Support Per Se Patents (Class 502/87)
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Patent number: 6828396Abstract: There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.Type: GrantFiled: January 21, 2003Date of Patent: December 7, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
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Patent number: 6806221Abstract: A method of making a spray-dried composition using a solution or mixture comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from 1 &mgr;m to about 12 &mgr;m.Type: GrantFiled: July 15, 2002Date of Patent: October 19, 2004Assignee: Dow Global Technologies Inc.Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
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Patent number: 6787497Abstract: The invention concerns a catalyst carrier comprising a fibre paper impregnated with a slurry comprising silica sol, micro fibres and a filler, wherein said micro fibres have an equivalent average particle size, measured with sedigraph method, from about 200 nm to about 30000 nm and said filler has an average equivalent particle size, measured with sedigraph method, from about 300 to about 10000 nm. The invention further concerns a method of its preparation, a slurry useful therefore, a catalyst comprising such a catalyst carrier and use of the catalyst.Type: GrantFiled: September 28, 2001Date of Patent: September 7, 2004Assignee: Akzo Nobel N.V.Inventors: Anna-Carin Dellve, Bozena Tokarz, Mats Nyström
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Patent number: 6780805Abstract: Zeolite/alumina composite, and a method for making, the composite for use as a catalyst substrate or catalyst carrier and comprising zeolite having a silica/alumina ratio of greater than 300 and gamma alumina having a specific surface area of greater than 100 m2/g. The zeolite/alumina composite exhibits a modulus of rupture of at least 750 psi. Additionally, the invention is also directed at a three catalyst (TWC) system for use in the removal of hydrocarbons, carbon monoxide and oxides of nitrogen from waste gas, the TWC system comprising the following components: (1) a zeolite/alumina composite catalyst support exhibiting a modulus of rupture of at least 750 psi and having a zeolite with a silica/zeolite ratio of at least 300 and the alumina comprising a gamma alumina having a specific surface area of greater than 100 m2/g; and, (2) a noble metal catalyst impregnated on the catalyst support, the noble metal selected from the group consisting of platinum, rhodium, iridium and palladium.Type: GrantFiled: May 9, 2002Date of Patent: August 24, 2004Assignee: Corning IncorporatedInventors: Margaret K. Faber, Shy-Hsien Wu, Yuming Xie, Kenneth E. Zaun
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Patent number: 6723808Abstract: Disclosed are polymerization catalyst activator compositions which include a carbonium cation and an aluminum containing anion. These activator compositions are prepared by combining a carbonium or trityl source and with an aluminum containing complex, preferably a perfluorophenylaluminum compound. Also disclosed are polymerization catalyst systems including the activator composition of the invention, and processes for polymerizing olefins utilizing same.Type: GrantFiled: October 8, 2002Date of Patent: April 20, 2004Assignee: Univation Technologies, LLCInventor: Matthew W. Holtcamp
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Patent number: 6682650Abstract: A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf.Type: GrantFiled: June 5, 2001Date of Patent: January 27, 2004Assignees: Japan Cooperation Center, Petroleum, National Institute of Advanced Industrial Science and TechnologyInventors: Kosaku Honna, Yasuhiro Araki, Yasuo Miki, Hiromichi Shimada
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Publication number: 20040010100Abstract: A spray-dried composition comprising an inert porous filler and a reaction product of 1) a mixture or reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound. The filler is substantially spherical and has an average particle size ranging from about 1 &mgr;m to about 12 &mgr;m. Methods of making spray-dried compositions, catalysts and polymerization processes employing such are also described.Type: ApplicationFiled: July 15, 2002Publication date: January 15, 2004Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
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Patent number: 6664352Abstract: The invention provides a process for the preparation of a supported polymerization catalyst, said process comprising impregnating a porous particulate support in a mechanically fluidized state with a catalyst material.Type: GrantFiled: April 9, 2001Date of Patent: December 16, 2003Assignee: Borealis Technology OyInventors: Siw Fredriksen, Tore Dreng, Vidar Almquist
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Patent number: 6653416Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided solid oxide compound.Type: GrantFiled: February 28, 2002Date of Patent: November 25, 2003Assignee: Phillips Petroleum CompanyInventors: Max P. McDaniel, Kathy S. Collins, James L. Smith, Elizabeth A. Benham, Marvin M. Johnson, Anthony P. Eaton, Michael D. Jensen, Joel L. Martin, Gil R. Hawley
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Patent number: 6645900Abstract: The invention relates to a catalyst support and to a method for the production of the catalyst support comprising the following steps: a) production of a silicic acid hydrogel having a solids content of from 10 to 25% by weight (calculated as SiO2) whose particles are substantially spherical, b) extraction of the hydrogel particles with an alcohol until at least 60% of the water present in the hydrogel has been removed, c) drying of the resultant hydrogel until the residual alcohol content is less than 10% by weight (xerogel formation) at temperatures of ≧160° C. at atmospheric pressure using an inert entraining gas, d) setting of the desired particle size of the resultant xerogel, in which the hydrogel particles have a particle size of ≧8 mm before the extraction, and to a catalyst and to a method for the production of the catalyst by loading the catalyst support with a chromium compound. The invention also relates to a method for the production of polyolefins using the catalyst.Type: GrantFiled: February 28, 2002Date of Patent: November 11, 2003Assignee: Basell Polyolefine GmbHInventors: Paulus de Lange, Guido Funk, Andreas Deckers, Peter Kölle
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Patent number: 6642340Abstract: A process for preparing an ethylene/&agr;-olefin copolymer, which includes the steps of (A) copolymerizing ethylene and an &agr;-olefin of 3 to 20 carbon atoms by continuous vapor phase polymerization; (B) copolymerization is conducted in the presence of a prepolymerized catalyst obtained by prepolymerizing an olefin in the presence of (a) a transition metal compound, (b) an organoaluminum oxy-compound, (c) a fine particle carrier, and optionally (d) an organoaluminum compound; and (C) copolymerization is conducted under such condition that the partial pressure of sum total of ethylene and &agr;-olefin is 10 to 28 kg/cm2. The resulting ethylene/&agr;-olefin copolymer has the following properties: (i) the density is in the range of 0.880 to 0.960 g/cm3, (ii) the melt flow rate of 190° C. under a load of 2.16 kg is in the range of 0.1 to 100 g/10 min, (iii) the melt tension (MT (g)) at 190° C. and the melt flow rate (MFR (g/10 min)) satisfy the relation MT≦2.2×MFR−084.Type: GrantFiled: June 30, 2000Date of Patent: November 4, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Mamoru Takahashi, Takasi Nakagawa, Masaaki Ohgizawa
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Patent number: 6635728Abstract: A process for making an ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The process is performed with a supported quinolinoxy-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen. The process significantly increases the catalyst activity and the UHMWPE produced has improved tensile and impact properties.Type: GrantFiled: January 10, 2002Date of Patent: October 21, 2003Assignee: Equistar Chemicals, LPInventor: Jia-Chu Liu
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Publication number: 20030153466Abstract: An agricultural and horticultural plant growth zeolite-based composition containing a particular zeolitic (i.e., zeolite-containing) material, termed “Jordanite,” is disclosed. This composition exhibits a collection of outstanding advantageous properties in agricultural and horticultural applications. Jordanite, which is found in a particular area of Jordan, comprises primarily phillipsite as the zeolite, optionally in conjunction with palagonite. Jordanite provides surprisingly better results as compared to when other zeolite-based soil amendment compositions, even when it is used as the mined material that has been only subject to a grinding or crushing operation to a desired mesh size. As mined, Jordanite contains very low levels of undesired Na+ ions. It can, therefore, be used without being subjected to a washing operation to remove these ions. Jordanite also possesses a very high CEC.Type: ApplicationFiled: December 21, 2001Publication date: August 14, 2003Applicant: ASI SPECIALITIES, LTD.Inventors: A. John Allen, Sebastian Braum
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Patent number: 6602816Abstract: Activated regular-shaped clay particles forming macropores therein, preserving fine structure of the dioctahedral smectite clay minerals, and having particle diameters controlled to lie within a range in which they exhibit excellent filtering property. The invention further provides method of producing activated regular-shaped clay particles comprising the steps of adjusting the particle size of the dioctahedral smectite clay minerals to possess a volume-based median diameter (D50) of from 1 to 10 &mgr;m as found by a laser diffraction method, mixing an acid-soluble or acid-decomposing inorganic compound to the milled product thereof, granulating the mixture into regular particles having a volume-based median diameter (D50) of from 10 to 60 &mgr;m as found by a laser diffraction method, and treating the regular-shaped particles with an acid while maintaining the particle shapes.Type: GrantFiled: March 13, 2001Date of Patent: August 5, 2003Assignee: Mizusawa Industrial Chemicals LtdInventors: Masashi Hatano, Hitoshi Yamamoto, Daisuke Kuse
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Publication number: 20030130110Abstract: There are provided:Type: ApplicationFiled: January 21, 2003Publication date: July 10, 2003Inventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
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Publication number: 20030130448Abstract: A process for making an ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The process is performed with a supported quinolinoxy-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen. The process significantly increases the catalyst activity and the UHMWPE produced has improved tensile and impact properties.Type: ApplicationFiled: January 10, 2002Publication date: July 10, 2003Inventor: Jia-Chu Liu
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Patent number: 6544921Abstract: There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.Type: GrantFiled: September 13, 2000Date of Patent: April 8, 2003Assignee: Sumitomo Chemical Comapny, LimitedInventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
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Patent number: 6531552Abstract: An olefin polymerization catalyst comprising the following components (A) and (B): Component (A): an ion-exchange layered silicate having an acid site of at most −8.2 pKa, the amount of the acid site is equivalent to at least 0.05 mmol/g of 2,6-dimethylpyridine consumed for neutralization; and Component (B): a compound of a transition metal belonging to Group 3 to Group 12 of the Periodic Table.Type: GrantFiled: January 10, 2001Date of Patent: March 11, 2003Assignee: Japan Polychem CorporationInventors: Hiroshi Nakano, Takao Tayano, Hideshi Uchino, Tadashi Takahashi
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Patent number: 6495484Abstract: Disclosed are polymerization catalyst activator compositions which include a carbonium cation and an aluminum containing anion. These activator compositions are prepared by combining a carbonium or trityl source and with an aluminum containing complex, preferably a perfluorophenylaluminum compound. Also disclosed are polymerization catalyst systems including the activator composition of the invention, and processes for polymerizing olefins utilizing same.Type: GrantFiled: August 28, 2000Date of Patent: December 17, 2002Assignee: Univation Technologies, LLCInventor: Matthew W. Holtcamp
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Patent number: 6476085Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.Type: GrantFiled: November 16, 2001Date of Patent: November 5, 2002Assignee: Conoco Inc.Inventors: Leo E. Manzer, Stephan Schwarz
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Patent number: 6475945Abstract: The present invention relates to functionalized catalyst supports that are useful in the formation of supported polymerization catalysts, supported catalysts derived from such functionalized catalyst supports, methods for preparing such functionalized catalyst supports and supported catalysts, and polymerization processes utilizing such supported catalysts. The functionalized catalyst support comprises a particulated support material having chemically bonded thereto a plurality of aluminum-containing groups derived from a non-ionic Lewis acid, said aluminum-containing groups: containing at least one fluoro-substituted hydrocarbyl ligand containing from 1 to 20 carbons, said hydrocarbyl ligand being bonded to aluminum, and being bonded to said support material, optionally through a bridging moiety, said composition being capable of activating a Group 3-10 metal complex for the addition polymerization of one or more addition polymerizable monomers.Type: GrantFiled: May 18, 2000Date of Patent: November 5, 2002Assignee: The Dow Chemical CompanyInventors: Edmund M. Carnahan, Grant B. Jacobsen
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Publication number: 20020140138Abstract: Zeolite based material and a method for making the zeolite, comprising a zeolite having a silica/alumina ratio of at least 300 and a surface area of 250 m2/g and no greater than about 20 parts, by weight, of a silica binder. The combination of properties this zeolite based material exhibits includes the following: (1) a modulus of rupture of at least 1500 psi; (2) a surface area of at least 100 m2/g; (3) a coefficient of thermal expansion of less than about +/−10 ppm/° C.; and, (4) a thermal shock resistance of at least 850° C. The zeolite-based material can include a third component, specifically a gamma alumina having a specific surface area of greater than 100 m2/g.Type: ApplicationFiled: December 12, 2000Publication date: October 3, 2002Inventors: Shy-Hsien Wu, Kenneth E. Zaun
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Patent number: 6413898Abstract: Zeolite/alumina composite, and a method for making, the composite for use as a catalyst substrate or catalyst carrier and comprising zeolite having a silica/alumina ratio of greater than 300 and gamma alumina having a specific surface area of greater than 100 m2/g. The zeolite/alumina composite exhibits a modulus of rupture of at least 750 psi. Additionally, the invention is also directed at a three catalyst (TWC) system for use in the removal of hydrocarbons, carbon monoxide and oxides of nitrogen from waste gas, the TWC system comprising the following components: (1) a zeolite/alumina composite catalyst support exhibiting a modulus of rupture of at least 750 psi and having a zeolite with a silica/zeolite ratio of at least 300 and the alumina comprising a gamma alumina having a specific surface area of greater than 100 m2/g; and, (2) a noble metal catalyst impregnated on the catalyst support, the noble metal selected from the group consisting of platinum, rhodium, iridium and palladium.Type: GrantFiled: December 12, 2000Date of Patent: July 2, 2002Assignee: Corning IncorporatedInventors: Margaret K. Faber, Shy-Hsien Wu, Yuming Xie, Kenneth E. Zaun
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Patent number: 6395666Abstract: This invention provides catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises as organometal compound, as organoaluminum compound, and a fluorided solid oxide compound.Type: GrantFiled: September 29, 1999Date of Patent: May 28, 2002Assignee: Phillips Petroleum CompanyInventors: Max P. McDaniel, Kathy S. Collins, James L. Smith, Elizabeth A. Benham, Marvin M. Johnson, Anthony P. Eaton, Michael D. Jensen, Joel L. Martin, Gil R. Hawley
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Publication number: 20020061812Abstract: The slurry for carrying zeolite of the present invention is slurry for attaching zeolite to a carrier and comprises zeolite and an organic emulsion binder dispersed in water. This slurry for carrying zeolite has viscosity not excessively high in spite of a large content of zeolite and binder and has a pH at which the zeolite and binder are stable. The slurry therefore can be stored for a long time in a stable manner.Type: ApplicationFiled: September 24, 2001Publication date: May 23, 2002Applicant: Nichias Co., Ltd.Inventors: Teruzi Yamazaki, Jun Shimada
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Patent number: 6387837Abstract: This invention relates to a process for the free-radical polymerization of monomers in gas phase or suspension processes using a supported, polymerization-initiating system comprising a) one or more polymerization-initiating components which initiate and start free-radical polymerization, b) a support, onto which said polymerization-initiating component is applied, and c) optionally, one or more modifiers which have an influence upon reaction kinetics and/or product properties.Type: GrantFiled: February 3, 1999Date of Patent: May 14, 2002Assignee: Bayer AktiengesellschaftInventors: Michael Dauben, Martin Hoch, Christiane Oppenheimer-Stix, Peter Schertl
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Publication number: 20020052289Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.Type: ApplicationFiled: November 16, 2001Publication date: May 2, 2002Inventors: Leo E. Manzer, Stephan Schwarz
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Patent number: 6372685Abstract: Silica powders and mixed silica-oxide powders and methods of preparing such powders for use as catalyst supports for polymerization processes.Type: GrantFiled: April 25, 2000Date of Patent: April 16, 2002Assignee: Chevron Phillips Chemical Company, LPInventors: Theresa A. Pecoraro, Ignatius Y. Chan, Darryl K. Whaley, Pamela R. Auburn
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Patent number: 6362122Abstract: A process for regenerating spent zeolite composites. The process involves contacting the composite, either as a shaped article or a fine powder, with a caustic solution, e.g., sodium hydroxide at treating condition. Once the contacting is completed, the composite is isolated, washed with water, dried and calcined to give a regenerated composite.Type: GrantFiled: November 8, 1999Date of Patent: March 26, 2002Assignee: UOP LLCInventor: Thomas R. Cannan
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Patent number: 6333289Abstract: The present invention relates to a process for activating catalysts for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization and at least one passivation using ammonia.Type: GrantFiled: April 9, 1999Date of Patent: December 25, 2001Assignee: Institut Francais du PetroleInventors: Jean-François Joly, Julia Magne-Drisch, Fabio Alario, Elisabeth Merlen, Eric Benazzi, Sylvie Lacombe
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Patent number: 6319872Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.Type: GrantFiled: August 18, 1999Date of Patent: November 20, 2001Assignee: Conoco INCInventors: Leo E. Manzer, Stephan Schwarz
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Publication number: 20010009884Abstract: The invention relates to a method for producing an adsorbent and/or catalyst and binder system comprising I) mixing components comprising (a) a binder comprising a colloidal metal oxide or colloidal metalloid oxide, (b) an oxide adsorbent and/or catalyst particle, and (c) an acid, (ii) removing a sufficient amount of water from the mixture to cross-link components a and b to form an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.Type: ApplicationFiled: December 7, 2000Publication date: July 26, 2001Inventors: Mark L. Moskovitz, Bryan E. Kepner, Eric A. Mintz
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Patent number: 6242167Abstract: An electron accepting developer useful for producing visible images by reaction with an electron donor in carbonless paper and photo-imaging systems, the developer comprising an acid-treated, water insoluble alkali metal-modified, inorganic oxide or an acid-treated molecular sieve.Type: GrantFiled: April 12, 1999Date of Patent: June 5, 2001Assignee: Rentech, Inc.Inventors: Dale R. Shackle, Benjamin Chaloner-Gill
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Patent number: 6174834Abstract: Oxychlorination catalyst is produced by mixing together wet support material, copper chloride or precursor thereof, to form a paste, wherein the wet support material is wet clay, wet silica, wet silica gel, wet alumina, wet diatomaceous earth, or a mixture of two or more thereof; removing water from the paste to produce a substantially dry mixture; and calcining the substantially dry mixture at elevated temperatures to produce a calcined mixture wherein alkali metal chloride or precursor thereof is mixed with the wet support material or an aqueous solution of alkali metal chloride or precursor thereof is applied to the paste, the substantially dry mixture, or the calcined mixture and the water of the aqueous solution is substantially removed. Preferably wet attapulgus clay, cupric chloride, and potassium chloride are mixed to form the paste.Type: GrantFiled: April 5, 1999Date of Patent: January 16, 2001Assignee: PPG Industries Ohio, Inc.Inventor: Henry W. Schussler, III
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Patent number: 6174430Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises: a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na2O level of less than or equal to about 0.2 weight percent; b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; and c) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m2/g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.Type: GrantFiled: March 28, 2000Date of Patent: January 16, 2001Assignee: Shell Oil CompanyInventors: Bruce Herman Charles Winquist, David Allen Cooper
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Patent number: 6093672Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises:a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na.sub.2 O level of less than or equal to about 0.2 weight percent;b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; andc) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal; wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m.sup.2 /g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.Type: GrantFiled: March 20, 1997Date of Patent: July 25, 2000Assignee: Shell Oil CompanyInventors: Bruce Herman Charles Winquist, David Allen Cooper
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Patent number: 5972831Abstract: The present invention concerns a novel photocatalytic composition, a photocatalytic element and a novel method for the photocatalytic treatment of effluents, comprising a gaseous or aqueous solution of the organic compounds to be destroyed.This novel photocatalytic composition consists of an inorganic gel comprising a photocatalyst and an aluminosilicate inorganic polymer binder of the Imogolite type.This composition destroys organic compounds efficaciously.Type: GrantFiled: June 12, 1997Date of Patent: October 26, 1999Assignee: Eastman Kodak CompanyInventors: Olivier J. Poncelet, Danielle M. Wettling
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Patent number: 5807800Abstract: Stereospecific catalysts and processes for the stereotactic polymerization of ethylenically unsaturated monomers, specifically C.sub.3 -C.sub.4 alpha olefins involving a molecular sieve supported metallocene catalyst comprising a stereospecific metallocene catalyst component and a co-catalyst component. The metallocene catalyst component incorporates a metallocene ligand structure having two sterically dissimilar cyclopentadienyl ring structures coordinated with the central transition metal atom. Both the metallocene catalyst component and the co-catalyst component are supported on a molecular sieve having an average effective pore size which is less than the kinetic diameter of at least one of said ring structures. This supported catalyst is contacted in a polymerization reaction zone with an ethylenically unsaturated monomer which contains 3 or more carbon atoms or which is a substituted vinyl compound under polymerization conditions to produce stereospecific polymerization of the monomer.Type: GrantFiled: February 11, 1997Date of Patent: September 15, 1998Assignee: Fina Technology, Inc.Inventors: Edwar S. Shamshoum, Margarito Lopez
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Patent number: 5756415Abstract: A method of preparing an enzyme immobilizing carrier includes the steps of providing a material consisting of kaolin mineral. The material is subject to acid treatment with a strong acid having a pH of 4 or less, and hydrothermal treatment at a temperature of from about 100.degree. C. to about 250.degree. C. The material is dried, thereby producing a porous powder. The porous powder is baked at a temperature of from about 350.degree. C. to about 1000.degree. C., for thereby producing the carrier.Type: GrantFiled: June 6, 1995Date of Patent: May 26, 1998Assignee: Toyo Denka Kogyo Co., Ltd.Inventors: Joji Takahashi, Eiji Kanazawa, Yoshitaka Yamashita, Tomio Kashiwai, Hideo Takenaka
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Patent number: 5750026Abstract: A device for purifying a workstream of contaminants and method of making. One device is made of an inorganic monolithic porous particulate filter and a continuous uninterrupted coating of activated carbon impregnated into the pores of the filter. Preferably the filter has inlet and outlet faces, and a multiplicity of cells separated by porous walls and extending longitudinally and mutually parallel therethrough from inlet to outlet end, a portion of the total number of cells being plugged at the inlet end face, and the remaining portion of the total number of cells being plugged at the outlet end face of the device. Another device can be made entirely of activated carbon having the multicellular structure. A workstream containing contaminants is passed through the device to cause retention of the contaminants. The device can have electrically conducting mechanism for conducting electric current therethrough for removal of the contaminants and regeneration of the device.Type: GrantFiled: January 15, 1997Date of Patent: May 12, 1998Assignee: Corning IncorporatedInventors: Kishor P. Gadkaree, Timothy V. Johnson
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Patent number: 5736479Abstract: The invention concerns new oxidation catalysts, methods of producing them and their use. These catalysts consist of titanium silicalites crystallized in situ onto activated charcoal or metal oxides. The titanium silicalite content lies preferably in the range of 30 to 60% by wt. The atomic ratio of Si to Ti in the carrier-borne phase is 10 to 100. Such catalysts are particularly suitable for oxidation reactions with H.sub.2 O.sub.2 under mild conditions, such as temperatures of 20.degree. to 120.degree. C. and pressures equal to or higher than atmospheric.Type: GrantFiled: May 24, 1995Date of Patent: April 7, 1998Assignee: Leuna-Katalysatoren GmbHInventors: Rainer Schodel, Peter Birke, Reinhard Geyer, Peter Kraak, Willibald Muller, Hans-Dieter Neubauer, Rolf Pester, Fritz Vogt, Klaus-Peter Wendlandt
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Patent number: 5721037Abstract: A honeycomb structural body is obtained by mixing 60.about.80 wt % of aggregate, which does not show a transformation of crystal structures substantially up to 500.degree. C., and 20.about.40 wt % of clay to obtain a mixture, adding phosphate as a hardening agent to the mixture in such a manner that more than 2.0 wt % of phosphoric acid exists therein with respect to 100 wt % of the mixture, adding a forming agent and a water to the mixture to obtain a formable batch, extruding the batch into a honeycomb structure to obtain a honeycomb structural formed body, drying the honeycomb structural formed body, and subjecting the honeycomb structural formed body to a heat treatment in 300.degree..about.500.degree. C. The thus obtained honeycomb structural body has excellent catalyst carrying property and fireproof property, which are used as a catalyst carrier for ozone dissolving, deodorizing and so on in an inexpensive manner.Type: GrantFiled: July 28, 1995Date of Patent: February 24, 1998Assignee: NGK Insulators, Ltd.Inventors: Kazuhiko Kumazawa, Tatsuya Ishiguro
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Patent number: 5716899Abstract: A body made up of substantially continuous high strength multicellular support having porous cell walls, and pores in the cell walls having an average pore diameter of which have active material embedded therein, and an outer surface. The body is made of material which can be ceramics, glass, glass-ceramic, cermet, metal, oxides, and combinations of these. The active material can be molecular sieve, activated carbon, and combinations these. A method for producing a pore-impregnated body which involves providing the substrate having a wall porosity greater than about 45% by volume, and an average pore diameter of about 15 to 30 micrometers, providing a slurry of active material dispersed in a medium, contacting the support with the slurry at subatmospheric pressure to substantially fill the open pores of the substrate with the active material, removing excess slurry from the outer surface and the non-pore surfaces of the cell walls, followed by drying.Type: GrantFiled: June 27, 1995Date of Patent: February 10, 1998Assignee: Corning IncorporatedInventors: Donald L. Guile, Jimmie L. Williams
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Patent number: 5698165Abstract: An ozone filter comprising a paper carrier made of inorganic fiber and having a high porosity is disclosed. Supported by the carrier is a zeolite powder having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of not smaller than 15 and fine powder-like activated manganese dioxide having ozone decomposing capability. A process for producing the ozone filter is also disclosed. The ozone filter does not give off a foul smell even when used for a long period of time.Type: GrantFiled: August 24, 1995Date of Patent: December 16, 1997Assignee: Nichias CorporationInventors: Isao Terada, Shinichiro Arai
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Patent number: 5632931Abstract: Bloated minerals previously used as aggregates for light-weight concrete are here fragmented, wetted, and intermixed with particulate chemical reactants or catalysts, to serve as inert carriers therefor in industrial processes. One use is in the deep-bed flow-through process of reacting and removing hydrogen sulfide as contained in natural gas.Type: GrantFiled: August 24, 1995Date of Patent: May 27, 1997Assignee: Gas Sweetener Associates, Inc.Inventors: Irwin Fox, deceased, Alvin Samuels
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Patent number: 5409671Abstract: A catalytic convertor for treating exhaust gas includes a first catalyst layer formed on a base material and a second catalyst layer formed on the first catalyst layer. The first catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one precious metal borne on the silicate, and the second catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one metal borne on the silicate which is selected from the group consisting of Zr, Co, Cu, Cr, Mn, Y, Fe, Ni, V, Ti, Zn, Ga, Ba, Mg, La, Ce, Pr, Nd, Sm and Tb and differs from the transition metal provided on the silicate by ion exchange.Type: GrantFiled: March 21, 1994Date of Patent: April 25, 1995Assignee: Mazda Motor CorporationInventors: Takashi Takemoto, Yasuto Watanabe, Masahiko Shigetsu, Kazunari Komatsu, Makoto Kyogoku
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Patent number: 5407880Abstract: A catalyst for the adsorption of hydrocarbons is used in an apparatus for the purification of exhaust gas from an internal engine and comprises a honeycomb monolith carrier, a first layer of at least one zeolite having a different crystalline structure, a second layer containing at least one of Pt and Pd as a catalytic component, and a third layer containing Rh as a catalytic component.Type: GrantFiled: November 5, 1993Date of Patent: April 18, 1995Assignee: Nissan Motor Co., Ltd.Inventors: Takuya Ikeda, Chiemi Hayashi, Tetsuo Ito, Koji Masuda, Maki Kamikubo
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Patent number: 5215724Abstract: A filter for removing impurities from waste gases, and especially from the waste gases of an internal combustion engine, includes a filter body consisting of a plurality of compression moulded, high temperature resistant, sintered filter plates consisting of metal powder, metal chips, metallic fibres or a mixture of these materials, which are arranged on top of or behind one another and kept at a distance from one another by spacers, to form between them a plurality of flow channels. The flow channels are open at one end and closed at the other end in order to form inlet and outlet channels. The walls of the filter plate situated between the inlet and outlet channels constitute filter surfaces. The filter plates are formed by filter discs lying on top of one another, arranged in a filter housing and having a free or open central interior space, so that the waste gases flow radially through the filter discs from the outside towards the interior space or from the interior space towards the outside.Type: GrantFiled: September 5, 1991Date of Patent: June 1, 1993Assignee: Schwabische Huttenwerke GmbHInventor: Hans A. Haerle
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Patent number: 5180701Abstract: The present invention relates to a process for preparing a shapable dough which comprises mixing and kneading a silica source, a dealuminated aluminosilicate zeolite source, water and a trialkanolamine containing at least two carbon atoms per alkanolamine moiety, to a shapable dough thus obtained, and to the preparation of extrudates containing dealuminated aluminosilicate zeolites by extruding a shapable dough comprising a silica source, a dealuminated aluminosilicate zeolite source, water and a trialkanolamine and having a total solids content between about 25% by weight and about 75% by weight and a trialkanolamine content between about 0.5% by weight and about 40% by weight, basis on the total solid content of the mixture.Type: GrantFiled: December 16, 1991Date of Patent: January 19, 1993Assignee: Shell Oil CompanyInventors: Patrick Moureaux, Jean P. Darnanville
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Patent number: 5149435Abstract: A molecular sieve material is combined with a porous carrier material. The pores of the molecular sieve material are impermeable to molecules or organisms having a size equal to or greater than that of the water molecule either because the molecular sieve material is selected so as to have pores which are smaller than such molecule or because the pores of the molecular sieve material are closed by a film. The pores of the molecular sieve material thus remain unoccupied and are able to exert an attractive force on molecules or organisms which are to be captured. The pores of the carrier material are designed to accept molecules or organisms having a size equal to or greater than that of the water molecule so that, when such molecules or organisms are attracted by the molecular sieve material, they can be trapped in the carrier material.Type: GrantFiled: September 6, 1989Date of Patent: September 22, 1992Assignee: H J L Projects & Developments Ltd.Inventor: Hans-Jurgen Laube