Carboxylic Acid Or Salt Thereof Other Than Formic, Acetic, Or Oxalic Acid Patents (Class 502/512)
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Patent number: 7393807Abstract: A hydrotreating catalyst comprising a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur, wherein the average coordination number [N(Mo)] of the molybdenum atoms around the molybdenum atom is from 1.5 to 2.5 and the average coordination number [N(S)] of the sulfur atoms around the molybdenum atom is from 3.5 to 5.0 when MoS2 structure in the catalyst is measured in accordance with extended X-ray absorption fine structure (EXAFS) analysis.Type: GrantFiled: May 18, 2005Date of Patent: July 1, 2008Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Yuji Yoshimura, Makoto Toba, Nobuyuki Matsubayashi, Takashi Matsui
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Patent number: 7214641Abstract: The present invention provides a process for hydrogenating carbonyl compounds, in particular C4-dicarboxylic acids to mixtures of tetrahydrofuran and gamma-butyrolactone, over supported rhenium catalysts, wherein rhenium and at least one further metal of groups VIII or Ib of the Periodic Table of the Elements, in particular ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), platinum (Pt), copper (Cu), silver (Ag) or cobalt (Co), is applied to the support in the form of at least one bimetallic precursor compound, and also to these catalysts.Type: GrantFiled: November 6, 2003Date of Patent: May 8, 2007Assignee: BASF AktiengesellschaftInventors: Markus Schubert, Michael Hesse, Rolf-Hartmuth Fischer, Take Constantinescu
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Patent number: 6852670Abstract: The present invention is a manufacturing method for an anion-layered double hydroxide intercalation compound that uses metal hydroxides as the stating material of the layered double hydroxides (LDH) which are the host material and allows sterically complicated and large-size anion compounds to be used as the guest material, and it has the characteristics such that a reaction mixture of the metal hydroxides and anion compound is heated and hydrothermally reacted in the absence of anion components other than the anion compound of the guest material. In addition, the present invention pertains to an anion-layered double hydroxide intercalation compound that uses bile acid as the anion compound of the guest material, which is effective as the carrier of medical drugs or as the absorbent of physiological active materials.Type: GrantFiled: November 4, 1999Date of Patent: February 8, 2005Assignee: Japan Science and Technology AgencyInventors: Makoto Ogawa, Shiho Asai
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Patent number: 6818254Abstract: A method and apparatus for treating the atmosphere comprising moving a vehicle through the atmosphere, the vehicle having at least one atmosphere contacting surface and a pollutant treating composition located on said surface. A specific embodiment comprises coating a motor vehicle radiator with pollutant treating catalyst.Type: GrantFiled: July 16, 1996Date of Patent: November 16, 2004Assignee: Engelhard CorporationInventors: Jeffrey B. Hoke, Fred M. Allen, Patrick W. Blosser, Zhicheng Hu, Ronald M. Heck
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Publication number: 20030027704Abstract: A ceramics dispersion liquid is provided. The dispersion liquid may form an applied film easily recovering hydrophilic properties with light irradiation even when contaminated by lipophilic materials. The ceramics dispersion liquid comprises a ceramics, a dispersion medium, and at least one compound selected from a carboxylic acid, an ammonium carboxylate, a salt of carboxylic acid with metal selected from Ia group, IIa group, IIIa group, Va group, VIa group, VIIa group, VIII group, Ib group, IIb group, IIIb group, IVb group and lanthanoid group, and a salt of oxalic acid with metal selected from IVa group.Type: ApplicationFiled: July 15, 2002Publication date: February 6, 2003Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshiaki Sakatani, Hironobu Koike, Hiroyuki Ando
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Patent number: 6133194Abstract: The production of cerium oxides, zirconium oxides, (Ce,Zr)O.sub.2 mixed oxides and (Ce,Zr)O.sub.2 solid solutions having improved particle size distribution, surface area, oxygen storage capacity and pore volume by the addition of an additive, such as anionic surfactants, nonionic surfactants, polyethylene glycols, carboxylic acids, and carboxylate salts, during the formation of the oxides or precursors thereof.Type: GrantFiled: April 21, 1997Date of Patent: October 17, 2000Assignee: Rhodia Rare Earths Inc.Inventors: Jean-Pierre Cuif, Julie Lynn Shreeve Keyer, Steven Eric Deutsch
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Patent number: 6001769Abstract: Compositions and methods for decreasing chemical contamination in subsurface water bearing geological formations, comprising an oxidized form of lignitic coal, or its derivatives, preferably leonardite, and at least one surface active agent. The compositions can be applied to an affected water bearing formation by conventional groundwater management methods, e.g., injection wells and groundwater extraction systems.Type: GrantFiled: September 25, 1997Date of Patent: December 14, 1999Assignee: Correctivaction, LLCInventors: John Michael Citterbart, Sam Kumar
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Patent number: 5906960Abstract: An adsorbent that can be used to remove environmental contaminants such as organics, cations and anions in a single process step is prepared from humic acid. The adsorbent can be a soluble humic acid in liquid form (e.g., in aqueous solution) or the humic acid can be insolubilized and/or immobilized on a solid support. The adsorbent can also be used to recover agriculturally desirable metals in chelated form from contaminated water. The liquid form of the adsorbent can be used to wash solids to remove contaminants.Type: GrantFiled: August 15, 1996Date of Patent: May 25, 1999Assignee: Arctech, Inc.Inventors: Hyderabad G. Sanjay, Kailash C. Srivastava, Daman S. Walia
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Patent number: 5861354Abstract: A catalyst and process for preparation of dihydroxy esters from specified hydroxy aldehydes is disclosed. In one embodiment, a catalyst liquid is provided which comprises from 10 percent to 60 percent magnesium salt of a specified alkanoic acid or acids, and from 90 percent to 40 percent of a particular alkanoic acid or acids, the molar ratio of alkanoic acid to magnesium salt being from about 1.5 to 20.3. The catalyst solution or liquid contacts or is contacted with a specified hydroxy aldehyde under suitable reaction conditions to form the desired dihydroxy ester. In another embodiment, dihydroxy esters are derived from specified hydroxy aldehydes by first forming a magnesium catalyst containing liquid by reacting magnesium or magnesium oxide, under suitable conditions, with a suitable alkanoic acid or acids, the acid or acids being provided in excess in specified molar ratios.Type: GrantFiled: May 3, 1996Date of Patent: January 19, 1999Inventors: Clyde Neal Clubb, Thomas James Devon, Garrett Clements Luce
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Patent number: 5539135Abstract: Hydrophobicized double-layer hydroxide compounds may be produced if double-layer hydroxide compounds of the general formula (I): [M.sup.(II).sub.1-x M.sup.(III).sub.x (OH).sub.2 ] A.sub.x.n H.sub.2 O, in which M.sup.(II) is a divalent metal cation, M.sup.(III) is a trivalent metal cation, A is an equivalent of a monobasic and/or multibasic inorganic acid, x is a number from 0.2 to 0.5 and n is a number from 0 to 10, are reacted at elevated temperature and under autogenous pressure with at least one carboxylic acid or its salt and the reaction product is then dried. The hydrophobicized double-layer hydroxide compounds obtained by this process are suitable as catalysts for the alkoxylation of compounds with active hydrogen atoms or of fatty acid esters.Type: GrantFiled: October 4, 1993Date of Patent: July 23, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Breuer, Claudia Mai, Hans-Christian Raths, Elvira Scholz
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Patent number: 5179060Abstract: A method of making a three-way catalyst based on platinum group metals, comprisng: (a) impregnating an alumina substrate with a platinum group metal ion by contacting such substrate with an aqueous solution containing the platinum group metal in an amount of 0.1-5% by weight of alumina substrate and a water soluble acid that forms RCOOH with R being an alkyl or equivalent, said acid being present in an amount of 10-120% by weight of the alumina substrate, the pH of said solution being less than 4.0; and (b) drying and calcining the wetted substrate without sintering said substrate.The three-way catalyst construction based on platinum group metals has enhanced catalytic activity. It comprises an alumina substrate and a platinum group metal impregnation layer thereover, said impregnation layer being comprised of raft-like particle structures, each having increased metal density resulting from the nesting of both small and large metal particles within a given volume.Type: GrantFiled: November 28, 1990Date of Patent: January 12, 1993Assignee: Ford Motor CompanyInventors: Somasundaram Subramanian, William L. H. Watkins, Mohinder S. Chattha
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Patent number: 4783434Abstract: Active catalysts are prepared by (1) impregnating a carrier with a solution of a complex of an active composition or precursor thereof wherein the viscosity of the solution is not decreased upon heating or evaporation of the solvent, (2) removing the solvent and (3) decomposing the complex.Type: GrantFiled: October 31, 1986Date of Patent: November 8, 1988Assignee: The Dow Chemical CompanyInventors: Johannes M. Wigman, John W. Geus, Jacobus E. Bongaarts, Garmt R. Meima
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Patent number: 4761393Abstract: A method for placing catalytically active alkali metal ion on a catalyst support to make an in situ catalyst is disclosed. Specifically, the method contemplates providing a quantity of a suitable catalyst support in a particulate form, providing a gaseous feed stream containing a predetermined amount of the alkali metal ion in the form of a volatile alkali metal compound, and contacting the catalyst support with the volatile alkali metal ion-containing feed stream for a time period sufficient to deposit at least some of the alkali metal present in the feed stream onto the thus-contacted catalyst support.Type: GrantFiled: July 27, 1987Date of Patent: August 2, 1988Assignee: Amoco CorporationInventors: Marc O. Baleiko, Edward F. Rader
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Patent number: 4663303Abstract: A silver salt solution suitable for depositing silver on a support in the preparation of silver catalysts is made by reacting a silver compound with a neo-acid, in a hydrocarbon solvent. The reaction is completed under reflux conditions, thereby removing water formed by the reaction and reacting at least 90% of the unreacted acid. Therefore, the solution may be used without further processing to impregnate a porous support, thereby providing a catalyst useful for oxidation of ethylene oxide.Type: GrantFiled: February 24, 1986Date of Patent: May 5, 1987Assignee: The Halcon SD Group, Inc.Inventors: Mitchell Becker, Kindtoken H. Liu