Chalcogen Or Nitrogen Bonded Directly To Ring Carbon Of The 1,3-hetero Ring , Or The 1,3-hetero Ring Has Two Double Bonds Between Ring Members Patents (Class 508/284)
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Patent number: 11867117Abstract: Use of an additive selected from nitrate compounds, peroxide compounds, nitrite compounds and polyether compounds, and mixtures thereof in a diesel fuel composition for reducing the build-up of deposits in an Exhaust Gas Recirculation (EGR) system of a compression ignition internal combustion engine.Type: GrantFiled: December 9, 2019Date of Patent: January 9, 2024Assignee: SHELL USA, INC.Inventors: Christopher William Clayton, Michael Gee, Rodney Glyn Williams, Emma Wyatt, Alan Norman Ross, Keith Woodall, Jacqueline Glen Reid, Simon Christopher Mulqueen, Stephen Leonard Cook
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Patent number: 10421923Abstract: The invention provides a lubricant composition comprising an oil of lubricating viscosity and 0.01 wt % to 15 wt % of a protic acid salt of an N-hydrocarbyl-substituted gamma- (?-) or delta- (?-)amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.Type: GrantFiled: May 6, 2015Date of Patent: September 24, 2019Assignee: The Lubrizol CorporationInventors: Daniel J. Saccomando, William R. S. Barton, Ewan E. Delbridge, Patrick E. Mosier
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Patent number: 10141017Abstract: A lubricant for a magnetic recording medium including an ionic liquid including a Bronsted acid and a Bronsted base that is primary amine as constituents of the ionic liquid, wherein the Bronsted acid includes a fluorine-containing chain, the Bronsted base includes a fluorine-containing chain that is a perfluoroalkyl chain or a perfluoropolyether chain, wherein the fluorine-containing chain in the Bronsted acid is a perfluoropolyether chain or the fluorine-containing chain in the Bronsted base is the perfluoropolyether chain, or the fluorine-containing chain in the Bronsted acid is the perfluoropolyether chain and the fluorine-containing chain in the Bronsted base is the perfluoropolyether chain, and a number average molecular weight of the fluorine-containing chain in the Bronsted acid is 1,500 or less.Type: GrantFiled: February 3, 2016Date of Patent: November 27, 2018Assignee: Dexerials CorporationInventors: Nobuo Tano, Kouki Hatsuda, Hirofumi Kondo
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Patent number: 9732263Abstract: A working fluid composition for a refrigerating machine comprises a refrigerant comprising monofluoroethane and a refrigerating machine oil comprising, as a base oil, at least one selected from a mineral oil having % CN in an n-d-M ring analysis of 10 to 60 and a pour point of ?15° C. or lower and a synthetic hydrocarbon oil having a pour point of ?15° C. or lower, and the refrigerating machine oil having a kinematic viscosity at 40° C. of 3 to 500 mm2/s.Type: GrantFiled: July 11, 2013Date of Patent: August 15, 2017Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Masanori Saito, Souichirou Konno, Kuniko Adegawa
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Publication number: 20140171348Abstract: A composition including an ionic liquid alkylammonium salt (e.g., tetraalkylammonium cation and bis(2-ethylhexyl)phosphate anion), or an ionic liquid imidazolium salt (e.g., 1,3-dialkylimidazolium cation and bis(2-ethylhexyl)phosphate anion), that have a structure sufficient to exhibit at least partial solubility in one or more Group I-V base stocks. The disclosure also relates to a lubricating oil base stock and lubricating oil containing the composition, a multifunctional functional fluid containing the composition, and a method for improving solubility of an ionic liquid in a lubricating oil by using as the lubricating oil a formulated oil including a lubricating oil base stock as a major component, and an ionic liquid alkylammonium salt cobase stock, or an ionic liquid imidazolium salt cobase stock, as a minor component.Type: ApplicationFiled: November 14, 2013Publication date: June 19, 2014Applicant: ExxonMobil Research and Engineering CompanyInventors: Abhimanyu Onkar Patil, Satish Bodige, Tezcan Guney
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Patent number: 8404624Abstract: The invention relates to an additive composition, which comprises an additive mixture that essentially consists of a) At least one ammonium phosphate ester; b) At least one thiophosphoric acid ester, and c) At least one dithiophosphoric acid derivative; in combination with sulphur containing oil additives; and a process for the reduction of wear in combustion engines, such as spark ignition or Diesel motor engines.Type: GrantFiled: March 13, 2006Date of Patent: March 26, 2013Assignee: Ciba Specialty Chemicals CorporationInventor: Marc Ribeaud
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Publication number: 20130053287Abstract: Provided is a lubricating oil additive which is able to impart friction adjusting performance and rust preventing performance which are essential for practical use of a lubricant composed of an ionic liquid, and is dissolved or dispersed in the ionic liquid even when blended with the ionic liquid, and thus, does not inhibit performances as a base oil of the ionic liquid. The present invention relates to a synthetic lubricant including a fluorine atom-containing ionic liquid (A) as a main component, wherein the synthetic lubricant contains an imidazolium phosphate ester salt (B).Type: ApplicationFiled: January 28, 2011Publication date: February 28, 2013Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: You Honda, Naritoshi Kawata, Masahiro Yamaguchi, Shigeyuki Mori
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Publication number: 20120266837Abstract: The present invention relates to a lubricating composition, particularly marine diesel engine lubricating compositions, comprising: (a) an oil of lubricating viscosity; (b) an asphaltene dispersant comprising a cyclic headgroup that contains a nitrogen atom and at least one other heteroatom; and (c) a detergent derived from an alkyl phenol. The invention further provides methods of using such compositions in the operation of engine, particularly marine diesel engines.Type: ApplicationFiled: July 28, 2010Publication date: October 25, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: William R.S. Barton, Stephen J. Cook, Daniel J. Saccomando, Alexandra Mayhew, Joanne L. Jones, Shaun P. Carney
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Patent number: 8268761Abstract: Disclosed are aminomethyl-substituted imidazole compounds and their use as friction modifiers in lubricating oils. Also disclosed is a process for preparing the aminomethyl-substituted imidazole compounds. A further aspect is directed to a lubricating oil composition and a lubricating oil additive concentrate having the aminomethyl-substituted imidazole compounds of the present invention.Type: GrantFiled: December 8, 2009Date of Patent: September 18, 2012Assignee: Chevron Oronite Company LLCInventors: Yat Fan Suen, Miranda L. Lackie, Farzan Parsinejad
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Publication number: 20110152145Abstract: Provided are an anti-wear agent comprising a heterocylclic compound having a heterocyclic skeleton derived from a compound selected from pyridines, pyrroles, pyrimidines, pyrazoles, pyridazines, imidazoles, pyrazines, triazines, triazoles, tetrazoles, oxazoles, oxadiazoles, thiazoles, thiadiazoles, furans, dioxanes, pyrans, and thiophenes and/or comprising a reaction product of the heterocyclic compound and a compound selected from a boron compound, a molybdenum compound, and a silicon compound, which is an anti-wear agent for a lubricating oil excellent in wear resistance, friction-reducing property, and base number-retaining property, and a lubricating oil composition comprising the anti-wear agent.Type: ApplicationFiled: June 30, 2008Publication date: June 23, 2011Applicant: Idemitsu Kosan Co., Ltd.Inventors: Hideki Kamano, Hiroaki Koshima
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Patent number: 7910528Abstract: There is provided a finished lubricant, comprising: a) a major amount of hydroisomerized Fischer-Tropsch wax, Fischer-Tropsch oligomerized olefins, or mixture thereof; and b) between about 0.10 and about 5 wt % of a solubility improver having an aniline point less than 10° C.; wherein the finished lubricant passes the 4 hour TORT B rust test.Type: GrantFiled: September 24, 2009Date of Patent: March 22, 2011Assignee: Chevron U.S.A. Inc.Inventor: Mark E. Okazaki
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Patent number: 7906466Abstract: A finished lubricant having a kinematic viscosity at 40° C. between about 90 and 1700 cSt that passes the 4 hour TORT B rust test, comprising: a) greater than 65 weight percent API Group III base oil, API Group IV base oil, polyinternal olefin base oil, or mixtures thereof; and b) between about 0.10 wt % and about 5 wt % solubility improver. The solubility improver has an aniline point less than 50° C., or even lower. The finished lubricant can additionally comprise a mixture of amine phosphates.Type: GrantFiled: December 30, 2009Date of Patent: March 15, 2011Assignee: Chevron U.S.A. Inc.Inventor: Mark E. Okazaki
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Publication number: 20100152078Abstract: A lubricant additive composition having environmentally compatible characteristics as defined by European Council Directive 67/548/EEC is disclosed. Such a composition may include components selected from non-persistent materials, non-bioaccumulative materials, or non-toxic materials.Type: ApplicationFiled: February 12, 2010Publication date: June 17, 2010Inventors: Ian MacPherson, Ann Pettigrew
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Publication number: 20090118150Abstract: The present invention provides a process for preparing a polymer, employing the steps of: (1) contacting a free radical initiator; a chain transfer agent containing a thiocarbonyl thio group and a free radical leaving group; and a radically polymerisable monomer, to form a polymer chain; and (2) contacting the polymer chain of step (1) with at least one of a polyvalent coupling agent, a polymerisation inhibitor, a grafting acylating agent, an amine and an oil of lubricating viscosity. The invention further provides compositions and uses for the polymer.Type: ApplicationFiled: October 21, 2005Publication date: May 7, 2009Inventors: Marina Baum, Barton J. Schober, Mark Davies, Daniel C. Visger, John R. Johnson
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Publication number: 20080312115Abstract: The invention relates to an additive composition, which comprises an additive mixture that essentially consists of a) At least one ammonium phosphate ester; b) At least one thiophosphoric acid ester, and c) At least one dithiophosphoric acid derivative; in combination with sulphur containing oil additives; and a process for the reduction of wear in combustion engines, such as spark ignition or Diesel motor engines.Type: ApplicationFiled: March 13, 2006Publication date: December 18, 2008Inventor: Marc Ribeaud
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Patent number: 6998368Abstract: A composition comprising: (a) from 0.1% to 20% of at least one cyclic compound having a nitroxyl group and a thioamide group; and (b) a lubricating oil.Type: GrantFiled: June 19, 2003Date of Patent: February 14, 2006Assignee: Rohm and Haas CompanyInventor: Ravindranath Mukkamala
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Patent number: 6734149Abstract: A composition comprising a compound of formula I: wherein W represents O, S—A2, or two groups, R3 and R4; bonds a and b are single or double bonds, provided that one of a and b is a single bond and the other is a double bond; c is a single or double bond, and d is a single bond, double bond, or two single bonds, provided that d is a single bond when c is a double bond, d is not a single bond when c is a single bond, and W is R3 and R4 when d is two single bonds; A1, A2, B1 and B2 are independently hydrogen, alkyl, alkenyl, aralkyl or one of the groups depicted in Scheme 1: and a dithiophosphate.Type: GrantFiled: June 10, 2002Date of Patent: May 11, 2004Assignee: Rohm and Haas CompanyInventor: Ravindranath Mukkamala
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Publication number: 20040029745Abstract: A composition comprising: (a) from 0.1% to 20% of at least one cyclic compound having a nitroxyl group and a thioamide group; and (b) a lubricating oil.Type: ApplicationFiled: June 19, 2003Publication date: February 12, 2004Inventor: Ravindranath Mukkamala
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Publication number: 20040029742Abstract: A composition comprising: (a) from 0.1% to 20% of at least one compound comprising: (i) a five-, six-, or seven-membered ring containing a thiourea functional group; and (ii) at least one of (A) a carbocyclic ring system fused to the five-, six-, or seven-membered ring; and (B) an aryl, aralkyl, C4-C22 alkyl or C4-C22 alkenyl group attached to a ring carbon atom of the five-, six-, or seven-membered ring; and (b) a lubricating oil.Type: ApplicationFiled: August 7, 2003Publication date: February 12, 2004Inventor: Ravindranath Mukkamala
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Publication number: 20040029746Abstract: A composition comprising: (a) from 0.Type: ApplicationFiled: August 7, 2003Publication date: February 12, 2004Inventor: Ravindranath Mukkamala
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Patent number: 6669872Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.Type: GrantFiled: July 13, 2001Date of Patent: December 30, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
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Patent number: 6602832Abstract: An oil-soluble lubricant additive composition comprising: (a) at least one compound of formula I: wherein R1, R2, R3 and R4 are independently hydrogen, alkyl, alkenyl, aryl or aralkyl; or R1 and R2, or R3 and R4, combine with the carbon atom to which they are attached to form an alkyl or alkenyl ring; and (b) an acid having the formula RCO2H, wherein R is C1-C25 alkyl, C2-C25 alkenyl, C2-C25 alkynyl, C5-C25 aryl or C5-C25 aralkyl.Type: GrantFiled: January 22, 2002Date of Patent: August 5, 2003Assignee: Crompton CorporationInventors: Ravindranath Mukkamala, Rajiv Manohar Banavali
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Patent number: 6602831Abstract: A compound of formula I: wherein W represents O, S—A2, or two groups, R3 and R4; bonds a and b are single or double bonds, provided that one of a and b is a single bond and the other is a double bond; c is a single or double bond, and d is a single bond, double bond, or two single bonds, provided that d is a single bond when c is a double bond, d is not a single bond when c is a single bond, and W is R3 and R4 when d is two single bonds; A1, A2, B and B2 are independently hydrogen, alkyl, alkenyl, aralkyl or one of the groups depicted in Scheme 1:Type: GrantFiled: January 22, 2002Date of Patent: August 5, 2003Assignee: Rohm and Haas CompanyInventor: Ravindranath Mukkamala
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Publication number: 20020198115Abstract: A composition comprising a compound of formula I: 1Type: ApplicationFiled: June 10, 2002Publication date: December 26, 2002Inventor: Ravindranath Mukkamala
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Patent number: 6462000Abstract: The use of copolymers containing structural units derived from the compounds of the formulae 1 and 2 in which R1 and R2 are H, C1-C4 alkyl or, with inclusion of the N—CO— group, form a ring of 5, 6, 7 or 8 ring atoms which in addition to the N—CO— group, may include further heteroatoms, R3 is H or C1-C4 alkyl, R4 is a branched or unbranched C1-C6 alkylene radical, and Y is an alkali metal or ammonium in amounts of from 0.01 to 2% by weight to prevent misting in water-based cooling lubricants.Type: GrantFiled: July 6, 2000Date of Patent: October 8, 2002Assignee: Clariant GmbHInventors: Rainer Kupfer, Karl Heinz Heier
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Publication number: 20020142921Abstract: A compound of formula I: 1Type: ApplicationFiled: January 22, 2002Publication date: October 3, 2002Inventor: Ravindranath Mukkamala
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Publication number: 20020137638Abstract: An oil-soluble lubricant additive composition comprising:Type: ApplicationFiled: January 22, 2002Publication date: September 26, 2002Inventors: Ravindranath Mukkamala, Rajiv Manohar Banavali
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Patent number: 6448208Abstract: A description is given of products obtainable by reacting components a), b), c) and, if desired, d), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II, component c) is a component of the formula IIIa and/or of the formula IIIb or a mixture of compounds of the formula IIIa and/or IIIb, and component d) is a compound of the formula IV or a mixture of compounds of the formula IV, in which the general symbols are as defined therein, where the compound of the formula I is, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,2-propanediol, diethylene glycol, triethylene glycol, 1,1,1-tris(hydroxymethyl)ethane, 2,2-dimethyl-1,3-propanediol or glycerol, the compound of the formula II is, for example, methyl 3-(3′,5′-di-tert-butyl-4′-hydroxyphenyl)propionate or methyl 3-(3′-tert-butyl-4′-hydroxy-5′-methylphenyl)-proType: GrantFiled: August 21, 2000Date of Patent: September 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Paul Dubs, Roger Martin, Samuel Evans, Stephan Allenbach, Marc Ribeaud
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Publication number: 20010044389Abstract: Transmission lubricant compositions comprise a mineral oil as a base oil of which % CP and % CA defined in ASTM D 3238 are 70 or more and 3 or less, respectively, a viscosity index improver, and a friction modifier. The transmission lubricant compositions have excellent low temperature fluidity, shear stability, and durability of anti-shudder properties and thus can be used for extended periods of time.Type: ApplicationFiled: March 21, 2001Publication date: November 22, 2001Applicant: Nippon Mitsubishi Oil CorporationInventors: Kenichi Komiya, Akira Yaguchi, Osamu Kurosawa
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Patent number: 6200938Abstract: Amphoteric derivatives of aliphatic polyamines, such as diethylenetriamine or triethylenetetramine reacted with long chain fatty acids, esters or triglycerides from various natural or synthetic sources are effective in the softening/texture modification of substrates such as paper, textiles, human skin surfaces and hair tresses, as well as in applications for metal working and lubrication. The polyamines are first reacted with fatty acids, esters or triglycerides derived from various animal, vegetable or synthetic sources ranging in molecular distribution from butyric through erucic acids (e.g. milkfat, soy bean oil, rapeseed oil) to form polyamines or imidazolines; they are then further reacted with unsaturated or halogenated carboxylic acids, carboxylated epoxy compounds or acid anhydrides (e.g. acrylic acid, itaconic acid, chloroacetic acid, maleic anhydrides octadecenyl anhydride) to form the various amphoteric structures.Type: GrantFiled: December 20, 1999Date of Patent: March 13, 2001Assignee: Mona Industries, Inc.Inventors: James e. Perella, Joseph A. Komor, Richard D. Katstra
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Patent number: 6187722Abstract: Disclosed herein is a composition comprising: (A) a lubricant, and (B) at least one imidazole thione compound of the formula: wherein R1, R2, R3, and R4 are independently selected from the group consisting of alkyl, functionalized alkyl, and hydrogen.Type: GrantFiled: July 22, 1999Date of Patent: February 13, 2001Assignee: Uniroyal Chemical Company, Inc.Inventors: Robert G. Rowland, Cyril A. Migdal
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Patent number: 6013200Abstract: A water soluble corrosion inhibitor containing a compound having at least one five-membered heterocyclic ring having at least one thione group and at least one other pendant group is described. Such a corrosion inhibiting compound can be made by reacting together a thiourea and a polyalkylene polyamine. A specific example includes preparing 1-(2-aminoethyl)-2-imidazolidinethione by reacting thiourea, per se, and diethylenetriamine. These corrosion inhibition compounds have greatly reduced aquatic toxicity, and may be employed as corrosion inhibitors in hydrocarbon streams.Type: GrantFiled: October 31, 1997Date of Patent: January 11, 2000Assignee: Baker Hughes IncorporatedInventor: Philippe Prince
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Patent number: 5935913Abstract: Disclosed herein is a composition comprising:(A) a lubricant, and(B) at least one cyclic thiourea selected from the group consisting of: ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of alkyl, functionalized alkyl, and hydrogen.Type: GrantFiled: October 16, 1998Date of Patent: August 10, 1999Assignee: Uniroyal Chemical Company, Inc.Inventors: Theodore T. Nalesnik, Cyril A. Migdal
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Patent number: 5693596Abstract: A water-soluble cutting fluid is produced by dissolving a polymer fatty acid triglyceride imidazole, 2-methyl-1-stearate, and boric acid imidazole in the dispersion of inorganic bentonite in water thereby preparing a main component and adding oleic acid (agent for enhancing the lubricity), Na salt of ethylenediamine tetraacetic acid (metallic ion adsorbent), benzotriazole (rust-preventing auxiliary agent), and a silicone type defoaming agent to the main component.Type: GrantFiled: October 23, 1995Date of Patent: December 2, 1997Assignee: Shin-Etsu Handotai Co., Ltd.Inventors: Shingo Kaburagi, Akio Ashida, Etsuo Kiuchi, Kazuo Hayakawa, Kohei Toyama
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Patent number: 5599779Abstract: This invention relates to synergistic rust inhibiting compositions consisting of (a) N-acylsarcosine compound, (b) dicarboxylic acid having 6 to 48 carbon atoms, and (c) an amine selected from primary, secondary or tertiary amines or imidazoline compounds.Lubricating compositions containing the synergistic rust inhibiting compositions possess good antirust stability.Type: GrantFiled: March 20, 1996Date of Patent: February 4, 1997Assignee: R. T. Vanderbilt Company, Inc.Inventors: Thomas J. Karol, Steven G. Donnelly, Brian W. Stunkel