And Rare Earth Metal (sc, Y Or Lanthanide)containing Patents (Class 502/65)
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Patent number: 11918974Abstract: Functionalized zeolites, including a zeolite substrate and a self-assembled monolayer of a phosphonic acid on a surface of the zeolite substrate, are disclosed, as are methods of making and using the functionalized zeolites. The disclosed methods and compositions have various applications, including in the use of molecular sieves to separate small-molecule gases from mixtures thereof. Gas adsorption selectivities and diffusion rates of the functionalized zeolites may be tuned or selected according to the disclosed methods.Type: GrantFiled: April 19, 2019Date of Patent: March 5, 2024Assignee: The Regents of the University of ColoradoInventors: John L. Falconer, James William Medlin, Lucas Delano Ellis, Hans H. Funke, Surya Parker
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Patent number: 11883805Abstract: A catalytic composition for treating a NOx-containing exhaust gas, wherein the composition comprises a copper-substituted small-pore zeolite comprising: i) Ce and/or La in a total amount of about 5 to about 400 g/ft3; and ii) Nd and/or Nb in a total amount of about 5 to about 400 g/ft3.Type: GrantFiled: May 12, 2022Date of Patent: January 30, 2024Assignee: Johnson Matthey Public Limited CompanyInventors: Daniel Avis, Yannick Bidal, Alexander Nicholas Michael Green, Neil Greenham, Matthew Eben Harris
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Patent number: 11850573Abstract: This exhaust gas cleaning catalytic device includes a base material and a first catalyst coat layer on the base material. The first catalyst coat layer has a pre-stage section on an exhaust gas flow upstream side, and a post-stage section on an exhaust gas flow downstream side. The first catalyst coat layer pre-stage section and post-stage section each contain inorganic oxide particles and rhodium supported by the inorganic oxide particles, while at least some of the inorganic oxide particles contain ceria. The ceria amount per unit length of the first catalyst coat layer post-stage section is larger than the ceria amount per unit length of the first catalyst coat layer pre-stage section. The first catalyst coat layer pre-stage section is disposed in such a manner that the end portion on the exhaust gas flow upstream side thereof is in direct contact with the exhaust gas flow.Type: GrantFiled: March 23, 2020Date of Patent: December 26, 2023Assignee: CATALER CORPORATIONInventors: Tomohiro Chiba, Kyosuke Murakami, Kenichi Taki, Shunsuke Haga
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Patent number: 11731114Abstract: A fluid catalytic cracking catalyst for hydrocarbon oil that is a blend of two types of fluid catalytic cracking catalysts each of which has a different hydrogen transfer reaction activity or has a pore distribution within a specific range after being pseudo-equilibrated. One catalyst is a catalyst containing a zeolite and matrix components, and the other catalyst is a catalyst containing a zeolite and matrix components. This catalyst is composed of the one catalyst and the other catalyst blended at a mass ratio within a range of 10:90 to 90:10.Type: GrantFiled: July 22, 2019Date of Patent: August 22, 2023Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Takaki Mizuno, Chisuzu Tanaka, Tomohiro Mitsui
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Patent number: 11642655Abstract: A catalytic article for treating exhaust gas comprising: a first catalytic region beginning at the inlet end and extending for less than the axial length L, wherein the first catalytic region comprises a first palladium component and a first oxygen storage capacity (OSC) material comprising ceria; a second catalytic region beginning at the outlet end and extending for less than the axial length L, wherein the second catalytic region comprises a second palladium component and a second OSC material comprising ceria; a third catalytic region beginning at the outlet end and extending for less than the axial length L, wherein the third catalytic region comprises a third rhodium component and a third OSC material comprising ceria; wherein at least a portion of the first catalytic region is not covered by the second catalytic region and/or the third catalytic region; and wherein (a) the ceria amount in the first catalytic region is less than 50% of the total ceria amount in the first, second, and third catalytic regType: GrantFiled: January 5, 2021Date of Patent: May 9, 2023Assignee: Johnson Matthey Public Limited CompanyInventors: Takeshi Kadono, Kenji Tanikawa
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Patent number: 11583834Abstract: An automotive catalytic converter includes a three-way catalyst having Rh as the only precious metal configured as a front zone and a three-way catalyst having a mixture of Rh and Pd, Pt, or both configured as a rear zone, such that an exhaust gas from an internal combustion engine passes through the front zone before passing through the rear zone to minimize sulfur poisoning of the catalytic converter.Type: GrantFiled: September 18, 2017Date of Patent: February 21, 2023Assignee: Ford Global Technologies, LLCInventors: Yisun Cheng, Giovanni Cavataio, Jeffrey Scott Hepburn, Mira Bumbaroska, Carolyn Parks Hubbard
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Patent number: 11471862Abstract: A microspherical fluid catalytic cracking (FCC) catalyst includes Y zeolite and a gamma-alumina.Type: GrantFiled: May 16, 2018Date of Patent: October 18, 2022Assignee: BASF CORPORATIONInventors: Junmei Wei, Lucas Dorazio, Karl C. Kharas, David J. Camerota, David M. Stockwell
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Patent number: 11439992Abstract: The present disclosure relates to processes for formation of a molecular sieve, particularly a metal-promoted molecular sieve, and more particularly an Iron(III) exchanged zeolite. Preferably, the zeolite is of the chabazite form or similar structure. The processes can include combining a zeolite with Iron(III) cations in an aqueous medium. The process can be carried out at a pH of less than about 7, and a buffering material can be used with the aqueous medium. The processes beneficially result in Iron exchange that can approach 100% along with removal of cations (such as sodium, NH4, and H) from the zeolite. An Iron(III)-exchanged zeolite prepared according to the disclosed processes can include about 2,000 ppm or less of cation and about 1% by weight or greater of Iron(III). The disclosure also provides catalysts (e.g., SCR catalysts) and exhaust treatment systems including the Iron(III)-exchanged zeolite.Type: GrantFiled: June 11, 2020Date of Patent: September 13, 2022Assignee: BASF CORPORATIONInventors: Qi Fu, Barbara Slawski, Peter Pfab
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Patent number: 11319424Abstract: A method of depolymerizing plastics using a halloysite catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.Type: GrantFiled: September 9, 2020Date of Patent: May 3, 2022Assignee: Basell Poliolefine Italia S.r.l.Inventors: Diego Brita, Sheri E. Davis, Volker Fraaije, Simona Guidotti, Dario Liguori, Sandor Nagy, David L. Ramage, Shahram Mihan, Christopher D. Smith, Daniel F. White, Xueyong Yang
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Patent number: 11142703Abstract: Methods for cracking a hydrocarbon oil include contacting the hydrocarbon oil with a catalyst system in a fluidized catalytic cracking unit to produce light olefins and gasoline fuel. The catalyst system includes a FCC base catalyst and a catalyst additive. The FCC base catalyst includes a Y-zeolite. The catalyst additive includes a framework-substituted *BEA-type zeolite. The framework-substituted *BEA-type zeolite has a modified *BEA framework. The modified *BEA framework is a *BEA aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms selected from titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. The FCC base catalyst may include a framework-substituted ultra-stable Y (USY)-zeolite as the Y-zeolite.Type: GrantFiled: August 5, 2020Date of Patent: October 12, 2021Assignees: Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center PetroleumInventors: Omer Refa Koseoglu, Robert Peter Hodgkins, Mitsunori Watabe, Koji Uchida
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Patent number: 10981152Abstract: The present invention pertains to the use of mesoporous ZSM-22 zeolite in a process for the cracking or conversion of a feed comprised of hydrocarbons, such as, for example, that obtained from the processing of crude petroleum, to a mixture high in propylene. Further, the present invention concerns the field of fluid catalytic cracking (FCC) processes and relates to the preparation and employment of additives based on zeolites having increased mesoporosity, such as altered ZSM-22. More particularly the present invention discloses a process for improving the production of propylene in FCC units.Type: GrantFiled: June 24, 2017Date of Patent: April 20, 2021Assignee: ALBEMARLE CORPORATIONInventors: Avelino Corma Canos, Joaquin Martinez-Triguero
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Patent number: 10888848Abstract: A catalytic cracking catalyst has a rare earth modified Y-type molecular sieve, an additive-containing alumina binder, and a clay. The rare earth modified Y-type molecular sieve has a rare earth oxide content of about 4-12 wt %, a phosphorus content of about 0-10 wt %, a sodium oxide content of no more than about 1.0 wt %, a total pore volume of about 0.36-0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20-40%, a lattice constant of about 2.440-2.455 nm, a percentage of non-framework aluminum content to the total aluminum content of no more than about 10%, a lattice collapse temperature of not lower than about 1060° C., and a ratio of B acid to L acid in the total acid content of the modified Y-type molecular sieve of no less than about 3.50.Type: GrantFiled: February 12, 2018Date of Patent: January 12, 2021Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Lingping Zhou, Weilin Zhang, Mingde Xu, Zhenyu Chen, Huiping Tian, Yuxia Zhu
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Patent number: 10792642Abstract: The present invention relates to the field of isobutylene preparation. Disclosed are a catalyst and preparation method thereof, and method for preparing isobutylene by applying the same; the catalyst has a core-shell structure, the core an amorphous silica-alumina particle and/or an aggregate molding thereof, and the shell aluminum oxide comprising silicon and tin; the weight ratio of aluminum oxide comprising silicon and tin to amorphous silica-alumina is 1:60-1:3; in the aluminum oxide comprising silicon and tin, on basis of the weight of aluminum oxide comprising silicon and tin, the content of silicon is 0.5-2 wt %, and of tin is 0.2-1 wt %. The catalyst of the present invention is used to catalyze a mixture of MTBE and TBA to prepare isobutylene, enabling the MTBE cleavage and TBA dehydration reactions to be conducted simultaneously to generate isobutylene, achieving higher conversion rates of TBA and MTBE, and higher selectivity for generating isobutylene.Type: GrantFiled: November 25, 2015Date of Patent: October 6, 2020Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.Inventors: Shumei Zhang, Feng Zhou, Kai Qiao, Qingtong Zhai, Chunmei Wang
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Patent number: 10794221Abstract: A gas turbine engine includes a rotatable component and a non-rotatable component. A seal is carried on one of the rotatable component or the non-rotatable component to provide sealing there between. The seal includes a geopolymer seal element.Type: GrantFiled: April 25, 2017Date of Patent: October 6, 2020Assignee: UNITED TECHNOLOGIES CORPORATIONInventors: Kevin Seymour, Christopher W. Strock
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Patent number: 10619110Abstract: The invention relates to a composition useful as a hydrotreating or hydrocracking catalyst, where fresh catalyst useful in hydrotreating or hydrocracking is combined with spent catalyst, and optionally with additional active metal. The resulting compositions can be used in hydrotreating or hydrocracking but not FCC processes.Type: GrantFiled: April 11, 2018Date of Patent: April 14, 2020Assignee: SAUDI ARABIAN OIL COMPANYInventors: Omer Refa Koseoglu, Robert Peter Hodgkins
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Patent number: 10577525Abstract: Disclosed is a composite abrasive with hard core and soft shell, comprising hard abrasive core with grain diameter in a range of 0.1˜1 ?m and a soft oxide shell with thickness in a range of 5˜100 nm, the grain size of the oxide of the soft oxide shell is in a range of 5˜20 nm, the composite abrasive is obtained from aqueous solution of oxide inorganic salt precursor and the hard abrasive by dispersing, constant temperature reflux hydrolyzing, solid-liquid separating, washing and drying. The component abrasive with hard core and soft shell of the present invention can improve the manufacturing efficiency and the surface quality during the ultraprecise manufacturing of the sapphire substrate.Type: GrantFiled: November 3, 2016Date of Patent: March 3, 2020Assignee: HUAQIAO UNIVERSITYInventors: Jing Lu, Xipeng Xu, Dayu Zhang, Yongchao Xu, Qiufa Luo
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Patent number: 10413890Abstract: STA-19, a molecular sieve having a GME structure and phosphorus in the framework, is described. STA-19AP (as prepared) can have a lower alkyl amine, such as trimethylamine, and olig-(1,4-diazabicyclo[2.2.2]octane)-pentyl dibromide ([DABCO-C5]x where x represents the number of repeating units) or olig-(1,4-diazabicyclo[2.2.2] octane)-hexyl dibromide ([DABCO-C6]x) as SDAs. A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide (TBAOH), can be used as a pH modifier for the preparation of SAPO-STA-19. A calcined product, STA-19C, formed from STA-19AP is also described. Methods of preparing STA-19AP, STA-19C and metal containing calcined counterparts of STA-19C are described along with methods of using STA-19C and metal containing calcined counterparts of STA-19C in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.Type: GrantFiled: April 21, 2017Date of Patent: September 17, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: John Casci, Alessandro Turrina, Paul Wright
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Patent number: 10300467Abstract: A method to make a phosphorus modified zeolite can include providing a zeolite including at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with one or more binders and shaping additives, and then shaping the mixture. The method can include making a ion-exchange. The shaped mixture can be steamed. Phosphorous can be introduced on the catalyst to introduce at least 0.1 wt % of phosphorus, such as be dry impregnation or chemical vapor deposition. A metal, such as calcium, can be introduced. The catalyst can be washed, calcinated, and then steamed. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.Type: GrantFiled: July 25, 2012Date of Patent: May 28, 2019Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Nikolai Nesterenko, Delphine Minoux, Cindy Adam, Jean-Pierre Dath
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Patent number: 10130943Abstract: The present invention provides a catalyst composition for use in a catalytic cracking process, said catalyst composition comprises 3.5 to 15.5% of pentasil zeolite, 9 to 40% of ultra-stable Y (USY) or rare earth exchanged USY (REUSY) zeolite, 3.5 to 15% of large pore active matrix based bottom up gradation component and 0.3 to 3% of a metal trap component, the percentage being based on weight of the catalyst composition. The present invention also provides a process for preparing the said catalyst composition and a catalytic cracking process comprising contacting the said catalyst composition with a feedstock.Type: GrantFiled: July 23, 2013Date of Patent: November 20, 2018Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Arumugam Velayutham Karthikeyani, Mohan Prabhu Kuvettu, Biswanath Sarkar, Pankaj Kumar Kasliwal, Balaiah Swamy, Ganga Shankar Mishra, Kamlesh Gupta, Santanam Rajagopal, Ravinder Kumar Malhotra, Kumar Brijesh
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Patent number: 9931619Abstract: Provided are an ethanol dehydration catalyst having a high ethylene yield even at a low temperature region, as an ethanol dehydration catalyst for converting a feedstock including anhydrous ethanol or hydrous ethanol to ethylene, and a method of preparing ethylene by using the same. In the ethanol dehydration catalyst for converting a feedstock including anhydrous ethanol or hydrous ethanol to ethylene of the present invention, the catalyst includes 0.1 wt % to 0.5 wt % of lanthanum (La) or 0.05 wt % to 1 wt % of gallium (Ga) in ZSM-5.Type: GrantFiled: April 14, 2014Date of Patent: April 3, 2018Assignee: LOTTE CHEMICAL CORPORATIONInventors: Joungmo Cho, In Ae Kim, Jae Yeon Lee, Seung Hee Kang, Young Jong Seo
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Patent number: 9889439Abstract: The present invention relates to a heavy oil catalytic cracking catalyst having a high yield of light oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a magnesium-modified ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The magnesium-modified ultra-stable rare earth type Y molecular sieve is obtained by the following manner: the raw material, a NaY molecular sieve, is subjected to a rare earth exchange, a dispersing pre-exchange, a magnesium salt exchange modification, an ammonium salt exchange for sodium reduction, a second exchange and a second calcination. The catalyst provided in the present invention is characteristic in its high conversion capacity of heavy oil and a high yield of light oil.Type: GrantFiled: April 13, 2012Date of Patent: February 13, 2018Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Di Li, Xueli Li, Zhengguo Tan, Xiaoliang Huang, Jinjun Cai, Yunfeng Zheng, Chenxi Zhang, Gengzhen Cao
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Patent number: 9844772Abstract: The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination.Type: GrantFiled: April 13, 2012Date of Patent: December 19, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Patent number: 9840422Abstract: The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: December 12, 2017Assignee: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Chaowei Liu, Di Li, Xueli Li, Zhengguo Tan, Yunfeng Zheng, Xiaoliang Huang, Jinjun Cai, Chenxi Zhang
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Patent number: 9815047Abstract: The catalyst for producing aromatic hydrocarbon is for producing monocyclic aromatic hydrocarbon having 6 to 8 carbon number from oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower and contains crystalline aluminosilicate and phosphorus. A molar ratio (P/Al ratio) between phosphorus contained in the crystalline aluminosilicate and aluminum of the crystalline aluminosilicate is from 0.1 to 1.0. The production method of monocyclic aromatic hydrocarbon is a method of bringing oil feedstock having a 10 volume % distillation temperature of 140° C. or higher and a 90 volume % distillation temperature of 380° C. or lower into contact with the catalyst for producing monocyclic aromatic hydrocarbon.Type: GrantFiled: December 28, 2011Date of Patent: November 14, 2017Assignee: JX Nippon Oil & Energy CorporationInventors: Shinichiro Yanagawa, Masahide Kobayashi, Yasuyuki Iwasa, Ryoji Ida
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Patent number: 9789475Abstract: The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 ?m and a D(v,0.9) of not more than 20 ?m.Type: GrantFiled: April 13, 2012Date of Patent: October 17, 2017Assignee: Petrochina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Patent number: 9753177Abstract: Methods, systems, devices, and products for estimating a parameter of interest of a volume of an earth formation. Methods may include correcting a measurement relating to the parameter of interest by a downhole tool using at least one correction model determined from a plurality of predefined models. The at least one correction model may be determined based on an estimated borehole standoff of the tool from the borehole wall that is associated with the measurement. Correcting the measurement may include determining a correction factor using the correction model and applying the correction factor to the measurement. Each of the plurality of predefined models may be associated with each of a plurality of standoff bins, wherein each of the plurality of standoff bins is defined as a mutually exclusive interval of distance values from the downhole tool to the borehole wall.Type: GrantFiled: November 12, 2013Date of Patent: September 5, 2017Assignee: BAKER HUGHES INCORPORATEDInventors: Feyzi Inanc, Joseph C. Koudelka
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Patent number: 9662611Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.Type: GrantFiled: March 30, 2010Date of Patent: May 30, 2017Assignee: BASF CorporationInventors: Chung-Zong Wan, Xiaolai Zheng, Suzanne Stiebels, Claudia Wendt, Torsten Neubauer, R. Samuel Boorse
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Patent number: 9518229Abstract: Disclosed are catalyst compositions including zeolite and silica components, methods of making, and processes of using in the thermo-catalytic conversion of biomass. Such disclosed methods of making include: i) spray drying of the catalyst precursor slurry at a pH below 1, or ii) the removal of ions such as sodium from the binder material prior to spray drying the catalyst precursor slurry at a pH below 2.7, or iii) spray drying the catalyst precursor including a pore regulating agent followed by steam treating, or iv) some combination of i), ii) and iii).Type: GrantFiled: March 15, 2013Date of Patent: December 13, 2016Assignee: Inaeris Technologies, LLCInventors: Jerry Jon Springs, Bruce ADkins, Stephen Schuyten, Gopal Juttu, Christine M. Henry, Kelsey Shogren
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Patent number: 9492818Abstract: Novel silicoaluminophosphate molecular sieve compositions comprising SAPO-11 and SAPO-41 with at least about 5 wt % of in situ-produced amorphous portion. Such compositions can be uncalcined or calcined and novel processes for their preparation are described. These compositions, when loaded or impregnated with a catalytically active species such as a Group VIII noble metal are novel, and are excellent hydroisomerization catalysts.Type: GrantFiled: June 10, 2010Date of Patent: November 15, 2016Assignee: ALBEMARLE EUROPE SPRLInventors: Martijn J. M. Mies, Mark H. Harte, Edgar Evert Steenwinkel, Emanuel Hermanus van Broekhoven
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Patent number: 9468912Abstract: Variations of ZPGM bulk powder catalyst materials, including Cu—Co—Mn ternary spinel systems for TWC applications are disclosed. Bulk powder catalyst samples are prepared employing a plurality of molar ratio variations, including disclosed Cu—Co—Mn spinel on Praseodymium-Zirconia support oxide made by incipient wetness method, or Cu—Co—Mn spinel on Niobium-Zirconia support oxide, which may be synthesized by co-precipitation method. A plurality of bulk powder catalyst samples may be tested by performing isothermal steady state sweep test, employing a flow reactor at inlet temperature of about 450° C., and testing a gas stream from lean to rich condition and influence on TWC performance measured/analyzed, which may lead into significant improvements in the manufacturing of ZPGM bulk powder catalyst materials for TWC applications.Type: GrantFiled: November 17, 2014Date of Patent: October 18, 2016Assignee: Clean Diesel Technologies, Inc.Inventors: Zahra Nazarpoor, Oguzhan Selim Yaglidere, Stephen J. Golden
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Patent number: 9464163Abstract: Disclosed is a novolak resin containing a repeating unit represented by the general formula (1). R1is a hydrogen atom or an alkyl group which is C1-4 straight-chain or C3-4 branched-chain, and some or all hydrogen atoms in the alkyl group may be replaced with a fluorine atom; R2 is a hydrogen atom, a phenyl group, an alkyl group which is C1-10 straight-chain or C3-10 branched-chain, or an alkyl group having a C3-10 cyclic structure, and some or all hydrogen atoms in the phenyl group and the alkyl group may be replaced with fluorine atoms; each of a and b is independently an integer of 1-3, and these are defined as 2?a+b?4; and d is an integer of 0-2. This novolak resin has high dissolution rate in the alkaline development solution in addition to the heat resisting property which is a property of phenolic resin.Type: GrantFiled: December 25, 2013Date of Patent: October 11, 2016Assignee: Central Glass Company, LimitedInventors: Junya Nakatsuji, Kazuhiro Yamanaka
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Patent number: 9278340Abstract: Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.Type: GrantFiled: August 20, 2009Date of Patent: March 8, 2016Assignee: KRITI ENTERPRISES INC.Inventors: Inder Pal Singh, Shradha Singh, Ritesh Patel, Bharat Mistry, Manish Mehta, Peter Omolo Otieno
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Patent number: 9168517Abstract: Catalyst composition for selective reduction of nitrogen oxides and soot oxidation comprising a physical mixture of one or more acidic zeolite or zeotype components with one ore more redox active metal compounds and a method for selective reduction of nitrogen oxides and soot oxidation by use of the catalyst composition.Type: GrantFiled: May 2, 2012Date of Patent: October 27, 2015Assignee: Haldor Topsoe A/SInventors: Alexandr Yu Stakheev, Marie Grill, Arkady Kustov
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Patent number: 9108181Abstract: A cracking catalyst contains a substantially inert core and an active shell, the active shell containing a zeolite catalyst and a matrix. Methods of making and using the cracking catalyst are also described.Type: GrantFiled: June 12, 2008Date of Patent: August 18, 2015Assignee: BASF CorporationInventors: David Matheson Stockwell, John M. Macaoay
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Publication number: 20150126357Abstract: The present invention is related to a nano-structured composite material and process of making for air detoxing and deodoring in enclosed spaces to prevent harmful chemicals in the air from damaging human health. The nano-structured composite material consists of nano-porous carbon, zeolites with sub nano-size pores and at least 1 other component chosen from nano-porous rare earth oxides and nano-sized catalysts, and is made into highly efficient configurations with high geometric surface and low resistance air flow channels. The synergetic action of those nano-structured components can effectively remove toxic chemicals including, but not limited to formaldehyde, benzene, toluene, xylene, propene, butadiene, acetone, carbon monoxide, nitric oxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, ammonia, alcohols, chlorine, mercaptans, as well as bad odors, such cigarette smoke and bathroom/toilet smells.Type: ApplicationFiled: October 27, 2014Publication date: May 7, 2015Inventors: Xiwang Qi, Mei Jiang
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Publication number: 20150118119Abstract: A three-way catalyst is disclosed. The three-way catalyst comprises a silver-containing extruded zeolite substrate and a catalyst layer disposed on the silver-containing extruded zeolite substrate. The catalyst layer comprises a supported platinum group metal catalyst comprising one or more platinum group metals and one or more inorganic oxide carriers. The invention also includes an exhaust system comprising the three-way catalyst. The three-way catalyst results in improved hydrocarbon storage and conversion, in particular during the cold start period.Type: ApplicationFiled: October 30, 2014Publication date: April 30, 2015Inventors: Hsiao-Lan CHANG, Hai-Ying CHEN, Kwangmo KOO, Jeffery Scott RIECK
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Patent number: 9011809Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: February 24, 2012Date of Patent: April 21, 2015Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Takashi Hihara, Makoto Nagata
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Patent number: 8987161Abstract: A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al+3, wherein the catalyst decreases NOx emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu—Fe-ZSM5, Cu—La-ZSM-5, Fe—Cu—La-ZSM5, Cu—Sc-ZSM-5, and Cu—In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.Type: GrantFiled: August 13, 2010Date of Patent: March 24, 2015Assignee: UT-Battelle, LLCInventors: Chaitanya K. Narula, Xiaofan Yang
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Publication number: 20150080209Abstract: The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination.Type: ApplicationFiled: April 13, 2012Publication date: March 19, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Zhengguo Tan, Di Li, Dong Ji, Hongchang Duan, Chenxi Zhang
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Publication number: 20150011378Abstract: The present invention relates to a heavy oil catalytic cracking catalyst having a high yield of light oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a magnesium-modified ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The magnesium-modified ultra-stable rare earth type Y molecular sieve is obtained by the following manner: the raw material, a NaY molecular sieve, is subjected to a rare earth exchange, a dispersing pre-exchange, a magnesium salt exchange modification, an ammonium salt exchange for sodium reduction, a second exchange and a second calcination. The catalyst provided in the present invention is characteristic in its high conversion capacity of heavy oil and a high yield of light oil.Type: ApplicationFiled: April 13, 2012Publication date: January 8, 2015Applicant: PetroChina Company LimitedInventors: Xionghou Gao, Haitao Zhang, Hongchang Duan, Di Li, Xueli Li, Zhengguo Tan, Xiaoliang Huang, Jinjun Cai, Yunfeng Zheng, Chenxi Zhang, Gengzhen Cao
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Patent number: 8926925Abstract: A catalyst for the selective catalytic reduction of nitrogen oxides in diesel engine exhaust gases using ammonia or a precursor compound decomposable to ammonia. The catalyst includes two superposed coatings applied to a support body, of which the first coating applied directly to the support body includes a transition metal-exchanged zeolite and/or a transition metal-exchanged zeolite-like compound, and effectively catalyzes the SCR reaction. The second coating is applied to the first coating to cover it on the exhaust gas side and prevent hydrocarbons having at least three carbon atoms present in the exhaust gas from contacting the first coating, without blocking the passage of nitrogen oxides and ammonia to the first coating. The second coating may be formed from small-pore zeolites and/or small-pore, zeolite-like compounds, and from suitable oxides, especially silicon dioxide, germanium dioxide, aluminum oxide, titanium dioxide, tin oxide, cerium oxide, zirconium dioxide and mixtures thereof.Type: GrantFiled: March 1, 2012Date of Patent: January 6, 2015Assignee: Umicore AG & Co. KGInventors: Nicola Soeger, Katja Adelmann, Michael Seyler, Thomas R. Pauly, Gerald Jeske
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Patent number: 8911697Abstract: The invention relates to a catalytically active material for reacting nitrogen oxides with ammonia in the presence of hydrocarbons. The material consists of an inner core (1) made of a zeolite exchanged with one or more transition metals or a zeolite-like compound exchanged with one or more transition metals. The core of the catalytically active material is encased by a shell (2), which is made of one or more oxides selected from silicon dioxide, germanium dioxide, aluminum oxide, titanium oxide, tin oxide, cerium oxide, zirconium dioxide, and mixed oxides thereof.Type: GrantFiled: March 1, 2012Date of Patent: December 16, 2014Assignee: Umicore AG & Co. KGInventors: Nicola Soeger, Katja Adelmann, Michael Seyler, Thomas R. Pauly, Gerald Jeske
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Patent number: 8901026Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radius of less than 0.95 ? at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.Type: GrantFiled: January 28, 2008Date of Patent: December 2, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Richard Franklin Wormsbecher, Ruizhong Hu
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Publication number: 20140336038Abstract: Compositions and methods for the preparation of ZPGM catalytic converters are disclosed. Addition of Mn to ZPGM catalytic converters from prior ZPGM catalytic may create a new ZPGM catalytic converter with greater improvement TWC conditions compared to previous types. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems. Disclosed ZPGM TWC systems in catalytic converters may be employed to decrease the pollution caused by exhaust from various sources, such as automobiles, utility plants, processing and manufacturing plants, airplanes, trains, all-terrain vehicles, boats, mining equipment, and other engine-equipped machines.Type: ApplicationFiled: May 10, 2013Publication date: November 13, 2014Applicant: CDTiInventors: Zahra Nazarpoor, Stephen J. Golden
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Patent number: 8883667Abstract: A purification catalyst which prevents contamination within a reflow furnace, including flux components, while suppressing the generation of CO is provided. A purification catalyst for a reflow furnace gas, having one or two of zeolite and silica-alumina as an active ingredient.Type: GrantFiled: October 10, 2007Date of Patent: November 11, 2014Assignee: Nikki-Universal Co., Ltd.Inventors: Yoshiki Nakano, Takanobu Sakurai, Shinichi Ueno
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Patent number: 8865120Abstract: The present invention is directed to a process for the production of ion-exchanged (metal-doped, metal-exchanged) Zeolites and Zeotypes, In particular, the method applied uses a sublimation step to incorporate the ion within the channels of the Zeolitic material. Hence, according to this dry procedure no solvent is involved which obviates certain drawbacks connected with wet exchange processes known in the art.Type: GrantFiled: December 8, 2011Date of Patent: October 21, 2014Assignee: Umicore AG & Co., KGInventors: Fei Wen, Barry W. L. Southward, Liesbet Jongen, Alexander Hofmann, Daniel Herein
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Patent number: 8853122Abstract: A process for the selective production of ethanol by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethanol is disclosed and claimed. In an embodiment of this invention reaction of acetic acid and hydrogen over either cobalt and palladium supported on graphite or cobalt and platinum supported on silica selectively produces ethanol in a vapor phase at a temperature of about 250° C.Type: GrantFiled: March 6, 2013Date of Patent: October 7, 2014Assignee: Celanese International CorporationInventors: Victor J. Johnston, Barbara F. Kimmich, Jan Cornelis van der Waal, James H. Zink, Virginie Zuzaniuk, Josefina T. Chapman, Laiyuan Chen
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Publication number: 20140294706Abstract: Catalyst composition for selective reduction of nitrogen oxides and soot oxidation comprising a physical mixture of one or more acidic zeolite or zeo-type components with one ore more redox active metal compounds and a method for selective reduction of nitrogen oxides and soot oxidation by use of the catalyst composition.Type: ApplicationFiled: May 2, 2012Publication date: October 2, 2014Applicant: Haldor Topsøe A/SInventors: Alexandr Yu Stakheev, Marie Grill, Arkady Kustov
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Patent number: 8845882Abstract: Catalytic cracking catalyst compositions and processes for cracking hydrocarbons to maximize light olefins production are disclosed. Catalyst compositions comprise at least one zeolite having catalytic cracking activity under catalytic cracking conditions, preferably Y-type zeolite, which zeolite has low amounts of yttrium in specified ratios to rare earth metals exchanged on the zeolite. Catalyst and processes of the invention provide increased yields of light olefins and gasoline olefins during a FCC process as compared to conventional lanthanum containing Y-type zeolite FCC catalysts.Type: GrantFiled: March 8, 2011Date of Patent: September 30, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Yuying Shu, Richard F. Wormsbecher, Wu-Cheng Cheng
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Patent number: 8845974Abstract: Catalyzed soot filters comprising a wall flow monolith having porous walls, a first washcoat permeating the porous walls and a second washcoat on the porous walls are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.Type: GrantFiled: November 24, 2010Date of Patent: September 30, 2014Assignee: BASF CorporationInventors: Yuejin Li, Stanley A. Roth, Alfred H. Punke, Gary A. Gramiccioni