Platinum Group (i.e., Ru, Rh, Pd, Os, Ir Or Pt) Patents (Class 502/261)
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Patent number: 9486786Abstract: A supported catalyst having an atomic level single atom structure is provided such that substantially all the catalyst is available for catalytic function. A process of forming a single atom catalyst unto a porous catalyst support is also provided.Type: GrantFiled: July 2, 2010Date of Patent: November 8, 2016Assignee: SAVANNAH RIVER NUCLEAR SOLUTIONS, LLCInventors: Xin Xiao, William L. West, William D. Rhodes
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Patent number: 9468913Abstract: The present invention relates to a catalyst for preparation of chlorine by catalytic gas phase oxidation of hydrogen chloride with oxygen, in which the catalyst comprises at least tin dioxide as a support material and at least one ruthenium-containing compound as a catalytically active material, and comprises, as an additional secondary constituent, a compound of an element or an element selected from the group of: Nb, V, Ta, Cr, Mo, Au, In, Sc, Y and lanthanoids, especially La and Ce.Type: GrantFiled: August 22, 2011Date of Patent: October 18, 2016Assignee: Covestro Deutschland AGInventors: Aurel Wolf, Leslaw Mleczko, Oliver Felix-Karl Schlüter
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Patent number: 9403151Abstract: An Oxygen Ion Conductor (OIC)/Oxygen Storage (OS) material is disclosed, more particularly an OIC/OS having a stable cubic crystal structure, related to a method for the promotion of the catalytic properties of OIC/OS by the post-synthetic introduction of non-precious metals via a basic (alkaline) exchange process and the application of said materials to control of vehicle exhaust emissions.Type: GrantFiled: January 30, 2009Date of Patent: August 2, 2016Assignee: UMICORE AG & CO. KGInventors: Barry W. L. Southward, Curt Ellis
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Patent number: 9034269Abstract: The present invention relates to a diesel oxidation catalyst comprising a carrier substrate, and a first washcoat layer disposed on the substrate, the first washcoat layer comprising palladium supported on a support material comprising a metal oxide, gold supported on a support material comprising a metal oxide, and a ceria comprising compound, as well as a process for the preparation of such catalyst.Type: GrantFiled: November 27, 2013Date of Patent: May 19, 2015Assignee: BASF SEInventors: Marcus Hilgendorff, Alfred H. Punke, Torsten W. Müller-Stach, Gerd Grubert, Torsten Neubauer, Jeffrey B. Hoke
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Patent number: 9034286Abstract: An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.Type: GrantFiled: November 21, 2013Date of Patent: May 19, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: David Bergeal, Andrew Francis Chiffey, John Benjamin Goodwin, Daniel Hatcher, Francois Moreau, Agnes Raj, Raj Rao Rajaram, Paul Richard Phillips, Cathal Prendergast
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Patent number: 9018129Abstract: Disclosed is an exhaust gas purifying catalyst in which grain growth of a noble metal particle supported on a support is suppressed. Also disclosed is a production process for producing an exhaust gas purifying catalyst. The exhaust gas purifying catalyst comprises a crystalline metal oxide support and a noble metal particle supported on the support, wherein the noble metal particle is epitaxially grown on the support, and wherein the noble metal particle is dispersed and supported on the outer and inner surfaces of the support. The process for producing an exhaust gas purifying catalyst comprises masking, in a solution, at least a part of the surface of a crystalline metal oxide support by a masking agent, introducing the support into a noble metal-containing solution containing a noble metal, and drying and firing the support and the noble metal-containing solution to support the noble metal on the support.Type: GrantFiled: December 12, 2013Date of Patent: April 28, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masao Watanabe, Oji Kuno, Nobusuke Kabashima, Keisuke Kishita, Noboru Otake, Hiromochi Tanaka
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Patent number: 9012353Abstract: Disclosed are three-way catalysts that are able to simultaneously convert nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas emissions into less toxic compounds. Also disclosed are three-way catalyst formulations comprising palladium (Pd)-containing oxygen storage materials. In some embodiments, the three-way catalyst formulations of the invention do not contain rhodium. Further disclosed are improved methods for making Pd-containing oxygen storage materials. The relates to methods of making and using three-way catalyst formulations of the invention.Type: GrantFiled: August 8, 2012Date of Patent: April 21, 2015Assignee: Clean Diesel Technologies, Inc.Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless, Johnny T. Ngo
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Patent number: 9011809Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: February 24, 2012Date of Patent: April 21, 2015Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Takashi Hihara, Makoto Nagata
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Patent number: 9012352Abstract: The present invention relates to a catalyst for Fischer-Tropsch synthesis which has excellent heat transfer capability. This catalyst contains (1) central core particle or particles made of a heat transfer material (HTM) selected from the group consisting of a metal, a metal oxide, a ceramic, and a mixture thereof; and (2) outer particle layer which surrounds the central core particles and is attached to the surfaces of the central core particles by a binder material layer. The outer particle layer has a support and catalyst particles in a powder form containing metal particles disposed on the support. The catalyst having such a dual particle structure shows excellent heat transfer capability and, thus, exhibits high selectivity to a target hydrocarbon. Therefore, the catalyst of the present invention is useful in a fixed-bed reactor for Fischer-Tropsch synthesis for producing hydrocarbons from synthetic gas.Type: GrantFiled: April 25, 2012Date of Patent: April 21, 2015Assignee: Korea Research Institute of Chemical TechnologyInventors: Kyoung Su Ha, Joo Young Cheon, Yun Jo Lee, Seung-Chan Baek, Geun Jae Kwak, Seon Ju Park, Ki Won Jun
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Patent number: 8986637Abstract: An emission control catalyst composition comprising a supported bimetallic catalyst consisting of gold and a metal selected from the group consisting of platinum, rhodium, ruthenium, copper and nickel is disclosed. Also disclosed is a catalytic convertor comprising a substrate monolith coated with the emission control catalyst composition and a lean burn internal combustion engine exhaust gas emission treatment system comprising the catalytic convertor. A variety of processes for preparing the catalyst composition are claimed.Type: GrantFiled: November 6, 2013Date of Patent: March 24, 2015Assignee: Johnson Matthey Public Limited CompanyInventors: Janet Mary Fisher, David Thompsett
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Patent number: 8980783Abstract: Disclosed is a catalyst for converting nitrogen oxide into ammonia, which is capable of converting nitrogen oxide into ammonia under fuel lean exhaust gas conditions of more than theoretical air-fuel ratio (A/F=14.7), and a method for manufacturing the same. The catalyst according to the present invention comprises a metal oxide support impregnated with a precious metal, such that conversion of nitrogen oxide into ammonia under fuel lean exhaust gas conditions of more than theoretical air-fuel ratio (A/F=14.7) is possible.Type: GrantFiled: August 23, 2012Date of Patent: March 17, 2015Assignees: Hyundai Motor Company, Postech Academy-Industry FoundationInventors: Jin Woo Choung, In-Sik Nam, Dal Young Yoon, Iljeong Heo
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Patent number: 8951931Abstract: The noble metal fine particle supported catalyst of the present invention includes a substrate, and a porous membrane formed on the substrate. The porous membrane contains support particles, noble metal fine particles, and an inorganic binder. In the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and the support particles form secondary particles each having a porous structure. The porous membrane is formed by binding, with the inorganic binder, the secondary particles formed of the support particles so that a gap is present at least partly between the secondary particles adjacent to each other.Type: GrantFiled: February 28, 2011Date of Patent: February 10, 2015Assignee: Nippon Sheet Glass Company, LimitedInventors: Ryohei Ogawa, Kiyoshi Miyashita
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Patent number: 8945309Abstract: A catalyst for cellulose hydrolysis and/or the reduction of hydrolysis products, in which a transition metal of group 8 to 11 is supported on a solid support. A method of producing sugar alcohols comprising: hydrolyzing cellulose in the presence of the catalyst in a hydrogen-containing atmosphere with pressurization; and reducing the hydrolysis product of cellulose. Provided are a catalyst for use in the production of sugar alcohols by the hydrolysis and hydrogenation of cellulose that affords easy separation of catalyst and product, and that does not require pH adjustment, acid or alkali neutralization, or activation of the catalyst during reuse, and a method of producing sugar alcohols from cellulose employing this catalyst.Type: GrantFiled: March 1, 2007Date of Patent: February 3, 2015Assignee: National University Corporation Hokkaido UniversityInventors: Atsushi Fukuoka, Paresh Laxmikant Dhepe
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Patent number: 8940657Abstract: An exhaust emission control catalyst disclosed herein is equipped with a rhodium catalytic layer and a platinum catalytic layer, and is characterized in that a relationship between a mole average (X) of a Pauling's electronegativity that is calculated as to elements included in the rhodium catalytic layer except platinum group elements and oxygen and a mole average (Y) of a Pauling's electronegativity that is calculated as to elements included in the platinum catalytic layer except platinum group elements and oxygen is 1.30?X?1.45 and 1.47?Y?2.0. According to this exhaust emission control catalyst, an interlayer transfer of platinum and/or rhodium and the alloying of platinum and/or rhodium are suppressed during use of the catalyst, and high exhaust gas purification performance can be exerted.Type: GrantFiled: May 31, 2012Date of Patent: January 27, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventor: Yoshihide Segawa
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Patent number: 8937203Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Patent number: 8932546Abstract: A catalytically active particulate filter is proposed which is suitable for use in an exhaust gas cleaning system for diesel engines. The particulate filter removes diesel soot particles from the exhaust gas and is also effective to oxidize carbon monoxide and hydrocarbons and to convert nitrogen monoxide at least proportionally into nitrogen dioxide. The particulate filter comprises a filter body (3) and two catalytically active coatings (1) and (2) which contain platinum and palladium, or platinum or palladium respectively, wherein the platinum content of the second catalytically active coating (2) is higher than the platinum content of the first catalytically active coating (1).Type: GrantFiled: January 29, 2013Date of Patent: January 13, 2015Assignee: Umicore AG & Co. KGInventors: Stephanie Frantz, Ulrich Goebel, Franz Dornhaus, Michael Schiffer
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Patent number: 8927454Abstract: An exhaust gas-purifying catalyst includes a support provided with one or more through-holes through which exhaust gas flows, and a catalytic layer supported by the support and containing an oxygen storage material. The exhaust gas-purifying catalyst includes a first section to which the exhaust gas is supplied, and a second section to which the exhaust gas having passed through the first section is supplied. The catalytic layer includes a layered structure of a first catalytic layer containing platinum and/or palladium and a second catalytic layer containing rhodium in the first catalytic section and further includes a third layer containing rhodium in the second section. The second section is smaller in oxygen storage material content per unit volumetric capacity than the first section.Type: GrantFiled: October 27, 2011Date of Patent: January 6, 2015Assignee: Cataler CorporationInventors: Minoru Itou, Michihiko Takeuchi, Tetsuya Shinozaki, Takaaki Kanazawa, Masaya Kamada, Tadashi Suzuki, Satoru Katoh, Naoki Takahashi
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Patent number: 8906330Abstract: The present invention relates to a catalyst composition comprising a carrier substrate, a layer (i) coated on said carrier substrate comprising at least one precious group metal, a layer (ii) comprising Rh, and a layer (iii) comprising Pd and/or Pt and being substantially free of Ce, Ba and Rh, wherein the layer (iii) has a lower weight than the layer (i) or the layer (ii). Furthermore, the present invention relates to a method for treating an exhaust gas stream using said catalyst composition.Type: GrantFiled: May 4, 2010Date of Patent: December 9, 2014Assignee: BASF CorporationInventors: Marcus Hilgendorff, Wen Mei Xue, Cesar Tolentino
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Patent number: 8889078Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.Type: GrantFiled: March 15, 2011Date of Patent: November 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
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Patent number: 8883100Abstract: The present invention relates to a particle filter comprising a porous carrier body, an SCR active component and an oxidation catalyst, wherein the SCR active component is present as coating on the exhaust-gas entry surface and the inner surface of the porous carrier body and the oxidation catalyst as coating on the exhaust-gas exit surface of the porous carrier body. According to the invention the oxidation catalyst changes its function depending on operating conditions. In normal operation it serves as NH3 slip catalyst for oxidizing excess NH3 and during filter regeneration it operates according to the 3-way principle for converting NOx and CO. The invention also relates to a method for producing the particle filter, the use of the particle filter for treating exhaust gases from the combustion of fossil, synthetic or biofuels as well as an exhaust-gas cleaning system which contains the particle filter according to the invention.Type: GrantFiled: November 4, 2009Date of Patent: November 11, 2014Assignee: Sued-Chemie IP GmbH & Co. KGInventors: Martin Paulus, Klaus Wanninger
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Patent number: 8871669Abstract: A catalyst composition is provided comprising a homogeneous solid mixture having ordered directionally aligned tubular meso-channel pores having an average diameter in a range of about 1 nanometer to about 15 nanometers, wherein the homogeneous solid mixture is prepared from a gel formed in the presence of a solvent, modifier, an inorganic salt precursor of a catalytic metal, an inorganic precursor of a metal inorganic network, and a templating agent. The templating agent comprises an octylphenol ethoxylate having a structure [I]: wherein “n” is an integer having a value of about 8 to 20.Type: GrantFiled: May 28, 2010Date of Patent: October 28, 2014Assignee: General Electric CompanyInventors: Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Ashish Balkrishna Mhadeshwar, Ming Yin
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Patent number: 8859458Abstract: Provided are a method of preparing an electrocatalyst for fuel cells in a core-shell structure, an electrocatalyst for fuel cells having a core-shell structure, and a fuel cell including the electrocatalyst for fuel cells. The method may be useful in forming a core and a shell layer without performing a subsequent process such as chemical treatment or heat treatment and forming a core support in which core particles having a nanosize diameter are homogeneously supported, followed by selectively forming shell layers on surfaces of the core particles in the support. Also, the electrocatalyst for fuel cells has a high catalyst-supporting amount and excellent catalyst activity and electrochemical property.Type: GrantFiled: September 21, 2011Date of Patent: October 14, 2014Assignee: Korea Institute of Science and TechnologyInventors: Seung Jun Hwang, Sung Jong Yoo, Soo Kil Kim, Eun Ae Cho, Jong Hyun Jang, Hyoung Juhn Kim, Suk Woo Nam, Tae Hoon Lim
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Patent number: 8858904Abstract: Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.Type: GrantFiled: February 22, 2011Date of Patent: October 14, 2014Assignee: BASF CorporationInventors: Alfred Helmut Punke, Gerd Grubert, Yuejin Li, Ruediger Wolff, Stanley Roth, Torsten Müller-Stach, Attilio Siani, Kenneth Voss, Torsten Neubauer
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Patent number: 8852519Abstract: Disclosed is an exhaust gas purifying catalyst in which grain growth of a noble metal particle supported on a support is suppressed. Also, disclosed is a production process of an exhaust gas purifying catalyst, by which the above exhaust gas purifying catalyst can be produced. The exhaust gas purifying catalyst comprises a crystalline metal oxide support and a noble metal particle supported on the support, wherein the noble metal particle is epitaxially grown on the support, and wherein the noble metal particle is dispersed and supported on the outer and inner surfaces of the support. The process for producing an exhaust gas purifying catalyst comprises masking, in a solution, at least a part of the surface of a crystalline metal oxide support by a masking agent, introducing the support into a noble metal-containing solution containing a noble metal, and drying and firing the support and the noble metal-containing solution to support the noble metal on the support.Type: GrantFiled: July 9, 2010Date of Patent: October 7, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masao Watanabe, Oji Kuno, Nobusuke Kabashima, Keisuke Kishita, Noboru Otake, Hiromochi Tanaka
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Patent number: 8833064Abstract: Catalyst articles comprising substantially only a palladium precious metal component in a first catalytic layer and a rhodium component in a second catalytic layer and related methods of preparation and use are disclosed. Also disclosed is a catalyst article comprising a first layer formed on a carrier substrate, wherein the first layer comprises a refractory metal oxide and has a surface that is substantially uniform; a second layer formed on the first layer, wherein the second layer comprises i) an oxygen storage component that is about 50-90% by weight of the second layer and ii) a palladium component in an amount of about 2-5% by weight of the second layer, wherein the palladium component is substantially the only platinum group metal component, and a palladium-free third layer comprising a rhodium component supported on a thermostable oxygen storage component which is about 80-99% by weight of the second layer. One or more improved properties are exhibited by the catalyst article.Type: GrantFiled: November 1, 2010Date of Patent: September 16, 2014Assignee: BASF CorporationInventors: Michael P. Galligan, Pascaline H. Tran, Keshavaraja Alive, Ye Liu
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Patent number: 8828343Abstract: Catalyst articles comprising palladium and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first catalytic layer formed on a substrate, wherein the first catalytic layer comprises palladium impregnated on a ceria-free oxygen storage component and platinum impregnated on a refractory metal oxide, and a second catalytic layer formed on the first catalytic layer comprising platinum and rhodium impregnated on a ceria-containing oxygen storage component. The palladium component of the catalyst article is present in a higher proportion relative to the other platinum group metal components. The catalyst articles provide improved conversion of carbon monoxide in exhaust gases, particularly under rich engine operating conditions.Type: GrantFiled: March 2, 2011Date of Patent: September 9, 2014Assignee: BASF CorporationInventors: Xinsheng Liu, Ye Liu, Pascaline Harrison Tran, Keshavaraja Alive, Michael P. Galligan
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Publication number: 20140227166Abstract: A catalyst comprising at least one catalytically active metal selected from the group consisting of elements of Groups 7 to 11, wherein the catalytically active metal is supported on a support material being grafted with acid groups other than OH groups, wherein a metal is in the bulk of the support material, and wherein the catalytically active metal is different from the metal of the support material. A method for preparing such catalyst and the use of such catalyst for catalyzing reactions.Type: ApplicationFiled: September 6, 2012Publication date: August 14, 2014Applicant: SOLVAY SAInventors: Frederique Desmedt, Yves Vlasselaer
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Patent number: 8795619Abstract: A catalyst for purification of exhaust gas, in which a noble metal is supported on a metal oxide support, has a basic site content of 1 mmol/L-cat or less, as determined on the basis of an amount of CO2 desorbed per liter of the catalyst as measured by a CO2 temperature-programmed desorption method.Type: GrantFiled: May 8, 2008Date of Patent: August 5, 2014Assignees: Toyota Jidosha Kabushiki Kaisha, Cataler CorporationInventors: Tadashi Suzuki, Satoru Kato, Naoki Takahashi, Takaaki Kanazawa, Masanori Yamato, Kazuhiro Yoshimoto, Michihiko Takeuchi, Yuuji Matsuhisa
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Publication number: 20140170045Abstract: Provided are catalysts comprising a small pore molecular sieve embedded with platinum group metal (PGM) and methods for treating lean burn exhaust gas using the same.Type: ApplicationFiled: June 5, 2012Publication date: June 19, 2014Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Joseph Michael Fedeyko, Hai-Ying Chen, Paul Joseph Andersen
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Patent number: 8741242Abstract: A NOx storage component comprises caesium silicate (Cs2SiO3) and at least one platinum group metal. The invention also includes a NOx absorber catalyst comprising a NOx storage component according to the invention disposed on a substrate monolith; a method of treating exhaust gas containing NOx from a lean burn internal combustion engine comprising the steps of contacting a NOx storage component comprising caesium silicate (Cs2SiO3) and at least one platinum group metal with lean exhaust gas containing NOx to adsorb NOx thereon; and periodically desorbing adsorbed NOx by contacting the NOx storage component with stoichiometric or rich exhaust gas; and a method of making a NOx storage component according to the invention comprising the steps of combining and reacting an aqueous salt of at least one platinum group metal, an aqueous caesium salt and a source of silica.Type: GrantFiled: October 20, 2011Date of Patent: June 3, 2014Assignee: Johnson Matthey PLCInventors: Jonathan Ashley Cooper, Michael Anthony Howard
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Patent number: 8734743Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.Type: GrantFiled: June 9, 2011Date of Patent: May 27, 2014Assignee: BASF SEInventors: Torsten W. Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer
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Patent number: 8683787Abstract: An exhaust gas purifying catalyst (1) of the present invention includes anchor/promoter simultaneous enclosure particles (5) including catalyst units (13) which contain: noble metal particles (8); and anchor particles (9) as an anchor material of the noble metal particles (8) supporting the noble metal particles (8); promoter units (14) which are provided not in contact with the noble metal particles (8) and contain first promoter particles (11) having an oxygen storage and release capacity; and an enclosure material (12) which encloses both the catalyst units (13) and the promoter units (14), and separates the noble metal particles (8) and the anchor particles (9) in the catalyst units (13) from the first promoter particles (11) in the promoter units (14). The exhaust gas purifying catalyst (1) further includes second promoter particles (6) which have the oxygen storage and release capacity, and are not enclosed in the anchor/promoter simultaneous enclosure particles (5) by the enclosure material (12).Type: GrantFiled: November 15, 2010Date of Patent: April 1, 2014Assignee: Nissan Motor Co., Ltd.Inventors: Takamasa Nakagawa, Masanori Nakamura, Misaki Fujimoto, Naoki Kachi
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Patent number: 8637193Abstract: In some embodiments, the present disclosure provides a fuel cell catalyst having a catalyst surface bearing a non-occluding layer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a sub-monolayer of iridium. In some embodiments, the present disclosure provides a fuel cell catalyst comprising a catalyst surface bearing a layer of iridium having a planar equivalent thickness of between 1 and 100 Angstroms. In some embodiments, the fuel cell catalyst comprises nanostructured elements comprising microstructured support whiskers bearing a thin film of nanoscopic catalyst particles. The layer of iridium typically has a planar equivalent thickness of between 1 and 100 Angstroms and more typically between 5 and 60 Angstroms. The fuel cell catalyst typically comprises no electrically conductive carbon material and typically comprises at least a portion of the iridium in the zero oxidation state.Type: GrantFiled: August 25, 2009Date of Patent: January 28, 2014Assignee: 3M Innovative Properties CompanyInventors: Andrew J. L. Steinbach, George D. Vernstrom, Mark K. Debe, Radoslav Atanasoski
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Patent number: 8618019Abstract: A producing method includes a preparing step of preparing a chemical compound having at least one of elements of alkali metals and alkali earth metals along with platinum, and a reducing step of reducing the prepared chemical compound with a reducing agent to form platinum nanoparticles.Type: GrantFiled: June 25, 2009Date of Patent: December 31, 2013Assignees: Aisin Seiki Kabushiki Kaisha, Toyota Jidosha Kabushiki Kaisha, The DoshishaInventors: Takeshi Kamizono, Gang Xie, Minoru Inaba
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Patent number: 8609578Abstract: An exhaust gas purifying catalyst is constituted by: noble metal particles (1); first compounds (2) which support the noble metal particles (1); second compounds (3) different in type from the first compounds (2); and oxides (4) which surround the noble metal particles (1), the first compounds (2) and the second compounds (3). A median diameter of the first compounds (2) and a median diameter of the second compounds (3) satisfy a relationship of a following inequality: median diameter of first compounds<median diameter of second compounds.Type: GrantFiled: June 30, 2009Date of Patent: December 17, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Masanori Nakamura, Yoshiaki Hiramoto, Hiroto Kikuchi, Hironori Wakamatsu, Kazuyuki Shiratori, Tetsuro Naito, Katsuo Suga
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Publication number: 20130303364Abstract: Disclosed is a catalyst for converting nitrogen oxide into ammonia, which is capable of converting nitrogen oxide into ammonia under fuel lean exhaust gas conditions of more than theoretical air-fuel ratio (A/F=14.7), and a method for manufacturing the same. The catalyst according to the present invention comprises a metal oxide support impregnated with a precious metal, such that conversion of nitrogen oxide into ammonia under fuel lean exhaust gas conditions of more than theoretical air-fuel ratio (A/F=14.7) is possible.Type: ApplicationFiled: August 23, 2012Publication date: November 14, 2013Applicants: POSTECH ACADEMY-INDUSTRY FOUNDATION, HYUNDAI MOTOR COMPANYInventors: Jin Woo Choung, In-Sik Nam, Dal Young Yoon, Iljeong Heo
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Patent number: 8524420Abstract: Disclosed is a method for preparing nickel or palladium nanoparticles supported on a carbon support. To a mixture solution wherein a stabilizer is dissolved in 1,2-propanediol, a carbon support is added to prepare a dispersion. Then, a precursor solution wherein a nickel or palladium precursor dissolved in 1,2-propanediol is mixed therewith and stirred. Then, nickel or palladium nanoparticles supported on the carbon support are prepared by reduction. The disclosed method for preparing nickel or palladium nanoparticles supported on a carbon support allows preparation of nanoparticles with narrow particle size distribution and good dispersibility through a simple process and the resulting nickel or palladium nanoparticles may be usefully applied, for example, as electrode materials of fuel cells.Type: GrantFiled: May 13, 2010Date of Patent: September 3, 2013Assignees: Hyundai Motor Company, SNU & R&DB FoundationInventors: Nak Hyun Kwon, Jae Seung Lee, Bumwook Roh, Yung-Eun Sung, Tae-Yeol Jeon, Hee-Young Park, Ju Wan Lim, Young-Hoon Chung
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Patent number: 8505285Abstract: A catalyst system includes a first catalytic composition and a second catalytic composition. The first catalytic composition includes a homogeneous solid mixture, which includes a first catalytic material disposed on a first substrate. The pores of the solid mixture have an average diameter of greater than about 45 nanometers. The second catalytic composition includes at least one of a zeolite or a second catalytic material disposed on a second substrate. The second catalytic material includes an element selected from the group that includes tungsten, titanium, and vanadium.Type: GrantFiled: October 6, 2010Date of Patent: August 13, 2013Assignee: General Electric CompanyInventors: Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
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Patent number: 8501132Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.Type: GrantFiled: December 5, 2011Date of Patent: August 6, 2013Assignee: Cristal USA Inc.Inventors: Guoyi Fu, Steven M. Augustine
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Patent number: 8496899Abstract: An exhaust gas purifying catalyst 1 has a catalyst substrate 3 and catalyst coating layers 5, 7 that are formed on the catalyst substrate 3 and contain (a) Rh, (b) Pt, (c) an alkali metal or alkaline earth element, and (d) an inorganic oxide. The catalyst coating layers 5, 7 has a layered structure including an inside layer 5 where the component (a) is substantially locally existing, and an outside layer 7 where the component (b) is substantially locally existing. The inside layer 5 also contains a zirconia oxide.Type: GrantFiled: January 25, 2008Date of Patent: July 30, 2013Assignee: Cataler CorporationInventor: Hiroto Imai
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Patent number: 8486853Abstract: An exhaust gas purifying catalyst (1) according to the present invention includes noble metal particles (6), a first compound (7) supporting the noble metal particles (6), and a second compound (9) disposed not in contact with the noble metal particles (6) and having an oxygen storage capacity. An average distance between the first compound (7) and the second compound (9) is between 5 nm and 300 nm.Type: GrantFiled: March 4, 2010Date of Patent: July 16, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Kazuyuki Shiratori, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Hiroto Kikuchi, Tetsuro Naito, Jun Ikezawa
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Publication number: 20130172599Abstract: A silica-based material comprising: silicon; aluminum; at least one fourth period element selected from the group consisting of iron, cobalt, nickel and zinc; and at least one basic element selected from the group consisting of alkali metal elements, alkali earth metal elements and rare earth elements, wherein the silica-based material comprises 42 to 90 mol % of the silicon, 3 to 38 mol % of the aluminum, 0.5 to 20 mol % of the fourth period element and 2 to 38 mol % of the basic element, based on a total mole of the silicon, the aluminum, the fourth period element and the basic element.Type: ApplicationFiled: September 16, 2010Publication date: July 4, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Ken Suzuki, Tatsuo Yamaguchi, Chihiro Iitsuka
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Publication number: 20130150617Abstract: Provided is a monolithic catalyst for synthesizing an oxalate by carbon monoxide (CO) gaseous-phase coupling, a preparation method and the use thereof. In the catalyst, a ceramic honeycomb or a metal honeycomb was used as skeletal carrier, metal oxides were used as a carrier coating, precious metals Pt, Pd, Ir, Rh were used as active ingredients, as well as Fe, Co, Ni were used as additives, wherein the carrier coating accounts for 5 to 50 wt % of the honeycomb carrier the active ingredients of the catalyst account for 0.1 to 5 wt. % of the carrier coating; the additives of the catalyst account for 0.3 to 10 wt. % of the carrier coating; and the atomic ratio of the active ingredients to the additives was 0.1 to 3. the reaction for synthesizing the oxalate was carried out in a fixed bed reactor, wherein, N2 was used as a carrier gas. The volume ratio of N2:CO: Alkyl nitrite was 20-80:5-60:10-40, and the retention time was 0.5-10 s.Type: ApplicationFiled: May 31, 2011Publication date: June 13, 2013Inventors: Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenghua Li
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Patent number: 8461373Abstract: Disclosed is a catalyst for use in production of carboxylic acid ester by reacting (a) aldehyde and alcohol, or (b) one or more types of alcohols, in the presence of oxygen; wherein oxidized nickel and X (wherein X represents at least one element selected from the group consisting of nickel, palladium, platinum, ruthenium, gold, silver and copper) are loaded onto a support within the range of the atomic ratio of Ni/(Ni+X) of from 0.20 to 0.99.Type: GrantFiled: July 31, 2008Date of Patent: June 11, 2013Assignee: Asahi Kasei Chemicals CorporationInventors: Ken Suzuki, Tatsuo Yamaguchi
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Patent number: 8455391Abstract: An exhaust gas purifying catalyst (1) includes: a three-dimensional structural substrate (10) having a plurality of cells (11) partitioned by cell walls (12) having pores (13); and catalyst layers (20) formed in the three-dimensional structural substrate (10). The catalyst layers (20) have pore-cover portions (22) formed on surfaces (13a) of the pores (13) of the cell walls (12). In addition, the catalyst layers (20) of the pore-cover portions (22) have activated pores (22a) with a pore diameter of 0.1 micrometers to 10 micrometers. In the exhaust gas purifying catalyst (1), the obstruction of the vent holes (pores (13)) in the catalyst layers (20) can be controlled, and the pressure loss can be reduced.Type: GrantFiled: March 30, 2009Date of Patent: June 4, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Yasunari Hanaki, Hiroshi Akama, Hitoshi Onodera, Toru Nishizawa, Yoshiaki Hiramoto, Hideaki Morisaka, Masahiro Takaya
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Patent number: 8455389Abstract: The invention provides an amorphous hydrocracking catalyst for conversion of a hydrocarbon feed having a fraction above the diesel boiling range to diesel and a process using said catalyst. The catalyst includes Al203—SiO2 support, a noble catalytically active metal which is active for hydrocracking of a hydrocarbon above the diesel boiling range and a transition metal oxide selected from group V, VI and VII.Type: GrantFiled: May 24, 2001Date of Patent: June 4, 2013Assignee: Sasol Technology (Pty) Ltd.Inventors: Aubin-Maurice Liwanga-Ehumbu, Jacobus Lucas Visagie, Dieter Otto Leckel
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Patent number: 8455390Abstract: An exhaust gas purifying catalyst includes a monolithic substrate (2), and a transition metal oxide layer (3) formed in the monolithic substrate (2). The transition metal oxide layer (3) contains transition metal oxide powder including: transition metal oxide particles (10); a first compound (20) on which the transition metal oxide particles (10) are supported; and a second compound (30) that surrounds a single body or an aggregate of the transition metal oxide particles (10) and the first compound (20).Type: GrantFiled: June 23, 2009Date of Patent: June 4, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Hiroto Kikuchi, Masanori Nakamura, Hironori Wakamatsu, Katsuo Suga, Toshiharu Miyamura, Jun Ikezawa, Tetsuro Naito, Junji Ito
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Publication number: 20130131399Abstract: A process for producing a catalyst, the process comprising the steps of: impregnating a first metal from a first metal precursor on a support to form a first impregnated support; calcining the first impregnated support; impregnating a second metal from a second metal precursor on the first impregnated support to form a second impregnated support; calcining the second impregnated support to form the catalyst, wherein the catalyst has a total metal loading of at least 2 wt. % based on the total weight of the catalyst. A method for hydrogenating alkanoic acids in the presence of the catalyst is also disclosed.Type: ApplicationFiled: November 23, 2011Publication date: May 23, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Heiko Weiner, Ana Rita Almeida, Graham Ormsby
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Patent number: 8445162Abstract: A cathode catalyst includes a carrier including Mo, S, and I, and an active metal supported on the carrier and including a material selected from the group consisting of Ru, Pt, Rh, and combinations thereof. It is shown that such a catalyst for a cathode has improved activity over platinum catalysts.Type: GrantFiled: March 16, 2007Date of Patent: May 21, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Alexey Alexandrovichserov, Chan Kwak, Si-Hyun Lee
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Patent number: 8425762Abstract: An MCM-41 catalyst having a crystalline framework containing SiO2 and a Group IV metal oxide, such as TiO2 or ZrO2 is provided. The catalyst is low in acidity and is suitable for use in processes involving aromatic saturation of hydrocarbon feedstocks.Type: GrantFiled: December 16, 2008Date of Patent: April 23, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen J. McCarthy, Wenyih Frank Lai, Michel A. Daage