Having Nonchromogenic Liquid Spread-control Or Transfer-improving Agent Or Component, Color Modifier, Stabilizer Or Preservative Patents (Class 503/209)
  • Patent number: 5935900
    Abstract: The present invention provides a heat sensitive recording material comprising a heat sensitive recording layer formed on a substrate and containing an electron-donating compound and an electron-accepting compound, and a protective layer formed on the recording layer when required, the recording material being characterized in that at least one benzotriazole compound represented by the formula (1) is incorporated into at least one of the heat sensitive recording layer and the protective layer ##STR1## wherein R.sup.1 is C.sub.1.about.4 alkyl, Ar is 1,3-phenylene or 1,4-phenylene.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: August 10, 1999
    Assignee: Ojl Paper Co., Ltd.
    Inventors: Tatsuya Meguro, Naoko Inatsu, Tetsuo Tsuchida
  • Patent number: 5932516
    Abstract: A reversible thermosensitive coloring composition is provided, which contains (a) an electron-donating coloring compound; and (b) an electron-accepting compound, which is an aromatic carboxylic acid compound comprising at least one hydrocarbon group, which induces color formation in the electron-donating coloring compound. The reversible thermosensitive coloring composition reversibly assumes a color-developed state or a decolorized state, in response to at least one of (1) the temperature thereof when heated and (2) the cooling rate of the reversible thermosensitive coloring composition when cooled after the heating thereof. A reversible thermosensitive recording medium using the coloring composition is also provided.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: August 3, 1999
    Assignee: Ricoh Company, Ltd.
    Inventors: Masafumi Torii, Hiromi Furuya, Masaru Shimada, Kyoji Tsutsui
  • Patent number: 5869421
    Abstract: A reversible thermosensitive recording material has a support and a reversible thermosensitive recording layer formed thereon, capable of reversibly assuming at least two different visible states depending upon the temperature thereof, containing an organic low-molecular weight material and a resin composition in which the organic low-molecular weight material is dispersed, the resin composition including a matrix resin, and a dispersion resin which has a glass transition temperature higher than that of the matrix resin, and having resin aggregates which are separately dispersed in the matrix resin in such a manner that the resin aggregates are associated with the matrix resin.
    Type: Grant
    Filed: August 21, 1997
    Date of Patent: February 9, 1999
    Assignee: Ricoh Company, Ltd.
    Inventors: Atsushi Kutami, Tohru Nogiwa, Fumihito Masubuchi, Haruhiro Horiuchi, Tetsuya Amano
  • Patent number: 5869420
    Abstract: A rewritable thermal recording medium comprises a recording material containing a color former and a developer. Recording-erasing of information is performed on the basis of a change in the state of the recording material. The developer is formed of a compound capable of forming a liquid crystal phase and/or represented by general formula (I) given below ##STR1## wherein Ar denotes a noncondensed polycyclic structure consisting of a plurality of ring structures connected to each other via any of a single bond, a vinylene bond and an ethynylene bond or a condensation polycyclic structure, X denotes an ether bond, a thioether bond, an ester bond or an amide bond, Y is an acidic group, R is a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, or a substituted or unsubstituted alkynyl group, m is an integer of 1 to 3, and n is 0 or 1.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: February 9, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Katsuyuki Naito
  • Patent number: 5858913
    Abstract: Receiving element for use according to transfer printing, comprising on a support a receiving layer comprising a silver source, capable of being reduced by means of heat in the presence of a reducing agent, a binder and a stabilizer selected from the group of benzotriazoles, heterocyclic mercaptanes, sulphinic acids, 1,3,4-triazo-indolizines, 1,3-dinitroaryl compounds, 1,2,3-triazoles, phthalic acids and phthalic acid derivatives.The receiving element provides images with higher stability at elevated temperatures and upon exposure to light.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: January 12, 1999
    Assignee: Agfa-Gevaert
    Inventors: Jean-Marie Dewanckele, Geert Defieuw, Marcel Monbaliu, Wilhelmus Janssens
  • Patent number: 5854174
    Abstract: A substantially non-photosensitive recording material comprising a thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a compound with an unsaturated 5-membered heterocyclic ring consisting of nitrogen and carbon atoms with at least one of the nitrogen atoms having a hydrogen atom and none of the carbon atoms being part of a thione-group, the ring not being annulated with an aromatic ring system and the compound being exclusive of 1,2,4-triazole and substituted 1,2,4-triazole compounds, in reactive association with the substantially light-insensitive organic silver salt and the organic reducing agent and a binder, on a support; and a thermal image recording process therefor.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: December 29, 1998
    Assignee: Agfa-Gevaert
    Inventors: Bartholomeus Horsten, Johan Loccufier, Geert Defieuw, Luc Leenders
  • Patent number: 5849651
    Abstract: A reversible thermal recording medium comprises a composition containing a color former, a developer, a reversible material capable of reversibly changing the state of the composition by supplying heat energies with two different values, and, as required, a phase separation controller which permits changing the phase separation speed of the developer at temperatures in the vicinity of the melting point of the phase separation controller, at least 80% by weight of the reversible material being a sterol compound in which the carbon-to-carbon bond between 2- and 3-positions of the stroid skeleton is a single bond, the carbon-to-carbon bond between 3- and 4-positions of the steroid skeleton is a single bond, a hydroxyl group is attached to the carbon atom in at least the 3-position of the steroid skeleton, and a specified chemical structure is bonded at 16- and 17-positions of the stroid skeleton, and the phase separation controller being provided by a low molecular organic material, the maximum carbon chain leng
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: December 15, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Satoshi Takayama, Sawako Fujioka, Tetsuo Okuyama, Hideyuki Nishizawa, Hirohisa Miyamoto, Masami Sugiuchi
  • Patent number: 5827796
    Abstract: A thermal recording material comprising a support having thereon at least one layer containing an electron donating colorless dye, an electron accepting compound and a diaryloxyalkane derivative represented by the following general formulae (I) to (III)Ar.sup.1 O (CH.sub.2).sub.n OAr.sup.2 (I)Ar.sup.2 O--W--OAr.sup.3 (II)Ar.sup.2 OR--X--ROAr.sup.3 (III)wherein Ar.sup.1 represents an aryl group having at least one substituent selected from the group consisting of an alkoxyl group containing 2 or more carbon atoms, an alkoxycarbonyl group containing 3 or more carbon atoms, an aryloxyl group, an aryloxycarbonyl group, an alkenyl group containing 2 or more carbon atoms, an aryl group containing 4 or more carbon atoms an acyloxyl group containing 2 or more carbon atoms, a fulorine atom, a bromine atom, a carboxyl group, an alkylenedioxy group, a cycloalkyl group and a hydroxyl group; Ar.sup.2 and Ar.sup.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: October 27, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Iwakura, Takekatsu Sugiyama, Masato Satomura, Akira Igarashi
  • Patent number: 5821196
    Abstract: A novel thermally responsive record material is disclosed, comprising support having provided thereon in substantially contiguous relationship with electron donating dye precursor, an acidic developer material, a sensitizer, and a binder therefor. The sensitizer comprises at least two components, the first component comprising 2,2-bis(4-hydroxyphenyl)-4-methylpentane and the second component comprising a mixture of dimethyl terephthalate and 1,2-diphenoxyethane, the first component being in a range of weight ratios from 1:2 to 2:1 relative the second component, said second component comprising from 50 to 70% dimethyl terephthalate. The sensitizer is prepared by admixing the first component and the second component and grinding the sensitizer to a particle size of less than 1 micron.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: October 13, 1998
    Assignee: Appleton Papers Inc.
    Inventors: Mary Ellen Schulz, Michael Gerald Cove
  • Patent number: 5817599
    Abstract: The object of the present invention is to provide a reversible heat sensitive recording material capable of formation and erasion of images with a clear contrast and capable of retaining stable images with time under the conditions of daily living. A reversible heat sensitive recording material comprising a support and, provided thereon, a normally colorless or light colored dye precursor and a reversible color developer which causes reversible change of color tone in the dye precursor due to the difference in cooling rate after heating, characterized in that said reversible heat sensitive recording material contains at least one specific color erasion accelerator containing a long chain alkyl group.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: October 6, 1998
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Kazuyuki Iida, Hidekazu Sano, Jun Maruyama, Masahiro Higuchi, Yukiko Shibuya
  • Patent number: 5811369
    Abstract: A thermal recording medium comprising a substrate having thereon a recording layer containing a colorless or pale colored dye precursor, and a color developer reactable with the dye precursor to develop a color as main ingredients, wherein the color developer includes at least one compound of Formula (1): and the recording layer contains at least one methylolated fatty acid amide of Formula (2): ##STR1## (wherein X denotes oxygen atom or sulfur atom; and R denotes substituted or unsubstituted phenyl group, naphthyl group, aralkyl group, a lower alkyl group of 1 to 6 carbon atoms, a cycloalkyl group of 3 to 6 carbon atoms, or a lower alkenyl group of 2 to 6 carbon atoms. Z denotes a lower alkyl group of 1 to 6 carbon atoms or an electron attracting group. n is an integer from 0 to 4, and p is an integer from 1 to 5, satisfying n+p .ltoreq.5.).R.sub.1 -CONHCH.sub.2 OH (2)(wherein R.sub.1 denotes an alkyl group of 11 to 21 carbon atoms).
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: September 22, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5811368
    Abstract: In a thermal sensitive recording medium comprising a thermal sensitive color developing layer which includes a basic leuco dye and an organic color developer on a substrate, characterized by the said thermal color developing layer includes 0.01-0.9 parts of aminobenzenesulfonamide derivatives indicated by general formula (I) based on 1 part of color developer and also includes at least one kind of methylolated fatty acid amide indicated by general formula (II) in proportion of 0.01-2 parts based on 1 part of color developer. ##STR1## (wherein, "X" indicates an oxygen or sulfur atom, "R" indicates non-substituted or substituted phenyl group, naphthyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6 or lower alkenyl group of carbon number 2-6. "Z" indicates lower alkyl group of carbon number 1-6 or electron attractive group. "n" indicates an integer from 0 to 4 and "P" indicates an integer from 1 to 5, wherein satisfies the numerical formula of n+p.ltoreq.5)R.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: September 22, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tadakazu Fukuchi, Kaoru Hamada, Tomoaki Nagai, Nobuhiro Kudoh, Akio Sekine
  • Patent number: 5753586
    Abstract: A thermal sensitive recording sheet comprising a substrate having thereon a thermal sensitive color developing layer mainly composed of basic leuco dye and an organic color developer, characterized by said thermal sensitive developing layer includes derivatives of amino benzene sulfone amide indicated by general formula (I) as an organic color developer, and includes sulfone amide compound indicated by general formula (II) as a sensitizer by amount of 0.01-2 parts based on 1 part of the color developer indicated by general formula (I). ##STR1## wherein "X" indicates an oxygen or sulfur atom, "Y" indicates a lower alkyl group of carbon number 1-4 or electron attracting group and "m" indicates an integral number from 0 to 4. "R" indicates a non-substituted or a substituted phenyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6, lower alkenyl group of carbon number 2-6 or naphthyl group.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 19, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kaoru Hamada, Yoshimi Midorikawa, Yutaka Wakita, Tomoaki Nagai, Akio Sekine, Hiroshi Ueda
  • Patent number: 5753588
    Abstract: The present invention provides a heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor, the recording material being characterized in that, the basic dye comprises an indolyldiazaphthalide derivative of the formula (1), and the color acceptor comprises a diphenyl sulfone derivative of the formula (2) and/or a benzanilide derivative of the formula (3) ##STR1## wherein R.sub.1 to R.sub.8 are defined in the specification.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: May 19, 1998
    Assignee: New Oji Paper Company Limited
    Inventors: Takeshi Iida, Tatsuya Meguro, Tetsuo Tsuchida
  • Patent number: 5750464
    Abstract: There is described a novel thermographic recording film, and more specifically, a novel image-forming system incorporated therein comprising at least one layer and including and a Lewis acid material, a di- or triarylmethane thiolactone dye precursor, an acidic organic material, a binder and a thermal stabilizer.Thermographic recording films comprising the novel image-forming system of the present invention exhibit excellent thermal stability, and desirable minimum optical densities, indicative of substantially less premature image development at elevated environmental temperatures.Embodiments of the invention wherein the thermographic recording films further include a light insensitive organic silver salt, a reducing agent, a binder and, preferably, a toning agent, show substantially enhanced image density.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: May 12, 1998
    Assignee: Polaroid Corporation
    Inventors: Edward J. Dombrowski, Jr., Donna J. Guarrera, Robert L. Jones, Mark R. Mischke, John C. Warner, Jiyue Yang
  • Patent number: 5750463
    Abstract: There is described a novel thermographic recording film, and more specifically, a novel image-forming system incorporated therein which employs both thiolactone and silver reduction chemistries.Thermographic recording films comprising the novel image-forming system of the present invention exhibit excellent thermal sensitivity and visual color saturation, enhanced image density, and desirable visual minimum optical densities.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: May 12, 1998
    Assignee: Polaroid Corporation
    Inventors: Edward J. Dombrowski, Jr., Robert L. Jones, John C. Warner, Jiyue Yang
  • Patent number: 5733843
    Abstract: Discloses a thermal sensitive recording sheet which has features of high sensitivity, excellent heat resistance, excellent water proof and excellent durability to oil. The thermal sensitive color developing layer is mainly composed of a basic achromatic dye including the compound indicated by general formula (I) or (II), an organic color developer and a stabilizer indicated by general formula (III). And the said layer is arranged on a substrate and forms the thermal sensitive recording sheet.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: March 31, 1998
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5728646
    Abstract: A heat-sensitive recording material, comprising a heat-sensitive recording layer containing at least one acid hydrazide compound represented by the following general formula (I): ##STR1## wherein X.sub.1 and X.sub.2 each independently represent a hydrogen atom, a hydroxyl group, a halogen atom or an alkyl group or alkoxy group having 1 to 10 carbon atoms, A represents --CO-- or --SO.sub.2 --, n is 1 or 2, when n is 1, R.sub.1 represents an alkyl group, an aryl group, a hydroxyaryl group, an alkoxyaryl group, or an alkylaryl group having 1 to 22 carbon atoms and when n is 2, R.sub.1 represents an alkylene group or arylene group having 1 to 18 carbon atoms or a direct bond.
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: March 17, 1998
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Nobuhide Tominaga, Keiji Oya
  • Patent number: 5721190
    Abstract: A thermosensitive recording medium including a support, and at least one layer provided on the support, wherein one of the at least one layer is a thermosensitive layer capable of forming a color image when heated imagewise, and one of the at least one layer contains a zinc dithiocarbamate of the formula: ##STR1## wherein R.sup.1 and R.sup.2 stand independently from each other for an alkyl group having 1-4 carbon atoms or a phenyl group. The zinc dithiocarbamate is contained in the thermosensitive layer or an intermediate layer interposed between the thermosensitive layer and the support.
    Type: Grant
    Filed: July 2, 1996
    Date of Patent: February 24, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Shuji Miyamoto, Yasutomo Mori, Takeshi Akimoto
  • Patent number: 5703006
    Abstract: A thermosensitive recording medium is disclosed which includes a support, and a thermosensitive color-developing layer formed on the support and containing a leuco dye having a melting point of at least 200.degree. C. and a color developer having a melting point of at least 180.degree..
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: December 30, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasutomo Mori, Motoi Orihara, Kunihiko Hada, Shuji Miyamoto
  • Patent number: 5679615
    Abstract: A reversible heat-sensitive recording medium which includes at least a support and formed thereon a heat-sensitive recording layer including at least the following components: an electron-donating color-forming compound having a lactone ring, (b) an electron-accepting compound having a phenolic hydroxyl group, (c) at least one organic compound selected from compounds represented by formulae (I) to (V), and (d) a thermoplastic resin having an erasing action. The content of the thermoplastic resin having an erasing action is being from 15 to 70% by weight based on the total amount of components (a) to (d) Formulae (I) to (V) are as follows:R.sub.1 --CO--N(R.sub.2)R.sub.3 (I)R.sub.1 --CO--NH--R.sub.4 --NH--CO--R.sub.2 (II)R.sub.1 --CO--O--R.sub.2 (III)R.sub.1 --NH--CO--NH--R.sub.2 (IV)R.sub.1 --CO--R.sub.2 (V)wherein R.sub.1 represents an alkyl group, an aryl group, an alkenyl group, or a hydroxyalkyl group; R.sub.2 and R.sub.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: October 21, 1997
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Tatsuru Matsumoto, Kenichi Tanaka
  • Patent number: 5672560
    Abstract: The present invention is directed to a heat-sensitive imaging material that comprises a support on which is formed a heat-sensitive imaging layer. This imaging layer comprises a color-forming amount of a substantially colorless, finally divided noble metal salt of an organic acid, an organic reducing agent that is capable of a color-forming reaction with the noble metal salt under heating conditions to produce a colored image, and a stabilizer compound of formula (I) that mitigates the formation of non-imaging background color in the imaging layer: ##STR1## In formula (I), Z.sub.1, Z.sub.2, and Z.sub.3 each independently represents hydrogen, an alkali metal ion, an alkyl group comprising 1 to about 8 carbon atoms, an aralkyl or cycloalkyl group comprising 5 to about 10 carbon atoms, or an aryl group comprising 6 to about 15 carbon atoms; or Z.sub.1 and Z.sub.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: September 30, 1997
    Assignee: Labelon Corporation
    Inventor: Kent R. Rush
  • Patent number: 5668080
    Abstract: A novel thermally-responsive record material is disclosed comprising a support having provided thereon in substantially contiguous relationship an election donating dye precursor and a compound of the formula ##STR1##
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: September 16, 1997
    Assignee: Appleton Papers Inc.
    Inventors: Michael Gerald Cove, Mary Ellen Schulz
  • Patent number: 5665675
    Abstract: In a thermal recording medium or an optically recordable thermal recording medium including a substrate having thereon a recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor to develop a color as main ingredients, the color developer includes at least one aminobenzenesulfonamide derivative of Formula (1): ##STR1## (wherein X denotes oxygen atom or sulfur atom; and R denotes substituted or unsubstituted phenyl group, naphthyl group, aralkyl group, a lower alkyl group of 1 to 6 carbon atoms, cycloalkyl group, or a lower alkenyl group of 2 to 6 carbon atoms. Z denotes a lower alkyl group of 1 to 6 carbon atoms or an electron attracting group. n is an integer from 0 to 4.).
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Tomoaki Nagai, Kaoru Hamada, Akio Sekine
  • Patent number: 5663115
    Abstract: A thermal recording medium comprising a color former, a developer and a reversible material which can effect a reversible change in at lease a part of a composition system where thermal energies with two different values are supplied or where two different heat histories are provided, and a phase separation controller serves to change phase separation rate between the color former or the developer and the reversible material in the vicinity of its melting point, if necessary.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: September 2, 1997
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Katsuyuki Naito, Masami Sugiuchi, Satoshi Takayama, Hirohisa Miyamoto, Hideyuki Nishizawa, Sawako Fujioka, Akiko Watanabe, Tatsuo Nomaki
  • Patent number: 5661100
    Abstract: A thermal recording sheet wherein a compound of Formula (I) or (II) is contained in a thermal color developing layer including a basic colorless dye and an organic color developer as main ingredients: ##STR1## (wherein A denotes hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1, R.sub.2, and R.sub.3 are hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1 and R.sub.2 may combine with each other to form an aromatic ring. Y is sulfur or oxygen atom.), ##STR2## (wherein B denotes hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1, R.sub.2, and R.sub.3 are hydrogen atom, an alkyl group of C.sub.1 to C.sub.4, an alkoxy group of C.sub.1 to C.sub.4, hydroxy group, or nitro group. R.sub.1 and R.sub.2 may combine with each other to form an aromatic ring. Y is sulfur or oxygen atom.).
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: August 26, 1997
    Assignees: Nippon Paper Industries Co., Ltd., Yoshitomi Pharmaceutical Industries, Ltd.
    Inventors: Toshiaki Minami, Tomoaki Nagai, Kaoru Hamada, Akio Sekine, Ryoichi Kinishi, Ryuzo Minakami
  • Patent number: 5646088
    Abstract: A thermosensitive recording material having a high degree of background whiteness, superior light resistance without coloring of the background when exposed to the light, and a method of producing a stable coating liquid or forming a thermosensitive coloring layer and a protective layer are provided.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: July 8, 1997
    Assignee: Ricoh Co., Ltd.
    Inventors: Kunihiko Hada, Yasutomo Mori, Motoi Orihara, Shuji Miyamoto
  • Patent number: 5641724
    Abstract: This invention generally relates to a reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof which have high light-resisting characteristics, wherein coloring and decolorizing can be repeated suitably.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: June 24, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Takehito Yamaguchi, Kyoji Tsutsui, Masaru Shimada
  • Patent number: 5637550
    Abstract: A heat-sensitive recording material suited for use in direct thermal imaging and having image-stabilization properties which material contains in a binder on a support (i) a substantially light-insensitive organic silver salt capable of thermally activated reduction to silver in thermal working relationship with (ii) at least one reducing agent capable of reducing the substantially light-insensitive organic silver salt when thermally activated, characterized in that the recording material contains in conjunction, preferably in admixture, with the reducing agent(s) at least one colourless photo-oxidizing substance that on exposure to ultraviolet (UV) radiation, such as present in daylight or artificial lighting, yields free radicals capable of inactivating said reducing agent(s) by oxidation, thereby rendering said reducing agent(s) incapable of reducing said organic silver salt to silver.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: June 10, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Luc Leenders, Leo Oelbrandt
  • Patent number: 5624882
    Abstract: There is disclosed a coating composition for the preparation of a CF sheet (i.e. a receiving sheet) of a carbonless paper copying system comprising a CF sheet and a CB sheet (i.e. a donating sheet). The coating composition comprises a color developer and an extender, wherein the extender comprises a particulate inorganic material which has been modified by treatment with a treating agent which has (i) a non-polar hydrophobic portion comprising at least one hydrocarbon group having a chain length of from 8 to 30 carbon atoms and (ii) a polar portion which is capable of binding with sites on the surface of the pigment particles.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: April 29, 1997
    Assignee: ECC International Limited
    Inventor: Patrick A. C. Gane
  • Patent number: 5614462
    Abstract: There is disclosed a coating composition for the preparation of a CF sheet (i.e. a receiving sheet) of a carbonless paper copying system comprising a CF sheet and a CB sheet (i.e. a donating sheet). The coating composition comprises a color developer and an extender, wherein the extender comprises a particulate inorganic material which has been modified by treatment with a treating agent which has (i) a non-polar hydrophobic portion comprising at least one hydrocarbon group having a chain length of from 8 to 30 carbon atoms and (ii) a polar portion which is capable of binding with sites on the surface of the pigment particles.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: March 25, 1997
    Assignee: ECC International Limited
    Inventor: Patrick A. C. Gane
  • Patent number: 5612279
    Abstract: In an optical recording sheet having a thermal recording layer containing a colorless or pale colored dye precursor and a color developer reactable with the dye precursor upon heating to develop a color, a dimerized or trimerized urea compound is used as the color developer to obtain an optical recording sheet which is superior in ground color stability and an optical recording sheet having a reversible recordability.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: March 18, 1997
    Assignee: Nippon Paper Industries, Ltd.
    Inventors: Toshimi Satake, Toshiyuki Takano, Hideki Hayasaka, Yukiko Uehori, Tomoaki Nagai
  • Patent number: 5607894
    Abstract: The heat-sensitive recording material of the present invention comprises a heat-sensitive recording layer containing at least one resorcylic anilide derivative represented by the following general formula: ##STR1## wherein R.sub.1 represents an alkyl or alkoxy, group having 1 to 4 carbon atoms and R.sub.2 represents a hydrogen atom or an alkyl or alkoxy group having 1 to 4 carbon atoms.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 4, 1997
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Mitsuo Akutsu, Nobuhide Tominaga, Keiji Oya, Athuo Tomita, Kouichi Shigeno
  • Patent number: 5605873
    Abstract: A pressure-sensitive, laser printer heat-resistant verification system for preventing unauthorized photoduplication of security documents comprising a support bearing an information area comprising a visible principal image, and a verification area comprising a localized, autogenous coating of a pressure-sensitive chromogenic composition for producing a visible colored image by external pressure. The chromogenic composition comprises (a) pressure-rupturable microcapsules containing a chromogen and (b) a color developer capable of reacting with the chromogen to form a visible image. The pressure-rupturable microcapsules and color developer are substantially coextensive on the support, and the verification area is spaced apart from the information area.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: February 25, 1997
    Assignee: Wallace Computer Services, Inc.
    Inventor: John C. H. Chang
  • Patent number: 5604176
    Abstract: A heat-sensitive recording material comprises a recording layer containing a colorless or light-colored basic dye and a developing agent on a support. The recording layer further contains a polyethylene having a melting point not lower than 60.degree. C., which is obtained as an emulsion not comprising a surfactant.The heat-sensitive recording material may be prepared by coating on a support an aqueous coating composition, which contains a colorless or light-colored basic dye and a developing agent together with a polyethylene emulsion comprising a polyethylene having a melting point not lower than 60.degree. C. but no surfactant (e.g. emulsifier), to form a recording layer.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: February 18, 1997
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Yoshihiro Shimizu, Masato Kawai, Yasuyoshi Morita, Kohei Michikawa, Takehiro Minami
  • Patent number: 5558699
    Abstract: A thermochromic color-memory compositions exhibiting high color contrast between high color density in a colored state and sufficiently low color density in a decolored state with high freedom of selection of the reaction medium, and highly useful as a thermochromic material. The thermochromic color-memory composition comprises a homogeneous solubilized mixture of essential three components of (a) an electron-donating color-developing organic compound, (b) an electron-accepting compound, and (c) a reaction medium for controlling a color reaction of the component (a) with the component (b); the component (c) being selected from aliphatic ketones of 10 to 22 total carbons and aryl alkyl ketones of 12 to 24 total carbons; and the composition changing the color thereof with a large hysteresis width (.DELTA.H) of from 8.degree. C. to 80.degree. C.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: September 24, 1996
    Assignee: The Pilot Ink Co., Ltd.
    Inventors: Akio Nakashima, Yutaka Shibahashi
  • Patent number: 5559075
    Abstract: A heat-sensitive recording material suited for use in direct thermal imaging by means of an information-wise energized heating element, which recording material comprises on the same side of a support, called the heat-sensitive side, one or more binder layers containing a substantially light-insensitive metal salt in thermal working relationship with at least one organic reducing agent, characterized in that said recording material also comprises an acid-sensitive leuco dye transformable into dye by means of an acid-reacting compound serving as dye developer that stands in thermal working relationship with said leuco dye.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: September 24, 1996
    Assignee: Agfa-Gevaert
    Inventors: Luc Leenders, Luc Bastiaens
  • Patent number: 5525572
    Abstract: An improved carbonless copy paper for use in magnetic image character recognition (MICR). Carbonless copy paper according to the present invention contains a coated front (CF) layer which contains a latex binding component. The improved carbonless copy paper of the present invention provides a more durable CF coating which when imprinted with indicia prevents sorting errors in magnetic image character recognition.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: June 11, 1996
    Assignee: Moore Business Forms, Inc.
    Inventor: Rodney E. Williams
  • Patent number: 5521138
    Abstract: A reversible thermosensitive coloring composition is composed of an electron-donor coloring compound; an electron-acceptor compound which is capable of producing a colored material with a regularly aggregated structure in the electron-doner coloring compound at a color development initiation temperature to obtain a color development state, and is capable of crystallizing out of the colored material at a decolorization initiation temperature which is lower than the color development initiation temperature; and an organic compound serving as a decolorization-accelerating agent capable of inducing the destruction of the regularly aggregated structure of the colored material to accelerate the decolorization of the composition. A reversible thermosensitive coloring recording medium is composed of a support and a recording layer formed thereon, which contains the above-mentioned reversible thermosensitive coloring composition.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: May 28, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaru Shimada, Hiroshi Goto, Eiichi Kawamura, Shoji Maruyama, Keishi Kubo, Kyoji Tsutsui
  • Patent number: 5518982
    Abstract: A thermosensitive recording medium comprising a thermosensitive recording layer containing an electron-donating color forming substance, an electron-accepting substance, and a color developability-improving agent is disclosed, said color developability-improving agent being a solid solution composed of two or more compounds containing at least one color developability-improving compound and having a single intrinsic melting point of not less than room temperature, preferably 60.degree. C. or higher. The recording medium exhibits well-balanced performance among color developing sensitivity, static color developability, image stability, and stability before recording.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: May 21, 1996
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Masaji Inagaki, Kikuo Tsuchiya, Ayuri Miyake, Shingo Araki
  • Patent number: 5480765
    Abstract: A recording material employing an electron-donating achromatic dye and an electron-accepting compound, which further contains at least one triarylamine derivative represented by general: formula (1), (2), (3) or (4); ##STR1## wherein all the symbols are defined in the specification.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: January 2, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Masanobu Takashima, Masato Shimazaki, Ken Iwakura, Tomohiro Kodama
  • Patent number: 5478792
    Abstract: A heat-sensitive recording material with a heat-sensitive recording layer comprising a modified polyvinyl alcohol containing 2.5 to 8 mole % of a carboxyl group-containing monomer units and having a degree of saponification of 40 to 65 mole % and a viscosity average degree of polymerization. of 50 to 500; a dispersing agent comprising the above modified polyvinyl alcohol for heat-sensitive dyes or color developing agents that can make the heat-sensitive dyes form color upon heating; and a process for producing aqueous dispersions which comprises dispersing a heat-sensitive dye or a color developing agent that can make the heat-sensitive dye form color upon heating, in an aqueous medium with a dispersing agent of the above modified polyvinyl alcohol.
    Type: Grant
    Filed: September 13, 1994
    Date of Patent: December 26, 1995
    Assignee: Kuraray Co., Ltd.
    Inventors: Eriko Seno, Tetsuya Katayama, Hirotoshi Miyazaki
  • Patent number: 5472930
    Abstract: A thermosensitive recording material contains a mono-, oligo- or polysaccharide and a catalyst in one or more binder layers arranged on a transparent support. A black-and-white image with high optical density, good grey step reproduction, great sharpness and good stability is formed when the material is heated imagewise, e.g. by means of a thermohead.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: December 5, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Wolfgang Podszun, Herman Uytterhoeven
  • Patent number: 5466655
    Abstract: A heat-sensitive recording material comprising a support and a heat-sensitive recording layer containing a leuco dye and a developer, formed on one side of the support, wherein the heat-sensitive recording layer contains an ultraviolet ray-absorbing agent, said ultraviolet ray-absorbing agent being a dimer ultraviolet ray-absorbing agent.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: November 14, 1995
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Naomasa Koike, Akira Nakano, Takao Kosaka, Naoya Sakata
  • Patent number: 5446009
    Abstract: In a thermal recording sheet including an intermediate layer, and a thermal color developing layer containing a leuco dye type chromogenic component containing a leuco dye and an organic color developer as main ingredients and a metal chelate type chromogenic component containing an electron acceptor and an electron donor as main ingredients, stacked on a substrate, the intermediate layer contains a pigment having an oil absorption of 100 ml/100 g or less measured according to JIS K 5101, and the thermal color developing layer contains at least one of compounds of Formula (I) and Formula (II) as an organic color developer, a metal double salt of higher fatty acid having 16 to 35 carbon atoms as an electron acceptor, and a polyhydric hydroxy aromatic compound of Formula (III) as an electron donor, whereby providing a thermal recording sheet which is superior in dynamic sensitivity, background color, image stability such as oil resistance and plasticizer resistance, and print adaptability: ##STR1## wherein R is
    Type: Grant
    Filed: November 17, 1993
    Date of Patent: August 29, 1995
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Toshiaki Minami, Tadakazu Fukuchi
  • Patent number: 5446010
    Abstract: A thermosensitive recording material having a high thermosensitivity and useful for recording thereon colored images having high storage persistency, comprises a thermosensitive colored image-forming layer formed on a surface of a substrate sheet and comprising a colorless dye precursor; a color-developing aromatic compound having, per molecule thereof, at least one arylsulfonylureido group of the formula (I): ##STR1## wherein R.sup.1 =aromatic group unsubstituted or substituted with at least one of lower alkyl and lower alkoxyl group and hologen atoms; a sensitizing aromatic amide compound of the formula (II): ##STR2## wherein Ar.sup.1, Ar.sup.2 =non-substituted phenyl or naphthyl group or substituted phenyl or naphthyl group with 1 to 3 substituent selected from aryl, aryloxy, aralkyl, alkyl, alkoxyl, trihalogenomethyl, nitro and alkylamino groups and halogen atoms; and a binder.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: August 29, 1995
    Assignee: New Oji Paper Co., Ltd.
    Inventors: Kunitaka Toyofuku, Akiko Iwasaki
  • Patent number: 5446011
    Abstract: A thermosensitive recording material capable of being imagewise colored when heated, having a support, and a thermosensitive recording layer formed thereon which contains an N-substituted indole or an aromatic polyhydroxy compound, a carbonyl compound, and an acid material.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: August 29, 1995
    Assignee: Ricoh Company, Ltd.
    Inventors: Kunio Hayakawa, Masafumi Torii
  • Patent number: 5444036
    Abstract: A thermosensitive recording material for recording thereon clear colored images having an excellent storage persistency over a long time, comprises a thermosensitive colored image-forming layer formed on a substrate and comprising a colorless dye precursor, a binder and a color developing agent comprising at least one compound having at least one group of the formula (I): ##STR1## wherein R = unsubstituted aromatic group or substituted aromatic group having at least one substituent selected from alkyl, alkoxyl and halogen, and the thermosensitive colored image-forming layer further comprises an additive comprising at least one member selected from the compounds of the formulae (II) and (III): ##STR2## wherein R.sup.1, R.sup.2, R.sup.3 = alkyl, alkoxyl, aralkyl, aryl, aryloxy, nitro, acetylamino, acetoacetylamino, halogen or hydrogen; and Ar.sub.1, Ar.sub.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: August 22, 1995
    Assignee: New Oil Paper Co., Ltd.
    Inventors: Akiko Iwasaki, Kunitaka Toyofuku, Kyoko Uchida, Masatoshi Fujino
  • Patent number: 5439869
    Abstract: New thermoreactive recording materials contain a mixture containing at least one specifically modified bisphenol carboxylic acid and at least one basic compound. They are distinguished by good stabilization of the color even upon extended storage, good light stabilities and excellent stabilities to water, plasticizers, greases and ingredients of text-marking pens.
    Type: Grant
    Filed: May 28, 1993
    Date of Patent: August 8, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Klug, Pieter Ooms, Christian Rasp
  • Patent number: 5418206
    Abstract: An abrasion resistant thermosensitive recording element having high gloss, and improved abrasion resistance and process of preparing said element are described. The element comprises (a) a support, (b) a first layer comprising an organic polymeric binder and a substantially colorless electron donating dye precursor, and (c) a second layer comprising an organic polymeric binder compatible with the binder in (b), an electron accepting compound capable of forming color by reaction with said dye precursor, and a crosslinking agent, wherein the first layer is interposed between the support and the second layer. These elements have wide application in the printing industry.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: May 23, 1995
    Assignee: International Paper Company
    Inventor: Albert H. Smith