Ingredient Contains A Metal Atom Patents (Class 521/92)
  • Patent number: 5470637
    Abstract: A thermoplastic polyester composition suited for preparing a film or fiber having excellent abrasion resistance, as well as a biaxially oriented polyester film consisting essentially of the polyester composition are disclosed. The thermoplastic polyester according to the present invention is characterized by comprising a thermoplastic polyester (A) and zirconium oxide particles (B) having monoclinic and/or tetragonal crystal structure.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: November 28, 1995
    Assignee: Toray Industries, Inc.
    Inventors: Jun Sakamoto, Minoru Yoshida, Masatoshi Aoyama, Masaru Suzuki, Yukari Nakamori, Iwao Okazaki, Koichi Abe
  • Patent number: 5462975
    Abstract: A rubber composition for sponge rubber which contains following components (A).about.(E) and satisfies the following requirements that the ratio by weight of (A)/(B) is 30/70.about.99/1 and the amount of component (C) is 50.about.400 parts by weight per 100 parts by weight of the total amount of components (A) and (B):(A): Epoxy group-containing acryl elastomer.(B): Ethylene copolymer which contains a carboxyl group(s) or a carboxylic anhydride group(s).(C): Hydroxyl compound of II or III group of typical metal element in periodic table.(D): Vulcanizer.(E): Foaming agent.The sponge rubber compositions of the invention can be used for sponge for insulator in the field of electricity, architecture, automobile and the like, because sponge rubber compositions of the invention have the characteristics of good heat resistance, good oil stability, high-foaming property, and good shape-retention.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: October 31, 1995
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Keisaku Yamamoto, Kiyoshi Ikeda, Masahiro Fukuyama
  • Patent number: 5453453
    Abstract: This invention is directed to a fire-resistant, essentially halogen-free epoxy composition that emits low amounts of smoke and toxic gas while burning. The one-part composition is particularly useful in aerospace applications for bonding, sealing and/or insulating metal, plastic and composite parts.
    Type: Grant
    Filed: April 6, 1994
    Date of Patent: September 26, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alain H. Lamon, Sylvie C. Le Cozannet
  • Patent number: 5445862
    Abstract: According to the present specification there is disclosed a porous film having a number of throughholes extending from one side to the other side, obtained by molding into a sheet form a resin composition comprising an ethylene-.alpha.-olefin copolymer, a thermoplastic elastomer and an inorganic filler and then subjecting the sheet to stretching for orientation. Said porous film has excellent flexibility, stretchability and moisture permeability. These properties are made possible by using individual components in particular proportions, molding the resulting composition into a sheet form and then stretching the sheet to form fine throughholes therein so as to have a moisture permeability of 2,000 g/m.sup.2.24 hr or more.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: August 29, 1995
    Assignee: Tokuyama Corporation
    Inventors: Shingo Kaneko, Yoshio Murakami, Yoshinari Yamashita
  • Patent number: 5442041
    Abstract: A thermoplastic resin such as a styrene/maleic anhydride copolymer is treated to remove volatile impurities such as unreacted styrene by admixing with a chemical blowing agent and extruding under a vacuum. The chemical blowing agent is converted into an inert gas such as carbon dioxide during extrusion; the gas evolved is removed, together with the volatile impurities, through one or more vents in the extruder. The use of a chemical blowing agent, rather than the inert gas itself, permits the facile distribution of the CO.sub.2 stripping agent throughout the molten thermoplastic resin using commonly available extruders without the need for elaborate gas injection means.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: August 15, 1995
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Ramesh Mallikarjun, Leon L. Otte, William J. Cleland
  • Patent number: 5438079
    Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: August 1, 1995
    Assignees: Gary De Laurentiis, Gary Peterson, Robert Schibel
    Inventor: Franklin A. Paris
  • Patent number: 5425992
    Abstract: A coated wire comprising:(i) an electrical conductor coated with(ii) a mixture of (a) two linear copolymers of ethylene and one alpha-olefin having 3 to 8 carbon atoms, the first ethylene copolymer having a density of about 0.900 to 0.930 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes and the second ethylene copolymer having a density of 0.931 to about 0.950 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes, and for each 100 parts by weight of the first ethylene copolymer, there are about 15 to about 100 parts by weight of the second ethylene copolymer, and (b) for each 100 parts by weight of component (a), there are about 65 to about 150 parts by weight of a mixture comprising huntite and hydromagnesite in a weight ratio of about 2:1 to about 1:1.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: June 20, 1995
    Assignee: Nippon Unicar Company Ltd.
    Inventors: Takeshi Tachikawa, Katsuhiro Horita
  • Patent number: 5413848
    Abstract: Low thermal conductivity insulation for refrigerators and the like is produced by blowing a resinous foam in an inert (e.g., nitrogen) atmosphere with a mixture of carbon dioxide and a low thermal conductivity inert gas such as krypton or xenon. The foam is then sealed in a gas-impervious enclosure and carbon dioxide is removed therefrom, typically by inclusion in said enclosure of a solid material reacted therewith such as an alkaline reagent. The final partial pressure of the low thermal conductivity gas in the enclosure is in the range of about 20-200 torr, and the total pressure is up to 110% of said partial pressure.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: May 9, 1995
    Assignee: General Electric Company
    Inventors: Heinz Jaster, William J. Ward, III
  • Patent number: 5403865
    Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: April 4, 1995
    Assignees: Reedy International Corporation, Genpak Corporation
    Inventors: Michael E. Reedy, Edward W. Rider, Jr.
  • Patent number: 5397828
    Abstract: A biaxially stretched polyester film is disclosed.The biaxially stretched polyester film comprises substantially spherical silica particles of colloidal state having average diameters ranging from approximately 20 nm to approximately 200 nm in amounts ranging from approximately 0.005% to approximately 1.0% by weight based on the total weight of the polyester; and alumina particles having average diameters ranging from approximately 50 nm to approximately 500 nm in amounts ranging from approximately 0.05% to approximately 5.0% by weight, the average diameter of the alumina particles being larger than that of the silica particles.The biaxially stretched film prepared according to the present invention has excellent surface properties such as slip property and abrasion resistance, so that the film may be used for manufacturing final products without scratches and white powders occurring thereon.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: March 14, 1995
    Assignee: Cheil Synthetics Inc.
    Inventors: Dae W. Ihm, Jeong L. Kim, Seung B. Jun
  • Patent number: 5393569
    Abstract: A water-permeable and fire-resistant film and the preparing method thereof is disclosed. The water-permeable and fire-resistant film comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyl oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb203 and Sb205. The surface of the film produced is smooth.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: February 28, 1995
    Assignee: China Textile Institute
    Inventors: Shin-Chuan Yao, Jong-Fu Wu, Kun-Lin Cheng, Chiu-Hsiung Tsai, Farn-Ping Koong, Kun-Lung Chuang, Shu-Lan Yao, Chin-Liu Liu
  • Patent number: 5389695
    Abstract: Low thermal conductivity insulation for refrigerators and the like is produced by blowing a resinous foam in an inert (e.g., nitrogen) atmosphere with a mixture of carbon dioxide and a low thermal conductivity inert gas such as krypton or xenon. The foam is then sealed in a gas-impervious enclosure and carbon dioxide is removed therefrom, typically by inclusion in said enclosure of a solid material reacted therewith such as an alkaline reagent. The final partial pressure of the low thermal conductivity gas in the enclosure is in the range of about 20-200 torr, and the total pressure is up to 110% of said partial pressure.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: February 14, 1995
    Assignee: General Electric Company
    Inventors: Heinz Jaster, William J. Ward, III
  • Patent number: 5376208
    Abstract: A water-permeable and fire-resistant product and the preparing method thereof is disclosed. The waterpermeable and fire-resistant product is made of a fabric layer and a purous film adhered thereon. The porous film of this invention comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyl oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb2O3 and Sb2O5. The surface of the product produced is smooth.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: December 27, 1994
    Assignee: China Textile Institute
    Inventors: Shin-Chuan Yao, Jong-Fu Wu, Kun-Lin Cheng, Chiu-Hsiung Tsai, Farn-Ping Koong, Kun-Lung Chuang, Shu-Lan Yao, Chin-Liu Liu
  • Patent number: 5366675
    Abstract: A foamable composition useful for rotational molding, is provided. The composition advantageously includes an ethylene vinyl ester copolymer as an additive. The additive beneficially has a higher melt index than the base resin of the composition.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: November 22, 1994
    Inventor: Donald G. Needham
  • Patent number: 5342857
    Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: August 30, 1994
    Assignees: Reedy International Corporation, Genpak Corporation
    Inventors: Michael E. Reedy, Edward W. Rider, Jr.
  • Patent number: 5336694
    Abstract: An expanded polymer product with high distortion temperature, high flame resistance and low smoke toxicity and opacity comprises, in combination:between 18% and 25% of a mixture of at least two isocyanates;between 8% and 11% of a styrene and maleic anhydride mixture;between 19% and 42% of a PVC resin in emulsion form;between 4% and 7% of at least one expanding agent;between 0.5% and 1% of at least one temperature stabilizer;between 16% and 40% of TiO.sub.2.Said product is used particularly in sea, ground and air transport, and in numerous constructional applications in which the materials must combine high technical characteristics with adequate lightness.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: August 9, 1994
    Assignee: Prima, S.p.A.
    Inventor: Leone Lauri
  • Patent number: 5328937
    Abstract: A foam spacer which is usable as a cork substitute in the base cushion layer of a glass spacer. The spacer, which is adapted to replace natural cork spacers is preferably laminated to a tack layer or otherwise adhered to a surface. The spacer is formed from a plasticized foamable resin which includes a quantity of incorporated reinforcing agents.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: July 12, 1994
    Assignee: Gaska Tape, Inc.
    Inventor: Lawrence A. Cascino
  • Patent number: 5318837
    Abstract: Soundproofing materials consisting essentially of zinc oxide whisker particles having a nucleus body and needle crystal portions extending radially from the central body in different plural directions. The materials may comprise a support material for supporting the zinc oxide whisker particles. Such support materials include inorganic materials such as metals, ceramics, glasses, cements, mortars and various fillers in the form of powder, flakes, fibers and the like, and organic materials such as resins, rubbers, waxes and the like. These materials are particularly suitable for sound insulation, sound proofing, vibration damping and vibration insulation.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: June 7, 1994
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Minoru Yoshinaka, Eizo Asakura, Mitsumasa Oku, Takeshi Hamabe, Motoi Kitano
  • Patent number: 5317033
    Abstract: The present invention concerns a process for producing a synthetic resin foam composed of cells having substantially two sizes, one of the sizes being at most 0.3 mm and the other size as being 0.4 to 1 mm, comprising the steps of:forming a mixture of one or more of a water-absorbent high molecular compound, a cell-controlling agent, a synthetic resin, and water; melting the mixture with heating; incorporating a volatile type foaming agent into the mixture under pressure; and extruding the mixture into a lower pressure space to form a foam.
    Type: Grant
    Filed: January 14, 1993
    Date of Patent: May 31, 1994
    Inventors: Shigeru Motani, Tadayuki Saito, Takahiro Hayashi
  • Patent number: 5317044
    Abstract: Compositions for producing foamed products which include additives and blowing agents which cause the surface treatment additives to migrate to the surfaces of foamed products. The products produced from the compositions require less additives because the incorporated additives are concentrated at the surfaces thereof.
    Type: Grant
    Filed: June 11, 1991
    Date of Patent: May 31, 1994
    Assignee: J. M. Huber Corporation
    Inventors: Gerry Mooney, Rod A. Garcia, Michael E. Tarquini, John A. Kosin
  • Patent number: 5314925
    Abstract: A process for producing structural aromatic polycarbonate thermoplastic foam is provided which involves gas expansion of a melted aromatic polycarbonate thermoplastic resin composition containing an amount of a polytetrafluoroethylene nucleating agent. The thermoplastic resin compositions provided exhibit an improved uniformity of cell structure in the resultant structural thermoplastic foam as a result of the incorporation of the polytetrafluoroethylene nucleating agent. The process and compositions are useful in the production of structural thermoplastic foam articles.
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: May 24, 1994
    Assignee: General Electric Company
    Inventors: Ann M. Burnell, Albin P. Berzinis, Timothy M. Conroy, Kim G. Balfour
  • Patent number: 5314420
    Abstract: A superabsorbent polymer having improved absorption under pressure and fast absorption rate is obtained by first providing a solution containing carboxylic acid monomers or water soluble salts thereof, and a crosslinking agent. A carbonate blowing agent and a polymerization initiator are added, individually or in combination, to the solution to form a carbonated monomer solution. A polymerization initiator is then added to the carbonated monomer solution which is then polymerized at temperatures ranging from about 0.degree. C. to about 130.degree. C., forming a microcellular hydrogel. The microcellular hydrogel is chopped or ground into gel pieces having a particle diameter ranging from about 0.1 mm to about 5.0 cm. The gel pieces are dried at temperatures ranging from about 85.degree. C. to about 210.degree. C., and are then ground to form a polymer having a particle size of from about 0.05 mm to about 5.0 mm. A mixture is formed from 100 parts by weight of the polymer and about 0.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: May 24, 1994
    Assignee: Nalco Chemical Company
    Inventors: Scott J. Smith, Eric J. Lind
  • Patent number: 5306736
    Abstract: Compositions for producing foamed products which include additives and blowing agents which cause the surface treatment additives to migrate to the surfaces of foamed products. The products produced from the compositions require less additives because the incorporated additives are concentrated at the surfaces thereof.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: April 26, 1994
    Assignee: J. M. Huber Corporation
    Inventors: Gerry Mooney, Rod A. Garcia, Michael E. Tarquini, John A. Kosin
  • Patent number: 5302624
    Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.
    Type: Grant
    Filed: May 14, 1993
    Date of Patent: April 12, 1994
    Inventors: Michael E. Reedy, Edward W. Rider, Jr.
  • Patent number: 5302625
    Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: April 12, 1994
    Assignee: Darlene May Paris
    Inventor: Franklin A. Paris, deceased
  • Patent number: 5300543
    Abstract: A thermoplastic molding composition suitable for the preparation of foam is disclosed. The composition comprises a thermoplastic resinous component and a foaming agent which includes A) (i) 0.01 to 4.8% alumina hydrate (aluminum hydroxide) in combination with (ii) 0.01 to 4.8% of an acidic additive or B) 0.01 to 4.8% of the reaction product of said (i) and said (ii), the percentages being relative to the weight of the composition to be foamed. The invention is based on the finding that the foaming of the composition does not lead to any significant reduction in molecular weight of the resinous component or to troublesome discoloration of the foam, even during its re-extrusion.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: April 5, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Ebert, Jurgen Kirsch, Burkhard Kohler, Wolfgang Beer, Siegfried Anders, Rolf Dhein
  • Patent number: 5288764
    Abstract: Disclosed is a process for obtaining polyester articles, including foamed articles, containing low levels of extractable branching agent. The process comprises: (1) forming a molten mixture comprising (i) a major amount of a first resin composition comprising polyester and from 0 up to about 1 wt. % of a compound capable of branching the polyester, and (ii) a minor amount of a second polyester resin composition comprising at least about 50 wt. % polyester resin and greater than about 2 wt. % of a compound capable of branching the polyester, wherein the relative amounts of (i) and (ii) are such that said molten mixture comprises from about 0.1 wt. % to about 1 wt. % of said branching compound; (2) adding a blowing agent to the molten mixture; and (3) extruding the resultant mixture to obtain a foam. The invention is also directed to the second composition used in the above process, and foamed polyester articles obtained from the process.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: February 22, 1994
    Assignee: Amoco Corporation
    Inventors: George E. Rotter, John L. Melquist, Weilong Chiang, Boh C. Tsai, John J. Kelly
  • Patent number: 5274006
    Abstract: The present invention provides a foamable epoxy resin composition (A) 100 parts by weight of a liquid epoxy resin (B) 0.5-20 parts by weight of a latent curing agent, (C) 0.5-15 parts by weight of a foaming agent having a decomposition temperature of 100.degree.-220.degree. C., (D) 0.05-5 parts by weight of a surface active agent and (E) 10-200 parts by weight of a rubbery elastomer or a powdery halogen-free thermoplastic resin of 150 .mu.m or less in average particle diameter, which composition has a melt viscosity of 2.5.times.10.sup.3 -5.times.10.sup.4 dPa.multidot.s at the decomposition temperature of said foaming agent. The composition can provide a foamed material of rigidity and good heat resistance, having an expansion ratio of 5 times or more and a dense cell structure of 0.5 mm or less in average cell diameter.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: December 28, 1993
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yutaka Kagoshima, Toshio Nagase, Takamitu Mikuni, Takeo Kobayashi
  • Patent number: 5272182
    Abstract: The present invention includes an improved blowing agent concentrate, comprising:(a) a vinyl aromatic polymer;(b) a preformed blend of a styrene/diene block copolymer and a hydrocarbon rubber extending oil; and(c) at least one blowing agent.The blowing agent concentrate is utilized to prepare foamable materials based on a variety of thermoplastic organic polymers. The foamable materials can in turn be molded into a variety of thermoplastic structures.
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: December 21, 1993
    Assignee: General Electric Company
    Inventor: Ann M. Burnell
  • Patent number: 5260345
    Abstract: Disclosed are absorbent foam materials suitable for use as or in the absorbent cores of absorbent articles, such as diapers which absorb and retain aqueous body fluids. Such foam materials comprise hydrophilic, flexible open-celled structures which are preferably prepared by polymerizing high internal phase (HIPE) water-in-oil emulsions. Such foam materials have a pore volume of from about 12 to 100 mL/g, and a capillary suction specific surface area of from about 0.5 to 5.0 m.sup.2 /g. These materials also exhibit a resistance to compression deflection such that a confining pressure of 5.1 kPa produces after 15 minutes a strain of from about 5% to 95% compression when the material is saturated at 37.degree. C. to its free absorbent capacity with synthetic urine.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: November 9, 1993
    Assignee: The Procter & Gamble Company
    Inventors: Thomas A. DesMarais, Keith J. Stone, Hugh A. Thompson, Gerald A. Young, Gary D. LaVon, John C. Dyer
  • Patent number: 5252618
    Abstract: Compositions for producing foamed products which include filler and/or pigment additives and blowing agents which enhance the strength of weld lines which are produced when the compositions are molded. The products produced from the compositions have weld line that demonstrate superior strengths as compared to similar foamed products which do not utilized the particular blowing agents.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: October 12, 1993
    Assignee: J. M. Huber Corporation
    Inventors: Rod A. Garcia, John A. Kosin, Gerry Mooney, Michael E. Tarquini
  • Patent number: 5250224
    Abstract: A stabilized powdered endothermic blowing agent which is a mixture of a polycarboxylic acid and an inorganic carbonate, the polycarboxylic acid and inorganic carbonate each having been surface treated with a component which prevents water from being absorbed thereby The blowing agent is incorporated into a polymeric concentrate used for producing foamed products.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: October 5, 1993
    Assignee: J. M. Huber Corporation
    Inventors: Satish K. Wason, Gerry Mooney, Claude R. Andrews, Michael E. Tarouini, John A. Kosin, Rod A. Garcia
  • Patent number: 5246625
    Abstract: Storage-stable 141b prepared by contacting 141b with alumina at temperatures of about 0-100 degrees Centigrade, compositions containing the thus treated 141b, and uses thereof for the production of polyurethane and polyisocyanurate foams.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: September 21, 1993
    Assignee: EH Atochem North America, Inc.
    Inventors: Richard M. Crooker, Maher Y. Elsheikh
  • Patent number: 5246626
    Abstract: Storage-stable 141b prepared by contacting 141b with alumina at temperatures of about 0-100 degrees Centigrade, compositions containing the thus treated 141b, and uses thereof for the production of polyurethane and polyisocyanurate foams.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: September 21, 1993
    Assignee: Elf Atochem North America, Inc.
    Inventors: Richard M. Crooker, Maher Y. Elsheikh
  • Patent number: 5246973
    Abstract: The introduction of a foamable silicone rubber composition that evolves neither toxic gas nor hydrogen, that does not suffer from inhibition of its cure to give silicone rubber, and that cures to give a silicone rubber foam containing uniform microcells. The foamable silicone rubber composition comprises:(A) 100 weight parts thermosetting liquid silicone rubber composition, and(B) 0.1 to 30 weight parts thermally expansible hollow plastic microparticles.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: September 21, 1993
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Akito Nakamura, Yuichi Tsuji
  • Patent number: 5240765
    Abstract: A silicone rubber composition comprising an organopolysiloxane and a curing agent is improved by adding a foaming agent in an amount of 0.1 to 10 parts by weight per 100 parts by weight of the organopolysiloxane. The composition is heat curable into silicone rubber films or coatings which are substantially unfoamed and tack-free on a surface.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: August 31, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Kazuma Momii
  • Patent number: 5236963
    Abstract: This invention relates to polymeric compositions capable of being converted into oriented microporous films having microvoid cells, interconnecting pores between the cells, and improved elongation, softness and tear strength, comprising an ethylene-propylene block copolymer having an ethylene content of about 10 to about 50 wt %, a low flexural modulus propylene-based polymer, a propylene homopolymer or copolymer having up to about 10 wt % of a comonomer of ethylene or an .alpha.-olefin of 4 to 8 carbon atoms, an inorganic filler such as calcium carbonate, a beta-spherulite nucleating agent, and optionally, a low molecular weight polypropylene and to microporous films formed from such compositions.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: August 17, 1993
    Assignee: Amoco Corporation
    Inventors: Philip Jacoby, William T. Tapp
  • Patent number: 5234963
    Abstract: The present invention is directed to the process and apparatus for compounding and pelletizing of chemical foaming agents in a high melt resin carrier and producing unique, uniform encapsulated and pelletized chemical foaming concentrates. More specifically, the present invention is directed to the compounding, encapsulating and pelletizing in a high melt resin carrier a highly loaded concentration (5 to 70 wt %) of foaming agents which include an endothermic foaming agent, an exothermic foaming agent or hybrid combinations of these two such that when incorporated into a thermoplastic resin to produce a foamed product will chemically react to form a mixture of carbon dioxide, nitrogen or hydrogen as the active foaming agent.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: August 10, 1993
    Assignee: Gaia Research
    Inventors: Rodrigo A. Garcia, Joseph G. Gho
  • Patent number: 5232955
    Abstract: The invention relates to a process for producing a highstrength a furan stone with high permeability and filtering effect mainly for protecting deep-drilled wells yielding mineral oil, natural gas and water against getting choked by sand. A mixture comprising an artificial resin as a binding material containing a catalyzer for controlling duration of binding and pumpability and an assorted granular material of high-strength forming the skeleton and salt filling and increasing pore spaces is homogenized and pumped into the corresponding producing section of the well into the area to be protected. After hardening of the mixture salt is dissolved from the obtained artificial stone and a filtering effect is achieved without binding the grains of the reservoir rock. Due to the mechanical characteristics and controlled porosity of the obtained artificial stone rock-parts, mainly sand delivered by the yielded fluidum into the well will be retained.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: August 3, 1993
    Assignees: Mol Magyar Olaj Es Gazipari Reszvenytarsasag, Koolajkutato Vallalat
    Inventors: Tibor Csabai, Miklos Magyar, Istvan Munkacsi, Mihaly Kun, Tibor Plajner, Ambrus Andristyak, Cecilia Fuzes nee Takacs, Istvan Balazs
  • Patent number: 5225315
    Abstract: A water-soluble coating or other deposit is produced from a formulation that is comprised of a curable liquid substance and a dispersed particulate effervescing agent. The formulation is particularly useful as a solder resist in the manufacture of PCBs, and the preferred composition contains n-vinyl-2-pyrrolidone, N,N-dimethylacrylamide, and polyvinylpyrrolidone.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: July 6, 1993
    Assignee: Dymax Corporation
    Inventors: Gary V. Grosclaude, Andrew G. Bachmann
  • Patent number: 5225107
    Abstract: The invention relates to new nucleating agents for the preparation of directly gassed thermoplastic foams. The new agents comprise a combination of citric acid, the salts or esters thereof and carbonate or bicarbonate and talc.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: July 6, 1993
    Assignee: Boehringer Ingelheim GmbH
    Inventors: Gunther Kretzschmann, Dieter Scholz, Karl-Heinz Hilgert
  • Patent number: 5225452
    Abstract: A foam forming composition comprises (a) one or more polysiloxanes having not less than three alkylhydrogen siloxane units per molecule, (b) one or more polysiloxanes having not less than two silicon-bonded hydroxyl group per molecule, (c) at least one liquid organic titanium compound and (d) a catalyst. Reaction between the organic titanate (e.g. tetraisopropyltitanate) and the hydroxy functional polysiloxane rapidly increases viscosity of the mixture to restrict flow of the composition as it cures to form a foam within 240 seconds of mixing. A vinyl polysiloxane may be incorporated.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: July 6, 1993
    Assignee: Dow Corning GmbH
    Inventors: Andre R. L. Colas, Heinz Mueller
  • Patent number: 5218006
    Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: June 8, 1993
    Inventors: Michael E. Reedy, Edward W. Rider, Jr.
  • Patent number: 5216037
    Abstract: A room temperature vulcanizable, foamable polysiloxane composition is described, which comprises:(A) a specific type of .alpha., .omega.-dihydroxyorganopolysiloxane which has a surface tension of not lower than 22 dynes/cm at 25.degree. C.;(B) a specific type of organopolyhydroxypolysiloxane;(C) a polyorganohydrogensiloxane which has at least two units of the following general formula in one moleculeR.sup.5.sub.a H.sub.b SiO.sub.(4-(a+b))/2wherein R.sup.5 represents a monovalent hydrocarbon group except for aliphatic unsaturated hydrocarbon group, a is an integer of 0 to 2, and b is an integer of from 0 to 3 provided that the total of a+b is an integer of from 1 to 3;(D) an unsubstituted or substituted alcohol having from 1 to 12 carbon atoms; and(E) a platinum catalyst.The composition has a high degree of foaming and the foamed product obtained from the composition has good foaming stability and good tensile strength.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: June 1, 1993
    Assignee: Shin-Etsu Chemical Co, Ltd.
    Inventors: Kei Miyoshi, Masatoshi Arai
  • Patent number: 5210107
    Abstract: A flexible foamed liquid crystal polymer film or sheet having uniformly small cells or bubbles. The foam cells are essentially spherical and have mean diameters less than or equal to approximately 250 microns. The cell size distribution is relatively small. The foamed sheet is made by extruding the polymer through a die under pressure at a temperature near or below the polymer's melting point; a gas or chemical blowing agent is extruded with the polymer to produce foaming as the polymer exits the die.
    Type: Grant
    Filed: January 17, 1991
    Date of Patent: May 11, 1993
    Assignee: Hoechst Celanese Corp.
    Inventors: Randy D. Jester, Detlef K. M. Frank
  • Patent number: 5187203
    Abstract: A composition and foam insulation for copper tubing is described herein which is formulated to retard copper oxidation and eliminate or reduce stress corrosion in the copper tubing. The copper compatible, elastomeric foam insulation is made from a composition comprising 100 parts by weight of rubber, vinyl chloride polymer at about 15 to about 85 pphr, a plasticizer selected from the group consisting of an alkyl phosphate ester and an oxyalkyl phosphate ester at about 10 to about 100 pphr, a fire retardant in an amount of at least about 100 pphr, a stabilizer in an amount effective to prevent degradation of the rubber and vinyl chloride polymer, a preservative at from about 0.1 to about 10 pphr, and a lubricant at about 10 to about 85 pphr, wherein the composition and foamed product contains no more than about 5 parts of free phenol per million.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: February 16, 1993
    Assignee: Armstrong World Industries, Inc.
    Inventors: Ronald S. Lenox, Kim S. Boyd, William S. Vought, Jr.
  • Patent number: 5174934
    Abstract: Processes using high temperature thermoplastic polymers in the in-situ fabrication in the formation of foamed composite sandwich or foam articles often result in weak unsound products which may be avoided by utilizing a high temperature thermoplastic in powder form (22), a blowing agent having a high decomposition temperature (24), and, if desired, reinforcers and/or fillers (28), admixing the thermoplastic, blowing agent and reinforcer and fillers (30), placing the admixture in a mold and, if forming a composite structure, in abutment with at least one skin (34), compacting the contents of the mold (37), and applying sufficient heat and/or pressure to the mold and its contents to melt the thermoplastic and generate gas within said mixture by decomposition of the blowing agent (38). Also, an activator may be included with the blowing agent which promotes the production of gas (26).
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: December 29, 1992
    Assignee: Sundstrand Corporation
    Inventor: Hossein Saatchi
  • Patent number: 5175194
    Abstract: A flame retardant composition and process which is particularly useful for rebonded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: December 29, 1992
    Assignee: Triad-Fabco, Inc.
    Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
  • Patent number: 5168104
    Abstract: A method to prepare uniform populations of macroscopic beads containing pores of at least 0.1 microns diameter is described. The beads consist essentially of a copolymer of a monoethylenically unsaturated monomer and a crosslinking polyethylenically unsaturated monomer, said resulting copolymer optionally being derivatized with functional groups, linking moieties, and/or affinity ligands. The macroporous beads are obtained by utilizing, as porogen in the polymerization reaction, porous inorganic particles which have been preabsorbed with a blowing agent. The blowing agent is not activated until after the polymerization takes place; when the blowing agent is activated, the organic polymer which isolates the inorganic porogen particles from each other in the bead is destroyed. Upon subsequent dissolution of the inorganic porogen, a network of pores throughout the organic copolymer-formed particle is formed. The resulting beads are useful in a variety of chromatographic, analytical and biomedical techniques.
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: December 1, 1992
    Assignee: Chembiomed, Ltd.
    Inventors: Nai-Hong Li, M. Abdul Mazid
  • Patent number: 5162280
    Abstract: A storage stable aqueous dispersion useful in the curing of unsaturated polyester resins and the suspension polymerization of vinyl monomers containing an aromatic diacyl peroxide, an alkylene glycol and dispersion-stabilizing amounts of magnesium aluminum silicate and a cellulose ether compound is disclosed. Also disclosed are the curing of polyester resins and the suspension polymerization of vinyl monomers using the dispersion.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: November 10, 1992
    Assignee: Witco Corporation
    Inventor: Lawrence A. Bock