With Organic Sulfonate Compound Patents (Class 508/372)
  • Patent number: 9587288
    Abstract: This gear has a predetermined chemical composition and has, in a surface-layer part, a texture of tempered martensite and/or tempered bainite and a steel material texture in which retained austenite exists in 1-10% by area percentage and in which a carbide is deposited in at least 5% by area percentage, and the nitrogen content at a depth of 20 ?m below the surface is 2.0-6.0%. Thus, a gear that achieves even better seizing resistance in a power transmission part subjected to high rotation and high slippage and using a low-kinematic-viscosity lubricating oil is provided.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: March 7, 2017
    Assignee: Kobe Steel, Ltd.
    Inventors: Sayaka Nagamatsu, Yosuke Shindo
  • Patent number: 8754017
    Abstract: An engine fueled by natural gas may be lubricated by providing thereto a lubricant composition of an oil of lubricating viscosity, an overbased monovalent metal detergent in an amount to provide at least about 0.01 weight percent monovalent metal to the lubricant composition, wherein the monovalent metal comprises about 10 to about 30 percent by weight of the total metal content of the lubricant composition, an overbased divalent metal detergent, in an amount to provide at least about 0.005 percent by weight of the divalent metal to the lubricant composition, a dispersant, and a metal salt of a phosphorus acid. The lubricant composition has a sulfated ash of less than about 0.8 percent.
    Type: Grant
    Filed: July 13, 2009
    Date of Patent: June 17, 2014
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, Mayur Shah
  • Publication number: 20130345103
    Abstract: A gear oil composition is provided having fuel saving performance and providing gears or bearings with sufficient durability. The composition includes a base oil having a blend of (A) a mineral lubricating base oil having a 100° C. kinematic viscosity of 2 to 6 mm2/s, a % CA of 0.5 or less and a tertiary carbon content of 7% or more and (B) a solvent-refined mineral lubricating oil having a 100° C. kinematic viscosity of 10 to 70 mm2/s in an amount of 2 to 40 percent by mass based on the total base oil composition mass; (D) zinc dialkyldithiophosphate in an amount of 0.02 to 0.5 percent by mass based on the zinc amount; and (E) an alkaline earth metal detergent having a base number of 100 mgKOH/g or greater in an amount of 0.1 to 0.5 percent by mass, based on the metal amount, of the gear oil composition mass.
    Type: Application
    Filed: September 13, 2011
    Publication date: December 26, 2013
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Hajime Nakao, Hitoshi Komatsubara
  • Patent number: 8586516
    Abstract: There is disclosed a Super Tractor Oil Universal lubricating composition comprising an oil of lubricating viscosity formulated with an additive package comprising at least one metal detergent, at least one phosphorus-based wear preventative, and at least one molybdenum compound. Methods for improving the braking performance of a tractor and the anti-wear protection of a tractor engine are also disclosed.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: November 19, 2013
    Assignee: Afton Chemical Corporation
    Inventors: Jeffrey L. Milner, Peter L. Leitner, John M. Pietras
  • Publication number: 20130137617
    Abstract: A method for improving fuel efficiency, while maintaining or improving wear protection, in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil having a HTHS viscosity of less than 2.6 cP at 150° C. In one form, the formulated oil has a composition that includes a lubricating oil base stock as a major component, and zinc dialkyl dithio phosphate, a mixture of (i) at least two alkali metal detergents, (ii) at least two alkaline earth metal detergents, or (iii) one or more alkali metal detergents and one or more alkaline earth metal detergents; and a viscosity index improver, as minor components. The lubricating oil has a HTHS viscosity of less than 2.6 cP at 150° C. The composition contains less than 2 weight percent of the viscosity index improver, based on the total weight of the formulated oil or lubricating engine oil.
    Type: Application
    Filed: November 13, 2012
    Publication date: May 30, 2013
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventor: ExxonMobil Research and Engineering Company
  • Patent number: 8367592
    Abstract: To provide a lubricant for metallic material working and a method of press working a metallic material that makes it possible to improve the working accuracy of a press worked product and prolong the life of the die assembly beyond prior levels of life. [Solution] A lubricant for metallic material working comprises a mixture of a sulfur-based extreme pressure agent, an organic zinc compound, a calcium-based additive, and an ester compound, with lubricant base oil. The sulfur-based extreme pressure agent has a sulfur content of 5% by weight or higher based on the total weight of the lubricant. The organic zinc compound has a zinc content of 0.5% by weight or higher based on the total weight of the lubricant. The calcium-based additive has a calcium content of 0.5% by weight or higher based on the total weight of the lubricant. And the ester compound occupies a content of 1.0% by weight or higher based on the total weight of the lubricant.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: February 5, 2013
    Assignee: Toyota Boshoku Kabushiki Kaisha
    Inventors: Mami Kato, Masami Sakakibara, Teruo Fukaya, Yoshio Miyasaka
  • Patent number: 8163681
    Abstract: A lubricant composition of a synthetic oil of lubricating viscosity, 3 to 6 percent by weight of a nitrogen-containing dispersant, 1 to 2.5 weight percent of an overbased magnesium detergent, 1 to 5 weight percent of an antioxidant; and 0.25 to 1.5 weight percent of a friction modifier is useful for lubricating a hydrogen-fueled engine. The composition will typically contain less than 0.01 weight percent Ca, less than 0.01 weight percent Zn, less than 0.06 weight percent P, and will have a sulfated ash level of less than 1.2%.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: April 24, 2012
    Assignee: The Lubrizol Corporation
    Inventors: Ewa Bardasz, William B. Chamberlain
  • Patent number: 8088720
    Abstract: The present invention is directed to method of making a green lubricant composition having improved wear protection and reduced phosphorus emissions.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: January 3, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jacob J. Habeeb, Douglas E. Deckman, Brandon T. Weldon, William L. Maxwell
  • Patent number: 7989406
    Abstract: An additive to a fuel oil for a Diesel engine having a Diesel particulate filter (DPF), which comprises a molybdenum compound and having the function of improving the combustion property of a particulate matter (PM) trapped with DPF; a fuel oil comprising the additive; a lubricating oil composition for a Diesel engine having DPF, which has a sulfated ash content of 1.0% by weight or smaller, a sulfur content of 0.3% by weight or smaller and a molybdenum content of 100 ppm or greater; and DPF for removing PM in combustion gas discharged from a Diesel engine vehicle by trapping and burning PM, DPF comprising a filter supporting a molybdenum compound. The combustion property of PM trapped with the filter of DPF is improved, PM is burned at a low temperature with stability, the efficiency of removal of PM is improved and the life of DPF is increased.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: August 2, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Tadashi Katafuchi
  • Patent number: 7704928
    Abstract: Provided is a lubricating oil composition for manual transmissions which has anti-seizure properties for shift forks and can provide manual transmissions with excellent shifting characteristics though it has a low viscosity and can save fuel to be used in automobiles. The lubricating oil composition for manual transmissions comprises a lubricating base oil with a kinematic viscosity at 100° C. of 4 to 6 mm2/s, on the basis of the total mass of the composition, (A) 0.14 to 0.20 percent by mass in terms of magnesium of magnesium sulfonate, (B) 0.14 to 0.18 percent by mass in terms of zinc of a specific zinc dithiophosphate, (C) 0.3 to 0.5 percent by mass in terms of sulfur of a sulfur-containing extreme pressure additive other than zinc dithiophosphate, and (D) 0.02 to 0.05 percent by mass in terms of phosphorus of an alkyl phosphite, and having a kinematic viscosity at 40° C. of 25 to 30 mm2/s.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: April 27, 2010
    Assignees: Nippon Oil Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Osamu Kurosawa, Masato Takahashi, Toru Matsuoka, Kazuo Yamamori, Koji Saito, Tetuzo Yoneda, Yoshikazu Yamamoto, Akihiko Ichikawa
  • Publication number: 20090192063
    Abstract: There is disclosed a lubricating composition comprising an oil of lubricating viscosity formulated with an additive package comprising at least one overbased metal detergent, at least one neutral metal detergent, and at least one phosphorus-based wear preventative. Methods for improving oxidation performance in a TO-4 fluid for use in heavy vehicle machinery are also disclosed.
    Type: Application
    Filed: December 17, 2008
    Publication date: July 30, 2009
    Applicant: Afton Chemical Corporation
    Inventors: David B. Gray, Charles A. Passut, Lee D. Saathoff
  • Patent number: 7285516
    Abstract: Lubricating oils containing an additive formulation including at least one sulphonate, saligenin and salixarate detergent provide improved wear performance and decreased sulphur and phosphorus emissions.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: October 23, 2007
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, R. Ian Wilby, James P Roski
  • Patent number: 7183241
    Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: February 27, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Stanley James Cartwright
  • Patent number: 6919300
    Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: July 19, 2005
    Assignee: Ashland Inc.
    Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
  • Patent number: 6790813
    Abstract: Oil compositions and formulated crankcase engine oils demonstrate improved fuel economy performance when comprising an overbased sulfonate detergent having a total base number greater than about 450 and which contain at least one other additive which includes a succinimide type dispersant. Methods for improving fuel economy employing such high TBN sulfonates and engine oil formulations and concentrates containing such are disclosed.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: September 14, 2004
    Assignee: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Patent number: 6730638
    Abstract: A lubricating composition for internal combustion engines especially useful with fuels having less than 350 ppm sulfur comprises a lubricating oil basestock, a boron containing ashless dispersant, a molybdenum containing friction reducing agent, a metal type detergent and zinc dithiophosphate.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: May 4, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Liehpao O. Farng, Andrew Jackson, Willie A. Givens, Jr., Douglas E. Deckman, William H. Buck
  • Patent number: 6727208
    Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and an additive system comprising (A) from about 0.1 to about 5% by weight of a detergent composition comprising at least two metal overbased compositions wherein said detergent composition consists essentially of (A-1) at least one alkali metal overbased detergent and (A-2) at least one calcium overbased detergent, wherein the ratio of total base number on a per 100 TBN and diluent-free basis contributed by the alkali metal detergent to the total base number contributed by the calcium detergent ranges from about 99.5-20 to about 0.5-80; (B) from about 1 to about 10% by weight of a succinimide dispersant; and (C) from about 0.1 to about 5 % by weight of a metal dihydrocarbyl dithiophosphate of the formula (I) wherein R1 and R2 are each, independently, hydrocarbyl groups containing from 3 to 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: April 27, 2004
    Assignee: The Lubrizol Corporation
    Inventor: Melody A. Wilk
  • Patent number: 6723685
    Abstract: A lubricating oil composition comprising a) an oil of lubricating viscosity having a viscosity index of at least 95; b) at least one calcium detergent; c) at least one oil soluble molybdenum compound; d) at least one organic ashless nitrogen-free friction modifier; and e) at least one metal dihydrocarbyldithiophosphate compound, the composition having a Noack volatility of about 15 wt. % or less, from 0.05 to 0.6 wt. % calcium from the calcium detergent, molybdenum in an amount of at least 10 ppm from the molybdenum compound, and phosphorus from the metal dihydrocarbyldithiophosphate compound in an amount up to about 0.1 wt. %.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: April 20, 2004
    Assignee: Infineum International Ltd.
    Inventors: Rolfe J. Hartley, Malcolm Waddoups
  • Publication number: 20040014613
    Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.
    Type: Application
    Filed: July 2, 2002
    Publication date: January 22, 2004
    Applicant: ASHLAND INC.
    Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
  • Patent number: 6656887
    Abstract: Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: wherein R2, R1, R3 and R4 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X1, X2, X3 and X4 are each independently oxygen or sulfur, but at least one of them is oxygen, and Y1 is a metal atom; and wherein R11 and R12 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X11 and X12are each independently oxygen or sulfur, but at least one of them is oxygen, U is a monovalent metal ion, an ammonium ion or a proton, and k1 is an integer of 1 to 20. Lubricating oil compositions have excellent anti-wear properties and base number maintaining properties.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: December 2, 2003
    Assignee: Nippon Mitsubishi Oil Corporation
    Inventors: Kazuhiro Yagishita, Jinichi Igarashi, Takeo Koizumi
  • Publication number: 20030199399
    Abstract: A lubricating oil composition comprising a) an oil of lubricating viscosity having a viscosity index of at least 95; b) at least one calcium detergent; c) at least one oil soluble molybdenum compound; d) at least one organic ashless nitrogen-free friction modifier; and e) at least one metal dihydrocarbyldithiophosphate compound, the composition having a Noack volatility of about 15 wt. % or less, from 0.05 to 0.6 wt. % calcium from the calcium detergent, molybdenum in an amount of at least 10 ppm from the molybdenum compound, and phosphorus from the metal dihydrocarbyldithiophosphate compound in an amount up to about 0.1 wt. %.
    Type: Application
    Filed: April 5, 2002
    Publication date: October 23, 2003
    Inventors: Rolfe J. Hartley, Malcolm Waddoups
  • Publication number: 20030158048
    Abstract: A lubricating composition for internal combustion engines especially useful with fuels having less than 350 ppm sulfur comprises a lubricating oil basestock, a boron containing ashless dispersant, a molybdenum containing friction reducing agent, a metal type detergent and zinc dithiophosphate.
    Type: Application
    Filed: January 24, 2003
    Publication date: August 21, 2003
    Inventors: Liehpao O. Farng, Andrew Jackson, Willie A. Givens, Douglas E. Deckman, William H. Buck
  • Patent number: 6605571
    Abstract: Concentrates for lubricating oil compositions are prepared by blending at elevated temperature: (A) at least one high molecular weight ashless dispersant; and (B) at least one oil-soluble metal detergent; in the presence of (C) at least one metal salt of a dihydrocarbylphosphorodithoic acid wherein the metal of the metal salt is an alkali metal, an alkaline earth metal, or zinc, aluminium, lead, tin, molybdenum, manganese, nickel or copper.
    Type: Grant
    Filed: April 2, 1999
    Date of Patent: August 12, 2003
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary Higton, Roger Glyde, Robert A. Wilkinson
  • Patent number: 6562766
    Abstract: Provided is a metal working oil composition not containing a chlorine compound. Its working capabilities in low-speed cutting or heavy cutting operations such as broaching or gun-drilling operations are comparable to or better than those of chlorine compound-containing lubricant oil. The composition comprises 100 parts by weight of a lubricant base oil that comprises from 0 to 30% by weight of (a) a mineral base oil and from 70% to 100% by weight of (b) a &pgr; electron-containing synthetic base oil, from 0.1 to 25 parts by weight of (c) a sulfur-containing extreme-pressure agent, and from 0.1 to 7 parts by weight of (d) an alkali metal and/or alkaline earth metal sulfonate.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: May 13, 2003
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Saburo Koyama, Hiroshige Matsuoka, Ryouichi Okuda
  • Publication number: 20030013620
    Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and an additive system comprising (A) from about 0.1 to about 5 % by weight of a detergent composition comprising at least two metal overbased compositions wherein said detergent composition consists essentially of (A-1) at least one alkali metal overbased detergent and (A-2) at least one calcium overbased detergent, wherein the ratio of total base number on a per 100 TBN and diluent-free basis contributed by the alkali metal detergent to the total base number contributed by the calcium detergent ranges from about 99.5-20 to about 0.5-80; (B) from about 1 to about 10 % by weight of a succinimide dispersant; and (C) from about 0.1 to about 5 % by weight of a metal dihydrocarbyl dithiophosphate of the formula (I) wherein R1 and R2 are each, independently, hydrocarbyl groups containing from 3 to 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.
    Type: Application
    Filed: May 23, 2002
    Publication date: January 16, 2003
    Inventor: Melody A. Wilk
  • Patent number: 6500786
    Abstract: Lubricating oil compositions exhibititing improved low temperature valve train wear performance with a lowered phosphorus content, which contain a reduced amount of a metal hydrocarbyl dithiophosphate, a molybdenum compound, a metal-free friction modifier and a phosphorus-free antioxidant.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: December 31, 2002
    Assignee: Infineum International Ltd.
    Inventors: Rolfe J. Hartley, Malcolm Waddoups
  • Publication number: 20020119896
    Abstract: Lubricant compositions comprise a lubricant base oil, and (A) a mono substituted amide type bissuccinimide in an amount from 0.5 to 20 percent by mass, (B) zinc dithiophosphate in an amount from 0.05 to 0.3 percent by mass of phosphorus, and (C) a metal-based detergent in an amount form 0.5 to 4.0 percent by mass of sulfated ash, based on the total mass of the composition. Lubricant compositions preferably further comprises (D) a dispersant type viscosity index improver in an amount from 0.1 to 20 percent by mass, based on the total mass of the composition.
    Type: Application
    Filed: September 27, 2001
    Publication date: August 29, 2002
    Applicant: NIPPON MITSUBISHI OIL CORPORATION
    Inventors: Kazuhiro Yagishita, Jinichi Igarashi, Osamu Kurosawa
  • Patent number: 6426323
    Abstract: To provide a lubricating oil composition for continuously variable transmission which ensures both a high coefficient of friction between metals required for a push belt-type CTV oil and an excellent wear preventing property relative to a belt and a pulley. A lubricating oil composition for continuously variable transmission is provided, which comprises a lubricating base oil made of a mineral oil and/or a synthetic oil formulated with a metal detergent and a phosphorus-based wear preventive characterized in that a ratio between a content (ppm) of a metal derived from said metal detergent and based on the total weight of the lubricating oil composition and a total base number (mg KOH/g) ranges 0.75-4.5 (ppm/mg KOH/g), and a ratio between the content (ppm) of the metal derived from said metal detergent and a content of phosphorus derived from said phosphorus-based wear preventive ranges 0.5-2.0 (ppm/ppm).
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: July 30, 2002
    Assignee: TonenGeneral Sekiyu K.K.
    Inventors: Takehisa Sato, Takanori Kugimiya
  • Patent number: 6423670
    Abstract: A heavy duty diesel engine lubricating oil composition having no more than 0.10 wt. % phosphorus comprises an ashless dispersant, a neutral calcium phenate, an overbased calcium or magnesium sulfonate, a metal dihydrocarbyldithiophosphate, and a phenolic or aminic antioxidant.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: July 23, 2002
    Assignee: Infineum International Ltd.
    Inventors: Christopher J. Locke, Isabel P. MacDonald
  • Patent number: 6413916
    Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: July 2, 2002
    Assignee: Ashland Inc.
    Inventors: Richard J. Baumgart, Michael A. Dituro, Christopher J. Nonevski, Mandeep S. Saini
  • Patent number: 6323162
    Abstract: The present invention provides for a lubricant oil composition for internal combustion engines, that resists oxidation in the presence of NOx and evaporation characteristics, and controls poisoning of a three-way catalyst system for occluding/reducing NOx and formation of deposit in an air intake system. The lubricant oil composition for internal combustion engines, comprises a base oil, which contains aromatic compounds at 1 wt. % or less, sulfur at 10 ppm or less, and paraffin and monocyclic naphthene compounds at 50 wt. % or more as total content, and has a kinematic viscosity of 2 to 50 mm2/s at 100° C. and evaporated quantity of 16 wt. % or less determined by the NOACK evaporation test, wherein the base oil is incorporated with a zinc dithiophosphate at 0.04 to 0.10 wt. % as phosphorus, a calcium phenate and/or calcium sulfonate having a total basic number of 100 to 400 mg KOH/g at 1 to 10 wt. %, and a polyalkenyl succinimide having a boron/nitrogen wt. ratio of 0 to 1.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: November 27, 2001
    Assignee: TonenGeneral Sekiyu K.K.
    Inventors: Sougawa Yasunori, Katsuya Arai
  • Patent number: 6310010
    Abstract: Concentrates for lubricating oil compositions are prepared by mixing at elevated temperature: (i) at least one high molecular weight ashless dispersant; (ii) at least one oil-soluble overbased metal detergent; and (iii) at least one surface-active agent comprising a low molecular weight hydroxyl or amine group.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: October 30, 2001
    Assignee: Exxon Chemicals Patents INC
    Inventors: Gary Higton, Jacob Emert, Robert A. Wilkinson, Isabel P. MacDonald, Karl J. Van Driesen, Salvatore Rea, James P. Stokes, Andrew J. D. Ritchie
  • Publication number: 20010019999
    Abstract: A lubricating oil composition containing a base oil of lubricating viscosity, overbased sulfurized alkylphenate detergent or its calcium salt, an overbased alkylsulfonate detergent or its calcium salt, an ashless dispersant, and a zinc dialkyldithiophosphate and/or zinc diaryldithiophosphate is described. The lubricating oil composition provides improved heat stability and anti-wear performance in marine diesel engines operated under severe conditions where the cylinder liner temperature reach 200 to 260° C.
    Type: Application
    Filed: February 9, 2001
    Publication date: September 6, 2001
    Inventors: Hiroyuki Nagamatsu, Shigeru Iwamoto, Hirokazu Fujita
  • Patent number: 6268315
    Abstract: Conditioning oil for use on bowling lanes. The oil contains a mixture of mineral oil, a leveling agent, and an antistatic agent. The mineral oil is a combination of paraffin and petroleum based mineral oils and/or a polyalphaolefin synthetic oil, and in some embodiments, the mixture also includes a flow agent, a fluorescent whitening agent, a lubricity agent, and a surfactant.
    Type: Grant
    Filed: May 15, 2000
    Date of Patent: July 31, 2001
    Assignee: Lane Masters, Inc.
    Inventors: Joseph Samuel Baca, Hermas N. Beaudet
  • Patent number: 6140279
    Abstract: Concentrates for lubricating oil compositions are prepared by mixing at elevated temperature:(i) at least one high molecular weight ashless dispersant;(ii) at least one oil-soluble overbased metal detergent; and (iii) at least one other concentrate additive provided that the additive is first mixed with the detergent or the dispersant.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: October 31, 2000
    Assignee: Exxon Chemical Patents Inc
    Inventors: Jacob Emert, Isabel P. MacDonald
  • Patent number: 6074993
    Abstract: A lubricating oil composition exhibiting improved fuel economy and wet clutch friction properties, which comprises: (a) an oil of lubricating viscosity; (b) at least one calcium or magnesium overbased detergent; (c) an oil soluble dimeric molybdenum compound; (d) an oil soluble organic trinuclear molybdenum compound; (e) at least one zinc dihydrocarbyldithiophosphate compound, wherein the composition has a TBN of at least 3.6 from the calcium or magnesium overbased detergent, a NOACK volatility of about 15 wt. % or less, molybdenum in an amount up to about 350 ppm from the trinuclear molybdenum compound, molybdenum in an amount up to 2,000 ppm from the dimeric molybdenum compound, and phosphorus in an amount up to about 0.1 wt. % from a zinc dihydrocarbyldithiophosphate compound.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: June 13, 2000
    Assignee: Infineuma USA L.P.
    Inventors: Malcolm Waddoups, Rolfe J. Hartley, Taisuke Miyoshi
  • Patent number: 6060437
    Abstract: A lubricating oil composition for internal combustion engines comprises:(A) a major amount of a basestock of lubricating viscosity containing from greater than 35 to less than 70 mass % of one or more PAO's, the balance preferably being one or more Group I basestocks as defined in API 1509; and(B) two or more additive components such as an ashless dispersant and a metal detergent.
    Type: Grant
    Filed: July 29, 1998
    Date of Patent: May 9, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Robert Robson, Trevor Anthony Brettell
  • Patent number: 6010988
    Abstract: A lubricating oil composition for a wet clutch, particularly for an automatic transmission, which comprises mineral oil, synthetic oil or a mixture thereof as a base oil, and which contains 0.1 to 4.0% by weight of at least one compound selected from the group consisting of calcium sulfonate and calcium phenate, 0.1 to 0.5% by weight of zinc dithiophosphate, and 0.1 to 1.5% by weight of a bisphenol antioxidant, each based on the total weight of the lubricating oil composition. The composition has excellent initial anti-shudder properties, anti-shudder properties of long duration, and good thermal-oxidative stability.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: January 4, 2000
    Assignee: Mitsubishi Oil Co., Ltd.
    Inventors: Toru Matsuoka, Hisayuki Wada, Susumu Yoshida, Naozumi Arimoto
  • Patent number: 6010986
    Abstract: Disclosed is a composition for reducing the copper-lead bearing corrosion of a formulation that includes a major amount of an oil of lubrication viscosity and a minor amount of a corrosion-reducing additive comprising:(A) a dispersant with a total base number of from 20 to 160 on an oil-free basis, with the proviso that the dispersant is substantially boron-free;(B) a metal salt of a phosphorus acid; and(C) a metal overbased composition comprising at least one carboxylate, phenate, or sulfonate wherein the metal is lithium, sodium, potassium, magnesium or calcium, and wherein the improvement comprises(D) a borate ester.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: January 4, 2000
    Assignee: The Lubrizol Corporation
    Inventors: Carl F. Stachew, James R. Shanklin
  • Patent number: 6008165
    Abstract: 1. A composition for reducing the copper-lead bearing corrosion of a formulation that includes a major amount of an oil of lubrication viscosity and a minor amount of a corrosion-reducing additive comprising(A) a borated dispersant with a total base number of from 20 to 160 on an oil-free basis;(B) a metal salt of a phosphorus acid; and(C) a metal overbased composition comprising at least one carboxylate, phenate, or sulfonate wherein the metal is lithium, sodium, potassium, magnesium or calcium, and wherein the improvement comprises(D) a borate ester.The borated ester and borated dispersant provide from 20 to about 800 parts per million (ppm) mass of boron in the composition.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: December 28, 1999
    Assignee: The Lubrizol Corporation
    Inventors: James R. Shanklin, Carl F. Stachew
  • Patent number: 5883055
    Abstract: Bowling lane conditioning oil in an aerosol container which has a propellant for dispensing the oil through a spray nozzle in an aerosol form. The oil includes a mixture of mineral oil, a leveling agent, and an antistatic agent. The mineral oil is a combination of paraffin and petroleum based mineral oils, and in some embodiments, the mixture also includes isopropyl alcohol, a fluorescent whitening agent, and a lubricity agent.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: March 16, 1999
    Assignee: Lane Masters, Incorporated
    Inventor: Joseph Samuel Baca
  • Patent number: 5672571
    Abstract: A grease composition for constant velocity joints comprises (a) a base oil; (b) a lithium-containing thickener selected from the group consisting of lithium soap and lithium complex soap; (c) an organic molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates; (d) a zinc dithiophosphate; (e) a sulfur-phosphorus extreme pressure agent free of any metal; and (f) a calcium salt selected from the group consisting of calcium salts of oxidized waxes, calcium salts of petroleum sulfonates and calcium salts of alkyl aromatic sulfonates. The grease composition for constant velocity joints exhibits a substantially improved effect of reducing friction coefficient and a substantially improved effect of reducing the axial force proportional to the third order component of rotation.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: September 30, 1997
    Assignee: Kyodo Yushi Co., Ltd.
    Inventors: Ko Hatakeyama, Shinya Kondo
  • Patent number: 5595962
    Abstract: A lubricant composition is disclosed which provides good antiwear characteristics in air at .gtoreq.100.degree. C. and exhibits a low friction coefficient, said composition comprising:(A) a fluorosilicone oil;(B) at least one compound selected from the group consisting of ferrocene, 1,1'-bis(diphenylphosphino) ferrocene and an N,N-disalicylidene-diaminoalkane in which the alkane portion has 3-6 carbon atoms; and(C) at least one phosphorous compound selected from the group consisting of triphenylphosphine, tri-o-tolylphosphine, 1,5-bis-diphenylphosphinopentane and a dialkyldithiophosphate salt in which the alkyl groups have 1-14 carbon atoms, wherein said components (B) and said component (C) is each present at a level of 0.01 to 0.3 percent based on the total weight of said composition.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: January 21, 1997
    Assignee: Dow Corning Corporation
    Inventors: Gerardo Caporiccio, Hugh A. Spikes