Faujasite Type (e.g., X Or Y, Etc.) Patents (Class 502/79)
  • Publication number: 20110236271
    Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.
    Type: Application
    Filed: March 17, 2011
    Publication date: September 29, 2011
    Applicant: NGK Insulators, Ltd.
    Inventors: Yoshio KIKUCHI, Haruo OTSUKA
  • Publication number: 20110232486
    Abstract: An adsorbent media composition has a finished media lithium-exchanged zeolite X (LiX) with a finished Li content in a range from 96% to 83%, based on the total cation equivalents in the LiX. The adsorbent media composition is obtained from a slurry comprising water, a LiX precursor having a pre-media production Li content that is greater than the finished media LiX Li content, and another media component material, such as fibers. The water used to produced the media has a specific conductance in a range from 2.2 ?Siemens/cm to 150 ?Siemens/cm. The finished media LiX has a monovalent cation (Na, K, Rb, Cs and combinations thereof) in a range from 0.05% to 3%, based on the total equivalents of exchangeable cations in the finished media LiX.
    Type: Application
    Filed: September 1, 2009
    Publication date: September 29, 2011
    Applicant: UOP LLC
    Inventors: Robert L. Bedard, Evgeny T. Kolev
  • Publication number: 20110224067
    Abstract: This invention comprises USY zeolite prepared by treating a USY zeolite under hydrothermal conditions after forming the USY zeolite from heat treating ammonium exchanged zeolite Y, e g, by calcination. When this invention is used in a FCC catalyst, a significant improvement of activity and selectivity in the fluid catalytic cracking (FCC) performance is observed, compared to FCC catalysts containing conventional USY zeolite. The process used to make the invention is efficient and comprises treating the USY zeolite in an exchange bath under the aforementioned hydrothermal conditions. The surface of the resulting USY zeolite has a molar ratio of alumina to silica that is higher than that seen in the bulk USY zeolite and has a unique structure as viewed by SEM and TEM.
    Type: Application
    Filed: December 17, 2009
    Publication date: September 15, 2011
    Inventors: Richard Franklin Wormsbecher, Wu-Cheng Cheng, Michael Wallace, Wilson Suarez, Yuying Shu
  • Publication number: 20110224068
    Abstract: This invention relates to the composition, method of making and use of a fluidized catalytic cracking (“FCC”) catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 ? (angstrom) range as determined by nitrogen adsorption measurements. FCC catalysts made from this new zeolite exhibit improved rates of heavy oil cracking heavy oil bottoms conversions and gasoline conversions. The fluidized catalytic cracking catalysts herein are particularly useful in fluidized catalytic cracking (“FCC”) processes for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms.
    Type: Application
    Filed: February 17, 2011
    Publication date: September 15, 2011
    Applicant: W.R. Grace & Co.-Conn.
    Inventors: Edward T. Habib, JR., Ruizhong Hu, Terry G. Roberie, Jianxin Jason Wu, William A. Wachter, Colin L. Beswick
  • Patent number: 8008223
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: August 30, 2011
    Assignee: Massachusetts Institute of Technology
    Inventor: Javier Garcia-Martinez
  • Publication number: 20110184165
    Abstract: The invention relates to aggregate zeolitic adsorbents based on faujasite X type zeolite powder having a low silica content and small crystals, exchanged with barium or based on faujasite X type zeolite having a low silica content and small crystals, exchanged with barium and potassium. The invention also relates to the method for preparing said aggregate zeolitic adsorbents, and also their uses for separating sugars, polyhydric alcohols, isomers of substituted toluene, cresols, or for recovering very high purity paraxylene.
    Type: Application
    Filed: December 16, 2008
    Publication date: July 28, 2011
    Applicants: Ceca S.A., Institut Francais Du Petrole
    Inventors: Ludivine Bouvier, Stéphane Kieger, Catherine Laroche, Philibert Leflaive, Tom Frising
  • Patent number: 7976697
    Abstract: A NOx reduction composition and process of using the composition to reduce the content of NOx emissions and gas phase reduced nitrogen species released from the regeneration zone during fluid catalytic cracking of a hydrocarbon feedstock into lower molecular weight components is disclosed. The process comprises contacting a hydrocarbon feedstock during a fluid catalytic cracking (FCC) process wherein a regeneration zone of an fluid catalytic cracking unit (FCCU) is operated in a partial or incomplete combustion mode under FCC conditions, with a circulating inventory of an FCC cracking catalyst and a particulate NOx reduction composition. The NOx reduction composition has a mean particle size of greater than 45 ?m and comprises (1) a zeolite component having (i) a pore size of form 2-7 A Angstroms and (ii) a SiO2 to Al2O3 molar ratio of less than 500, and (2) at least one noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, rhenium and mixtures thereof.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: July 12, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: M. Sundaram Krishnamoorthy, Michael Scott Ziebarth, George Yaluris, Roger Jean Lussier, John Allen Rudesill
  • Publication number: 20110160042
    Abstract: The present invention provides a method for constructing a fractal network structure in hydrogen storage material to improve the hydrogen uptake at room temperature, the method including the following steps: providing a hydrogen storage material comprising a source and a receptor of hydrogen atoms, wherein the source is disposed above the receptor, and a chemical bridge is disposed between the source and the receptor, wherein the chemical bridge is composed of precursor material; and treating the hydrogen storage material to construct a fractal network structure of mesopores and micropores in the receptor, so as to enhance the hydrogen storage capacity of the hydrogen storage material at room temperature.
    Type: Application
    Filed: October 15, 2010
    Publication date: June 30, 2011
    Applicant: Institute of Nuclear Energy Research Atomic Energy Council, Executive Yuan
    Inventors: CHENG-SI TSAO, Ming-Sheng Yu, Yi-Ren Tzeng, Tsui-Yun Chung, Hsiu-Chu Wu, Haw-Yeu Chuang, Chien-Hung Chen, Kang-Ning Lee, Hua-Wen Chang, Huan-Hsiung Tseng
  • Publication number: 20110155641
    Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: June 30, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110139684
    Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.
    Type: Application
    Filed: February 23, 2011
    Publication date: June 16, 2011
    Applicant: BASF Catalysts LLC
    Inventors: Xingtao Gao, James Fu
  • Publication number: 20110139677
    Abstract: Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS2 or WS2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle-sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
    Type: Application
    Filed: June 8, 2009
    Publication date: June 16, 2011
    Applicant: ENI S.P.A.
    Inventors: Giuseppe Bellussi, Giacomo Rispoli, Angela Carati
  • Patent number: 7960307
    Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: June 14, 2011
    Assignee: BASF Corporation
    Inventors: Xingtao Gao, James Fu
  • Publication number: 20110136658
    Abstract: A catalyst used in the reaction of oxidative bromination of methane is provided. The catalyst is prepared by the following procedures: mixing at least one of the precursors selected from the compounds of Rh, Ru, Cu, Zn, Ag, Ce, V, W, Cd, Mo, Mn, Cr and La which can dissolve in water with the Si precursor, hydrolyzing, drying and sintering. In the catalysis system, methane reacts with HBr, H2O and oxygen source (O2, air or oxygen-rich air), finally CH3Br and CH2Br2 are produced. Another catalyst used in the reaction of condensation of methane bromide to C3-C13 hydrocarbons is also provided. This catalyst is prepared by supporting compounds of Zn or Mg on molecular sieves such as HZSM-5, HY, Hb, 3A, 4A, 5A or 13X et al. With this catalyst, CH3Br and CH2Br2 produced in the former process can react further to give C3 to C13 hydrocarbons and HBr, and HBr can be recycled as a medium.
    Type: Application
    Filed: April 14, 2008
    Publication date: June 9, 2011
    Inventors: Zhen Liu, Hongmin Zhang, Wensheng Li, Yanqun Ren, Xiaoping Zhou
  • Publication number: 20110132807
    Abstract: The present invention is directed to a method for making a catalyst for hydroprocessing a carbonaceous feedstock under hydroprocessing conditions. More particularly, the present invention is directed to methods for inhibiting rapid decomposition of ammonium nitrate during calcination of the catalyst following metal impregnation, wherein ammonium nitrate is formed when a nitrate-containing composition and an ammonium-containing component is used in the deposition of metal onto the catalyst.
    Type: Application
    Filed: December 6, 2010
    Publication date: June 9, 2011
    Inventor: Bi-Zeng Zhan
  • Publication number: 20110120100
    Abstract: A catalyst system comprising a first catalytic composition comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic support. The pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers. The catalytic metal comprises nanocrystals.
    Type: Application
    Filed: November 24, 2009
    Publication date: May 26, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Ming Yin, Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Benjamin Hale Winkler, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Publication number: 20110118107
    Abstract: Methods for enhancing the mesoporosity of a zeolite-containing material. Such methods may comprise contacting a composite shaped article containing at least one zeolite and at least one non-zeolitic material with at least one pH controlling agent and at least one surfactant. Such methods may be performed under conditions sufficient to increase the pore volume of at least one 10 angstrom subset of mesoporosity.
    Type: Application
    Filed: October 19, 2010
    Publication date: May 19, 2011
    Applicant: RIVE TECHNOLOGY, INC.
    Inventors: Javier Garcia-Martinez, Lawrence B. Dight, Barry K. Speronello
  • Publication number: 20110108462
    Abstract: A catalyst composition prepared based on high solids formulation containing a zeolite, a binder precursor, a matrix and a slurring agent and a process for preparing a shaped catalyst product to be used in fluid catalytic cracking process for converting a heavier hydrocarbon fraction into a lighter hydrocarbons, particularly gasoline and light olefins.
    Type: Application
    Filed: November 10, 2009
    Publication date: May 12, 2011
    Inventor: Yun-Feng Chang
  • Patent number: 7939701
    Abstract: One exemplary embodiment can be an ion-exchanged xylene isomerization catalyst. The ion-exchanged xylene isomerization catalyst can include: about 1-about 99%, by weight, of at least one of MFI, MEL, EUO, FER, MFS, MTT, MTW, TON, MOR, and FAU zeolite; about 1-about 99%, by weight, of a binder having an aluminum phosphate; and no more than about 350 ppm, by weight, of a noble metal based on the weight of the catalyst. Generally, the catalyst has a quotient of (CO area)/(weight % of the noble metal) of no more than about 0.10.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: May 10, 2011
    Assignee: UOP LLC
    Inventors: Patrick C. Whitchurch, Paula L. Bogdan, Terrence E. Deak, Dimitri A. Trufanov
  • Publication number: 20110105301
    Abstract: An agglomerated zeolite adsorbent which comprises 95-99.5 mass % of X zeolite and 0.5-5.0 mass % of binder, wherein the exchangeable cationic sites of said X zeolite are occupied by Group IIA metal and/or K, the total pore volume of said adsorbent is no less than 0.26 mL/g as measured by mercury porosimetry, the volume of pores with pore diameters from 100 to 500 nm is at least 60% based on the total pore volume. During shaping, a pore-forming agent is added to this adsorbent, and then the adsorbent is alkali treated for in-situ crystallization, followed by ion exchange. Said adsorbent has high adsorption capacity, fast mass transfer rate and good mechanical strength. Said adsorbent is suitable for liquid phase adsorptive separation of para-xylene from C8 aromatic hydrocarbons and is also suitable for adsorptive separation of other alkyl aromatic hydrocarbons isomers.
    Type: Application
    Filed: January 24, 2009
    Publication date: May 5, 2011
    Inventors: Huiguo Wang, Jianfeng Ma, Dehua Wang, Zhuo Yu
  • Publication number: 20110092356
    Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.
    Type: Application
    Filed: December 16, 2010
    Publication date: April 21, 2011
    Applicant: BATTELLE ENERGY ALLIANCE, LLC
    Inventors: Harry W. Rollins, Lucia Petkovic, Daniel M. Ginosar
  • Publication number: 20110085940
    Abstract: A honeycomb filter includes a honeycomb structure and a zeolite. The honeycomb structure has cell walls to define cells between the cell walls. The zeolite is supported on the cell walls. An amount of the zeolite is from about 80 g/L to about 150 g/L. The cells include a large volume cell and a small volume cell. A porosity of the cell walls is from about 55% to about 65%. A proportion of a sum of a pore volume A and a pore volume B relative to a total pore volume C is about 20% or less. The pore volume A indicates a pore volume of pores having a pore diameter of one half or less of the average pore diameter. The pore volume B indicates a pore volume of pores having a pore diameter of twice or more the average pore diameter.
    Type: Application
    Filed: April 9, 2010
    Publication date: April 14, 2011
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazutake Ogyu, Toyoki Ogasawara
  • Patent number: 7918991
    Abstract: Compositions for reduction of NOx generated during a catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise a fluid catalytic cracking catalyst composition, preferably containing a Y-type zeolite, and a NOx reducing zeolite having a pore size ranging from about 2 to about 7.2 Angstroms and a SiO2 to Al2O3 molar ratio of less than about 500 and being stabilized with a metal or metal ion selected from the group consisting of zinc, iron and mixtures thereof. Preferably, the NOx reducing zeolite particles are bound with an inorganic binder to form a particulate composition. In the alternative, the NOx reducing zeolite particles are incorporated into the cracking catalyst as an integral component of the catalyst.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: April 5, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Michael Scott Ziebarth, M. Sundaram Krishnamoorthy, Roger Jean Lussier
  • Publication number: 20110077441
    Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises particles of a porous refractory material, crystals of a zeolite material grown within the pores of the refractory material, and at least one catalytically active metal or metal compound associated with the zeolite crystals.
    Type: Application
    Filed: September 22, 2010
    Publication date: March 31, 2011
    Inventor: Larry L. Iaccino
  • Publication number: 20110071264
    Abstract: The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a). selecting at least one molecular sieve selected from one of: a P-modified molecular sieve which contains at least 0.3 wt % of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt % of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a).
    Type: Application
    Filed: January 23, 2009
    Publication date: March 24, 2011
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk, Delphine Minoux
  • Patent number: 7902106
    Abstract: The invention is a composition that is suitable for reducing sulfur species from products produced by petroleum refining processes, especially gasoline products produced by fluidized catalytic cracking (FCC) processes. The composition comprises zeolite, yttrium, and at least one element selected from the group consisting of zinc, magnesium and manganese, wherein the yttrium and element are present as cations. The yttrium and zinc are preferably present as cations that have been exchanged onto the zeolite. The zeolite is preferably a zeolite Y.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: March 8, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Ruizhong Hu, Richard Franklin Wormsbecher
  • Patent number: 7902107
    Abstract: Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: March 8, 2011
    Assignee: BASF Corporation
    Inventors: Joseph A. Patchett, Joseph C. Dettling, Elizabeth A. Przybylski
  • Publication number: 20110047995
    Abstract: A catalyst system comprising a first catalytic composition comprising, (i) a first component comprising a zeolite, and (ii) a second component comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic network; wherein the pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers; wherein the first component and the second component form an intimate mixture. The catalyst system may further comprise a second catalytic composition and a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. An exhaust system comprising the catalyst systems described herein is also provided.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Donald Wayne Whisenhunt, Jr., Dan Hancu, Ashish Balkrishna Mhadeshwar, Benjamin Hale Winkler, Daniel George Norton, Oltea Puica Siclovan
  • Publication number: 20110039689
    Abstract: The present invention relates to a shaped catalyst body comprising a core and a first catalytically active layer arranged on sections of the core, characterized in that the total density of the core is greater than the total density of the catalytically active layer. The invention further relates to the use of said shaped catalyst body as an oxidation catalyst in the cleaning of exhaust gases or for reducing and decomposing nitrogen oxides and nitrous oxide.
    Type: Application
    Filed: April 21, 2008
    Publication date: February 17, 2011
    Inventors: Arno Tissler, Hans-Christoph Schwarzer, Roderik Althoff
  • Patent number: 7879749
    Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.
    Type: Grant
    Filed: August 15, 2006
    Date of Patent: February 1, 2011
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Harry W. Rollins, Lucia M. Petkovic, Daniel M. Ginosar
  • Patent number: 7858062
    Abstract: Embodiments of the present invention relate to a method for synthesizing nanocrystalline zeolites, the method comprising contacting starting products that comprise a solvent, a silicon source, a cation base, an organic template, and an aluminum source, or any combination thereof sufficient to produce a zeolite gel by hydrolysis, heating the zeolite gel sufficient to produce a first batch of zeolite crystals and a first clear solution, separating the first batch of zeolite crystals from the first clear solution, heating the first clear solution sufficient to produce a second batch of zeolite crystals and second clear solution and separating the second batch of zeolite crystals from the second clear solution.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: December 28, 2010
    Assignee: University of Iowa Research Foundation
    Inventors: Sarah Larsen, Vicki Grassian, Weiguo Song, Gonghu Li
  • Publication number: 20100319332
    Abstract: To equip a diesel particle filter with a zeolite-containing coating uniformly over the entire length of the particle filter and with a further zeolite-free coating which is applied, from the entry side of the filter, solely up to a specific length of the filter, it is proposed, first, to apply the zeolite-free coating from the entry side of the filter and only thereafter to apply the zeolite-containing coating over the entire length of the filter from the exit side of the filter. As a result of this sequence of coatings, a better adhesive strength of the coatings than when both coatings are applied from the entry side is ensured.
    Type: Application
    Filed: February 17, 2009
    Publication date: December 23, 2010
    Inventors: Gerald Jeske, Marcus Pfeifer, Wolfgang Schneider, Franz Dornhaus, Ralf Mueller, Michael Schiffer
  • Publication number: 20100316547
    Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
    Type: Application
    Filed: May 20, 2010
    Publication date: December 16, 2010
    Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
  • Publication number: 20100304957
    Abstract: Zeolite-based honeycomb bodies and methods of manufacturing same. Zeolite-based honeycomb bodies especially suited for engine exhaust treatment applications include a primary phase comprising a zeolite having a SiO2 to Al2O3 molar ratio in the range from 5 to 300. The zeolite-based composites are porous with an open porosity of at least 25% and a median pore diameter of at least 1 micron. The zeolite-based honeycomb bodies can be manufactured by an extrusion method.
    Type: Application
    Filed: June 3, 2010
    Publication date: December 2, 2010
    Inventors: Steven Bolaji Ogunwumi, Patrick David Tepesch, Raja Rao Wusirika
  • Patent number: 7807132
    Abstract: A quantity of solution sufficient to dissolve a pH controlling substance and/or substantially dissolve a surfactant without substantial excess solution is controlled under a set of time and temperature conditions to transform an inorganic material having long-range crystallinity to a mesostructure having long-range crystallinity. The method employs concentrated conditions that have a consistency similar to a thick slurry. The economic viability of scaling up such thick slurry methods is improved relative to prior more dilute methods of transforming an inorganic material to a mesostructure.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: October 5, 2010
    Assignee: Rive Technology, Inc.
    Inventor: Javier Garcia-Martinez
  • Publication number: 20100222205
    Abstract: A method of manufacturing a catalyst body which includes: combining one or more inorganic components with an inorganic binder, and optionally with an organic binder, to form a mixture, the one or more inorganic components comprising a primary phase material being zeolite, or CeO2—ZrO2, or a combination; forming the mixture into a shaped body; firing the shaped body to allow the inorganic binder to bind the one or more inorganic components; impregnating the shaped body with a source of a reducing or oxidizing element; and heating the impregnated shaped body to form a redox oxide from the source, the redox oxide being supported by the shaped body.
    Type: Application
    Filed: February 27, 2009
    Publication date: September 2, 2010
    Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil
  • Publication number: 20100221165
    Abstract: The present invention relates to a process for reactivating a catalyst which comprises a zeolite doped with an iron species, which comprises the step of treating the catalyst with hydrogen chloride-containing gas. The invention further relates to a reactivated catalyst which is obtained with the aid of the process according to the invention and to the use thereof for treatment of off-gases from incineration processes, especially for the treatment of off-gases from refuse incineration plants, very particularly for the reduction of nitrogen oxides.
    Type: Application
    Filed: July 2, 2008
    Publication date: September 2, 2010
    Applicant: Sud-Chemie AG
    Inventors: Ingo Hanke, Arno Tissler
  • Patent number: 7776775
    Abstract: The present invention provides a cracking catalyst, containing a rare-earth Y-zeolite and a support, which is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite is 4-15 wt % of RE2O3; the original unit cell size is 2.440-2.465 nm; the equilibrium unit cell size of the catalyst after 100% steam-aging treatment at 800° C. for 17 hours is larger than 2.435 nm; the rare-earth atom content in the support is 1.0-8.0 wt % of the support. The present invention also relates to a preparation process for the same catalyst.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: August 17, 2010
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Jun Du, Zheng Li, Jun Long, Mingde Xu, Zhijian Da, Huiping Tian, Mingyuan He
  • Publication number: 20100202946
    Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%. Other embodiments include one or more oxidatively active halides of a nonoxidative metal dispersed on sorbent substrate particles mixed with activated carbon in an amount up to 30% by weight. Further embodiments include physical blending of a flow modifier into the sorbent composition.
    Type: Application
    Filed: February 17, 2010
    Publication date: August 12, 2010
    Applicant: BASF Catalysts LLC
    Inventors: Xiaolin D. Yang, Pascaline H. Tran, Lawrence Shore
  • Publication number: 20100197989
    Abstract: Method for preparation of an adsorbent that comprises successive shaping stages by co-granulation of a faujasite-type zeolite powder A, with a powder B that consists of alumina, whereby the ratio per unit of mass of the powder A in the mixture of powders A and B is between 10 and 70%, for treatment under water vapor and drying. The invention also relates to a process for adsorption of organic contaminants that contain at least one heteroatom and that are present in an olefinic feedstock that comprises at least 50% by volume of hydrocarbons, whereby this process comprises the stage for bringing the olefinic feedstock into contact with the adsorbent that is obtained by the preparation method according to the invention.
    Type: Application
    Filed: June 18, 2008
    Publication date: August 5, 2010
    Applicant: IFP
    Inventors: Olivier Ducreux, Christophe Nedez, Catherine Pommier
  • Publication number: 20100160667
    Abstract: Processes comprising: (a) providing a shaped body having a surface and comprising a metal oxide, and impregnating the shaped body with a liquid comprising an unsaturated compound; (b) subjecting the impregnated shaped body to thermolysis under an inert gas atmosphere at a temperature of 250 to 400° C., such that at least 10% by weight of the unsaturated compound is thermalized to form a layer of a high molecular weight polyaromatic on at least a portion of the surface of the shaped body; and (c) reacting the shaped body with a reagent to functionalize the polyaromatic layer, wherein the shaped body has a smallest dimension in any spatial direction of at least 1 mm to provide a shaped catalyst body having ion- exchange properties; shaped catalyst bodies prepared thereby and uses therefor as catalysts.
    Type: Application
    Filed: August 7, 2007
    Publication date: June 24, 2010
    Applicant: BASF SE
    Inventors: Marco Bosch, Nawid Kashani-Shirazi, Christian Kuhrs
  • Publication number: 20100160152
    Abstract: A system is provided for desulfurizing a hydrocarbon fuel containing a light amount of methanol and a slight amount of water. The desulfurization system uses a Y-type zeolite-based desulfurizing agent containing at least copper arranged upstream of the system and an X-type zeolite-based desulfurizing agent containing at least silver arranged downstream of the system and thus can maintain desulfurization effect for a long period of time.
    Type: Application
    Filed: March 4, 2008
    Publication date: June 24, 2010
    Applicant: NIPPON OIL CORPORATION
    Inventors: Yoshiyuki NAGAYASU, Atsushi SEGAWA, Kazunori MIYAZAWA, Yoshihiro KOBORI
  • Publication number: 20100143227
    Abstract: Disclosed herein is a catalyst comprising a binder; and a catalytic composition, the catalytic composition comprising a first catalyst composition that comprises a zeolite; and a second catalyst composition that comprises a catalytic metal disposed upon a porous inorganic material, wherein the porous inorganic material is a metal oxide, an inorganic oxide, an inorganic carbide, an inorganic nitride, an inorganic hydroxide, an inorganic oxide having a hydroxide coating, an inorganic carbonitride, an inorganic oxynitride, an inorganic boride, an inorganic borocarbide, or a combination comprising at least one of the foregoing inorganic materials; wherein the catalyst is in the form of an extrudate or foam.
    Type: Application
    Filed: December 5, 2008
    Publication date: June 10, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Hrishikesh Keshavan, Benjamin Hale Winkler, Dan Hancu
  • Patent number: 7723252
    Abstract: There is disclosed in embodiments catalysts produced by a two-stage loading of a zeolite carrier with an aqueous solution of a cobalt compound, with drying in an air current after each loading. Methods using the catalysts to produce synfuel are disclosed.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: May 25, 2010
    Assignee: Wesco
    Inventors: Lapidus Albert Lvovich, Budtsov Vladimir Sergeevich
  • Patent number: 7718840
    Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: May 18, 2010
    Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical Technology
    Inventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
  • Publication number: 20100116134
    Abstract: High rate and high crush-strength adsorbent particles and collections of such particles, and particularly LiLSX particles, are provided. A binder is employed in the form of a colloidal solution during the method of manufacture. Suitable binders include various silica binders. The particles are made using the steps of mixing, agglomeration, calcination and in the case of certain adsorbents such as LiX and LiLSX, ion exchange and activation. When the adsorption rate is expressed in the form SCRR/?p (mmol mm2/g s), desirable collections of adsorbent particles can have values of at least 4.0 for the highly-exchanged Li (at least 90% Li exchanged) form of the collection of particles and can further be characterized by particles having average crush strengths of at least 0.9 lbf for particles having an average diameter of at least about 1.0 mm.
    Type: Application
    Filed: March 10, 2008
    Publication date: May 13, 2010
    Inventors: Jian Zheng, Steven John Pontonio, Neil Andrew Stephenson, Philip Alexander Barrett
  • Patent number: 7713904
    Abstract: This invention relates to a composition with desulfurization property, in which the desulfurization component is a kind of molecular sieves with incorporation of vanadium into the skeleton. The composition has high hydrothermal stability and the vanadium is hard to lose.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: May 11, 2010
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPEC
    Inventors: Baoning Zong, Jinyu Zheng, Wenhua Xie, Yong Xu, Xuhong Mu, Yibin Luo, Minggang Li, Xingtian Shu
  • Publication number: 20100113854
    Abstract: The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15<Si/AL<1.5, consisting of crystals with a mean diameter of 1.7 mm or less and of an inert binder, at least 90% of the exchangeable cationic sites of the zeolite X being occupied by barium ions. They may be obtained by agglomerating a zeolite X powder having a mean diameter of 1.7 mm or less with a binder, followed by zeolitization of the binder, exchange of the zeolite ions with barium (and potassium) ions and activation of the adsorbents thus exchanged.
    Type: Application
    Filed: July 13, 2007
    Publication date: May 6, 2010
    Inventors: Ludivine Bouvier, Stephane Kieger, Catherine Laroche, Philibert Leflaive, Dominique Plee
  • Publication number: 20100111796
    Abstract: Catalysts, methods of preparing catalyst, and methods for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes an upstream zone effective to catalyze the conversion of a mixture of NOx and NH3 to N2, and a downstream zone effective for the conversion of ammonia to N2 in the presence or absence of NOx. In an embodiment, a method for preparing a catalyst system includes: first coating one end of a substrate along at least 5% of its length with an undercoat washcoat layer containing a material composition effective to catalyze the removal of ammonia; second coating with an overcoat layer containing a material composition effective to catalyze the conversion of a mixture of NOx and NH3 to N2.
    Type: Application
    Filed: November 3, 2008
    Publication date: May 6, 2010
    Applicant: BASF Catalysts LLC
    Inventors: Matthew Tyler Caudle, Martin Dieterle, Scott E. Buzby
  • Patent number: 7700511
    Abstract: A process for converting polyalkylaromatics to monoalkylaromatics, particularly cumene, in the presence of a modified LZ-210 zeolite catalyst is disclosed. The process attains greater selectivity, reduced formation of undesired byproducts, and increased activity.
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: April 20, 2010
    Assignee: UOP LLC
    Inventors: Thomas M. Reynolds, Christopher J. Garrett, Deng-Yang Jan, Robert J. Schmidt, Mathias P. Koljack
  • Patent number: RE41314
    Abstract: A gas adsorbing element is formed into a honeycomb-shaped laminate having many small channels penetrating from one end surface to the other and in which hydrophobic high silica zeolite powder is exposed on the walls of the small channels. The hydrophobic high silica zeolite is, for example, a zeolite which is produced by removing most of the aluminum component from an ordinary zeolite. In forming the honeycomb-shaped laminate, it is favorable that non-flammable sheets are laminated and the laminate is impregnated with a dispersion of high silica zeolite powder and with an inorganic binder, and that the high silica zeolite powder is fixed in fiber gaps and on the surface of the non-flammable paper. It is desirable that the non-flammable sheet is a low density inorganic fiber paper and is baked either before or after forming the honeycomb-shaped laminate.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: May 4, 2010
    Assignee: Kabushiki Kaisha Seibu Giken
    Inventors: Toshimi Kuma, Chieko Kuma