At Least One Polymer Is Derived From Reactant Containing Two Or More Three Membered Heterocyclic Rings Having Two Carbon Atoms And One Chalcogen Atom Or Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/135)
  • Patent number: 11820922
    Abstract: An epoxy-based crash durable adhesive composition including: (I) a liquid resin system comprising: (a) at least one epoxy resin; and (b) at least one toughener; wherein the viscosity of the above liquid resin system is less than about 800 Pa s at a temperature of 15° C.; and wherein the viscosity of the above liquid resin system is greater than about 5 Pa-s at a temperature of 60° C.; (II) a solid material comprising: (c) at least one hydrophobic fumed silica, wherein the fumed silica is present in the adhesive composition at a concentration of greater than 5 weight percent; and (III) a curative material comprising: (d) at least one latent heat-activated curing agent; wherein the rheology of the epoxy-based crash durable adhesive composition is such that the adhesive composition is pumpable at a temperature of 15° C.
    Type: Grant
    Filed: October 2, 2018
    Date of Patent: November 21, 2023
    Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US, LLC
    Inventors: Tyler Auvil, Gary L. Jialanella, Eric E. Cole, Felix Koch, Andreas Lutz, Daniel Schneider
  • Patent number: 11217219
    Abstract: Disclosed are a method for preparing a sound-absorbing member and a sound-absorbing member. The method for preparing a sound-absorbing member includes: providing non-foaming sound-absorbing material powder and a foaming material; uniformly mixing the non-foaming sound-absorbing material powder with the foaming material and adding an auxiliary to form a sound-absorbing mixture; and foaming the sound-absorbing mixture to form foam with cells, wherein the non-foaming sound-absorbing material powder adheres to a surface and the cells of the foam. The foamed sound-absorbing material powder and the foam constitute a sound-absorbing member.
    Type: Grant
    Filed: May 18, 2016
    Date of Patent: January 4, 2022
    Assignee: GOERTEK INC.
    Inventor: Xiaodong Cao
  • Patent number: 10745567
    Abstract: Provided is a powdered paint containing powdered particles and inorganic particles, the powdered paint having an attenuation factor AF[30-300] (%) represented by an absolute value of [(Q30?Q300)/Q30] is 30% or more and 60% or less, wherein Q30 represents electric charge amount in an adherent layer including 100 g/m2 of the powdered paint adhered to a substrate 30 seconds after forming the adherent layer, and Q300 represents electric charge amount in the adherent layer 300 seconds after forming the adherent layer.
    Type: Grant
    Filed: July 5, 2017
    Date of Patent: August 18, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Masato Mikami, Susumu Yoshino, Takeshi Agata, Hiroshi Saegusa, Minquan Tian, Makoto Furuki
  • Patent number: 10150893
    Abstract: An uncured adhesive contains 2 to 10 weight percent of particles of a semi-crystalline organic material, preferably a polyester having a number-average molecular weight of 2000 to 10,000, a hydroxyl number of 10 to 60, and a melting temperature of 50 to 125° C. The adhesive is applied by heating it just prior to application, to melt the particles. After application, the adhesive is cooled to below the melting temperature of the semi-crystalline organic material, and then cured. The process allows the adhesive to be stored and pumped at ambient temperatures, due to the moderate viscosity of the material. Upon melting and re-cooling the semi-crystalline organic material, the adhesive assumes a high yield stress that imparts very good wash-off resistance. In preferred embodiments, the adhesive composition includes an epoxy resin and an epoxy curing agent.
    Type: Grant
    Filed: July 14, 2015
    Date of Patent: December 11, 2018
    Assignee: Dow Global Technologies LLC
    Inventors: Glenn G. Eagle, Michael R. Golden, Andreas Lutz
  • Patent number: 9790341
    Abstract: The subject matter of the present application is a thermally expandable preparation that can be pumped at application temperatures below 70° C., containing (a) at least one first epoxy resin E1 that has an epoxy equivalent weight of at most 280 g/eq and a viscosity of at most 1250 Pa*s at 25° C., (b) at least one second epoxy resin E2 that has an epoxy equivalent weight of at least 300 g/eq and a viscosity of at most 250 Pa*s at 25° C., (c) at least one hardener that can be thermally activated, (d) at least one propellant that can be thermally activated, and (e) at least 1 wt. % of organic fibres having a fibre length of 0.2 mm to 10 mm.
    Type: Grant
    Filed: September 19, 2014
    Date of Patent: October 17, 2017
    Assignee: Henkel AG & Co. KGaA
    Inventors: Emilie Barriau, Martin Renkel, Rainer Schoenfeld, Sven Wucherpfennig, Tim Welters
  • Patent number: 9758668
    Abstract: An acoustic stack is described, where the acoustic stack comprises a plurality of acoustic stack components, which are laminated with an accelerated cure adhesive, which comprises an epoxy resin. The epoxy resin comprises one or more modified epoxy resins, which are selected from a group consisting of epoxy phenol novolac, bisphenol A, and bisphenol F. Further described is a method for producing an acoustic stack. The method comprises providing a plurality of acoustic stack components and dispensing an accelerated cure adhesive to the acoustic stack components. The accelerated cure adhesive dispensed on, to, and/or in the acoustic stack components includes an epoxy resin, which comprises at least one modified epoxy resin selected from a group consisting of epoxy phenol novolac, bisphenol A, and bisphenol F. After the accelerated cure adhesive is dispensed to the acoustic stack components, the accelerated cure adhesive is cured.
    Type: Grant
    Filed: July 2, 2015
    Date of Patent: September 12, 2017
    Assignee: GENERAL ELECTRIC COMPANY
    Inventors: Jessica Abraham, Jessica Subit
  • Patent number: 9109147
    Abstract: An adhesive composition for a semiconductor has two exothermic peaks between 65° C. and 350° C. and has an area ratio of voids of less than 10%, measured after curing at 150° C. for 10 minutes and then at 150° C. for 30 minutes, and then molding at 175° C. for 60 seconds. A first exothermic peak appears between 65° C. and 185° C. and a second exothermic peak appears between 155° C. and 350° C.
    Type: Grant
    Filed: June 24, 2013
    Date of Patent: August 18, 2015
    Assignee: CHEIL INDUSTRIES, INC.
    Inventors: Baek Soung Park, Ki Tae Song, Dong Seon Uh, In Hwan Kim
  • Publication number: 20150080486
    Abstract: A flame retardant containing composition resistant to becoming sticky from moisture is prepared by the introduction of epoxy containing compound either into the ethyleneamine polyphosphates or into the polymeric composition.
    Type: Application
    Filed: May 19, 2012
    Publication date: March 19, 2015
    Inventor: Robert Valentine Kasowski
  • Patent number: 8946343
    Abstract: An adhesive composition for semiconductors, an adhesive film prepared using the adhesive composition, and a semiconductor device including the adhesive film, the adhesive composition exhibiting two exothermic peaks at temperatures ranging from 65° C. to 350° C., wherein a first exothermic peak appears at a lower temperature than a second exothermic peak, and the adhesive composition has a curing rate of about 70% to 100% in a first exothermic peak zone, as calculated by Equation 1: Curing rate=[(Heating value upon 0 cycle?Heating value after 1 cycle)/Heating value upon 0 cycle]×100.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: February 3, 2015
    Assignee: Cheil Industries, Inc.
    Inventors: Baek Soung Park, Ki Tae Song, In Hwan Kim
  • Publication number: 20150004402
    Abstract: An intumescent coating composition having improved char yield, while maintaining its physical, mechanical, and esthetic properties comprises (a) particulate poly(phenylene ether), wherein the mean particle size of the poly(phenylene ether) is 1 to 100 micrometers; (b) a film-forming binder; (c) an acid source; (d) a blowing agent; and (e) optionally, a carbon source other than the particulate poly(phenylene ether); wherein polyolefins, homopolystyrenes, rubber-modified polystyrenes, styrene-containing copolymers, and hydrogenated and unhydrogenated block copolymers of an alkenyl aromatic compound and a conjugated diene are all absent from the composition.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 1, 2015
    Inventors: EYLEM TARKIN-TAS, EDWARD NORMAN PETERS
  • Publication number: 20140357744
    Abstract: A process for the production of PET foams includes the extrusion of a mixture of PET, epoxy resin, catalyst consisting of imidazole, derivatives of imidazole or mixtures thereof plus a blowing agent, wherein the homopolymerization reaction of the epoxy phase is performed in the extruder, upstream of the introduction of the blowing agent. Compared to the methods of the known art, a process according to the invention offers the advantage of providing a stable PET foam, in which the structure of the polymer chains is kept unaltered. The system therefore has viscoelasticity characteristics which allow the PET/epoxy homopolymer to receive the expanding action of the blowing agent, as far as the innermost and deepest layers of foam also even if they have a significant thickness.
    Type: Application
    Filed: January 14, 2013
    Publication date: December 4, 2014
    Applicant: DIAB INTERNATIONAL AB
    Inventors: Leone Lauri, Raffaela Bressan, Luigi Aliperta, Eva-Lotta Magdalena Petersson
  • Publication number: 20140238575
    Abstract: An improved approach toward the formation of an adhesive comprising a separated liquid component and solid component and application of the adhesive to a substrate immediately upon mixing the liquid and solid components.
    Type: Application
    Filed: February 21, 2014
    Publication date: August 28, 2014
    Inventors: Blake Synnestvedt, Craig Knepper, David Egle, Patrick Moore, Jeanne Bednarski, David Sheasley
  • Patent number: 8790779
    Abstract: A thermally curable adhesive in strip or film form, having a thickness in the range of 0.1 to 5 mm, containing: a) at least one reactive epoxy prepolymer, b) at least one latent hardener for epoxies, and c) one or more elastomers that are selected from: c1) thermoplastic polyurethanes, c2) thermoplastic isocyanates, and c3) block copolymers having thermoplastic polymer blocks. Further components can additionally be contained, for example a blowing agent for foaming. The adhesive in the uncured state at 22° C. is bendable or wrappable and can be extended at least 100% before tearing. It can be laid onto a foil. It can be used, for example, for adhesive bonding of planar, tubular, or cylindrical components, preferably components made of metal, wood, ceramic, or ferrites.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: July 29, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Eugen Bilcai, Emilie Barriau, Martin Renkel, Sven Wucherpfennig
  • Publication number: 20140199135
    Abstract: A coating composition adapted for application on a fastener, the coating composition composed of a binder component composed of a polymeric resin present in the composition at a concentration between 1.0% and 15.0% by total composition weight, wherein the binder component is composed of at least one of a solvent dispersible compound; a reactive cross-linking component present in the composition in an amount between 1.0% and 80.0%; at least one curing agent; optionally at least one expansion agent, wherein at least one of the curing agent or the reactive cross-linking component are physically and reactively isolated from other components of the composition.
    Type: Application
    Filed: January 13, 2014
    Publication date: July 17, 2014
    Applicant: ND Industries, Inc.
    Inventors: Christopher T. Hable, Norman M. Rawls, Brian J. Phillips, Desiree N. Snyder
  • Patent number: 8758549
    Abstract: The present invention relates to heat-curable compositions containing a mixture of reactive epoxy resins that contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and at least one latent hardener.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: June 24, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Pablo Walter, Mustapha Benomar, Stefan Kreiling, Angelika Troll, Rainer Schoenfeld
  • Patent number: 8598243
    Abstract: Polymer foams comprising macropores, the macropores having average cross sections of above 500 nm, are obtainable by reacting one or more epoxy resins with one or more amphiphilic epoxy resin hardeners in water in a phase inversion polymerization, where, during the phase inversion polymerization, but after phase inversion has taken place, a volume increase of the internal voids which form initially, and which are present predominantly as micropores having average cross sections of below 500 nm, is induced such that the fraction of the macropores—relative to the entirety of micropores and macropores present in the polymer foam—at the end of the phase inversion polymerization is above 50% by volume. Polymer foams of the present invention are suitable for use as acoustic insulation materials in means of transport and in industrial and plant construction.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: December 3, 2013
    Assignee: Cognis IP Management GmbH
    Inventors: Paul Birnbrich, Hans-Josef Thomas, Dagmar Stahlhut-Behn, Gilbert Schenker
  • Publication number: 20130281559
    Abstract: An adhesive composition for a semiconductor has two exothermic peaks between 65° C. and 350° C. and has an area ratio of voids of less than 10%, measured after curing at 150° C. for 10 minutes and then at 150° C. for 30 minutes, and then molding at 175° C. for 60 seconds. A first exothermic peak appears between 65° C. and 185° C. and a second exothermic peak appears between 155° C. and 350° C.
    Type: Application
    Filed: June 24, 2013
    Publication date: October 24, 2013
    Inventors: Baek Soung Park, Ki Tae SONG, Dong Seon UH, In Hwan KIM
  • Publication number: 20130273286
    Abstract: Components for heavy duty trucks are described that exhibit high strength and flexibility. The components are formed from a polyarylene sulfide that exhibits high strength and flexibility characteristics. Methods for forming the components are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The heavy duty truck components can include tubular member such as pipes and hoses that can be utilized in exhaust systems, charge air systems, urea tanks, fuel systems, and so forth.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 17, 2013
    Applicant: Ticona LLC
    Inventors: Rong Luo, Xinyu Zhao
  • Publication number: 20130273287
    Abstract: Components formed of blow molded thermoplastic compositions are described. The blow molded thermoplastic compositions exhibit high strength and flexibility. Methods for forming the thermoplastic compositions are also described. Formation methods include dynamic vulcanization of a composition that includes an impact modifier dispersed throughout a polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 17, 2013
    Applicant: TICONA LLC
    Inventors: Rong Luo, Xinyu Zhao, Joseph Grenci
  • Publication number: 20130210621
    Abstract: A breathable film formed from a thermoplastic composition that contains a rigid renewable polyester and has a voided structure is provided. To achieve such a structure, a thermoplastic composition that contains a renewable polyester and polymeric toughening additive is extruded onto a surface to form a precursor film in which the toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. The precursor film is thereafter stretched or drawn at a temperature below the glass transition temperature of the polyester (i.e., “cold drawn”). Without intending to be limited by theory, the present inventors believe that the deformation force and elongational strain of the drawing process causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This creates a network of voids located adjacent to the discrete domains.
    Type: Application
    Filed: February 10, 2012
    Publication date: August 15, 2013
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Ryan J. McEneany, Neil T. Scholl, Thomas A. Eby
  • Publication number: 20130150471
    Abstract: A foamable composition, foamed product and method of forming a foamed product are disclosed. The foamed product includes an epoxy resin crosslinked with a polycarboxylic acid to form a polymeric foam having cells filled with a blowing agent. The reaction between the epoxy resin and the carboxylic acid is catalyzed by a chromium (III) catalyst, particularly an active, carboxylated chromium salt, so as to speed the reaction at ambient temperature to allow the foam to set and cure so rapidly that, when applied to a vertical surface, the effects of gravity do not destroy the foam by pulling it down before the foam sets. Other ingredients preferably include a rheology modifier or thixotrope. The foams may be used for a wide variety of applications including sealing and/or insulating building structures.
    Type: Application
    Filed: December 13, 2012
    Publication date: June 13, 2013
    Applicant: OWENS CORNING INTELLECTUAL CAPITAL, LLC
    Inventor: Owens Corning Intellectual Capital, LLC
  • Publication number: 20130065975
    Abstract: The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.
    Type: Application
    Filed: March 14, 2011
    Publication date: March 14, 2013
    Inventors: Hiroshi Natsui, Hiroshi Yamauchi, Hiroyuki Morita
  • Publication number: 20130056153
    Abstract: A solid dry to the touch at ambient temperature structural adhesive which can be cured at elevated temperature and which can be moulded at an intermediate temperature is provided as well as the use of the adhesive for bonding metals.
    Type: Application
    Filed: May 9, 2011
    Publication date: March 7, 2013
    Applicant: ZEPHYROS, INC.
    Inventor: Michael Czaplicki
  • Publication number: 20130035411
    Abstract: Bilayer platelet fillers are employed to compensate for a positive coefficient of thermal expansion (CTE) of an embedding polymeric material, or even to provide a composite structure having a negative CTE to eliminate or alleviate thermomechanical stress and/or delamination during thermal cycling. A bilayer platelet includes two joined layers having different CTEs. The CTE mismatch induces bending of the bilayer platelets, thereby causing cavities at temperatures lower than the joining temperature at which the bilayers are joined. The decrease in the volume of the polymeric material and the bilayer platelets at low temperatures is compensated by an accompanying increase in the volume of the cavities so that the composite structure has a temperature independent volume, a low net CTE, or even a negative CTE.
    Type: Application
    Filed: October 11, 2012
    Publication date: February 7, 2013
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventor: International Business Machines Corporation
  • Publication number: 20120295997
    Abstract: A resin kneaded material has not more than 30 pores having a pore diameter of not less than 20 ?m in a surface area of 4.00 mm2.
    Type: Application
    Filed: May 18, 2012
    Publication date: November 22, 2012
    Applicant: NITTO DENKO CORPORATION
    Inventors: Tsuyoshi TORINARI, Hirofumi ONO, Minoru YAMANE, Eiji TOYODA, Yuusaku SHIMIZU, Tsutomu NISHIOKA
  • Patent number: 8293807
    Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond an
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: October 23, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Emge, Daniel Freidank, Holger Seifert
  • Publication number: 20120258316
    Abstract: Corrosion and chip-resistant coatings for high tensile steel components, such as automotive coil springs, can be formed from a coating composition comprising a primer having an epoxy resin with the proviso that the epoxy resin does not have an EEW of about 860 to about 930, a polyhydroxyl functional phenolic curing agent having a HEW of about 200 to about 500, and a platy filler. The primer contains less than 20 wt % zinc. The topcoat includes an epoxy resin having an epoxy equivalent weight of about 450 to about 1400, an elastomer-modified epoxy resin having an epoxy equivalent weight of about 1000 to about 1600, a foaming agent and a reinforcing fiber.
    Type: Application
    Filed: July 27, 2010
    Publication date: October 11, 2012
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventor: Chad Lucas
  • Publication number: 20120183694
    Abstract: Hybrid spray foams utilize a urethane reactant, a crosslinker, and an (optional) epoxy and/or acrylic resin along with a blowing agent and rheology modifier to produce a quick-setting foam that remains in place until the foam forms and cures. The urethane reactant may be formed as an adduct with or without the use of isocyanate chemistry. In some embodiments, the polyurethane oligomer is made by reacting cyclocarbonates and di- or polyamines, while in other embodiments the polyurethane backbone employs the use of commercially available capped or blocked urethane oligomers made by any method. The oligomers contain reactive groups, typically at the oligomer ends, that crosslink with crosslinkers or with acrylic or epoxy resins to form hybrid polyurethane foams. Foams may also contain a plasticizer, and/or a surfactant as well as other optional additives. Methods of making such foams are also provided.
    Type: Application
    Filed: January 10, 2012
    Publication date: July 19, 2012
    Applicant: OWENS CORNING INTELLECTUAL CAPITAL, LLC
    Inventor: Fatemeh Nassreen Olang
  • Patent number: 8217088
    Abstract: By reaction of one or more epoxy resins with an amphiphilic epoxy resin hardener in water in a phase inversion polymerization, nanoporous polymer foams are obtained. These foams are suitable as thermal insulation materials.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: July 10, 2012
    Assignee: Cognis IP Management GmbH
    Inventors: Paul Birnbrich, Hans-Josef Thomas, Martina Balser
  • Patent number: 8207237
    Abstract: By reaction of one or more epoxy resins with an amphiphilic epoxy resin hardener in water in a phase inversion polymerization, nanoporous polymer foams are obtained. These foams are suitable as filter materials.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: June 26, 2012
    Assignee: Cognis IP Management GmbH
    Inventors: Paul Birnbrich, Hans-Josef Thomas, Martina Balser
  • Patent number: 8193256
    Abstract: An epoxy resin mixture with at least one epoxy resin of between approximately 50 wt % and 100 wt %, an anhydride cure agent of between approximately 0 wt % and approximately 50 wt %, a tert-butoxycarbonyl anhydride foaming agent of between proximately 0.1-20 wt %, a surfactant and an imidazole or similar catalyst of less than approximately 2 wt %, where the resin mixture is formed from at least one epoxy resin with a 1-10 wt % tert-butoxycarbonyl anhydride compound and an imidazole catalyst at a temperature sufficient to keep the resin in a suitable viscosity range, the resin mixture reacting to form a foaming resin which in the presence of an epoxy curative can then be cured at a temperature greater than 50° C. to form an epoxy foam.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: June 5, 2012
    Assignee: Sandia Corporation
    Inventor: Mathias Celina
  • Patent number: 8133929
    Abstract: A structural reinforcing material and method of making the same is disclosed and described. The material is prepared by coating glass reinforcing fibers with a molten epoxy-based composition. The glass fiber reinforced material can then be formed into a preform suitable for injection molding into an expandable sealing baffle.
    Type: Grant
    Filed: April 15, 2008
    Date of Patent: March 13, 2012
    Assignee: Sika Technology AG
    Inventors: Frank Hoefflin, Patricia Heidtman, Eric R. Medaris
  • Publication number: 20120055631
    Abstract: Heat-curable epoxy resin compositions and the use thereof, for example, in motor vehicle construction and sandwich panel construction, are disclosed. Exemplary heat-curable epoxy resin compositions include, in addition to epoxy resin components A1, optionally A2, a hardener component B, a carboxylic acid C and a hydroxyalkylamide or hydroxyalkylurea H, an accelerator E for activation of the conversion of components A1, A2 and B. The compositions and the structural foams produced therefrom are notable for high mechanical strength, high glass strength and good adhesion capacity on metallic and nonmetallic substrates, and it is possible at the same time to dispense with the use of toxic or inflammable blowing agents.
    Type: Application
    Filed: September 2, 2011
    Publication date: March 8, 2012
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Jürgen FINTER, Elyes Jendoubi
  • Publication number: 20110306693
    Abstract: Cell nucleation compositions and pellets, methods for making same, methods and compositions for making polymer foam, and polymer foams made by the methods are disclosed.
    Type: Application
    Filed: June 19, 2009
    Publication date: December 15, 2011
    Inventors: Clive P. Bosnyak, Thomas J. Pitzi, Chris Schwier
  • Publication number: 20110275730
    Abstract: Prepare extruded polymer foam comprising at least 50 weight-percent alkenyl aromatic polymer, a brominated flame retardant providing 0.8 to 1.4 weight percent bromide, 0.05 to 0.5 weight-percent hydrobromic acid scavenger, at least 1.5 weight-percent graphite and less than 0.1 weight-percent C—C and O—O labile organic compounds using a blowing agent composition comprising at least 0.3 weight-parts per 100 weight parts polymer and that consists of blowing agents having an ozone depletion potential of zero and a global warming potential that is less than 1000.
    Type: Application
    Filed: January 5, 2010
    Publication date: November 10, 2011
    Inventors: John Gordon-Duffy, David R. Arrowsmith, Simon P. Lee, Ralph Schmidt
  • Publication number: 20110187029
    Abstract: The present invention provides an aliphatic aromatic polyester comprising: i) 40 to 60 mol %, based on components i to ii, of one or more dicarboxylic acid derivatives selected from the group consisting of: sebacic acid, azelaic acid and brassylic acid; ii) 60 to 40 mol %, based on components i to ii, of a terephthalic acid derivative; iii) 98 to 102 mol %, based on components i to ii, of 1,3-propanediol or 1,4-butanediol, and iv) 0.01% to 5% by weight, based on the total weight of said components i to iii, of a chain extender and/or crosslinker selected from the group consisting of a polyfunctional isocyanate, isocyanurate, oxazoline, carboxylic anhydride, epoxide and/or an at least trihydric alcohol or an at least tribasic carboxylic acid. The present invention further provides a process for producing the polyesters, polyester blends comprising these polyesters and also for the use of these polyesters and polyester blends.
    Type: Application
    Filed: September 22, 2009
    Publication date: August 4, 2011
    Applicant: BASF SE
    Inventors: Björn Dietrich, Kai Oliver Siegenthaler, Gabriel Skupin, Andreas Künkel, Motonori Yamamoto
  • Publication number: 20110178196
    Abstract: The present invention relates to biodegradable polymer mixtures comprising i) 40% to 95% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic or aliphatic and aromatic dicarboxylic acids and aliphatic dihydroxy compounds; ii) 5% to 60% by weight, based on the total weight of said components i to ii, of polyalkylene carbonate, particularly polypropylene carbonate; iii) 0% to 60% by weight, based on the total weight of said components i to iii, of at least one biodegradable homo- or copolyester selected from the group consisting of polylactic acid, polycaprolactone and polyhydroxyalkanoate, and/or of an inorganic or organic filler; iv) 0% to 10% by weight, based on the total weight of said components i to ii, of an epoxy-containing copolymer based on styrene, acrylic ester and/or methacrylic ester, and v) 0% to 15% by weight of an additive selected from the group consisting of lubricant, antiblocking agent, antistat, UV absorber, UV stabilizer, thermal stabil
    Type: Application
    Filed: September 21, 2009
    Publication date: July 21, 2011
    Applicant: BASF SE
    Inventors: Tobias Heinz Steinke, Jürgen Ahlers, Freddy Gruber, Gabriel Skupin
  • Publication number: 20110152394
    Abstract: An adhesive composition for stealth dicing of a semiconductor, an adhesive film, and a semiconductor device including the adhesive film, the adhesive composition including a polymer resin, the polymer resin having a glass transition temperature of about 5° C. to about 35° C., an epoxy resin, the epoxy resin including a liquid epoxy resin and a solid epoxy resin, a phenolic epoxy resin curing agent, an inorganic filler, a curing catalyst, and a silane coupling agent.
    Type: Application
    Filed: December 16, 2010
    Publication date: June 23, 2011
    Inventors: Ah Ram PYUN, Jae Hyun Cho, Ki Tae Song
  • Publication number: 20110045278
    Abstract: Provided is a filling foam composition for filling a gap between members by foaming. The filling foam composition has a heat sagged length of 14 mm or less in (1) heat sag test without any breakage caused by (2) impact test.
    Type: Application
    Filed: August 19, 2010
    Publication date: February 24, 2011
    Applicant: Nitto Denko Corporation
    Inventors: Atsushi Kuriu, Yoshiaki Mitsuoka
  • Publication number: 20100273905
    Abstract: The invention relates to a material mixture comprising at least one epoxy resin and a thermoplast, selected from such copolymers that comprise at least three different monomers. Preferably, the thermoplast is selected from such where at least one monomer is a hydrocarbon without heteroatoms and with at least one C?C double bond and where at least one other monomer is an optionally substituted acrylate or an optionally substituted acrylic acid ester. The invention also relates to a material mixture of said kind that additionally comprises the following components: at least one blowing agent, at least one hardener and at least one filler. The invention relates to methods for the production of molded bodies made from said material mixture, to the molded bodies and the use thereof for structural reinforcement.
    Type: Application
    Filed: June 17, 2010
    Publication date: October 28, 2010
    Applicant: Henkel AG & Co. KGaA
    Inventor: Xaver Muenz
  • Patent number: 7820729
    Abstract: A process for preparing functionalised microporous polymers (which are also known as micro-cellular polymers or polyHIPE polymers (PHPs)) using intensified internal heating (for example by microwave irradiation).
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: October 26, 2010
    Assignee: University of Newcastle Upon Tyne, c/o School of Chemical Engineering and Advanced Materials
    Inventors: Galip Akay, Zainura Zainon Noor, Omer Faruk Calkan, Teresa Manguangua Ndlovu, David Robert Burke
  • Publication number: 20100239834
    Abstract: The invention relates to a foam ply based on a biodegradable polyester mixture, comprising i) from 70 to 5% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, and ii) from 30 to 95% by weight, based on the total weight of components i to ii, of poly-lactide, and iii) from 0.1 to 5% by weight, based on the total weight of components i to ii, of a copolymer which comprises epoxy groups and is based on styrene, acrylates, and/or methacrylates, and iv) from 0.5 to 15% by weight of additives; and v) from 0 to 50% by weight of inorganic or organic filler, and also to processes for production of the foam ply mentioned, and to the use of the foam plies for the production of moldings and foils, and also to moldings and foils comprising the foam plies mentioned.
    Type: Application
    Filed: February 11, 2008
    Publication date: September 23, 2010
    Applicant: BASF SE
    Inventors: Bjoern Dietrich, Daniela Longo, Gabriel Skupin, Florian Krueckl
  • Publication number: 20100183863
    Abstract: A foam is disclosed that can be cured by heat having, for example, 10 to 80 vol. % of at least one gas and a compound that can be cured by heat. The foam can include at least one polyurethane polymer and at least one curing agent that can be activated by increased temperature. Foams that can be cured are suitable as flues, sealing compounds, or for the production of coatings, and can be cured by heat for structural adhesive bonds and for lining in vehicle construction.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 22, 2010
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Martin LINNENBRINK, Jan Olaf Schulenburg, Michael Gutgsell
  • Publication number: 20100108258
    Abstract: Hot-curing epoxy resin compositions are disclosed which firstly are solid in a hardened state at room temperature and secondly form an adhesion-free surface and are impact-resistant and can have high glass transition temperatures, above, for example, 110° C. An exemplary hot-curing epoxy resin composition can form separate phases on hardening, a continuous phase being formed by epoxy resins. If the compositions include a blowing agent, they can have excellent suitability for production of foams, such as structural foams.
    Type: Application
    Filed: November 2, 2009
    Publication date: May 6, 2010
    Applicant: SIKA TECHNOLOGY AG
    Inventors: Juergen Finter, Elyes Jendoubi
  • Publication number: 20090298960
    Abstract: A composition containing at least one epoxy resin, at least one phenol compound that is solid at room temperature, at least one polyether amine, at least one propellant, at least one hardener, at least one filler suitable for manufacturing structural foams that are notable for ductile behavior under compressive or flexural loading, i.e. an elastic deformation is observed under compressive load or in the three-point flexural test.
    Type: Application
    Filed: April 20, 2009
    Publication date: December 3, 2009
    Applicant: Henkel AG & Co. KGaA
    Inventors: Xaver Muenz, Larissa Bobb
  • Publication number: 20090069456
    Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.
    Type: Application
    Filed: February 12, 2007
    Publication date: March 12, 2009
    Applicant: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 7473715
    Abstract: The present invention relates to methods, materials, and products for forming a foamed product, comprising the steps of combining an epoxy-based component with an amine-based component. The epoxy component is cross-linked through a polymerization reaction catalyzed by the amine formulation. In this regard, an reactive mixture or exothermic reaction is created between the epoxy component and the amine component when combined. The heat generated by the exothermic reaction softens a thermoplastic shell of a blowing agent formulated within the epoxy component thereby enabling a solvent core within the thermoplastic shell of the blowing agent to expand from the heat generated by the exothermic or reactive mixture.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: January 6, 2009
    Assignee: Zephyros, Inc.
    Inventors: Michael J. Czaplicki, David J. Kosal, Kevin Hicks
  • Patent number: 7473717
    Abstract: Expandable thermosettable compositions containing at least one epoxy resin, at least one finely divided thermoplastic polymer powder, at least one blowing agent, at least one curing agent, and at least one filler are suitable for the production of thermosetting laminated bodies with a tacky surface. These laminated bodies can be produced and handled in a simple manner and are suitable for stiffening and reinforcing flat structural components, in particular vehicle body structural components, such as vehicle body frames, doors, trunk lids, engine hoods and/or roof components in automobile construction. The expandable thermosettable compositions are also suitable for the production of thermosetting, thermally expandable shaped articles for reinforcing hollow structural members by the injection molding process. In preferred embodiments, the composition is injected onto a metallic or thermoplastic carrier.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: January 6, 2009
    Assignee: Henkel AG & Co. KGaA
    Inventors: Xaver Muenz, Thomas Leeb, Rajat K. Agarwal, Gregory A. Ferguson, Michael Puckett
  • Patent number: 7199165
    Abstract: An expandable material and articles incorporating the same are disclosed. The material includes a polymeric admixture; a blowing agent; a curing agent; a tackifier; and optionally, a filler or fiber.
    Type: Grant
    Filed: June 15, 2004
    Date of Patent: April 3, 2007
    Assignee: L & L Products, Inc.
    Inventors: Abraham Kassa, Matthew Harthcock, Jeffrey Apfel
  • Patent number: 7119149
    Abstract: The present invention is directed to a high expansion two-component structural foam that expands to about twice its original volume while maintaining good cell structure. The foam of the present invention is based on epoxy resins. Each component of the foam system exhibits storage stability, e.g., no phase separation, yet reacts when combined to provide a cured material having exceptionally good compression strength and modulus. The blowing system used to prepare the foam produces a foam which is uniform in appearance and is essentially free of the large voids often found in conventional two-part thermosettable compositions, even when a relatively large mass is utilized.
    Type: Grant
    Filed: January 3, 2003
    Date of Patent: October 10, 2006
    Assignee: Henkel Kommanditgesellschaft AUF
    Inventors: Gregory A. Ferguson, Rajat K. Agarwal, Vettithara C. Koshy