elution A.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: June 26, 2001
    Assignee: Asahi Glass Company Ltd.
    Inventors: Osamu Yanagisawa, Yuichi Kuroki, Ryousuke Akagi
  • Patent number: 6235667
    Abstract: A lead-free glass, which is suitable for use as imitation lead crystal tableware and decorative crystal glassware, has a chemical composition as a percentage by weight within the following range: silica 50-58 zirconium oxide 0-5 potash (K2O) 0-13, e.g. 0-12 yttrium oxide 0-5 soda (Na2O) 0-9 alumina 0-3 lithium oxide 0-4 tin oxide 0-5 calcium oxide 0-3 lanthanum oxide 0-9 magnesium oxide 0-4 niobium oxide 0-9 boric anhydride (B2O3) 0-2 bismuth oxide 0-13, e.g. 0-12 zinc oxide 16-30 germanium oxide 0-5 barium oxide 0-13, e.g. 0-12 antimony oxide 0-1 titanium oxide 0-6.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: May 22, 2001
    Assignee: CALP Cristalleria Artistica la Piana S.p.A.
    Inventors: Fabio Paloschi, Giancarlo Boschi
  • Patent number: 6206958
    Abstract: Porcelain compositions of the present invention comprises particulate of one or more glass or glass-ceramic powder components. Additionally, one or more opacifing agents, pigments, fluorescing agents and the like may be included in the composition. Based on volume percent, the particulate has a d10 of from about 1.1 and about 1.8 microns; a d50 of from about 3 to about 6 microns; a d90 of from about 8 to about 16 microns; and about 1.0 to about 4.0% by volume of the particulate has a particle size greater than or equal to about 20 microns. The mean particle size is preferably in the range of about 3.0 microns to about 7.5 microns.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: March 27, 2001
    Assignee: Jeneric/Pentron, Incorporated
    Inventors: Paul Panzera, Jana N. Pruden, Dmitri Brodkin, Lisa M. Kaiser, Richard A. Brightly, Carlino Panzera
  • Patent number: 6207603
    Abstract: A borosilicate glass having properties that enable it to be drawn as microsheets for use as a solar cell cover glass, and a solar cell having such microsheet as a cover glass, the glass having a composition consisting essentially of, expressed in terms of weight percent on an oxide basis: SiO2 59-69 ZnO 6.5-8.5 B2O3 8.5-14  CeO2 0.25-3   Al2O3   2-2.5 TiO2 0-1 Na2O  5.5-12.5 CeO2 + TiO2 0.5-4   K2O 0-8 Sb2O3    0-0.5.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: March 27, 2001
    Assignee: Corning Incorporated
    Inventors: Paul S. Danielson, Ronald L. Stewart
  • Patent number: 6200137
    Abstract: An apatite glass ceramic is described which is characterized by good chemical stability, a low expansion coefficient and high translucence, and is particularly suitable, by itself or together with glasses or other glass ceramics, as a veneering material for ceramic dental restorations.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: March 13, 2001
    Assignee: Ivoclar AG
    Inventors: Wolfram Höland, Martin Frank, Helga Drescher, Volker Rheinberger
  • Patent number: 6197429
    Abstract: A glass-ceramic material which exhibits extremely low (e.g. less than 100 ppm) shrinkage, when exposed to 900° C. for 6 hours, and methods for making such glass-ceramics. The glass-ceramic is cerammed at a sufficiently high temperature and then cooling in a controlled manner, preferably to below the strain point of the resultant material. Using this technique, glass-ceramic materials were fabricated which exhibited dimensional shrinkage comparable to and in some cases even less than that achieved by fused silica substrates, when exposed to high temperature poly-Si processing temperatures (e.g. 900° C. for 6 hours).
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: March 6, 2001
    Assignee: Corning Incorporated
    Inventors: Josef C. Lapp, Chad B. Moore, Linda R. Pinckney
  • Patent number: 6184166
    Abstract: This invention relates to lead-free silicate glasses that find use in producing fine crystal glassware and in laminated ware applications. The glasses consist essentially, in weight percent, of: SiO2 52-66 ZnO 15-30 Al2O3 0-4 BaO 0-7 Li2O 0-4 MgO + CaO + SrO 0-4 Na2O  3-16 ZrO2 0-4 K2O  0-12 B2O3  0-4.
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: February 6, 2001
    Assignee: Corning Incorporated
    Inventors: George B. Hares, Jeffrey T. Kohli, James E. Webb
  • Patent number: 6180218
    Abstract: Radiation stable glass for space applications, especially glass in the form of thin sheet for cladding of spacecraft, is produced by including at least 5% by weight of barium oxide in a borosilicate glass composition. Because barium has a low absorption in the ultra violet, its use enables radiation stable glasses of low ultra violet absorption to be produced, alleviating problems of overheating when the glasses are used for cladding space craft. The glass is useful in the production of solar cell cover slips and second surface mirrors for cladding purposes, and space applications generally.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: January 30, 2001
    Assignee: Pilkington PLC
    Inventors: Kenneth Melvin Fyles, Helen Louise Eaves, Peter Shorrock
  • Patent number: 6177169
    Abstract: A glass including SiO2, Na2O, MgO, Al2O3 and cobalt oxide, wherein the cobalt oxide is 4.5-85 wt % as an oxide of CoO or 4.9-91 wt % as an oxide of Co3O4.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: January 23, 2001
    Assignee: Hitachi, Ltd.
    Inventors: Hiroki Yamamoto, Takashi Naito, Takashi Namekawa, Yasutaka Suzuki, Ken Takahashi, Motoyasu Terao, Toshimichi Shintani
  • Patent number: 6174828
    Abstract: A gradient-index optical element comprises SiO2, BaO, and TiO2 as essential components, and has a refractive index profile in its diametrical direction. The molar ratio of barium to silicon at the center of the element in its diametrical direction is limited to Ba/Si≧0.4. This gradient-index optical element has a small refractive index difference with reduced chromatic aberrations and, hence, is suitable for use with optical equipment.
    Type: Grant
    Filed: July 29, 1998
    Date of Patent: January 16, 2001
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Yuko Morita, Satoshi Noda, Hiroaki Kinoshita
  • Patent number: 6171988
    Abstract: The dielectric constant of low loss tangent glass-ceramic compositions, such as cordierite-based glass ceramics, is modified over a range by selective addition of high dielectric constant ceramics, such as titanates, tantalates and carbides and metals, such as copper. The low loss tangent is retained or improved over a range of frequencies, and the low CTE of the glass-ceramic is maintained. BaTiO3, SrTiO3 and Ta2O5 produce the most effective results.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: January 9, 2001
    Assignee: International Business Machines Corporation
    Inventors: Benjamin V. Fasano, Robert A. Rita
  • Patent number: 6153127
    Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 28, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichiro Nakamura, Koichi Maeda
  • Patent number: 6133174
    Abstract: A method for producing a machinable feldspathic porcelain comprising leucite is presented. Machinability is imparted to feldspathic porcelains by achieving homogeneous distribution of fine crystalline constituent comprised of at least one of the following leucite phases: potassium tetragonal leucite, rubidium leucite, cesium stabilized cubic leucite, rubidium stabilized cubic leucite, and pollucite. The porcelains produced in accordance with the present invention are readily machinable by using available diamond tooling techniques. Furthermore, the porcelains are especially useful for the fabrication of dental restorations using CAD/CAM technology.
    Type: Grant
    Filed: October 9, 1998
    Date of Patent: October 17, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
  • Patent number: 6127296
    Abstract: Disclosed is a novel ceramic-glass composite material useful as a material of electronic parts for attenuation of noise components in the GHz range. The composite material is a sintered body obtained by a heat treatment of a powder blend consisting of 35-55% by weight of a hexagonal ferrite of the formula Ba.sub.3 M.sub.2 Fe.sub.24 O.sub.41 (M.dbd.Co, Ni and/or Zn) and the balance of a glass material consisting of SiO.sub.2, Al.sub.2 O.sub.3, SrO, CaO, MgO and B.sub.2 O.sub.3, of which the content of SrO is 15-25% by moles, at a relatively low sintering temperature of 850-920 .degree. C. for 10-30 minutes.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: October 3, 2000
    Assignee: TDK Corporation
    Inventor: Fumio Uchikoba
  • Patent number: 6123872
    Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by .gamma.-rays, X-rays, UV-rays, etc., light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for night illumination or night signal, but also as a material for confirming an infrared laser or controlling an optical axis because of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing of .gamma.-rays, X-rays or UV-rays images. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 1 to 55% B.sub.2 O.sub.3 1 to 50% (SiO.sub.2 + B.sub.2 O.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: September 26, 2000
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6121175
    Abstract: Alkali silicate glasses are described which, in view of their good chemical stability and their optical properties and processing properties, are particularly suitable as a coating or veneering material for ceramic dental frameworks and hence for the production of all-ceramic dental restorations such as crowns or bridges.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: September 19, 2000
    Assignee: Ivoclar AG
    Inventors: Helga Drescher, Frank Martin, Volker Rheinberger, Wolfram Holand
  • Patent number: 6120591
    Abstract: A dental porcelain composition, comprising a glassy matrix and leucite crystallites embedded therein, and having maturing temperatures in the range from about 600.degree. C. to about 885.degree. C. and CTEs in the range from about 11 to about 19, more preferably in the range from about 11.5 to about 18, and most preferably in the range from about 12 to about 17.5.times.10.sup.-6 /.degree.C. (measured from 25.degree. C. to 500.degree. C.). The tetragonal leucite is preferably both fine-grained (i.e, having average diameters of less than about 7 microns) and uniformly-sized. Preferably, the average diameters are less than about 1 to about 3 microns.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: September 19, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Dmitri Brodkin, Carl Panzera, Paul Panzera, Jana N. Pruden, Lisa Kaiser, Richard Brightly
  • Patent number: 6107224
    Abstract: Glass compositions displaying decreased far infrared radiation transmission, high biosolubility, and excellent moisture resistance are capable of fiberization by the rotary process, and may be used to prepare thermal insulation products exhibiting high thermal insulation efficiency as reflected by low thermal index values. The insulation products also exhibit excellent stiffness and recovery properties.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: August 22, 2000
    Assignee: Johns Manville International, Inc.
    Inventors: Xiaojie Xu, Foster Laverne Harding, Mark Alan Albers
  • Patent number: 6087284
    Abstract: The invention relates to a solarization-stable aluminosilicate glass which has the following composition (in % by weight, based on oxide): SiO.sub.2 45-68; Al.sub.2 O.sub.3 >5-18; Na.sub.2 O 0-5; K.sub.2 O>9-15; where Na.sub.2 O+K.sub.2 O.gtoreq.10; CaO 0-10; SrO 0.5-18; BaO 0-10; where CaO+SrO+BaO 8-<17; ZrO.sub.2 1-6; TiO.sub.2 0.2-5. The glass is particularly suitable as substrate glass in display technology, in particular for plasma display panels.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: July 11, 2000
    Assignee: Schott Glas
    Inventors: Peter Brix, Wilfried Linz
  • Patent number: 6086662
    Abstract: A dental porcelain composition, comprising a glassy matrix and rubidium leucite crystallites embedded therein, and having maturing temperatures in the range from about 650.degree. C. to about 800.degree. C. and CTEs in the range from about 13 to about 17, more preferably in the range from about 13.5 to about 16, and most preferably in the range from about 14 to about 16.times.10.sup.-6 /.degree. C. (measured from 25.degree. C. to 400.degree. C.). The tetragonal rubidium leucite is preferably both fine-grained (i.e., having average diameters of less than about 5 microns) and uniformly sized. Preferably, the average diameters are less than about 1 to about 2 microns.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: July 11, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Dmitri Brodkin, Carlino Panzera
  • Patent number: 6087282
    Abstract: Porcelain compositions of the present invention possess non-greening properties and comprise one or more glass or glass-ceramic components. Additionally, an oxygen release agent is included in the compositions. The porcelain compositions may vary depending upon the specific thermal properties desired.The application temperature of the porcelain compositions ranges from about 600.degree. C. to about 930.degree. C. depending upon the method of application of the porcelain. The coefficient of thermal expansion is preferably in the range of about 11.times.10.sup.-6 /.degree. C. to about 16.times.10.sup.-6 /.degree. C. The porcelain is compatible with cores and/or substrates having coefficients of thermal expansion in the range of about 11 to about 20.times.10.sup.-6 /.degree. C.
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: July 11, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Carlino Panzera, Dmitri Brodkin, Paul Panzera
  • Patent number: 6063718
    Abstract: The invention relates to a glass composition intended for the manufacture of thermally stable substrates or panes, which comprises the following constituents in the following proportions by weight:______________________________________ SiO.sub.2 55-70% Al.sub.2 O.sub.3 0-5% or 5-10% ZrO.sub.2 5-10% or 0-5% B.sub.2 O.sub.3 0-3% Na.sub.2 O 2-6% K.sub.2 O 5-11% MgO 0-6% CaO 2-11% SrO 4-12% BaO 0-2% ______________________________________with the following relationships:Na.sub.2 O+K.sub.2 O.gtoreq.8%MgO+CaO+SrO+BaO>10%the said composition having a strain point which is in excess of 600.degree. C.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: May 16, 2000
    Assignee: Saint-Gobain Vitrage
    Inventors: Nathalie El Khiati, Nathalie Dideron, Daniel Ricoult, Pascale Laborde
  • Patent number: 6054401
    Abstract: The present invention relates to a fireproof sheet glass formed of glass composition which should be classified as a soda-lime glass. Thus far, there has been a demand for a fireproof sheet glass made of soda-lime glass which provides high productivity of sheet glass and which hardly reduces the life of glass melting furnace. However, there has existed none made of soda-lime glass which has high durability and hardly softens. Then, by preparing soda-lime glass in a predetermined glass composition and by using it to obtain a softening point of 780.degree. C. or higher, there has been provided a fireproof sheet glass made of soda-lime glass which provides high durability and which hardly softens.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: April 25, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Kiminari Sugiura, Akihiro Koyama, Tetsuro Yoshii
  • Patent number: 6042806
    Abstract: Applicant has synthesized a family of novel non-pillared metal oxide compositions which have a triple layered perovskite structure and a surface area of at least 30 m.sup.2 /g. These compositions are described by the empirical formulaAB.sub.2 M.sub.3 O.sub.10-xwhere A is a monovalent exchangeable cation such as cesium, B is a divalent or trivalent cation such as strontium or lanthanum and M is a +2, +3, +4 or a +5 valent metal such as niobium, titanium, aluminum or copper.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: March 28, 2000
    Assignee: UOP LOC
    Inventor: Robert L. Bedard
  • Patent number: 6034011
    Abstract: A glass-ceramic substrate for a magnetic head has as its predominant crystal phase a mixed crystal of lithium disilicate (Li.sub.2 O.2SiO.sub.2) and either or both of .alpha.-quartz (.alpha.-SiO.sub.2) and .alpha.-cristobalite (.alpha.-SiO.sub.2), the .alpha.-quartz has a globular grain structure each globular crystral grain being made of aggregated particles and having a grain diameter within a range from 0.1 .mu.m to 3.0 .mu.m, the .alpha.-cristobalite has a globular grain structure each globular grain having a grain diamter within a range from 0.1 .mu.m to 1.0 .mu.m, and surface roughness (Ra) of the glass-ceramic substrate after polishing is within a range from 5 .ANG. to 50 .ANG..
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: March 7, 2000
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Katsuhiko Yamaguchi, Naoyuki Goto
  • Patent number: 6022819
    Abstract: Porcelain compositions of the present invention comprise one or more glass or glass-ceramic powder components. Additionally, one or more opacifying agents, pigments, fluorescing agents and the like may be included in the composition. Based on volume percent, 10% of the particulate in the porcelain has a particle size of less than between about 1.1 microns and about 1.5 microns, 50% of the particulate in the porcelain has a particle size of less than between about 3 and about 6 microns, 90% of the particulate in the porcelain has a particle size of less than between about 8 and about 13.5 microns, and the maximum particle size of the particulate is greater than about 20 microns and less than about 60 microns. The mean particle size is preferably in the range of about 3.0 microns to about 6.5 microns.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: February 8, 2000
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Paul Panzera, Jana Pruden, Dmitri Brodkin, Lisa M. Kaiser, Richard A. Brightly, Carlino Panzera
  • Patent number: 6017835
    Abstract: Compositions for producing irregularly-shaped dual-glass fibers include a first glass composition and a second glass composition, the first and second glass compositions having nonidentical coefficients of thermal expansion, the difference between the coefficients of thermal expansion being greater than about 2.0 ppm/.degree. C.
    Type: Grant
    Filed: November 5, 1993
    Date of Patent: January 25, 2000
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventor: Russell M. Potter
  • Patent number: 6004894
    Abstract: The present invention provides a porcelain enamel coating composition for use in forming a coating composition upon a metal substrate having an infrared reflectivity of at least 50% at 2.5 .mu.-microns measured with a Perkin Elmer Lambda 19 UV/VIS/NIR spectrometer with a labsphere RSA-PE 19 reflectance spectroscopy accessory. The coating composition comprises a glass component and a separate and distinct addition of cerium oxide. Preferably, the coating composition comprises from about 0.20% to about 3.0% by weight of the cerium oxide.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: December 21, 1999
    Assignee: Ferro Corporation
    Inventors: William D. Faust, Holger F. Evele
  • Patent number: 5994248
    Abstract: The invention relates to lenses such as aspherical lenses and to a process for their manufacture. According to the invention, the lens is composed of a glass matrix including the constituents below in the following weight proportions:______________________________________ SiO.sub.2 65-85% Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3 0-20% Li.sub.2 O + Na.sub.2 O + K.sub.2 O 3-20% CaO + MgO + BaO 1-15% FeO + Fe.sub.2 O.sub.3 0-0.1%, ______________________________________wherein the K.sub.2 O content is equal to or less than 1% and the BaO content is equal to or less than 1%.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: November 30, 1999
    Assignee: Saint-Gobain Vitrage
    Inventors: Jose Francisco Gandarillas-Lastra, Benoit Trouille
  • Patent number: 5990023
    Abstract: Use is made, for the manufacture of fire-resistant glazings of the G fire-resistance classes, comprising panes made of glass toughened by the thermal route by means of a conventional toughening plant and possessing safety glass properties, of glasses which exhibit a thermal expansion coefficient .alpha..sub.20-300 of between 6 and 8.5.times.10.sup.-6 K.sup.-1, a thermal stress factor .phi. of between 0.5 and 0.8N/(mm.sup.2.K), a softening point of between 750 and 830.degree. C. and a transformation point of at the very most 1190.degree. C.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: November 23, 1999
    Assignee: Vetrotech Saint-Gobain International AG
    Inventors: Horst Siedel, Claude Morin, Pierre Jeanvoine
  • Patent number: 5985473
    Abstract: A barium/lead-free ceramic glaze includes by weight:(i) between about 44 and 50% SiO.sub.2 ;(ii) between about 7 and 13% Al.sub.2 O.sub.3 ;(iii) between about 22 and 26% B.sub.2 O.sub.3 ;(iv) between about 3 and 9% CaO;(v) between about 1 and 3% SrO;(vi) up to about 2% ZnO;(vii) between about 2 and 4% K.sub.2 O;(viii) up to about 2% Li.sub.2 O; and(ix) between about 5 and 9% Na.sub.2 O.This barium/lead-free glaze can be effectually applied to a ceramic substrate at firing temperatures on the order of 1550 to 1650.degree. F. (843 to 899.degree. C.).
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: November 16, 1999
    Assignee: Cooper Automotive Products, Inc.
    Inventor: Randy Owen Knapp
  • Patent number: 5981414
    Abstract: Described is an inorganic fiber comprising silica dioxide, calcium oxide, and alkali oxide having a free energy of hydration greater than (more positive than) -5.00 kcal/mol, an enthalpy of formation less than (more than negative than) -210.0 kcal/mol, a dissolution rate in simulated extra cellular fluid greater than 750 (calculated as nanograms of fiber/per square centimeter of fiber surface area/per hour) having an average fiber diameter not greater than 4.5 micrometers. Also described is a method of manufacturing the fibers.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: November 9, 1999
    Assignee: Johns Manville International, Inc.
    Inventors: Jon Frederick Bauer, Kevin Dean Schaal
  • Patent number: 5981412
    Abstract: A bioactive ceramic composition including 47 to 51% SiO.sub.2, 23 to 25% CaO, 23 to 25% Na.sub.2 O and 0 to 6% P.sub.2 O.sub.5, the bioactive ceramic having a bioacitivity level such that the composition forms at least a thin layer of HCA within about 30 hours of implantation into a patient. The bioactive ceramic composition having a crystallinity of 34 to 60 volume percent and a crystalline phase of 1Na.sub.2 O.2CaO.3SiO.sub.2.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: November 9, 1999
    Assignee: University of Florida Research Foundation
    Inventors: Larry L. Hench, Guy La Torre, Oscar P. Filho, Edgar Zanotto
  • Patent number: 5977001
    Abstract: The invention relates to a glass composition for electric lamps which glass composition comprises SiO.sub.2, Al.sub.2 O.sub.3, Na.sub.2 O, K.sub.2 O, Li.sub.2 O, B.sub.2 O.sub.3, BaO and SrO and optionally CaO, MgO, ZnO, P.sub.2 O.sub.5, Sb.sub.2 O.sub.3, TiO.sub.2, MnO.sub.2, Fe.sub.2 O.sub.3 and/or CeO.sub.2. The composition according to the invention has a B.sub.2 O.sub.3 content of 1 to 2.8 mass %, a SrO content of 2.1 to 4.5 mass %, a BaO content of 3 to 6 mass % and of the components being present optionally, the amount of CaO is maximum 1 mass %, that of MgO is maximum 2.4 mass % and that of ZnO is maximum 3 mass %, on the condition that the total amount of SrO and B.sub.2 O.sub.3 is at least 3.6 mass %, the total amount of CaO and MgO is maximum 2.4 mass % and the total amount of MgO and ZnO is maximum 4.5 mass %.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: November 2, 1999
    Assignee: General Electric Company
    Inventors: Zoltan Kamill Suha, Zsuzsanna Klara Varga, Zoltan Laszlo Bako
  • Patent number: 5961883
    Abstract: A glass material is provided which is capable of exhibiting fluorescence in the visible region by ultraviolet ray excitation. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %):______________________________________ SiO.sub.2 2 to 60%, B.sub.2 O.sub.3 5 to 70% (SiO.sub.2 + B.sub.2 O.sub.3 = 50 to 70%) RO 5 to 30% (R: at least one atom selected from Mg, Ca, Sr and Ba) ZnO 0 to 15% ZrO.sub.2 0 to 10%, Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3 2 to 15% (containing either of Tb.sub.2 O.sub.3 or Eu.sub.2 O.sub.3) Ln.sub.2 O.sub.3 0 to 20% (Ln: at least one atom selected from Y, La, Gd, Yb, Lu, Sm, Dy and Tm) CeO.sub.2 0 to 1% Bi.sub.2 O.sub.3 0 to 2% Sb.sub.2 O.sub.3 0.01 to 0.5% and R'.sub.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: October 5, 1999
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Masaaki Otsuka, Hideaki Takaku, Naruhito Sawanobori
  • Patent number: 5958810
    Abstract: Optical glasses or lenses are described having a refractive index that varies as a function of at least one coordinate, which is made from a starting material with a constant refractive index by ion exchange. Greater index gradients than with the prior art are achieved by special compositions and ion exchange baths intended therefor. In addition, the stability of the glasses is increased.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: September 28, 1999
    Assignee: Optische Werke G. Rodenstock
    Inventors: Werner Mohr, Boris Goldenfang, Vladimir Il'Lin, Vladislav Lifschitz, Nikolai Remizov
  • Patent number: 5958363
    Abstract: Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The containment vessel is enclosed within an aqueous atmosphere that is above the supercritical temperature and pressure of the solvent of the metal alkoxide solution.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: September 28, 1999
    Assignee: The Regents of the University of California
    Inventor: Paul R. Coronado
  • Patent number: 5958812
    Abstract: This invention concerns a thermally stable glass composition, which comprises the following constituents in the following proportions by weight:______________________________________ SiO.sub.2 45 to 68% Al.sub.2 O.sub.3 0 to 20% ZrO.sub.2 0 to 20% B.sub.2 O.sub.3 0 to 10% Na.sub.2 O 2 to 12% K.sub.2 O 3.5 to 9% CaO 1 to 13% MgO 0 to 8% ______________________________________the sum of the contents of the oxides SiO.sub.2, Al.sub.2 O.sub.3 and ZrO.sub.2 remaining equal to or less than 70%, the sum of the oxides Al.sub.2 O.sub.3 and ZrO.sub.2 being equal to or greater than 2%, the sum of the alkaline oxides Na.sub.2 O and K.sub.2 O being equal to or greater than 8%, said composition comprising, if desired, the oxides BaO and/or SrO in proportions such that:11%.ltoreq.MgO+CaO--BaO+SrO>30%This glass composition may be used for the production of substrates for an emissive screen or for that of a fire-resistant pane.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: September 28, 1999
    Assignee: Saint-Gobain Vitrage
    Inventors: Stephanie Koch, Didier Jousse, Rene Gy, Gilles Courtemanche
  • Patent number: 5945360
    Abstract: Glass compositions suitable for pot and marble fiberization display excellent chemical resistance to both acids and moisture while being highly biosoluble at the same time. The glass compositions are characterized by ratios of components which are reflective of acid resistance, biosolubility, and moisture resistance. Preferred glasses have a difference between HTV (10.sup.3 poise) and liquidus greater than 500.degree. F., and a biodissolution greater than about 350 ng/cm.sup.2 /hr.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: August 31, 1999
    Assignee: Johns Manville International, Inc.
    Inventors: Foster Laverne Harding, Jon Frederick Bauer, Harry Hand Russell, III, Xiaojie Xu
  • Patent number: 5925583
    Abstract: A heat-resistant glass composition which comprises, in % by weight; 56 to 68% of SiO.sub.2, 0.2 to 5% of Al.sub.2 O.sub.3, 0 to 6.4% of ZrO.sub.2, 0 to 0.5% of Li.sub.2 O, 0.2 to 8% of Na.sub.2 O, 2.5 to 14% of K.sub.2 O, 1 to 7% of MgO, 2 to 12% of CaO, 0 to 12% of SrO, 0 to 13% of BaO, 0 to 2% of ZnO, 0 to 1% in total of SO.sub.3 and Sb.sub.2 O.sub.3, and 0 to 3% of TiO.sub.2, with the proviso of the total amount of Na.sub.2 O and K.sub.2 O being 7 to 17%, the total amount of MgO and CaO being 7 to 15%, the total amount of SrO and BaO being 4 to 18%, the total amount of MgO, CaO, SrO, and BaO being 15 to 27%, and the total amount of SiO.sub.2, Al.sub.2 O.sub.3, and ZrO.sub.2 being 58% or more, and which has an average thermal expansion coefficient of 75.times.10.sup.-7 to 100.times.10.sup.-7 /K at 50 to 350.degree. C. and a strain point of 530.degree. C. or more.
    Type: Grant
    Filed: September 11, 1997
    Date of Patent: July 20, 1999
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Tetsuro Yoshii, Akihiro Koyama, Hiroyuki Tanaka, Nobuyuki Yamamoto, Shigekazu Yoshii
  • Patent number: 5925582
    Abstract: A novel type of glass having a low sodium content (<0.1 wt. % Na.sub.2 O), which can be used as a bulb glass (10) for "TL" lamps and for compact fluorescent lamps. Said glass is free of the toxic and/or corrosive components PbO, F, As.sub.2 0.sub.3 and Sb.sub.2 0.sub.3. Apart from favorable properties as regards phosphor poisoning and mercury absorption, resulting in a favorable maintenance of the lamp, said glass is characterized by a wide working range W.R. (=T.sub.work -T.sub.soft), so that glass tubing can be readily made of said glass. By virtue of the low liquidus temperature (T.sub.liq), the glass can be drawn into glass tubing which is free of crystals.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: July 20, 1999
    Assignee: U.S. Philips Corporation
    Inventors: Bartholomeus Filmer, Gerardus H.A.M. Van Der Steen
  • Patent number: 5914356
    Abstract: Novel fillers comprising combeite glass-ceramic are provided, along with filled polymerizable resin composites. Further provided are methods for making the combeite crystallite-containing novel fillers for use in hardenable, biocompatible bone restorations. Hard, shaped bodies or orthopaedic, dental and other uses are also provided.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: June 22, 1999
    Assignee: Orthovita, Inc.
    Inventor: Erik M. Erbe
  • Patent number: 5908794
    Abstract: A glass composition for a substrate consisting essentially of from 56 to 72 wt % of SiO.sub.2, from 1 to less than 14 wt % of Al.sub.2 O.sub.3, from 0 to 9 wt % of MgO, from 0.5 to 11 wt % of CaO, from 0 to 4 wt % of SrO, from 0 to 3 wt % of BaO, from 6 to less than 14 wt % of MgO+CaO+SrO+BaO, from 0 to 9 wt % of Na.sub.2 O, from 6 to 20 wt % of K.sub.2 O, and from 6 to 20 wt % of Na.sub.2 O+K.sub.2 O.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: June 1, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Kei Maeda, Hitoshi Onoda, Yasumasa Nakao, Jeetendra Sehgal
  • Patent number: 5900296
    Abstract: A glass substrate for magnetic disks, obtained by chemical strengthening treatment of a glass consisting essentially of from 50 to 65 wt % of SiO.sub.2, from 5 to 15 wt % of Al.sub.2 O.sub.3, from 2 to 7 wt % of Na.sub.2 O, from 4 to 9 wt % of K.sub.2 O, from 7 to 14 wt % of Na.sub.2 O+K.sub.2 O, from 12 to 25 wt % of MgO+CaO+SrO+BaO, and from 1 to 6 wt % of ZrO.sub.2.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: May 4, 1999
    Assignee: AG Technology Co., Ltd.
    Inventors: Ichiro Hayashi, Kei Maeda, Kazuo Mannami
  • Patent number: 5900052
    Abstract: There is provided a belt coating material for a belt type continuous casting, which is capable of adsorbing the intermediate between a cast slab and the coating material to prevent the intermediate from remaining on the slab, and reducing the averaged heat flux during the casting to avoid an occurrence of cracking in a medium carbon steel. The belt coating material comprises: (1) a powder having a composition comprising 10 to 40 weight % of SiO.sub.2, 1 to 10 weight % of Al.sub.2 O.sub.3, 10 to 40 weight % of CaO, 10 to 30 weight % of Na.sub.2 O, 1 to 10 weight % of MgO, 10 to 20 weight % of F, and 1 to 5 weight % of LiO.sub.2, the powder being prepared by once melting the blended components, solidifying the melt, and crushing it into the powder to adjust the average grain diameter of the powder to be equal to or smaller than 10 .mu.m; (2) 0.1 to 10 weight % of graphite mixed into the powder to provide a mixture, the graphite having the same grain diameter with the powder; and (3) 0.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: May 4, 1999
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Hiroshi Nakajima, Kouichi Hirata, Hironori Fujioka
  • Patent number: 5900380
    Abstract: A conductive glass lining composition includes 100 parts by weight of a frit and 0.05 to 1.5 parts by weight of a metal fibers of 0.1 to 30 .mu.m in diameter, 1.5 to 10 mm in length and a length-to-diameter ratio of not less than 50.
    Type: Grant
    Filed: July 15, 1997
    Date of Patent: May 4, 1999
    Assignee: Ikebukuro Horo Kogyo Co., Ltd.
    Inventors: Yoshihiro Iizawa, Mitsuru Akazawa
  • Patent number: 5897678
    Abstract: The invention provides a method by which a crystal glass composition which employs TiO.sub.2 as a raw material substituted for PbO can be produced while effectively preventing development of a yellowish color of the glass composition which is caused by TiO.sub.2. In the production method, to a batch composition which is composed of 50 to 60 percent by weight of SiO.sub.2, 4 to 14 percent by weight of K.sub.2 O, 10 to 20 percent by weight of BaO and 3 to 10 percent by weight of TiO.sub.2, NaNO.sub.3 (sodium nitrate) is added by 1.0 to 5.0 percent by weight or BaO.sub.2 (barium peroxide) is added by 0.3 to 2.0 percent by weight for elimination of development of a color which arises from the 3 to 10 percent by weight of TiO.sub.2, and also one of Sb.sub.2 O.sub.3 (antimony oxide) and As.sub.2 O.sub.3 (arsenious acid) is added by 0.2 to 1.0 percent by weight for defoaming. Instead, NaSb(OH).sub.6 (sodium antimonate) having color development elimination and defoaming actions may be added by 0.5 to 2.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: April 27, 1999
    Assignee: Toyo Glass Company Limited
    Inventors: Hidetoshi Komiya, Shizue Inaba
  • Patent number: 5897956
    Abstract: Glass having low solar radiation and ultraviolet ray transmittance, which consists essentially of a soda lime-silica type matrix glass containing from 0.53 to 0.70 wt % of total iron calculated as Fe.sub.2 O.sub.3, from 0.2 to 0.4 wt % of TiO.sub.2 and from 0.5 to 0.8 wt % of total cerium calculated as CeO.sub.2, wherein the weight of FeO calculated as Fe.sub.2 O.sub.3 is from 30 to 40% of the weight of the total iron calculated as Fe.sub.2 O.sub.3.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: April 27, 1999
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takashi Kijima, Toru Kudo, Mizuki Ito, Fumio Kamei, Akira Kondo