Silicon Carbide Patents (Class 502/178)
  • Publication number: 20120198769
    Abstract: A catalyst-coated support including a sheetlike support, a primer layer applied thereto and composed of nanoparticles composed of silicon oxide-comprising material, and at least one catalyst layer applied to the primer layer. The layers applied are notable for a particularly good adhesive bond strength and can be used particularly efficiently in heterogeneously catalyzed gas phase reactions, especially in microreactors.
    Type: Application
    Filed: June 23, 2010
    Publication date: August 9, 2012
    Inventors: Steffen Schirrmeister, Martin Schmitz-Niederau, Ingo Klüppel, Christoph Filthaut
  • Publication number: 20120108417
    Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.
    Type: Application
    Filed: December 1, 2011
    Publication date: May 3, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
  • Publication number: 20120108416
    Abstract: A catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.
    Type: Application
    Filed: December 1, 2011
    Publication date: May 3, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
  • Publication number: 20120028166
    Abstract: It is an object to inhibit a corrosion and disappearance of carbon included in a catalyst carrier to enhance the durability of a fuel cell. A catalyst carrier is used to adhere a catalyst metal (23) to the surface of a protective layer for carbon (22), the catalyst carrier comprising carbon (21) and the protective layer for carbon (22) with which the carbon (21) is coated, the protective layer for carbon (22) comprising silicon oxide and silicon carbide. Among the protective layer for carbon (22), a vicinity part of an interface between the protective layer for carbon (22) and the carbon (21) comprises silicon carbide, and the surface part of said protective layer for carbon (22) desirably comprises silicon oxide.
    Type: Application
    Filed: July 22, 2011
    Publication date: February 2, 2012
    Inventors: Makoto MORISHIMA, Shuichi Suzuki
  • Patent number: 8105972
    Abstract: A catalyst for the oxidative dehydrogenation of a paraffin to form an olefin, the catalyst having a general formula MoaVbXcYdOn wherein: X=at least one of Nb and Ta; Y=at least one of Te, Sb, Ga, Pd, W, Bi and Al; a=1.0; b=0.05 to 1.0; c=0.001 to 1.0; d=0.001 to 1.0; and n is determined by the oxidation states of the other elements. The catalyst may have a selectivity to the olefin of at least 90 mole % at a paraffin conversion of at least 65%.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: January 31, 2012
    Assignee: Lummus Technology Inc.
    Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
  • Patent number: 8105971
    Abstract: A process for forming a catalyst useful for the production of an olefin from a hydrocarbon is disclosed. The process may include: admixing at least one of elemental metals and compounds to form a multi-metal composition comprising Mo, V, Nb, Te and at least one of Ni and Sb; adjusting the pH of the multi-metal composition by adding nitric acid; drying the acidified multi-metal composition; calcining the dried multi-metal composition; and grinding the calcined multi-metal composition. The ground multi-metal composition may then be sized or shaped to form a mixed metal oxide catalyst. Alternatively, the ground multi-metal composition may be treated with an acid, optionally annealed, and sized or shaped to form a mixed metal oxide catalyst.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: January 31, 2012
    Assignee: Lummus Technology Inc.
    Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
  • Patent number: 8093173
    Abstract: There is provided a honeycomb structure where a catalyst is loaded on surfaces of inner pores of the surface layer and on a surface of the surface layer; a relation between a catalyst area proportion A of the catalyst to a gap area proportion B of a gap in a cross-section of the surface layer on the inlet side is 1%<A/B<90%; and a relation between an average catalyst area proportion, A1, from the surface to a point having a depth of one third of the thickness of the surface layer including the surface of the surface layer on the inlet side and a catalyst area proportion A2 in a central portion of the surface layer is A1/A2>1.5.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: January 10, 2012
    Assignee: NGK Insulators, Ltd.
    Inventors: Yukio Miyairi, Takashi Mizutani, Takuya Hiramatsu
  • Publication number: 20110312488
    Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is disclosed. Generating the polyol involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.
    Type: Application
    Filed: July 28, 2011
    Publication date: December 22, 2011
    Applicant: UOP LLC
    Inventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
  • Publication number: 20110312487
    Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is performed in a continuous or batch manner. Generating the polyol involves, contacting, hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one unsupported component and at least one supported component.
    Type: Application
    Filed: July 28, 2011
    Publication date: December 22, 2011
    Applicant: UOP LLC
    Inventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
  • Publication number: 20110268634
    Abstract: The invention relates to a monolithic support member comprising channels with walls separating the channels from each other and having a coating deposited thereon, the non-coated channels having a polygonal cross-section profile, wherein the mean thickness dC of the coating in a corner of said cross-section profile is smaller than or equal to the mean thickness dE of the coating on an edge of said cross-section profile plus 85 micrometer; and further relates to a method for the preparation of such coated monolithic support member, the method comprising (i) providing a suspension having a viscosity in the range of from 0.5 to 100 mPas and having a solid content in the range of from 1 to 40 wt.
    Type: Application
    Filed: March 31, 2011
    Publication date: November 3, 2011
    Applicants: BASF Corporation, BASF SE
    Inventors: Markus Linsenbühler, Bernd Sachweh, Saadallah Nemeh, Michel Deeba, Michael Mertler, Matthias Wilhelm Meier
  • Publication number: 20110262312
    Abstract: The invention relates to a photocatalyst comprising a ?-SiC cellular foam and a photocatalytically active phase, deposited directly on said cellular foam or on an intermediate phase deposited on said cellular foam. The average size of the cells is between 2500 ?m and 5000 ?m. The foam can comprise nanotubes or nanofibers (particularly of carbon, SiC, and TiO2) that consist of, or carry as an intermediate phase, a photocatalytically active phase.
    Type: Application
    Filed: September 14, 2009
    Publication date: October 27, 2011
    Inventors: Cuong Pham-Huu, Nicolas Keller, Marc-Jacques Ledoux, Valérie Keller-Spitzer, Dominique Begin, Mathieu Grandcolas, Izabela Janowska, Shabnam Hajesmaili
  • Patent number: 8029882
    Abstract: A silicon carbide porous object includes silicon carbide as an aggregate and metal silicon as a binder, the particles of silicon carbide being bonded to one another so as to have pores thereamong. A method for producing a silicon carbide porous object includes: firing raw materials formed by mixing silicon carbide and metal silicon with metal aluminum or an alloy including metal silicon and metal aluminum in an inert gas atmosphere or a reduced-pressure atmosphere to produce a metal aluminum-metal silicon-silicon carbide porous object; and oxidizing and firing the metal aluminum-metal silicon-silicon carbide porous object in an oxygen atmosphere.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: October 4, 2011
    Assignee: NGK Insulators, Ltd.
    Inventors: Yoshio Kikuchi, Shinji Kawasaki
  • Patent number: 8022008
    Abstract: A method is provided for making a catalyst support, and includes the steps of providing an aqueous suspension of refractory inorganic oxide and refractory inorganic carbide; forming the suspension into droplets; exposing the droplets to a gelling agent whereby the droplets are at least partially solidified so as to provide substantially sphere-shaped portions of refractory inorganic oxide and refractory inorganic carbide; and drying and calcining the sphere-shaped portions so as to provide substantially spherical particles of catalyst support containing refractory inorganic oxide and refractory inorganic carbide. Catalytically active metal phases and hydrogenation processes using the catalyst are also described.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: September 20, 2011
    Assignee: Intevep, S.A.
    Inventors: Jorge M. Martinis, Maria E. Valera, Jose R. Velasquez, Angel R. Carrasquel
  • Patent number: 8017543
    Abstract: The invention relates to a method of obtaining a homogeneous filtering structure for a catalytic application, which can be used as a particulate filter in an internal combustion engine exhaust line, said structure comprising a plurality of honeycomb filter elements in which a homogeneity criterion characteristic of the constituent support material of said elements, in the absence of a catalytic coating, is determined in a prior step, and then the elements making up the structure are selected by means of this homogeneity criterion so as to obtain a structure suitable for homogeneous deposition, within an element and from one element to another, of a catalyst for treating the pollutants in gas phase. The invention also relates to the homogeneous filtration structure obtained by said method.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: September 13, 2011
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Patricia Andy, Sebastien Bardon, Vincent Marc Gleize
  • Patent number: 7977013
    Abstract: The present invention discloses nanowires for use in a fuel cell comprising a metal catalyst deposited on a surface of the nanowires. A membrane electrode assembly for a fuel cell is disclosed which generally comprises a proton exchange membrane, an anode electrode, and a cathode electrode, wherein at least one or more of the anode electrode and cathode electrode comprise an interconnected network of the catalyst supported nanowires. Methods are also disclosed for preparing a membrane electrode assembly and fuel cell based upon an interconnected network of nanowires.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: July 12, 2011
    Assignee: Nanosys, Inc.
    Inventors: Chunming Niu, Calvin Y. H. Chow, Stephen A. Empedocles, J. Wallace Parce
  • Patent number: 7977275
    Abstract: The invention proposes a particulate filter having a catalytic coating which contains two catalysts arranged one behind the other. The first catalyst is located in the gas inlet region of the filter and contains a palladium/platinum catalyst. The second catalyst is arranged downstream of the first catalyst and preferably contains platinum alone as catalytically active component. The combination of these two catalysts provides the coated filter with a good ageing stability and resistance to sulphur poisoning.
    Type: Grant
    Filed: August 13, 2005
    Date of Patent: July 12, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Marcus Pfeifer, Markus Koegel, Roger Staab, Pascal Adolph, Yvonne Demel, Tobias Kuhl, Egbert Lox, Thomas Kreuzer, Frank-Walter Schuetze
  • Publication number: 20110143929
    Abstract: To provide a photocatalyst having high selectivity and carrying out a reductive reaction with light having a longer wavelength. A photocatalyst has a structure in which a semiconductor and a substrate are joined, in which the substrate causes a catalytic reaction by transfer to the substrate of excited electrons, which are generated by applying light to the semiconductor.
    Type: Application
    Filed: August 10, 2009
    Publication date: June 16, 2011
    Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO
    Inventors: Shunsuke Sato, Takeshi Morikawa, Tomiko Mori, Shu Saeki, Tsutomu Kajino, Hiromitsu Tanaka
  • Publication number: 20110143928
    Abstract: The invention relates to a structure of the honeycomb type, made of a porous ceramic material, said structure being characterized in that the porous ceramic material of which it is composed comprises at least partly 45 to 90% by weight of silicon carbide SiC, preferably in the alpha form, and 10 to 55% by weight of a ceramic oxide phase substantially in the form of aluminum titanate Al2TiO5, said material also having a porosity greater than 10%, and a median pore diameter of between 5 and 60 microns.
    Type: Application
    Filed: May 26, 2009
    Publication date: June 16, 2011
    Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EURO
    Inventor: Carine Dien-Barataud
  • Publication number: 20110105305
    Abstract: An architecture made of a ceramic or a metallic foam has at least one continuous and/or discontinuous, axial and/or radial porosity gradient ranging from 10 to 90% associated to a pore size range from 2 to 60 ppi, at least one continuous and/or discontinuous, axial and/or radial concentration gradient of catalytic active(s) phase(s) from 0.01 wt % to 100 wt % preferentially from 0.1 wt % to 20 wt %, and a microstructure with a specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 16, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Daniel Gary, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Fabrice Rossingnol
  • Publication number: 20110105304
    Abstract: Architecture comprising ceramic or metallic foam, characterized in that the foam has a constant axial and radial porosity between 10 to 90% with a pore size between 2 to 60 ppi, and at least one continuous and/or discontinuous, axial and/or radial concentration of catalytic active(s) phase(s) from 0.01 wt % to 100 wt %, preferentially from 0.1 to 20 wt. %, and in that the architecture has a microstructure comprising specific area ranging between 0.1 to 30 m2/g, a grain size between 100 nm and 20 microns and a skeleton densification above 95%.
    Type: Application
    Filed: June 15, 2009
    Publication date: May 5, 2011
    Applicant: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Ex ploitation Des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Thierry Chartier, Mathieu Cornillac, Raphael Faure, Daniel Gary, Fabrice Rossignol
  • Patent number: 7932408
    Abstract: The invention is directed to a catalyst for the epoxidation of an olefin to an olefin oxide, the catalyst comprising a support having at least two pore size distributions, each pore size distribution possessing a different mean pore size and a different pore size of maximum concentration, the catalyst further comprising a catalytically effective amount of silver, a promoting amount of rhenium, and a promoting amount of one or more alkali metals, wherein the at least two pore size distributions are within a pore size range of about 0.01 ?m to about 50 ?m. The invention is also directed to a process for the oxidation of an olefin to an olefin oxide using the above-described catalyst.
    Type: Grant
    Filed: January 27, 2009
    Date of Patent: April 26, 2011
    Assignee: Scientific Design Company, Inc.
    Inventor: Christian Gückel
  • Patent number: 7928032
    Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: April 19, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Robin Ziebarth, Robert T. Nilsson, Steven J. Martin
  • Patent number: 7910082
    Abstract: A method for preparing ordered mesoporous silicon carbide (OMSiC) nanocomposites uses an evaporation-induced self-assembly of a precursor composition that preferably includes a phenolic resin, pre-hydrolyzed tetraethyl orthosilicate, a surfactant, and butanol. The precursor mixture is dried, cross-linked and heated to form ordered mesoporous silicon carbide material having discrete domains of ordered, mesoscale pores.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: March 22, 2011
    Assignee: Corning Incorporated
    Inventors: Steven Bruce Dawes, Wageesha Senaratne
  • Publication number: 20100316547
    Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
    Type: Application
    Filed: May 20, 2010
    Publication date: December 16, 2010
    Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
  • Patent number: 7851396
    Abstract: A method of manufacturing a porous sintered body includes mixing first silicon carbide particles, second silicon carbide particles, and a pore forming material having an average particle diameter Y ?m to obtain a molding material. The first silicon carbide particles have an average particle diameter X ?m larger than an average particle diameter of the second silicon carbide particles. Relationships 15?X, 0.5·X?Z?0.9·X, and 0.8·Z?Y?1.8·Z are satisfied, wherein Z ?m is an average pore diameter of the porous sintered body no less than 10 ?m and no greater than 20 ?m. The molding material is molded into a molded body. The molded body is degreased to eliminate the pore forming material from the molded body.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: December 14, 2010
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Masafumi Kuneda, Yuki Fujita
  • Publication number: 20100312032
    Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.51?j?120, 1?k?50, A is transition metal, and x is a number satisfying conditions according to valence of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefin by using the same.
    Type: Application
    Filed: June 4, 2010
    Publication date: December 9, 2010
    Applicant: LG Chem, Ltd.
    Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
  • Patent number: 7833936
    Abstract: The present invention provides a method for producing a honeycomb structure which carries a catalyst component containing at least one element selected from the group consisting of alkali metals and alkaline earth metals and purifies exhaust emissions.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: November 16, 2010
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Kazutake Ogyu, Masayuki Hayashi, Masafumi Kunieda
  • Publication number: 20100255983
    Abstract: Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy.
    Type: Application
    Filed: October 31, 2008
    Publication date: October 7, 2010
    Inventor: Tao Zhang
  • Publication number: 20100233051
    Abstract: Nitrogen oxide storage catalysts are used to remove nitrogen oxides from the exhaust gas of internal combustion engines operated predominantly under lean burn conditions. When these catalysts are used in diesel vehicles, the increased sulfur content in the fuel during operation results in poisoning of the catalyst, which is reversible at high temperatures under reduced exhaust gas conditions. In the case of conventional nitrogen oxide storage catalysts, temperatures of more than 600° C. have to be obtained for desulfurization. This is not always possible in diesel vehicles with a nitrogen oxide storage catalyst in the underbody area. The invention presents a process whose application allows the desulfurization temperature of conventional nitrogen oxide storage catalysts which comprise a platinum component and at least one nitrogen oxide storage material to be lowered. The basicity of the chemical environment of the platinum is lowered, while the nitrogen oxide storage material can remain unchanged as such.
    Type: Application
    Filed: April 14, 2010
    Publication date: September 16, 2010
    Inventors: Ina GRISSTEDE, Friedemann ROHR, Stephan ECKHOFF, Wilfried MUELLER, Thomas KREUZER
  • Patent number: 7790650
    Abstract: The present invention relates to catalysts comprising at least one support and at least one layer applied to said support, said layer containing a) 20 to 95% by weight of at least one aluminum, silicon, titanium or magnesium oxide compound or a silicon carbide or a carbon support or mixtures thereof, and b) 5 to 50% by weight of at least one nanocarbon. The catalysts can be used to produce unsaturated hydrocarbons by means of the oxidative dehydrogenation of alkylaromatics, alkenes and alkanes in the gas phase.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: September 7, 2010
    Assignee: NanoC Sdn. Bhd.
    Inventors: Robert Schlogl, Gerhard Mestl
  • Publication number: 20100222205
    Abstract: A method of manufacturing a catalyst body which includes: combining one or more inorganic components with an inorganic binder, and optionally with an organic binder, to form a mixture, the one or more inorganic components comprising a primary phase material being zeolite, or CeO2—ZrO2, or a combination; forming the mixture into a shaped body; firing the shaped body to allow the inorganic binder to bind the one or more inorganic components; impregnating the shaped body with a source of a reducing or oxidizing element; and heating the impregnated shaped body to form a redox oxide from the source, the redox oxide being supported by the shaped body.
    Type: Application
    Filed: February 27, 2009
    Publication date: September 2, 2010
    Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil
  • Publication number: 20100197484
    Abstract: The present invention relates to a process for preparing mineral particles (p) from mineral species precursors, said process comprising a step (E) in which a fluid medium (F) containing said precursors in solution and/or dispersed in a solvent is injected into a reactor containing CO2 in the supercritical state by way of an injection nozzle opening into a zone where the supercritical CO2 is at a temperature greater than or equal to the temperature for conversion of the precursors into corresponding mineral species. The invention also relates to the particles (p) as obtained by the process, as well as uses thereof.
    Type: Application
    Filed: April 23, 2008
    Publication date: August 5, 2010
    Applicants: AREVA NP, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Beatrice Sala, Stephanie Willemin, Joel Mazoyer, Thierry Muller, Nathalie Masquelez, Didier Cot, Anne Julbe, Pierre Guillermier
  • Publication number: 20100105545
    Abstract: A ceramic honeycomb structure includes an outer peripheral wall, partition walls provided in the form of a honeycomb inside the outer peripheral wall, and a plurality of cells partitioned by the partition walls and at least partly penetrating both ends of the structure. In the ceramic honeycomb structure, a catalyst material used for burning carbon and containing silver dispersed into layered alumina is supported on an inner surface of the plurality of cells.
    Type: Application
    Filed: March 19, 2008
    Publication date: April 29, 2010
    Applicant: DENSO CORPORATION
    Inventor: Yasushi Hayashi
  • Patent number: 7704913
    Abstract: A visible-light-responsive three-dimensional fine cell-structured photocatalytic filter in accordance with the present invention includes a sponge-like porous structure (B) containing an anatase-type titanium oxide coating formed on a surface of a sponge-like porous structural body (A) which has a porosity of 85 vol % or more.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: April 27, 2010
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Eiji Tani, Kunio Kimura
  • Patent number: 7696387
    Abstract: The present invention relates to a novel method for preparing a catalyst for partial oxidation of methylbenzenes, comprising, (a) a step of preparing a solution or slurry of the compounds comprising tungsten; (b) a step of supporting the solution or slurry obtained in the step (a) on inorganic carrier; (c) a step of drying the catalyst obtained in the step (b); and (d) a step of calcining the dried catalyst obtained in the step (c), characterized in that the ratio of the pore volume of inorganic carrier and the volume of the solution or slurry in the step (b) is 1:0.9˜1.1, and the catalyst provides superior aromatic aldehydes selectivity to those prepared by the conventional impregnation or heat evaporation method over a wide range of conversion rate.
    Type: Grant
    Filed: May 17, 2006
    Date of Patent: April 13, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Won Ho Lee, Dong Il Lee, Jong Hyun Chae, Hyun Kyung Yoon
  • Patent number: 7662739
    Abstract: A catalyst body including a catalytic material containing an alkali metal and/or an alkaline earth metal, a carrier carrying the catalytic material, and a method of manufacturing the catalyst body are provided. The carrier has a cordierite binder phase and aggregate phases dispersed in the cordierite binder phase.
    Type: Grant
    Filed: October 20, 2008
    Date of Patent: February 16, 2010
    Assignee: NGK Insulators, Ltd.
    Inventors: Misako Fujii, Kenji Morimoto, Shinji Kawasaki
  • Publication number: 20100036138
    Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
    Type: Application
    Filed: June 18, 2009
    Publication date: February 11, 2010
    Applicant: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Atsushi OKAMOTO
  • Patent number: 7648932
    Abstract: The invention relates to a process for the production of a molded porous ceramic article containing ?-SiC, which process comprises the following steps: the preparation of a molded article containing silicon and carbon and the subsequent pyrolysis and siliconization of the article containing silicon and carbon to form SiC. The invention further relates to a molded porous ceramic article containing SiC which has been produced from a molded article containing silicon and carbon.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: January 19, 2010
    Assignee: Mann+Hummel Innenraumfilter GmbH & Co. KG
    Inventors: Lars Weisensel, Thomas Wolff, Heino Sieber, Peter Greil
  • Publication number: 20090291841
    Abstract: A honeycomb structure includes at least one honeycomb unit and a peripheral wall at a peripheral surface connecting one end face and another end face of the honeycomb structure. The honeycomb unit includes inorganic particles, an inorganic binder, and cell walls extending along a longitudinal direction of the at least one honeycomb unit to define cells. The at least one honeycomb unit has a b-axis compression strength of about 1.0 MPa or less. A thickness T of the peripheral wall of the honeycomb structure is larger than 0.42V-0.25 (mm), where V is a volume of the honeycomb structure and in a range from about 1.0 liters to about 10 liters.
    Type: Application
    Filed: February 17, 2009
    Publication date: November 26, 2009
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Masafumi KUNIEDA, Takahiko IDO
  • Publication number: 20090247399
    Abstract: There are provided a catalytic diesel particulate filter that is arranged in an exhaust system of a diesel engine and includes a catalyst that burns a particulate matter contained in an exhaust gas from the diesel engine, wherein the catalyst is configured in such a manner that a ceria based catalyst coat layer 6 containing no noble metal and a noble metal based catalyst coat layer 11 containing a noble metal are separately provided on a substrate constituted of a honeycomb structure, and a method for producing the same.
    Type: Application
    Filed: March 9, 2009
    Publication date: October 1, 2009
    Applicant: NGK INSULATORS, LTD.
    Inventors: Takashi MIZUTANI, Chika SAITO
  • Publication number: 20090238733
    Abstract: A honeycomb structure includes at least one honeycomb member including inorganic fibers and having walls extending along a longitudinal direction to define cells. A catalyst is provided on the wall in an amount of at least about 100 g and at most about 400 g per liter of volume of the honeycomb structure. The honeycomb member has a pore distribution measured using mercury porosimetry in which a pore distribution curve has a first peak in a range from about 0.005 ?m to about 0.03 ?m of a pore diameter, a second peak in a range from about 1 ?m to about 15 ?m of the pore diameter, and a third peak in a range from about 15 ?m to about 50 ?m of the pore diameter, where the curve is drawn by plotting the pore diameter (?m) on an X-axis and a log differential pore volume (mL/g) on a Y-axis.
    Type: Application
    Filed: December 30, 2008
    Publication date: September 24, 2009
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Kazutake Ogyu, Yusuke Kondo
  • Patent number: 7576035
    Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: August 18, 2009
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Tomokazu Oya
  • Publication number: 20090198076
    Abstract: The invention is directed to a catalyst for the epoxidation of an olefin to an olefin oxide, the catalyst comprising a support having at least two pore size distributions, each pore size distribution possessing a different mean pore size and a different pore size of maximum concentration, the catalyst further comprising a catalytically effective amount of silver, a promoting amount of rhenium, and a promoting amount of one or more alkali metals, wherein the at least two pore size distributions are within a pore size range of about 0.01 ?m to about 50 ?m. The invention is also directed to a process for the oxidation of an olefin to an olefin oxide using the above-described catalyst.
    Type: Application
    Filed: January 27, 2009
    Publication date: August 6, 2009
    Applicant: Scientific Design Company, Inc.
    Inventor: Christian Guckel
  • Publication number: 20090163356
    Abstract: An improved soot catalyst is comprised of an alkali compound at least partially coated by a ceramic coating comprised of C bonded to a metal, semimetallic element or combination thereof. The improved soot catalyst may be employed in catalyzed Diesel particulate filters. In one method to make a catalyzed Diesel particulate filter, the improved filter is made by contacting a porous ceramic body having an alkali catalyst thereon, coating the alkali catalyst with an organic ceramic precursor, heating the ceramic body to a temperature in an atmosphere sufficient to decompose the organic ceramic precursor to form the soot catalyst on the porous ceramic body without volatilizing substantial amount of the alkali catalyst away.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 25, 2009
    Applicant: Dow Global Technologies Inc.
    Inventors: Robert T. Nilsson, Robin Ziebarth, Steven J. Martin
  • Publication number: 20090149319
    Abstract: To provide a production process of an oxidation catalyst apparatus for purifying an exhaust gas which enables to oxidize and purify particulate matter in the exhaust gas of an internal combustion engine at a lower temperature. The production process of the oxidation catalyst apparatus 1 for purifying an exhaust gas comprises a step of burning a plurality of metal compounds to obtain a burnt product, a step of mixing and grinding the obtained burnt product with water and a binder which is a sol comprising zirconia to prepare a slurry, a step of applying the slurry to a porous filter base material 2, and a step of burning the porous filter base material 2 to form a porous catalyst layer 3 supported on the porous filter base material 2. The porous catalyst layer 3 has a thickness in a range of 10 to 150 ?m and fine pores having a diameter in a range of 0.01 to 5 ?m, the total porosity of and the porous filter base material 2 and the porous catalyst layer 3 have a porosity of 35 to 70% as a whole.
    Type: Application
    Filed: December 4, 2008
    Publication date: June 11, 2009
    Inventors: Kiyoshi Tanaami, Yuji Isogai
  • Patent number: 7534737
    Abstract: A selective hydrogenation process and a layered catalyst composition for use in the selective hydrogenation process are disclosed. The process is useful for the selective hydrogenation of diolefins having from about 8 to about 19 carbon atoms per molecule to monoolefins.
    Type: Grant
    Filed: June 12, 2008
    Date of Patent: May 19, 2009
    Assignee: UOP LLC
    Inventor: Gregory J. Gajda
  • Publication number: 20090111687
    Abstract: The invention relates to a catalyst with large surface area structure, in particular for steam-reforming catalysts, which is characterised in that the large surface area structure is formed of a large number of round or parallel penetrating holes of polygonal cross-section, wherein the catalyst carrier is prepared in the injection moulding process, coated with a washcoat and then impregnated with the active component. The catalyst carrier includes at least one sinterable material and has a lateral pressure resistance of at least 700 N. The invention further relates to a process for the preparation of such catalysts and the use thereof in a reactor.
    Type: Application
    Filed: September 25, 2008
    Publication date: April 30, 2009
    Applicant: Sud-Chemie AG
    Inventors: Wolfgang GABRIEL, Ingo HANKE
  • Publication number: 20090105066
    Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.
    Type: Application
    Filed: May 23, 2008
    Publication date: April 23, 2009
    Applicant: LG Chem, Ltd.
    Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
  • Publication number: 20090088317
    Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.
    Type: Application
    Filed: September 28, 2007
    Publication date: April 2, 2009
    Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
  • Publication number: 20090054227
    Abstract: The invention relates to a method of obtaining a homogeneous filtering structure for a catalytic application, which can be used as a particulate filter in an internal combustion engine exhaust line, said structure comprising a plurality of honeycomb filter elements in which a homogeneity criterion characteristic of the constituent support material of said elements, in the absence of a catalytic coating, is determined in a prior step, and then the elements making up the structure are selected by means of this homogeneity criterion so as to obtain a structure suitable for homogeneous deposition, within an element and from one element to another, of a catalyst for treating the pollutants in gas phase. The invention also relates to the homogeneous filtration structure obtained by said method.
    Type: Application
    Filed: September 29, 2006
    Publication date: February 26, 2009
    Applicant: SAINT GOBAIN CENTRE DE RECHERCHES ET D-ETUDES EUR
    Inventors: Patricia Andy, Sebastien Bardon, Vincent Marc Gleize