Having Nonchromogenic Liquid Spread-control Or Transfer-improving Agent Or Component, Color Modifier, Stabilizer Or Preservative Patents (Class 503/209)
  • Patent number: 4792542
    Abstract: A recording material is described comprising an electron donating colorless dye, an electron accepting compound, and at least one compound represented by formula (I), (II), or (III)Ar.sub.1 O--R--SAr.sub.2 (I)Ar.sub.1 S--R--SAr.sub.2 (II)Ar.sub.1 S--R--X--Ar.sub.2 (III)wherein Ar.sub.1 and Ar.sub.2 each represents a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic ring, R is a divalent group containing from 1 to 10 carbon atoms, and X represents --COO-- group or ##STR1## group.
    Type: Grant
    Filed: November 10, 1986
    Date of Patent: December 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanobu Takashima, Masato Satomura, Ken Iwakura, Akira Igarashi
  • Patent number: 4792543
    Abstract: A pressure-sensitive recording sheet is disclosed. The sheet comprises a support having provided thereon a color-forming layer containing microcapsules prepared by encapsulating oil droplets having dissolved therein one or more substantially colorless color formers, wherein said microcapsules contain a compound represented by formula (I) ##STR1## wherein A and B each represents an alkylene group having from 1 to 12 carbon atoms or an alkenylene group having from 2 to 12 carbon atoms; R represents an alkyl group having from 1 to 18 carbon atoms; and n represents an integer of from 5 to 50.
    Type: Grant
    Filed: June 17, 1987
    Date of Patent: December 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shojiro Sano, Keiso Saeki
  • Patent number: 4791094
    Abstract: A recording sheet comprising microcapsules containing a substantially colorless electron donating dye, a diarylaminofluoran derivative, and a quinoline derivative represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkoxy group having from 1 to 8 carbon atoms, an aryloxy group having from 6 to 18 carbon atoms or an aralkyloxy group having from 7 to 18 carbon atoms; R.sub.2 represents a hydrogen atom or a methyl group; and n is an integer of 1 to 10. The recording sheet has a layer of microcapsules which does not turn blue on the surface thereof and does not experience any color staining where a surface of the coating is cut.
    Type: Grant
    Filed: December 1, 1986
    Date of Patent: December 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shojiro Sano, Keiso Saeki
  • Patent number: 4791095
    Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive color-forming layer which contains a colorless or slightly colored electron-donating dye precursor and an electron-accepting compound capable of reacting with the electron-donating dye precursor to form color, wherein the heat-sensitive color-forming layer further contains at least one of the compounds represented by the general formulae (I) to (VI) shown in the specification and at least one of the compounds represented by the general formulae (VIII) to (XII) shown in the specification, or wherein the heat-sensitive color-forming layer further contains about 0.5 wt % to less than about 20 wt %, based on the electron-accepting compound, of the compound represented by the general formula (XIII) shown in the specification. The heat-sensitive recording material obtained provides a high density color image and does not undergo a decrease in heat responsibility and an increase in background fog formation.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: December 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kensuke Ikeda, Ken Iwakura
  • Patent number: 4771033
    Abstract: A heat-sensitive record material having on a base sheet a recording layer which comprises a basic colorless chromogenic material and an acceptor in the state of that the colorless chromogenic material is contacted with the acceptor by heating to produce color images. The recording layer comprises at least one phenol compound represented by the following formula (I) together with the colorless chromogenic material and the acceptor, ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 radicals is hydrogen, C.sub.1-8 alkyl or C.sub.5-8 cycloalkyl, but at least one of R.sub.1, R.sub.2 and R.sub.3 radicals is C.sub.5-8 cycloalkyl; and each of R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 radicals is hydrogen or C.sub.1-8 alkyl.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: September 13, 1988
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Yoshihiro Shimizu, Naoto Arai
  • Patent number: 4764501
    Abstract: A heat-sensitive recording material containing a special sensitizer in a heat-sensitive recording layer is excellent in thermal response and sensitivity.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: August 16, 1988
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Haruhiko Ikeda, Masahiro Higuchi, Shigetoshi Hiraishi
  • Patent number: 4764500
    Abstract: A thermosensitive recording sheet having a coated film containing a color-forming lactone compound, an acidic substance and a sensitizer. The sensitizer is at least one aliphatic carboxylic acid ester represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and each represents an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group, an aryl group, a group of the formula --C.sub.n H.sub.2n --Ar in which n is an integer of 1 to 8 and Ar is an aryl group, or a group of the formula --C.sub.n H.sub.2n --CO--Ar in which n and Ar are as defined; R.sup.3 represents a group of the formula --C.sub.n H.sub.2n --in which n is as defined; R.sup.4 and R.sup.5 are identical or different and each represents an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group, a group of the formula --C.sub.n H.sub.2n --Ar in which n and Ar are as defined, or a group of the formula --C.sub.n H.sub.2n --CO--Ar in which n and Ar are as defined; and R.sup.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: August 16, 1988
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shingo Araki, Ryugo Maeda, Masaji Inagaki, Teijiro Kitao, Shigeki Ueno
  • Patent number: 4761396
    Abstract: In a heat-sensitive recording material comprising a colorless or pale-colored basic dye and an electron accepting reactant material which is reactive with the basic dye to form a color when contacted therewith, and comprising at least one of the specific phthalide derivatives as the basic dye, the heat-sensitive recording material characterized in that at least one compound selected from the group consisting of the specific fluorene derivatives and the specific p-phenylenediamine derivatives is further contained in the recording material.
    Type: Grant
    Filed: February 5, 1987
    Date of Patent: August 2, 1988
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Nobuo Kanda, Kazuko Hirahara, Mitsuru Kondo
  • Patent number: 4749679
    Abstract: This invention discloses a heat sensitive recording material having a heat sensitive layer on a support; either of a color forming material or a developer which are contained in the heat sensitive layer is encased in a microcapsule. Since a plasticizer for a wall material of the microcapsule and a compound having an effect to depress the melting point of at least one member out of developers, a color forming reaction is carried out smoothly under a recording condition, therefore, a density of an obtained image is sufficient. Especially good results are obtained when a macromolecule substance selected from a group of polyurethane, polyurea, polyamide, polyester and polycarbonate is used as a wall material of the microcapsule. A coloring reaction assistant may be contained in any place of the heat sensitive layer.A preferable plasticizer can be selected from a group of phenols, alcohols, ureas, sulfonamides, carbamates and aromatic methoxy compounds.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: June 7, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shohei Yoshida, Toshiaki Endo, Sumitaka Tatsuta, Toshimasa Usami
  • Patent number: 4746644
    Abstract: A recording material comprising a support having provided thereon, microcapsules containing a basic leuco dye dissolved in an organic solvent is disclosed. The microcapsules further contains at least one compound selected from the group consisting of 2-mercaptobenzothiazoles, guanidines, thioureas, 2-mercaptoimidazolines and thiurams. The recording material is free from coloration due to exposure to light and provides a recorded image of high density and high contrast.
    Type: Grant
    Filed: October 9, 1985
    Date of Patent: May 24, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masataka Kiritani, Toshiharu Tanaka, Toshimasa Usami
  • Patent number: 4745097
    Abstract: A microcapsule-coated paper for a pressure-sensitive copying paper comprising a base paper having coated thereon consecutively (a) a subbing layer and (b) a coated layer including microcapsules wherein said subbing layer is capable of aggregating said microcapsules.
    Type: Grant
    Filed: March 11, 1986
    Date of Patent: May 17, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Maekawa, Yasuhiro Ogata
  • Patent number: 4742042
    Abstract: There is disclosed a thermosensitive recording material improved in thermal response and image retention which comprises a support and, provided thereon, a thermosensitive recording layer containing a generally colorless or slightly colored dye precursor and a developer which, upon being heated, reacts with said dye precursor to develop color, wherein said thermosensitive recording layer contains as sensitizer a compound selected from a group consisting of p-benzylbiphenyl, diaryl esters of adipic acid, ##STR1## (wherein R represents a substituted or unsubsitituted aralkyl group), ##STR2## (wherein R.sub.1 and R.sub.2 each represents an alkyl, aralkyl, or aryl group), and ##STR3## and said developer is bis(3-allyl-4-hydroxyphenyl)sulfone.
    Type: Grant
    Filed: January 27, 1986
    Date of Patent: May 3, 1988
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Shigetoshi Hiraishi, Naomasa Koike, Kazuyoshi Kondo, Mitsuru Fuchigami
  • Patent number: 4737484
    Abstract: A heat-sensitive recording material is described, comprising a support having provided thereon a recording layer comprising a diazo compound and a coupling component, wherein the improvement comprises including said diazo compound and at least one compound selected from a polymerizable compound containing an ethylenically unsaturated bond therein or at least one compound capable of releasing a free radical upon exposure to light together in microcapsules.
    Type: Grant
    Filed: April 19, 1985
    Date of Patent: April 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masayuki Iwasaki, Hiroshi Kamikawa, Toshimasa Usami
  • Patent number: 4732614
    Abstract: Correction compositions for correcting markings provided on the surface of a pressure-sensitive chemical recording medium carrying a developer material which comprises an acidic developer by interaction of the developer material with a color-providing material. The compositions comprise a substantially uniform dispersion of an opacifying pigment, a polymeric film-forming material, and a Lewis acid. The composition is applied to a marking to provide a film which covers the marking, and a visible correcting marking can be provided on the film by applying a pattern of color-providing material corresponding to the corrected marking to the film.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: March 22, 1988
    Assignee: The Gillette Company
    Inventors: Lamar E. Brooks, Sue R. Liu
  • Patent number: 4731354
    Abstract: A thermosensitive recording material is disclosed, which comprises a support material and a thermosensitive coloring layer formed thereon comprising a leuco dye, a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, and a diether compound having the following general formula (I): ##STR1## wherein R represents a straight or branched hydrocarbon having 2 to 12 carbon atoms, including 1 to 4 double bonds therein, X and Y each represent an alkyl group having 1 to 6 carbon atoms; an alkoxy group having 1 to 6 carbon atoms; halogen; an aryl group; an aralkyl group; an acyloxy group (R'COO--), wherein R' is an alkyl group having 1 to 6 carbon atoms; an aryloxy group; or an aralkyloxy group; and m and n each represent an integer of 1 to 3.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: March 15, 1988
    Assignee: Ricoh Company, Ltd.
    Inventors: Keishi Taniguchi, Hiromi Huruya
  • Patent number: 4721701
    Abstract: A thermosensitive recording sheet having a thermosensitive color developing layer containing a basic leuco dye and an organic color developer, said organic color developer consisting of at least partly of a halogen-substituted benzoic acid zinc salt represented by the following general formula ##STR1## wherein X.sub.1 represents a halogen atom, X.sub.2 represents a hydrogen or halogen atom, and R.sub.1, R.sub.2 and R.sub.3, independently from each other, represent a hydrogen atom or an alkyl, alkoxy, cycloalkyl, nitro, cyano or hydroxyl group.
    Type: Grant
    Filed: December 30, 1985
    Date of Patent: January 26, 1988
    Assignee: Jujo Paper Co., Ltd.
    Inventors: Toshimi Satake, Toshiaki Minami, Tomoaki Nagai, Fumio Fujimura
  • Patent number: 4719198
    Abstract: A heat sensitive recording sheet including p-benzyloxybenzoic acid benzylester and filler in its color-forming layer which contains a basic colorless or pale-colored chromogenic dyestuff and an organic color-developing agent whereby a heat sensitive recording sheet having a highly stable developed image against oily substances such as hair oil, sweat, etc. is provided without deteriorating the fundamental qualities of the heat sensitive recording sheet.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: January 12, 1988
    Assignee: Jujo Paper Co., Ltd.
    Inventors: Masuhiko Sato, Toshimi Satake
  • Patent number: 4713364
    Abstract: A heat-sensitive recording material excellent in stability of recorded images is disclosed, which comprises a support having formed thereon a heat-sensitive recording layer comprising a colorless or pale-colored basic dye and a color developer capable of forming a color upon coming into contact with the basic dye, wherein said heat-sensitive recording layer further comprises at least one compound selected from the compounds represented by following formulae (I) and (II): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, and R.sub.8 independently represent a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms.
    Type: Grant
    Filed: March 6, 1986
    Date of Patent: December 15, 1987
    Assignee: Kanzaki Paper Mfg. Co., Ltd.
    Inventor: Naoto Arai
  • Patent number: 4708947
    Abstract: This invention relates to a water resistant composition which comprises (A) polyvinyl alcohol, (B) a chitosan of which aqueous 1% solution has a viscosity not greater than 70 centipoise at 20.degree. C. and (C) an aldehyde compound, as well as a heat-sensitive recording sheet which comprises said composition. The composition has excellent water resistant properties and the heat-sensitive recording sheet has improved color forming properties and excellent resistance to water and solvents.
    Type: Grant
    Filed: January 2, 1986
    Date of Patent: November 24, 1987
    Assignee: Kuraray Co., Ltd.
    Inventors: Hitoshi Maruyama, Isao Ono, Hiroji Kohno, Junnosuke Yamauchi, Takuji Okaya
  • Patent number: 4707463
    Abstract: Heat-sensitive recording materials comprising a colorless or light-colored dye precursor and a color developer capable of developing a color of the dye precursor, upon reaction with said dye precursor with heating, further contain as sensitizers specific styryl-containing compounds. By incorporating these specific sensitizers, the heat-sensitive recording materials provide excellent thermal response and high sensitivity.
    Type: Grant
    Filed: August 28, 1986
    Date of Patent: November 17, 1987
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Haruhiko Ikeda, Shigetoshi Hiraishi
  • Patent number: 4704379
    Abstract: A pressure sensitive manifold sheet characterized in that a chelate record material comprising an iron (III) compound and/or a vanadium compound, and an aromatic compound having at least one of hydroxyl group and mercapto group on the aromatic ring in combination therewith is used further in combination with an infrared absorbing organic compound.
    Type: Grant
    Filed: March 3, 1986
    Date of Patent: November 3, 1987
    Assignee: Kanzaki Paper Manufacturing Co. Ltd.
    Inventors: Shunsuke Shioi, Kazuyuki Shinmitsu, Nobuo Kanda, Mitsuru Kondo, Makoto Miyake
  • Patent number: 4689644
    Abstract: A pressure-sensitive recording sheet capable of providing colored images by a reaction of a substantially colorless electron donating dye precursor and an electron accepting developer is described, wherein a layer comprising the electron accepting developer of the pressure-sensitive recording sheet contains (1) a metal salt of an aromatic carboxyl acid, and (2) at least one of a 2-mercaptobenzothiazole and a 2-mercaptobenzimidazole.
    Type: Grant
    Filed: February 27, 1986
    Date of Patent: August 25, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shojiro Sano, Keiso Saeki
  • Patent number: 4688058
    Abstract: A highly sensitive thermal recording material excellent in response to heat is obtained by incorporating as a sensitizer at least one compound into a thermal printing material comprising a usually colorless or light-colored dye precursor and a developer which reacts with each other to develop color on heating, said compound being selected from the following compounds represented by the following general formulas (I), (II) and (III): ##STR1##
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: August 18, 1987
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Haruhiko Ikeda, Shigetoshi Hiraishi
  • Patent number: 4682193
    Abstract: A recording material is described, containing (A) an electron-donating colorless dye and (B) an electron-accepting compound, wherein the electron-accepting compound is a compound represented by formula (I) ##STR1## wherein R.sup.1 represents an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, or an aryloxyalkyl group, Y.sup.1 is an alkyl group, an alkoxyl group, a halogen atom, or a hydrogen atom, and m is 0, 1 or 2.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: July 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Iwakura, Takekatsu Sugiyama
  • Patent number: 4675705
    Abstract: An improved heat sensitive coating composition and heat sensitive paper for thermal printing containing the composition are disclosed. The composition contains a color-forming amount of a finely divided solid colorless or pale colored chromogenic fluoran dyestuff, a color-developing amount of a finely divided mixture of benzyl p-hydroxy benzoate and a halogenated derivative of 4,4'-isopropylidenediphenol and a carrier composition.
    Type: Grant
    Filed: June 10, 1985
    Date of Patent: June 23, 1987
    Assignee: Labelon Corporation
    Inventors: Barry L. Marginean, Warren A. Hookway, Jr.
  • Patent number: 4672401
    Abstract: A heat-sensitive recording material contains, in its heat-sensitive, color-developing layer comprising a leuco dye and an organic acid that reacts with said leuco dye to develop color upon heating, a hydrocarbon compound melting at a temperature in the range from 50.degree. C. to 200.degree. C. and selected from benzylbiphenyls, alkyl-substituted benzylbiphenyls, hydrogenated benzylbiphenyls, hydrogenated alkyl-substituted benzylbiphenyls, hydrogenated terphenyls and hydrogenated alkyl-substituted terphenyls. With its quick thermal response, this material is suitable for high-speed recording.
    Type: Grant
    Filed: June 12, 1985
    Date of Patent: June 9, 1987
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Yasuharu Yamada, Tadashi Komoto, Hidehiko Koishi
  • Patent number: RE32466
    Abstract: Disclosed is a heat-sensitive color-forming recording material which comprises a recording layer comprising a particulate phenolic color developer and a particulate leuco pigment, which are dispersed in a binder independently from each other, wherein the phenolic color developer and/or leuco pigment is present in the form of compatible solid particles with a substantially inactive organic solid medium having a melting or softening point lower than that of the phenolic color developer and/or leuco pigment and said organic solid medium is present in said compatible solid particles in an amount .[.2 to 250 times as large as.]. .Iadd.of 0.2 to 250% by weight, based on .Iaddend.the amount of the phenolic color developer and/or leuco pigment on the weight base. This heat-sensitized color-forming recording material is highly sensitive without substantial increase of the fog density.
    Type: Grant
    Filed: June 30, 1986
    Date of Patent: July 28, 1987
    Assignee: Mita Industrial Co Ltd.
    Inventor: Nobuhiro Miyakawa