And Rare Earth (i.e., Elements With Atomic Number 39 Or 57-71) Patents (Class 501/78)
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Patent number: 6753281Abstract: An optical glass has optical constants which are an refractive index (nd) of 1.70-1.75 and an Abbe number (&ngr;d) of 45.0-54.0; a glass transformation temperature (Tg) of 500-580° C. The glass has the following composition in mass percent of: SiO2 more than 5 to 15%; B2O3 20 to less than 30%; a total amount of SiO2+B2O3 more than 25 to 40%; La2O3 more than 21 to less than 30%; Y2O3 more than 5 to 15%; Gd2O3 0 to less than 10%; ZrO2 1-8%; Nb2O5 0.1-5%; Ta2O5 more than 5 to 12%; a total amount of ZrO2+Nb2O5+Ta2O5 7-20%; ZnO 0-10%; CaO 0-10%; SrO 0-5%; BaO 0-10%; a total amount of ZnO+CaO+SrO+BaO 5-15%; Li2O 1-8%; Sb2O3 0-1%; and As2O3 0-1%. Devitrification is not generated when the optical glass is kept at a temperature of 920° C. for two hours.Type: GrantFiled: June 18, 2002Date of Patent: June 22, 2004Assignee: Kabushiki Kaisha OharaInventor: Susumu Uehara
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Patent number: 6753278Abstract: The optical glass has an index of refraction (nd) greater than or equal to 1.70, an Abbé number (&ngr;d) greater than or equal to 35 and a density (&rgr;) less than or equal to 4.5 g/cm3. Optical elements made with this optical glass are especially desirable in optical data transfer applications, particularly in read-write devices with movable read-write heads. The glass compositions required to make optical glass with these properties are described.Type: GrantFiled: May 2, 2002Date of Patent: June 22, 2004Assignee: Schott GlasInventors: Silke Wolff, Ute Woelfel, Ulrich Siepe
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Publication number: 20040116272Abstract: An optical glass has optical constants which are an refractive index (nd) of 1.70-1.75 and an Abbe number (vd) of 45.0-54.0; a glass transformation temperature (Tg) of 500-580° C. The glass has the following composition in mass percent of: SiO2 more than 5-15%; B2O3 20-less than 30%; a total amount of SiO2+B2O3 more than 25-40%; La2O3 more than 21-less than 30%; Y2O3 more than 5-15%; Gd2O3 0-less than 10%; ZrO2 1-8%; Nb2O5 0.1-5%; Ta2O5 more than 5-12%; a total amount of ZrO2+Nb2O5+Ta2O5 7-20%; ZnO 0-10%; CaO 0-10%; SrO 0-5%; BaO 0-10%; a total amount of ZnO+CaO+SrO+BaO 5-15%; Li2O 1-8%; Sb2O3 0-1%; and As2O3 0-1%. The glass is substantially free of Yb2O3 and Al2O3. Devitrification is not generated when the optical glass is kept at a temperature of 920° C. for two hours.Type: ApplicationFiled: December 10, 2003Publication date: June 17, 2004Applicant: KABUSHIKI KAISHA OHARAInventor: Susumu Uehara
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Publication number: 20040106507Abstract: Provided are optical glass exhibiting a refractive index (nd) in a range of 1.75 to 1.87, an Abbé number (&ngr;d) in a range of 80 to 45, and excellent low-temperature softening properties even when not incorporating Th2O5 as well as permitting a low production cost; a precision press molding preform and an optical element comprised of such glass; a method of manufacturing the preform; and a method of manufacturing the optical element. The optical glass comprises, in a molar percent, 30 to 45 percent of B2O3, 2 to 15 percent of SiO2, 10 to 20 percent of La2O3, 1 to 10 percent of TiO2, 10 to 30 percent of ZnO, 2 to 15 percent of Li2O, higher than 0 percent and 10 percent or less of WO3, 0 to 15 percent of Nb2O5, and 0 to 10 percent of ZrO2, wherein the total amount of the above-mentioned components is higher than 95 percent, the glass exhibits a refractive index (nd) in a range of 1.75 to 1.87, and an Abbé number (&ngr;d) in a range of 80 to 45.Type: ApplicationFiled: August 20, 2003Publication date: June 3, 2004Applicant: HOYA CORPORATIONInventors: Yoshiko Kasuga, Xuelu Zou
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Publication number: 20040079258Abstract: The invention relates to the use of ions of weakly basic oxides as linking ions for polyacids in cements, preferably polyelectrolyte cements. Suitable ions comprise elements of the scandium series, for example, Sc3+, Y3+, La3+, Ce4+ and all subsequent tri- and tetra-valent lanthanides and the ions Mg2+, Zn2+, Ga2+, In2+. The application of said ions permits a regulation of the cement reaction without surface treatment of the glass powder.Type: ApplicationFiled: December 8, 2003Publication date: April 29, 2004Inventors: Stefan Hoescheler, Markus Mikulla, Gabriele Rackelmann, Volker Bambach
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Patent number: 6716780Abstract: A glass composition including from 0.10 to 2.0% yttrium oxide (e.g., Y2O3) and employing in its colorant portion iron (total iron expressed as Fe2O3), erbium (e.g., Er2O3), and/or holmium (e.g., Ho2O3). In certain embodiments, the glass may be grey in color.Type: GrantFiled: September 26, 2001Date of Patent: April 6, 2004Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Anthony V. Longobardo, Scott V. Thomsen, David R. Hall, Jr.
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Patent number: 6713419Abstract: An optical glass for precision press molding that has desired optical constants, a low glass transformation point (Tg), and a devitrification temperature that is lower than a temperature of a glass melt, at which a viscosity suitable for forming of a preform material is obtained, is provided. The optical glass for precision press molding has a lanthanum borosilicate system glass having optical constants of refractive index (nd) within a range from 1.65 to 1.73 and Abbe number (&ngr;d) within a range from 50 to 60, a Tg within a range of 480-580° C. The optical glass for precision press molding has a devitrification temperature that is lower than a temperature of the glass melt when the glass melt has a viscosity &eegr; (poise) of log &eegr;=2.5. The optical glass for precision press molding has a specific composition range of SiO2—B2O3—La2O3—Y2O3—Ta2O5—CaO—Li2O system composition.Type: GrantFiled: March 19, 2001Date of Patent: March 30, 2004Assignee: Kabushiki Kaisha OharaInventors: Masahiro Onozawa, Takehiro Sakamoto
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Publication number: 20040023787Abstract: The lead-free and preferably arsenic-free optical glass has a refractive index nd of 1.84≦nd≦1.96 and an Abbé number &ngr;d of 27≦&ngr;d≦36, with good chemical resistance, excellent crystallization resistance and the following composition (in % by weight based on oxide): SiO2, 1 to 8, B2O3, 13 to 19.5, La2O3, 34 to 50; MgO, 0 to 6, CaO, 0 to 6, BaO, 0 to 6, ZnO, 0 to 9 with &Sgr; MO, 1 to 10; and TiO2, 4 to 15, ZrO2, 0 to 11, Nb2O5, 6 to 14.5. In addition, the glass according to the invention, as well as having a maximum alkali metal oxide content of 10% by weight, may also contain standard refining agents, although arsenic is not preferred. The glass according to the invention is used in imaging, projection, telecommunications, optical communication and/or laser technology.Type: ApplicationFiled: June 16, 2003Publication date: February 5, 2004Inventors: Silke Wolff, Ute Woelfel
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Patent number: 6667256Abstract: When ceramic electronic parts such as multilayer ceramic substrates that have a substrate body and metal wiring conductors comprising silver are manufactured, a composition comprising not only a borosilicate glass powder and a ceramic powder, but also an additive powder comprising at least one of cerium oxide, bismuth, bismuth oxide, antimony and antimony oxide is used as a composition for preparing the substrate body. Gray discoloration of the substrate body and yellow discoloration in the vicinities of the metal wiring conductors can be prevented.Type: GrantFiled: May 2, 2003Date of Patent: December 23, 2003Assignee: Murata Manufacturing Co., Ltd.Inventor: Kenji Masuko
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Patent number: 6656584Abstract: A glass fiber comprising core glass and clad glass, wherein the core glass consists essentially of from 25 to 70 mol % of Bi2O3, from 5 to 74.89 mol % of B2O3+SiO2, from 0.1 to 30 mol % of Al2O3+Ga2O3, and from 0 to 10 mol % of CeO2.Type: GrantFiled: November 24, 2000Date of Patent: December 2, 2003Assignee: Asahi Glass Company, LimitedInventors: Naoki Sugimoto, Setsuro Ito
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Patent number: 6653251Abstract: An optical amplifying glass having Er doped in an amount of from 0.01 to 10% as represented by mass percentage to a matrix glass comprising, by mol %, BiO2: 20 to 80, B2O3+SiO2: 5 to 75, Ga2O3+WO3+TeO2: 0.1 to 35, Al2O3≦10, GeO2≦30, TiO2≦30, and SnO2≦30, and containing no CeO2.Type: GrantFiled: July 18, 2002Date of Patent: November 25, 2003Assignee: Asahi Glass Company, LimitedInventors: Naoki Sugimoto, Setsuro Ito
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Publication number: 20030211929Abstract: A high-refractivity high-dispersion optical glass for producing an optical element, which requires no machining, such as polishing or lapping, of an optical-function surface after precision press molding, containing B2O3, SiO2, La2O3, Gd2O3, ZnO, Li2O, ZrO2 and Ta2O5 as essential components, containing 0 to 1 mol % of Sb2O3 as an optional component, substantially containing none of PbO and Lu2O3, having a glass transition temperature of 630° C. or lower, and (1) having a refractive index nd and an Abbe's number &ngr;d which satisfy all of the following relational expressions, 1.80<nd≦1.90, 35<&ngr;d≦50, and nd≧2.025−(0.005×&ngr;d) or (2) having an nd of greater than 1.85 and a &ngr;d of greater than 35.Type: ApplicationFiled: March 12, 2003Publication date: November 13, 2003Inventors: Kazutaka Hayashi, Xuelu Zou
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Patent number: 6645894Abstract: An optical glass that substantially does not contain any Ta2O5 and has high-refractivity low-dispersion optical properties and various optical parts made of such optical glass are provided stably at a low cost, and an optical part made thereof is provided, the optical glass having a glass composition comprising, by weight %, 0 to 7% of SiO2, 18 to 30% of B2O3, provided that the total content of SiO2 and B2O3 is 23 to 35%, 2 to 10% of ZnO, 30 to 50% of La2O3, 0 to 20% of Gd2O3, 0 to 20% of Y2O3, provided that the total content of La2O3, Gd2O3 and Y2O3 is 45 to 60%, 3 to 8% of ZrO2 and 3 to 12% of Nb2O5, the total content of these components being at least 95% by weight, the optical glass having a refractive index [nd] and an Abbe's number [&ngr;d] which satisfy specified relational expressions.Type: GrantFiled: March 27, 2002Date of Patent: November 11, 2003Assignee: Hoya CorporationInventor: Michio Endo
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Publication number: 20030191008Abstract: An optical glass suitable for precision press molding has a refractive index (nd) of 1.Type: ApplicationFiled: April 1, 2003Publication date: October 9, 2003Inventor: Susumu Uehara
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Patent number: 6620748Abstract: An optical amplifying glass comprising a matrix glass and, added thereto, from 0.01 to 10 wt % of Er, characterized in that said matrix glass substantially comprises, as represented by mol %, 20 to 80 of Bi2O3, 0 to 74.89 of B2O3, 0 to 79.99 of SiO2, 0.01 to 10 of CeO2, 0 to 50 of Li2O, 0 to 50 of TiO2, 0 to 50 of ZrO2, 0 to 50 of SnO2, 0 to 30 of WO3, 0 to 30 of TeO2, 0 to 30 of Ga2O3 and 0 to 10 of Al2O3, with the proviso that said matrix glass contains at least one of B2O3 and SiO2.Type: GrantFiled: April 20, 2001Date of Patent: September 16, 2003Inventors: Naoki Sugimoto, Yutaka Kuroiwa, Setsuro Ito, Setsuhisa Tanabe, Teiichi Hanada
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Patent number: 6610621Abstract: When ceramic electronic parts such as multilayer ceramic substrates that have a substrate body and metal wiring conductors comprising silver are manufactured, a composition comprising not only a borosilicate glass powder and a ceramic powder, but also an additive powder comprising at least one of cerium oxide, bismuth, bismuth oxide, antimony and antimony oxide is used as a composition for preparing the substrate body. Gray discoloration of the substrate body and yellow discoloration in the vicinities of the metal wiring conductors can be prevented.Type: GrantFiled: November 28, 2001Date of Patent: August 26, 2003Assignee: Murata Manufacturing Co., Ltd.Inventor: Kenji Masuko
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Patent number: 6599853Abstract: An optical amplifier glass comprising a matrix glass containing Bi2O3 and at least one of Al2O3 and Ga2O3, and Er doped to the matrix glass, wherein from 0.01 to 10% by mass percentage of Er is doped to the matrix glass which has a total content of Al2O3 and Ga2O3 of at least 0.1 mol %, a content of Bi2O3 of at least 20 mol %, a refractive index of at least 1.8 at a wavelength of 1.55 &mgr;m, a glass transition temperature of at least 360° C. and an optical basicity of at most 0.49.Type: GrantFiled: January 23, 2001Date of Patent: July 29, 2003Assignee: Asahi Glass Company, LimitedInventors: Naoki Sugimoto, Setsuro Ito, Setsuhisa Tanabe
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Publication number: 20030126803Abstract: Al2O3-rare earth oxide-ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.Type: ApplicationFiled: August 2, 2002Publication date: July 10, 2003Applicant: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Publication number: 20030126804Abstract: Alumina-zirconia materials and methods of making the same. Embodiments of the invention include abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.Type: ApplicationFiled: August 2, 2002Publication date: July 10, 2003Applicant: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Ahmet Celikkaya, Thomas J. Anderson
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Publication number: 20030125186Abstract: A high-refractivity low-dispersion optical glass that gives press-molding preforms excellent in high-temperature shapability and suitable for precision press-molding, including an optical glass comprising B2O3, La2O3, Gd2O3 and ZnO as essential components, substantially containing none of lead and fluorine, having a refractive index (nd) of 1.72 to 1.83, an Abbe's number (vd) of 45 to 55 and a glass transition temperature (Tg) of 630° C. or lower and having a viscosity of at least 0.6 Pa•s at its liquidus temperature, and an optical glass comprising, by mol %, 45 to 65% of B2O3, 5 to 22% of La2O3, 1 to 20% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 14 to 30%, 5 to 30% of ZnO, 0 to 10% of SiO2, 0 to 6.5% of ZrO2 and 0 to 1% of Sb2O3, substantially containing none of lead and fluorine, and having a refractive index (nd) of 1.72 to 1.83 and an Abbe's number (vd) of 45 to 55.Type: ApplicationFiled: February 20, 2002Publication date: July 3, 2003Inventors: Kazutaka Hayashi, Yasuhiro Fujiwara, Zou Xuelu
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Publication number: 20030110708Abstract: Al2O3—Y2O3—ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.Type: ApplicationFiled: August 2, 2002Publication date: June 19, 2003Applicant: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Publication number: 20030110709Abstract: Methods of making amorphous material and ceramic materials. Embodiments of the invention can be used to make abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.Type: ApplicationFiled: August 2, 2002Publication date: June 19, 2003Applicant: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Ahmet Celikkaya, Thomas J. Anderson
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Publication number: 20030064878Abstract: An optical amplifying glass having Er doped in an amount of from 0.01 to 10% as represented by mass percentage to a matrix glass comprising, by mol %, BiO2: 20 to 80, B2O3+SiO2: 5 to 75, Ga2O3+WO3+TeO2: 0.1 to 35, Al2O3≦10, GeO2≦30, TiO2≦30, and SnO2≦30, and containing no CeO2.Type: ApplicationFiled: July 18, 2002Publication date: April 3, 2003Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Naoki Sugimoto, Setsuro Ito
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Publication number: 20030050177Abstract: An optical glass has optical constants which are an refractive index (nd) of 1.70-1.75 and an Abbe number (&ngr;d) of 45.0-54.0; a glass transformation temperature (Tg) of 500-580° C. The glass has the following composition in mass percent of: SiO2 more than 5 to 15%; B2O3 20 to less than 30%; a total amount of SiO2+B2O3 more than 25 to 40%; La2O3 more than 21 to less than 30%; Y2O3 more than 5 to 15%; Gd2O3 0 to less than 10%; ZrO2 1-8%; Nb2O5 0.1-5%; Ta2O5 more than 5 to 12%; a total amount of ZrO2+Nb2O5+Ta2O5 7-20%; ZnO 0-10%; CaO 0-10%; SrO 0-5%; BaO 0-10%; a total amount of ZnO+CaO+SrO+BaO 5-15%; Li2O 1-8%; Sb2O3 0-1%; and As2O3 0-1%. Devitrification is not generated when the optical glass is kept at a temperature of 920° C. for two hours.Type: ApplicationFiled: June 18, 2002Publication date: March 13, 2003Applicant: KABUSHIKI KAISHA OHARAInventor: Susumu Uehara
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Publication number: 20030032542Abstract: An optical glass that substantially does not contain any Ta2O5 and has high-refractivity low-dispersion optical properties and various optical parts made of such optical glass are provided stably at a low cost, and an optical part made thereof is provided, the optical glass having a glass composition comprising, by weight %, 0 to 7% of SiO2, 18 to 30% of B2O3, provided that the total content of SiO2 and B2O3 is 23 to 35%, 2 to 10% of ZnO, 30 to 50% of La2O3, 0 to 20% of Gd2O3, 0 to 20% of Y2O3, provided that the total content of La2O3, Gd2O3 and Y2O3 is 45 to 60%, 3 to 8% of ZrO2 and 3 to 12% of Nb2O5, the total content of these components being at least 95% by weight, the optical glass having a refractive index [nd] and an Abbe's number [&ngr;d] which satisfy specified relational expressions.Type: ApplicationFiled: March 27, 2002Publication date: February 13, 2003Inventor: Michio Endo
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Publication number: 20030029194Abstract: Pyrogenically produced oxides of metals and/or metalloids doped with erbium oxide, in which the base component is a pyrogenically produced oxide doped with erbium oxide in an amount of 0.000001 to 40 wt %, in which the BET surface of the doped oxide lies between 1 and 1000 m2/g, are produced by feeding an aerosol into a flame, as used for production of pyrogenic oxide, in which an erbium salt solution is used as the starting product for the aerosol, the aerosol being produced by atomization with an aerosol generator, this aerosol is mixed homogeneously before reaction with a gas mixture for flame oxidation or flame hydrolysis, the aerosol-gas mixture is then allowed to react in a flame, and the formed pyrogenic oxides doped with erbium oxide are separated from the gas stream in a known fashion. The pyrogenic oxide of metals and/or metalloids doped with erbium oxide can be used as glass raw material.Type: ApplicationFiled: July 10, 2002Publication date: February 13, 2003Inventors: Helmut Mangold, Rainer Golchert, Roland Schilling
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Patent number: 6515795Abstract: A borosilicate glass composition comprises SiO2 having a concentration of about 40 mole percent to about 60 mole percent, B2O3 having a concentration of about 10 mole percent to about 30 mole percent, and an alkaline earth and/or alkali compound having a concentration of 10 mole percent to about 40 mole percent. An optical fiber amplification device comprises a borosilicate glass material cladding. The core comprises a germanate glass material doped with Tm3+. The germanate glass material has a first surface configured to receive an optical signal having a wavelength of from about 1400 nm to about 1540 nm and a second surface configured to output an amplified optical signal. In this manner, low cost fiber amplifiers in the 1450-1530 nm wavelength region (corresponding to the S-band) can be achieved.Type: GrantFiled: June 29, 2001Date of Patent: February 4, 2003Assignee: Corning IncorporatedInventors: Matthew J. Dejneka, Ji Wang
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Publication number: 20030022782Abstract: There is provided an optical glass suitable for precision mold pressing having optical constants of a refractive index (nd) within a range from 1.75 to 1.85 and an Abbe number (&ngr;d) within a range from 35 to 45, comprising in mass % on oxide basis: 1 SiO2 + B2O3 16.5-less than 30% in which SiO2 1-7.5% B2O3 15.5-25% La2O3 25-40% ZrO2 1.5-10% Nb2O5 1-15% Ta2O5 1-10% WO3 1-10% ZnO 15.5-30% Li2O 0.6-5%.Type: ApplicationFiled: May 31, 2002Publication date: January 30, 2003Inventor: Susumu Uehara
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Patent number: 6503860Abstract: According to one aspect of the present invention an optically active glass contains Sb2O3, up to about 4 mole % of an oxide of a rare earth element, and 0-20 mole % of a metal halide selected from the group consisting of a metal fluoride, a metal bromide, a metal chloride, and mixtures thereof, wherein this metal is a trivalent metal, a divalent metal, a monovalent metal, and mixtures thereof. In addition, any of the glass compositions described herein may contain up to 15 mole % B2O3 substituted for an equivalent amount of Sb2O3.Type: GrantFiled: February 4, 2000Date of Patent: January 7, 2003Assignee: Corning IncorporatedInventors: James E. Dickinson, Adam J. G. Ellison, Alexandre M. Mayolet, Michel Prassas
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Patent number: 6503858Abstract: Provided are a glass such as a sealing glass which contains a rare earth element and crystalline particles, a structure made by sealing with said sealing glass, a magnetic head made by bonding using said sealing glass, and a magnetic recording and reproducing apparatus on which said magnetic heads are mounted. According to the glass of the present invention, magnetic heads, and other structures can be bonded at low temperatures and a high bond strength can be attained, and thus, magnetic heads having high-speed sliding properties and magnetic recording and reproducing apparatuses of high reliability can be obtained. The glass can be also used for heat resistant parts such as a pannel glass for a cathode-ray tube and the like.Type: GrantFiled: July 26, 2000Date of Patent: January 7, 2003Assignee: Hitachi, Ltd.Inventors: Hiroki Yamamoto, Takashi Naito, Takashi Namekawa, Ken Takahashi, Noriyuki Kumasaka, Kenkichi Inada
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Patent number: 6495482Abstract: A glass composition well suited for use in optical amplification consists of an erbium-doped borate glass composition comprising at least 30 mole percent of B2O3, not over 30 mole percent of SiO2, preferably not over 5 mole percent of La2O3, a ratio of B2O3 to (&Sgr;X2O+&Sgr;YO) that is at least 3.5, preferably 4.5, where X2O represents monovalent metal oxides(s) and YO represents divalent metal oxides, the glass providing a wide useful bandwidth (50 nm and greater) for optical amplification around the 1545 nm region.Type: GrantFiled: May 5, 2000Date of Patent: December 17, 2002Assignee: Corning IncorporatedInventors: Jean-Philippe de Sandro, David Jacob, Michel Prassas
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Patent number: 6482758Abstract: A bulk single phase glass comprising 23 molar % to 50 molar % rare earth oxides, RE203, and 50 molar % to 77 molar % aluminum oxide, A12O3 is provided. The glass contains at least 50 molar % of Al2O3+RE2O3 and smaller amounts of oxide glass forming agents and other oxides than are found in prior art glasses. The addition of small amounts of lanthanum oxide, La2O3, prevents phase separation. The single phase glass is useful for optical applications such as lasers and optical amplifiers.Type: GrantFiled: October 4, 2000Date of Patent: November 19, 2002Assignee: Containerless Research, Inc.Inventors: J. K. Richard Weber, Johan G. Abadie, April D. Hixson, Paul C. Nordine
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Patent number: 6444599Abstract: The present invention relates to an oxyhalide glass matrix including 0-70 mol. % SiO2, 5-35 mol. % Al2O3, 1-50 mol. % B2O3, 5-35 mol. % R2O, 0-12 wt. % F, 0-12 wt. % Cl, and 0 to 0.2 mol. % rare earth element, wherein R is Li, Na, K, Rb, or Cs. The present invention further relates to a method of producing the glass matrix and to a method of modifying the spectral properties of an oxyhalide glass.Type: GrantFiled: June 1, 2000Date of Patent: September 3, 2002Assignee: Corning IncorporationInventors: James E. Dickinson, Adam J. G. Ellison
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Patent number: 6429161Abstract: The present invention provides a new and improved porcelain enamel coating composition for use in forming a self-cleanable coating upon aluminized steel. The coating composition comprises a glass component having a composition comprising from about 30% to about 55% SiO2, from about 11% to about 20% TiO2, from about 0% to about 10% B2O3, from about 20% to about 40% alkali metal oxides, less than about 5% rare earth metal oxides, from about 0% to about 10% CaO, from about 0% to about 10% BaO, from about 0% to about 10% MnO, from about 2% to about 12% CuO, from about 0% to about 10% Sb2O3, from about 1.5% to about 10% Fe2O3, from about 0% to about 10% SnO2, from about 0% to about 10% P2O5, less than about 2% MoO3, and less than about 5% V2O5.Type: GrantFiled: August 7, 2000Date of Patent: August 6, 2002Assignee: Ferro France S.A.R.L.Inventors: Thierry Souchard, Alain Aronica
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Patent number: 6420290Abstract: The object of the present invention is colorless inorganic glasses, as well as products manufactured from said glasses. Said glasses are of the type containing copper halides or copper cadmium halides and having a sharp optical absorption cutoff between 370 nm and 425 nm essentially having the composition below, expressed in cationic percentages: 23-73% SiO2 15-45% B2O3 0-24% Al2O3 0-12% Li2O 0-20% Na2O 0-12% K2O 0-5% CaO + BaO + SrO 0.125-1% Cu2O 0-1% CdO 0-5% ZrO2 with 0-1.75% Cl 0.Type: GrantFiled: February 11, 2000Date of Patent: July 16, 2002Assignee: Corning S.A.Inventors: Yves A. H. Brocheton, Christophe Remy
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Patent number: 6413894Abstract: When a glass melt of an optical glass having a refractive index (nd) of at least 1.7 and an Abbe number (&ngr;d) of 28 to 41 is flowed down from a flow pipe made of Pt or a Pt alloy to form glass gobs continuously, there is caused a problem that the glass gobs have striae or that the weight variability among the glass gobs is large, and the problem can be overcome by the use of an optical glass comprising silicon oxide and boron oxide, the ratio of a content of the silicon oxide to a content of the boron oxide being greater than 0.78, the optical glass having a contact angle of at least 40° to Pt or a Pt alloy at a predetermined temperature equivalent to, or higher than, its liquidus temperature or in a predetermined temperature range whose lower limit is equivalent to, or higher than, the liquidus temperature and having a sag temperature Ts of 580° C. or lower.Type: GrantFiled: April 27, 1999Date of Patent: July 2, 2002Assignee: Hoya CorporationInventor: Kouichi Sato
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Patent number: 6410467Abstract: A glass consisting essentially of antimony oxide. An optically active glass consisting essentially of antimony oxide and up to about 4 mole % of an oxide of a rare earth element. A rare earth-doped, antimony oxide-containing glass including 0-99 mole % SiO2, 0-99 mole % GeO2, 0-75 mole % (Al, Ga)2O3, 0.5-99 mole % Sb2O3, and up to about 4 mole % of an oxide of a rare earth element. The oxide of the rare earth element may comprise Er2O3. The glass of the invention further includes fluorine, expressed as a metal fluoride. An optical energy-producing or light-amplifying device, in particular, an optical amplifier, comprising the above-described glass. The optical amplifier can be either a fiber amplifier or a planar amplifier, either of which may have a hybrid composition. Embodiments of the glass of the invention can be formed by conventional glass making techniques, while some of the high content antimony oxide embodiments are formed by splat or roller quenching.Type: GrantFiled: April 8, 1999Date of Patent: June 25, 2002Assignee: Corning IncorporatedInventors: James E. Dickinson, Adam J G Ellison, Alexandre M. Mayolet, Michel Prassas
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Patent number: 6379805Abstract: A low temperature-fired porcelain article includes a barium component in an amount of 40 to 65 wt % when calculated as BaO, a silicon component in an amount of 25 to 46 wt % when calculated as SiO2, an aluminum component in an amount of 0.1 to 20 wt % when calculated as Al2O3, a boron component in an amount of 0.3 to 1.5 wt % when calculated as B2O3, and a zinc component in an amount of 0.5 to 20 wt % when calculated as ZnO, optionally also a chromium component in an amount of 0.5 to 3.5 wt % when calculated as Cr2O3 wherein the porcelain article has a dielectric constant ∈r of not more than 10, a quality coefficient Q of not less than 2500, and preferably has an absolute value of a temperature coefficient &tgr;f of the resonance frequency of not more than 30 ppm/° C.Type: GrantFiled: January 19, 2000Date of Patent: April 30, 2002Assignee: NGK Insulators, Ltd.Inventors: Takeshi Oobuchi, Yasunori Kouda, Hideyuki Baba
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Patent number: 6380112Abstract: The invention relates to lead-free optical glasses having a refractive index nd of from 1.52 to 1.58, an Abbe number vd of from 50 to 57 and a negative partial dispersion &Dgr;Pg,F of <−0.0090, having a composition (in % by weight, based on oxide) of SiO2>15-25; B2O3 45-55; Al2O3 8-13; CaO 2-8; ZnO 0-5; with CaO+ZnO 2-10; Li2O 0-4; Na2O 0-4; K2O 0-4; with Li2O+Na2O+K2O 3-8; La2O3 0-14; Nb2O5 0-4.8; Ta2O5>10-17; with Ta2O5+Nb2O5>10-17; SnO2 0-2; ZrO2 0-7; with Ta2O5+ZrO2>10-<18.Type: GrantFiled: May 26, 2000Date of Patent: April 30, 2002Assignee: Schott GlasInventors: Uwe Kolberg, Ute Wölfel, Magdalena Winkler-Trudewig, Nicole Surges
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Patent number: 6380111Abstract: A novel amorphous optical device contributes to economic construction of optical computers. Since economic parallel processing of signals such as image information is made possible, the novel amorphous optical device contributes also to development of optical computers capable of performing ultra-high speed and parallel processing, object recognizing apparatuses in which image optical signals are processed by using image optical signals, motion picture extracting apparatuses used for eyes of robots and object movement monitors and optical surge absorbers. An amorphous optical device which is doped with an element having a negative optical input-output characteristic to incident light, wherein the number of ions and/or atoms of the element is 1×1026 to 2.Type: GrantFiled: September 11, 2000Date of Patent: April 30, 2002Assignees: Nihon Yamamura Glass Co., Ltd.Inventors: Yoshinobu Maeda, Akio Konishi, Hidekazu Hashima, Hajimu Wakabayashi
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Patent number: 6372155Abstract: The object of the present invention is to provide an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by &ggr;-rays, X-rays, UV-rays, etc. and light emission can be continued for a long time even after stopping the excitation. That is, the present invention relates to an oxide glass capable of exhibiting a long lasting afterglow and photostimulated luminescence, characterized by a constitutional composition comprising, at least, terbium oxide (Tb2O3) or manganese oxide (MnO), gallium oxide (Ga2O3) or aluminum oxide (Al2O3), alkali metal oxide or alkaline earth metal oxide and boron oxide (B2O3) or silicon oxide (SiO2) or zinc oxide (ZnO).Type: GrantFiled: November 30, 1999Date of Patent: April 16, 2002Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
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Publication number: 20020039958Abstract: Glass for a light filter capable of preventing variation of refractive index in a band-pass filter has a coefficient of thermal expansion within a range from 90×10−7/° C. within a temperature range from −20° C. to +70° C. and, preferably, Young's modulus of 75 GPa or over and Vickers hardness of 550 or over, and light transmittance for plate thickness of 10 mm of 90% or over within a wavelength range from 950 nm to 1600 nm.Type: ApplicationFiled: October 10, 2001Publication date: April 4, 2002Inventor: Naoyuki Goto
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Patent number: 6362119Abstract: A barium borosilicate glass which consists essentially of, as represented by mass% based on the following oxides: B2O3 5 to 35%, SiO2 0.5 to 30%, BaO 25 to 75%, Al2O3 0.5 to 13%, SnO2 0 to 2%, CeO2 0 to 2%, MgO + CaO + SrO 0 to 10%, ZnO 0 to 20%, TiO2 0 to 5%, ZrO2 0 to 5%, Li2O 0 to 5%, Na2O 0 to 5%, and K2O 0 to 5%.Type: GrantFiled: May 31, 2000Date of Patent: March 26, 2002Assignee: Asahi Glass Company, LimitedInventor: Jiro Chiba
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Patent number: 6346493Abstract: The present invention provides a new and improved lead-free and cadmium-free glass enamel composition that displays good flow at traditional glass enamel firing temperatures and upon firing produces an enamel finish that displays no cracking, good chemical resistance, good weatherability, and improved color values. The glass enamel composition of the present invention includes a glass component, an oxidizer, a pigment system, and optional vehicles and fillers. The presence of the oxidizer in the composition, which can be included as part of the glass component, as a separately added material, or both, improves the color values of the fired enamel as compared to enamels formed using similar glass enamel compositions having no oxidizer present.Type: GrantFiled: October 27, 1999Date of Patent: February 12, 2002Assignee: Ferro CorporationInventors: Galina Kniajer, Jeffrey David Cosby, Ivan H. Joyce, Srinivasan Sridharan, John J. Maloney
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Publication number: 20020006857Abstract: Disclosed is an optical glass having high-refractivity and low-dispersion optical properties and having a low glass transition point so that a heat-treating furnace can be operated for a long period of time.Type: ApplicationFiled: May 24, 2001Publication date: January 17, 2002Inventor: Kazuo Tachiwama
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Patent number: 6333288Abstract: The invention can relate to essentially lead-free optical glasses having a refractive index nd of from about 1.65 to about 1.87 and an Abbe number &ngr;d of from about 27 to about 43 and a composition (in % by weight, based on oxide) of SiO2 about 10-about 25, B2O3>about 10-about 25, Na2O about 2.5-about 10, K2O 0-about 3, CaO about 0.5-about 5, BaO about 15-about 30, ZnO about 5-about 15, TiO2 about 6-about 15, ZrO2 about 0.5-about 8, Y2O3 about 0.1-about 2, La2O3 about 0.5-about 8, Nb2O5 about 6-about 12, with La2O3+Nb2O5≦about 17,Ta2O5 0-about 1, and Gd2O3 0-about 1.Type: GrantFiled: May 8, 2000Date of Patent: December 25, 2001Assignee: Schott GlasInventors: Marc Clement, Silke Wolff, Magdalena Winkler-Trudewig
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Publication number: 20010044369Abstract: An optical amplifier glass comprising a matrix glass containing Bi2O3 and at least one of Al2O3 and Ga2O3, and Er doped to the matrix glass, wherein from 0.01 to 10% by mass percentage of Er is doped to the matrix glass which has a total content of Al2O3 and Ga2O3 of at least 0.1 mol %, a content of Bi2O3 of at least 20 mol %, a refractive index of at least 1.8 at a wavelength of 1.55 &mgr;m, a glass transition temperature of at least 360° C. and an optical basicity of at most 0.49.Type: ApplicationFiled: January 23, 2001Publication date: November 22, 2001Inventors: Naoki Sugimoto, Setsuro Ito, Setsuhisa Tanabe
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Patent number: 6284687Abstract: The present invention relates to glasses of high refractive index having the following composition of oxides, expressed in percentages by weight: SiO2 29-35, B2O3 0.5-5, Li2O 0.5-3, Na2O 4-8, K2O 0-2, PbO 28-40, BaO 4-14, La2O3 4-12, TiO2 3-8, ZnO 0-8, ZrO2 0-4, Nb2O5 0-5, with: Li2O+Na2O+K2O 5.5-9; their use for the production of segments for multifocal corrective lenses; and multifocal corrective lenses incorporating at least one such segment in their structure.Type: GrantFiled: April 7, 2000Date of Patent: September 4, 2001Assignee: Corning S.A.Inventors: Marie M. J. Comte, Paulo Marques
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Patent number: 6271160Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of &ggr;-rays, X-rays or UV-rays images and further can be used as an optical recording material of such a type that can be read. This glass material is represented, in term of atoms for making up the glass, by the following chemical composition (mol %): GeO2 21 to 80% ZnO 0 to 50% Ga2O2 0 to 55% (ZnO + Ga2O3 = 3 to 55%) Tb2O3 0 to 10% MnO 0 to 2% (Tb2O3 + MnO = 0.01 to 10%) R2O 0 to 45% (R: at least one atom selected from Li, Na, K and Cs) R′O 0 to 40% (R′: at least one atom selected from Mg, Ca, Sr and Ba) R2O + R′O 0.Type: GrantFiled: May 12, 1999Date of Patent: August 7, 2001Assignee: Sumita Optical Glass, Inc.Inventors: Yoshinori Yamamoto, Masaaki Yamazaki, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 6255240Abstract: The object of the present invention is a novel inorganic glass, which is capable of being strengthened by ionic exchange, and which has a refractive index of between 1.67 and 1.72; said novel glass strengthened on the surface thereof; its method of strengthening; and the corresponding ophthalmic lenses. Said novel glass has the following composition, expressed in wt. % of oxides: SiO2 33-37 B2O3 7.5-13 with SiO2 + B2O3 44-48 Li2O 5-8 Na2O >2.5-7.5 K2O 0-2 with Li2O + Na2O + K2O <14 CaO 0-<8 Al2O3 0-6 Nb2O5 8-13 ZrO2 4-6 TiO2 5-10 La2O3 12-19 SrO 2-4 As2O3 and/or Sb2O3 0-0.8 (refining agents).Type: GrantFiled: May 21, 1999Date of Patent: July 3, 2001Assignee: Corning S.A.Inventors: Marie J. M. Comte, Alexandre M. Mayolet