And Rare Earth (i.e., Elements With Atomic Number 39 Or 57-71) Patents (Class 501/78)
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Publication number: 20080261797Abstract: The optical glass for press molding of the present invention contains 35 to 45% by weight of SiO2, 15 to 30% by weight of B2O3, and 18 to 33% by weight of CaO so that the total amount is 75 to 96% by weight. Also, the glass has an index of refraction (nd) of 1.55 to 1.63, an optical constant value ranging from 55 to 63 by the Abbe number (?d), a specific gravity of not more than 2.75, and a glass transition temperature (Tg) of not more than 550° C. According to the present invention, it is possible to provide inexpensive optical glass for press molding which exerts intended optical performance while realizing further reduction in size and weight of optical devices.Type: ApplicationFiled: December 28, 2007Publication date: October 23, 2008Inventors: Takashi Tsutsumi, Risa Suzuki
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Publication number: 20080254965Abstract: Glass has optical constants of a refractive index (nd) of 1.79 or over and an Abbe number (?d) of 27 or over and a specific gravity (D) of 3.20 or over and is free from devitrification in the interior of the glass in a reheat test. The glass has chemical durability according to the Powder Method (acid-proof property RA according to the Powder Method) which is Class 1.Type: ApplicationFiled: January 12, 2006Publication date: October 16, 2008Applicant: KABUSHIKI KAISHA OHARAInventor: Junko Ishioka
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Publication number: 20080220961Abstract: An optical glass having refractive index (nd) exceeding 1.85, Abbe number (?d) of 36 or over, comprising SiO2, B2O3, La2O3, Gd2O3, Ta2O5 and Li2O as essential components, being free of Pb and As components, and having glass transition temperature (Tg) of 630° C. or below.Type: ApplicationFiled: May 31, 2005Publication date: September 11, 2008Applicant: OHARA, INC.Inventors: Susumu Uehara, Koji Shimizu
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Publication number: 20080207429Abstract: An optical glass for press-molding contains as glass ingredients, by weight: 0.5-4% SiO2; 20-30% B2O3; 10-20% ZnO; 1-10% ZrO2; 30-45% La2O3; 5-12% Nb2O5; 1-15% WO3; 0.5-3.5% TiO2; 0.5-3% CaO; 0.1-0.5% Li2O; 0-0.4% Na2O (zero inclusive); and 0-0.4% K2O (zero inclusive), with the total content of Li2O+Na2O+K2O accounting for 0.1-0.5%.Type: ApplicationFiled: February 19, 2008Publication date: August 28, 2008Applicant: Konica Minolta Opto, Inc.Inventor: Manabu IZUKI
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Publication number: 20080207427Abstract: The object of the present invention is to provide an optical glass which has optical constants such as a refractive index of from 1.45 to 1.65 and an Abbe number of at least 65 and which is yet excellent in chemical durability. A phosphate optical glass comprising, as glass components by mass %, from 73 to 85 of P2O5, from 14 to 26 of Al2O3, from 1 to 12 of K2O+Li2O, from 0 to 12 of SiO2, from 0 to 12 of B2O3, from 0 to 12 of Na2O, from 0 to 12 of Y2O3, from 0 to 12 of La2O3, from 0 to 12 of MgO+CaO+SrO+BaO, from 0 to 10 of ZrO2+TiO2+Gd2O3, from 0 to 10 of Ta2O5+GeO2+Ga2O3+Nb2O5+WO3+TeO2, from 0 to 2 of Sb2O3, and from 0 to 12 of ZnO+PbO.Type: ApplicationFiled: April 28, 2008Publication date: August 28, 2008Applicant: Asahi Glass Company, LimitedInventors: Hiroyuki Ohkawa, Naoki Sugimoto
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Publication number: 20080194395Abstract: An optical glass whose refractive index is high and whose coloring is decreased comprising, by weight %, 2 to 45% of B2O3, 0 to 30% of SiO2 provided that the content of B2O3>the content of SiO2, 10 to 50% of La2O3, 0 to 30 % of TiO2, 0 to 15% of ZnO, 0 to 15% of ZrO2, 0 to 35% of Nb2O5, 0 to 35% of BaO, 0 to 5% of SrO, 0% or more but less than 8% of CaO, 0% or more but less than 13% of MgO, provided that the total content of BaO, SrO, CaO and MgO is 0 to 40%, 0 to 20% of Gd2O3, 0 to 15% of Y2O3, 0 to 18% of Ta2O5, 0% or more but less than 0.5% of WO3, 0% or more but less than 1.5% of a total of Na2O, K2O and Li2O, 0 to 10% of GeO2, 0 to 20% of Bi2O3, 0 to 10% of Yb2O3, 0 to 10% of Al2O3, 0% or more but less than 2% of Sb2O3 and 0 to 1% of SnO2.Type: ApplicationFiled: April 9, 2008Publication date: August 14, 2008Applicant: HOYA CORPORATIONInventor: Michio Endo
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Publication number: 20080188368Abstract: An optical glass includes, in percent by weight, 2-11% SiO2, 28-45% B2O3, 2-15% CaO, 3-18% ZnO, 1-8% ZrO2, 9-40% La2O3, 0.5-11% Gd2O3, 0-10% Y2O3, 0-3% Al2O3, at most 8% R2O, where R2O is selected from the group consisting of Li2O, Na2O and K2O, at most 20% R?O, where R?O is selected from the group consisting of MgO, CaO, SrO and BaO, 0-3% WO3, 0-2% Nb2O5, and 0-1% Sb2O3. The optical glass is free from environmental and human harmful components such as PbO and As2O3. The optical glass has a refractive index in the range of 1.66-1.72, an Abbe number in the range of 51-56, a liquidus temperature (LT) of at most 1000° C. and a raw material melting temperature of at most 1300° C. The optical glass is suitable for mass production, and is stable against devitrification during manufacturing of preforms and precision molding of lenses.Type: ApplicationFiled: February 1, 2008Publication date: August 7, 2008Applicant: Asia Optical Co., IncInventors: Tsung-yuen Tsai, Hsiang-jen Shih
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Patent number: 7407902Abstract: A Bismuth glass composition including 0.5 to 14 wt % of SiO2, 3 to 15 wt % of B2O3, 4 to 22 wt % of ZnO, 55 to 90 wt % of Bi2O3 and 4 wt % or less of Al2O3, and further including 5 wt % or less of an oxide of Group A, 12 wt % or less of an oxide of Group B and 0.1 to 10 wt % of an oxide of Group C, wherein the oxide of Group A is at least one selected from the group consisting of Li2O, Na2O and K2O, the oxide of Group B is at least one selected from the group consisting of MgO, CaO, SrO and BaO, and the oxide of Group C is at least one selected from the group consisting of Sc2O3, Y2O3, La2O3, CeO2, Pr2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, Tb2O3, Dy2O3, Ho2O3, Er2O3, Tm2O3, Yb2O3 and Lu2O3.Type: GrantFiled: March 28, 2003Date of Patent: August 5, 2008Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shinya Hasegawa, Hiroshi Onishi, Mikie Kanai, Tetsuya Kamimoto
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Publication number: 20080176733Abstract: An optical glass contains as glass ingredients, by weight: 10-35% SiO2; 8-30% B2O3; 4-9% Li2O; 26-40% ZnO; 1-25% La2O3; and 6-22% Nb2O5.Type: ApplicationFiled: January 22, 2008Publication date: July 24, 2008Inventor: Akio Oogaki
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Publication number: 20080176734Abstract: An optical glass contains as glass ingredients, by weight: 0-8% SiO2; 34.5-46% B2O3; 2.6-6% Li2O; 21-38% ZnO; 0-40% La2O3; 0-35% Gd2O3; and 0-15% Y2O3, with the total content of La2O3+Gd2O3+Y2O3 accounting for 10-40%. The optical glass also has a predetermined index of refraction and a predetermined dispersion.Type: ApplicationFiled: January 22, 2008Publication date: July 24, 2008Inventor: Akio Oogaki
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Publication number: 20080167172Abstract: Provided is an optical glass having high-refractivity low-dispersion properties, having a low glass transition temperature and having the property of being softened at a low temperature so that a preform therefrom is precision press-moldable, and the optical glass comprises, as essential components, B2O3, La2O3, Gd2O3 and ZnO and has a refractive index (nd) of over 1.86, an Abbe's number (vd) of less than 35 and a glass transition temperature (Tg) of 630° C. or lower.Type: ApplicationFiled: January 7, 2008Publication date: July 10, 2008Applicant: HOYA CORPORATIONInventor: Kazutaka Hayashi
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Publication number: 20080139376Abstract: An optical glass for the manufacture of large transmission optics, such as lenses having a thickness of 100 millimeters or more, comprises 35 to 70 wt.-% SiO2, 17 to 35 wt.-% Al2O3, 3 to 17 wt.-% P2O5, 0 to 6 wt.-% Li2O, 0.5 to 4 wt.-% MgO, 0.5 to 3 wt.-% ZnO, a maximum of 1 wt.-% CaO, a maximum of 0.5 wt. % BaO, 0.5 to 6 wt.-% TiO2, 0.5 to 3 wt.-% ZrO2, 0 to 1 wt.-% Na2O, 0 to 1 wt.-% K2O, a maximum of 1 wt.-% of refining agents (As2O3, SP2O3) and a maximum of 500 ppm of other contaminants. The glass composition may be equal to the composition of the glass ceramic Zerodur® and allows to manufacture large transmission optics in a cost-effective way, has a maximum of transmittance which is in the range of a He—Ne lasers and has a CTE of about 3·10?6/K.Type: ApplicationFiled: December 5, 2007Publication date: June 12, 2008Inventors: Thorsten Doehring, Ina Mitra
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Patent number: 7368404Abstract: An optical glass having a refractive index (nd) and Abbe number (?d) within a range enclosed with a border line consisting of straight lines connecting point A (nd being 1.75 and ?d being 50.0), point B (nd being 1.80 and ?d being 46.0), point C (nd being 1.80 and ?d being 50.0) and point D (nd being 1.75 and ?d being 56.0) in the order of the point A, the point B, the point C, the point D and the point A in x-y rectangular coordinates in which x coordinate represents Abbe number (?d) and y coordinate represents refractive index (nd), including refractive index (nd) and Abbe number (?d) on the border line except for the straight line connecting the point A with the point D and the straight line connecting the point B with the point C, containing, as essential components, SiO2, B2O3, La2O3, Gd2O3, Li2O and F, and being substantially free of As2O3.Type: GrantFiled: October 26, 2004Date of Patent: May 6, 2008Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Patent number: 7351675Abstract: An optical glass taking account of meltability and the moldability of a preform, having optical constants including a refractive index (nd) of at least 1.57 but less than 1.67 and an Abbe's number (?d) of over 55 but not more than 65, having the property of softening at a low temperature and being suitable as a glass for precision press-molding, the optical glass including an optical glass containing B2O3, SiO2, La2O3, Gd2O3, an alkali metal oxide and an alkaline earth metal oxide as essential components, having a B2O3 and SiO2 total content of 52% by weight or more and having an SiO2/B2O3 content ratio of from 0.38 to 1.2, and an optical glass wherein the relationship of the refractive index (nd) and the Abbe's number (?d) satisfies the equation (1), ?d>260?126×nd.Type: GrantFiled: January 21, 2005Date of Patent: April 1, 2008Assignee: Hoya CorporationInventors: Yoshiko Kasuga, Xuelu Zou
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Patent number: 7341965Abstract: The invention relates to bismuth oxide glass, containing germanium oxide, a method for the production thereof, the use thereof and a glass fiber consisting of said inventive glass.Type: GrantFiled: September 7, 2002Date of Patent: March 11, 2008Assignee: Schott AGInventors: Bianca Schreder, Ruediger Sprengard, Ulrich Peuchert, Martin Letz, Joseph S. Hayden, Sally Pucilowski
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Patent number: 7335614Abstract: An optical glass having a refractive index (nd) and an Abbe number (vd) which are within an area surrounded by the straight lines which are drawn by connecting point A (nd=1.835, vd=46.5), point B (nd=1.90, vd=40.0), point C (nd=1.90, vd=35.0) and point D (nd=1.835, vd=38.0) in a sequence of A, B, C, D and A as border lines in x-y coordinates shown in FIG. 1, in which X-axis is the Abbe number (vd) and Y-axis is the refractive index (nd), the area including the border line. The optical glass has low glass transition temperature (Tg), and suitable for precision mold pressing.Type: GrantFiled: June 12, 2006Date of Patent: February 26, 2008Assignee: Kabushiki Kaisha OharaInventors: Susumu Uehara, Koji Shimizu, Shinya Mashiko
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Patent number: 7332453Abstract: Ceramics (including glasses and glass-ceramics) comprising nitrogen, and methods of making the same.Type: GrantFiled: July 29, 2004Date of Patent: February 19, 2008Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Berkan K. Endres, Thomas J. Anderson
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Patent number: 7332864Abstract: A plasma display panel is able to contrast thereof by increasing a color temperature of the plasma display panel, which comprises a dielectric layer controlling a light transmittance for visible light of a certain wavelength emitted from a phosphor in the plasma display panel.Type: GrantFiled: January 24, 2007Date of Patent: February 19, 2008Assignee: LG Electronics Inc.Inventor: Myeong Soo Chang
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Publication number: 20080035887Abstract: A wavelength-converting member with high emission intensity and that is superior in weather resistance and reliability is obtained. There is provided a phosphor on which a cleaning treatment and/or a coating treatment are/is performed is contained in a glass material having a composition of SiO2: 30 to 50%, Li2O: 0 to 15%, Na2O: 0 to 10%, K2O 0 to 10%, Li2O+Na2O+K2O: 20 to 30%, B2O3:5 to 15%. MgO: 0 to 10%, BaO: 0 to 10% , CaO: 0 to 10%, SrO: 0 to 10%, Al2O3: 0 to 10%, ZnO: 0 to 15%, TiO2: 10 to 20%, Nb2O5: 1 to 5%, La2O3: 0 to 5%, and TiO2+Nb2O5+La2O3: 11 to 20% by mole percentage.Type: ApplicationFiled: August 2, 2007Publication date: February 14, 2008Inventors: Masaru Iwao, Yoshio Umayahara
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Patent number: 7320949Abstract: An optical glass suitable for precision mold pressing has a refractive index (nd) of 1.88 or over and an Abbe number (? d) within a range from 22 to 28, comprises, in mass %, SiO2 15-25%? B2O3 0-5%? La2O3 0-5%? TiO2 5-15% ZrO2 0-10% Nb2O5 more than 30% and less than 50% WO3 0-5%? CaO 0-10% BaO 0-10% Li2O 3-12% Na2O 0-10% K2O 0-10% Bi2O3 0-15% Ta2O5 0-7%? and has a glass transition point (Tg) within a range from 500° C. to 580° C. The optical glass preferably has a yield point (At) within a range from 550° C. to 640° C.Type: GrantFiled: June 2, 2004Date of Patent: January 22, 2008Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Patent number: 7297647Abstract: The present invention relates to lead and arsenic free optical glasses, used for the application areas imaging, digital projection, photolithography, laser technology, wafer/chip technology as well as telecommunication, optical communications engineering, optics, illumination and in the automotive sector. The glasses have a refraction power of from 1.73?nd?1.82 and an Abbé value of 43?vd?53 with good chemical consistency and excellent crystallisation stability with the following composition (in weight-%): SiO2 0.1-5.5 B2O3 27-35 La2O3 42-48 BaO 0-5 ZnO 0.5-5?? Y2O3 ?6-12 TiO2 0-4 ZrO2 ?4-10 Nb2O5 0-5 WO3 ?0-5.Type: GrantFiled: February 28, 2005Date of Patent: November 20, 2007Assignee: Schott AGInventors: Silke Wolff, Karl Mennemann, Ute Woelfel
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Patent number: 7291571Abstract: The invention relates to crystallizable aluminosilicate magnesium-containing glass which is used for producing extremely solid and break-resistant glass-ceramics having an easily polished surface. The inventive crystallizable glass contains 5-33 mass % of SiO2, 25-40 mass % of Al2O3, 5-25 mass % of MgO, 0-15 mass % of B2O3, 0.1-30 mass % of Y2O3, Ln2O3, As2O3 and/or Nb2O5 and 0.1-10 mass % of P2O5.Type: GrantFiled: September 26, 2003Date of Patent: November 6, 2007Assignee: Schott AGInventors: Dirk Sprenger, Thilo Zachau, Rainer Liebald
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Patent number: 7262144Abstract: The invention relates to a photostructurable body, in particular glass or glass-ceramic, in which the glass is a multicomponent glass and/or the glass-ceramic is a multicomponent glass-ceramic, in each case having a positive change in refractive index ?n as a result of the action of light.Type: GrantFiled: February 3, 2004Date of Patent: August 28, 2007Assignee: Schott AGInventors: Bianca Schreder, Josè Zimmer, Matthias Brinkmann, Michael Kluge
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Patent number: 7253559Abstract: A plasma display panel is able to contrast thereof by increasing a color temperature of the plasma display panel, which comprises a dielectric layer controlling a light transmittance for visible light of a certain wavelength emitted from a phosphor in the plasma display panel.Type: GrantFiled: September 13, 2002Date of Patent: August 7, 2007Assignee: LG Electronics, Inc.Inventor: Myeong Soo Chang
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Publication number: 20070179038Abstract: An optical glass has optical constants of a refractive index (nd) within a range from 1.73 to less than 1.80 and an Abbe number (?d) within a range from 43 to 55, comprises SiO2, B2O3, Y2O3, La2O3, ZnO and Li2O as essential components, is substantially free of lead component, arsenic component and fluorine component, has a ratio of SiO2/B2O3 of 0.30 to 1.55 and a ratio of Y2O3/La2O3 of 0.15 to 1.00, and has a glass transition temperature (Tg) of 620° C. or below.Type: ApplicationFiled: January 31, 2007Publication date: August 2, 2007Applicant: OHARA INC.Inventor: Susumu UEHARA
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Publication number: 20070149381Abstract: The invention relates to optical glasses intended for the application fields of imaging, sensors, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, and for telecommunication, optical communication engineering and optics/lighting in the automotive sector, having a refractive index of 1.60?nd?1.80 and/or an Abbe number of 30??d?40 with a pronounced short flint character, good chemical stability, excellent crystallization stability, good solarization stability and the following composition (in wt. % based on oxide): SiO2 19–45 B2O3 ??3–7.5 Nb2O5 25–31 K2O 2–8 TiO2 0.1–2?? ZrO2 ?6–10 Ta2O5 0.Type: ApplicationFiled: December 8, 2006Publication date: June 28, 2007Inventors: Silke Wolff, Goran Sabljic, Ute Woelfel
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Patent number: 7138349Abstract: An optical glass having a refractive index (nd) and an Abbe number (vd) which are within an area surrounded by the straight lines which are drawn by connecting point A (nd=1.835, vd=46.5), point B (nd=1.90, vd=40.0), point C, (nd=1.90, vd=35.0) and point D (nd=1.835, vd=38.0) in a sequence of A, B, C, D and A as border lines in x-y coordinates shown in FIG. 1, in which X-axis is the Abbe number (vd) and Y-axis is the refractive index (nd), the area including the border line. The optical glass has low glass transition temperature (Tg), and suitable for precision mold pressing. The optical glass which has the refractive index (nd) and Abbe number (vd) within the above-described area, where the area includes the border lines, has the composition of SiO2—B2O3—La2O3—Gd2O3—Li2O—F system, the transition temperature (Tg) of 550 to 650° C., and is free from lead, cadmium, thorium, Y2O3, P2O5 and TeO2.Type: GrantFiled: December 12, 2003Date of Patent: November 21, 2006Assignee: Kabushiki Kaisha OharaInventors: Susumu Uehara, Koji Shimizu, Shinya Mashiko
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Patent number: 7138348Abstract: An optical glass has optical constants which are an refractive index (nd) of 1.70–1.75 and an Abbe number (vd) of 45.0–54.0; a glass transformation temperature (Tg) of 500–580° C. The glass has the following composition in mass percent of: SiO2 more than 5–15%; B2O3 20-less than 30%; a total amount of SiO2+B2O3 more than 25–40%; La2O3 more than 21-less than 30%; Y2O3 more than 5–15%; Gd2O3 0-less than 10%; ZrO2 1–8%; Nb2O5 0.1–5%; Ta2O5 more than 5–12%; a total amount of ZrO2+Nb2O5+Ta2O5 7–20%; ZnO 0–10%; CaO 0–10%; SrO 0–5%; BaO 0–10%; a total amount of ZnO+CaO+SrO+BaO 5–15%; Li2O 1–8%; Sb2O3 0–1%; and As2O3 0–1%. The glass is substantially free of Yb2O3 and Al2O3. Devitrification is not generated when the optical glass is kept at a temperature of 920° C. for two hours.Type: GrantFiled: December 10, 2003Date of Patent: November 21, 2006Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Patent number: 7098158Abstract: A glass for press molding, containing substantially no lead, consisting substantially of, as represented by mol % based on oxides: Bi2O3 25 to 70%, B2O3 + SiO2 ?5 to 75%, CeO2 ?0 to 10%, Al2O3 ?0 to 20%, Ga2O3 ?0 to 20%, Al2O3 + Ga2O3 ?0 to 30%, and ZnO + TeO2 + BaO + WO3 ?0 to 40%, and having a refractive index of at least 1.9 to a light having a wavelength of 0.8 ?m.Type: GrantFiled: April 22, 2003Date of Patent: August 29, 2006Assignee: Asahi Glass Company, LimitedInventors: Norio Natsugari, Koichi Murata
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Patent number: 7091145Abstract: The lead-free and arsenic-free optical glass has a refractive index nd of 1.84?nd?1.96 and an Abbé number ?d of 27??d?36, with good chemical resistance, excellent crystallization resistance and the following composition (in % by weight based on oxide): SiO2, 1 to 8, B2O3, 13 to 19.5, La2O3, 34 to 50; MgO, 0 to 6, CaO, 0 to 6, BaO, 0 to 6, ZnO, 0 to 9 with ?MO, 1 to 10; and TiO2, 4 to 15, ZrO2, 0 to 11, Nb2O5, 6 to 14.5. In addition, the glass according to the invention, as well as having a maximum alkali metal oxide content of 10% by weight, may also contain standard refining agents other than arsenic. The glass according to the invention is used in imaging, projection, telecommunications, optical communication and/or laser technology.Type: GrantFiled: June 16, 2003Date of Patent: August 15, 2006Assignee: Schott AGInventors: Silke Wolff, Ute Woelfel
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Patent number: 7074732Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number ?d of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38–58, ZnO 0.3–42, PbO 0–<30, ZnO+PbO 20–55, Li2O 0–<3, Na2O 0–14, K2O 0–12, Li2O+Na2O+K2O ?2, F 0–3, MgO 0–6, CaO 0–<5, SrO 0–6, BaO 0–<0.9, B2O3 0–<1, Al2O3 0–<1.5 and ZrO2 0–<2 and, if appropriate, refining agents in the customary amounts.Type: GrantFiled: October 15, 2004Date of Patent: July 11, 2006Assignee: Schott GlasInventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
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Patent number: 7005187Abstract: Glass for a light filter capable of preventing variation of refractive index in a band-pass filter has a coefficient of thermal expansion within a range from 90×10?7/° C. within a temperature range from ?20° C. to +70° C. and, preferably, Young's modulus of 75 GPa or over and Vickers hardness of 550 or over, and light transmittance for plate thickness of 10 mm of 90% or over within a wavelength range from 950 nm to 1600 nm.Type: GrantFiled: October 10, 2001Date of Patent: February 28, 2006Assignee: Kabushiki Kaisha OharaInventor: Naoyuki Goto
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6936556Abstract: The present invention provides partially crystallizing lead-free and cadmium-free glass enamel composition that fuse at low temperatures. Glass enamel compositions according to the present invention form predominantly bismuth titanate and optionally zinc titanate crystals upon firing. Preferably, glass enamel compositions according to the invention include a glass component that includes by weight from about 11% to about 52% SiO2, from 10.2% to about 40% TiO2, from about 5% to about 75% Bi2O3, up to about 8% B2O3, up to about 14% BaO+SrO, and up to about 45% by weight ZnO, where the sum of Bi2O3 and ZnO comprises from about 30% to about 85% of the glass component by weight.Type: GrantFiled: April 7, 2003Date of Patent: August 30, 2005Assignee: Ferro CorporationInventors: Srinivasan Sridharan, George C. Korn, Jérôme Anquetil, Robert Blonski, Ivan H. Joyce
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Patent number: 6911160Abstract: A high-gain phosphate glass composition, which can be used to produce ultra-short gain length lasers and optical amplifiers is described wherein the composition of the glass in addition to exhibiting high gain for lasers and amplifiers, also exhibits high thermal shock resistance, high cross section, insignificant concentration quenching, and high solubility for rare earth ions and other properties which enable the material to be fabricated into a new class of ultra-short length micro-laser, fiber laser and amplifier configurations and designs.Type: GrantFiled: March 21, 2003Date of Patent: June 28, 2005Assignee: Kigre, Inc.Inventors: John D. Myers, Michael J. Myers
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Patent number: 6844279Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (?d) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa·s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (?d) of 45 to 55.Type: GrantFiled: February 20, 2002Date of Patent: January 18, 2005Assignee: Hoya CorporationInventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
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Publication number: 20040254057Abstract: The invention relates to bismuth oxide glass, containing germanium oxide, a method for the production thereof, the use thereof and a glass fiber consisting of said inventive glass.Type: ApplicationFiled: March 8, 2004Publication date: December 16, 2004Inventors: Bianca Schreder, Rudiger Sprengard, Ulrich Peuchert, Martin Letz, Joseph s Hayden, Sally Pucilowski
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Publication number: 20040242397Abstract: An optical glass that has a refractive index (nd) of 1.56-1.66, an Abbe number (vd) of 52-63, and a transformation temperature of 420° C.-580° C., as provided by compositions including as essential components (a) SiO2, (b) B2O3, (c) BaO, (d) Y2O3, (e) Li2O, and (f) one or more from CaO, MgO, SrO, and ZnO, and optionally one or more components from (g) Na2O, (h) K2O, (i) Al2O3, and (j) ZrO2.Type: ApplicationFiled: May 21, 2004Publication date: December 2, 2004Applicant: HIKARI GLASS CO., LTD.Inventor: Yoshiyuki Nakayama
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Patent number: 6825142Abstract: The present invention generally relates to an interference filter including a glass substrate, useful in fiber optic systems.Type: GrantFiled: January 7, 2002Date of Patent: November 30, 2004Assignee: Schott Glass Technologies, Inc.Inventors: Sally Pucilowski, David G. Krashkevich
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Publication number: 20040235638Abstract: An optical glass having a refractive index (nd) and an Abbe number (vd) which are within an area surrounded by the straight lines which are drawn by connecting point A (nd=1.835, vd=46.5), point B (nd=1.90, vd=40.0), point C, (nd=1.90, vd=35.0) and point D (nd=1.835, vd=38.0) in a sequence of A, B, C, D and A as border lines in x-y coordinates shown in FIG. 1, in which X-axis is the Abbe number (vd) and Y-axis is the refractive index (nd), the area including the border line. The optical glass has low glass transition temperature (Tg), and suitable for precision mold pressing. The optical glass which has the refractive index (nd) and Abbe number (vd) within the above-described area, where the area includes the border lines, has the composition of SiO2—B2O3—La2O3—Gd2O3—Li2O—F system, the transition temperature (Tg) of 550 to 650° C., and is free from lead, cadmium, thorium, Y2O3, P2O5 and TeO2.Type: ApplicationFiled: December 12, 2003Publication date: November 25, 2004Applicant: KABUSHIKI KAISHA OHARAInventors: Susumu Uehara, Koji Shimizu, Shinya Mashiko
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Patent number: 6818314Abstract: A chemical, thermal, and electrical corrosion resistant dry mix for use in fusing glass to metal motor vehicle and building industry articles. A chemical, thermal, and electrical corrosion resistant composition for fusing glass to metal motor vehicle and building industry articles. A method of glass fusing metal motor vehicle and building industry articles using a chemical, thermal, and electrical corrosion resistant dry mix. A method of glass fusing metal motor vehicle and building industry articles with a chemical, thermal, and electrical corrosion resistant composition. A method of fusing single or multiple layers of glass to metal motor vehicle and building industry articles.Type: GrantFiled: November 20, 2002Date of Patent: November 16, 2004Inventor: Gary D. Wilson
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Patent number: 6818578Abstract: An optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time. The optical glass has a refractive index nd of at least 1.875, an Abbe's number &ngr;d of at least 39.5 and a glass transition point Tg of 700° C. or lower, and contains at least one of La2O3, Gd2O3, Y2O3 or Yb2O3 and at least one of ZrO2, Ta2O5 or Nb2O5, with a weight ratio of the total content of La2O3, Gd2O3, Y2O3 and Yb2O3 to the total content of SiO2 and B2O3 of from 3.2 to 5 and the weight ratio of the total content of ZrO2, Ta2O5 and Nb2O5 to the total content of SiO2 and B2O3 is from 1.1 to 1.5.Type: GrantFiled: May 24, 2001Date of Patent: November 16, 2004Assignee: Hoya CorporationInventor: Kazuo Tachiwama
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Publication number: 20040220041Abstract: There is provided an optical glass that (1) has a high refractive index and high dispersion, (2) does not include any Pb compound that will tend to adversely impact the environment or human bodies, (3) is excellent in terms of economic efficiency, and (4) is suitable for mass production. This optical glass contains SiO2, B2O3, BaO, La2O3, TiO2, and, as necessary, one or more from Nb2O5, Ta2O5, WO3, ZrO2, MgO, CaO, SrO, ZnO, Li2O, Na2O, K2O, Y2O3, Gd2O3, and Al2O3—each in an amount within a predetermined range. This optical glass also has optical constant values such as a refractive index (nd) of 1.70-1.93 and an Abbe number (vd) of 28-45.Type: ApplicationFiled: May 24, 2004Publication date: November 4, 2004Applicant: HIKARI GLASS CO., LTD.Inventors: Jyunichi Isowaki, Akihiro Takishita
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Publication number: 20040220040Abstract: An optical glass suitable for precision mold pressing has a refractive index (nd) of 1.Type: ApplicationFiled: June 2, 2004Publication date: November 4, 2004Inventor: Susumu Uehara
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Patent number: 6806217Abstract: A mold lens glass including B2O3, SiO2, La2O3, ZnO, BaO, and CaO, wherein the components in the composition are present in a weight ratio: of B2O3 (25% to 35% by weight), SiO2 (1% to 7% by weight), wherein the total amount of B2O3 and SiO2 is 30% to 40% by weight. La2O3 is present in an amount of 12% to 20% by weight, and the total amount of ZnO, BaO and CaO is 40% to 55% by weight. By using the mold lens glass of the present invention, it is possible to obtain a mold lens glass having a high refractive index, excellent water resistance, and a stable glassy state.Type: GrantFiled: March 7, 2003Date of Patent: October 19, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shigeo Furukawa, Masahiro Hiraka, Shigeki Yamada, Yoshiki Higashiyama
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Patent number: 6800375Abstract: A chemical, thermal, and electrical corrosion resistant dry mix for use in fusing glass to metal motor vehicle and building industry articles. A chemical, thermal, and electrical corrosion resistant composition for fusing glass to metal motor vehicle and building industry articles. A method of glass fusing metal motor vehicle and building industry articles using a chemical, thermal, and electrical corrosion resistant dry mix. A method of glass fusing metal motor vehicle and building industry articles with a chemical, thermal, and electrical corrosion resistant composition. A method of fusing single or multiple layers of glass to metal motor vehicle and building industry articles.Type: GrantFiled: November 20, 2002Date of Patent: October 5, 2004Inventor: Gary D. Wilson
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Patent number: 6797659Abstract: There is provided an optical glass suitable for precision mold pressing having optical constants of a refractive index (nd) within a range from 1.75 to 1.85 and an Abbe number (&ngr;d) within a range from 35 to 45, comprising in mass % on oxide basis: SiO2 + B2O3 16.5-less than 30% in which SiO2 1-7.5% B2O3 15.5-25% La2O3 25-40% ZrO2 1.5-10% Nb2O5 1-15% Ta2O5 1-10% WO3 1-10% ZnO 15.5-30% Li2O 0.6-5%. having a transition point (Tg) within a range from 500° C. to 590° C. and a yield point (At) within a range from 530° C. to 630° C., and being free from devitrification in a devitrification test conducted under a condition of 950° C./2 hours.Type: GrantFiled: May 31, 2002Date of Patent: September 28, 2004Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Publication number: 20040186003Abstract: There is provided an optical glass suitable for precision mold pressing having optical constants of a refractive index (nd) within a range from 1.75 to 1.85 and an Abbe number (&ngr;d) within a range from 35 to 45, comprising, said optical glass being free of Yb2O3, Y2O3 and TeO2, in mass % on the basis of the oxides: 1 SiO2 + B2O3 16.5-less than 30% in which SiO2 1-7.5% B2O3 15.5-25% La2O3 25-40% ZrO2 1.5-10% Nb2O5 1-15% Ta2O5 1-10% WO3 1-10% ZnO 15.5-30% Li2O 0.Type: ApplicationFiled: March 26, 2004Publication date: September 23, 2004Inventor: Susumu Uehara
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Patent number: 6773816Abstract: The invention relates to driving glasses in which a thermic ray reflection layer 2 made of a metal or an organic substance is provided on the outer surface of a glass matrix 1, and an anti-reflection layer 3 is provided on the inner surface thereof, werein the glass matrix 1 contains neodymium oxide Nd2O3 of 1 through 12% by weight and praseodymium oxide Pr6O11 of 0.5 through 8% by weight, and forms an absorption peak of light transmittance at a wavelength of 510 through 540 nm and a wavelength of 570 through 590 nm.Type: GrantFiled: December 31, 2002Date of Patent: August 10, 2004Assignees: O.M.G. Kabushiki Kaisha, Inui Lens Co., Ltd.Inventor: Takashi Tsutsumi
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Publication number: 20040127343Abstract: An optical glass having a refractive index (nd) of 1.57 to 1.67, an Abbe's number (&ngr;d) of 55 to 65 and a glass transition temperature (Tg) of 560° C. or lower and having a low-temperature softening property and excellent climate resistance or a haze value of 3% or less, or an optical glass comprising, by mol %, 22 to 40% of B2O3, 12 to 40% of SiO2, 2 to 20% of Li2O, 5 to 15% of CaO, 2 to 14% of ZnO, 0.5 to 4% of La2O3, 0 to 3% of Gd2O3, 0 to 3% of Y2O3, the total content of La2O3, Gd2O3 and Y2O3 being at least 1%, 0 to 5% of Al2O3, 0 to 3% of ZrO2 and 0 to 5% of BaO, the total content of the above components being more than 96%, and having a refractive index (nd) of 1.57 to 1.67 and an Abbe's number (&ngr;d) of 55 to 65.Type: ApplicationFiled: June 30, 2003Publication date: July 1, 2004Applicant: Hoya CorporationInventors: Yoshiko Kasuga, Xuelu Zou