Nitrogen Attached Indirectly To The Nitrogen By Nonionic Bonding Patents (Class 508/556)
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Patent number: 9029304Abstract: An oil-soluble lubricating oil additive composition comprising (a) at least 3.5 wt-% of at least one friction modifier selected from the group consisting of fatty acids, fatty acid amides, fatty acid esters, and alkane diols which have a melting point of greater than 30° C.; (b) at least 10 wt-% actives dispersant; and (c) a sufficient amount of surfactant to make said additive composition haze-, sediment-, and skin-free, provided that said additive composition contains at least 150 mm surfactant per kg of said lubricating oil additive composition.Type: GrantFiled: September 30, 2008Date of Patent: May 12, 2015Assignee: Chevron Oronite Company LLCInventor: Deane S. Walker
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Patent number: 8969266Abstract: The invention provides a lubricating composition comprising an oil of lubricating viscosity and an amine-functionalized additive, wherein the amine-functionalized additive is derived from an amine having at least 3 aromatic groups, at least one —NH2 functional group, and at least 2 secondary or tertiary amino groups. The invention further provides for the additive to have improved thermal and oxidative stability modifying properties. The lubricating composition may include circulating oils, turbine oils, hydraulic fluids, transformer oils and greases as well as others that require good oxidation stability and good rust inhibition properties.Type: GrantFiled: June 1, 2011Date of Patent: March 3, 2015Assignee: The Lubrizol CorporationInventors: Seth L. Crawley, Matthew R. Sivik, Betsy J. Butke
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Publication number: 20140329916Abstract: Provided herein is a non-naturally occurring microbial organism having a methanol metabolic pathway that can enhance the availability of reducing equivalents in the presence of methanol. Such reducing equivalents can be used to increase the product yield of organic compounds produced by the microbial organism, such as adipate, 6-aminocaproate, hexamethylenediamine or caprolactam. Also provided herein are methods for using such an organism to produce adipate, 6-aminocaproate, hexamethylenediamine or caprolactam.Type: ApplicationFiled: December 16, 2013Publication date: November 6, 2014Applicant: Genomatica, Inc.Inventors: Anthony P. Burgard, Robin E. Osterhout, Stephen J. Van Dien, Cara Ann Tracewell, Priti Pharkya, Stefan Andrae
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Patent number: 8835366Abstract: Provided are lubricant compositions with improved oxidative stability and frictional and wear resistance properties for use in engine oil applications. The lubricant compositions include: i) a first base stock selected from a Group I base stock, a Group II base stock or a combination thereof at 50 to 80 wt %; ii) a block copolymer at 1 to 10 wt %; iii) a viscosity modifier at 3 to 15 wt % selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes; and iv) an additive package including a combination of antioxidants, dispersants, detergents, friction modifiers and antiwear agents at 2 to 30 wt %.Type: GrantFiled: December 22, 2011Date of Patent: September 16, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Abhimanyu Onkar Patil, Jacob Joseph Habeeb, Benjamin Daniel Eirich, Nicole D. Vaughn, Charles Lambert Baker, Jr.
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Patent number: 8822392Abstract: A lubricating oil comprising a major amount of a base oil and a minor amount of an additive package, and the additive package comprises at least one friction modifier selected from compounds of the formulae II, III and IV, and carboxylate salts thereof: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 28 carbon atoms, n is 0 or 1; and the carboxylate salts have a cation that is an alkali metal, alkaline earth metal, group IIB metal, or ammonium cation. Methods of using the engine oil to improve thin film and/or boundary layer friction in an engine are also provided.Type: GrantFiled: July 18, 2013Date of Patent: September 2, 2014Assignee: Afton Chemical CorporationInventor: John T. Loper
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Publication number: 20140162923Abstract: Hindered amines useful as ashless TBN sources for lubricating oil compositions that are compatible with fluoroelastomeric engine seal materials, and lubricating oil compositions containing such compounds.Type: ApplicationFiled: December 10, 2012Publication date: June 12, 2014Inventors: Tushar K. Bera, Joseph P. Hartley, Guifeng Li, Gabriele Candido, Christina E. Gulacsy
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Patent number: 8664442Abstract: A dialkylanilino-cyclohexane compound useful as an antioxidant has the following formula I or formula II: wherein Ar1 and Ar2 can be the same or different and each is an alkylaromatic group; each of R1, R2, R3, and R4 is independently selected from hydrogen or CR7R8; each of R5, R6, and R7 is independently selected from hydrogen and a substituted or unsubstituted C1 to C32 hydrocarbyl group; and each R8 is independently selected from hydrogen and a C1 to C2 alkyl group, provided that when, each of R1 and R2 is CR7R8 and each such R8 is other than hydrogen, R1 and R2 may be joined to form a five or six-membered ring, and provided further that when, each of R3 and R4 is an adjacent CR7R8 and each such R8 is other than hydrogen, R3 and R4 may be joined to form a five or six-membered ring.Type: GrantFiled: September 9, 2008Date of Patent: March 4, 2014Assignee: Chemtura CorporationInventor: Theodore E. Nalesnik
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Patent number: 8642520Abstract: Compositions comprising silicone fluids are formulated to provide improved metal-to-metal lubrication. Such Lubricating compositions comprise a major amount of (1) one or more siloxane polymer (“silicone fluids”) selected from dimethyl siloxane polymers (also known as dimethyl silicone) and/or phenylmethyl dimethyl siloxane copolymers (also known as phenyl silicone), and lesser amounts of (2) synthetic and/or bio-based ester co-fluid, and (3) an alkoxylated aliphatic polyamine derivative. Unexpectedly, the compositions show a significant improvement in metal-to-metal lubrication, performing better than either the silicone fluids alone or and a combination of silicone with-ester and or silicone with-alkoxylated aliphatic polyamine combinations.Type: GrantFiled: June 29, 2011Date of Patent: February 4, 2014Assignee: Vanderbilt Chemicals, LLCInventors: Gaston A. Aguilar, Francis S. Cheng, Ronald J. Tepper
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Patent number: 8623798Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a N,N,N?,N?-tetraalkyl-naphthalene-1,8-diamine and at least one additive selected from antioxidants, dispersants, and detergents which together provide superior oxidation inhibition and are suitable lubricants for automotive and truck crankcase lubricants; as well as transmission lubricants, gear lubricants, hydraulic fluids, compressor oils, diesel and marine lubricants.Type: GrantFiled: December 16, 2008Date of Patent: January 7, 2014Assignee: Chevron Oronite Company LLCInventors: Richard E. Cherpeck, Carrie Y. Chan, Gaurav Bhalla
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Patent number: 8530397Abstract: Compositions in the form of lubricating oil compositions, greases, fuels or functional fluids containing, in the form of Michael adducts, N-substituted phenylenediamine additives in which at least one of the substituents on the N atoms carries a carbonyl group that is connected to an alkyl, alkoxyalkyl, or alkylthioalkyl group either directly or via an oxygen atom.Type: GrantFiled: December 12, 2007Date of Patent: September 10, 2013Assignees: Infineum International Limited, Chemtura CorporationInventors: Tushar Kanti Bera, Rolfe J. Hartley, Jacob Emert, Jie Cheng, Theodore E. Nalesnik, Robert G. Rowland
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Publication number: 20130203638Abstract: The invention provides a lubricating composition comprising an oil of lubricating viscosity and an amine-functionalised additive, wherein the amine-functionalised additive is derived from an amine having at least 3 aromatic groups, at least one —NH2 functional group, and at least 2 secondary or tertiary amino groups. The invention further provides for the additive to have improved thermal and oxidative stability modifying properties. The lubricating composition may include circulating oils, turbine oils, hydraulic fluids, transformer oils and greases as well as others that require good oxidation stability and good rust inhibition properties.Type: ApplicationFiled: June 1, 2011Publication date: August 8, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: Seth L. Crawley, Matthew R. Sivik, Betsy J. Butke
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Patent number: 8481467Abstract: Lubricating oil compositions have low friction properties and anti-wear properties and are excellent in long drain capability. The lubricating oil compositions are particularly suitable for use as a fuel efficient type lubricating oil for internal combustion engines. The lubricating oil compositions contain a lubricating oil additive comprising one or more compounds selected from a specific nitrogen-containing compound, an acid-modified derivative thereof, and an oil soluble metal complex obtained by mixing the nitrogen-containing compound and/or acid-modified derivative thereof with an organic metal salt and/or organic metal complex.Type: GrantFiled: April 14, 2006Date of Patent: July 9, 2013Assignee: Nippon Oil CorporationInventors: Kazuhiro Yagishita, Shouzaburou Konishi
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Patent number: 8465665Abstract: The present invention provides a refrigerator oil composition which satisfies both sludge dispersibility and prevention of wear and seizing of sliding parts made of aluminum and/or iron, and a compressor and a refrigeration apparatus using the refrigerator oil composition. The refrigerator oil composition is characterized by comprising a base oil which is at least one member selected from mineral oils and synthetic oils, and at least one polyamide compound having two or more amide groups in the molecule and being present in an amount of 0.01 to 5% by mass based on the total amount of the refrigerator oil composition.Type: GrantFiled: June 29, 2011Date of Patent: June 18, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventor: Masato Kaneko
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Patent number: 8389450Abstract: The present invention relates to a lubricant concentrate containing the following components (i) at least one amine, (ii) at least one phosphate according to the general formula (I), (iii) at least one acid, (iv) optionally at least one ether carboxylic acid compounds with the general formula (II) R20—(O(CH2)m)nOCH2COO?M+??(II), (v) optionally at least one further aid or additive.Type: GrantFiled: September 22, 2011Date of Patent: March 5, 2013Assignee: Diversey, Inc.Inventors: Holger Theyssen, Mario Stanga, Franco Bruschi, Stefan Wiemer
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Publication number: 20130023455Abstract: Provided are lubricating compositions comprising in admixture at least 40 wt % of a base stock selected from the group consisting of Group I, Group II, Group III, Group IV and Group V base stocks, or any combination thereof, and one or more polyetheramines. Also provided are methods of improving the friction and wear properties of a base stock selected from the group consisting of Group I, Group II, Group III, Group IV and Group V base stocks, or any combination thereof, comprising blending the base stock with one or more polyetheramines, to form a lubricating composition.Type: ApplicationFiled: June 27, 2012Publication date: January 24, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Jacob Joseph Habeeb, Nicole D. Vaughn, Benjamin Daniel Eirich, Abhimanyu Onkar Patil, Charles Lambert Baker, JR., Beth A. Winsett
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Publication number: 20120178661Abstract: The present invention relates to an additive concentrate comprising a friction modifier, a corrosion inhibitor, and an oil of lubricating viscosity. The invention further provides a method for lubricating a transmission using the additive concentrate.Type: ApplicationFiled: March 27, 2012Publication date: July 12, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Susie Hurley, James L. Sumiejski
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Publication number: 20120115763Abstract: Provided are lubricant compositions with improved oxidative stability and frictional and wear resistance properties for use in engine oil applications. The lubricant compositions include: i) a first base stock selected from a Group I base stock, a Group II base stock or a combination thereof at 50 to 80 wt %; ii) a block copolymer at 1 to 10 wt %; iii) a viscosity modifier at 3 to 15 wt % selected from polymers and copolymers of methacrylate, butadiene, olefins and alkylated styrenes; and iv) an additive package including a combination of antioxidants, dispersants, detergents, friction modifiers and antiwear agents at 2 to 30 wt %.Type: ApplicationFiled: December 22, 2011Publication date: May 10, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Abhimanyu Onkar Patil, Jacob Joseph Habeeb, Benjamin Daniel Eirich, Nicole D. Vaughn, Charles Lambert Baker, JR.
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Patent number: 8119580Abstract: The present invention relates to a lubricant concentrate containing the following components (i) at least one amine, (ii) at least one phosphate according to the general formula (I), (iii) at least one acid, (iv) optionally at least one ether carboxylic acid compounds with the general formula (II) R20—(O(CH2)m)nOCH2COO?M+??(II), (v) optionally at least one further aid or additive.Type: GrantFiled: February 2, 2006Date of Patent: February 21, 2012Assignee: Diversey, Inc.Inventors: Holger Theyssen, Mario Stanga, Franco Bruschi, Stefan Wiemer
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Publication number: 20110239970Abstract: Disclosed is a method for improving copper corrosion performance of a lubricating oil composition containing (a) a major amount of a base oil of lubricating viscosity; and (b) one or more dispersants containing one or more basic nitrogen atoms. The method involves adding to the lubricating oil composition an effective amount of one or more copper corrosion performance improving agents containing one or more oil-soluble titanium compounds.Type: ApplicationFiled: March 31, 2010Publication date: October 6, 2011Applicant: Chevron Oronite Company LLCInventors: Keneth D. Nelson, Elaine S. Yamaguchi, Kam-Sik Ng, Paula S. Rogers
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Patent number: 8017805Abstract: Diaromatic amine compounds or an isomer or isomeric mixture thereof is provided having the general formula: wherein n, m, R, R1, R2, R3, R4 and R5 are as defined herein are provided. Lubricating oil compositions and stabilizer-containing compositions containing the diaromatic amine compounds are also provided.Type: GrantFiled: October 10, 2006Date of Patent: September 13, 2011Assignee: Chemtura CorporationInventor: Theodore E. Nalesnik
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Publication number: 20100152079Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a N,N,N?,N?-tetraalkyl-naphthalene-1,8-diamine and at least one additive selected from antioxidants, dispersants, and detergents which together provide superior oxidation inhibition and are suitable lubricants for automotive and truck crankcase lubricants; as well as transmission lubricants, gear lubricants, hydraulic fluids, compressor oils, diesel and marine lubricants.Type: ApplicationFiled: December 16, 2008Publication date: June 17, 2010Inventors: Richard E. Cherpeck, Carrie Y. Chan, Gaurav Bhalla
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Publication number: 20100062955Abstract: A dialkylanilino-cyclohexane compound useful as an antioxidant has the following formula I or formula II: wherein Ar1 and Ar2 can be the same or different and each is an alkylaromatic group; each of R1, R2, R3, and R4 is independently selected from hydrogen or CR7R8; each of R5, R6, and R7 is independently selected from hydrogen and a substituted or unsubstituted C1 to C32 hydrocarbyl group; and each R8 is independently selected from hydrogen and a C1 to C2 alkyl group, provided that when, each of R1 and R2 is CR7R8 and each such R8 is other than hydrogen, R1 and R2 may be joined to form a five or six-membered ring, and provided further that when, each of R3 and R4 is an adjacent CR7R8 and each such R8 is other than hydrogen, R3 and R4 may be joined to form a five or six-membered ring.Type: ApplicationFiled: September 9, 2008Publication date: March 11, 2010Inventor: Theodore E. Nalesnik
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Patent number: 7566687Abstract: Improved desulfurization compositions are provided for removing substantial fractions of sulfur, sulfur complexes, and sulfur compounds from liquid hydrocarbons such as crude oil and fuels. The preferred compositions comprise respective quantities of an alkylphenol ethoxylate, an amine, and an alkali metal nitrite. The compositions may be contacted with liquid hydrocarbons to achieve high levels of desulfurization.Type: GrantFiled: October 12, 2005Date of Patent: July 28, 2009Assignee: Jacam Chemical, LLCInventors: Gene H. Zaid, Beth Ann Wolf, Gary W. Zorn
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Publication number: 20090111720Abstract: This invention encompasses a lubricating oil composition contaminated with at least about 0.3 wt % of a biodiesel fuel or a decomposition product thereof, based on the total weight of the lubricating oil composition, comprising: a. a major amount of base oil of lubricating viscosity; and b. a diarylamine compound, wherein, the amount of the diarylamine compound is at least about 0.1 wt. %, based on the total weight of the lubricating oil composition. Methods of using the lubricating oil compositions are also described.Type: ApplicationFiled: October 26, 2007Publication date: April 30, 2009Inventor: Alexander B. Boffa
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Patent number: 7452851Abstract: Lubricant compositions having improved anticorrosion performance comprising an extreme pressure compound comprising a sulfur-containing compound, an antiwear compound comprising a phosphorous-containing compound, an alkylene amine friction modifying compound, a dispersant compound containing basic nitrogen, and a diluent or base oil as applicable, wherein any of compounds other than the diluent or base oil can be the same or different compounds. These lubricant compositions provide improved anticorrosion resistance and fatigue performance, which prolongs service lives of lubricated parts, especially those used in outdoor applications.Type: GrantFiled: October 24, 2003Date of Patent: November 18, 2008Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Helen T. Ryan
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Publication number: 20080248981Abstract: The lubricating oil composition of the invention comprises a lubricating base oil with a urea adduct value of no greater than 4% by mass and a viscosity index of 100 or higher, an ashless friction modifier at 0.01-10% by mass and a phosphorus-containing anti-wear agent at 0.01-0.2% by mass as phosphorus, based on the total amount of the composition.Type: ApplicationFiled: March 28, 2008Publication date: October 9, 2008Inventors: Shigeki Matsui, Kazuo Tagawa
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Patent number: 6548457Abstract: The present invention provides a lubricant for a compression type refrigeration system using ammonia as a refrigerant, which comprises polyether compounds and aromatic amine compounds or phenothiazine compounds, and preferably further comprises alcohol compounds such as polyhydric alcohol partial ether and/or benzotriazole compounds. Further, the present invention provides a working fluid composition comprising the lubricant and an ammonia refrigerant, and a refrigeration system which is filled with the working fluid composition. The lubricant has not only good compatibility with ammonia, but excellent stability and lubricating property, and therefore can suitably used in a compression type refrigeration system using an ammonia refrigerant that does not have the possibility of ozone layer depletion and global warming phenomenon.Type: GrantFiled: January 17, 2001Date of Patent: April 15, 2003Assignee: Japan Energy CorporationInventors: Takashi Kaimai, Hitoshi Takahashi
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Publication number: 20020103089Abstract: A lubricant composition for a surface treatment of a steel filament comprises at least one specified compound as a lubricant component and a rubber-steel filament composite body is prepared by using a steel filament treated with the lubricant composition.Type: ApplicationFiled: June 29, 2001Publication date: August 1, 2002Applicant: BRIDGESTONE CORPORATIONInventors: Yasuo Fukushima, Hajime Kondo
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Patent number: 6235687Abstract: Lubricating oils exhibiting anti rust properties are obtained by adding to the lubricating oil an acidic anti rust additive and an acid scavenger such as carbodiimide, in a specific sequence.Type: GrantFiled: September 21, 1999Date of Patent: May 22, 2001Assignee: Exxon Research and Engineering CompanyInventors: Todd Timothy Nadasdi, William Nelson Hayter
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Patent number: 5945388Abstract: A lubricating oil composition suitable for use in a low or medium speed diesel engine comprising a fuel oil with a residual oil content is characterised in that the lubricating oil composition further comprises a hydrocarbyl substituted amine or polyamine. The effect of such an amine is to reduce deposits due to the residual oil. A method of reducing deposits in a low or medium speed diesel engine is also disclosed.Type: GrantFiled: April 23, 1996Date of Patent: August 31, 1999Assignee: Lubrizol Adibis Holdings (UK) Ltd.Inventors: Stephen J. Cook, Sean P. O'Connor
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Patent number: 5906970Abstract: A dendrimer-based cold flow additive material.Type: GrantFiled: March 20, 1997Date of Patent: May 25, 1999Assignee: Exxon Chemical Patents Inc.Inventor: Robert Dryden Tack
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Patent number: 5900392Abstract: An aqueous belt lubricant composition comprising water and from 1.0 to 10 wt % of at least a fatty alkyl propylene tetramine, from 1.0 to 10 wt % of at least a fatty alcohol polygylcol ether, all percentages are based on the total weight of the aqueous belt lubricant composition, and at least one acid in an amount sufficient to establish a pH value between about 5.0 and about 7.0. The composition may further comprising one or more of alkoxylated fatty alkyl monoamines, alkoxylated fatty alkyl diamines and/or a solutizer.Type: GrantFiled: July 24, 1998Date of Patent: May 4, 1999Assignee: Loeffler Chemical CorporationInventor: Laut Bernhard
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Patent number: 5851969Abstract: The present invention is directed to a grease containing base oil, a thickener and a hydrocarbyl substituted diamine additive exhibiting enhanced resistance to corrosion.Type: GrantFiled: March 14, 1997Date of Patent: December 22, 1998Assignee: Exxon Research and Engineering CompanyInventors: David Leslie Andrew, Brian Leslie Slack
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Patent number: 5558808Abstract: Automatic transmission fluid containing a red dye stable even in long-lived transmission fluids.Type: GrantFiled: June 7, 1995Date of Patent: September 24, 1996Assignee: United Color Manufacturing, Inc.Inventors: Michael J. Smith, Bharat Desai
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Patent number: 5547593Abstract: Disclosed is a lubricant oil composition comprising: (A) a fluorine-containing aromatic compound, and(B) an alkyl- or alkyl derivative-substituted aromatic compound having a kinetic viscosity of from 0.1 to 500 cSt as measured at 40 .degree. C., wherein:the compound (A) is represented by the formula:R(XR.sub.f).sub.n (A)wherein X represents an oxygen or a sulfur atom; n is an integer of from 1 to 4; R represents an n-valent, unsubstituted or substituted aromatic group having from 6 to 60 carbon atoms; and R.sub.f represents an unsubstituted or partially substituted fluorocarbon group having from 1 to 25 carbon atoms; andthe compound (B) comprises at least one substituted aromatic nucleus, wherein a substituent is an unsubstituted or substituted alkyl group having from 1 to 30 carbon atoms, or a derivative thereof. The lubricant oil composition having a kinetic viscosity of from 2 to 500 cSt as measured at 40.degree. C.Type: GrantFiled: August 11, 1994Date of Patent: August 20, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kenichi Sanechika, Hiroyuki Fukui, Masanori Ikeda