Nickel Containing Patents (Class 502/315)
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Patent number: 7638459Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.Type: GrantFiled: May 25, 2005Date of Patent: December 29, 2009Assignee: UOP LLCInventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
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Patent number: 7638455Abstract: A process for the preparation of a catalyst, which process comprises the steps of: i) mixing an alumina precursor with combustible carbon-containing fibers with a diameter in the range of from 0.5 to 5 ?m and a length of no greater than 100 ?m in an amount in the range of from 20 to 40 wt % based on the total dry mixture; ii) adding nitric acid and water to form an extrudable mass; iii) extruding the mixture to form shaped particles; iv) drying the shaped particles; v) heating the particles in an atmosphere comprising no more than 5 vol % oxygen at a temperature in the range of from 350 to 600° C.; and vi) then heating the particles in a gas mixture comprising at least 12 vol % oxygen at a temperature in the range of from 450 to 600° C.Type: GrantFiled: March 8, 2007Date of Patent: December 29, 2009Assignee: Shell Oil CompanyInventors: Peter Birke, Frank Heinz Goerlitz, Wigbert Gerhard Himmel, Jürgen Hunold, Hans-Heino John
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Patent number: 7632777Abstract: A composite oxide catalyst for the oxidation of an olefin containing Mo and Bi as essential components, characterized in that it has a specific surface area of 5 to 25 m2/g and a pore volume of 0.2 to 0.7 cc/g, and has a pore diameter distribution wherein the volume of the pores having a pore diameter of 0.03 to 0.1 ?m accounts for 30% or more of the total pore volume, the volume of the pores having a pore diameter of 0.1 to 1 ?m accounts for 20% or more of the total pore volume, and the volume of the pores having a pore diameter of less than 0.Type: GrantFiled: November 8, 2002Date of Patent: December 15, 2009Assignee: Mitsubishi Chemical CorporationInventors: Isao Teshigahara, Nariyasu Kanuka, Tomoatsu Iwakura
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Publication number: 20090298677Abstract: A chelated hydroprocessing catalyst exhibiting low moisture is obtained by hearing an impregnated, calcined carrier to a temperature higher than 200° C. and less than a temperature and for a period of time that would cause substantial decomposition of the chelating agent.Type: ApplicationFiled: December 11, 2006Publication date: December 3, 2009Applicant: ADVANCED REFINING TECHNOLOGIES LLCInventors: Cecelia A. Radlowski, Gill M. Malick, Colleen T. Miedona
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Patent number: 7618916Abstract: An object of the present invention is to provide a hydrotreating catalyst capable of being produced by a simple method and capable of realizing ultra-deep desulfurization of sulfur components in gas oil without requiring severer operating conditions as well as capable of reducing nitrogen components simultaneously, to provide a process for producing the catalyst, and to provide a process for desulfurizing gas oil using the catalyst. The invention relates to a catalyst containing on an inorganic oxide support 10 to 40% by weight of a metal in the Group 6 of the periodic table, 1 to 15% by weight of a metal in the Group 8 of the periodic table, 1.5 to 8% by weight of phosphorus, each in terms of an oxide amount based on the catalyst, and 2 to 14% by weight of carbon in terms of an element amount based on the catalyst, wherein the catalyst has a specific surface area of 150 to 300 m2/g, a pore volume of 0.3 to 0.Type: GrantFiled: December 17, 2003Date of Patent: November 17, 2009Assignee: Cosmo Oil Co., Ltd.Inventors: Takashi Fujikawa, Masahiro Kato, Nobumasa Nakajima, Minoru Hashimoto
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Patent number: 7605107Abstract: This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids. The catalyst precursor is thermally treated to partially decompose the organic agent, then sulfided.Type: GrantFiled: September 29, 2005Date of Patent: October 20, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Stuart L. Soled, Sabato Miseo, Joseph E. Baumgartner, Christine E. Kliewer, Andrzej Malek, Andrew C. Moreland
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Patent number: 7598203Abstract: Provided are a hydrogenation catalyst for hydrocarbon oil, having markedly improved desulfurization activity, denitrogenation activity, and dearomatization activity; a carrier for the catalyst and its production; and a method of hydrogenation of hydrocarbon oil with the catalyst.Type: GrantFiled: January 17, 2007Date of Patent: October 6, 2009Assignee: Idemitsu Kosan Co., Ltd.Inventors: Narinobu Kagami, Ryuichiro Iwamoto
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Patent number: 7598204Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.Type: GrantFiled: September 19, 2005Date of Patent: October 6, 2009Assignee: General Motors CorporationInventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
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Patent number: 7592290Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.Type: GrantFiled: April 7, 2005Date of Patent: September 22, 2009Assignee: Sulzer Metco(Canada) Inc.Inventors: Syed Tajammul Hussain, Eugene Stelmack
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Publication number: 20090230026Abstract: This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions.Type: ApplicationFiled: February 23, 2009Publication date: September 17, 2009Inventors: Ki-Hyouk Choi, Sameer Ali Al-Ghamdi, Ali H. Al-Shareef, Ali H. Al-Hamadah
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Patent number: 7585812Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.Type: GrantFiled: June 20, 2008Date of Patent: September 8, 2009Assignee: Sud-Chemie Inc.Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
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Patent number: 7585810Abstract: A catalyst member formed of a substrate configured for gas flow therethrough, a base metal catalytic component disposed in a base metal catalytic layer on the substrate, and a rhodium catalytic material disposed in a rhodium layer. The base metal catalytic component is formed of a base metal; namely, nickel, cobalt, or a combination of at least one of the foregoing base metals. The catalyst member is made by depositing a base metal catalytic component on a substrate configured for gas flow therethrough, and depositing a rhodium catalytic material over the base metal catalytic component.Type: GrantFiled: September 1, 2004Date of Patent: September 8, 2009Assignee: Umicore AG & Co. KGInventors: Laiyuan Chen, Jeffrey G. Weissman
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Patent number: 7569513Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.Type: GrantFiled: April 21, 2008Date of Patent: August 4, 2009Assignee: W. R. Grace & Co.-Conn.Inventor: Stephen Raymond Schmidt
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Publication number: 20090192032Abstract: Disclosed herein is a light-responsive photocatalyst composition, which is a composite oxide semiconductor containing tungsten, and which can efficiently absorb visible light emitted from the sun and light emitted from interior lamps, such as fluorescent lamps, etc., and a method of preparing the light-responsive photocatalyst composition. The visible light-responsive photocatalyst composition can decompose volatile organic compounds or harmful organic matter causing sick house syndrome, even indoors, because it can be activated by visible light outdoors and can respond to light emitted from interior lamps, such as fluorescent lamps, etc.Type: ApplicationFiled: March 26, 2008Publication date: July 30, 2009Applicant: Seoul National University Industry FoundationInventors: In Sun Cho, Sang Wook Lee, Jun Hong Noh, Shin Tae Bae, Dong Wook Kim, Chin Moo Cho, Chae Hyun Kwak, Tae Hoon Noh, Duk Kyu Lee, Kug Sun Hong
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Publication number: 20090187036Abstract: The present invention is directed to nickel compositions and methods for making nickel oxide compositions, specifically, such metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.Type: ApplicationFiled: November 1, 2007Publication date: July 23, 2009Applicant: Symyx Technologies, Inc.Inventor: Alfred Hagemeyer
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Patent number: 7563743Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).Type: GrantFiled: September 8, 2005Date of Patent: July 21, 2009Assignee: Institute Francais du PetroleInventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
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Patent number: 7560047Abstract: The present invention relates to a structured catalyst for reforming of gasoline and a method of preparing the same, more particularly to a structured catalyst for reforming of gasoline for fuel-cell powered vehicles prepared by wash-coating the transition metal based reforming catalyst on the surface of the ceramic honeycomb support wash-coated with sub-micron sized alumina or its precursor to sufficiently increase the effective surface area and the performance of the catalyst and a method of preparing the same.Type: GrantFiled: July 28, 2008Date of Patent: July 14, 2009Assignee: Korea Institute of Science and TechnologyInventors: Dong Ju Moon, Jong Woo Ryu, Dong Min Kang, Byung Gwon Lee, Byoung Sung Ahn, Sang Deuk Lee
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Patent number: 7557063Abstract: The invention relates to noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof.Type: GrantFiled: September 17, 2007Date of Patent: July 7, 2009Assignees: Honda Giken Kogyo Kabushiki Kaisha, Symyx Technologies, Inc.Inventors: Alfred Hagemeyer, Christopher James Brooks, Raymond E. Carhart, Karin Yaccato, Michael Herrmann
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Patent number: 7557062Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.Type: GrantFiled: February 20, 2004Date of Patent: July 7, 2009Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van den Tol-Kershof
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Publication number: 20090145808Abstract: This invention relates to a hydrodesulfurization catalyst and a method for preparing the catalyst by spray pyrolysis. The catalyst is useful for the hydrodesulfurization of gas oils, particularly diesel. The catalyst particles can include at least one metal selected from molybdenum, cobalt and nickel, and a silicon dioxide support. The spray pyrolysis technique allows for the preparation of catalyst particles having high loading of catalyst on the substrate.Type: ApplicationFiled: November 24, 2008Publication date: June 11, 2009Applicant: SAUDI ARABIAN OIL COMPANYInventors: Ki-Hyouk Choi, Isao Mochida
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Patent number: 7544285Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.Type: GrantFiled: February 20, 2004Date of Patent: June 9, 2009Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
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Patent number: 7544633Abstract: The present invention relates to a catalyst for partial oxidation and a preparation method thereof, more particularly to a preparation method of a complex metal oxide catalyst that shows high activity for conversion of propylene or isobutylene, maintains good selectivity for such unsaturated aldehyde as acrolein or methacrolein and improves production yield of such unsaturated carboxylic acid as acrylic acid or methacrylic acid through stable process by using a drying control chemical additive.Type: GrantFiled: February 24, 2005Date of Patent: June 9, 2009Assignee: LG Chem, Ltd.Inventors: Jung-Hwa Kang, Won-Ho Lee, Min-Ho Kil, Sang-Heup Moon, Bu-Young Jo
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Publication number: 20090139904Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2?. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5.Type: ApplicationFiled: October 25, 2006Publication date: June 4, 2009Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: Sona Eijsbouts-Spickova, Jacobus Nicolaas Louwen, Frans L. Plantenga, Robertus Gerardus Leliveld, Sabato Miseo, Stuart Leon Soled
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Patent number: 7541012Abstract: The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.Type: GrantFiled: July 7, 2004Date of Patent: June 2, 2009Assignee: The Hong Kong University of Science and TechnologyInventors: King Lun Yeung, Nan Yao, Ka Yee Ho
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Patent number: 7541310Abstract: This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.Type: GrantFiled: October 12, 2004Date of Patent: June 2, 2009Assignee: ConocoPhillips CompanyInventors: Rafael L. Espinoza, Kandaswamy Jothimurugesan, Kevin L. Coy, James Dale Ortego, Jr., Nithya Srinivasan, Olga P. Ionkina
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Patent number: 7538066Abstract: This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids.Type: GrantFiled: September 29, 2005Date of Patent: May 26, 2009Assignee: Exxonmobil Research and Engineering CompanyInventors: Stuart L. Soled, Sabato Miseo, Joseph E. Baumgartner, Christine E. Kliewer, Jeffrey T. Elks
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Publication number: 20090127165Abstract: The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.Type: ApplicationFiled: October 25, 2006Publication date: May 21, 2009Applicant: Albemarle Netherlands B.V.Inventors: Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Marinus Bruce Cerfontain, Frans L. Plantenga, Eelco Titus Carel Vogt, Jacobus Nicolaas Louwen, Stuart Leon Soled, Sabato Miseo, Kenneth L. Riley
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Publication number: 20090112025Abstract: The present invention provides a novel hydrogenation catalyst, process of preparing the catalyst and process for the preparation of optically active L-norephedrine, [(1R,2S)-2-amino-1-phenyl-1-propanol] by a catalytic hydrogenation process, said catalyst comprising of finely divided nickel metal containing a metal from group III A of the periodic table as an activator and a metal from group VI B or VIII as promoter,Type: ApplicationFiled: February 4, 2008Publication date: April 30, 2009Applicant: Emmellen Biotech Pharmaceuticals LimitedInventor: Sunil Vaman Joshi
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Patent number: 7514055Abstract: Methods of controlling emissions from a diesel engine are provided. The method includes contacting the emissions with a perovskite-type catalyst consisting essentially of a metal oxide composition represented by the general formula Aa?xBxMOb, in which A is a mixture originally in the form of single phase mixed lanthanides collected from bastnasite; B is a divalent or monovalent cation; M is at least one element selected from the group consisting of M is at least one element selected from the group consisting of elements of an atomic number of from 22 to 30, 40 to 51, and 73 to 80; a is 1 or 2; b is 3 when a is 1 or b is 4 when a is 2; and x is a number defined by 0<x<0.7. The perovskite-type catalyst may be used to oxidize hydrocarbons and carbon monoxide and to control particulate emissions in the diesel exhaust.Type: GrantFiled: September 20, 2005Date of Patent: April 7, 2009Assignee: Catalytic Solutions, Inc.Inventor: Stephen J. Golden
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Publication number: 20090088317Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.Type: ApplicationFiled: September 28, 2007Publication date: April 2, 2009Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
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Publication number: 20090082198Abstract: A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula (1): PtxRuyMozTu ??(1) In the formula (1), the T-element is at least one selected from the group consisting of W and V, x is 20 to 80 at. %, y is 10 to 60 at. %, z is 1 to 30 at. % and u is 1 to 30 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.Type: ApplicationFiled: September 28, 2007Publication date: March 26, 2009Inventors: Wu Mei, Taishi Fukazawa, Itsuko Mizutani, Tsuyoshi Kobayashi, Yoshihiko Nakano, Mina Farag, Yi-Qun Li, Shinji Aoki
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Patent number: 7504358Abstract: A crystalline alpha-chromium oxide where from about 0.05 atom % to about 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are substituted by nickel atoms, and optionally, additional chromium atoms in the alpha-chromium oxide lattice are substituted by trivalent cobalt atoms (provided that the total amount of the nickel atoms and the trivalent cobalt atoms in the alpha-chromium oxide lattice is no more than 6 atom %) is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline substituted alpha-chromium oxide.Type: GrantFiled: August 21, 2003Date of Patent: March 17, 2009Assignee: E. I. du Pont de Nemours and CompanyInventors: Velliyur Nott Mallikarjuna Rao, H. David Rosenfeld, Allen C. Sievert, Shekhar Subramoney, Munirpallam Appadorai Subramanian
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Patent number: 7504357Abstract: A catalyst composition having the formula: Mo1VaSbbNbcMdOx wherein M is gallium, bismuth, silver or gold, a is 0.01 to 1, b is 0.01 to 1, c is 0.01 to 1, d is 0.01 to 1 and x is determined by the valence requirements of the other components. Other metals, such as tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, platinum, boron, arsenic, lithium, sodium, potassium, rubidium, calcium, beryllium, magnesium, cerium, strontium, hafnium, phosphorus, europium, gadolinium, dysprosium, holmium, erbium, thulium, terbium, ytterbium, lutetium, lanthanum, scandium, palladium, praseodymium, neodymium, yttrium, thorium, tungsten, cesium, zinc, tin, germanium, silicon, lead, barium or thallium may also be components of the catalyst. This catalyst is prepared by co-precipitation of metal compounds which are calcined to form a mixed metal oxide catalyst that can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process.Type: GrantFiled: May 24, 2007Date of Patent: March 17, 2009Assignee: Saudi Basic Industries CorporationInventors: Paulette N. Hazin, Paul E. Ellis, Jr.
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Publication number: 20090069172Abstract: Embodiments of the present invention are directed to ternary and/or quaternary catalyst alloys for a direct methanol fuel cell (DMFC). The catalyst has the composition (Pt1-xRux)yM?zM?1-y-z, where M? is selected from the group consisting of W, Mo, Nb, and Ta; M? is selected from the group consisting of V, Co, Ni, Mn, and Cu; x ranges from about 0 to about 1; y ranges from about 0.01 to about 0.99; and y+z is about equal to 1. The catalyst may be deposited onto a porous carrier, and the deposition method may include ion-beam sputtering. The onset voltages of the present compositions are lower than that of conventional Pt—Ru binary systems by approximately 0.355 volts, and thus provide enhanced catalytic activity.Type: ApplicationFiled: July 2, 2008Publication date: March 12, 2009Applicant: INTEMATIX CORPORATIONInventors: Mina Touma Farag, Yi-Qun Li
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Patent number: 7501377Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula: Mo12BiaWbFecCodNieSbfCsgMghZniPjOx wherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3-5.0, c:a=2.0-6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95-1.10.Type: GrantFiled: May 24, 2007Date of Patent: March 10, 2009Assignee: Saudi Basic Industries CorporationInventors: Wugeng Liang, Scott A. Stevenson, James W. Kauffman, John S. Ledford, Joseph R. Linzer
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Patent number: 7498289Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.Type: GrantFiled: April 11, 2007Date of Patent: March 3, 2009Assignee: Celanese International CorporationInventor: Yumin Liu
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Publication number: 20090041646Abstract: Provided is a catalyst for reducing and decomposing oxygen in gas, highly efficiently and stably in from a low temperature region to a relatively high temperature region, in the presence of a reducing substance, containing at least one kind of a metal oxide selected from the group consisting of Ti, Si, W, Mo, Zr and Fe, as a catalyst component A; and at least one kind of a metal selected from the group consisting of Pt, Pd, Rh, Ir, Ru, Ni and Co, and/or a metal oxide thereof, as a catalyst component B; in removing oxygen, presence of a reducing substance in gas is effective.Type: ApplicationFiled: March 15, 2006Publication date: February 12, 2009Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Mitsuaki Ikeda, Kazunori Yoshino, Toshikatsu Ikenogami, Atsushi Morita
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Patent number: 7485597Abstract: A method for improving the selectivity of a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, which method comprises contacting the catalyst, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.; and a process for the epoxidation of an olefin, which process comprises contacting a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.Type: GrantFiled: June 26, 2003Date of Patent: February 3, 2009Assignee: Shell Oil CompanyInventors: John Robert Lockemeyer, Randall Clayton Yeates, Donald Reinalda
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Publication number: 20090023965Abstract: The invention provides a catalyst composition, which includes an emulsion of an aqueous phase in an oil phase, wherein the aqueous phase comprises an aqueous solution containing a group 6 metal and a group 8, 9 or 10 metal. The metals can be provided in two separate emulsions, and these emulsions are well suited for treating hydrocarbon feedstocks.Type: ApplicationFiled: May 1, 2008Publication date: January 22, 2009Applicant: INTEVEP, S.A.Inventors: Pedro Pereira, Guaicaipuro Rivas, Jose Cordova, Francisco Granadillo, Roger Marzin, Bruno Solari, Luis Zacarias
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Publication number: 20090022642Abstract: An object of the present invention is to improve the decomposition at low temperatures of perfluorocompounds containing only fluorine as a halogen, such as CF4, C2F6 and the like. In the present invention, a perfluorocompound containing only fluorine as a halogen is brought into contact with a catalyst comprising Al, Ni and W as catalytically active ingredients and comprising a mixed oxide or complex oxide of Ni and Al and a mixed oxide or complex oxide of W and Ni, in the presence of steam or a combination of steam and air at a temperature of 500 to 800° C. to convert the fluorine in the perfluorocompound to hydrogen fluoride. Employment of the catalyst of the present invention improves the decomposition at low temperatures and hence makes it possible to decompose the perfluoro-compound at a high percentage of decomposition at a lower temperature.Type: ApplicationFiled: September 8, 2008Publication date: January 22, 2009Inventors: Shuichi Kanno, Shin Tamata, Shinichi Ichikawa, Terufumi Kawasaki, Hisao Yamashita
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Publication number: 20090023051Abstract: The present teachings are directed toward electrocatalyst compositions of alloys of platinum, tungsten and nickel for use in fuel cells. The alloys consists essentially of platinum present in an atomic percentage ranging between about 20 percent and about 45 percent, tungsten present in an atomic percentage ranging between about 30 percent and about 70 percent, and nickel present in an atomic percentage ranging between about 5 percent and about 25 percent.Type: ApplicationFiled: September 26, 2008Publication date: January 22, 2009Inventors: Ting HE, Eric Rolland KREIDLER
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Patent number: 7470418Abstract: The present invention discloses ultra-fine fibrous carbon and preparation of the same. Specifically, the present ultra-fine fibrous carbon is characterized by the graphite-like structure with the sp2 hybrid carbon content of more than 95% per total content; the (002) plane interlayer spacing (d002, d-spacing of C(002) profiles determined by X-ray diffraction method) of 0.3370-0.3700 nm; the (002) plane stacking of more than 4 layers, namely the stacking height (Lc002) of more than 1.5 nm; fibrous carbon length per fibrous carbon width of diameter (aspect ratio) of more than 20; the average diameter of 5˜50 nm.Type: GrantFiled: October 17, 2003Date of Patent: December 30, 2008Assignee: Nexen Nano Tech Co., Ltd.Inventor: Seong Ho Yoon
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Patent number: 7468342Abstract: As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining.Type: GrantFiled: May 7, 2002Date of Patent: December 23, 2008Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoshinori Kanamori, Shuji Ebata, Kengo Tsukahara, Yasushi Hiramatsu
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Publication number: 20080308462Abstract: The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.Type: ApplicationFiled: October 25, 2006Publication date: December 18, 2008Applicant: Albemarle Netherlands B.V.Inventors: Sona Eijsbouts-Spickova, Robertus Gerardos Leliveld, Bob Gerardus Oogjen, Marinus Bruce Cerfontain, Johannes Cornelis Sitters
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Publication number: 20080305947Abstract: The instant invention is directed to the preparation of a slurry catalyst composition. The slurry catalyst composition is prepared in a series of steps, involving mixing a Group VIB metal oxide and aqueous ammonia to form an aqueous mixture and sulfiding the mixture to form a slurry. The slurry is then promoted with a Group VIII metal. Subsequent steps involve mixing the slurry with a hydrocarbon oil, and combining the resulting mixture with hydrogen gas (under conditions which maintain the water in a liquid phase) to produce the active slurry catalyst.Type: ApplicationFiled: July 7, 2008Publication date: December 11, 2008Inventors: Kaidong Chen, Bruce E. Reynolds
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Publication number: 20080293896Abstract: A process and catalyst for producing homopolymers or copolymers of conjugated dienes by polymerising the monomer with a catalyst system comprising (A) a first transition metal compound selected from Cr, Mo and W compounds, and a second transition metal compound selected from Fe Co and Ni compounds (B) a catalyst modifier (eg triphenyl phosphine) and optionally (C) one or more catalyst activators (eg MAO). The cis, trans and 1,2-vinyl microstructure of the produced diene polymer can be controlled.Type: ApplicationFiled: October 26, 2007Publication date: November 27, 2008Inventors: Juan Jose Chirinos-Colina, Vernon Charles Gibson, Grant Berent Jacobsen
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Patent number: 7452844Abstract: The Fischer-Tropsch catalyst of the present invention is a transition metal-based catalyst having a high surface area, a smooth, homogeneous surface morphology, an essentially uniform distribution of cobalt throughout the support, and a small metal crystallite size. In a first embodiment, the catalyst has a surface area of from about 100 m2/g to about 250 m2/g; an essentially smooth, homogeneous surface morphology; an essentially uniform distribution of metal throughout an essentially inert support; and a metal oxide crystallite size of from about 40 ? to about 200 ?. In a second embodiment, the Fischer-Tropsch catalyst is a cobalt-based catalyst with a first precious metal promoter and a second metal promoter on an aluminum oxide support, the catalyst having from about 5 wt % to about 60 wt % cobalt; from about 0.0001 wt % to about 1 wt % of the first promoter, and from about 0.01 wt % to about 5 wt % of the second promoter.Type: GrantFiled: May 8, 2001Date of Patent: November 18, 2008Assignee: Süd-Chemie IncInventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
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Publication number: 20080265212Abstract: The invention relates to novel bimetallic and trimetallic catalysts, their manufacture and use in both steam reforming and oxidative steam reforming of liquid fuels such as jet fuels, diesel fuels and gasoline to produce synthesis gas and/or hydrogen for fuel cell applications. The invention further relates to manufacture of synthesis gas and/or hydrogen gas for chemicals synthesis and fuel processing. The catalysts have high sulfur tolerance and carbon resistance when used in steam reforming and/or oxidative steam reforming of heavy hydrocarbon fuels.Type: ApplicationFiled: January 17, 2008Publication date: October 30, 2008Applicant: The Penn State Research FoundationInventors: Chunshan Song, James J. Strohm, Jian Zheng, Weidong Gu, Chao Xie, Xiaoxing Wang
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Patent number: 7435504Abstract: The present teachings are directed toward electrocatalyst compositions of alloys of platinum, tungsten and one of either of nickel or zirconium for use in fuel cells. The alloys consists essentially of platinum present in an atomic percentage ranging between about 20 percent and about 45 percent, tungsten present in an atomic percentage ranging between about 30 percent and about 70 percent, and one of either nickel present in an atomic percentage ranging between about 5 percent and about 25 percent, or zirconium present in an atomic percentage ranging between about 5 percent and about 40 percent.Type: GrantFiled: August 25, 2005Date of Patent: October 14, 2008Assignee: Honda Motor Co., Ltd.Inventors: Ting He, Eric Rolland Kreidler
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Patent number: 7429682Abstract: A catalyst for gas phase oxidation of methylbenzenes in the presence of molecular oxygen to produce corresponding aromatic aldehydes, a method for preparing the catalyst, and a method for producing aromatic aldehydes from methylbenzenes by using the catalyst. The catalyst comprises a compound represented by the following formula (1): WaXbYcOx ??(1) wherein W represents a tungsten atom, X represents one or more alkali metals selected from the group consisting of Li, Na, K, Rb, and Cs, Y represents one or more elements selected from the group consisting of Fe, Co, Ni, Cu, Mn, Re, Cr, V, Nb, Ti, Zr, Zn, Cd, Y, La, Ce, B, Al, Sn, Mg, Ca, Sr, and Ba, O stands for an oxygen atom, and the ratio of a:b:c is 12:0.001˜1:0˜5.Type: GrantFiled: November 22, 2006Date of Patent: September 30, 2008Assignee: LG Chem, Ltd.Inventors: Won Ho Lee, Hyun Kyung Yoon, Dong Il Lee, Jong Hyun Chae, Ji Hyang Son, In Kyu Park, Won Jae Lee