Hydrocarbon Patents (Class 502/31)
  • Patent number: 11524272
    Abstract: The present invention relates to an adsorbent suitable for the adsorption of MOAH and/or MOSH compounds, the use of the adsorbent for the production of a packaging material or a container comprising the adsorbent, the process of production of the packaging material or container as well as the respective packaging material and container.
    Type: Grant
    Filed: March 14, 2018
    Date of Patent: December 13, 2022
    Assignee: Clariant International Ltd
    Inventors: Hubertus Besting, Gabriele Hölzl, Alexander Mayerhofer, Friedrich Ruf
  • Patent number: 11440765
    Abstract: Apparatus for a drill powered wire puller are disclosed. In an embodiment the drill powered wire puller includes a center plate, a cradle plate, a housing, a support, the support including a receiver, and a capstan. The center plate is coupled with the cradle plate at a proximal end. The cradle plate includes a U-shaped notch and two hooks or catches which are configured to couple the cradle plate with a powered rotary tool, such as a drill. The right side of the center plate is coupled with a housing, the left side of the center plate is coupled with a support. The left side of the support is coupled with a capstan. The support laterally offsets the receiver to align a longitudinal axis of the receiver with a radially curved portion of the capstan.
    Type: Grant
    Filed: May 20, 2019
    Date of Patent: September 13, 2022
    Assignee: Tommy D Electrical Products LLC
    Inventor: Thomas DeBellis
  • Patent number: 10512906
    Abstract: The present invention is an in-situ cleaning procedure for the recovery of catalytic activity of a based alumina HDS catalyst, molybdenum, nickel coated coke and contaminants and it has an HDS activity seriously diminished. The catalyst under study had between 13 and 18 wt % total carbon. Reformate, half the total volume, industrial toluene=35 volume % and Iso-propylic alcohol, 15 volume %, in order to reactivate a deactivated catalyst, a solvent mixture with the following volumetric ratio is prepared. Or it can also be used only reformate (100% volume). The solvent mixture is passed using a LHSV of 2 hr?1 for 72 hours at 50° C. or also using a recirculating three 24-hour cycles at 50° C. Option lasts 24 hours pure reformate LHSV=2h?1 to 50° C. The washed catalyst is fed back to the load reaction conditions maintained for 36 hours at 340° C., to initiate HDS activity balances. During this treatment oxides of molybdenum and nickel in the active phase are re-sulfided by increasing the HDS activity.
    Type: Grant
    Filed: November 30, 2015
    Date of Patent: December 24, 2019
    Assignee: INSTITUTO MEXICANO DEL PETRÓLEO
    Inventors: Leonardo Díaz Garcia, María del Rosario Socorro Luna Ramírez, Gonzalo Hernández Tapia, Blanca Lucía Medellín Rivera, Maria Teresa Gómez Pérez, Maria Teresa Cortez De La Paz, Alicia del Rayo Jaramillo Jacob
  • Patent number: 10253270
    Abstract: Provided is an improved alkylation process using a delaminated SSZ-70 catalyst. The process comprises contacting a hydrocarbon feedstock comprising olefins and isoparaffins with a catalyst comprising delaminated SSZ-70 under alkylating reaction conditions. The delaminated SSZ-70 offers a zeolite layer with a single unit cell of thickness in one dimension, allowing an elimination of mass transfer in comparison with regular SSZ-70. This prevents coke formation inside zeolite channels and improves catalyst stability.
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: April 9, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventors: Bi-Zeng Zhan, Stacey Ian Zones, Christopher M. Lew
  • Patent number: 10047021
    Abstract: A process of tuning a hydrocarbon product composition is described. The process involves selecting paraffins for reaction. The equilibrium constants for reactions of the selected paraffins can be used to select appropriate feed ratios, or an equilibrium composition as function of C/H molar ratio. A selected feed is reacted to obtain the product. Equilibrium product compositions and non-equilibrium product compositions can be obtained using the process.
    Type: Grant
    Filed: June 12, 2014
    Date of Patent: August 14, 2018
    Assignee: UOP LLC
    Inventors: Stuart Smith, Alakananda Bhattacharyya, Peter K. Coughlin
  • Patent number: 9968925
    Abstract: A process of recovering and recycling a catalyst includes feeding an epoxidized fatty acid ester, a solvent, and a catalyst to a reactor. The solvent is reacted with the epoxidized fatty acid ester to open epoxy rings of the ester and produce a polyol. Some unreacted solvent remains after the reaction. The unreacted solvent is separated from a mixture of the polyol and the catalyst. The polyol/catalyst mixture is passed to an adsorption bed so that the catalyst is adsorbed and the polyol passes through the bed. The polyol is recovered. The adsorption bed is rinsed with the unreacted solvent to desorb the catalyst and obtain a mixture of the solvent and the catalyst. The mixture of solvent and catalyst is recycled to the reactor for further reaction.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: May 15, 2018
    Assignee: BATTELLE MEMORIAL INSTITUTE
    Inventor: Daniel B. Garbark
  • Patent number: 9649610
    Abstract: A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.
    Type: Grant
    Filed: August 25, 2014
    Date of Patent: May 16, 2017
    Assignee: RES USA, LLC
    Inventors: Harold A. Wright, Belma Demirel, Sergio Mohedas, Bahman Rejai, Ray J. Huang, Deena Ferdous, Jesse W. Taylor, Dawid J. Duvenhage, Sara L. Rolfe
  • Patent number: 9138738
    Abstract: A process for regenerating a catalyst used in a reaction zone. In a regeneration zone, the catalyst may be cooled before passing into a chloride rich zone. The regeneration zone may also receive a heated ambient oxygen in a catalyst heating zone. The regeneration zone may also receive recovered chloride from a chloride recovering zone which removes and recovers chloride from regeneration gas taken from the regeneration zone. Heated ambient oxygen may also be introduced into a chlorination zone.
    Type: Grant
    Filed: April 14, 2014
    Date of Patent: September 22, 2015
    Assignee: UOP LLC
    Inventors: Bryan K. Glover, Ka Lok, Mary J. Wier, Mohamed S. Shakur, Michael A. Moore, Alexander Sabitov
  • Patent number: 9079175
    Abstract: While at least one exemplary embodiment has been presented in the foregoing detailed description of the invention, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the invention in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment of the invention. It being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the invention as set forth in the appended claims.
    Type: Grant
    Filed: March 28, 2014
    Date of Patent: July 14, 2015
    Assignee: UOP LLC
    Inventors: Stuart Smith, Alakananda Bhattacharyya, Erin M. Broderick
  • Patent number: 9029281
    Abstract: A regenerated spent hydroprocessing catalyst treated with a chelating agent and having incorporated therein a polar additive.
    Type: Grant
    Filed: August 11, 2011
    Date of Patent: May 12, 2015
    Assignee: Shell Oil Company
    Inventors: Alexei Grigorievich Gabrielov, Ed Ganja, Salvatore Philip Torrisi
  • Patent number: 9006123
    Abstract: A catalytic reforming process including a reaction zone and a separate catalyst regeneration zone where catalyst is collected in a catalyst collector in the reaction zone and then directed to the catalyst regeneration zone wherein the catalyst collector is purged with a net gas stream.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: April 14, 2015
    Assignee: UOP LLC
    Inventor: Brian Nabozny
  • Patent number: 8921636
    Abstract: Methods for converting an HF alkylation unit to an ionic liquid alkylation system configured for performing ionic liquid catalyzed alkylation processes may comprise connecting at least one component configured for ionic liquid catalyzed alkylation to at least one component of the HF alkylation unit, wherein the at least one component of the HF alkylation unit is retained, modified or adapted for use in the ionic liquid alkylation system. An ionic liquid alkylation system derived from an existing or prior HF alkylation unit is also disclosed.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: December 30, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Robert Fletcher Cleverdon, Christine Marie Phillips, Hye Kyung Cho Timken
  • Publication number: 20140296057
    Abstract: The behavior of a monitored condition over time for a reactor or reaction system can be analyzed using groupings or windows of data to identify anomalous features in the time-average values. Anomalous features can be identified based on a threshold value generated from the analysis. Based on identification of an anomalous feature, a corrective action can be taken. For example, when the monitored condition is the pressure drop across a catalyst bed, detection of an anomaly can indicate the time to initiate a wash process for the catalyst bed before a large drop in catalyst activity occurs. By detecting an anomaly at an earlier point in time, a wash cycle can be initiated earlier so that the wash is more effective at restoring the catalyst bed to a desired condition.
    Type: Application
    Filed: February 28, 2014
    Publication date: October 2, 2014
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Teh C. Ho, Krishnan Kumaran, Richard C. Dougherty
  • Publication number: 20140237995
    Abstract: System, apparatus, and methods are disclosed for treating a reduction catalyst that has been exposed to an amount of sulfur. The treating of the reduction catalyst includes providing a fluid stream at a position upstream of the reduction catalyst. The fluid stream includes a temperature and a reductant amount, and the reductant amount includes an amount of urea, ammonia, or hydrocarbons.
    Type: Application
    Filed: February 25, 2014
    Publication date: August 28, 2014
    Applicant: Cummins Inc.
    Inventors: Aleksey Yezerets, Krishna Kamasamudram, Neal W. Currier, Ashok Kumar, Michael A. Smith
  • Patent number: 8772191
    Abstract: The invention provides a process for the off site regeneration of a solid catalyst, comprising two consecutive steps: a first step of washing the catalyst using one or more fluid(s) in the supercritical state, so as to extract from the catalyst at least a portion of the hydrocarbons present at the surface of the latter, followed by a second step of combustion of at least a portion of the coke present at the surface of the said catalyst by a heat treatment of the latter in the presence of oxygen and at a temperature ranging from 300° C. to 600° C.
    Type: Grant
    Filed: January 6, 2012
    Date of Patent: July 8, 2014
    Assignee: Eurecat S.A.
    Inventors: Philippe Kerleau, Pierre Dufresne
  • Patent number: 8765622
    Abstract: A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. Filtering in the deoiling zone can comprise filtering the slurry and solvent through a cross-flow microfiltration unit, recovering a retentate stream of the cross-flow microfiltration unit, combining the retentate stream of the cross-flow microfiltration unit with solvent to form a combined retentate-solvent stream, and filtering the combined retentate-solvent stream through a cross-flow microfiltration unit.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: July 1, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Lalit S. Shah, Christopher A. Powers, James R. Stoy, Fred D. Brent, Bruce E. Reynolds, Andre R. Da Costa
  • Patent number: 8759242
    Abstract: An improved slurry catalyst feed system for heavy oil upgraded is provided. The catalyst feed system comprises a fresh slurry catalyst and a deoiled spent catalyst, with the deoiled spent catalyst being present in an amount of at least 10% the catalyst feed system. The deoiled spent catalyst is a slurry catalyst that has been used in a hydroprocessing operation resulting in than 80% but more than 10% of original catalytic activity, and containing less than 10 wt. % soluble hydrocarbons as unconverted heavy oil feed. The deoiled spent catalyst is slurried in a hydrocarbon medium as dispersed particles prior to being fed to the heavy oil upgrade system.
    Type: Grant
    Filed: September 15, 2011
    Date of Patent: June 24, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Shuwu Yang, Julie Chabot, Bruce Edward Reynolds
  • Patent number: 8722556
    Abstract: A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. The deoiling zone can comprise a membrane that is rapidly displaced in a horizontal direction.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: May 13, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Andre R. DaCosta, Paul Bryan
  • Patent number: 8658557
    Abstract: A process for the preparation of a promoted VPO catalyst, wherein the catalyst comprises the mixed oxides of vanadium and phosphorus and wherein the catalyst is promoted with at least one of niobium, cobalt, iron, zinc, molybdenum or titanium, said process comprising the steps of (i) preparing a VPO catalyst comprising vanadyl pyrophosphate as the major component and containing less than 5 wt % of vanadyl phosphate, (ii) contacting the VPO catalyst with a solution comprising a metal source compound of at least one metal selected from the group consisting of niobium, cobalt, iron, zinc, molybdenum or titanium to form a metal impregnated VPO catalyst, and (iii) drying the metal impregnated VPO catalyst to form the promoted VPO catalyst. In one embodiment, a niobium promoted VPO catalyst is prepared.
    Type: Grant
    Filed: October 25, 2011
    Date of Patent: February 25, 2014
    Assignee: INEOS USA LLC
    Inventors: Muin S. Haddad, Robert A. Gustaferro
  • Publication number: 20130277603
    Abstract: The present invention describes the method for preparing, using and recovering an absorbent material for apolar compounds or mixtures of apolar compounds, such as organic solvents, mineral oil and derivatives thereof, lubricant oils, edible oils, inter alia. The absorbent material is composed of an inorganic matrix of high porosity, low density and high mechanical resistance. This matrix is rendered water-proof, thus acquiring the property of absorbing apolar compounds or mixtures of apolar compounds.
    Type: Application
    Filed: July 14, 2011
    Publication date: October 24, 2013
    Applicant: UNIVERSIDADE FEDERAL DE MINAS GERAIS
    Inventors: Geraldo Magela De Lima, Jadson Cláudio Belchior, Geison Voga Pereira, Fabrício Vieira De Andrade, Márcio Guimarães Coelho, Daneile Santos Cavanellas Gomes, Nathália Gabriela Silva Pinheiro
  • Patent number: 8524073
    Abstract: Disclosed herein is a sorbent composition including an adsorbent support; and a metal component comprising a transition metal, wherein the metal component is impregnated on a surface of the adsorbent support; and wherein the metal component effects the removal of sulfur and vanadium from a hydrocarbon fuel. Also disclosed herein is a sorbent composition comprising an adsorbent support, wherein a surface of the adsorbent support has been chemically modified to comprise functional groups; and wherein the adsorbent support effects the removal of sulfur and vanadium from a hydrocarbon fuel.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: September 3, 2013
    Assignee: General Electric Company
    Inventors: John Aibangbee Osaheni, Thomas Joseph Fyvie, Gregory Allen O'Neil, Deborah Ann Haitko, Grigorii Lev Soloveichik, Paul Burchell Glaser
  • Patent number: 8476180
    Abstract: A process for regenerating a molecular sieve absorbent bed used for dehydrating an organic solvent is disclosed. The process is illustrated by regenerating a molecular sieve bed used for dehydrating ethanol, which includes a dehydrating cycle where an ethanol/water vapor mixture is loaded onto the molecular sieve bed at a first temperature to absorb water and recover a substantially dehydrated ethanol vapor effluent. In a regeneration cycle, the bed is subjected to a temperature swing technique whereby a dried gas, such as dried CO2, heated to at a second temperature greater than the first temperature, is passed over the molecular sieve bed, optimally in a counter current directional flow with respect to the dehydrating cycle. The process obviates the need for applying a vacuum pressure swing to regenerate the molecular sieve bed. Water and residual ethanol are removed with the CO2 effluent and can optionally be condensed and combined with a feed input for a subsequent dehydrating cycle.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: July 2, 2013
    Assignee: Archer Daniels Midland Company
    Inventors: Ahmad K. Hilaly, Joseph R. Beggin
  • Patent number: 8470725
    Abstract: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle(s), comprising the steps of: (i) oxidizing the catalyst particle(s) at a temperature between 20 and 400° C.; (ii) treating the catalyst particle(s) for more than 5 minutes with a solvent, which solvent comprises an amine, (iii) drying the catalyst particle(s); and (iv) optionally reducing the catalyst particle(s) with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s).
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: June 25, 2013
    Assignee: Shell Oil Company
    Inventors: Gerrit Leendert Bezemer, Stephen Nkrumah
  • Patent number: 8455383
    Abstract: A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can lead to the reactivation of the catalyst in the primary alkylation reactor.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: June 4, 2013
    Assignee: Fina Technology, Inc.
    Inventor: James R. Butler
  • Patent number: 8435920
    Abstract: Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having the following formulas: (a) CexByB?zB?O?, wherein B=Ba, Sr, Ca, or Zr; B?=Mn, Co, and/or Fe; B?=Cu; 0.01<x<0.99; 0<y<0.6; 0<z<0.5; (b) Ce1-x-yNixByO2-*, wherein B=Zr, Ba, Ca, La, or K; 0.02<x<0.1; 0<y<0.1; and 0.02<*<0.15; and 1<?<2.2 and (c) coal ash either as a catalyst material itself or as a support for said unary or binary metal oxides.
    Type: Grant
    Filed: October 11, 2010
    Date of Patent: May 7, 2013
    Assignee: Eltron Research & Development, Inc.
    Inventors: James H. White, Erick J. Schutte, Sara L. Rolfe
  • Patent number: 8361919
    Abstract: Processes for the alcoholysis, inclusive of transesterification and/or disproportionation, of reactants are disclosed. The alcoholysis process may include feeding reactants and a trace amount of soluble organometallic compound to a reactor comprising a solid alcoholysis catalyst, wherein the soluble organometallic compound and the solid alcoholysis catalyst each independently comprise a Group II to Group VI element, which may be the same element in various embodiments. As an example, diphenyl carbonate may be continuously produced by performing transesterification over a solid catalyst followed by disproportionation, where a trace amount of soluble organometallic compound is fed to the transesterification reactor.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: January 29, 2013
    Assignee: Catalytic Distillation Technologies
    Inventor: J. Yong Ryu
  • Publication number: 20120231947
    Abstract: The invention provides a process for the off site regeneration of a solid catalyst, comprising two consecutive steps: a first step of washing the catalyst using one or more fluid(s) in the supercritical state, so as to extract from the catalyst at least a portion of the hydrocarbons present at the surface of the latter, followed by a second step of combustion of at least a portion of the coke present at the surface of the said catalyst by a heat treatment of the latter in the presence of oxygen and at a temperature ranging from 300° C. to 600° C.
    Type: Application
    Filed: January 6, 2012
    Publication date: September 13, 2012
    Applicant: Eurecat S.A.
    Inventors: Philippe Kerleau, Pierre Dufresne
  • Patent number: 8227366
    Abstract: One exemplary embodiment can be an alkylation system including a catalyst regeneration zone. Generally, the catalyst regeneration zone includes first and second columns. The first column can provide an overhead stream having a catalyst and a first hydrocarbon, a side-stream having the catalyst and water, and a bottom stream having a second hydrocarbon. Typically, the second column receives the side-stream as a feed.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: July 24, 2012
    Assignee: UOP LLC
    Inventor: Robert L. Mehlberg
  • Patent number: 8193111
    Abstract: One exemplary embodiment can be a process for desorbing an adsorbent bed. The process can include passing a desorbent stream through the adsorbent bed to remove at least one of a nitrile compound and an oxygenate compound. Generally, the desorbent stream after desorbing is combined with a feed stream for an alkylation zone after a selective hydrogenation zone.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: June 5, 2012
    Assignee: UOP LLC
    Inventors: Gavin P. Towler, Charles P. Luebke, David N. Myers, Steven L. Krupa
  • Patent number: 8187991
    Abstract: A method of regenerating adsorbent material includes providing a spent adsorbent material and contacting the adsorbent material with a solvent composition to facilitate removing oil and impurities from the spent solvent material.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: May 29, 2012
    Assignee: General Electric Company
    Inventors: John Aibangbee Osaheni, Thomas Joseph Fyvie, Deborah Ann Haitko, Gregory Allen O'Neil, Paul Burchell Glaser
  • Patent number: 8148284
    Abstract: A system for effecting the pretreatment therewith of a sorbent comprising a conveying line (105), such as a pipe, and a plurality of solution nozzles operative for purposes of introducing a solution to treat the sorbent. More particularly, the conveying line (105) includes an inlet (107), an outlet (109), and an inner surface (105a) that is operative to define a passageway (190) through which sorbent particles are capable of being transported between the inlet (107) of the conveying line (105) and the outlet (109) of the conveying line (105).
    Type: Grant
    Filed: February 11, 2008
    Date of Patent: April 3, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: James F. Durant, David J. Matteson, Kurt W. Johnson
  • Patent number: 8067656
    Abstract: A process for separating an ionic liquid from hydrocarbons employs a coalescer material having a stronger affinity for the ionic liquid than the hydrocarbons. The coalescer material can be a high surface area material having a large amount of contact area to which ionic liquid droplets dispersed in the hydrocarbons may adhere. The process includes feeding a mixture comprising ionic liquid droplets dispersed in hydrocarbons to a coalescer comprising the coalescer material. The process further includes a capture step involving adhering at least a portion of the ionic liquid droplets to the coalescer material to provide captured droplets and a coalescing step involving coalescing captured droplets into coalesced droplets. After the capture and coalescence steps, the coalesced droplets are allowed to fall from the coalescer material to separate the ionic liquid from the hydrocarbons and provide a hydrocarbon effluent.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: November 29, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Huping Luo, Moinuddin Ahmed, Krishniah Parimi, Bong-Kyu Chang
  • Patent number: 7935229
    Abstract: A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles with a hydrocarbon H, including performing the steps of a) concentrating the reaction effluent before step b) by distillation at pressures of from 0.1 to 5000 mbar and temperatures of from 10 to 150° C., b) adding a hydrocarbon H to the concentrated reaction effluent to obtain a stream I, and c) feeding stream I, without prior separation of the liquid phases, into an extraction apparatus and extracting it at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: May 3, 2011
    Assignee: BASF SE
    Inventors: Petra Deckert, Peter Bassler, Michael Bartsch, Gerd Haderlein, Hermann Luyken, Jens Scheidel, Peter Pfab, Tobias Aechtner, Wolfgang Siegel
  • Publication number: 20110045965
    Abstract: Processes for the alcoholysis, inclusive of transesterification and/or disproportionation, of reactants are disclosed. The alcoholysis process may include feeding reactants and a trace amount of soluble organometallic compound to a reactor comprising a solid alcoholysis catalyst, wherein the soluble organometallic compound and the solid alcoholysis catalyst each independently comprise a Group II to Group VI element, which may be the same element in various embodiments. As an example, diphenyl carbonate may be continuously produced by performing transesterification over a solid catalyst followed by disproportionation, where a trace amount of soluble organometallic compound is fed to the transesterification reactor.
    Type: Application
    Filed: October 28, 2010
    Publication date: February 24, 2011
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventor: J. Yong Ryu
  • Publication number: 20100304956
    Abstract: One exemplary embodiment can be an alkylation system including a catalyst regeneration zone. Generally, the catalyst regeneration zone includes first and second columns. The first column can provide an overhead stream having a catalyst and a first hydrocarbon, a side-stream having the catalyst and water, and a bottom stream having a second hydrocarbon. Typically, the second column receives the side-stream as a feed.
    Type: Application
    Filed: June 1, 2009
    Publication date: December 2, 2010
    Inventor: Robert L. Mehlberg
  • Patent number: 7824574
    Abstract: Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having one of the following formulas: (a) CexByB?zB?O?, wherein B=Ba, Sr, Ca, or Zr; B?=Mn, Co, or Fe; B?=Cu; 0.01<x<0.99; 0<y<0.6; 0<z<0.5; and 1<?<2.2; (b) SrvLawBxB?yB?zO?, wherein B=Co or Fe; B?=Al or Ga; B?=Cu; 0.01<v<1.4; 0.1<w<1.6; 0.1<x<1.9; 0.1<y<0.9; 0<z<2.2; and 3<?<5.5).
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: November 2, 2010
    Assignee: Eltron Research & Development
    Inventors: James H. White, Erick J. Schutte, Sara L. Rolfe
  • Patent number: 7790646
    Abstract: A process for converting fine catalyst slurried in heavy oil into a coke-like material from which catalytic metals can be recovered comprises mixing fine catalyst slurried in heavy oil with solvent, which causes asphaltenes in the heavy oil to precipitate from the heavy oil; separating fine catalyst and precipitated asphaltenes from the heavy oil and solvent; and converting precipitated asphaltenes to a coke-like material by pyrolizing fine catalyst and precipitated asphaltenes separated from the heavy oil.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: September 7, 2010
    Assignee: Chevron U.S.A. Inc.
    Inventors: Jose Guitian Lopez, Christopher A. Powers, Donald H. Mohr
  • Patent number: 7767609
    Abstract: A method for recovering reforming catalyst comprises obtaining spent reforming catalysts; immersing the spent reforming catalysts with different degrees of aging into a light solution to obtain immersed catalysts and allowing the light solution to enter pores in the spent reforming catalysts to lower a pseudo-skeletal density of each spent reforming catalyst to obtain immersed catalysts; immersing the immersed catalysts into a heavy solution that has a density greater than pseudo-skeletal density of the immersed catalysts and replacing the light solution in the pores in the immersed catalysts by the heavy solution to increase density of the immersed catalysts; and awaiting the immersed catalysts to settle in the heavy solution to obtain settled catalysts, wherein different settling velocities due to aging creates layers of settled catalysts. Therefore, the reforming catalysts with different degrees of aging are easily classified into different layers, which can be reused for cost saving.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: August 3, 2010
    Assignee: Chinese Petroleum Corporation
    Inventors: Wen-Cheng Kang, Hung-Tzu Chiu, Shu-Li Wang, Cheng-Chieh Shih, Cheng-Tsung Hong
  • Publication number: 20100190631
    Abstract: A method for recovering reforming catalyst comprises obtaining spent reforming catalysts; immersing the spent reforming catalysts with different degrees of aging into a light solution to obtain immersed catalysts and allowing the light solution to enter pores in the spent reforming catalysts to lower a pseudo-skeletal density of each spent reforming catalyst to obtain immersed catalysts; immersing the immersed catalysts into a heavy solution that has a density greater than pseudo-skeletal density of the immersed catalysts and replacing the light solution in the pores in the immersed catalysts by the heavy solution to increase density of the immersed catalysts; and awaiting the immersed catalysts to settle in the heavy solution to obtain settled catalysts, wherein different settling velocities due to aging creates layers of settled catalysts. Therefore, the reforming catalysts with different degrees of aging are easily classified into different layers, which can be reused for cost saving.
    Type: Application
    Filed: January 26, 2009
    Publication date: July 29, 2010
    Inventors: Wen-Cheng Kang, Hung-Tzu Chiu, Shu-Li Wang, Cheng-Chieh Shih, Cheng-Tsung Hong
  • Publication number: 20100160148
    Abstract: A catalytic reforming process including a reaction zone and a separate catalyst regeneration zone where catalyst is collected in a catalyst collector in the reaction zone and then directed to the catalyst regeneration zone wherein the catalyst collector is purged with a net gas stream.
    Type: Application
    Filed: December 23, 2008
    Publication date: June 24, 2010
    Inventor: Brian Nabozny
  • Patent number: 7732363
    Abstract: A process for regenerating a used acidic catalyst which has been deactivated by conjunct polymers by removing the conjunct polymers so as to increase the activity of the catalyst is disclosed. Methods for removing the conjunct polymers include hydrogenation, addition of a basic reagent and alkylation. The methods are applicable to all acidic catalysts and are described with reference to certain ionic liquid catalysts.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: June 8, 2010
    Assignee: Chevron U.S.A. Inc.
    Inventors: Saleh Elomari, Thomas V. Harris
  • Publication number: 20100130800
    Abstract: A process for separating an ionic liquid from hydrocarbons employs a coalescer material having a stronger affinity for the ionic liquid than the hydrocarbons. The coalescer material can be a high surface area material having a large amount of contact area to which ionic liquid droplets dispersed in the hydrocarbons may adhere. The process includes feeding a mixture comprising ionic liquid droplets dispersed in hydrocarbons to a coalescer comprising the coalescer material. The process further includes a capture step involving adhering at least a portion of the ionic liquid droplets to the coalescer material to provide captured droplets and a coalescing step involving coalescing captured droplets into coalesced droplets. After the capture and coalescence steps, the coalesced droplets are allowed to fall from the coalescer material to separate the ionic liquid from the hydrocarbons and provide a hydrocarbon effluent.
    Type: Application
    Filed: November 26, 2008
    Publication date: May 27, 2010
    Applicant: Chevron U.S.A. Inc.
    Inventors: Huping Luo, Moinuddin Ahmed, Krishniah Parimi, Bong-Kyu Chang
  • Publication number: 20090312176
    Abstract: A method of regenerating adsorbent material includes providing a spent adsorbent material and contacting the adsorbent material with a solvent composition to facilitate removing oil and impurities from the spent solvent material.
    Type: Application
    Filed: June 11, 2008
    Publication date: December 17, 2009
    Inventors: John Aibangbee Osaheni, Thomas Joseph Fyvie, Deborah Ann Haitko, Gregory Allen O'Neil, Paul Burchell Glaser
  • Patent number: 7576023
    Abstract: Naphtha is selectively hydrodesulfurized in the presence of a sulfided, treated catalyst comprising at least a Group VIB metal catalytic component, to produce sulfur-reduced naphtha with reduced olefin loss due to saturation. The catalyst is treated with hydrogen, a selectively deactivating agent which deactivates its hydrogenation activity, and a protective agent which preserves its hydrodesulfurization activity during the treatment.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: August 18, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Garland B. Brignac, Michele S. Touvelle, Randolph J. Smiley
  • Publication number: 20090203933
    Abstract: Processes for the alcoholysis, inclusive of transesterification and/or disproportionation, of reactants are disclosed. The alcoholysis process may include feeding reactants and a trace amount of soluble organometallic compound to a reactor comprising a solid alcoholysis catalyst, wherein the soluble organometallic compound and the solid alcoholysis catalyst each independently comprise a Group II to Group VI element, which may be the same element in various embodiments. As an example, diphenyl carbonate may be continuously produced by performing transesterification over a solid catalyst followed by disproportionation, where a trace amount of soluble organometallic compound is fed to the transesterification reactor.
    Type: Application
    Filed: February 11, 2008
    Publication date: August 13, 2009
    Applicant: CATALYTIC DISTILLATION TECHNOLOGIES
    Inventor: J. Yong Ryu
  • Publication number: 20090163350
    Abstract: A process to upgrade heavy oil and convert the heavy oil into lower boiling hydrocarbon products is provided. The process employs a catalyst slurry comprising catalyst particles with an average particle size ranging from 1 to 20 microns. In the upgrade process, spent slurry catalyst in heavy oil is generated as an effluent stream, which is subsequently recovered/separated from the heavy oil via membrane filtration. In one embodiment, dynamic filtration is used for the separation of the heavy oil from the catalyst particles. Valuable metals can be recovered from catalyst particles for subsequent re-use in a catalyst synthesis unit, generating a fresh slurry catalyst.
    Type: Application
    Filed: December 30, 2008
    Publication date: June 25, 2009
    Inventors: Andre R. Da Costa, Bruce Reynolds, Christopher A. Powers
  • Publication number: 20090029846
    Abstract: The regeneration of HF alkylation acid in an alkylation unit is improved by withdrawing a vapor stream from the HF regenerator tower and condensing the stream to form a liquid fraction which is accumulated in a side distillation zone; the collected liquid fraction, comprising HF acid, water and some stripping medium is distilled in a batch or continuous type operation to drive off the HF acid (along with stripping medium) and the vapor is returned to the regenerator-stripper vessel. The distillation of the sidedraw liquid is continued until the composition of the liquid attains the azeotropic value or as near to that value as desired. The azeotrope, comprising water and acid can then be dropped out of the distillation vessel for disposal by neutralization in the conventional way.
    Type: Application
    Filed: July 27, 2007
    Publication date: January 29, 2009
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Jeffrey M. Fitt, Curtis A. Lawrence, Richard M. Janclaes, Brett Keegan Johnson, Michael W. Boyea, Nicholas Steiner Conley
  • Patent number: 7449420
    Abstract: Improved processes are provided for the production of alkyl aromatic compounds using zeolite catalyst(s) and for periodic reactivation in situ of zeolite catalyst(s) that have at least in part become deactivated. Processes according to this invention are typically carried out in a reaction section loaded with catalyst(s) wherein a desired alkyl aromatic compound is produced from feed aromatic and olefin compounds followed by a separation section in which the desired product is isolated and recovered. Alkylation, transalkylation, and/or isomerization reactions that occur in the reaction section are carried out in liquid phase or partial liquid phase over the said zeolite catalyst(s).
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: November 11, 2008
    Assignee: Stone & Webster Inc.
    Inventors: Shyh-Yuan Henry Hwang, Waheed A. Mukaddam, Francis A. Demers, Dana Johnson
  • Patent number: 7407905
    Abstract: A method of reactivating a catalyst, such as a solid catalyst or a liquid catalyst. The method comprises providing a catalyst that is at least partially deactivated by fouling agents. The catalyst is contacted with a fluid reactivating agent that is at or above a critical point of the fluid reactivating agent and is of sufficient density to dissolve impurities. The fluid reactivating agent reacts with at least one fouling agent, releasing the at least one fouling agent from the catalyst. The at least one fouling agent becomes dissolved in the fluid reactivating agent and is subsequently separated or removed from the fluid reactivating agent so that the fluid reactivating agent may be reused. A system for reactivating a catalyst is also disclosed.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: August 5, 2008
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Daniel M. Ginosar, David N. Thompson, Raymond P. Anderson
  • Patent number: 7282151
    Abstract: A process is disclosed that relates to the recovery of a metal catalyst from an oxidizer purge stream produced in the synthesis of carboxylic acid, typically terephthalic. More particularly, the process involves recovery of a metal catalyst from an oxidizer purge stream through the use of a pressure filter, the combining of water with a mother liquor to recover the metal catalyst and then subjecting an aqueous mixture so formed to a single stage extraction with an extraction solvent to produce an extract stream comprising organic impurities and a raffinate stream comprising the metal catalyst.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: October 16, 2007
    Assignee: Eastman Chemical Company
    Inventors: Kenny Randolph Parker, Robert Lin