Plural Nitrogens Bonded Directly To A Single Benzene Ring Patents (Class 508/557)
  • Patent number: 10538714
    Abstract: An additive composition improves the stability and the engine performances of gas oils, including gas oils of the non-road type in compliance with the decree of 10 Dec. 2010. The additive composition includes: at least one metal deactivator or chelating agent, at least one antioxidant of the hindered phenol type (alkylphenol), at least one dispersant and/or detergent, and at least one metal passivator, wherein the composition includes improved properties, in particular relative to the oxidation resistance, storage stability, thermal stability, reduction in fouling of the injectors, reduction in loss of power, reduction in the tendency of filters to clog.
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: January 21, 2020
    Assignee: Total Marketing Services
    Inventors: Frédéric Tort, Christian Vermorel
  • Patent number: 9523060
    Abstract: Compositions comprise first antioxidants and first additives, such as, a surface additives, performance enhancing additives and lubricant protective additives and optionally second additives and/or second antioxidants. The compositions are useful to improve lubricants, lubricant oils and other lubricant materials. The compositions and methods generally provide longer shelf lives, increased oxidative resistance, improved quality and/or enhanced performance to lubricants or lubricant oils.
    Type: Grant
    Filed: December 11, 2014
    Date of Patent: December 20, 2016
    Assignee: Polnox Corporation
    Inventors: Ashok L. Cholli, Ashish Dhawan, Rajesh Kumar, Vijayendra Kumar, Suizhou Yang, Taizoon Canteenwala
  • Patent number: 9321980
    Abstract: The present invention is a lubricant or functional fluid additive for a polyolefin oil blend, comprising a mixture of: (a) an anti-wear component consisting essentially of 95% isopropylated triarylphosphate and 5% dodecyl phosphate, the dodecyl phosphate being only partially esterified, the anti-wear component present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (b) an antioxidant component selected from the group consisting of alkylated phenyl-alpha-naphthylamine, phenyl-alpha-naphthylamine and mixtures thereof, and present in the polyolefin oil blend in a range of from about 0.75 percent to about 2.00 percent by weight; (c) an anti-rust component comprising an alkylated succinic acid ester anti-rust agent, and present in the polyolefin oil blend in a range of from about 0.050 percent to about 0.
    Type: Grant
    Filed: March 21, 2013
    Date of Patent: April 26, 2016
    Assignee: Materials Engineering and Technical Support Services Corp.
    Inventor: William F. Ricks
  • Patent number: 8987515
    Abstract: Radical initiated reactions of phenylenediamines with alkylated aromatic amines produce an antioxidant mixture containing cross reaction products of the phenylenediamines and alkylated aromatic amines which are useful, for example, as antioxidants, stabilizers, and antiozonants for lubricants, electronic chemicals, rubbers, urethanes and other polymer resins, crop protection, pharmaceuticals, dyes and toners.
    Type: Grant
    Filed: November 20, 2012
    Date of Patent: March 24, 2015
    Assignee: Chemtura Corporation
    Inventor: Robert G. Rowland
  • Patent number: 8741824
    Abstract: Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines, particularly heavy duty diesel engines, equipped with EGR systems, particularly EGR systems operating in a condensing mode, can be ameliorated by addition of a phenylenediamine compound.
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: June 3, 2014
    Assignee: Infineum International Limited
    Inventors: Dennis L. Malandro, Michael L. Alessi
  • Patent number: 8703682
    Abstract: Tetra-alkylated phenylenediamine compounds useful as ashless TBN sources for lubricating oil compositions that are compatible with fluoroelastomeric engine seal materials and meet copper corrosion requirements, and lubricating oil compositions containing such phenylenediamine compounds.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: April 22, 2014
    Assignee: Infineum International Limited
    Inventors: Joseph P. Hartley, Robert G. Rowland, Jie Cheng, Jacob Emert, Joseph Stieber
  • Patent number: 8563489
    Abstract: An alkylated 1,3-benzenediamine compound used as a deposit-control lubricant additives for organic materials including lubricating oil, gasoline, and diesel fuels. The invention improves the oxidative stability of the lubricants and fuels by adding the alkylated 1,3-benzenediamine compound. The alkylated 1,3-benzenediamine compound is formed using a catalytic hydrogenation that alkylates the 4 and/or 6 position of the central aromatic ring.
    Type: Grant
    Filed: September 17, 2008
    Date of Patent: October 22, 2013
    Assignee: Chemtura Corporation
    Inventors: Robert G. Rowland, Joseph F. Stieber, Clifford M. Pratt, Ronald D. Abbott
  • Publication number: 20130150275
    Abstract: Radical initiated reactions of phenylenediamines with alkylated aromatic amines produce an antioxidant mixture containing cross reaction products of the phenylenediamines and alkylated aromatic amines which are useful, for example, as antioxidants, stabilizers, and antiozonants for lubricants, electronic chemicals, rubbers, urethanes and other polymer resins, crop protection, pharmaceuticals, dyes and toners
    Type: Application
    Filed: November 20, 2012
    Publication date: June 13, 2013
    Applicant: CHEMTURA CORPORATION
    Inventor: Chemtura Corporation
  • Publication number: 20130130955
    Abstract: Compositions comprise first antioxidants and first additives, such as, a surface additives, performance enhancing additives and lubricant protective additives and optionally second additives and/or second antioxidants. The compositions are useful to improve lubricants, lubricant oils and other lubricant materials. The compositions and methods generally provide longer shelf lives, increased oxidative resistance, improved quality and/or enhanced performance to lubricants or lubricant oils.
    Type: Application
    Filed: May 11, 2012
    Publication date: May 23, 2013
    Applicant: Polnox Corporation
    Inventors: Ashok L. Cholli, Ashish Dhawan, Rajesh Kumar, Vijayendra Kumar, Suizhou Yang, Taizoon Canteenwala
  • Publication number: 20120178656
    Abstract: The disclosed invention relates to a composition comprising a grafted polymer. The polymer backbone comprises an olefin block and a vinyl aromatic block. The polymer backbone is grafted with a pendant carbonyl containing group, the grafting being conducted in oil in the presence of an initiator. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.
    Type: Application
    Filed: July 6, 2010
    Publication date: July 12, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Michael R. Sutton, William R.S. Barton, David Price, Mark C. Davies
  • Patent number: 8183191
    Abstract: A grease composition containing a lubricant base oil, diurea compounds represented by the following general formulas (1) to (3), and at least one species selected from the group consisting of paraffin oxides and phosphorus compounds; wherein respective contents of the diurea compounds represented by the following general formulas (1) to (3) satisfy conditions defined by the following expressions (4) and (5); and wherein the total content of the paraffin oxides and phosphorus compounds is 0.1 to 15 mass % based on the total amount of the grease composition: where R1 is a hydrocarbon group containing an aromatic ring, R2 is a divalent hydrocarbon group, and R3 is a hydrocarbon group containing an aliphatic ring; 5?W1+W2+W3?30??(4) 0.3?(W1+0.5×W2)/(W1+W2+W3)?0.7??(5) where W1, W2, and W3 are respective contents (mass %) of the diurea compounds represented by general formulas (1) to (3) based on the total amount of the grease composition.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: May 22, 2012
    Assignee: Nippon Oil Corporation
    Inventors: Hirotsugu Kinoshita, Souichi Nomura, Takashi Arai, Kiyomi Sakamoto
  • Patent number: 7977286
    Abstract: The invention comprises lubricating compositions and hydraulic fluids containing N,N?-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids. The invention further comprises a method of making N,N?-diaryl-o-phenylenediamine compounds.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: July 12, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu O. Patil, Jacob J. Habeeb, Michael E. Landis, Manuel A. Francisco, Manika Varma-Nair
  • Publication number: 20110105374
    Abstract: Monoaryltrialkyl phenylenediamine compounds useful as ashless TBN sources for lubricating oil compositions that are compatible with fluoroelastomeric engine seal materials and meet copper corrosion requirements, and lubricating oil compositions containing such phenylenediamine compounds.
    Type: Application
    Filed: October 29, 2009
    Publication date: May 5, 2011
    Inventors: Jie Cheng, Jacob Emert, Joseph P. Hartley, Robert G. Rowland, Joseph Stieber
  • Publication number: 20110105372
    Abstract: Tetra-alkylated phenylenediamine compounds useful as ashless TBN sources for lubricating oil compositions that are compatible with fluoroelastomeric engine seal materials and meet copper corrosion requirements, and lubricating oil compositions containing such phenylenediamine compounds.
    Type: Application
    Filed: October 29, 2009
    Publication date: May 5, 2011
    Inventors: Joseph P. Hartley, Robert G. Rowland, Jie Cheng, Jacob Emert, Joseph Stieber
  • Patent number: 7846884
    Abstract: Lubricating oil compositions containing (a) at least one oil of lubricating viscosity and (b) an effective amount of at least one thio-functionalized phenylenediamine compound of the general formula: wherein R1, R2, R3, R4 and n are as defined herein are provided. Methods of operating an engine employing the lubricating oil composition are also provided.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: December 7, 2010
    Assignee: Chemtura Corporation
    Inventor: Qinggao Ma
  • Patent number: 7759295
    Abstract: The invention comprises lubricating compositions and hydraulic fluids containing substituted N,N?-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: July 20, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu O. Patil, Jacob J. Habeeb
  • Patent number: 7704931
    Abstract: A lubricant composition is disclosed that comprises lubricating oil and a mixture of at least two antioxidants, the first antioxidant being a secondary diarylamine and the second antioxidant being a substituted para-phenylenediamine. Also disclosed is a method of increasing the oxidation stability of a lubricating oil comprising adding thereto at least two antioxidants, the first antioxidant being a secondary diarylamine and the second antioxidant being a substituted para-phenylenediamine.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: April 27, 2010
    Assignee: Chemtura Corporation
    Inventors: Jun Dong, Cyril A. Migdal
  • Patent number: 7683017
    Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a nitro-substituted diphenylamine and a diarylamine which together provide superior oxidation inhibition.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: March 23, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: Richard E. Cherpeck, Carrie Y. Chan
  • Publication number: 20090156448
    Abstract: Compositions in the form of lubricating oil compositions, greases, fuels or functional fluids containing, in the form of Michael adducts, N-substituted phenylenediamine additives in which at least one of the substituents on the N atoms carries a carbonyl group that is connected to an alkyl, alkoxyalkyl, or alkylthioalkyl group either directly or via an oxygen atom.
    Type: Application
    Filed: December 12, 2007
    Publication date: June 18, 2009
    Inventors: Tushar kanti Bera, Rolfe J. Hartley, Jacob Emert, Jie Cheng, Theodore E. Nalesnik, Robert G. Rowland
  • Publication number: 20090156449
    Abstract: An alkylated 1,3-benzenediamine compound used as a deposit-control lubricant additives for organic materials including lubricating oil, gasoline, and diesel fuels. The invention improves the oxidative stability of the lubricants and fuels by adding the alkylated 1,3-benzenediamine compound. The alkylated 1,3-benzenediamine compound is formed using a catalytic hydrogenation that alkylates the 4 and/or 6 position of the central aromatic ring.
    Type: Application
    Filed: September 17, 2008
    Publication date: June 18, 2009
    Inventors: Robert G. Rowland, Joseph F. Stieber, Clifford M. Pratt, Ronald D. Abbott
  • Publication number: 20080248984
    Abstract: The invention comprises lubricating compositions and hydraulic fluids containing N,N?-diaryl-m-phenylene diamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids.
    Type: Application
    Filed: April 3, 2007
    Publication date: October 9, 2008
    Inventors: Abhimanyu O. Patil, Jacob J. Habeeb
  • Publication number: 20080248985
    Abstract: The invention comprises lubricating compositions and hydraulic fluids containing substituted N,N?-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids.
    Type: Application
    Filed: April 3, 2007
    Publication date: October 9, 2008
    Inventors: Abhimanyu O. Patil, Jacob J. Habeeb
  • Publication number: 20070265178
    Abstract: The invention comprises lubricating compositions and hydraulic fluids containing N,N?-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids. The invention further comprises a method of making N,N?-diaryl-o-phenylenediamine compounds.
    Type: Application
    Filed: April 3, 2007
    Publication date: November 15, 2007
    Inventors: Abhimanyu O. Patil, Jacob J. Habeeb, Michael E. Landis, Manuel A. Francisco, Manika Varma-Nair
  • Publication number: 20040106526
    Abstract: A method for marking a liquid petroleum hydrocarbon. The method comprises adding to the liquid petroleum hydrocarbon: (i) at least one anthraquinone dye having an absorption maximum in the range from 710 nm to 850 nm selected from the group consisting of 1,4,5,8-tetrasubstituted anthraquinones and anthraquinone dimers; and (ii) at least one visible dye having an absorption maximum in the range from 500 nm to 700 nm.
    Type: Application
    Filed: November 12, 2003
    Publication date: June 3, 2004
    Inventors: David Roderick Baxter, Peter John Cranmer, Kim Sang Ho
  • Patent number: 6514917
    Abstract: Colorless markers for petroleum products and methods and composition for detecting them.
    Type: Grant
    Filed: June 7, 2000
    Date of Patent: February 4, 2003
    Assignee: United Color Manufacturing, Inc.
    Inventors: Michael J. Smith, Bharat Desai, Justin J. Frederico
  • Patent number: 6242394
    Abstract: A lubricant composition suitable for fuel injected two-stroke cycle engines includes an oil of lubricating viscosity, an amount, sufficient to reduce or prevent piston scuffing, of a mixture of (A) at least one phenol selected from (A-1) an aminophenol and (A-2) a reaction product of a nitrophenol and an amino compound, and (B) at least one Mannich dispersant, amine dispersant, nitrogen-containing carboxylic dispersant, or ester dispersant. The composition further includes an amount, sufficient to reduce degradation of the lubricant composition upon exposure to oxygen or oxides of nitrogen, of a nitrogen-containing inhibitor, a hindered phenol inhibitor, or a sulfur-containing organic inhibitor.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: June 5, 2001
    Assignee: The Lubrizol Corporation
    Inventor: William B. Chamberlin, III
  • Patent number: 6048827
    Abstract: In lubricant (5) of a magnetic recording medium made of conventional perfluoropolyether, one or more conductive high molecular compound is mixed. The conductive lubricant (5) prevents electric charge generated by frictional electricity from staying on the medium surface, and effectively prolongs the head-life by suppressing the break of the head element because of electric discharge between the disk medium and the head element. By employing the conductive lubricant, magnetic recording media and magnetic recording devices which are more reliable and durable can be realized.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: April 11, 2000
    Assignee: NEC Corporation
    Inventor: Takashi Fukuchi
  • Patent number: 5536427
    Abstract: A non-flammable electric discharge machining fluid for electric discharge machining which comprises a non-flammable water base solution, a block copolymer represented by the general formula: ##STR1## wherein n ranges from 1 to 5 and n/(m+p) ranges from 0.5 to 2.5. The fluid contributes to a lowered electrode wear rate and an improved machining removal rate.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: July 16, 1996
    Assignee: Sodick Co., Ltd.
    Inventors: Nobuyuki Takahashi, Makoto Sugai