Silicon Carbide Patents (Class 502/178)
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Publication number: 20120198769Abstract: A catalyst-coated support including a sheetlike support, a primer layer applied thereto and composed of nanoparticles composed of silicon oxide-comprising material, and at least one catalyst layer applied to the primer layer. The layers applied are notable for a particularly good adhesive bond strength and can be used particularly efficiently in heterogeneously catalyzed gas phase reactions, especially in microreactors.Type: ApplicationFiled: June 23, 2010Publication date: August 9, 2012Inventors: Steffen Schirrmeister, Martin Schmitz-Niederau, Ingo Klüppel, Christoph Filthaut
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Publication number: 20120108417Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: ApplicationFiled: December 1, 2011Publication date: May 3, 2012Applicant: LG CHEM, LTD.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20120108416Abstract: A catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: ApplicationFiled: December 1, 2011Publication date: May 3, 2012Applicant: LG CHEM, LTD.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20120028166Abstract: It is an object to inhibit a corrosion and disappearance of carbon included in a catalyst carrier to enhance the durability of a fuel cell. A catalyst carrier is used to adhere a catalyst metal (23) to the surface of a protective layer for carbon (22), the catalyst carrier comprising carbon (21) and the protective layer for carbon (22) with which the carbon (21) is coated, the protective layer for carbon (22) comprising silicon oxide and silicon carbide. Among the protective layer for carbon (22), a vicinity part of an interface between the protective layer for carbon (22) and the carbon (21) comprises silicon carbide, and the surface part of said protective layer for carbon (22) desirably comprises silicon oxide.Type: ApplicationFiled: July 22, 2011Publication date: February 2, 2012Inventors: Makoto MORISHIMA, Shuichi Suzuki
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Patent number: 8105972Abstract: A catalyst for the oxidative dehydrogenation of a paraffin to form an olefin, the catalyst having a general formula MoaVbXcYdOn wherein: X=at least one of Nb and Ta; Y=at least one of Te, Sb, Ga, Pd, W, Bi and Al; a=1.0; b=0.05 to 1.0; c=0.001 to 1.0; d=0.001 to 1.0; and n is determined by the oxidation states of the other elements. The catalyst may have a selectivity to the olefin of at least 90 mole % at a paraffin conversion of at least 65%.Type: GrantFiled: April 2, 2009Date of Patent: January 31, 2012Assignee: Lummus Technology Inc.Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
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Patent number: 8105971Abstract: A process for forming a catalyst useful for the production of an olefin from a hydrocarbon is disclosed. The process may include: admixing at least one of elemental metals and compounds to form a multi-metal composition comprising Mo, V, Nb, Te and at least one of Ni and Sb; adjusting the pH of the multi-metal composition by adding nitric acid; drying the acidified multi-metal composition; calcining the dried multi-metal composition; and grinding the calcined multi-metal composition. The ground multi-metal composition may then be sized or shaped to form a mixed metal oxide catalyst. Alternatively, the ground multi-metal composition may be treated with an acid, optionally annealed, and sized or shaped to form a mixed metal oxide catalyst.Type: GrantFiled: April 2, 2009Date of Patent: January 31, 2012Assignee: Lummus Technology Inc.Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
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Patent number: 8093173Abstract: There is provided a honeycomb structure where a catalyst is loaded on surfaces of inner pores of the surface layer and on a surface of the surface layer; a relation between a catalyst area proportion A of the catalyst to a gap area proportion B of a gap in a cross-section of the surface layer on the inlet side is 1%<A/B<90%; and a relation between an average catalyst area proportion, A1, from the surface to a point having a depth of one third of the thickness of the surface layer including the surface of the surface layer on the inlet side and a catalyst area proportion A2 in a central portion of the surface layer is A1/A2>1.5.Type: GrantFiled: January 13, 2010Date of Patent: January 10, 2012Assignee: NGK Insulators, Ltd.Inventors: Yukio Miyairi, Takashi Mizutani, Takuya Hiramatsu
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Publication number: 20110312488Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is disclosed. Generating the polyol involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.Type: ApplicationFiled: July 28, 2011Publication date: December 22, 2011Applicant: UOP LLCInventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
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Publication number: 20110312487Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.Type: ApplicationFiled: July 28, 2011Publication date: December 22, 2011Applicant: UOP LLCInventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
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Publication number: 20110268634Abstract: The invention relates to a monolithic support member comprising channels with walls separating the channels from each other and having a coating deposited thereon, the non-coated channels having a polygonal cross-section profile, wherein the mean thickness dC of the coating in a corner of said cross-section profile is smaller than or equal to the mean thickness dE of the coating on an edge of said cross-section profile plus 85 micrometer; and further relates to a method for the preparation of such coated monolithic support member, the method comprising (i) providing a suspension having a viscosity in the range of from 0.5 to 100 mPas and having a solid content in the range of from 1 to 40 wt.Type: ApplicationFiled: March 31, 2011Publication date: November 3, 2011Applicants: BASF Corporation, BASF SEInventors: Markus Linsenbühler, Bernd Sachweh, Saadallah Nemeh, Michel Deeba, Michael Mertler, Matthias Wilhelm Meier
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Publication number: 20110262312Abstract: The invention relates to a photocatalyst comprising a ?-SiC cellular foam and a photocatalytically active phase, deposited directly on said cellular foam or on an intermediate phase deposited on said cellular foam. The average size of the cells is between 2500 ?m and 5000 ?m. The foam can comprise nanotubes or nanofibers (particularly of carbon, SiC, and TiO2) that consist of, or carry as an intermediate phase, a photocatalytically active phase.Type: ApplicationFiled: September 14, 2009Publication date: October 27, 2011Inventors: Cuong Pham-Huu, Nicolas Keller, Marc-Jacques Ledoux, Valérie Keller-Spitzer, Dominique Begin, Mathieu Grandcolas, Izabela Janowska, Shabnam Hajesmaili
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Patent number: 8029882Abstract: A silicon carbide porous object includes silicon carbide as an aggregate and metal silicon as a binder, the particles of silicon carbide being bonded to one another so as to have pores thereamong. A method for producing a silicon carbide porous object includes: firing raw materials formed by mixing silicon carbide and metal silicon with metal aluminum or an alloy including metal silicon and metal aluminum in an inert gas atmosphere or a reduced-pressure atmosphere to produce a metal aluminum-metal silicon-silicon carbide porous object; and oxidizing and firing the metal aluminum-metal silicon-silicon carbide porous object in an oxygen atmosphere.Type: GrantFiled: September 8, 2008Date of Patent: October 4, 2011Assignee: NGK Insulators, Ltd.Inventors: Yoshio Kikuchi, Shinji Kawasaki
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Patent number: 8022008Abstract: A method is provided for making a catalyst support, and includes the steps of providing an aqueous suspension of refractory inorganic oxide and refractory inorganic carbide; forming the suspension into droplets; exposing the droplets to a gelling agent whereby the droplets are at least partially solidified so as to provide substantially sphere-shaped portions of refractory inorganic oxide and refractory inorganic carbide; and drying and calcining the sphere-shaped portions so as to provide substantially spherical particles of catalyst support containing refractory inorganic oxide and refractory inorganic carbide. Catalytically active metal phases and hydrogenation processes using the catalyst are also described.Type: GrantFiled: November 30, 2009Date of Patent: September 20, 2011Assignee: Intevep, S.A.Inventors: Jorge M. Martinis, Maria E. Valera, Jose R. Velasquez, Angel R. Carrasquel
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Patent number: 8017543Abstract: The invention relates to a method of obtaining a homogeneous filtering structure for a catalytic application, which can be used as a particulate filter in an internal combustion engine exhaust line, said structure comprising a plurality of honeycomb filter elements in which a homogeneity criterion characteristic of the constituent support material of said elements, in the absence of a catalytic coating, is determined in a prior step, and then the elements making up the structure are selected by means of this homogeneity criterion so as to obtain a structure suitable for homogeneous deposition, within an element and from one element to another, of a catalyst for treating the pollutants in gas phase. The invention also relates to the homogeneous filtration structure obtained by said method.Type: GrantFiled: September 29, 2006Date of Patent: September 13, 2011Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Patricia Andy, Sebastien Bardon, Vincent Marc Gleize
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Patent number: 7977013Abstract: The present invention discloses nanowires for use in a fuel cell comprising a metal catalyst deposited on a surface of the nanowires. A membrane electrode assembly for a fuel cell is disclosed which generally comprises a proton exchange membrane, an anode electrode, and a cathode electrode, wherein at least one or more of the anode electrode and cathode electrode comprise an interconnected network of the catalyst supported nanowires. Methods are also disclosed for preparing a membrane electrode assembly and fuel cell based upon an interconnected network of nanowires.Type: GrantFiled: December 20, 2006Date of Patent: July 12, 2011Assignee: Nanosys, Inc.Inventors: Chunming Niu, Calvin Y. H. Chow, Stephen A. Empedocles, J. Wallace Parce
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Patent number: 7977275Abstract: The invention proposes a particulate filter having a catalytic coating which contains two catalysts arranged one behind the other. The first catalyst is located in the gas inlet region of the filter and contains a palladium/platinum catalyst. The second catalyst is arranged downstream of the first catalyst and preferably contains platinum alone as catalytically active component. The combination of these two catalysts provides the coated filter with a good ageing stability and resistance to sulphur poisoning.Type: GrantFiled: August 13, 2005Date of Patent: July 12, 2011Assignee: Umicore AG & Co. KGInventors: Marcus Pfeifer, Markus Koegel, Roger Staab, Pascal Adolph, Yvonne Demel, Tobias Kuhl, Egbert Lox, Thomas Kreuzer, Frank-Walter Schuetze
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Publication number: 20110143929Abstract: To provide a photocatalyst having high selectivity and carrying out a reductive reaction with light having a longer wavelength. A photocatalyst has a structure in which a semiconductor and a substrate are joined, in which the substrate causes a catalytic reaction by transfer to the substrate of excited electrons, which are generated by applying light to the semiconductor.Type: ApplicationFiled: August 10, 2009Publication date: June 16, 2011Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Shunsuke Sato, Takeshi Morikawa, Tomiko Mori, Shu Saeki, Tsutomu Kajino, Hiromitsu Tanaka
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Publication number: 20110143928Abstract: The invention relates to a structure of the honeycomb type, made of a porous ceramic material, said structure being characterized in that the porous ceramic material of which it is composed comprises at least partly 45 to 90% by weight of silicon carbide SiC, preferably in the alpha form, and 10 to 55% by weight of a ceramic oxide phase substantially in the form of aluminum titanate Al2TiO5, said material also having a porosity greater than 10%, and a median pore diameter of between 5 and 60 microns.Type: ApplicationFiled: May 26, 2009Publication date: June 16, 2011Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROInventor: Carine Dien-Barataud
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Publication number: 20110105305Abstract: An architecture made of a ceramic or a metallic foam has at least one continuous and/or discontinuous, axial and/or radial porosity gradient ranging from 10 to 90% associated to a pore size range from 2 to 60 ppi, at least one continuous and/or discontinuous, axial and/or radial concentration gradient of catalytic active(s) phase(s) from 0.01 wt % to 100 wt % preferentially from 0.1 wt % to 20 wt %, and a microstructure with a specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.Type: ApplicationFiled: June 16, 2009Publication date: May 5, 2011Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Pascal Del-Gallo, Daniel Gary, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Fabrice Rossingnol
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Publication number: 20110105304Abstract: Architecture comprising ceramic or metallic foam, characterized in that the foam has a constant axial and radial porosity between 10 to 90% with a pore size between 2 to 60 ppi, and at least one continuous and/or discontinuous, axial and/or radial concentration of catalytic active(s) phase(s) from 0.01 wt % to 100 wt %, preferentially from 0.1 to 20 wt. %, and in that the architecture has a microstructure comprising specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.Type: ApplicationFiled: June 15, 2009Publication date: May 5, 2011Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Ex ploitation Des Procedes Georges ClaudeInventors: Pascal Del-Gallo, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Daniel Gary, Fabrice Rossignol
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Patent number: 7932408Abstract: The invention is directed to a catalyst for the epoxidation of an olefin to an olefin oxide, the catalyst comprising a support having at least two pore size distributions, each pore size distribution possessing a different mean pore size and a different pore size of maximum concentration, the catalyst further comprising a catalytically effective amount of silver, a promoting amount of rhenium, and a promoting amount of one or more alkali metals, wherein the at least two pore size distributions are within a pore size range of about 0.01 ?m to about 50 ?m. The invention is also directed to a process for the oxidation of an olefin to an olefin oxide using the above-described catalyst.Type: GrantFiled: January 27, 2009Date of Patent: April 26, 2011Assignee: Scientific Design Company, Inc.Inventor: Christian Gückel
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Patent number: 7928032Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.Type: GrantFiled: December 18, 2008Date of Patent: April 19, 2011Assignee: Dow Global Technologies LLCInventors: Robin Ziebarth, Robert T. Nilsson, Steven J. Martin
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Patent number: 7910082Abstract: A method for preparing ordered mesoporous silicon carbide (OMSiC) nanocomposites uses an evaporation-induced self-assembly of a precursor composition that preferably includes a phenolic resin, pre-hydrolyzed tetraethyl orthosilicate, a surfactant, and butanol. The precursor mixture is dried, cross-linked and heated to form ordered mesoporous silicon carbide material having discrete domains of ordered, mesoscale pores.Type: GrantFiled: August 13, 2008Date of Patent: March 22, 2011Assignee: Corning IncorporatedInventors: Steven Bruce Dawes, Wageesha Senaratne
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Publication number: 20100316547Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.Type: ApplicationFiled: May 20, 2010Publication date: December 16, 2010Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
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Patent number: 7851396Abstract: A method of manufacturing a porous sintered body includes mixing first silicon carbide particles, second silicon carbide particles, and a pore forming material having an average particle diameter Y ?m to obtain a molding material. The first silicon carbide particles have an average particle diameter X ?m larger than an average particle diameter of the second silicon carbide particles. Relationships 15?X, 0.5·X?Z?0.9·X, and 0.8·Z?Y?1.8·Z are satisfied, wherein Z ?m is an average pore diameter of the porous sintered body no less than 10 ?m and no greater than 20 ?m. The molding material is molded into a molded body. The molded body is degreased to eliminate the pore forming material from the molded body.Type: GrantFiled: March 8, 2007Date of Patent: December 14, 2010Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Masafumi Kuneda, Yuki Fujita
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Publication number: 20100312032Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.51?j?120, 1?k?50, A is transition metal, and x is a number satisfying conditions according to valence of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefin by using the same.Type: ApplicationFiled: June 4, 2010Publication date: December 9, 2010Applicant: LG Chem, Ltd.Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
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Patent number: 7833936Abstract: The present invention provides a method for producing a honeycomb structure which carries a catalyst component containing at least one element selected from the group consisting of alkali metals and alkaline earth metals and purifies exhaust emissions.Type: GrantFiled: March 1, 2007Date of Patent: November 16, 2010Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Kazutake Ogyu, Masayuki Hayashi, Masafumi Kunieda
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Publication number: 20100255983Abstract: Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy.Type: ApplicationFiled: October 31, 2008Publication date: October 7, 2010Inventor: Tao Zhang
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Publication number: 20100233051Abstract: Nitrogen oxide storage catalysts are used to remove nitrogen oxides from the exhaust gas of internal combustion engines operated predominantly under lean burn conditions. When these catalysts are used in diesel vehicles, the increased sulfur content in the fuel during operation results in poisoning of the catalyst, which is reversible at high temperatures under reduced exhaust gas conditions. In the case of conventional nitrogen oxide storage catalysts, temperatures of more than 600° C. have to be obtained for desulfurization. This is not always possible in diesel vehicles with a nitrogen oxide storage catalyst in the underbody area. The invention presents a process whose application allows the desulfurization temperature of conventional nitrogen oxide storage catalysts which comprise a platinum component and at least one nitrogen oxide storage material to be lowered. The basicity of the chemical environment of the platinum is lowered, while the nitrogen oxide storage material can remain unchanged as such.Type: ApplicationFiled: April 14, 2010Publication date: September 16, 2010Inventors: Ina GRISSTEDE, Friedemann ROHR, Stephan ECKHOFF, Wilfried MUELLER, Thomas KREUZER
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Patent number: 7790650Abstract: The present invention relates to catalysts comprising at least one support and at least one layer applied to said support, said layer containing a) 20 to 95% by weight of at least one aluminum, silicon, titanium or magnesium oxide compound or a silicon carbide or a carbon support or mixtures thereof, and b) 5 to 50% by weight of at least one nanocarbon. The catalysts can be used to produce unsaturated hydrocarbons by means of the oxidative dehydrogenation of alkylaromatics, alkenes and alkanes in the gas phase.Type: GrantFiled: July 13, 2005Date of Patent: September 7, 2010Assignee: NanoC Sdn. Bhd.Inventors: Robert Schlogl, Gerhard Mestl
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Publication number: 20100222205Abstract: A method of manufacturing a catalyst body which includes: combining one or more inorganic components with an inorganic binder, and optionally with an organic binder, to form a mixture, the one or more inorganic components comprising a primary phase material being zeolite, or CeO2—ZrO2, or a combination; forming the mixture into a shaped body; firing the shaped body to allow the inorganic binder to bind the one or more inorganic components; impregnating the shaped body with a source of a reducing or oxidizing element; and heating the impregnated shaped body to form a redox oxide from the source, the redox oxide being supported by the shaped body.Type: ApplicationFiled: February 27, 2009Publication date: September 2, 2010Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil
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Publication number: 20100197484Abstract: The present invention relates to a process for preparing mineral particles (p) from mineral species precursors, said process comprising a step (E) in which a fluid medium (F) containing said precursors in solution and/or dispersed in a solvent is injected into a reactor containing CO2 in the supercritical state by way of an injection nozzle opening into a zone where the supercritical CO2 is at a temperature greater than or equal to the temperature for conversion of the precursors into corresponding mineral species. The invention also relates to the particles (p) as obtained by the process, as well as uses thereof.Type: ApplicationFiled: April 23, 2008Publication date: August 5, 2010Applicants: AREVA NP, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Beatrice Sala, Stephanie Willemin, Joel Mazoyer, Thierry Muller, Nathalie Masquelez, Didier Cot, Anne Julbe, Pierre Guillermier
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Publication number: 20100105545Abstract: A ceramic honeycomb structure includes an outer peripheral wall, partition walls provided in the form of a honeycomb inside the outer peripheral wall, and a plurality of cells partitioned by the partition walls and at least partly penetrating both ends of the structure. In the ceramic honeycomb structure, a catalyst material used for burning carbon and containing silver dispersed into layered alumina is supported on an inner surface of the plurality of cells.Type: ApplicationFiled: March 19, 2008Publication date: April 29, 2010Applicant: DENSO CORPORATIONInventor: Yasushi Hayashi
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Patent number: 7704913Abstract: A visible-light-responsive three-dimensional fine cell-structured photocatalytic filter in accordance with the present invention includes a sponge-like porous structure (B) containing an anatase-type titanium oxide coating formed on a surface of a sponge-like porous structural body (A) which has a porosity of 85 vol % or more.Type: GrantFiled: April 22, 2004Date of Patent: April 27, 2010Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Eiji Tani, Kunio Kimura
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Patent number: 7696387Abstract: The present invention relates to a novel method for preparing a catalyst for partial oxidation of methylbenzenes, comprising, (a) a step of preparing a solution or slurry of the compounds comprising tungsten; (b) a step of supporting the solution or slurry obtained in the step (a) on inorganic carrier; (c) a step of drying the catalyst obtained in the step (b); and (d) a step of calcining the dried catalyst obtained in the step (c), characterized in that the ratio of the pore volume of inorganic carrier and the volume of the solution or slurry in the step (b) is 1:0.9˜1.1, and the catalyst provides superior aromatic aldehydes selectivity to those prepared by the conventional impregnation or heat evaporation method over a wide range of conversion rate.Type: GrantFiled: May 17, 2006Date of Patent: April 13, 2010Assignee: LG Chem, Ltd.Inventors: Won Ho Lee, Dong Il Lee, Jong Hyun Chae, Hyun Kyung Yoon
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Patent number: 7662739Abstract: A catalyst body including a catalytic material containing an alkali metal and/or an alkaline earth metal, a carrier carrying the catalytic material, and a method of manufacturing the catalyst body are provided. The carrier has a cordierite binder phase and aggregate phases dispersed in the cordierite binder phase.Type: GrantFiled: October 20, 2008Date of Patent: February 16, 2010Assignee: NGK Insulators, Ltd.Inventors: Misako Fujii, Kenji Morimoto, Shinji Kawasaki
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Publication number: 20100036138Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.Type: ApplicationFiled: June 18, 2009Publication date: February 11, 2010Applicant: Mitsubishi Gas Chemical Company, Inc.Inventor: Atsushi OKAMOTO
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Patent number: 7648932Abstract: The invention relates to a process for the production of a molded porous ceramic article containing ?-SiC, which process comprises the following steps: the preparation of a molded article containing silicon and carbon and the subsequent pyrolysis and siliconization of the article containing silicon and carbon to form SiC. The invention further relates to a molded porous ceramic article containing SiC which has been produced from a molded article containing silicon and carbon.Type: GrantFiled: July 5, 2006Date of Patent: January 19, 2010Assignee: Mann+Hummel Innenraumfilter GmbH & Co. KGInventors: Lars Weisensel, Thomas Wolff, Heino Sieber, Peter Greil
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Publication number: 20090291841Abstract: A honeycomb structure includes at least one honeycomb unit and a peripheral wall at a peripheral surface connecting one end face and another end face of the honeycomb structure. The honeycomb unit includes inorganic particles, an inorganic binder, and cell walls extending along a longitudinal direction of the at least one honeycomb unit to define cells. The at least one honeycomb unit has a b-axis compression strength of about 1.0 MPa or less. A thickness T of the peripheral wall of the honeycomb structure is larger than 0.42V-0.25 (mm), where V is a volume of the honeycomb structure and in a range from about 1.0 liters to about 10 liters.Type: ApplicationFiled: February 17, 2009Publication date: November 26, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Masafumi KUNIEDA, Takahiko IDO
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Publication number: 20090247399Abstract: There are provided a catalytic diesel particulate filter that is arranged in an exhaust system of a diesel engine and includes a catalyst that burns a particulate matter contained in an exhaust gas from the diesel engine, wherein the catalyst is configured in such a manner that a ceria based catalyst coat layer 6 containing no noble metal and a noble metal based catalyst coat layer 11 containing a noble metal are separately provided on a substrate constituted of a honeycomb structure, and a method for producing the same.Type: ApplicationFiled: March 9, 2009Publication date: October 1, 2009Applicant: NGK INSULATORS, LTD.Inventors: Takashi MIZUTANI, Chika SAITO
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Publication number: 20090238733Abstract: A honeycomb structure includes at least one honeycomb member including inorganic fibers and having walls extending along a longitudinal direction to define cells. A catalyst is provided on the wall in an amount of at least about 100 g and at most about 400 g per liter of volume of the honeycomb structure. The honeycomb member has a pore distribution measured using mercury porosimetry in which a pore distribution curve has a first peak in a range from about 0.005 ?m to about 0.03 ?m of a pore diameter, a second peak in a range from about 1 ?m to about 15 ?m of the pore diameter, and a third peak in a range from about 15 ?m to about 50 ?m of the pore diameter, where the curve is drawn by plotting the pore diameter (?m) on an X-axis and a log differential pore volume (mL/g) on a Y-axis.Type: ApplicationFiled: December 30, 2008Publication date: September 24, 2009Applicant: IBIDEN CO., LTD.Inventors: Kazushige OHNO, Kazutake Ogyu, Yusuke Kondo
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Patent number: 7576035Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.Type: GrantFiled: April 7, 2008Date of Patent: August 18, 2009Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Tomokazu Oya
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Publication number: 20090198076Abstract: The invention is directed to a catalyst for the epoxidation of an olefin to an olefin oxide, the catalyst comprising a support having at least two pore size distributions, each pore size distribution possessing a different mean pore size and a different pore size of maximum concentration, the catalyst further comprising a catalytically effective amount of silver, a promoting amount of rhenium, and a promoting amount of one or more alkali metals, wherein the at least two pore size distributions are within a pore size range of about 0.01 ?m to about 50 ?m. The invention is also directed to a process for the oxidation of an olefin to an olefin oxide using the above-described catalyst.Type: ApplicationFiled: January 27, 2009Publication date: August 6, 2009Applicant: Scientific Design Company, Inc.Inventor: Christian Guckel
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Publication number: 20090163356Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.Type: ApplicationFiled: December 18, 2008Publication date: June 25, 2009Applicant: Dow Global Technologies Inc.Inventors: Robert T. Nilsson, Robin Ziebarth, Steven J. Martin
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Publication number: 20090149319Abstract: To provide a production process of an oxidation catalyst apparatus for purifying an exhaust gas which enables to oxidize and purify particulate matter in the exhaust gas of an internal combustion engine at a lower temperature. The production process of the oxidation catalyst apparatus 1 for purifying an exhaust gas comprises a step of burning a plurality of metal compounds to obtain a burnt product, a step of mixing and grinding the obtained burnt product with water and a binder which is a sol comprising zirconia to prepare a slurry, a step of applying the slurry to a porous filter base material 2, and a step of burning the porous filter base material 2 to form a porous catalyst layer 3 supported on the porous filter base material 2. The porous catalyst layer 3 has a thickness in a range of 10 to 150 ?m and fine pores having a diameter in a range of 0.01 to 5 ?m, the total porosity of and the porous filter base material 2 and the porous catalyst layer 3 have a porosity of 35 to 70% as a whole.Type: ApplicationFiled: December 4, 2008Publication date: June 11, 2009Inventors: Kiyoshi Tanaami, Yuji Isogai
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Patent number: 7534737Abstract: A selective hydrogenation process and a layered catalyst composition for use in the selective hydrogenation process are disclosed. The process is useful for the selective hydrogenation of diolefins having from about 8 to about 19 carbon atoms per molecule to monoolefins.Type: GrantFiled: June 12, 2008Date of Patent: May 19, 2009Assignee: UOP LLCInventor: Gregory J. Gajda
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Publication number: 20090111687Abstract: The invention relates to a catalyst with large surface area structure, in particular for steam-reforming catalysts, which is characterised in that the large surface area structure is formed of a large number of round or parallel penetrating holes of polygonal cross-section, wherein the catalyst carrier is prepared in the injection moulding process, coated with a washcoat and then impregnated with the active component. The catalyst carrier includes at least one sinterable material and has a lateral pressure resistance of at least 700 N. The invention further relates to a process for the preparation of such catalysts and the use thereof in a reactor.Type: ApplicationFiled: September 25, 2008Publication date: April 30, 2009Applicant: Sud-Chemie AGInventors: Wolfgang GABRIEL, Ingo HANKE
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Publication number: 20090105066Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: ApplicationFiled: May 23, 2008Publication date: April 23, 2009Applicant: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20090088317Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.Type: ApplicationFiled: September 28, 2007Publication date: April 2, 2009Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
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Publication number: 20090054227Abstract: The invention relates to a method of obtaining a homogeneous filtering structure for a catalytic application, which can be used as a particulate filter in an internal combustion engine exhaust line, said structure comprising a plurality of honeycomb filter elements in which a homogeneity criterion characteristic of the constituent support material of said elements, in the absence of a catalytic coating, is determined in a prior step, and then the elements making up the structure are selected by means of this homogeneity criterion so as to obtain a structure suitable for homogeneous deposition, within an element and from one element to another, of a catalyst for treating the pollutants in gas phase. The invention also relates to the homogeneous filtration structure obtained by said method.Type: ApplicationFiled: September 29, 2006Publication date: February 26, 2009Applicant: SAINT GOBAIN CENTRE DE RECHERCHES ET D-ETUDES EURInventors: Patricia Andy, Sebastien Bardon, Vincent Marc Gleize