And Vanadium Containing Patents (Class 502/209)
  • Patent number: 8518852
    Abstract: The present invention provides a catalyst base material and a catalyst which have high strength, high porosity or high activity and methods of producing the catalyst base material and catalyst. The present invention relates to a method of producing a catalyst base material, the method comprising dispersing or dissolving a hydrophilic polymer coagulant as a first component, a water-soluble thickener as a second component, a colloidal inorganic binder as a third component and an inorganic fiber as a fourth component in water to form a catalytic slurry or paste, supporting the catalytic slurry or paste on a net-like substrate such that the meshes of the net-like substrate are filled up with the slurry or paste, by drying and/or calcinating the substrate.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: August 27, 2013
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Naomi Imada
  • Publication number: 20130217897
    Abstract: An oxidation catalyst comprising vanadium, phosphorus, and oxygen having average vanadium valence less than about 4.10, and a method of preparing such catalyst, is provided. The catalyst has side crush strength of at least about 5 lbs. and improved yield of maleic anhydride from n-butane between about 1% and about 6% absolute. The catalyst is formed by exposing a conventional active VPO catalyst having average vanadium valence between about 4.10 and about 4.40 to an organic solvent having a dielectric constant between about 5 and about 55 under conditions that facilitate an oxidation-reduction reaction, reducing the valence of the vanadium below 4.10.
    Type: Application
    Filed: August 24, 2011
    Publication date: August 22, 2013
    Applicant: HUNTSMAN PETROCHEMICAL LLC
    Inventors: Zhiping Shan, Michael J. Mummey, William S. Frazee, Bennie A. Horrell
  • Patent number: 8513153
    Abstract: Described are catalyst compositions and methods for their preparation and use. Certain catalyst compositions can include at least one reduction catalyst and at least one oxidation catalyst. A catalyst composition as described herein is useful in providing certain benefits to a combustible fuel, such as, for example, reducing harmful emissions and/or improving overall fuel economy.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: August 20, 2013
    Assignee: UTO Environmental Products Limited
    Inventors: S. Deborah Oyler, Edward Carroll Hale, III
  • Patent number: 8481448
    Abstract: The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: July 9, 2013
    Assignee: Saudi Basic Industries Corporation
    Inventors: Wugeng Liang, David Sullivan, James W. Kauffman, Clark Rea, Joe Linzer, Shahid Shaikh
  • Publication number: 20130165671
    Abstract: A process for preparing a catalyst by selecting an active catalyst and contacting the active catalyst with one or more fluids containing an organic solvent or mixture of organic solvents. In one embodiment, each organic solvent has a dielectric constant within a range of about 5 to about 55 when measured at a temperature of 20° C. to 25° C. The catalyst thus prepared may be used in a process for preparing maleic anhydride.
    Type: Application
    Filed: February 20, 2013
    Publication date: June 27, 2013
    Applicant: HUNTSMAN PETROCHEMICAL CORPORATION
    Inventor: HUNTSMAN PETROCHEMICAL CORPORATION
  • Patent number: 8470728
    Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10:0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: June 25, 2013
    Assignee: Babcock Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
  • Publication number: 20130123517
    Abstract: The invention relates to novel silver vanadium phosphates, catalysts based on these silver vanadium phosphates and the use of these catalysts for carrying out organic reactions in the gas phase.
    Type: Application
    Filed: November 9, 2012
    Publication date: May 16, 2013
    Applicant: BASF SE
    Inventors: Andrey Karpov, Cornelia Katharina Dobner, Frank Rosowski, Patrick Hubach, Robert Glaum, Stephan Schunk, Gerhard Cox
  • Publication number: 20130102455
    Abstract: A process for the preparation of a promoted VPO catalyst, wherein the catalyst comprises the mixed oxides of vanadium and phosphorus and wherein the catalyst is promoted with at least one of niobium, cobalt, iron, zinc, molybdenum or titanium, said process comprising the steps of (i) preparing a VPO catalyst comprising vanadyl pyrophosphate as the major component and containing less than 5 wt % of vanadyl phosphate, (ii) contacting the VPO catalyst with a solution comprising a metal source compound of at least one metal selected from the group consisting of niobium, cobalt, iron, zinc, molybdenum or titanium to form a metal impregnated VPO catalyst, and (iii) drying the metal impregnated VPO catalyst to form the promoted VPO catalyst. In one embodiment, a niobium promoted VPO catalyst is prepared.
    Type: Application
    Filed: October 25, 2011
    Publication date: April 25, 2013
    Inventors: Muin S. Haddad, Robert A. Gustaferro
  • Patent number: 8415268
    Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: April 9, 2013
    Assignee: BASF SE
    Inventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
  • Patent number: 8410013
    Abstract: Provided is a catalyst for treating exhaust gas capable of reducing the amount of a highly corrosive mercury-chlorinating agent to be added while keeping the mercury oxidation efficiency high in an exhaust gas treatment. By the catalyst for treating exhaust gas, nitrogen oxide in the exhaust gas is removed upon contact with ammonia serving as a reducing agent, and mercury is oxidized using a halogen serving as an oxidant. The catalyst includes: TiO2 as a support; an oxide of at least one selected from the group consisting of V, W and Mo, which is supported as an active component on the support; and at least one selected from the group consisting of Bi, P, and compounds containing Bi and/or P, which is supported as a co-catalyst component on the support.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: April 2, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsumi Nochi, Yoshiaki Obayashi, Masashi Kiyosawa
  • Publication number: 20130079553
    Abstract: In one embodiment, the invention is to a catalyst composition comprising vanadium and titanium. The catalyst composition has a surface area of at least 22.6 m2/g and a plurality of pores, and the plurality of pores have a pore diameter of less than 11.9 nm.
    Type: Application
    Filed: September 22, 2011
    Publication date: March 28, 2013
    Applicant: Celanese International Corporation
    Inventors: Heiko Weiner, Josefina T. Chapman, Alexandra S. Locke, Craig J. Peterson, Mark O. Scates, Dick Nagaki
  • Patent number: 8404614
    Abstract: A process for preparing a catalyst by selecting an active catalyst and contacting the active catalyst with one or more fluids containing an organic solvent or mixture of organic solvents. In one embodiment, each organic solvent has a dielectric constant within a range of about 5 to about 55 when measured at a temperature of 20° C. to 25° C. The catalyst thus prepared may be used in a process for preparing maleic anhydride.
    Type: Grant
    Filed: October 22, 2008
    Date of Patent: March 26, 2013
    Assignee: Huntsman Petrochemical LLC
    Inventor: Zhiping Shan
  • Publication number: 20130072716
    Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
    Type: Application
    Filed: September 16, 2011
    Publication date: March 21, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: David William Norman, Greg Alan King
  • Publication number: 20130072715
    Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
    Type: Application
    Filed: September 16, 2011
    Publication date: March 21, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: David William Norman, Gerald Charles Tustin, Michael James Nash, Lui Deng, Theresa Sims Barnette
  • Publication number: 20130053599
    Abstract: In one embodiment, the invention is to a catalyst composition comprising titanium, phosphorus, and less than 1 wt. % vanadium. The catalyst composition has a molar ratio of phosphorus to titanium of at least 1.0:1.0.
    Type: Application
    Filed: August 22, 2011
    Publication date: February 28, 2013
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Heiko Weiner, Josefina T. Chapman, Alexandra S. Locke, Dick Nagaki, Craig J. Peterson, Mark O. Scates
  • Patent number: 8383543
    Abstract: The invention relates to a bulk multi-metallic catalyst for hydrotreating heavy oil feeds and to a method for preparing the catalyst. The bulk multi-metallic catalyst is prepared by sulfiding a catalyst precursor having a poorly crystalline structure with disordered stacking layers, with a type IV adsorption-desorption isotherms of nitrogen with a hysteresis starting point value of about 0.35, for a sulfided catalyst that will facilitate the reactant's and product's diffusion in catalytic applications. In another embodiment, the precursor is characterized as having a type H3 hysteresis loop. In a third embodiment, the hysteresis loop is characterized as having a well developed plateau above P/Po of about 0.55. The mesapores of the precursor can be adjustable or tunable.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: February 26, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Theodorus Maesen, Alexander E. Kuperman, Dennis Dykstra
  • Patent number: 8357625
    Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: January 22, 2013
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Atsushi Okamoto
  • Publication number: 20130004397
    Abstract: In light of the fact that a catalyst of the prior art rapidly deteriorates in an exhaust gas of biomass combustion, the present invention realizes a NOX reduction catalyst which is less likely to be deteriorated even if used in a treatment of an exhaust gas containing a high concentration of potassium component in a combustion ash, like an exhaust gas of biomass combustion, and provides a method for reduction of NOX in an exhaust gas of biomass combustion with high efficiency for a long period using the catalyst.
    Type: Application
    Filed: February 9, 2011
    Publication date: January 3, 2013
    Inventor: Yasuyoshi Kato
  • Patent number: 8343887
    Abstract: A catalyst precursor composition and methods for making such catalyst precursor is disclosed. In one embodiment, the catalyst precursor is of the general formula Av[(MP)(OH)x(L)ny]z(MVIBO4), wherein MP is selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof; L is one or more oxygen-containing ligands, and L has a neutral or negative charge n<=0, MVIB is at least a Group VIB metal having an oxidation state of +6; MP:MVIB has an atomic ratio between 100:1 and 1:100; v?2+P*z?x*z+n*y*z=0; and 0?y??P/n; 0?x?P; 0?v?2; 0?z. In one embodiment, the catalyst precursor further comprises a cellulose-containing material. In another embodiment, the catalyst precursor further comprises at least a diluent (binder). In one embodiment, the diluent is a magnesium aluminosilicate clay.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: January 1, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Theodorus Ludovicus Michael Maesen, Alexander E. Kuperman
  • Publication number: 20120323026
    Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 ?m, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 ?m, and a water absorption of 10-80%.
    Type: Application
    Filed: February 24, 2011
    Publication date: December 20, 2012
    Inventors: John Robert Lockemeyer, Marek Matusz, Randall Clayton Yeates
  • Patent number: 8323597
    Abstract: Provided are a catalyst for removing mercury metal, which has high activity for a long time even in an exhaust gas containing SO2, and a method for oxidizing mercury metal using the catalyst. A method for purifying exhaust gas, including bringing an exhaust gas containing mercury metal into contact with a catalyst containing titanium oxide as a first component and a sulfate or phosphate of nickel (Ni), manganese (Mn) or vanadium as a second component, at a temperature of from 100° C. to 200° C., and thereby oxidizing the mercury metal.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: December 4, 2012
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventor: Yasuyoshi Kato
  • Publication number: 20120289743
    Abstract: In one embodiment, the invention is to a catalyst composition comprising vanadium, titanium; and at least one oxide additive. The at least one oxide additive is present in an amount of at least 0.1 wt % based on the total weight of the catalyst composition. The molar ratio of titanium to metal additive in an active phase of the catalyst composition is at least 0.05:1.
    Type: Application
    Filed: May 11, 2011
    Publication date: November 15, 2012
    Applicant: Celanese International Corporation
    Inventors: Dick Nagaki, Heiko Weiner, Josefina T. Chapman, Mark O. Scates, Alexandra S. Locke, Craig J. Peterson
  • Publication number: 20120277466
    Abstract: In one embodiment, the invention is to a catalyst composition, comprising vanadium and titanium. Preferably, the molar ratio of vanadium to titanium in an active phase of the catalyst composition is greater than 0.5:1.
    Type: Application
    Filed: April 27, 2011
    Publication date: November 1, 2012
    Applicant: Celanese International Corporation
    Inventors: Dick Nagaki, Heiko Weiner, Josefina T. Chapman, Mark O. Scates, Alexandra S. Locke, Craig J. Peterson
  • Patent number: 8298981
    Abstract: An improved process to produce high surface area nanoparticle vanadium phosphorus oxide catalysts comprises the steps of reducing vanadium-containing compounds in an alcohol solution selected from the group consisting of isobutanol and benzyl alcohol and any combination derives thereof under reflux for 4 to 6 hours to form a suspended mixture; reacting dopants and phosphorus-containing compounds to the suspended mixture under reflux for 30 minutes to 3 hours to form precursors of the vanadium phosphorus oxide catalysts; drying the formed precursors; and calcining the dried precursors in a flow of gaseous n-butane/air mixture at 400 to 460° C. to form activated vanadium phosphorus oxide catalysts.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: October 30, 2012
    Assignee: Universiti Putra Malaysia
    Inventors: Yun Hin Taufiq-Yap, Ali Asghar Rownaghi
  • Publication number: 20120245365
    Abstract: A method for producing phthalic anhydride by catalytic gas-phase oxidation of o-xylene and/or naphthalene, carried out by means of a catalyst arrangement which has a first catalyst layer at the gas inlet side and at least one second catalyst layer after the first catalyst layer in the gas flow direction with different catalytic activity, wherein when the gas-phase oxidation is being carried out a lower maximum temperature is formed in the first catalyst layer than in the second catalyst layer. Furthermore, a method for producing the catalyst arrangement, as well as the catalyst arrangement itself.
    Type: Application
    Filed: September 8, 2010
    Publication date: September 27, 2012
    Applicant: SUD-CHEMIE AG
    Inventors: Hans-Jörg Wölk, Gerhard Mestl
  • Publication number: 20120245397
    Abstract: An olefin hydration catalyst and method for producing same is provided. The olefin hydration catalyst can be prepared by contacting a niobium containing compound with a strong Bronsted acid, such as sulfuric or phosphoric acid, to produce niobium oxo sulfate or niobium oxo phosphate nanoparticles. The nanoparticles can be separated, dried and utilized in a reactor for the hydration of olefins to their corresponding alcohols.
    Type: Application
    Filed: March 21, 2011
    Publication date: September 27, 2012
    Applicant: Saudi Arabian Oil Company
    Inventors: Abdennour Bourane, Stephan Ralf Vogel, Wei Xu
  • Patent number: 8252709
    Abstract: An object of the present invention is to provide a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, with which sulfur compounds in the hydrocarbon oil can be desulfurized to a high degree and which simultaneously is extremely effective in reducing the wax deposit content; a process for producing the catalyst; and a method of hydrotreatment with the catalyst. The invention relates to a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, comprising a support comprising an inorganic oxide containing at least one crystalline aluminosilicate having a one- or two-dimensional pore path system and, having provided thereon, 10 to 35% by mass of a metal in Group 6 of the Periodic Table, 1 to 10% by mass of a metal in Group 8 of the Periodic Table, and 1.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: August 28, 2012
    Assignee: Cosmo Oil Co., Ltd.
    Inventors: Yoshinori Kato, Hiroshi Kimura, Kazuyuki Kiriyama, Takashi Fujikawa
  • Patent number: 8242041
    Abstract: The invention includes a method for impregnating a molecular sieve primary catalyst with an aromatic co-catalyst, the method comprising contacting the small pore molecular sieve primary catalyst having a porous framework structure with a combination of from at least 50 wt % to about 99.9 wt % of an aromatic co-catalyst and from about 0.1 wt % to less than 50 wt % of a polar impregnation agent containing one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, phosphorus, and boron, under conditions sufficient to impregnate the porous framework structure of the primary catalyst with the aromatic co-catalyst (and optionally also with the polar impregnation agent), thus forming an integrated catalyst system. Methods for converting oxygenates to olefins using said integrated catalyst system are also described herein.
    Type: Grant
    Filed: January 12, 2009
    Date of Patent: August 14, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stephen H. Brown, Guang Cao, Teng Xu
  • Patent number: 8242043
    Abstract: A process for production of a supported catalyst that, when used for production of lower aliphatic carboxylic acids from oxygen and lower olefins, improves yields of the lower aliphatic carboxylic acids and minimizes production of carbon dioxide gas (CO2) by-product compared to the prior art. A compound comprising at least one element selected from elements of Groups 8, 9 and 10 of the Periodic Table, at least one chloride of an element selected from copper, silver and zinc, and a chloroauric acid salt, are loaded on a carrier, after which there are further loaded a compound comprising at least one element selected from gallium, indium, thallium, germanium, tin, lead, phosphorus, arsenic, antimony, bismuth, sulfur, selenium, tellurium and polonium, and a heteropoly acid.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: August 14, 2012
    Assignee: Showa Denko K.K.
    Inventor: Atsuyuki Miyaji
  • Patent number: 8232224
    Abstract: Methods for preparing catalysts for oxidation of unsaturated and/or saturated aldehydes to unsaturated acids is disclosed where the catalyst includes at least molybdenum (Mo), phosphorus (P), vanadium (V), bismuth (Bi), where the bismuth component was dissolved in an organic acid solution prior to adding the bismuth containing solution to a solution of the other components.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: July 31, 2012
    Assignee: Saudi Basic Industries Corporation
    Inventors: Wugeng Liang, Scott A. Stevenson, Angie McGuffey
  • Patent number: 8207080
    Abstract: The invention concerns a compound comprising a combination of two crystal phases. The first crystal phase corresponds to the formula: AaEbVcModPeOfHg wherein A is an alkali-metal; E is Te, Sb or Bi; and 0?a?3, 0<b?3, 0?c?3, 0<d?13, 0<e?2, 0?g?3. The second crystal phase corresponds to the formula ZgMohXiOj wherein: Z is selected among trivalent rare earths; X is selected among the elements V, Ga, Fe, Bi, Ce, Ti, Sb, Mn, Zn, Te; and 0<g?3, 0?h?3, 0?i?1. The indices f and j represent the number of oxygen atoms required for satisfying the relative valency and atomic proportions of the elements present. The invention also concerns the method for preparing said compound, and its use in particular as catalyst for oxidizing alkanes.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: June 26, 2012
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Jean-Marc Millet, Phillippe Lacorre, Quyen Huynh
  • Publication number: 20120149919
    Abstract: A process for preparing a vanadium, phosphorus, and oxygen comprising catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms, which comprises (a) reacting vanadium pentoxide with 102% to 110% strength phosphoric acid in the presence of isobutanol and optionally of a primary or secondary, noncyclic or cyclic, unbranched or branched, saturated alcohol having 3 to 6 carbon atoms in a temperature range from 80 to 160° C.; (b) isolating the precipitate formed; (c) (i) drying the isolated precipitate down to a residual isobutanol content of less than 5% by weight; (ii) then passing a gas which in addition to one or more inert gases comprises 0.1% to 9% by volume of oxygen through the dried precipitate, directly or after isolation, in the temperature range from 130° C. to 200° C.
    Type: Application
    Filed: August 23, 2010
    Publication date: June 14, 2012
    Applicant: BASF SE
    Inventors: Stefan Altwasser, Cornelia Katharina Dobner, Hagen Wilmer, Frank Rosowski
  • Publication number: 20120088654
    Abstract: A mesoporous oxide composition includes, other than oxygen, a major amount of aluminum and lesser amounts of phosphorus and at least one rare earth element. The compositions have high surface area and excellent thermal and hydrothermal stability, with a relatively narrow pore size distribution in the mesoporous range. These compositions may be prepared by a hydrothermal co-precipitation method using an organic templating agent. These mesoporous oxide compositions may be used as catalysts or as supports for catalysts, for example, in a fluid catalytic cracking process.
    Type: Application
    Filed: October 8, 2010
    Publication date: April 12, 2012
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Kun Wang, Robert C. Lemon
  • Patent number: 8143461
    Abstract: The present invention provides a process for producing a vanadium/phosphorus oxide catalyst by (i) preparing a catalyst precursor powder containing vanadium, phosphorus and an optional promoter element; (ii) converting the catalyst precursor powder into an activated catalyst by heat treatment; (iii) and compressing the activated catalyst into a desired shape to form the vanadium/phosphorus oxide catalyst. The vanadium/phosphorus oxide catalyst may be used in the production of maleic anhydride by the catalytic oxidation of hydrocarbon feed streams.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: March 27, 2012
    Assignee: Huntsman Petrochemical LLC
    Inventor: Matthew W. Forkner
  • Publication number: 20120071671
    Abstract: The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe.f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d=4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 AA (+?0.
    Type: Application
    Filed: May 28, 2010
    Publication date: March 22, 2012
    Applicant: BASF SE
    Inventors: Andrey Karpov, Hartmut Hibst, Christine Deißler, Cornelia Katharina Dobner, Frank Rosowski, Nadine Brem, Stephan Schunk
  • Patent number: 8137591
    Abstract: The present invention relates to a catalyst composition for preparing carbon nanotube containing multi-component support materials of amorphous Si, Mg and Al as well as a bulk scale preparation process for preparing carbon nanotube using said catalyst composition. More specifically, this invention relates to a process for preparing carbon nanotube using the catalyst composition comprising a transition metal catalyst and support materials of amorphous Si, Mg and Al.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: March 20, 2012
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Dong Hwan Kim, Sang-Hyo Ryu, Wan Sung Lee, Namsun Choi, Hyun-Kyung Sung, Youngchan Jang
  • Publication number: 20120065427
    Abstract: An object of the present invention is to provide a process for stably producing a catalyst for methacrylic acid production exhibiting high activity and high performance. The process for producing a catalyst for methacrylic acid production of the invention is characterized in that the water content of the catalyst ingredient powder for use in molding, temperature and humidity of a molding step, humidity and temperature of a baking step are individually controlled in the case where molding is performed by a coating method using an Mo—V—P—Cu-based hetero polyacid as an active ingredient and water or an alcohol and/or an aqueous solution of an alcohol as a binder.
    Type: Application
    Filed: November 17, 2011
    Publication date: March 15, 2012
    Applicant: NIPPONKAYAKU KABUSHIKIKAISHA
    Inventors: Atsushi Sudo, Kazuo Shiraishi, Hideki Sugi, Hiroyoshi Nowatari, Fumio Sakai, Tomoaki Kobayashi, Tatsuhiko Kurakami
  • Patent number: 8114805
    Abstract: The present invention relates to a method of preparing a heteropoly acid catalyst used for the production of methacrylic acid by gas phase oxidation of methacrolein, more precisely a method of preparing a heteropoly acid catalyst comprising the steps of preparing a slurry by adding metal precursors and ammonium salt to protonic acid Keggin-type heteropoly acid aqueous solution and stirring thereof; and drying, molding and firing the slurry to give a catalyst. The present invention provides a method of preparing a heteropoly acid catalyst exhibiting high methacrolein conversion rate and methacrylic acid selectivity without pre-firing process by using high purity protonic acid Keggin-type heteropoly acid and ammonium salt.
    Type: Grant
    Filed: June 13, 2008
    Date of Patent: February 14, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Hyun-Kuk Noh, Hyun-jong Shin, Won-ho Lee, Byung-yul Choi, Gyo-hyun Hwang, Ju-yeon Park, Duk-ki Kim, Young-hyun Choe, Min-ho Kil, Min-suk Kim, Young-jin Cho, Sung-chul Lim
  • Publication number: 20120027666
    Abstract: Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.
    Type: Application
    Filed: March 17, 2010
    Publication date: February 2, 2012
    Applicant: EMORY UNIVERSITY
    Inventors: Craig L Hill, Yurii V Gueletii, Djamaladdin G. Musaev, Qiushi Yin, Bogdan Botar
  • Publication number: 20120022291
    Abstract: A process for converting glycerin into valuable chemical raw material. A catalyst for use in the production of acrolein and acrylic acid by a dehydration reaction of glycerin, which enables the production of acrolein and acrylic acid in high yield. Glycerin dehydration catalyst which mainly comprises a phosphorus-vanadium complex oxide that contains phosphorus and vanadium as the essential constituent elements.
    Type: Application
    Filed: October 20, 2009
    Publication date: January 26, 2012
    Applicant: Arkema France
    Inventors: Yasuhiro Magatani, Kimito Okumura, Jean Luc Dubois
  • Publication number: 20120016159
    Abstract: The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.
    Type: Application
    Filed: July 19, 2010
    Publication date: January 19, 2012
    Applicant: Saudi Basic Industries Corporation
    Inventors: Wugeng Liang, David Sullivan, James W. Kauffman, Clark Rea, Joe Linzer, Shahid Shaikh
  • Patent number: 8080492
    Abstract: A catalyst precursor for preparing a bulk multi-metallic catalyst upon sulfidation is provided. The precursor has an essentially monomodal pore volume distribution with at least 90% of the pores being macropores, and a total pore volume of at least 0.08 g/cc. The bulk multi-metallic prepared from the precursor is particularly suitable for hydrotreating heavy oil feeds having a boiling point in the range of 343° C. (650° F.)—to 454° C. (850° F.), an average molecular weight Mn ranging from 300 to 400, and an average molecular diameter ranging from 0.9 nm to 1.7 nm.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: December 20, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra, Soy Uckung, Darren Fong
  • Patent number: 8058203
    Abstract: A method for preparing a bulk multi-metallic suitable for hydrotreating heavy oil feeds is provided. In the process of preparing the catalyst precursor which is subsequently sulfided to form the bulk catalyst, non-agglomerative drying is employed to keep the catalyst precursor from aggregating/clumping, resulting in a catalyst precursor with optimum porosity with at least 90% of the pores being macropores, and having a total pore volume of at least 0.08 g/cc.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: November 15, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis Dykstra, Theodorus Maesen, Alexander E. Kuperman, Soy Uckung, Darren Fong
  • Patent number: 8053386
    Abstract: The present invention relates to a heteropoly acid catalyst which is used for the production of methacrylic acid by gas phase oxidation of methacrolein and a preparing method thereof. The present invention, thereby, provides a novel heteropoly acid catalyst having excellent methacrolein conversion rate, methacrylic acid selectivity and yield.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: November 8, 2011
    Assignee: LG Chem, Ltd.
    Inventors: Gyo-hyun Hwang, Min-ho Kil, Hyun-kuk Noh, Won-ho Lee, Min-suk Kim
  • Patent number: 8048820
    Abstract: The invention relates to a shaped catalyst body for preparing maleic anhydride, which comprises mixed oxides of vanadium and of phosphorus as catalyst components. To develop a generic shaped catalyst body further so that it has improved properties, it is proposed that the basic geometric body enveloping the shaped catalyst body (100; 200) be a prism (180) having a first triangular face and a second triangular face and the shaped catalyst body (100; 200) be provided with three through openings (111, 121, 131; 211, 221, 231) which extend from a first face of the shaped body (100; 200) which contacts the first triangular face of the prism (180) to a second face of the shaped body (100; 200) which contacts the second triangular face of the prism (180).
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: November 1, 2011
    Assignee: Sud-Chemie AG
    Inventors: Willi Brandstädter, Leopold Streifinger, Marvin Estenfelder
  • Publication number: 20110257413
    Abstract: The invention relates to a catalyst molded body for preparing maleic anhydride by gas-phase oxidation of a hydrocarbon having at least four carbon atoms using a catalytically active composition contains vanadium, phosphorus and oxygen, where the shaped catalyst body has an essentially cylindrical body having a longitudinal axis, wherein the cylindrical body has at least two parallel internal holes which are essentially parallel to the cylinder axis of the body and go right through the body. The catalyst molded body has a large outer surface area, a lower pressure loss and sufficient mechanical stability.
    Type: Application
    Filed: December 21, 2009
    Publication date: October 20, 2011
    Applicant: BASF SE
    Inventors: Cornelia Katharina Dobner, Stefan Altwasser, Hagen Wilmer, Frank Rosowski
  • Publication number: 20110257414
    Abstract: The catalytically active mass of a catalyst molded body comprises a multi-element oxide containing vanadium and phosphorus. The specific pore volume PV (in ml/g) of the catalyst molded body, the bulk density p of the catalyst molded body (in kg/l), the geometric surface area Ageo (in mm2), and the geometric volume Vgeo (in mm3) of the catalyst molded body satisfy the condition 0.275<PV·?·Ageo/Vgeo. In a method for producing maleic acid anhydride by heterogeneously catalytic gas phase oxidation of a hydrocarbon, the catalyst molded body allows a lower pressure loss and a high yield.
    Type: Application
    Filed: December 21, 2009
    Publication date: October 20, 2011
    Applicant: BASF SE
    Inventors: Cornelia Katharina Dobner, Stefan Altwasser, Hagen Wilmer, Frank Rosowski
  • Publication number: 20110250114
    Abstract: A vanadia-based catalytic composition for reduction of nitrogen oxides includes a titania-based support material; vanadia deposited on the titania-based support material; a primary promoter comprising tungsten oxide, molybdenum oxide or combinations thereof; and an amount of phosphate to achieve a mole ratio of phosphorus to vanadium plus molybdenum of about 0.2:1 or greater. A zirconia, tin or manganese oxide can be added to further inhibit the volatility of molybdenum. Results show low SO2 oxidation rates and excellent NOx conversion and/or molybdenum stability.
    Type: Application
    Filed: April 13, 2010
    Publication date: October 13, 2011
    Inventors: Steve M. Augustine, Modasser El-Shoubary, Dennis Clark
  • Publication number: 20110230668
    Abstract: A catalyst for gas phase oxidations comprises an inert support and a catalytically active material which comprises vanadium oxide and titanium dioxide and has been applied thereto. The titanium dioxide has a content of sulfur compounds, calculated as S, of less than 1000 ppm and a content of calcium compounds, calculated as Ca, of less than 150 ppm. The catalyst has a relatively high activity and/or selectivity and thus enables relatively high yields of the desired target product, for example phthalic anhydride. Also described is a process for preparing phthalic anhydride, wherein a gas stream which comprises molecular oxygen and o-xylene, naphthalene or mixtures thereof is contacted with the catalyst.
    Type: Application
    Filed: March 21, 2011
    Publication date: September 22, 2011
    Applicant: BASF SE
    Inventors: Stefan Altwasser, Christine Deißler, Andrey Karpov, Cornelia Katharina Dobner, Bastian Ewald, Frank Rosowski, Hagen Wilmer
  • Publication number: 20110201830
    Abstract: Embodiments of the present invention disclose improved micro-pore catalyst structures containing catalytic material comprised of mixed oxides of vanadium and phosphorus and using such improved micro-pore catalyst structures for the production of maleic anhydride.
    Type: Application
    Filed: October 8, 2009
    Publication date: August 18, 2011
    Applicant: Huntsman Petrochemical LLC
    Inventor: Zhiping Shan