Iron Containing Patents (Class 502/316)
  • Publication number: 20100196260
    Abstract: The invention relates to producing hydrogen by means of the vapour conversion of carbon monoxide and a catalyst for said process and can be used in different industries. The invention discloses an iron-chromium catalyst containing an iron-chromium hydroxyl compound phase having a goethite and/or hydrohematite structure, a method for the preparation thereof and a method for the use thereof in a process for the vapour conversion of carbon monoxide. The catalyst can also contain copper. The catalyst is obtainable by precipitating sodium and potassium, by means on solutions of carbonates or ammonia hydroxides, from solutions of mixture of iron 2+ and 3+ and chromium 3+ nitrates which are obtained by the oxidation-reduction interaction of metal iron, chromium 6+ compounds and nitric acid. A process for the vapour conversion of carbon monoxide using said catalyst according to the inventive method is carried out at a temperature greater than 250° C.
    Type: Application
    Filed: August 23, 2007
    Publication date: August 5, 2010
    Inventors: Tamara Mikhailovna Jurieva, Margarita Petrovna Demeshkina, Alexandr Alexandrovich Khasin, Tatyana Petrovna Minjukova, Ljudmila Mikhailovna Plyasova, Natalya Alekseevna Baronskaya, Marina Valerievna Lebedeva, Irina Dmitrievna Reznichenko, Leonid Gennadievich Volchatov, Alexandr Petrovich Bocharov, Marina Ivanovna Tseljutina, Olga Mikhailovna Posokhova, Tatyana Ivanovna Andreeva
  • Publication number: 20100193402
    Abstract: A complex metal oxide catalyst comprising a Group VIII metal MI and at least two Group VIB metals MII and MIII, wherein the molar ratio of Group VIII metal MI to Group VIB metals MII+MIII is 1:9-9:1 and the molar ratio of the Group VIB metals MII and MIII is 1:5 to 5:1. When applied to the hydrodesulfurization of diesel, the catalyst exhibits a super high HDS activity. The sulfur level in the diesel can be reduced from 1200 ppm to 27 ppm under a gentle operating condition.
    Type: Application
    Filed: November 26, 2008
    Publication date: August 5, 2010
    Inventors: Can Li, Zongxuan Jiang, Lu Wang
  • Patent number: 7749937
    Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: July 6, 2010
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van Den Tol-Kershof
  • Publication number: 20100158775
    Abstract: Air treatment catalyst systems and methods for treating the air in the aircraft cabin environment are provided. The catalyst system and method remove ozone, volatile organic compounds, NOx and other pollutants. The catalyst system used to treat the cabin air comprises a plurality of discrete substrates having an ozone abatement catalyst loaded thereon and arranged in a stacked configuration between a source of the air stream and the passenger cabin, the at least the first two substrates adjacent the source of the air stream comprise an iron-based alloy.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Applicant: BASF Catalysts LLC
    Inventors: Michael P. Galligan, Mark Buelow, Martin Volland, Pascaline Harrison Tran, Bruce J. Frishberg
  • Publication number: 20100155301
    Abstract: The invention describes a catalyst comprising at least one metal from group VIB, at least two metals from group VIII termed the major promoter VIII-1 and co-promoters VIII-i, where i is in the range 2 to 5, and at least one support constituted by a porous refractory oxide, in which the elements from group VIII are present in proportions defined by the atomic ratio [VIII-1/(VIII-1+ . . . +VIII-i)], said ratio being in the range 0.5 to 0.85, as well as a process for the hydrotreatment of heavy hydrocarbon feeds, comprising at least one hydrodemetallization step and at least one hydrodesulphurization step, and employing a catalyst in accordance with the invention with an identical atomic ratio in each of the hydrodemetallization and hydrodesulphurization steps.
    Type: Application
    Filed: December 17, 2009
    Publication date: June 24, 2010
    Applicant: IFP
    Inventors: Bertrand Guichard, Denis Guillaume
  • Publication number: 20100116713
    Abstract: Heavy crude oil residue and vacuum residue is upgraded using an ionic liquid catalyst formulated with metals of Group VIB and VIIIB of the periodic table, which catalyst is highly miscible in the hydrocarbon phase. The combination of different metals and acidity from the protons that make up the ionic liquid breaks the links C—S, C—N and C—O of the resins and asphaltenes and increases API gravity, decreases viscosity, removes sulfur and nitrogen compounds, and results in conversion of 50 to 70% of the waste oil and heavy crude oil into lighter distillates.
    Type: Application
    Filed: May 11, 2009
    Publication date: May 13, 2010
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Felipe de Jesús Ortega García, Persi Schacht Hernández, Marco Antonio Ramírez Garnica, Natalya Victorovna Likhanova, Joaquín Rodolfo Hernández Pérez, Ricardo Jesús Ramírez López
  • Patent number: 7712471
    Abstract: Smoking article components, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided that use transition metal oxide clusters capable of catalyzing and/or oxidizing the conversion of carbon monoxide to carbon dioxide and/or adsorbing carbon monoxide. Cut filler compositions, cigarette paper and cigarette filter material can comprise transition metal oxide clusters.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: May 11, 2010
    Assignee: Philip Morris USA Inc.
    Inventors: Budda V. Reddy, Firooz Rasouli, Mohammad R. Hajaligol, Shiv N. Khanna
  • Patent number: 7713908
    Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: May 11, 2010
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
  • Patent number: 7687428
    Abstract: A method of preparing carbon-loaded, gold-based nanoparticle catalysts useful as anode catalysts for the electrocatalytic methanol oxidation reaction (MOR) as well as the oxygen reduction reaction (ORR). AumPtnM100-m-n catalysts may be prepared by either a two-phase protocol or by a thermal decomposition/reduction protocol. The prepared nanoparticles having different bimetallic ratios are assembled on carbon black support materials and activated by thermal treatment. This approach provides good control of nanoparticle size, composition and/or surface properties. Electrocatalytic MOR activities of the prepared and activated AuPt nanoparticle provided in accordance with the methods of the invention are present in both acidic and alkaline electrolytes.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: March 30, 2010
    Assignee: The Research Foundation of the State University of New York
    Inventors: Chuan-Jian Zhong, Jin Luo, Nancy N. Kariuki, Linyang Wang, Peter Njoki, Derrick Mott
  • Publication number: 20100063326
    Abstract: Catalyst comprising a combination of oxidized metals and processes for cleaving phenylalkyl hydroperoxides in the presence of the catalyst.
    Type: Application
    Filed: May 14, 2007
    Publication date: March 11, 2010
    Inventors: Narayana Mysore, John Charles Saukaitis, John Anthony Smegal
  • Publication number: 20100022386
    Abstract: A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof, b) at least one of Fe and Rh, their oxides and mixtures thereof, and c) at least one member selected from the group consisting of Sc, Y, Ti, Zr, V, Nb, Ta, Mo, Re, Co, Ni, Pd, Ge, Sn, Sb, La, Ce, Pr, Nd, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
    Type: Application
    Filed: July 20, 2009
    Publication date: January 28, 2010
    Inventors: Alfred Hagemeyer, Christopher James Brooks, Raymond E. Carhart, Karin Yaccato, Cory Bernard Phillips, Peter Strasser, Robert K. Grasselli
  • Patent number: 7641875
    Abstract: A multi-phase catalyst for the simultaneous conversion of oxides of nitrogen, carbon monoxide, and hydrocarbons is provided. A catalyst composition comprising the multi-phase catalyst and methods of making the catalyst composition are also provided. The multi-phase catalyst may be represented by the general formula of CeyLn1-xAx+sMOZ, wherein Ln is a mixture of elements originally in the form of single-phase mixed lanthanides collected from natural ores, a single lanthanide, or a mixture of lanthanides; A is an element selected from a group consisting of Mg, Ca, Sr, Ba, Li, Na, K, Cs, Rb, or any combination thereof; and M is an element selected from the group consisting of Fe, Mn, Cr, Ni, Co, Cu, V, Zr, Pt, Pd, Rh, Ru, Ag, Au, Al, Ga, Mo, W, Ti, or any combination thereof; x is a number defined by 0?x<1.0; y is a number defined by 0?y<10; s is a number defined by 0?s<10; where s=0 only when y>0 and y=0 only when s>0.
    Type: Grant
    Filed: November 3, 2008
    Date of Patent: January 5, 2010
    Assignee: Catalytic Solutions, Inc.
    Inventor: Stephen J. Golden
  • Patent number: 7638459
    Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: December 29, 2009
    Assignee: UOP LLC
    Inventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
  • Patent number: 7638455
    Abstract: A process for the preparation of a catalyst, which process comprises the steps of: i) mixing an alumina precursor with combustible carbon-containing fibers with a diameter in the range of from 0.5 to 5 ?m and a length of no greater than 100 ?m in an amount in the range of from 20 to 40 wt % based on the total dry mixture; ii) adding nitric acid and water to form an extrudable mass; iii) extruding the mixture to form shaped particles; iv) drying the shaped particles; v) heating the particles in an atmosphere comprising no more than 5 vol % oxygen at a temperature in the range of from 350 to 600° C.; and vi) then heating the particles in a gas mixture comprising at least 12 vol % oxygen at a temperature in the range of from 450 to 600° C.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: December 29, 2009
    Assignee: Shell Oil Company
    Inventors: Peter Birke, Frank Heinz Goerlitz, Wigbert Gerhard Himmel, Jürgen Hunold, Hans-Heino John
  • Patent number: 7632777
    Abstract: A composite oxide catalyst for the oxidation of an olefin containing Mo and Bi as essential components, characterized in that it has a specific surface area of 5 to 25 m2/g and a pore volume of 0.2 to 0.7 cc/g, and has a pore diameter distribution wherein the volume of the pores having a pore diameter of 0.03 to 0.1 ?m accounts for 30% or more of the total pore volume, the volume of the pores having a pore diameter of 0.1 to 1 ?m accounts for 20% or more of the total pore volume, and the volume of the pores having a pore diameter of less than 0.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: December 15, 2009
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Isao Teshigahara, Nariyasu Kanuka, Tomoatsu Iwakura
  • Patent number: 7628968
    Abstract: The present invention is directed to high activity titanium oxide DeNOx catalysts. In preferred embodinents, by depositing vanadium oxide on a titania supported metal oxide such as tungsten oxide, an improved catalyst may be generated. This catalyst may be used in the treatment of exhaust from sources such as automobiles and industrial plants.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: December 8, 2009
    Assignee: Millenium Inorganic Chemicals, Inc.
    Inventors: Steven M Augustine, Guoyi Fu
  • Patent number: 7618916
    Abstract: An object of the present invention is to provide a hydrotreating catalyst capable of being produced by a simple method and capable of realizing ultra-deep desulfurization of sulfur components in gas oil without requiring severer operating conditions as well as capable of reducing nitrogen components simultaneously, to provide a process for producing the catalyst, and to provide a process for desulfurizing gas oil using the catalyst. The invention relates to a catalyst containing on an inorganic oxide support 10 to 40% by weight of a metal in the Group 6 of the periodic table, 1 to 15% by weight of a metal in the Group 8 of the periodic table, 1.5 to 8% by weight of phosphorus, each in terms of an oxide amount based on the catalyst, and 2 to 14% by weight of carbon in terms of an element amount based on the catalyst, wherein the catalyst has a specific surface area of 150 to 300 m2/g, a pore volume of 0.3 to 0.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: November 17, 2009
    Assignee: Cosmo Oil Co., Ltd.
    Inventors: Takashi Fujikawa, Masahiro Kato, Nobumasa Nakajima, Minoru Hashimoto
  • Patent number: 7598204
    Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: October 6, 2009
    Assignee: General Motors Corporation
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
  • Patent number: 7598203
    Abstract: Provided are a hydrogenation catalyst for hydrocarbon oil, having markedly improved desulfurization activity, denitrogenation activity, and dearomatization activity; a carrier for the catalyst and its production; and a method of hydrogenation of hydrocarbon oil with the catalyst.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: October 6, 2009
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Narinobu Kagami, Ryuichiro Iwamoto
  • Patent number: 7592290
    Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: September 22, 2009
    Assignee: Sulzer Metco(Canada) Inc.
    Inventors: Syed Tajammul Hussain, Eugene Stelmack
  • Publication number: 20090232728
    Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.
    Type: Application
    Filed: March 14, 2008
    Publication date: September 17, 2009
    Applicant: Sud-Chemie Inc.
    Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
  • Publication number: 20090230026
    Abstract: This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions.
    Type: Application
    Filed: February 23, 2009
    Publication date: September 17, 2009
    Inventors: Ki-Hyouk Choi, Sameer Ali Al-Ghamdi, Ali H. Al-Shareef, Ali H. Al-Hamadah
  • Patent number: 7585812
    Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: September 8, 2009
    Assignee: Sud-Chemie Inc.
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Patent number: 7569513
    Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: August 4, 2009
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Stephen Raymond Schmidt
  • Publication number: 20090192032
    Abstract: Disclosed herein is a light-responsive photocatalyst composition, which is a composite oxide semiconductor containing tungsten, and which can efficiently absorb visible light emitted from the sun and light emitted from interior lamps, such as fluorescent lamps, etc., and a method of preparing the light-responsive photocatalyst composition. The visible light-responsive photocatalyst composition can decompose volatile organic compounds or harmful organic matter causing sick house syndrome, even indoors, because it can be activated by visible light outdoors and can respond to light emitted from interior lamps, such as fluorescent lamps, etc.
    Type: Application
    Filed: March 26, 2008
    Publication date: July 30, 2009
    Applicant: Seoul National University Industry Foundation
    Inventors: In Sun Cho, Sang Wook Lee, Jun Hong Noh, Shin Tae Bae, Dong Wook Kim, Chin Moo Cho, Chae Hyun Kwak, Tae Hoon Noh, Duk Kyu Lee, Kug Sun Hong
  • Patent number: 7563743
    Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: July 21, 2009
    Assignee: Institute Francais du Petrole
    Inventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
  • Patent number: 7560047
    Abstract: The present invention relates to a structured catalyst for reforming of gasoline and a method of preparing the same, more particularly to a structured catalyst for reforming of gasoline for fuel-cell powered vehicles prepared by wash-coating the transition metal based reforming catalyst on the surface of the ceramic honeycomb support wash-coated with sub-micron sized alumina or its precursor to sufficiently increase the effective surface area and the performance of the catalyst and a method of preparing the same.
    Type: Grant
    Filed: July 28, 2008
    Date of Patent: July 14, 2009
    Assignee: Korea Institute of Science and Technology
    Inventors: Dong Ju Moon, Jong Woo Ryu, Dong Min Kang, Byung Gwon Lee, Byoung Sung Ahn, Sang Deuk Lee
  • Patent number: 7557062
    Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: July 7, 2009
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van den Tol-Kershof
  • Publication number: 20090145808
    Abstract: This invention relates to a hydrodesulfurization catalyst and a method for preparing the catalyst by spray pyrolysis. The catalyst is useful for the hydrodesulfurization of gas oils, particularly diesel. The catalyst particles can include at least one metal selected from molybdenum, cobalt and nickel, and a silicon dioxide support. The spray pyrolysis technique allows for the preparation of catalyst particles having high loading of catalyst on the substrate.
    Type: Application
    Filed: November 24, 2008
    Publication date: June 11, 2009
    Applicant: SAUDI ARABIAN OIL COMPANY
    Inventors: Ki-Hyouk Choi, Isao Mochida
  • Patent number: 7544633
    Abstract: The present invention relates to a catalyst for partial oxidation and a preparation method thereof, more particularly to a preparation method of a complex metal oxide catalyst that shows high activity for conversion of propylene or isobutylene, maintains good selectivity for such unsaturated aldehyde as acrolein or methacrolein and improves production yield of such unsaturated carboxylic acid as acrylic acid or methacrylic acid through stable process by using a drying control chemical additive.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: June 9, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Jung-Hwa Kang, Won-Ho Lee, Min-Ho Kil, Sang-Heup Moon, Bu-Young Jo
  • Patent number: 7541012
    Abstract: The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: June 2, 2009
    Assignee: The Hong Kong University of Science and Technology
    Inventors: King Lun Yeung, Nan Yao, Ka Yee Ho
  • Patent number: 7541310
    Abstract: This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: June 2, 2009
    Assignee: ConocoPhillips Company
    Inventors: Rafael L. Espinoza, Kandaswamy Jothimurugesan, Kevin L. Coy, James Dale Ortego, Jr., Nithya Srinivasan, Olga P. Ionkina
  • Patent number: 7538064
    Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a tungstated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a phosphorus component, and at least one platinum-group metal component which is preferably platinum. The catalyst has a structure other than a hetropoly anion structure.
    Type: Grant
    Filed: June 26, 2008
    Date of Patent: May 26, 2009
    Assignee: UOP LLC
    Inventors: Ralph D. Gillespie, Feng Xu
  • Publication number: 20090124712
    Abstract: Process for the production of hybrid catalysts formed by mixing two catalysts; one active in Fischer-Tropsch synthesis, the other being bifunctional. Such hybrid catalyst thus formed is active both in hydrocracking and in hydroisomerisation reactions. The present invention in addition provides obtainment of a hybrid catalyst and application thereof conjointly with FT catalysts in Fischer-Tropsch synthesis reactions. The hybrid catalyst of the present invention is capable of producing in conditions typically such as those utilised in Fischer-Tropsch synthesis branched hydrocarbons in diverse bands relating to the products thereof (for example naphtha and diesel), reducing or even eliminating necessity for a subsequent hydrotreatment stage in such synthesis reactions.
    Type: Application
    Filed: October 29, 2008
    Publication date: May 14, 2009
    Applicant: PETROLEO BRASILEIRO S.A.- PETROBRAS
    Inventors: Alexandre DE FIGUEIREDO COSTA, Agustin Martines Feliu, Joan Rollan Martinez, Henrique Soares Cerqueira, Joberto Ferreira Dias Junior, Eduardo Falabella Sousa Aguiar
  • Publication number: 20090117447
    Abstract: For the oxygen reduction reaction at the cathode of proton exchange membrane fuel cells, a metal alloy catalyst contains the metals Pd, M1 and M2 where M1 and M2 are different metals selected from Co, Fe, Au, Cr and W (but excluding the combination PdCoAu). Preferred ternary alloys for use as catalysts may be selected from PdCoCr, PdCoW, PdFeCr, PdFeW, PdCrW, PdWAu, PdCrAu, PdCoFe and PdFeAu. Compositional ranges that are specially effective are assessed by a high throughput physical vapour deposition method. Catalysts especially suitable for use in direct methanol fuel cells are identified.
    Type: Application
    Filed: October 6, 2006
    Publication date: May 7, 2009
    Applicant: IIika Technologies Ltd.
    Inventors: Karen M. Brace, Brian E. Hayden, Christopher E. Lee, Thierry Le Gall
  • Publication number: 20090088317
    Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.
    Type: Application
    Filed: September 28, 2007
    Publication date: April 2, 2009
    Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
  • Patent number: 7504357
    Abstract: A catalyst composition having the formula: Mo1VaSbbNbcMdOx wherein M is gallium, bismuth, silver or gold, a is 0.01 to 1, b is 0.01 to 1, c is 0.01 to 1, d is 0.01 to 1 and x is determined by the valence requirements of the other components. Other metals, such as tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, platinum, boron, arsenic, lithium, sodium, potassium, rubidium, calcium, beryllium, magnesium, cerium, strontium, hafnium, phosphorus, europium, gadolinium, dysprosium, holmium, erbium, thulium, terbium, ytterbium, lutetium, lanthanum, scandium, palladium, praseodymium, neodymium, yttrium, thorium, tungsten, cesium, zinc, tin, germanium, silicon, lead, barium or thallium may also be components of the catalyst. This catalyst is prepared by co-precipitation of metal compounds which are calcined to form a mixed metal oxide catalyst that can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: March 17, 2009
    Assignee: Saudi Basic Industries Corporation
    Inventors: Paulette N. Hazin, Paul E. Ellis, Jr.
  • Patent number: 7501377
    Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula: Mo12BiaWbFecCodNieSbfCsgMghZniPjOx wherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3-5.0, c:a=2.0-6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95-1.10.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: March 10, 2009
    Assignee: Saudi Basic Industries Corporation
    Inventors: Wugeng Liang, Scott A. Stevenson, James W. Kauffman, John S. Ledford, Joseph R. Linzer
  • Publication number: 20090062587
    Abstract: A dehydrogenation catalyst is described that comprises an iron oxide, an alkali metal or compound thereof, and rhenium or a compound thereof. A process for preparing a dehydrogenation catalyst comprising preparing a mixture of iron oxide, an alkali metal or compound thereof, and rhenium or a compound thereof is also described. Additionally, a dehydrogenation process using the catalyst and a process for preparing polymers are described.
    Type: Application
    Filed: May 1, 2008
    Publication date: March 5, 2009
    Inventor: Ruth Mary KOWALESKI
  • Publication number: 20090062588
    Abstract: A dehydrogenation catalyst is described comprising an iron oxide, an alkali metal or compound thereof, and silver or a compound thereof. Further a process is described for preparing a dehydrogenation catalyst that comprises preparing a mixture of iron oxide, an alkali metal or compound thereof, and silver or a compound thereof and calcining the mixture. A process for dehydrogenating a dehydrogenatable hydrocarbon and a process for polymerizing the dehydrogenated hydrocarbon are also described.
    Type: Application
    Filed: May 1, 2008
    Publication date: March 5, 2009
    Inventor: Ruth Mary KOWALESKI
  • Patent number: 7491673
    Abstract: The present invention provides a method for producing a catalyst comprising an inert carrier an a mixed metal oxide as a catalytically active component supported on the inert carrier, the method comprising the steps of: a) adding organic acid(s) into solvent(s) and salt of each metal component which will form a mixed metal oxide, to prepare a catalyst precursor solution for the mixed metal oxide; b) adjusting pH of the catalyst precursor solution using a basic solution; c) containing the catalyst precursor solution for the mixed metal oxide, of which the pH is adjusted, on the inert carrier, d) removing the solvent(s); and e) calcining the resultant from step d. The catalyst produced by the present method has improved reproducibility, activity and yield, while maintaining a high selectivity.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: February 17, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Jung Hwa Kang, Won Ho Lee, Min Ho Kil, Hyun Jong Shin, Byung Yul Choi, Yeon Shick Yoo, Young Hyun Choi, Ju Yeon Park
  • Patent number: 7491676
    Abstract: The present invention is directed to high activity titanium oxide DeNOx catalysts. In preferred embodiments, by depositing vanadium oxide on a titania supported metal oxide such as tungsten oxide, an improved catalyst may be generated. This catalyst may be used in the treatment of exhaust from sources such as automobiles and industrial plants.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: February 17, 2009
    Assignee: Millennium Inorganic Chemicals
    Inventors: Steven M. Augustine, Guoyi Fu
  • Patent number: 7485597
    Abstract: A method for improving the selectivity of a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, which method comprises contacting the catalyst, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.; and a process for the epoxidation of an olefin, which process comprises contacting a supported highly selective epoxidation catalyst comprising silver in a quantity of at most 0.17 g per m2 surface area of the support, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a catalyst temperature above 250° C. for a duration of up to 150 hours, and subsequently decreasing the catalyst temperature to a value of at most 250° C.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: February 3, 2009
    Assignee: Shell Oil Company
    Inventors: John Robert Lockemeyer, Randall Clayton Yeates, Donald Reinalda
  • Patent number: 7473666
    Abstract: A particulate porous ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile by reacting propylene, isobutene or tert-butyl alcohol with molecular oxygen and ammonia in a fluidized-bed reactor, the catalyst comprising a metal oxide and a silica carrier having supported thereon the metal oxide, wherein the metal oxide contains at least two elements selected from the group consisting of molybdenum, bismuth, iron, vanadium, antimony, tellurium and niobium, and the catalyst having a particle diameter distribution wherein the amount of catalyst particles having a particle diameter of from 5 to 200 ?m is from 90 to 100% by weight, based on the weight of the catalyst, and having a pore distribution wherein the cumulative pore volume of pores having a pore diameter of 80 ? or less is not more than 20%, based on the total pore volume of the catalyst and wherein the cumulative pore volume of pores having a pore diameter of 1,000 ? or more is not more than 20%, based on the total pore volume of the
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: January 6, 2009
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hiroyuki Yanagi, Hideo Midorikawa, Tutomu Ueda
  • Patent number: 7470418
    Abstract: The present invention discloses ultra-fine fibrous carbon and preparation of the same. Specifically, the present ultra-fine fibrous carbon is characterized by the graphite-like structure with the sp2 hybrid carbon content of more than 95% per total content; the (002) plane interlayer spacing (d002, d-spacing of C(002) profiles determined by X-ray diffraction method) of 0.3370-0.3700 nm; the (002) plane stacking of more than 4 layers, namely the stacking height (Lc002) of more than 1.5 nm; fibrous carbon length per fibrous carbon width of diameter (aspect ratio) of more than 20; the average diameter of 5˜50 nm.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: December 30, 2008
    Assignee: Nexen Nano Tech Co., Ltd.
    Inventor: Seong Ho Yoon
  • Patent number: 7468341
    Abstract: Catalysts for oxidation of methanol to formaldehyde, comprising a catalytic mixtures of Fe2(MoO4)3/MoO3, wherein the Mo/Fe atomic ratio ranges from 1.5 to 5, and a compound of cerium molybdenum and oxygen in a quantity from 0.1 to 10% by weight expressed as cerium.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: December 23, 2008
    Assignee: Sud-Chemie Catalysts Italia S.R.L.
    Inventors: Esterino Conca, Carlo Rubini, Marcello Marchi
  • Publication number: 20080305947
    Abstract: The instant invention is directed to the preparation of a slurry catalyst composition. The slurry catalyst composition is prepared in a series of steps, involving mixing a Group VIB metal oxide and aqueous ammonia to form an aqueous mixture and sulfiding the mixture to form a slurry. The slurry is then promoted with a Group VIII metal. Subsequent steps involve mixing the slurry with a hydrocarbon oil, and combining the resulting mixture with hydrogen gas (under conditions which maintain the water in a liquid phase) to produce the active slurry catalyst.
    Type: Application
    Filed: July 7, 2008
    Publication date: December 11, 2008
    Inventors: Kaidong Chen, Bruce E. Reynolds
  • Publication number: 20080293896
    Abstract: A process and catalyst for producing homopolymers or copolymers of conjugated dienes by polymerising the monomer with a catalyst system comprising (A) a first transition metal compound selected from Cr, Mo and W compounds, and a second transition metal compound selected from Fe Co and Ni compounds (B) a catalyst modifier (eg triphenyl phosphine) and optionally (C) one or more catalyst activators (eg MAO). The cis, trans and 1,2-vinyl microstructure of the produced diene polymer can be controlled.
    Type: Application
    Filed: October 26, 2007
    Publication date: November 27, 2008
    Inventors: Juan Jose Chirinos-Colina, Vernon Charles Gibson, Grant Berent Jacobsen
  • Patent number: 7452844
    Abstract: The Fischer-Tropsch catalyst of the present invention is a transition metal-based catalyst having a high surface area, a smooth, homogeneous surface morphology, an essentially uniform distribution of cobalt throughout the support, and a small metal crystallite size. In a first embodiment, the catalyst has a surface area of from about 100 m2/g to about 250 m2/g; an essentially smooth, homogeneous surface morphology; an essentially uniform distribution of metal throughout an essentially inert support; and a metal oxide crystallite size of from about 40 ? to about 200 ?. In a second embodiment, the Fischer-Tropsch catalyst is a cobalt-based catalyst with a first precious metal promoter and a second metal promoter on an aluminum oxide support, the catalyst having from about 5 wt % to about 60 wt % cobalt; from about 0.0001 wt % to about 1 wt % of the first promoter, and from about 0.01 wt % to about 5 wt % of the second promoter.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: November 18, 2008
    Assignee: Süd-Chemie Inc
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Publication number: 20080265212
    Abstract: The invention relates to novel bimetallic and trimetallic catalysts, their manufacture and use in both steam reforming and oxidative steam reforming of liquid fuels such as jet fuels, diesel fuels and gasoline to produce synthesis gas and/or hydrogen for fuel cell applications. The invention further relates to manufacture of synthesis gas and/or hydrogen gas for chemicals synthesis and fuel processing. The catalysts have high sulfur tolerance and carbon resistance when used in steam reforming and/or oxidative steam reforming of heavy hydrocarbon fuels.
    Type: Application
    Filed: January 17, 2008
    Publication date: October 30, 2008
    Applicant: The Penn State Research Foundation
    Inventors: Chunshan Song, James J. Strohm, Jian Zheng, Weidong Gu, Chao Xie, Xiaoxing Wang