With Organic Phosphorus Compound Patents (Class 508/282)
  • Patent number: 10633607
    Abstract: A fluid contains a base oil and an antioxidant, the base oil consisting of sulfur-containing polyalkylene glycol where greater than 80 weight-percent of the fluid is a sulfur-containing polyalkylene glycol and less than one weight-percent of the fluid is water, with weight percent based on total fluid weight an wherein the sulfur-containing polyalkylene glycol is free of oxygen bound directly to sulfur.
    Type: Grant
    Filed: August 17, 2016
    Date of Patent: April 28, 2020
    Assignee: Dow Global Technologies LLC
    Inventors: Martin R. Greaves, Ronald Van Voorst, Marinus Meertens
  • Patent number: 9296976
    Abstract: The lubricating oil composition of the invention comprises a lubricant base oil, a 3,4,5-trihydroxybenzoic acid ester at 5-5000 ppm by mass, and a phosphorus compound at 0.001-10.0% by mass, based on the total mass of the lubricating oil composition. The lubricating oil composition of the invention significantly lowers wear and exhibits a stable low frictional coefficient, while having a high rust-preventing effect for iron-based sliding sections. The lubricating oil composition of the invention is therefore suitable for prolonged use, and exhibits a notable effect for energy savings as well due to its stable low frictional coefficient property.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: March 29, 2016
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Tomonari Matsumoto, Fumiyuki Nara, Takeshi Okido, Katsuya Takigawa
  • Publication number: 20140303053
    Abstract: A lubricant composition comprising at least 90 wt % of at least one oil soluble polyalkylene glycol (OSP), wherein the OSP comprises at least 40 wt % units derived from butylene oxide and at least 40 wt % units derived from propylene oxide, initiated by one or more initiators selected from monols, diols, and polyols; and at least 0.05 wt % of at least one anti-wear additive; wherein the lubricant composition exhibits a four ball anti-wear of less than or equal to 0.35 mm and an air release value at 50° C. of less than or equal to 1 minute is provided.
    Type: Application
    Filed: October 25, 2012
    Publication date: October 9, 2014
    Inventor: Martin R. Greaves
  • Publication number: 20140162913
    Abstract: Disclosed are corrosion-inhibiting lubricant compositions and methods of making and using the compositions. The lubricant compositions contain petroleum based components, corrosion-inhibiting additives and a cationic surfactant. In some embodiments, the lubricant compositions also contain nano diamonds. Under standard salt fog tests, compositions exhibited 120 or 168 hours to failure, or 0-20% rust at 192 hours. Under standard wear preventative characteristics tests, compositions exhibited as low as 0.55 mm wear. Also disclosed are a device and method for aerosol delivery of a corrosion-inhibiting lubricant.
    Type: Application
    Filed: July 25, 2012
    Publication date: June 12, 2014
    Inventor: David McCreery
  • Publication number: 20140045736
    Abstract: The present invention relates to a synergistic combination of an antioxidant and an antiwear additive that results in improved antioxidancy performance in turbine, hydraulic, and other industrial lubricating compositions. The invention further relates to the processes to make the improved lubricating compositions and methods of their use in industrial fluids.
    Type: Application
    Filed: May 14, 2012
    Publication date: February 13, 2014
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Seth L. Crawley, Betsy J. Butke
  • Patent number: 8557754
    Abstract: A composition of biodegradable gear oil that mainly contains modified nontauedible vegetable oils. Mono-esters are hydrogenated, epoxidized or aryl alkylated or mixture thereof, and C7 to C12 primary alcohol. In addition to chemically modified non-edible vegetable oils, the composition also contains an additive pack, which comprises at least one: antioxidant, an extreme pressure additive, an anti foaming agent, a pour point depressant, a corrosion inhibitor and a detergent-dispersant additive. The product of this invention has utility as industrial and automotive gear oil GL 4 grade. The compositions are significantly biodegradable, eco-friendly, reduce use of petroleum, have lower cost than synthetic oil, are miscible in mineral & synthetic fluids and safe to use due to higher flash point.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: October 15, 2013
    Assignee: Counsel of Scientific & Industrial Research
    Inventors: Arun Kumar Singh, Aruna Chamoli
  • Publication number: 20130217605
    Abstract: The present invention is a lubricant or functional fluid additive for a polyolefin oil blend, comprising a mixture of: (a) an anti-wear component consisting essentially of 95% isopropylated triarylphosphate and 5% dodecyl phosphate, the dodecyl phosphate being only partially esterified, the anti-wear component present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (b) an antioxidant component selected from the group consisting of alkylated phenyl-alpha-naphthylamine, phenyl-alpha-naphthylamine and mixtures thereof, and present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (c) an anti-rust component comprising an alkylated succinic acid ester anti-rust agent, and present in the polyolefin oil blend in a range of from about 0.050 percent to about 0.
    Type: Application
    Filed: March 21, 2013
    Publication date: August 22, 2013
    Applicant: Materials Engineering and Technical Support Services Corp., dba METSS Corporation
    Inventor: Materials Engineering and Technical Support Services Corp., dba METSS Corporation
  • Publication number: 20130157909
    Abstract: Lubricant compositions including a random or block copolymer first high-EO content polyalkylene glycol, a random copolymer second polyalkylene glycol based on propylene oxide and butylene oxide or a second polyalkylene homopolymer having propylene oxide or butylenes oxide units and at least one corrosion inhibitor selected from the group of sarcosines, amine phosphates, and calcium dinonylnaphthalenesulfonate/carboxylates are provided. Lubricant compositions for extreme conditions are also provided.
    Type: Application
    Filed: August 17, 2011
    Publication date: June 20, 2013
    Applicant: Dow Global Technologies LLC
    Inventors: Martin R. Greaves, Daniel Zweifel, Evelyn A. Zaugg-Hoozemans
  • Publication number: 20120101015
    Abstract: Described is a lubricating composition of an anti-wear agent or a combination of anti-wear agents having a reduced neurotoxicity, the anti-wear agent(s) being selected from triaryl phosphate compounds preferably substituted with one or more linear or branched alkyl group(s) including from 2 to 12 carbon atoms.
    Type: Application
    Filed: June 23, 2010
    Publication date: April 26, 2012
    Applicant: NYCO SA
    Inventors: Pascal Frapin, Issa Latif, Christophe Corbun, Jean-Louis Mansoux
  • Publication number: 20110207638
    Abstract: A composition of biodegradable gear oil that mainly contains modified nontauedible vegetable oils. Mono-esters are hydrogenated, epoxidized or aryl alkylated or mixture thereof, and C7 to C12 primary alcohol. In addition to chemically modified non-edible vegetable oils, the composition also contains an additive pack, which comprises at least one: antioxidant, an extreme pressure additive, an anti foaming agent, a pour point depressant, a corrosion inhibitor and a detergent-dispersant additive. The product of this invention has utility as industrial and automotive gear oil GL 4 grade. The compositions are significantly biodegradable, eco-friendly, reduce use of petroleum, have lower cost than synthetic oil, are miscible in mineral & synthetic fluids and safe to use due to higher flash point.
    Type: Application
    Filed: March 5, 2009
    Publication date: August 25, 2011
    Inventors: Arun Kumar Singh, Aruna Chamoli
  • Publication number: 20110065617
    Abstract: The present invention relates to a lubricating composition containing an oil of lubricating viscosity, a metal containing antiwear agent and a metal containing dispersant. The invention further provides for a method for lubricating a hydraulic system.
    Type: Application
    Filed: November 18, 2010
    Publication date: March 17, 2011
    Applicant: THE LUBRIZOL CORPORATION
    Inventor: Allan Barber
  • Patent number: 7294607
    Abstract: The present invention relates to a lubricant composition exhibiting enhanced load-carrying capacity and oxidative/corrosion stability. The lubricant composition of the present invention comprises a major portion of an aliphatic ester base oil having lubrication properties and formed by the reaction of pentaerythritol and an organic carboxylic acid. The lubricant composition further comprises 3-(di-isobutoxy-thiophosphonylsulfanyl)-2-methyl-propionic acid (DITMPA) as an additive comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition as well as yellow metal passivator comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition. The enhanced load-carrying capacity and oxidative/corrosion stability of lubricant compositions containing DITMPA and yellow metal passivator is achieved without deleteriously affecting other salient properties of the lubricant.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: November 13, 2007
    Assignee: BP Corporation North America Inc.
    Inventors: Patrick E. Godici, David G. V. Jones, Kim E. Fyfe
  • Patent number: 6919300
    Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: July 19, 2005
    Assignee: Ashland Inc.
    Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
  • Patent number: 6858567
    Abstract: The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of ?30 to 80° C. with one kind of a lubricating oil, and they are free from change of properties over a long period of time.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: February 22, 2005
    Assignee: Citizen Watch Co., Ltd.
    Inventor: Yuji Akao
  • Publication number: 20040072701
    Abstract: The present invention relates to a lubricant composition exhibiting enhanced load-carrying capacity and oxidative/corrosion stability. The lubricant composition of the present invention comprises a major portion of an aliphatic ester base oil having lubrication properties and formed by the reaction of pentaerythritol and an organic carboxylic acid. The lubricant composition further comprises 3-(di-isobutoxy-thiophosphonylsulfanyl)-2-methyl-propionic acid (DITMPA) as an additive comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition as well as yellow metal passivator comprising from about 0.01 to about 0.40 weight percent of the fully formulated lubricating oil composition. The enhanced load-carrying capacity and oxidative/corrosion stability of lubricant compositions containing DITMPA and yellow metal passivator is achieved without deleteriously affecting other salient properties of the lubricant.
    Type: Application
    Filed: August 21, 2003
    Publication date: April 15, 2004
    Inventors: Patrick E. Godici, David G. V. Jones, Kim E. Fyfe
  • Patent number: 6645920
    Abstract: A lubricating oil composition containing in oxidation inhibitor package, a rust inhibitor and metal deactivator is used in industrial fluids. The oxidation package contains alkylated diphenylamines, substituted hydrocarbyl monosulphides and optionally sterically hindered phenols. The rust inhibitor contains at least 1 of alkylated amine salts of alkylphosphoric acid, dialkyldithiophosphoric acid or hydrocarbyl aryl sulphonic acids. The metal deactivator is 5-methylbenzotriazole.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: November 11, 2003
    Assignee: The Lubrizol Corporation
    Inventor: Betsy J. Butke
  • Patent number: 6573223
    Abstract: The invention relates to a lubricating composition comprising: (a) at least one sulfur-free hydrocarbyl phosphoric acid ester or salt, (b) at least one sulfur-containing hydrocarbyl phosphoric acid or salt, (c) an organic polysulfide, (d) at least one dispersant, and (e) at least one triazole metal deactivator. The composition may also include a thiadiazole derivative. This additive combination provides good antiwear and thermal stability properties, even under severe thermal conditions. These compositions also have good demulsibility properties. The above combination of additives provides the antiwear and extreme-pressure protection necessary for automotive and industrial gear applications. These additives additionally provide this protection without adversely effecting demulsibility properties of the lubricant.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: June 3, 2003
    Assignee: The Lubrizol Corporation
    Inventor: James N. Vinci
  • Publication number: 20030050197
    Abstract: The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of −30 to 80° C. with one kind of a lubricating oil, and they are free from change of properties over a long period of time.
    Type: Application
    Filed: October 9, 2001
    Publication date: March 13, 2003
    Inventor: Yuji Akao
  • Publication number: 20020117648
    Abstract: Disclosed are phosphate ester base fluids and aircraft hydraulic fluids containing a novel combination of phosphate ester components. The disclosed aircraft hydraulic fluids contain from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-iso-butyl phosphate; from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-n-butyl phosphate; from about 10 to about 15 weight percent, based on the total weight of the fluid, of one or more triaryl phosphates; and an effective amount of a viscosity index improver, an acid control additive and an erosion inhibitor.
    Type: Application
    Filed: September 28, 2001
    Publication date: August 29, 2002
    Inventors: Mark E. Okazaki, Adrian D'Souza, Shlomo Antika
  • Patent number: 6194359
    Abstract: The operational fluid according to the invention is well suited for the lifelong lubrication and cooling of combustion engines. It comprises as the basic fluid a polyalkylene glycol produced from ethylene oxide and propylene oxide and an additive mixture comprising a) 0.012-1.0 percent by weight of a reaction product of diphenyl amine and 2,4,4-trimethyl pentene; b) 0.01-1.0 percent by weight of a pentaerythritol partially or completely esterified with an alkyl-substituted p-hydroxy propionic acid; c) 0.01-1.0 percent by weight of a mono- or di-(C4-C8) alkyl phosphoric acid (C10-C15) alkyl amide; d) 0.01-1.0 percent by weight of triphenyl thiophosphate; e) 0.01-0.1 percent by weight of a tolutriazol amino-methylated with a straight-chain or branched alkyl group with 2-10 carbon atoms, and/or f) 0.01-0.1 percent by weight of 1H-benzotriazol.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: February 27, 2001
    Assignees: Fragol Schmierstoff GmbH & Co. KG, DaimlerChrysler AG
    Inventors: Ludwig Beyer, Herbert Gasthuber, Heiner Müske, Mathias Woydt
  • Patent number: 5955403
    Abstract: A sulfur free lubricating composition comprises a major portion of a synthetic base lubricating oil and a minor portion of a tri(alkyl phenyl) phosphate or di(alkylphenyl)phosphoric acid antiwear agent, an amine antioxidant a substituted succinamide rust inhibitor and a tolytriazole. The tri(alkylphenyl)phosphate antiwear agent is incorporated in the oil in an amount ranging between about 0.1 to 2.0 wt % and the amine antioxidant in amount ranging from about 0.1 to 5 wt %. The succinamide is present in an amount ranging from about 0.01 to 0.5 wt % and the tolytriazole, from about 0.01 to 0.5 wt %. In the foregoing, the wt % is based on the weight of oil.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: September 21, 1999
    Assignee: Exxon Research and Engineering Company
    Inventor: Chung-Lai Wong
  • Patent number: 5885942
    Abstract: The multifunctional lubricant additive compositions of the invention preferably contain a methylene bis(dibutyldithiocarbamate) as an antiwear and extreme pressure additive, a 2,5-dimercapto-1,3,4-thiadiazole derivative as an antioxidant and antiwear additive, a tolutriazole compound as an antioxidant and corrosion inhibitor, a glycerol monooleate as a friction modifier, a calcium sulfonate as a detergent and extreme pressure additive, a zinc dialkyl dithiophosphate as an antiwear and antioxidant additive, a polymethylacrylate as a dispersant, a polyol ester as a carrier and friction modifier, a red dye for leak detection, and optionally, solvent neutral oil and a pour point depressant.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: March 23, 1999
    Assignee: NCH Corporation
    Inventors: Ruiming Zhang, Robert M. Hooks
  • Patent number: 5756430
    Abstract: Mist oil lubricants are disclosed based on polycarboxylic acid esters as the base oil which have added 1 to 5% of polyisobutylene Mn 400-2500 as stray mist suppressants.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: May 26, 1998
    Assignee: Exxon Chemical Patents Inc
    Inventor: James Zielinski
  • Patent number: 5536423
    Abstract: A hydraulic working oil composition for buffers which comprises:a lubricating oil as a base oil,(A) at least one phosphorus-containing compound selected from the group consisting of a phosphoric acid ester having a specific structure, a phosphorous acid ester having a specific structure and a salt of-the phosphoric acid ester and/or the phosphorous acid ester with an aliphatic monoamine having 8-22 carbon atoms, and(B) at least one nitrogen-containing compound selected from the group consisting of an aliphatic polyamine having a specific structure and a salt of the aliphatic polyamine with an aliphatic acid having 6 carbon atoms, the compounds (A) and (B) being essential components added to said base oil.
    Type: Grant
    Filed: February 8, 1995
    Date of Patent: July 16, 1996
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Toru Miyagawa, Mitsuo Okada
  • Patent number: 5531912
    Abstract: A stearate free solid lubricant for cold working of metals contains approximately equal amounts of an alkene-acrylate ionomer and an alkoxylated alcohol in which the alcohol moiety has from 18-60 carbon atoms and the alkoxylate block has about the same number of carbon atoms. This lubricant can be conveniently applied from aqueous solution/suspension and works effectively even when the underlying steel surface has no conversion coating, which is usually required with stearate lubricants for best results.
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: July 2, 1996
    Assignee: Henkel Corporation
    Inventors: Richard J. Church, Kenneth J. Hacias
  • Patent number: RE37101
    Abstract: A fluid composition suitable for use as an aircraft hydraulic fluid is disclosed. The fluid composition comprises a fire resistant phosphate ester base stock comprising between about 10% and about 100% by weight of a trialkyl phosphate, between about 0% and about 70% by weight of a dialkyl aryl phosphate, and from about 0% to about 25% by weight of an alkyl diaryl phosphate, with the proviso that the sum of the proportionate amount of each base stock component must equal 100%. The alkyl substituents of the trialkyl phosphate, the dialkyl aryl phosphate, and the alkyl diaryl phosphate contain between 3 and 8 carbon atoms, preferably between 4 and 8 carbon atoms, more preferably between 4 and 5 carbon atoms, and are bonded to the phosphate moiety via a primary carbon. It is still further preferred that the alkyl substituents of the trialkyl phosphate, the dialkyl aryl phosphate, and the alkyl diaryl phosphate are isoalkyl groups.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: March 20, 2001
    Assignee: Solutia Inc.
    Inventor: Gerbrand Deetman