Liquid Make-up Patents (Class 514/845)
  • Patent number: 5463009
    Abstract: A fluorine-modified silicon compound having a polymerization degree of from 1 to 400 and containing at least one siloxane unit represented by formula (1): ##STR1## wherein R.sup.1 represents an aliphatic straight-chain or branched hydrocarbon group having 1 to 20 carbon atoms or an alicyclic hydrocarbon group having 5 to 10 carbon atoms or an aromatic hydrocarbon compound having 6 to 10 carbon atoms; and m represents 0 or an integer of from 1 to 10; a process for preparing the same; and a cosmetic containing the same are disclosed. The fluorine-modified silicone derivative exhibits high water- and oil-repellency to provide cosmetics which wear long and have a good feel on use.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: October 31, 1995
    Assignee: Kao Corporation
    Inventors: Jouji Okada, Akira Kawamata, Tadayuki Tokunaga, Makoto Torizuka, Masahiko Asahi
  • Patent number: 5455232
    Abstract: The invention relates to a pharmaceutical preparation comprising as an active ingredient at least one rhamnolipid or a pharmaceutically acceptable salt thereof, and a carrier and/or diluent, preferably comprising a rhamnolipid of the general formula: ##STR1## wherein R.sub.1 =H, alpha-L-rhamnopyranosyl; ##STR2## R.sub.3 =(C.sub.5 -C.sub.20)-saturated, -mono- of poly-unsaturated alkyl; R.sub.4 =(C.sub.5 -C.sub.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: October 3, 1995
    Inventors: Goran Piljac, Visnja Piljac
  • Patent number: 5447920
    Abstract: A cosmetic composition comprising an inclusion product having a slightly water-soluble component with a hydroxyalkylated cyclodextrin formulated therein.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: September 5, 1995
    Assignee: Shiseido Company Ltd.
    Inventors: Hajime Matsuda, Kenzo Ito, Akio Taki, Osamu Uejima
  • Patent number: 5447723
    Abstract: A method of providing a cosmetic product or a cleaning composition with defoaming properties, includes adding to the cosmetic product or the cleaning composition a triethanolamine product mixture which has not been distilled and which is composed of a major part by weight of triethanolamine; a minor part by weight of diethanolmono-C.sub.3-4 -alkanolamine and monoethanoldi-C.sub.3-4 -alkanolamine; and less than 1% by weight of a mixture of diethanolamine and monoethanolamine. Preferably, the triethanolamine product mixture is composed of from 60-90% by weight of triethanolamine; from 10-40% by weight of a mixture of diethanolmono-C.sub.3-4 -alkanolamine and monoethanoldi-C.sub.3-4 -alkanolamine; and less than 1% by weight of a mixture of diethanolamine and monoethanolamine.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: September 5, 1995
    Assignee: Berol Nobel AB
    Inventor: Rolf Skold
  • Patent number: 5443855
    Abstract: Cosmetic and pharmaceutical compositions containing effective amounts of substantially intact extensin proteins and the related methods.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: August 22, 1995
    Assignee: Revlon Consumer Products Corporation
    Inventors: Barbara Wolf, Marlene Tietjen
  • Patent number: 5441725
    Abstract: The present invention relates to cosmetic compositions containing at least one polyethoxylated vitamin E species, which may be prepared by reacting a vitamin E with ethylene oxide, and exhibit an excellent cell protecting activity in the living body. The cosmetic compositions in the form of a skin-care, hair-care, lip-care and make-up cosmetic composition, which contain at least one polyethoxylated vitamin E species in an amount of 0.01 to 50% by weight, provide a protection against harmful oxygen species, show a moisture retention ability, and increase the tensile strength of hair, and substantivity and durability of the cosmetic compositions, when applied to the skin or hair.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: August 15, 1995
    Assignee: Pacific Corporation
    Inventors: Young D. Kim, Chang K. Kim, Choong N. Lee, Byung J. Ha
  • Patent number: 5431912
    Abstract: The present invention addresses a cosmetic or dermopharmaceutical composition comprising, in a suitable vehicle, an antioxidizing system possessing a synergic effect consisting of the combination of laroylmethionate of lysine, histidine or arginine, and of at least one polyphenol chosen from:a) a derivative of (2,5-dihydroxyphenyl)-carboxylic acid, a homologue or a corresponding salt,b) an ester or amide of caffeic acid,c) a flavonoid or an extract containing flavenoids, andd) a rosemary extract containing diphenols, and their mixtures. The use of the antioxidizing system enables good preservation of compositions containing oxidation-sensitive fats.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: July 11, 1995
    Assignee: L'Oreal
    Inventor: Quang L. N'Guyen
  • Patent number: 5425938
    Abstract: Cosmetic compositions are described wherein .alpha.-hydroxyacids, .alpha.-ketoacids and related compounds are formed into amine salts through neutralization with a multi-amine functionalized polymer. Particularly preferred are glycolic acid and lactic acid salts of poly(ethylenimine).
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: June 20, 1995
    Assignee: Chesebrough-Pond's USA Co., Division of Conopco, Inc.
    Inventors: Alexander P. Znaiden, Anthony W. Johnson, Brian A. Crotty
  • Patent number: 5412004
    Abstract: A silicone polymer, a paste-like silicone composition prepared by kneading the silicone polymer and a silicone oil under a shearing force, and a water-in-oil type cosmetic composition comprising the paste-like silicone composition as an oil phase component are disclosed. The silicone polymer is prepared by the addition polymerization of components comprising an organohydrogenpolysiloxane R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (1) or R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (2) and a polyoxyalkylene C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-l (A) or an organopolysiloxane R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B) the components, including (1) or (A) as an essential component. The silicone polymer can swell in silicone oils and function as a viscosity increasing agent for silicone oils.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: May 2, 1995
    Assignees: Kose Corporation, Shin-Etsu Chemical Co., Ltd.
    Inventors: Kiyomi Tachibana, Koji Sakuta, Kenichi Isobe
  • Patent number: 5382433
    Abstract: Cosmetic formulations have activatable dormant pigments dispersed in an anhydrous base or vehicle. Shear forces applied to the cosmetic formulation following application to the skin causes activation of the dormant pigment thereby releasing the pigment and giving the original color of the anhydrous base or vehicle renewed intensity or a "long wearing" affect.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: January 17, 1995
    Assignee: Avon Products, Inc.
    Inventors: Harold E. Pahlck, Shari R. Martin, Michael E. Squires
  • Patent number: 5382588
    Abstract: Free radical deactivating 4- or 1,4-substituted, 2,2,6,6-tetramethyl piperidines are condensed with UV absorbing cinnamic acids or benzoic acids or benzoazols or benzophenones to produce skin anti-aging compounds and compositions which have both free radical deactivation and UV absorbing properties.
    Type: Grant
    Filed: October 14, 1993
    Date of Patent: January 17, 1995
    Assignee: 3V Sigma S.p.A.
    Inventor: Giuseppe Raspanti
  • Patent number: 5362482
    Abstract: A water-in-oil type emulsified solid composition containing (a) an oil component such as a silicone oil, (b) a solid wax and/or an oil-gelling agent, (c) water, and (d) (i) a polyoxyalkylene modified organopolysiloxane or (ii) a lipophilic surfactant and a hydrophobically treated powder, wherein the water content is 5% by weight or more, based upon the total amount of the composition.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: November 8, 1994
    Assignee: Shiseido Company Ltd.
    Inventors: Toshio Yoneyama, Yasuo Matsuoka, Harumi Suzuki, Shigenori Kumagai, Susumu Takada
  • Patent number: 5360788
    Abstract: This invention relates to personal care compositions, and, more specifically, to a composition comprising a pyrithione salt or acid, a basic lipopeptide, and a suitable carrier. The pyrithione plus the lipopeptide provide antimicrobial efficacy to the personal care composition. The personal care composition is useful in a variety of dermatological items, such as soaps, shampoos, and skin care medicaments.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: November 1, 1994
    Assignee: Olin Corporation
    Inventor: John D. Nelson
  • Patent number: 5330681
    Abstract: Stable diphase emulsions consisting of:a) perfluoropolyethers having perfluoroalkyl end groups;b) a conventional surfactant, dispersed inc) a continuous dispersing phase consisting of glycerol or of a polyhydroxylated compound containing at least three hydroxyl groups, selected from polyalcohols and saccharides, dissolved in a hydrophile solvent and/or water.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: July 19, 1994
    Assignee: Ausimont S.r.l.
    Inventors: Fabio Brunetta, Giovanni Pantini
  • Patent number: 5324506
    Abstract: Disclosed are colored cosmetic compositions that, when applied to a person's skin (e.g., the lips or cheeks), hair or nails, exhibit exceptional brilliance and clarity of color, and a method of using those compositions to provide an aesthetically pleasing appearance to the skin, hair or nails. The compositions comprise (a) a pigment formed by incorporating a solvated dye into a resin, and (b) a cosmetic carrier having admixed therein the pigment in an amount effective to provide an attractive cosmetic effect to the composition when it is applied to a person's skin, hair, or nails. The methods of this invention comprise applying an effective amount of the foregoing composition to a person's skin (e.g., lips or cheeks), hair or nails.
    Type: Grant
    Filed: July 6, 1992
    Date of Patent: June 28, 1994
    Assignee: Estee Lauder, Inc.
    Inventors: Louis C. Calvo, David W. Peters
  • Patent number: 5308621
    Abstract: The present invention concerns a composition for topical application to deliver ascorbic acid by transdermal migration. The composition includes fine particulate ascorbic acids suspended in a pharmaceutically acceptable carrier. The invention also concerns methods of treatment, involving such a composition.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: May 3, 1994
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Reginald M. Taylor, David J. Wilson
  • Patent number: 5294444
    Abstract: A cosmetic composition is provided comprising (A) 0.05-30% by weight of an amphiphatic lipid, (B) 0.05-30% by weight of a nonionic surfactant, (C) 1-50% by weight, based on (b), of an ionic surfactant, and (D) 40-99% by weight of an aqueous medium, wherein said composition is transparent or semi-transparent, and wherein the ratio of (A)/[(B)+(C)] is 0.2-10, which is beautifully transparent or semi-transparent, and in which the amphiphatic lipids are stably microdispersed.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: March 15, 1994
    Assignee: Kao Corporation
    Inventors: Mami Nakamura, Seiji Honma
  • Patent number: 5266321
    Abstract: An oily make-up cosmetic composition which can provide an excellent feeling upon use, a superior make-up effect, and good stability over time is disclosed. The cosmetic composition is normally of a solid form, and comprises a silicone gel composition and a cosmetic powder material, both dispersed in an oil base. The composition may further comprises an aqueous gel of water-soluble polymer containing glycerine.
    Type: Grant
    Filed: March 17, 1992
    Date of Patent: November 30, 1993
    Assignee: Kobayashi Kose Co., Ltd.
    Inventors: Koichi Shukuzaki, Kazuhiro Suzuki, Miki Yamazoe
  • Patent number: 5260295
    Abstract: Aromatic heterocyclic derivatives have the formula ##STR1## wherein R.sub.1 represents (i)--CH.sub.3, (ii)--CH.sub.2 OH or (iii) ##STR2## wherein R.sub.3 represents hydrogen, --OR.sub.4 wherein R.sub.4 represents hydrogen, alkyl having 1-20 carbon atoms or mono- or polyhydroxyalkyl or R.sub.3 represents ##STR3## wherein r' and r" represent hydrogen, lower alkyl or together form a heterocycle, R.sub.2 represents hydrogen or --CH.sub.3 and Ar represents ##STR4## wherein R.sub.6 is hydrogen or alkyl having 1-10 carbon atoms and R.sub.7 represents alkyl having 4-12 carbon atoms or cycloalkyl, Y is CH or a nitrogen atom and X represents oxygen, sulfur or --N--R.sub.8 when R.sub.8 represents hydrogen, lower alkyl or lower alkoxycarbonyl, with the proviso that (i) when Y is CH and X is oxygen or sulfur Ar is other than C and (ii) when Y is nitrogen and X is oxygen, Ar is other than (C) or (D) in which R.sub.6 is alkyl having 1-4 carbon atoms and R.sub.7 is branched alkyl having 4-12 atoms.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: November 9, 1993
    Assignee: Centre International de Recherches Dermatologiques (C.I.R.D.)
    Inventors: Braham Shroot, Jacques Eustache, Jean-Michel Bernardon
  • Patent number: 5258391
    Abstract: Therapeutic as well as preventative measures to improve the cosmetic conditions or to alleviate the symptoms of dermatologic disorders with phenyl alpha acyloxyalkanoic acids and derivatives is disclosed. The cosmetic conditions and dermatologic disorders in humans in which the compounds may be useful include brittle or soft nails; abnormally thin skin, mucous membranes or wound; friction blisters; brittle hairs; pruritus; acne; and diseased nails, skin or mucous membranes due to natural or unnatural causes including but not limited to in flammations or infections. The phenyl alpha acyloxyalkanoic acids and derivatives include, for example, diphenyl alpha acetoxyacetic acid, phenyl alpha acetoxyacetic acid, phenyl alpha methyl alpha acetoxyacetic acid and phenyl alpha acetoxypropanoic acid. The compositions containing the active ingredients are also useful for treatment of skin, nails and hair conditions or disorders in domestic animals.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: November 2, 1993
    Inventors: Eugene J. Van Scott, Ruey J. Yu
  • Patent number: 5252323
    Abstract: Compound of formula: ##STR1## in which R.sub.1 is of the formula: ##STR2## and R.sub.2 is a C.sub.8 -C.sub.20 alkoxy or mono- or dialkylamino or is of the formula: ##STR3## where n=0 or 1; R.sub.4 denotes H, OH or C.sub.1 -C.sub.6 alkoxy; R.sub.5 denoted H or COOR.sub.3 and R.sub.3 is a C.sub.4 -C.sub.20 alkyl.Application of these compounds for the protection of the skin and hair against ultraviolet radiation.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: October 12, 1993
    Assignee: L'Oreal
    Inventors: Herve Richard, Madeleine Leduc, Alex Junino
  • Patent number: 5236698
    Abstract: The invention relates to a compound of formula: ##STR1## where R.sub.1 is of the formula: ##STR2## where R.sub.3 represents a linear or branched C.sub.1 -C.sub.20 alkyl; R.sub.2 is identical to R.sub.1 or is a halogen or a linear or branched C.sub.1 -C.sub.20 alkoxy or mono- or dialkylamino or is of the formulae (III) or (IV): ##STR3## where R.sub.5 is a linear or branched C.sub.1 -C.sub.20 alkyl and n=0 or 1;R.sub.4 denotes H, OH or C.sub.1 -C.sub.5 alkoxy; ##STR4## Application of these compounds to the protection of the skin and hair against ultraviolet radiation.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: August 17, 1993
    Assignee: L'Oreal
    Inventors: Herve Richard, Madeleine Leduc, Alex Junino
  • Patent number: 5230891
    Abstract: The invention provides a modified protease such that a protease is coupled to a polysaccharide via a triazine ring. This modified protease is considerably stable, safe and active as compared with the conventional modified proteases and immobilized proteases. Therefore, cosmetic products containing this modified protease are less liable to undergo aging, easier to use and improved in effect on the skin.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: July 27, 1993
    Assignee: Kanebo Limited
    Inventors: Hiroshi Nakayama, Shinichi Fukunaga, Yasumitsu Fujino, Kenji Mori
  • Patent number: 5217709
    Abstract: Cosmetic composition containing, by way of a compound screening cut UV of wavelengths 280-380 nm, a 5-benzylidene-3-oxacyclopentanone of formula (I): ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 denote C.sub.1 -C.sub.8 alkyl, aralkyl or aryl, or alternatively R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 form, with the carbon to which they are attached, a saturated 5- or 6-membered ring, andR.sub.5, R.sub.6 and R.sub.7 denote H, C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.8 alkenyl, C.sub.1 -C.sub.12 alkoxy, C.sub.2 -C.sub.8 alkenyloxy, C.sub.2 -C.sub.12 acyloxy, benzyloxy or --COOR.sub.10 where R.sub.10 is a C.sub.1 --C.sub.8 alkyl, hydrogen, an alkali metal or alkaline earth metal or a radical derived from an amine, it also being possible for one of the substituents R.sub.5, R.sub.6 and R.sub.7 to denote a radical ##STR2## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 have the above meanings. This composition can be a protective composition for the human epidermis or the hair or an antisun composition.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: June 8, 1993
    Assignee: L'Oreal
    Inventors: Alain Lagrange, Serge Forestier, Gerard Lang, Bernadette Luppi
  • Patent number: 5216030
    Abstract: An antimicrobial, low toxicity blend composition of several bis-quaternary ammonium compounds of defined structure, and in defined amounts of the composition, and polyvinylpyrrolidone, is described herein.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: June 1, 1993
    Assignee: ISP Investments Inc.
    Inventor: John J. Merianos
  • Patent number: 5213799
    Abstract: This invention refers to cosmetic compositions, particularly a skin treating preparation, comprising a transparent oil phase and a transparent aqueous phase, preferably with humectant effect, which permits a homogeneous mixture when being shaken, and which separates again in two transparent phases thereafter. These properties are achieved by the addition of 0.1 to 1.0% by weight of a C.sub.12 -C.sub.18 fatty acid triglycerol ester.
    Type: Grant
    Filed: December 5, 1991
    Date of Patent: May 25, 1993
    Assignee: Goldwell AG
    Inventors: Stefan M. Goring, Claudia Koss
  • Patent number: 5208012
    Abstract: An anti-inflammatory cosmetic composition having a large effect of absorbing and shielding all of UV-A, UV-B and UV-C, small degeneration with the passage of time even upon absorption of light, small influence upon the skin, not lowered effect of absorbing light and high stability for heat is provided. This anti-inflammatory cosmetic composition comprises 0.1 to 20% by weight of a hydroxyaryl-s-triazine compound represented by the following structural formula in a cosmetically acceptable oil carrier: ##STR1## wherein R.sub.1 and R.sub.2 represent, same or different, hydrogen atoms, chlorine atoms, hydroxyl groups, alkoxy groups of 1 to 18 carbon atoms, aryloxy groups of 6 to 8 carbon atoms or mono- or dialkylamino groups containing 1 to 4 carbon atoms and R.sub.3 and R.sub.4 represent, same or different, hydrogen atoms, chlorine atoms, alkyl groups of 1 to 8 carbon atoms, methoxy groups or ethoxy groups.
    Type: Grant
    Filed: July 31, 1991
    Date of Patent: May 4, 1993
    Assignee: Daikyo Gomu Seiko Ltd.
    Inventors: Mirihiro Sudo, Tomoyasu Muraki, Eiji Kawachi, Yasushi Kawachi
  • Patent number: 5204092
    Abstract: A cosmetic composition comprises in solution in an appropriate vehicle at least one polymer having 50-100% of repeating units of the .beta.-alanine type having the formula ##STR1## and 0-50% of repeating units of the acrylamide type having the formula ##STR2## wherein R.sub.1 represents hydrogen or a member selected fromthe group consisting of (i) ##STR3## (ii) --CH.sub.2 OH, (iii) --(CH.sub.2).sub.n --CH.sub.3 wherein n is 0 or a whole number from1 to 11, (iv) ##STR4## wherein r' and r" each independently represent hydrogen or alkyl having 1-3 carbon atoms, (v) --CHOH--COOH, (vi) --CH.sub.2 --SO.sub.3 Na,(vii) ##STR5## and (viii) --(CH.sub.2 --CH.sub.2 --O).sub.m H wherein m ranges from 1 to 10, and R.sub.2 and R.sub.3 represent hydrogen or methyl.
    Type: Grant
    Filed: June 30, 1982
    Date of Patent: April 20, 1993
    Assignee: Societe Anonyme dite: L'oreal
    Inventors: Claude Mahieu, Christos Papantoniou
  • Patent number: 5196189
    Abstract: A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,--(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3)--(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4)--(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5)--(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6)--(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: March 23, 1993
    Assignee: Societe Anonyme dite: l'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 5179127
    Abstract: Compounds of the formula ##STR1## wherein A is selected from the group consisting of (1) phenyl, (2) naphthyl, (3) phenyl substituted with one or more halo, cyano, (C.sub.1 -C.sub.4)alkyl, nitro, (C.sub.1 -C.sub.4)haloalkyl, and (C.sub.1 -C.sub.4)thioalkyl, (4) naphthyl substituted with one or more halo, cyano, (C.sub.1 -C.sub.4) alkyl, nitro, (C.sub.1 -C.sub.4)haloalkyl, and (C.sub.1 -C.sub.4)thioalkyl, (5) thiophene, (6) furan, (7) thiophene substituted with one or more substituents selected from halo and nitro, and (8) furan substituted with one or more substituents selected from halo and nitro;R is selected from the group consisting of hydrogen, (C.sub.1 -C.sub.4)alkyl and substituted or unsubstituted phenyl wherein the substituents are selected from one or more halo, cyano, (C.sub.1 -C.sub.4)alkyl, nitro, (C.sub.1 -C.sub.4) haloalkyl, and (C.sub.1 -C.sub.4)thioalkyl andR.sup.1 is selected from the group consisting of (C.sub.1 -C.sub.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: January 12, 1993
    Assignee: Rohm and Haas Company
    Inventor: Adam C. Hsu
  • Patent number: 5171573
    Abstract: A novel glycoside, 4.sup.G -alpha-D-glucopyranosyl rutin, is formed by a saccharide-transferring enzyme and glucoamylase in a solution which contains rutin together with glucoamylase. The 4.sup.G -alpha-D-glucopyranosyl rutin formed in such a solution is purified with a synthetic macroreticular resin, and crystallization in an organic solvent yields a complex crystal with the organic solvent. 4.sup.G -Alpha-D-glucopyranosyl rutin exhibits the same molecular absorption coefficient as intact rutin, and is readily water-soluble, substantially tasteless and odorless, and readily hydrolyzable in vivo to exhibit physiological activities inherent to rutin. These render 4.sup.G -alpha-D-glucopyranosyl rutin very useful as a highly-safe, natural yellow coloring agent, antioxidant, stabilizer, quality-improving agent, preventive, remedy, uv-absorbent and deterioration-preventing agent in foods, beverages, tobaccos, cigarets, feeds, pet foods, pharmaceuticals, cosmetics and plastics.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: December 15, 1992
    Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo
    Inventors: Yukio Suzuki, Kei Suzuki, Masaru Yoneyama, Toshio Miyake
  • Patent number: 5143722
    Abstract: Compositions comprising water-in-oil emulsions are disclosed comprising pigment coated with polysiloxane; a silicone phase; a water phase; and a polydiorganosiloxane-polyoxylalkylene copolymeric surfactant.
    Type: Grant
    Filed: June 12, 1991
    Date of Patent: September 1, 1992
    Assignee: Revlon, Inc.
    Inventors: Jane Hollenberg, Lou A. Lombardi, Marlene Tietjen
  • Patent number: 5141741
    Abstract: A novel anti-sunburn skin-care preparation, such as creams, foundations, milky lotions and the like, is proposed which contains, as the ultraviolet-absorbing and -shielding ingredient, a salt of ellagic acid with a polyvalent metal, e.g., calcium, barium and magnesium. The skin-care preparation is free from the problem of irritation and sensitization of human skin and exhibits excellent anti-sunburn effect with durability.
    Type: Grant
    Filed: December 4, 1989
    Date of Patent: August 25, 1992
    Assignee: Lion Corporation
    Inventors: Keiichiro Ishida, Yoshimi Sato, Makoto Egawa, Keiji Takeuchi
  • Patent number: 5135748
    Abstract: An aqueous composition is provided which includes from about 0.1 to about 30% by weight of a quaternary ammonium functionalized phosphate ester and from about 0.01 to about 10% by weight of a cationic polysaccharide. These compositions are freeze-thaw cycle stable and exhibit unusual skin mildness properties.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: August 4, 1992
    Assignee: Chesebrough-Pond's USA Co., Division of Conopco, Inc.
    Inventors: Philip D. Ziegler, Michael C. Cheney
  • Patent number: 5106611
    Abstract: Use of modified diorganopolysiloxanes as antioxidants in cosmetics or in dermatology.Use, as an antioxidizing agent in cosmetics or in dermatology, of diorganopolysiloxanes (i) of formula (I): ##STR1## in which the symbols R denote alkyl or phenyl, B are chosen from the radicals R and A, a an integer chosen between 0 and 200 inclusive, b an integer chosen between 0 and 50 inclusive, and if b is equal to 0, at least one of the two symbols B is A,A is of formula: ##STR2## where: R.sub.1 denotes hydrogen or an alkyl,R.sub.2 denotes hydrogen, hydroxyl, alkyl or alkoxy,R.sub.3 denotes hydrogen, hydroxyl or alkyl,R.sub.4 denotes hydrogen or alkyl,R.sub.5 denotes hydrogen, hydroxyl or alkoxy,Y denotes:(O).sub.n --CH.sub.2 --CH(R.sub.6)--CH.sub.2 --whereR.sub.6 denotes hydrogen or alkyl and n has the value of 0 or 1,or (ii) of formula (II): ##STR3## where c is an integer between 1 and 20 inclusive,d is an integer between 2 and 20 inclusive, andc+d equal to or greater than 3.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: April 21, 1992
    Assignee: L'Oreal
    Inventors: Serge Forestier, Gerard Lang, Herve Richard
  • Patent number: 5098895
    Abstract: A benzonaphthalene compound has the formula ##STR1## wherein R.sub.1 represents ##STR2## or (ii) --CH.sub.2 OH; R.sub.6 represents ##STR3## or OR.sub.7 wherein R.sub.7 represents hydrogen, alkyl having 1-20 carbon atoms, monohydroxyalkyl or polyhydroxyalkyl, r' or r" represent hydrogen, lower alkyl, mono or polyhydroxyalkyl, aryl or a residue of an amino acid or a sugar, or together form a heterocycle; R.sub.2 represents hydrogen, alkyl having 1-15 carbon atoms, alkoxy having 1-4 carbon atoms or a cycloaliphatic radial; R.sub.3 represents hydrogen, hydroxy, alkyl having 1-4 carbon atoms, alkoxy having 1-10 carbon atoms, a cycloaliphatic radical, a thiocycloaliphatic radical or --O--Si(CH.sub.3).sub.2 --R.sub.8 wherein R.sub.8 represents lower alkyl; and R.sub.4 and R.sub.5 represent hydrogen, lower alkyl, hydroxy or lower acyloxy.This compound is useful in the topical and systemic treatment of dermatologic diseases and in the treatment of the degeneration of conjunctive tissues.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: March 24, 1992
    Assignee: Centre International de Recherches Dermatologiques (C.I.R.D.)
    Inventors: Braham Shroot, Jacques Eustache, Jean-Michel Bernardon
  • Patent number: 5096697
    Abstract: Cell-stimulating composition having hair-growing effect and skin-vivifying effect. The composition comprising as an effective ingredient an aliphatic alcohol having odd number of carbon atoms or a derivative thereof in a cosmetically acceptable carrier.
    Type: Grant
    Filed: August 23, 1989
    Date of Patent: March 17, 1992
    Assignee: Lion Corporation
    Inventors: Kuniaki Adachi, Hideo Tamai, Masanao Sadai
  • Patent number: 5089269
    Abstract: A cosmetic composition on an external treatment agent containing microcapsules, with an average particle size of 0.1 to 2000 .mu.m, enclosing a hydrophobic component, wherein the microcapsules are composed of a gelatin film swollen with water.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: February 18, 1992
    Assignee: Shiseido Company Ltd.
    Inventors: Akira Noda, Michihiro Yamaguchi, Masanori Aizawa, Yoshimaru Kumano
  • Patent number: 5071640
    Abstract: Non-ionic products of the formula:R--X--[C.sub.2 H.sub.3 (OCH.sub.2 CH.sub.2).sub.n(OH)--CH.sub.2 --Y--R'in which R and R' denote alkyl or alkenyl radicals having from 6 to 20 carbon atoms, the sum of the numbers of carbon atoms in R and R' being 24 to 32; X denotes an oxygen atom, a sulphur atom or a sulphoxide group; Y denotes a sulphur atom, a sulphoxide group or a methylene group (if Y denotes methylene, the sum of the numbers of carbon atoms in R and R' is 22 to 30); and n denotes an integer or decimal number from 1 to 40 are disclosed. These non-ionic compounds are suitable for use in pharmaceutical or cosmetic applications, in particular for the care of the skin or hair.
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: December 10, 1991
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag
  • Patent number: 5064644
    Abstract: A water-in-oil emulsion type cosmetic composition comprising 0.1% to 20% by weight of a propylene oxide-ethylene oxide addition product having the general formula (I): ##STR1## wherein a is an integer of 7 to 19, b is an integer of a+2, m is an average addition mol number of 5 to 30, and n is an average addition mol number of 5 to 30, and 0.01% to 20% by weight of an iron oxide.This water-in-oil emulsion type cosmetic composition has excellent emulsification stability and excellent dispersion stabililty of an iron oxide pigment at a wide temperature range.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: November 12, 1991
    Assignee: Shiseido Company Ltd.
    Inventors: Hideo Nakajima, Kiyoshi Kawada, Kazuo Tokubo
  • Patent number: 5061479
    Abstract: Use in cosmetics, as UV filters, of diorganopolysiloxanes containing a 3-benzylidenecamphor functional group of formula: ##STR1## R being C.sub.1 -C.sub.10 alkyl, phenyl or 3,3,3-trifluoropropyl, B denoting R or A, r=0-200, s=0-50, if s=0, at least one of the symbols B denotes A, or of formula: ##STR2## where u=1-20 and t=0-20,A and/or B denoting an optionally substituted alkylene or alkyleneoxy-3-benzylidenecamphor group.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: October 29, 1991
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Herve Richard, Serge Forestier, Gerard Lang
  • Patent number: 5061481
    Abstract: Cosmetic comprising (A) a specific acryl-silicone graft copolymer having an organosiloxane side chain is disclosed. The copolymer is prepared by radical polymerization of (i) a dimethylpolysiloxane compound having a polymerizable radical group on one of the molecular chain terminals and (ii) a radically polymerizable monomer comprising as major components an acrylate or methacrylate, or both. Various cosmetics including makeup cosmetics, o/w emulsion cosmetics, and w/o emulsion cosmetics, are prepared by using the copolymer in combination with (B) a low-viscosity silicone oil, (C) a partially cross-linked organopolysiloxane polymeric compound, (D) a low-boiling-point oil, (E) a volatile solvent, (F) a cosmetic powder material, (G) a polyacrylic acid, (H) a volatile hydrocarbon, (I) a surface active agent, or (J) water. The cosmetic compositions give a good sensation upon use, and exhibit superior water-repellency, water-resistance, oil-resistance, and good retentiveness of the makeup.
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: October 29, 1991
    Assignee: Kobayashi Kose Co., Ltd.
    Inventors: Kazuhiro Suzuki, Toru Shimizu, Miki Yamazoe, Tosiaki Sugisaki
  • Patent number: 5039513
    Abstract: Disclosed are topical compositions comprising sorbohydroxamic acid with a radical scavenging compound which prevent damage to skin caused UV radiation. Also disclosed is a method for using these compositions topically, to prevent damage to skin caused by UV radiation exposure.
    Type: Grant
    Filed: August 25, 1989
    Date of Patent: August 13, 1991
    Assignee: The Procter & Gamble Company
    Inventors: Ranjit U. Chatterjee, Stephen J. Kirchner
  • Patent number: 5036108
    Abstract: A water-in-oil type emulsion cosmetic, which comprises a specific emulsifier mixture, an oily base containing a silicone oil and water and has a viscosity of 20,000 cps or below at 25.degree. C. is disclosed. The water-in-oil type emulsion cosmetic of the present invention imparts a good feel to the skin during use, is safe to use and has a high storage stability, which makes it widely applicable for use in, for example, milky lotions, body-care lotions and liquid-type foundations.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: July 30, 1991
    Assignee: Kao Corporation
    Inventors: Masahiko Asahi, Noriko Shirakawa, Yuko Kikuta
  • Patent number: 5034226
    Abstract: A content of a sparkling wine, particularly champagne prepared in champagne-like manner unexpectedly increases the effectiveness of cosmetic products. Preferably most of the aqueous phase of such products comprises liquid constituents of such sparkling wine, particularly champagne.
    Type: Grant
    Filed: February 19, 1988
    Date of Patent: July 23, 1991
    Inventor: Julius H. Beck
  • Patent number: 5032390
    Abstract: A novel anti-suntan cosmetic composition comprises from 1 to 25% by weight of fine particulate zinc oxide having an average particle size of from 70 to 300 m.mu., which scatters or absorbs ultraviolet rays, especially those in UV-A region.The composition prevent human skin from blotches and freckles, and supress the aging of the skin.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: July 16, 1991
    Assignee: Kao Corporation
    Inventors: Katsumasa Iwaya, Hajime Hotta
  • Patent number: 5028417
    Abstract: Novel sunscreen compositions containing titanium dioxide having a particle size less than 10 m.mu. are described as well as methods of protecting the skin from damaging ultraviolet radiation.
    Type: Grant
    Filed: July 20, 1987
    Date of Patent: July 2, 1991
    Assignee: Johnson & Johnson Consumer Products, Inc.
    Inventors: Gulguhji R. Bhat, Martin K. O. Lindemann, Prakash Naik-Satam
  • Patent number: 5015469
    Abstract: A water-in-oil type emulsified composition containing a water-swellable clay mineral, a nonionic surfactant, an oil component, and water as the essential constituents or containing a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant, one or two more kinds of polyoxyalkylene modified organopolysiloxane, an aqueous phase, and an oil phase containing one or two or more kinds of organic silicone resin comprising the units of the formula:RnSiO.sub.(4-n)/2wherein R is a hydrocarbon group having 1 to 6 carbon atoms or a phenyl group, and n represents a value of 1.0 to 1.8, and a water- and polyhydric alcohol-in-oil type emulsified composition containing an oil phase containing a polyoxyalkylene modified organopolysiloxane, a water-swellable clay mineral, a quaternary ammonium salt type cationic surfactant and a silicone oil, water, and a polyhydric alcohol.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: May 14, 1991
    Assignee: Shideido Company Ltd.
    Inventors: Toshio Yoneyama, Michihiro Yamaguchi, Shinji Tobe, Tomiyuki Nanba, Masaaki Ishiwatari, Hidekazu Toyoda, Shin Nakamura, Yoshimaru Kumano, Sadaki Takata, Hiromi Ito
  • Patent number: RE33993
    Abstract: A cosmetic composition for the treatment of the hair and skin comprising, in an aqueous medium, particles of pulverized flowers or flower tops having a granulometry lower than 125 microns and a cohesion agent present in an amount effective to maintain the homogeneity of the composition. The cohesion agent can be a thickening agent, a water-in-oil emulsion or an oil-in-water emulsion.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: July 14, 1992
    Assignee: Societe Anonyme dite: l'Oreal
    Inventors: Jean-Francois Grollier, Josiane Allec, Chantal Fourcadier, Georges Rosenbaum, Patrick Darmenton
  • Patent number: RE34440
    Abstract: A benzonaphthalene compound has the formula ##STR1## wherein R.sub.1 represents ##STR2## or (ii) --CH.sub.2 OH; R.sub.6 represents ##STR3## or OR.sub.7 wherein R.sub.7 represents hydrogen, alkyl having 1-20 carbon atoms, monohydroxyalkyl or polyhydroxyalkyl, r' or r" represent hydrogen, lower alkyl, mono or polyhydroxyalkyl, aryl or a residue of an amino acid or a sugar, or together form a heterocycle; R.sub.2 represents hydrogen, alkyl having 1-15 carbon atoms, alkoxy having 1-4 carbon atoms or a cycloaliphatic radial; R.sub.3 represents hydrogen, hydroxy, alkyl having 1-4 carbon atoms, alkoxy having 1-10 carbon atoms, a cycloaliphatic radical, a thiocycloaliphatic radical or --O--Si(CH.sub.3).sub.2 --R.sub.8 wherein R.sub.8 represents lower alkyl; and R.sub.4 and R.sub.5 represent hydrogen, lower alkyl, hydroxy or lower acyloxy.This compound is useful in the topical and systemic treatment of dermatologic diseases and in the treatment of the degeneration of conjunctive tissues.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: November 9, 1993
    Assignee: Centre International de Recherches Dermatologiques (C.I.R.D.)
    Inventors: Braham Shroot, Jacques Eustache, Jean-Michel Bernardon