Abstract: A thermally and dimensionally stable structural foam plastic product having a cellular core and an integral solid skin on the surface thereof. The structural foam product is produced by injection molding and comprises a thermoplastic resin and from 1 to 30% by volume of flake mica as a filler.

Abstract: A process is disclosed for producing polyurethane resins using novel catalysts selected from the group consisting of a process for the production of cellular or non-cellular polyurethane resins comprising reacting:(a) polyisocyanates; with(b) compounds having at least 2 isocyanate reactive hydrogen atoms; in the presence of(c) tertiary amines as catalysts; optionally with the addition of(d) blowing agents, stabilizers and other known additives; characterized in that the substances used as component (c) comprise compounds selected from the group consisting of ##STR1## and mixtures thereof in which formulae: the symbols R may be the same or different and represent straight or branched-chain alkyl groups having from 1 to 4 carbon atoms;the symbols n may be the same or different and represent 2 or 3;the symbols m may be the same or different and represent 2 or 3; andk represents an integer of from 1 to 5.

Abstract: This disclosure relates to a new color stable integral skin polyurethane foam and method of producing the same wherein an integral skin foam is provided which will not "yellow" or change color severely when exposed to ultraviolet light or other visible radiation. The foam composition in its most basic aspect involves the combination of a polyol, an isocyanate, and a crosslinker or chainextender, with a catalyst comprised of stannous octoate and dimethyltin dilaurate. Other ingredients such as a blowing agent, a pigment, an ultraviolet stabilizer, an anti-oxidant, and an anti-ozonant may be added depending upon the final properties desired.

Abstract: A process for the production of silicic acid heteropolycondensates, wherein at least one hydrolysable silicic acid derivative; at least one substituted silane; optionally at least one functional silane and/or optionally at least one substantially involatile oxide soluble in the reaction medium or at least one compound forming a substantially involatile oxide are condensed in the presence of at least the quantity of water stoichiometrically required for hydrolysis and optionally in the presence of a condensation catalyst and/or a solvent. The polycondensates are useful in the production of membranes and adsorbents.

Abstract: A flexible polyurethane foam having a low flame spread index is produced by combining polyol (preponderantly diol and/or triol) with polyisocyanate (preponderantly diisocyanate) in the presence of a foaming catalyst and a blowing agent. By combining at least 75% by weight of pentabromoethyl benzene, based upon the weight of the polyol, a flame spread index less than 150 can be achieved for the resulting foam in the ASTM test E-162-76. Significantly, polyurethane foams having a flame spread index less than 25 have been produced with this invention.

Abstract: Pressure-resistant polyurethane-polyurea particles with textured internal mass prepared from a liquid phase immiscible with water and containing organic solvents, isocyanate prepolymers and optionally active substances or mixtures of active substances, the liquid phase being dispersed in an aqueous phase at temperatures of from 0.degree. C. to 95.degree. C., wherein the liquid organic phase contains as isocyanate prepolymer a reaction product of a stoichiometric excess of an aliphatic, aromatic, cycloaliphatic, or araliphatic di- or polyisocyanate with a di- or polyol, the reaction product having a mean molecular weight in the range of from about 300 to 10,000, and an alkyl and/or alkoxyalkyl acetate of the formula ##STR1## in which m is zero, 1 or 2, n is 1 to 4, and R is (C.sub.1 -C.sub.5)alkyl, and the aqueous phase contains a protective colloid and optionally a surface-active agent.

Abstract: An unfoamed permeable material, which absorbs and desorbs moisture satisfactorily and which is suitable for making thin-walled articles having a maximum thickness of 3 mm, is based on plastic and/or rubber mixtures containing macromolecular hydrophilic fillers. The hydrophilic fillers are synthetic, water insoluble, cross-linked macromolecular materials containing pendent polar groups, which are able to bind water reversibly, e.g. hydroxy, amine, amide, carboxylic and sulfonic groups in H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, Ca.sup.++, or Ba.sup.++ form, or quaternary ammonium groups in OH.sup.-, Cl.sup.- or HSO.sub.4.sup.- form.

Abstract: The instant invention relates to a one-step process for the production of elastomeric moldings which have a compact surface by the technique of reaction injection molding, using highly reactive systems of specific polyisocyanates, polyhydroxyl compounds and specific active aromatic polyamines. The instant invention further relates to active hydrogen containing blends useful in preparing elastomeric moldings, said blends comprising polyhydroxyl compounds, and specific active aromatic diamines. The blends herein may also contain catalyst for the reaction between hydroxyl groups and isocyanate groups.

Abstract: A hydrophile polyurethane foam prepared from a hydrophile polyol, a polyisocyanate in which NCO groups are not directly bonded to an aromatic ring, a surface active agent, a swelling agent and a catalyst comprising:(A) at least one compound selected from the group consisting of:(1) diazabicyclo-alkenes of formula: ##STR1## (2) substituted guanidines and salts of formula: ##STR2## (3) substituted biguanidines of formula: ##STR3## (4) substituted biguanidines of formula: ##STR4## wherein the substituents can have different meanings, and (B) at least an alkali metal or alkaline earth metal salt of organic acids having a dissociation constant Ka<10.sup.-1.

Abstract: The instant invention is directed to a process for the production of weather-resistant rigid molded foams based on polyurethanes having a dimensional stability under heat according to DIN 53 432 of at least 70.degree. C. and a compact surface, a cellular core and an integral density distribution throughout the cross-section of the moldings, comprising foaming a foamable reaction mixture of polyisocyanates, polyhydroxyl compounds, blowing agents and, optionally, other isocyanate-reactive compounds, activators and other auxiliaries in a closed mold under the conditions of in-mold foaming, the improvement wherein the polyisocyanates used are reaction products containing isocyanate groups and urethane groups, said reaction products formed by reacting diisocyanates containing at least one cycloaliphatically bound isocyanate group and no more than one aliphatically bound isocyanate group with sub-stoichiometric quantities of organic polyhydroxyl compounds.

Abstract: A bung for closing a wine bottle in the manner of a cork is formed in a conventional injection-moulding machine from ethylene-vinyl acetate copolymer (EVA) with the addition of sodium metabisulphite and sodium bicarbonate. The sodium metabisulphite, which is in stoichiometric excess in relation to the sodium bicarbonate, decomposes to liberate sulphur dioxide. The sodium bicarbonate decomposes to liberate water and carbon dioxide. The bung as moulded accordingly has a foamed core with a liquid-impervious skin. It contains sulphur dioxide, and water enabling the sulphur dioxide to act as an oxygen scavenger when the bung is in use in a wine bottle. The bung therefore provides the bottle with a long shelf life, with no noticeable tainting of the wine.

Abstract: A molding composition is disclosed for forming in a single step a natural sandwich foam product having a cellular core and a thick, densified outer layer. A hard, particulate filler material such as fly ash is admixed with an unreacted, rigid polyurethane foam system, together with a density distribution control agent such as carbon tetrachloride which lowers the viscosity of the admixture. In molding, the mold cavity is charged with the admixture and the foam reaction is permitted to occur with the mold closed. The resultant, filled foam product has a thick outer layer formed adjacent the mold surface of substantially greater density than its core. In the densified layer, both the polyurethane and filler material components of the resultant product are concentrated to provide over three times the density of the core structure. Formulations are set forth which provide substantial layer thickness and an outer surface having a durometer hardness value of 50 or greater over the entire surface area.

Abstract: A tough board of thermoplastic resin foam provided with skin layers on both surfaces thereof and formed of large cells elongated in the direction of the thickness of said board, wherein an intermediate high density layer thicker than 0.1mm lies substantially halfway between the upper and lower surfaces of said board. The board is formed by extruding thermoplastic resin containing dissolved foaming agent as a sheet, cooling the upper and lower surfaces rapidly to form solid skin layers and then slowly cooling while allowing controlled expansion thereof between expansion restricting members.

Abstract: A process for preparing polyurethane with integral skin, wherein a composition comprising following ingredients: polyol, polyisocyanate, at most one part by weight of water to 100 parts by weight of polyol and catalyst, is reacted in a mould so that a polyurethane is formed, characterized in that one uses a polyisocyanate the NCO groups of which are not directly bonded to an aromatic group and, as catalyst, at least one of the following four synergistic combinations:(1) at least an amine containing the structure: ##STR1## in association with at least an alkali metal or alkaline-earth metal salt, alcoholate and/or phenolate of an acid the dissociation constant of which Ka.ltoreq.10.sup.-1, preferably Ka.ltoreq.10.sup.

Abstract: This invention relates to filter material consisting substantially of a microporous and/or macroporous sheet structure obtained by coagulation of a polymer solution in which at least one surface area of the sheet structure is abraded more or less, depending on the desired pore size and a process for producing said filter materials.

Abstract: Cellular and non-cellular polyurethane plastics and semi-hard polyurethane foams which are prepared by the use of novel Mannich bases of the general formula ##STR1## and which have improved strength and tear resistance are disclosed herein.

Abstract: Polyurethane plastics are dyed with dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, halogen, optionally substituted C.sub.1 -C.sub.4 -alkyl, optionally substituted C.sub.1 -C.sub.4 -alkoxy and optionally substituted C.sub.1 -C.sub.4 -alkylcarbonylamino and R.sub.2 denotes hydrogen, optinally substituted C.sub.1 -C.sub.4 -alkyl and optionally substituted C.sub.1 -C.sub.4 -alkoxy, while A and B denote optionally branched alkylene chains which can be identical or different and preferably have 2 to 6 carbon atoms, with formation of covalent bonds, in that the dyestuffs are added before or during the polyaddition reaction to the reacton mixture of polyol and polyisocyanate or to one of the components.

Abstract: The instant invention is directed to novel mold release agents for polyurethane resins and to the use thereof, particularly in the closed mold forming of polyurethane foams. The mold release agents disclosed herein are applied to the surface of the mold prior to molding and broadly comprise talc dispersed in an emulsion of water and an organic solvent.

Abstract: A mold-release agent is provided which consists essentially of 99.9% to 80% by weight of an aromatic polyisocyanate containing at least two isocyanate groups and 0.1% to 20% by weight of a fatty acid ester, e.g., glycerol trioleate, olive oil, peanut oil, etc. A process of using the material by incorporating it in polyurethane foams is disclosed.

Abstract: A zero pressure device is composed of either a microcellular or homogeneous polyurethane made by reacting an organic polyisocyanate with at least three polyols, a monomeric polyol of 2 to 3 hydroxyls having a molecular weight of less than 250, a polyester polyol of 2 to 3 hydroxyls having a molecular weight of 800 to 3000 and a polyether polyol of 2 to 3 hydroxyls having a molecular weight of 4 to 7000. When the zero pressured device is a run-flat ring for a tire-wheel assembly, it has an average density of 60 to 65 pounds per cubic foot and 30 to 42 pounds per cubic foot when it is a tire.

Abstract: A zero pressure device is composed of either a microcellular or homogeneous polyurethane made by reacting an organic polyisocyanate with at least three polyols, a monomeric polyol of 2 to 3 hydroxyls having a molecular weight less than 250, a polyether triol having a molecular weight of 4600 to 6000 and a polyether glycol having a molecular weight of 3500 to 4200. When the zero pressured device is a run-flat ring for a tire wheel assembly, it has an average density of 60 to 65 pounds per cubic foot and 30 to 42 pounds per cubic foot when it is a tire.

Abstract: A rigid, dimentionally stable, distortion-free article of foamed polyvinyl aromatic resin, having a solid outer skin, is formed by incorporating in a foamable polyvinyl aromatic resin a finely, divided inert solid that has been surface treated to render the solid hydrophobic and then molding the foamable composition under foaming conditions. Foamed polyvinyl aromatic resin articles molded in accordance with the present invention have physical dimensions capable of meeting tolerances in the order of .+-. 0.002 inches and are suitable for use in the manufacture of precision measuring devices and, particularly, frames for level instruments.

Abstract: This invention relates to compositions and methods for forming polyether polyurethanes utilizing internal release additives for the purpose of facilitating mold release in the production of molded objects. The invention discloses four classes of internal release additives: (1) mixtures of aliphatic or aryl carboxylic acid and a polar metal compound; (2) carboxyalkylsiloxanes; (3) aliphatic glyoximes; and (4) aralkyl quaternary ammonium salts.

Abstract: An elastic polyurethane foam having a density, sag factor, tensile strength and elongation at break which adapt it for use in upholstery is prepared by reacting a poly(alkylene ether) polyol having at least about 10% by weight of primary hydroxyl groups and hydrazine or a hydrazine adduct with an organic polyisocyanate which contains at least about 50% by weight of distilled tolylene diisocyanate.

Abstract: The present invention relates to the production in closed molds, of foams with outstanding mold-release properties. These improved properties are obtained by including in the foamable mixture salts of saturated or unsaturated aliphatic or cycloaliphatic carboxylic acids having at least 8 carbon atoms and tertiary amines of the type in which the atom ratio of tertiary amine nitrogen to carbon in the molecule is between 1:3 and 1:12.

Abstract: Polystyrene foam is extruded upwardly as a tube into a cooling media of boiling water, both the interior and exterior surfaces of the cylindrically shaped extrudate passing through a bath of boiling water of variable depth. The polystyrene foam extrudate produced by such a method has a high density at the interior and exterior surfaces, with the density progressively decreasing from these surfaces toward the center core of the extrudate.