Other Rare Earth (i.e., Sc,y,ce,pr,nd,pm,sm,eu,gd,tb,dy,ho,er,tm,yb,lu) And Alkaline Earth (i.e., Ca,sr,ba,ra) Patents (Class 505/779)
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Patent number: 8843126Abstract: A programmable device generates a test signal indicative of a RF signal and receives a processed test signal indicative of the test signal after processing thereof by one of a RF transmission system and a RF receiving system. The programmable device performs a comparison between the processed test signal and calibration data, and generates a report based on the comparison. A hardwire signal router provides the test signal to one of the RF transmission system and the RF receiving system, and provides the processed test signal to the programmable device. The router includes a first switching mechanism and a second switching mechanism operating in a coordinated fashion to define one of a first state for testing the RF transmission system and a second state for testing the RF receiving system.Type: GrantFiled: August 3, 2012Date of Patent: September 23, 2014Assignee: The United States of America as represented by the Secretary of the NavyInventor: Curtis Z. Richard
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Patent number: 8716187Abstract: The films of this invention are high temperature superconducting (HTS) thin films specifically optimized for microwave and RF applications. In particular, this invention focuses on compositions with a significant deviation from the 1:2:3 stoichiometry in order to create the films optimized for microwave/RF applications. The RF/microwave HTS applications require the HTS thin films to have superior microwave properties, specifically low surface resistance, Rs, and highly linear surface reactance, Xs, i.e. high JIMD. As such, the invention is characterized in terms of its physical composition, surface morphology, superconducting properties, and performance characteristics of microwave circuits made from these films.Type: GrantFiled: December 21, 2010Date of Patent: May 6, 2014Assignee: Superconductor Technologies, Inc.Inventors: Brian Moeckly, Viktor Gliantsev, Shing-jen (Luke) Peng, Balam Willemsen
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Patent number: 7867950Abstract: The films of this invention are high temperature superconducting (HTS) thin films specifically optimized for microwave and RF applications. In particular, this invention focuses on compositions with a significant deviation from the 1:2:3 stoichiometry in order to create the films optimized for microwave/RF applications. The RF/microwave HTS applications require the HTS thin films to have superior microwave properties, specifically low surface resistance, Rs, and highly linear surface reactance, Xs, i.e. high JIMD. As such, the invention is characterized in terms of its physical composition, surface morphology, superconducting properties, and performance characteristics of microwave circuits made from these films.Type: GrantFiled: December 22, 2005Date of Patent: January 11, 2011Assignee: Superconductor Technologies, Inc.Inventors: Brian Moeckly, Viktor Gliantsev, Shing-jen (Luke) Peng, Balam Willemsen
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Publication number: 20100149707Abstract: A method of controlling fault currents within a utility power grid is provided. The method may include coupling a superconducting electrical path between a first and a second node within the utility power grid and coupling a non-superconducting electrical path between the first and second nodes within the utility power grid. The superconducting electrical path and the non-superconducting electrical path may be electrically connected in parallel. The superconducting electrical path may have a lower series impedance, when operated below a critical current level, than the non-superconducting electrical path. The superconducting electrical path may have a higher series impedance, when operated at or above the critical current level, than the non-superconductor electrical path.Type: ApplicationFiled: January 25, 2010Publication date: June 17, 2010Inventors: Douglas C. Folts, James Maguire, Jie Yuan, Alexis P. Malozemoff
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Patent number: 7667562Abstract: A new class of fundamental devices and methods for their manufacture and use. The bulk magnetic field replicators of the present invention require no precision machining or alignment to accurately reproduce magnetic fields of any complexity, nor extreme positional stability to maintain superconductivity. Such bulk devices may be formed of either low or high critical temperature superconductive materials, but are particularly adapted to formation from high critical temperature materials.Type: GrantFiled: February 20, 1990Date of Patent: February 23, 2010Inventor: Roy Weinstein
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Patent number: 7547661Abstract: An superconductive article and method of forming such an article is disclosed, the article including a substrate and a layer of a rare earth barium cuprate film upon the substrate, the rare earth barium cuprate film including two or more rare earth metals capable of yielding a superconductive composition where ion size variance between the two or more rare earth metals is characterized as greater than zero and less than about 10×10?4, and the rare earth barium cuprate film including two or more rare earth metals is further characterized as having an enhanced critical current density in comparison to a standard YBa2Cu3Oy composition under identical testing conditions.Type: GrantFiled: August 25, 2004Date of Patent: June 16, 2009Assignee: Los Alamos National Security, LLCInventors: Judith L. Driscoll, Stephen R. Foltyn
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Patent number: 7112556Abstract: Superconducting ceramics having relatively high critical temperatures are composed of rare earth metals, alkaline earth metals and copper. They have few defects and a limited polycrystalline interfacial area.Type: GrantFiled: May 24, 1993Date of Patent: September 26, 2006Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 6740623Abstract: An Hg- or Nd-based oxide superconductor comprises Ba as a constituent element and has a content of carbon as an impurity at a level of not greater than 2.0 atomic % whereby the oxide superconductor stably shows high superconducting characteristics without causing degradation with time. For its production, BaO, which has a reduced content of carbon impurity of 0.5% or below, is provided as a feed stock for Ba, and the starting materials are mixed and processed in a dry atmosphere wherein an amount of a carbon-containing gas is suppressed to a certain level, thereby obtaining the oxide superconductor.Type: GrantFiled: January 24, 2003Date of Patent: May 25, 2004Assignee: International Superconductivity Technology CenterInventors: Ayako Yamamoto, Wei-Zhi Hu, Setsuko Tajima
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Patent number: 6624122Abstract: Improvements in critical current capacity for superconducting film structures are disclosed and include the use of a superconducting RE-BCO layer including a mixture of rare earth metals, e.g., yttrium and europium, where the ratio of yttrium to europium in the RE-BCO layer ranges from about 3 to 1 to from about 1.5 to 1.Type: GrantFiled: May 30, 2001Date of Patent: September 23, 2003Assignee: The Regents of the University of CaliforniaInventors: Terry G. Holesinger, Quanxi Jia, Stephen R. Foltyn
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Patent number: 6592782Abstract: Metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes having the formula: AxA′x′A″2-(x+x′)ByFey′B″2-(y+y′)O5+z where: x and x′ are greater than 0; y and y′ are greater than 0; x+x′ is equal to 2; y+y′ is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the lanthanide elements; A′ is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A″ is an element selected from the f block lanthanides, Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof and B″ is Co or Mg, with the exception that when B″ is Mg, A′ and A″ are not Mg. The metal oxides are useful for preparation of dense membranes which may be formed from dense thin films of the mixed metal oxide on a porous metal oxide element.Type: GrantFiled: December 22, 2000Date of Patent: July 15, 2003Assignee: Eltron Research, Inc.Inventors: Richard MacKay, Michael Schwartz, Anthony F. Sammells
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Patent number: 6559103Abstract: A process is provided for preparing solid superconducting mixed-metal oxides whereby the superconductor can be formed into any predetermined shape by way of viscous sol precursors. The superconductors are also formed by this process into homogeneous phases.Type: GrantFiled: March 17, 1989Date of Patent: May 6, 2003Assignee: The Boeing CompanyInventors: Brad Lee Kirkwood, Thomas S. Luhman, Ronald Roy Stephenson, Michael Strasik
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Patent number: 6451450Abstract: A laminate article consists of a substrate and a biaxially textured protective layer over the substrate. The substrate can be biaxially textured and also have reduced magnetism over the magnetism of Ni. The substrate can be selected from the group consisting of nickel, copper, iron, aluminum, silver and alloys containing any of the foregoing. The protective layer can be selected from the group consisting of gold, silver, platinum, palladium, and nickel and alloys containing any of the foregoing. The protective layer is also non-oxidizable under conditions employed to deposit a desired, subsequent oxide buffer layer. Layers of YBCO, CeO2, YSZ, LaAlO3, SrTiO3, Y2O3, RE2O3, SrRuO3, LaNiO3 and La2ZrO3 can be deposited over the protective layer. A method of forming the laminate article is also disclosed.Type: GrantFiled: May 2, 2000Date of Patent: September 17, 2002Assignee: UT-Battelle, LLCInventors: Amit Goyal, Donald M. Kroeger, Mariappan Paranthaman, Dominic F. Lee, Roeland Feenstra, David P. Norton
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Patent number: 6441394Abstract: Using an oxide superconductor that does not require cryogenic temperatures, a superconducting tunnel junction device is provided which can accurately control the magnitudes of critical current and step voltage necessary for electronics applications and which has good characteristics as designed. The intrinsic Josephson superconducting tunnel junction device includes an oxide superconductor defined by a general expression (I): Bi2−zPbzSr2Can(1−x)RnxCun+1O2n+6 (n≧1, 0<x≦0.2, 0≦z≦1.0, R: rare-earth element).Type: GrantFiled: December 26, 2000Date of Patent: August 27, 2002Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Yuji Kasai, Shigeki Sakai
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Patent number: 6281171Abstract: A Mg-doped high-temperature superconductor having low superconducting anisotropy includes a two-dimensional layered structure constituted by a charge reservoir layer and a superconducting layer, wherein some or all atoms constituting the charge reservoir layer are Cu and O atoms, metallizing or rendering the charge reservoir layer superconducting, a portion of the Ca of the CunCan−1O2n constituting the superconducting layer is replaced by Mg, increasing superconductive coupling between CuO2 layers, a thickness of the superconducting layer is increased, and therefore coherence length in a thickness direction is increased based on the uncertainty principle, lowering superconducting anisotropy.Type: GrantFiled: March 16, 1999Date of Patent: August 28, 2001Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Hideo Ihara, Shyam Kishore Agarwal
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Patent number: 5958840Abstract: An oxide superconductor which has high mechanical strength and exhibits favorable magnetic properties and high resistance to environment. Further, a method of manufacturing this oxide superconductor, namely, a method of manufacturing a RE--Ba--Cu--O oxide superconductor (RE is one or more kinds of rare earth elements including Y) by performing a treatment, which includes at least a burning process to be performed in a range of temperatures that are higher than the melting point of a raw material mixture containing a RE-compound raw material, a Ba-compound raw material and a Cu-compound raw material, on the aforesaid raw material mixture. This method further comprises the addition step of adding 1 to 30 in percent by weight (wt %) of Ag to the raw material mixture, and the crystallization step of melting the raw material mixture, to which Ag is added, at a temperature that is not lower than a temperature at which the raw material mixture is decomposed and fused into the RE.sub.2 BaCuO.sub.Type: GrantFiled: July 30, 1997Date of Patent: September 28, 1999Assignees: Dowa Mining Co., Ltd., Chubu Electric Power Company, IncorporatedInventors: Shuichi Kohayashi, Shuetsu Haseyama, Shuji Yoshizawa, Shigeo Nagaya
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Patent number: 5952268Abstract: The present invention relates to method of preparing a superconductor material consisting in preparing a precursor constituted by a powder of Ba.sub.2 Ca.sub.n-1 Cu.sub.n+1 O.sub.x or Ba.sub.2 Ca.sub.n-1 Cu.sub.n+1 O.sub.x where n is an integer greater than 1 and x is greater than 2n+2; in mixing said powder with silver oxide power, optionally in the presence of excess copper oxide, in a proportion of one mole of precursor for one to three moles of silver oxide; and in heating to high temperature and high pressure.Type: GrantFiled: July 23, 1996Date of Patent: September 14, 1999Assignee: AlcatelInventors: Miguel Angel Alario-Franco, Catherine Chaillout, Jean-Jacques Capponi, Jean-Louis Tholence, Benedicte Souletie
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Patent number: 5906964Abstract: Highly oriented HgBa.sub.2 Ca.sub.2 Cu.sub.3 O.sub.8+.delta. on Ni-tapes with a buffer layer of Cr/Ag or Cr/(Ag--Pd) have been described with a high transition temperature are described along with, one and two step methods of manufacture.Type: GrantFiled: January 15, 1997Date of Patent: May 25, 1999Assignee: University of HoustonInventors: Ching-Wu Chu, Ruling L. Meng, Yu-Yi Xue
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Patent number: 5849667Abstract: A high critical temperature and high critical current density superconductor is disclosed which contains a metal oxide expressed by the following formula (I):(R.sup.1.sub.1-x, Ba.sub.x)Ba.sub.2 Cu.sub.3 O.sub.d (I)wherein R.sup.1 stands for at least one element selected from the group consisting of La, Nd, Sm, Eu and Gd, x is a number greater than 0 but not greater than 0.5 and d is a number between 6.2 and 7.2. Fine phases of RE211, RE422 and/or a metal oxide expressed by the formula (R.sup.2.sub.1-z, Ba.sub.z) (Ba.sub.1-y, R.sup.2.sub.y).sub.2 Cu.sub.3 O.sub.p (R.sup.2 =La, Nd, Sm, Eu or Gd) may be dispersed in a matrix of the matrix phase of the formula (I). The above superconductor may be obtained by cooling a melt having a temperature of 1,000.degree.-1,300.degree. C. and containing R.sup.1, Ba, Cu and O at a cooling rate of 5.degree. C./hour or less under a partial pressure of oxygen of between 0.00001 and 0.05 atm, followed by annealing at 250.degree.-600.degree. C. in an oxygen atmosphere.Type: GrantFiled: July 19, 1996Date of Patent: December 15, 1998Assignees: International Superconductivity Technology Center, Railway Technical Research Institute, Shikoku Denryoku Kabushikigaisha, Tosoh CorporationInventors: Masato Murakami, Sang-Im Yoo, Naomichi Sakai, Hiroshi Takaichi, Takamitsu Higuchi, Shoji Tanaka
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Patent number: 5776861Abstract: Hg,Tl-based superconductors are produced by HIPping. A new superconducting phase, having a double (Hg,Tl)-layer and the nominal composition:(Hg.sub.1-x Tl.sub.x).sub.2 (Ba.sub.1-a Sr.sub.a).sub.2 (Ca.sub.1-b Y.sub.b).sub.2 Cu.sub.3 O.sub.zwhere 0.ltoreq.x.ltoreq.0.95, 0.ltoreq.a.ltoreq.1, 0.ltoreq.b.ltoreq.1, and z is sufficient to provide said phase with a resistive and magnetic superconducting transition of 100K or above, can be produced. Either precursor oxides, or partially or fully reacted mixed oxides, can be used in the HIPping mixture.Type: GrantFiled: April 28, 1995Date of Patent: July 7, 1998Assignee: The United States of America as represented by the Secretary of the NavyInventors: Louis E. Toth, William Lechter, Earl F. Skelton, Michael Osofsky
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Patent number: 5716907Abstract: The present invention is an oxide superconductor containing alkaline earth metal M (where M is at least one element of Ba, Sr, and Ca) and having a crystalline structure in which a portion based on two rock-salt structures including the alkaline earth metal M, oxygen, and chlorine, and a 2n-1 piece of infinite layer structure portion are alternately layered on each other, said 2n-1 piece of infinite layer structure portion having an atom layer including copper atoms and oxygen atoms in a ratio of 1 to 2 and of an atom layer including only M atoms layered on each other (where n is an integer of 1 or more and where copper atoms and oxygen atom are contained in a ratio of 1 to 2 if n is 1).Type: GrantFiled: March 20, 1996Date of Patent: February 10, 1998Assignees: International Superconductivity Technology Center, The Furukawa Electric Co., Ltd., Tohoku Electric PowerInventors: Tadashi Tatsuki, Seiji Adachi, Makoto Itoh, Toshiyuki Tamura, Changqin Jin, Xiao-Jing Wu, Hisao Yamauchi
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Patent number: 5620945Abstract: Processes are provided for forming a superconductive composite, comprising a superconductive metal oxide and a ceramic. The composite may be formed in any desired shape. Liquid nitrogen can be held around the superconductor longer and delivered in a more controlled fashion and the composite has improved resistance to shatter and thermal shock. The ceramic also provides protection from atmospheric deterioration of the superconductive oxide.Type: GrantFiled: June 5, 1995Date of Patent: April 15, 1997Assignee: The Boeing CompanyInventors: Anna L. Baker, Michael Strasik
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Patent number: 5614471Abstract: A superconductive material is in composition expressed as Y.sub.0.33 Ba.sub.0.67).sub.a Cu.sub.b (OF).sub.c. The usual a, b and c are so selected as to satisfy a relation expression ax (mix valence of A)+bx (mix valence of B)=cx (mix valence of C).Type: GrantFiled: May 25, 1995Date of Patent: March 25, 1997Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kengo Ohkura, Hajime Hitotsuyanagi, Hiromi Takei
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Patent number: 5599775Abstract: Provided is an Hg--Ba--Ca--Cu--O oxide superconductor having a high superconductivity transition temperature Tc and a method which can prepare the same in excellent reproducibility. This oxide superconductor consists essentially of Hg, Ba, Ca, Cu and O, and is expressed in a chemical formula (Hg.sub.1-X Cu.sub.X)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.y, wherein X=0.05 to 0.7 and Y=8 to 8.75. A method of preparing the oxide superconductor comprises a step of mixing raw materials of Hg, Ba, Ca and Cu with each other so that (Hg+Ba):Ca:Cu =b:1:C and Hg:Ba=(1-a):a, wherein 0.625.ltoreq.a.ltoreq.0.714, 1.ltoreq.b.ltoreq.3 and 1.667.ltoreq.c.ltoreq.3.444, in mole ratio, and compression-molding the mixture, and a step of heat treating a compact obtained by the compression molding. This oxide superconductor has a superconductivity transition temperature Tc of 134 K, which is the highest at present.Type: GrantFiled: January 26, 1996Date of Patent: February 4, 1997Assignees: Sumitomo Electric Industries, Ltd., Tohoku Electric Power Co., Inc., Matsushita Electric Industrial Co., Ltd., International Superconductivity Technology CenterInventors: Makoto Itoh, Ayako Yamamoto, Kazuyuki Isawa, Seiji Adachi, Hisao Yamauchi, Shoji Tanaka
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Patent number: 5589441Abstract: Processes are provided for forming a superconductive composite, comprising a superconductive metal oxide and a ceramic. The composite may be formed in any desired shape. Liquid nitrogen can be held around the superconductor longer and delivered in a more controlled fashion and the composite has improved resistance to shatter and thermal shock. The ceramic also provides protection from atmospheric deterioration of the superconductive oxide.Type: GrantFiled: August 19, 1994Date of Patent: December 31, 1996Assignee: The Boeing CompanyInventors: Anna L. Baker, Michael Strasik
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Patent number: 5583093Abstract: Provided is a metal oxide material represented by the composition formula of Ln.sub.a Sr.sub.b Cu.sub.3-x M.sub.x O.sub.c, where 2.7.ltoreq.a+b.ltoreq.3.3; 0.8 .ltoreq.a.ltoreq.1.2; 6.ltoreq.c.ltoreq.9; and 0.05 .ltoreq.x.ltoreq.0.7, Ln is at least one element selected from the group of elements of Y and lanthanoids or an atomic group consisting of said elements, and M is at least one element selected from the group of elements of Ti, V, Ga, Ge, Mo, W and Re or an atomic group consisting of said elements.Type: GrantFiled: June 7, 1995Date of Patent: December 10, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Tamaki Kobayashi
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Patent number: 5578554Abstract: A metal oxide material comprises components, the composition of which is expressed by the following composition formula (I):Ln.sub.a Ca.sub.b Sr.sub.c Ba.sub.d Cu.sub.2+e-h M.sub.h O.sub.6+f C.sub.g(I)wherea+b+c+d=3, 0.2.ltoreq.a.ltoreq.0.8,0.2.ltoreq.b.ltoreq.1.0, 0.3.ltoreq.c.ltoreq.2.2,0.ltoreq.d.ltoreq.1.7, 0.ltoreq.e.ltoreq.0.8,0.ltoreq.h.ltoreq.0.2, 0<f<2.0,0.2.ltoreq.g.ltoreq.1.0,Ln is one or more elements or atomic groups selected from a group consisting of Y and lanthanoid elements and M is one or more elements or atomic groups selected from a group consisting of Al, Si, Ti, V, Cr, Fe, Co, Ga, Ge and Pd.Type: GrantFiled: May 15, 1995Date of Patent: November 26, 1996Assignee: Canon Kabushiki KaishaInventors: Jun Akimitsu, Norio Kaneko, Tohru Den, Tamaki Kobayashi
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Patent number: 5559084Abstract: Disclosed are a composition and a method of preparing a composition of the formula R.sub.2 Q.sub.4 Cu.sub.7 O.sub.x, wherein R is a rare-earth ion or a mixture of rare earth ions, and Q is Ba, or Ba combined with either Sr or Ca or both Sr and Ca. Such compositions have a unique crystalline structure and are superconducting oxides.Type: GrantFiled: May 28, 1991Date of Patent: September 24, 1996Assignee: Massachusetts Institute of TechnologyInventors: John B. Vandersande, Gregory J. Yurek, Toshihiro Kogure
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Patent number: 5556831Abstract: A method of treating a part made of a superconductive ceramic of the (Ln).sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-.delta. type, where Ln is chosen from the rare earth elements other than cerium and terbium, the method being designed to reduce the value of .delta., in which method said part is heat treated in an oxidizing atmosphere, said method being wherein, during said treatment, an electric current with a density lying in the range 0.1 A/cm.sup.2 to 2 A/cm.sup.2 is caused to flow through said part, said treatment atmosphere having a partial pressure of oxygen lying in the range 0.1 atmospheres to 1 atmosphere, the treatment temperature lying in the range 200.degree. C. to 500.degree. C., and the duration of said treatment lying in the range 1 hour to 200 hours.Type: GrantFiled: June 21, 1994Date of Patent: September 17, 1996Assignee: Alactel Alsthom Compagnie Generale d'ElectriciteInventors: Alain Wicker, Jean-Pierre Bonnet, Mariano Sanz, Patrice Dordor, Christophe Magro
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Patent number: 5550105Abstract: Superconducting compositions characterized by the formula (Pb.sub.a A.sub.1-a)(Sr.sub.b Ba.sub.1-b).sub.2 (Ca.sub.c B.sub.1-c)Cu.sub.2 O.sub.7 wherein at least half the A atoms are Hg and the remainder, if any, are selected from one or more of Cd, Tl and Cu, B is selected from Y and the rare earths, a is from 0.3 to 0.7, b is from 0 to 1 and c is from 0.2 to 0.5 are disclosed. The superconductive compositions display zero-resistance temperatures up to about 80K.Type: GrantFiled: January 31, 1995Date of Patent: August 27, 1996Assignee: BICC Public Limited ComapanyInventors: Peter P. Edwards, Shu-Fen Hu, Ru-Shi Liu, David A. Jefferson
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Patent number: 5536705Abstract: A family of mercury-containing Sr-(Ca.cndot.Y)-Cu-O superconducting materials having a zero-resistance temperature, T.sub.c(zero), greater than 90 K so that they can be cooled to and maintain the desired superconducting characteristics using relatively less expensive liquid nitrogen, are disclosed. The high-temperature superconductor is represented by the formula of: (Pb.sub.0.5 Hg.sub.0.5)(Sr.sub.2-x Ba.sub.x)(Ca.sub.0.7 Y.sub.0.3)Cu.sub.2 O.sub.7-.delta. ; wherein the value of x ranges between about 0.1 and about 0.6, preferably between about 0.2 and about 0.3. These superconducting materials are prepared by first grinding and mixing in open air constituent oxide powders of PbO, HgO, SrO.sub.2, BaO.sub.2, CaO, Y.sub.2 O.sub.3, and CuO. After mixing, the powder mixture is pressed under a pressure of about 5 ton/cm.sup.2 to form a pellet having a diameter of 8 mm and a thickness of 3 mm. Thereafter, the pressed pellet is wrapped with a gold foil (with a thickness of 0.Type: GrantFiled: July 31, 1995Date of Patent: July 16, 1996Assignee: Industrial Technology Research InstituteInventors: Ru-shi Liu, Der-Shiuh Shy, Chung-Ho Tai, Hui-Wen Lee
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Patent number: 5534490Abstract: Provided is an Hg-Ba-Ca-Cu-O oxide superconductor having a high superconductivity transition temperature Tc and a method which can prepare the same in excellent reproducibility. This oxide superconductor consists essentially of Hg, Ba, Ca, Cu and O, and is expressed in a chemical formula (Hg.sub.1-X Cu.sub.X)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.Y, wherein X=0.05 to 0.7 and Y=8 to 8.75. A method of preparing the oxide superconductor comprises a step of mixing raw materials of Hg, Ba, Ca and Cu with each other so that (Hg+Ba):Ca:Cu=b:1:C and Hg:Ba=(1-a):a, wherein 0.625.ltoreq.a.ltoreq.0.714, 1.ltoreq.b.ltoreq.3 and 1.667.ltoreq.c.ltoreq.3.444, in mole ratio, and compression-molding the mixture, and a step of heat treating a compact obtained by the compression molding. This oxide superconductor has a superconductivity transition temperature Tc of 134 K., which is the highest at present.Type: GrantFiled: June 23, 1994Date of Patent: July 9, 1996Assignees: Sumitomo Electric Industries, Ltd., Tohoku Electric Power Co., Inc., Matsushita Electric Industrial Co., Ltd., International Superconductivity Technology CenterInventors: Makoto Itoh, Ayako Yamamoto, Kazuyuki Isawa, Seiji Adachi, Hisao Yamauchi, Shoji Tanaka
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Patent number: 5529981Abstract: The present invention discloses a process and apparatus for forming textures in materials. It uses so called "normal aligners" having an anisotropy in the paramagnetic susceptibility within a magnetic field having compositions REBa.sub.2 Cu.sub.3 O.sub.x or Bi(Tl).sub.2 Sr.sub.2 Ca.sub.1-y RE.sub.y Cu.sub.2 O.sub.x, where RE=Eu, Er, Tm, and Yb. One version of the process for preparing bulk and elongated objects comprises two steps. In the first step the material is uniaxially aligned. In the second step uniaxially aligned material is heated to a temperature approaching its melting point while a magnetic field of at least 10.sup.4 Oe, with a direction perpendicular to the axis of uniaxial alignment is simultaneously applied. The process results in biaxially, highly textured bulk and elongated materials.Type: GrantFiled: July 20, 1993Date of Patent: June 25, 1996Inventor: Alex Holloway
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Patent number: 5523284Abstract: In accordance this invention, there is provided a process for making a bulk superconductive material. In the first step of this process, a diffusion couple is formed from superconductor oxide and impurity oxide. Thereafter, the diffusion couple is heated to a temperature in excess of 800 degrees Centigrade, cooled at a controlled rate, and annealed.Type: GrantFiled: September 30, 1994Date of Patent: June 4, 1996Assignee: Alfred UniversityInventors: James G. Fagan, Jr., Vasantha R. W. Amarakoon
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Patent number: 5512542Abstract: A novel metallic oxide of a Ln-Ca-Sr-Ba-Cu-B-O type and a process for manufacturing such a metallic oxide. The above metallic oxide has a composition expressed by the following formula (I):(Ln.sub.1-a Ca.sub.a)(Sr.sub.2-b Ba.sub.b)(Cu.sub.3-c B.sub.c)O.sub.d(I)wherein Ln is one or more kinds of elements selected from the group consisting of Y and lanthanoid elements except for Ce and Tb and wherein the following conditions are met: 0.1.ltoreq.a.ltoreq.0.5, 0.7.ltoreq.b.ltoreq.1.7, 0.1.ltoreq.c.ltoreq.0.5, and 6.5.ltoreq.d.ltoreq.7.5. A process for manufacturing the metallic oxide has the following steps. A mixture of materials including H.sub.3 BO.sub.3 used as a starting material of B is prepared. The resultant mixture is heated at a rate of 5.degree. C. or lower per minute up to 900.degree. C. or lower. Then, it is heated in an oxygen atmosphere at a range from 900.degree.-1050.degree. C.Type: GrantFiled: August 30, 1994Date of Patent: April 30, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Norio Kaneko, Tamaki Kobayashi
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Patent number: 5512538Abstract: Provided is a metal oxide material represented by the composition formula of Ln.sub.a Sr.sub.b Cu.sub.3-x M.sub.x O.sub.c, where 2.7.ltoreq.a+b.ltoreq.3.3; 0.8.ltoreq.a.ltoreq.1.2; 6.ltoreq.c.ltoreq.9; and 0.05 .ltoreq.x.ltoreq.0.7, Ln is at least one element selected from the group of elements of Y and lanthanoids or an atomic group consisting of said elements, and M is at least one element selected from the group of elements of Ti, V, Ga, Ge, Mo, W and Re or an atomic group consisting of said elements.Type: GrantFiled: June 27, 1994Date of Patent: April 30, 1996Assignee: Canon Kabushiki KaishaInventors: Tohru Den, Tamaki Kobayashi
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Patent number: 5508253Abstract: The present invention is characterized in that oxides of Y, Ba and Cu having a superconductive substance-forming composition are melted, the melt is rapidly cooled and solidified, the obtained sheet is heated at a temperature of 1000.degree. to 1350.degree. C. to produce a partially melted state thereof, and the sheet is gradually cooled at a rate lower than 200.degree. C./hr, whereby a micro-structure in which precipitates of the RE.sub.2 BaCuO.sub.5 phase having a diameter smaller than 20 .mu.m are dispersed in the REBa.sub.2 Cu.sub.3 O.sub.7-y crystal is obtained.Type: GrantFiled: April 17, 1995Date of Patent: April 16, 1996Assignee: Nippon Steel CorporationInventors: Mitsuru Morita, Katsuyoshi Miyamoto, Masato Murakami, Shoichi Matsuda
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Patent number: 5498594Abstract: A high temperature superconducting system comprising M--R--Tl--Sr--Cu--O wherein: M is at least one compound selected from the group consisting of Hg, Pb, K, and Al; and R represents rare earth metals. In one embodiment, a composition forms a 93K superconducting phase having the composition: M--R--Tl--Sr--Cu--O wherein: M is selected from the group consisting of Hg and Al; and R is a rare earth metal. In another embodiment, the composition comprises M--R--Tl--Sr--Cu--O wherein: M is selected from the group of Pb and/or K; and R is a rare earth metal.Type: GrantFiled: February 17, 1994Date of Patent: March 12, 1996Assignee: University of ArkansasInventors: Zhengzhi Sheng, John Meason, Ying Xin
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Patent number: 5468724Abstract: Disclosed herein are high-temperature oxide superconductors of RBa.sub.2 Cu.sub.4 O.sub.8 type, with Ba partly replaced by Sr or Ca, or with R and Ba partly replaced by Ca and Sr, respectively, as represented by the chemical composition formula of R(Ba.sub.1-y Sr.sub.y).sub.2 Cu.sub.4 O.sub.8 or R(Ba.sub.1-z Ca.sub.z).sub.2 Cu.sub.4 O.sub.8 or (R.sub.1-x Ca.sub.x) (Ba.sub.1-y Sr.sub.y).sub.2 Cu.sub.4 O.sub.8. They exhibit superconductivity at high temperatures. Especially, the last one exhibits superconductivity at a higher temperature than the former two. All of them can be made with a less amount of Ba as a deleterious substance, and the first two have improved sinterability. The best results are obtained when they are produced by the process involving the hot hydrostatic pressure treatment of the mixture of raw materials at 850.degree.-1100.degree. C. in an atmosphere composed of an inert gas and oxygen. The process permits a wider selection of Ba raw materials.Type: GrantFiled: May 27, 1993Date of Patent: November 21, 1995Assignees: International Superconductivity Technology Center, Matsushita Electric Industrial Co., Ltd., Kyocera Corporation, Mitsubishi Metal Corporation, The Tokyo Electric Power Company, Incorporated, Kabushiki Kaisha Kobe Seiko ShoInventors: Takahiro Wada, Shin-ichi Koriyama, Takeshi Sakurai, Nobuo Suzuki, Takayuki Miyatake, Hisao Yamauchi, Naoki Koshizuka, Shoji Tanaka
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Patent number: 5462917Abstract: A superconductor material having a current density, J, of from about 30,000 to about 85,000 amps/cm.sup.2 at zero magnetic field and 77.degree. K is disclosed. The 123 superconductor, of the formula L.sub.1 Ba.sub.2 Cu.sub.3 O.sub.6 +.delta. wherein L is preferably yttrium, is capable of entrapping sufficiently high magnetic fields and exhibits a low microwave surface resistance. The process of preparing the superconductor comprises compacting the bulk product, L.sub.1 Ba.sub.2 Cu.sub.3 O, and then sintering the reaction product at a temperature between about 40.degree. C. to about 90.degree. C. below its melting point, i.e., for Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.6 +.delta. at a temperature of approximately 940.degree. C. The composition is then heated in a preheated chamber maintained at approximately 1090.degree. C. to about 1,200.degree. C. (approximately 1,100.degree. C. for Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.6 +.delta.Type: GrantFiled: February 14, 1994Date of Patent: October 31, 1995Assignee: University of Houston-University ParkInventors: Kamel Salama, Venkatakrishnan Selvamanickam
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Patent number: 5445766Abstract: The disclosed substance has a composition of a general chemical formula ofBi.sub.2 -(Sr.sub.2 Ca.sub.1).sub.1-x (La.sub.2 Y.sub.1).sub.x -Cu.sub.y -O.sub.z,where 0.4.ltoreq.x.ltoreq.1, y=2 and z=9-10.5, wherein said substance is an insulator or a semiconductor in the dark, and has a photoconductivity Q(.lambda.,T) in conjugate with superconductivity of a superconductor of an adjacent component of the Bi-SrCa-LaY-Cu-O system at and below a critical temperature (T) of less than 105-115K and below 65-85K at photoexcitation in an optical wavelength range (.lambda.) of 420-670 nm. The present invention relates to a method for producing the same and a superconductive optoelectronic device by using the same. The present invention also relates to an organized integration of the element or device into an apparatus to further develop a new field of "Superconductive Optoelectronics.Type: GrantFiled: July 15, 1992Date of Patent: August 29, 1995Assignee: The University of TokyoInventor: Taizo Masumi
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Patent number: 5444425Abstract: A flux-trapped superconducting magnet which is formed of high transition temperature superconducting mixture doped with a magnetic material having a Curie temperature below the transition temperature of the superconducting mixture.Type: GrantFiled: February 28, 1994Date of Patent: August 22, 1995Assignee: The Regents of the University of ColoradoInventors: Allen M. Hermann, Gol A. Naziripour, Timir Datta
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Patent number: 5432143Abstract: A method of producing a microcrystalline RBa.sub.2 Cu.sub.3 O.sub.y structure where R denotes a lanthanide chosen from Y, La, Nd, Sm, Eu, Gd, Tb, Ho, Er, Tm, Yb and Lu and where y has a value between 6.9 and 7 starts with a powder of composition [x(123) ; (1-x) (7BaO--18CuO] where (123) denotes the 123 phase of RBaB.sub.2 Cu.sub.3 O.sub.y and where the value of x is between 0.01 and 1. The powder is compressed and sintered at a temperature below 920.degree. C. (the BaCuO.sub.2 and CuO binary eutectic temperature) to form a sample. The sample is placed on an oxide of the lanthanide R. The sample and its support undergo heat treatment enabling chemical reaction between the liquid part of the sample and its support whereby substantially all of the liquid part is consumed and highly regular 123 monocrystals are obtained. Cooling is applied. At least one annealing is carried out in pure oxygen at a temperature between 350.degree. C. and 500.degree. C. to obtain the orthorhombic form characteristic of RBa.sub.2 Cu.Type: GrantFiled: January 11, 1994Date of Patent: July 11, 1995Assignee: Alcatel Alsthom Compagnie Generale D'ElectriciteInventors: Nadia Pellerin, Philippe Odier
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Patent number: 5430011Abstract: A superconducting thin film formed on a substrate, comprising at least one oxide superconductor layer formed on the principal surface of said substrate and at least one oxide layer formed of an oxide which compensates for crystalline incompleteness at the surface of said oxide superconductor layer, and which is arranged on or under the superconducting layer.Type: GrantFiled: September 17, 1992Date of Patent: July 4, 1995Assignee: Sumitomi Electric Industries, Ltd.Inventors: So Tanaka, Michitomo Iiyama
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Patent number: 5430008Abstract: Superconducting materials and methods of forming superconducting materials are disclosed. Highly oxidized superconductors are heated at a relatively high temperature so as to release oxygen, which migrates out of the material, and form a non-superconducting phase which does not diffuse out of grains of the material. The material is then reoxidized at a lower temperature, leaving the non-superconducting inclusions inside a superconducting phase. The non-superconducting inclusions act as pinning centers in the superconductor, increasing the critical current thereof.Type: GrantFiled: October 28, 1991Date of Patent: July 4, 1995Assignee: The Regents of the University of CaliforniaInventor: Donald E. Morris
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Patent number: 5422336Abstract: A superconducting transistor with superior withstand voltage having source region and a drain region formed of oxide superconductors 3, a PrBa.sub.2 Cu.sub.3 O.sub.7-x layer 2 or an ScBa.sub.2 Cu.sub.3 O.sub.7-x layer 2 forming an intermediate region sandwiched by the source and drain regions. The regions are disposed on a substrate 1. An insulation layer 4 is disposed on the intermediate region. A transistor uses the intermediate region as an insulator when the gate is turned off, and as a superconductor when the gate is turned on.Type: GrantFiled: September 22, 1993Date of Patent: June 6, 1995Assignee: Fuji Electric Co., Ltd.Inventors: Koichi Tsuda, Toshiyuki Matsui, Takeshi Suzuki, Hiroshi Kimura, Takashi Ishii, Akihiko Ohi, Kazuo Mukae
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Patent number: 5417073Abstract: A Cryogenic Cooling System generally comprises a portable Dewar and a charging station for the Dewar. In the preferred embodiment, a HTSC device, such as a MRI coil, is contained in the Dewar which uses liquid nitrogen as a cryogenic coolant. The Dewar includes a reservoir for holding cryogenic fluid, an optional wicking material, a transfer tube between the reservoir and the HTSC device (or wick), and a vacuum space. Preferably a vent channel is adjacent the reservoir and provides an escape path for evaporating gas from the wick and/or HTSC device. The vent channel preferably provides a feed-back system: as more cryogenic coolant is transferred via the transfer tube, more cool gas is vented through the channel which cools the reservoir and thereby reduces the transfer. A charging system may also be provided as a source of cryogenic coolant. In the preferred embodiment, the charging system comprises a relatively large reservoir for liquid nitrogen.Type: GrantFiled: July 16, 1993Date of Patent: May 23, 1995Assignee: Superconductor Technologies Inc.Inventors: Timothy W. James, Wallace Y. Kunimoto
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Patent number: 5389603Abstract: A new class of high temperature superconductive oxides is disclosed. An exemplary member of the class has nominal composition Pb.sub.2 Sr.sub.2 Y.sub.0.5 Ca.sub.0.5 Cu.sub.3 O.sub.8 and has a transition temperature T.sub.c (onset) of about 79K.Type: GrantFiled: February 9, 1990Date of Patent: February 14, 1995Assignee: AT&T Corp.Inventors: Bertram J. Batlogg, Robert J. Cava
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Patent number: 5378683Abstract: The disclosure relates to a Josephson junction formed by a non-superconducting barrier between two superconducting films of the (R) BaCuO (R=rare earth) group. In order to take advantage of the greater coherence length of superconductors along the CuO planes, i.e. perpendicularly to the long axis "c" of the crystal unit cell, the superconducting film is oriented so that the axis "c" is parallel to the plane of the junction. The device can be applied to Josephson junctions and to SQUIDs.Type: GrantFiled: April 21, 1992Date of Patent: January 3, 1995Assignee: Thomson-CSFInventors: Regis Cabanel, Guy Garry, Alain Schuhl, Bruno Ghyselen
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Patent number: 5372990Abstract: Provided is an oxide superconductor in which superconducting layer is sandwiched between two blocking layers having different compositions. Available superconducting layers include a one-layer system having one Cu-O.sub.2 sheet, a two-layer system having a mediating layer sandwiched between two Cu-O.sub.2 sheets, and a three-layer system having mediating layers sandwiched individually between three Cu-O.sub.2 sheets.Since the blocking layers are of different compositions, seventy-seven kinds of oxide superconductors can be obtained.Type: GrantFiled: May 20, 1992Date of Patent: December 13, 1994Assignee: Toray Industries, Ltd.Inventors: Hitoshi Nobumasa, Kazuharu Shimizu
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Patent number: RE35376Abstract: The present invention comprises novel oxide materials exhibiting bulk superconductivity up to and exceeding 85K and processes for their synthesis. The oxides are within the formula R.sub.a Ba.sub.b Cu.sub.c O.sub.d wherein 1.9<a<2.1, 3.9<b<4.1, 6.8<c<7.2, 14.4<d<15.2 and wherein R is Y or any of the lanthanide rare earth elements. Certain substitutions such as Ca and La on the R and Ba sites are included.Type: GrantFiled: December 28, 1994Date of Patent: November 5, 1996Assignee: Industrial Research LimitedInventors: Jeffrey L. Tallon, Robert G. Buckley, Donald M. Pooke