Inorganic Acid Component (e.g., Sodium Bisulfate, Etc.) Patents (Class 510/269)
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Patent number: 6455483Abstract: A well stimulation and purging composition which is typically used in well cleanup, well stimulation and formation purging applications for enhancing oil and gas production. The composition is a cationic surfactant characterized by a homogenous aqueous solution of a coco diamine amido benzyl chloride type quaternary compound, phosphate chelator/ester, isopropanol anhydrous, ammonium bisulfide, and potassium chloride or a clay stabilizer formulation, and aids in extracting water and condensate from wells and dissipates, disperses and retards bacterial growth and buildup of iron sulfide, iron oxide, calcium and salt. The composition is applied to the wells in order to clear the water and condensate and significantly enhance total well production by chelating minerals such as salt, iron and calcium; retarding bacterial growth; and flocculating and foaming the water, condensate and solids from the well.Type: GrantFiled: September 11, 2000Date of Patent: September 24, 2002Inventor: Charles C. Carey
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Patent number: 6436891Abstract: An adduct that has an acidic solution of sparingly-soluble Group IIA complexes (“AGIIS”) and at least one additive. The AGIIS can be prepared by mixing a mineral acid (such as sulfuric acid), and a Group IIA hydroxide (such as calcium hydroxide) or a Group IIA salt of a dibasic acid (such as calcium sulfate), or a mixture of the two Group IIA compounds, followed by removing the solid formed. The additives can be an alcohol, an organic acid or a surface active agent. The composition has various uses, including cleaning, food production, decontamination, bioremediation, agricultural application, medical application, and detoxification of substances.Type: GrantFiled: February 9, 2000Date of Patent: August 20, 2002Assignee: Mionix CorporationInventors: Maurice Clarence Kemp, Robert B. Lalum, Zhong Wei Xie, Michael A. Cunha, Robert H. Carpenter, Zhang Shu, Yao Yu, David E. Lewis
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Patent number: 6432899Abstract: Cleaning and deoxidizing aluminum surfaces can be accomplished simultaneously by contacting the surfaces with an aqueous liquid composition that contains as its cleaning active ingredients (i) alcohols and/or ether alcohols, (ii) alkaline builders, and (iii) alkali stable surfactants, and, optionally but preferably, also contains fluoride and chelating agents.Type: GrantFiled: July 13, 2000Date of Patent: August 13, 2002Assignee: Henkel CorporationInventor: Terry D. Sjostrom
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Patent number: 6384001Abstract: A dilute composition for use in semiconductor processing includes both phosphoric acid and acetic acid. Each of the acidic components may be at a concentration of less than about 10% by volume of the dilute composition. The dilute composition can be used for cleaning various surfaces, such as, for example, patterned metal layers and vias by exposing the surfaces to the dilute composition.Type: GrantFiled: March 3, 1997Date of Patent: May 7, 2002Assignee: Micron Technology, Inc.Inventors: Max Hineman, Guy T. Blalock
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Patent number: 6355605Abstract: A cleaning composition and method are provided for removing iron stains and scale from the external surfaces of duck decoys. An illustrative composition contains hydrochloric acid, stannous chloride, ammonium bifluoride, and water. The compositions are applied to the duck decoys with a pressurized sprayer to discolor and dislodge the stain and scale and thereafter the decoys are water rinsed with a garden hose or the like to remove the dislodged material.Type: GrantFiled: July 3, 2001Date of Patent: March 12, 2002Inventors: David L. Weller, Charles C. Hager, Jr.
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Patent number: 6352967Abstract: A composition for treating a mineral acid using with a blend of sodium thiosulfate, sodium sulfite and trisodium phosphate. This formulation enhances the corrosion properties of a mineral acid to produce a superior acid reaction when measured in terms of corrosiveness or in terms of the time required to react with a chemical base or alkaline compound.Type: GrantFiled: July 19, 1999Date of Patent: March 5, 2002Inventor: David W. Irwin
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Patent number: 6284056Abstract: A composition useful for removal of organic deposits from a ceramic, glass, plastic, or metal substrate, and a method of use thereof. In a preferred embodiment, the invention pertains to a composition for cleaning an organically fouled smoking apparatus such as a pipe, a cigarette holder, or a water pipe, and to a process whereby the smoking apparatus is cleaned and disinfected.Type: GrantFiled: August 11, 1999Date of Patent: September 4, 2001Inventor: Gustavo M. Gonzalez
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Patent number: 6218349Abstract: The present invention provides for a composition suitable for removing proteinaceous material comprising water, an emulsifier, a chelating agent, one or more mineral acids, and a surfactant; wherein: the emulsifier is a polyether nonionic emulsifier or an amine oxide; the chelating agent is an alkylaminophosphonic acid, a hydroxyalkylphosphonic acid, or an alkylphosphonic acid carboxylic acid; the one or more mineral acids are present in an mount such that the pH of the composition is less than about 4.Type: GrantFiled: March 17, 2000Date of Patent: April 17, 2001Assignee: Ecolab, Inc.Inventors: Joseph I. Kravitz, Richard O. Ruhr, Michael E. Besse
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Patent number: 6194369Abstract: The invention relates to an aqueous preparation for the pickling and activation of aluminum-steel composites prior to electroless dip tinning. Specifically, the invention provides pickling/activation solutions for the pretreatment of aluminum-steel composites prior to dip tinning which comprise sulfuric acid, hexafluorosilicic acid, at least one wetting agent, at least one transition metal cation and nitrate and/or nitrite ions.Type: GrantFiled: June 25, 1999Date of Patent: February 27, 2001Assignee: Th. Goldschmidt AGInventors: Jan Eberhardt, Dieter Guhl, Frank Honselmann
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Patent number: 6153015Abstract: The process for removing a soap-contaminated conversion layer remaining on a metal workpiece after cold-forming with an aqueous acidic cleaning composition containing water, a surfactant such as an alkyl amine ethoxylate and nitric acid, phosphoric acid and/or amidosulphonic acid includes immersing the contaminated metal workpiece in the aqueous acidic cleaning composition at a temperature above 60.degree. C. until it has a clean bright surface and a fatty acid formed by reaction of the soap in the conversion layer is dispersed in the cleaning composition and then subsequently separating the metal workpiece from the cleaning solution and, after the separating, cooling the recovered aqueous acidic cleaning composition to a temperature below 55.degree. C. until a fatty acid layer including the fatty acid is separated from the aqueous acidic cleaning composition.Type: GrantFiled: December 8, 1998Date of Patent: November 28, 2000Assignee: Metallgesellschaft AGInventors: Joachim Geldner, Klaus Wittel, Georg Bluemlhuber
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Patent number: 6143709Abstract: Well stimulation and purging compositions for enhancing oil and gas production. The compositions include two base solutions which are typically used in combination with each other in well cleanup, well stimulation and formation purging applications. The first base solution is an anionic surfactant characterized by an aqueous solution of ether sulfate, isopropanol anhydrous, ammonium bisulfide, and either potassium chloride or a clay stabilizer formulation. In treatment of oil and gas wells, the solution is capable of reducing surface tension of well fluids and dissipating and dispersing various solids and minerals by dehydrating the well bore and well formation. The composition flocculates and foams the solids, minerals, water and condensate to the well surface.Type: GrantFiled: March 28, 2000Date of Patent: November 7, 2000Inventor: Charles C. Carey
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Patent number: 6124252Abstract: A multipurpose scale removal compound having a nonyl phenol ethoxylate with 10 moles of ethylene oxide at 0.85% of a total weight of the compound, hydrofluoric acid at 0.85% of the total weight of the compound, and softened water at 98.3% of the total weight of the compound. This multipurpose scale removal compound is formed by filling a reactor with 160 liters of softened water, adding 20 kilograms of hydrofluoric acid to the water in the first reactor, agitating the hydrofluoric acid and water in the first reactor, adding 20 kilograms of nonyl phenol ethoxylate with 10 moles of ethylene oxide to the first reactor, agitating the nonyl phenol ethoxylate, the ethylene oxide and the agitated hydrofluoric acid and water in the first reactor so as to obtain a uniform solution, adding 182.9 liters of softened water and 17.1 kilograms of the uniform solution to a second reactor, and agitating the softened water and uniform solution in the second reactor so as to obtain a uniform mixture.Type: GrantFiled: March 17, 1999Date of Patent: September 26, 2000Assignee: Lubrimak Corporation, S.A. de C.V.Inventor: Mario Alberto Chavez Amaro
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Patent number: 6121219Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.Type: GrantFiled: August 10, 1999Date of Patent: September 19, 2000Assignee: Ecolab Inc.Inventors: Brandon L. Herdt, David A. Halsrud
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Patent number: 5998358Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.Type: GrantFiled: March 23, 1999Date of Patent: December 7, 1999Assignee: Ecolab Inc.Inventors: Brandon L. Herdt, David A. Halsrud
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Concentrate for a dihydrogen phosphate-based metal cleaning composition that does not damage plastic
Patent number: 5998348Abstract: An aqueous liquid composition containing dihydrogen phosphate salt, surfactant(s), and a dual coordinate bonding agent for iron cleans soiled metal surfaces without damaging any plastic parts that come into contact with the composition, supporting the growth of bacteria that cause unpleasant odors, or obscuring the transparency of any transparent window that it contacts. The composition is particularly useful for cleaning unpainted aluminum sided rail transport cars that have polycarbonate housings insulating electrical contact points that provide motive electric power to the cars; many conventional aqueous alkaline and acid cleaners promote stress cracking of polycarbonate plastics.Type: GrantFiled: October 1, 1998Date of Patent: December 7, 1999Assignee: Henkel CorporationInventor: Donald P. Murphy -
Patent number: 5976265Abstract: A process for selectively removing an aluminide-containing coating from the surface of a metal-based substrate is disclosed. It includes the following steps:(a) contacting the surface of the substrate with at least one stripping composition to degrade the coating without severely pitting the substrate, wherein the stripping composition is selected from the group consisting of: (i) aliphatic or aromatic sulfonic acids; (ii) a solution of an inorganic acid and an organic solvent; and (iii) sulfuric acid or an aqueous solution of sulfuric acid; and then(b) removing the degraded coating without damaging the substrate.Type: GrantFiled: April 27, 1998Date of Patent: November 2, 1999Assignee: General Electric CompanyInventors: D. Sangeeta, Leo Spitz MacDonald
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Patent number: 5977051Abstract: A cleaning and dusting composition, particularly useful as a treatment for dusting implements such as a cloth or feather duster, comprised of a high quality natural wax in an alcohol solution. In the preferred embodiment, a near-saturated solution of lanolin in denatured ethyl alcohol is employed to provide a rapidly drying, non-smear, low residue, and safe dusting treatment composition.Type: GrantFiled: January 5, 1998Date of Patent: November 2, 1999Assignee: Joe A. Dominguez, Jr.Inventor: Joe A. Dominguez, Jr.
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Patent number: 5935921Abstract: The present invention relates to a liquid descaling composition containing a phosphoric acid, a phosphonic acid, a cationic surfactant, an amine oxide and water.Type: GrantFiled: January 26, 1999Date of Patent: August 10, 1999Assignee: Colgate-Palmolive Co.Inventor: Philippe Meunier
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Patent number: 5932024Abstract: Glass surfaces having titanium, stainless steel and/or other metals metallized thereon are denuded or reconditioned for a repeat of the initial metallization by contacting the initially metallized surface with an aqueous mixture of one or more strong mineral acids and various of the transition metal salts containing cerium, vanadium, niobium, praseodymium, zirconium, or hafnium, with the optional inclusion of a surfactant to effect removal of the titanium, stainless steel, or whatever metals that are present in or involved in the coating. Oxidation can usually be entirely completed within minutes at modest temperatures of about 20 to about 90 degrees Celsius. The resultants are then water washed, and flushed or scrubbed from the glass surface which can then be processed the same as new glass for repeating metallization with titanium or other metals.Type: GrantFiled: July 1, 1997Date of Patent: August 3, 1999Inventor: Jesse C. Moore
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Patent number: 5932020Abstract: An aqueous liquid composition containing dihydrogen phosphate salt, sulfur containing surfactant, and preferably a small amount of phosphoric acid cleans soiled metal surfaces without damaging any plastic parts that come into contact with the composition with the composition and without supporting the growth of bacteria that cause unpleasant odors. The composition is particularly useful for cleaning unpainted aluminum sided rail transport cars that have polycarbonate housings insulating electrical contact points that provide motive electric power to the cars; many conventional aqueous alkaline and acid cleaners promote stress cracking of polycarbonate plastics.Type: GrantFiled: April 8, 1997Date of Patent: August 3, 1999Assignee: Henkel CorporationInventor: Donald P. Murphy
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Patent number: 5905063Abstract: A remover solution composition for resist which comprises (a) a salt of hydrofluoric acid with a metal-free base, (b) a water-soluble organic solvent, and (c) water and optionally (d) an anticorrosive, and has a pH or 5 to 8. A method for removing resist which comprises the steps of (I) forming a resist layer on a substrate having a metal film, (II) light-exposing the resist layer through a mask pattern and subsequently developing the resist layer to form a resist pattern, and (III) dry-etching the substrate using the resist pattern as a mask and then removing the unnecessary resist and modified resist film with the remover solution composition.Type: GrantFiled: June 3, 1998Date of Patent: May 18, 1999Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Masahito Tanabe, Kazumasa Wakiya, Masakazu Kobayashi, Toshimasa Nakayama
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Patent number: 5830838Abstract: A solution for cleaning metal surfaces particularly non ferrous alloys such as copper, brass and high strength aluminum alloys. The solution is prepared by mixing Ca(OH).sub.2 and KOH with equivalent sulfuric acid in water then passing the solution through a 10 micron filter. The resulting concentrate can be used full strength or diluted depending on the degree of surface oxidation of the metal to be treated.Type: GrantFiled: August 26, 1996Date of Patent: November 3, 1998Inventors: Stephen R. Wurzburger, James M. Overton
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Patent number: 5821212Abstract: Hydrogen peroxide rinse aid solutions of the present invention added to hydrochloric acid rinse baths for acid pickled stainless steel enables hydrochloric acid rinse baths to easily remove stainless steel oxides and smutt from the surfaces of acid pickled stainless steel to produce a bright and clean finish that is comparable to the finish produced by nitric/hydrofluoric acid rinse systems.Type: GrantFiled: October 9, 1997Date of Patent: October 13, 1998Assignee: Crown Technology, Inc.Inventor: Joseph C. Peterson
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Patent number: 5792274Abstract: A remover solution composition for resist which comprises (a) a salt of hydrofluoric acid with a metal-free base, (b) a water-soluble organic solvent, and (c) water and optionally (d) an anticorrosive, and has a pH of 5 to 8. A method for removing resist which comprises the steps of (I) forming a resist layer on a substrate having a metal film, (II) light-exposing the resist layer through a mask pattern and subsequently developing the resist layer to form a resist pattern, and (III) dry-etching the substrate using the resist pattern as a mask and then removing the unnecessary resist and modified resist film with the remover solution composition.Type: GrantFiled: November 13, 1996Date of Patent: August 11, 1998Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Masahito Tanabe, Kazumasa Wakiya, Masakazu Kobayashi, Toshimasa Nakayama
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Patent number: 5776876Abstract: Effective, multi-use filter cleaning compositions include 5% to 60% of a strong acid, 1% to 40% of a surfactant, and 0.5% to 20% of a sequesterant/builder. The filter cleaning compositions optionally include 0.5% to 10% of a water soluble organic solvent, and/or 0.5% to 10% of a nonionic surfactant.Type: GrantFiled: July 18, 1996Date of Patent: July 7, 1998Assignee: Bio-Lab, Inc.Inventor: John P. Garris
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Patent number: 5759618Abstract: A coating composition of an alkoxy silane reacted with the surface of a glass substrate and a cleaning composition and method for cleaning said glass area is disclosed. The coating provides water repellency, durability and ease of cleaning to a glass or other siliceous surface. The coating is formed by applying an excess of an alkoxy solution containing a sulfuric acid to a glass surface with an excess of solution being applied. Preparatory to such coating application, the glass, especially if its surface is a weathered (non-virgin) surface, is cleaned vigorously with a cleaning solution containing water, phosphoric acid, hydrofluoric acid and sulfuric acid.Type: GrantFiled: February 27, 1997Date of Patent: June 2, 1998Assignee: Diamond Seal, Inc.Inventor: George S. Taylor
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Patent number: 5733859Abstract: Acidic aqueous cleaning compositions containing a strong acid and maleic acid are disclosed. The maleic acid provides improved surface safety.Type: GrantFiled: September 11, 1996Date of Patent: March 31, 1998Assignee: The Procter & Gamble CompanyInventors: Michel Jean Carrie, Axel Koenig, Eddy Vos
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Patent number: 5672578Abstract: Limescale removing compositions contain a low level of surfactant, i.e., less than about 1% and maleic acid and have a pH of from about 0.1 to about 4.5. The surfactant can be anionic, nonionic, amphoteric, or cationic, but is preferably cationic. The composition can be used neat, or diluted, by applying it to the surface to be treated, leaving it to react, and then rinsing.Type: GrantFiled: August 2, 1996Date of Patent: September 30, 1997Assignee: The Procter & Gamble CompanyInventors: Michel Jean Carrie, Eddy Vos
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Patent number: 5669980Abstract: A composition of matter is disclosed for cleaning an aluminum surface comprising:a hydroxy organic acid;an organic complexing agent;a phosphorous oxide acid;a nitrogen oxide acid;optionally a urea compound; andoptionally a compound having a fluoride ion.Type: GrantFiled: March 24, 1995Date of Patent: September 23, 1997Assignee: Atotech USA, Inc.Inventors: Maynard W. McNeil, Edward J. Reimbold, King C. Waldron
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Patent number: 5634979Abstract: The invention is a cleaning solution for degreasing metal articles which contains at least one chlorine-free nonionic surfactant with an HLB in the range of 6.5 to 9.5; a second chlorine-free nonionic surfactant with an HLB in the range of above 9.5 to about 14; a chlorinated nonionic surfactant, and an alkalinizing agent and optionally also one or more of anionic or amphoteric surfactant; hydrotroping agents; solubilizers; organic builders, and corrosion inhibitors. The preferred composition of the invention can replace a vapor degreasing process for cleaning oil, grease, and waxy-type contaminants from metal articles to the level of cleanliness required in the aerospace industry.Type: GrantFiled: December 22, 1994Date of Patent: June 3, 1997Assignee: Henkel CorporationInventors: Lawrence R. Carlson, Philip M. Johnson, Dennis A. Kent
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Patent number: 5607911Abstract: A biodegradable, acidic aqueous composition, with an anionic surfactant for the removal of rust, inorganic and organic deposits from a variety of surfaces. Said composition comprising Hydrochloric Acid, Phosphoric Acid, Tetrasodium EDTA, Anionic Surfactant, Perfume Oil, Dye and Water.Type: GrantFiled: April 22, 1996Date of Patent: March 4, 1997Inventors: Scott Levin, Eric Levin, Joseph Levin
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Patent number: 5603862Abstract: There disclosed a boiler compound which comprises as the effective components thereof: (A) metabisulfurous acid or metabisulfites; (B) aliphatic dicarboxylic acids or salts thereof represented by the general formula:M.sup.1 OOC--(CH.sub.2).sub.n --COOM.sup.,wherein M.sup.1 and M.sup.2 are each a hydrogen atom, a sodium atom, a potassium atom or an ammonium group and n is an integer of 1 to 10; and optionally (C) a water-soluble polymer for scale inhibitor. The boiler compound is safe for human health, has excellent stability, can be used as a liquid formulation having anticorrosion activity (activity of eliminating oxygen) or both of anticorrosion activity and antiscale activity and exhibits enhanced anticorrosion activity by increasing concentration of sulfite ion which is an oxygen scavenger.Type: GrantFiled: May 4, 1995Date of Patent: February 18, 1997Assignee: Kurita Water Industries Ltd.Inventors: Shiro Taya, Takayasu Ueda, Moriyasu Itoh