Ingredient Contains A Metal Atom Patents (Class 521/92)
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Patent number: 5470637Abstract: A thermoplastic polyester composition suited for preparing a film or fiber having excellent abrasion resistance, as well as a biaxially oriented polyester film consisting essentially of the polyester composition are disclosed. The thermoplastic polyester according to the present invention is characterized by comprising a thermoplastic polyester (A) and zirconium oxide particles (B) having monoclinic and/or tetragonal crystal structure.Type: GrantFiled: November 23, 1993Date of Patent: November 28, 1995Assignee: Toray Industries, Inc.Inventors: Jun Sakamoto, Minoru Yoshida, Masatoshi Aoyama, Masaru Suzuki, Yukari Nakamori, Iwao Okazaki, Koichi Abe
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Patent number: 5462975Abstract: A rubber composition for sponge rubber which contains following components (A).about.(E) and satisfies the following requirements that the ratio by weight of (A)/(B) is 30/70.about.99/1 and the amount of component (C) is 50.about.400 parts by weight per 100 parts by weight of the total amount of components (A) and (B):(A): Epoxy group-containing acryl elastomer.(B): Ethylene copolymer which contains a carboxyl group(s) or a carboxylic anhydride group(s).(C): Hydroxyl compound of II or III group of typical metal element in periodic table.(D): Vulcanizer.(E): Foaming agent.The sponge rubber compositions of the invention can be used for sponge for insulator in the field of electricity, architecture, automobile and the like, because sponge rubber compositions of the invention have the characteristics of good heat resistance, good oil stability, high-foaming property, and good shape-retention.Type: GrantFiled: November 14, 1994Date of Patent: October 31, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Keisaku Yamamoto, Kiyoshi Ikeda, Masahiro Fukuyama
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Patent number: 5453453Abstract: This invention is directed to a fire-resistant, essentially halogen-free epoxy composition that emits low amounts of smoke and toxic gas while burning. The one-part composition is particularly useful in aerospace applications for bonding, sealing and/or insulating metal, plastic and composite parts.Type: GrantFiled: April 6, 1994Date of Patent: September 26, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alain H. Lamon, Sylvie C. Le Cozannet
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Patent number: 5445862Abstract: According to the present specification there is disclosed a porous film having a number of throughholes extending from one side to the other side, obtained by molding into a sheet form a resin composition comprising an ethylene-.alpha.-olefin copolymer, a thermoplastic elastomer and an inorganic filler and then subjecting the sheet to stretching for orientation. Said porous film has excellent flexibility, stretchability and moisture permeability. These properties are made possible by using individual components in particular proportions, molding the resulting composition into a sheet form and then stretching the sheet to form fine throughholes therein so as to have a moisture permeability of 2,000 g/m.sup.2.24 hr or more.Type: GrantFiled: December 22, 1994Date of Patent: August 29, 1995Assignee: Tokuyama CorporationInventors: Shingo Kaneko, Yoshio Murakami, Yoshinari Yamashita
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Patent number: 5442041Abstract: A thermoplastic resin such as a styrene/maleic anhydride copolymer is treated to remove volatile impurities such as unreacted styrene by admixing with a chemical blowing agent and extruding under a vacuum. The chemical blowing agent is converted into an inert gas such as carbon dioxide during extrusion; the gas evolved is removed, together with the volatile impurities, through one or more vents in the extruder. The use of a chemical blowing agent, rather than the inert gas itself, permits the facile distribution of the CO.sub.2 stripping agent throughout the molten thermoplastic resin using commonly available extruders without the need for elaborate gas injection means.Type: GrantFiled: January 19, 1995Date of Patent: August 15, 1995Assignee: ARCO Chemical Technology, L.P.Inventors: Ramesh Mallikarjun, Leon L. Otte, William J. Cleland
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Patent number: 5438079Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.Type: GrantFiled: April 11, 1994Date of Patent: August 1, 1995Assignees: Gary De Laurentiis, Gary Peterson, Robert SchibelInventor: Franklin A. Paris
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Patent number: 5425992Abstract: A coated wire comprising:(i) an electrical conductor coated with(ii) a mixture of (a) two linear copolymers of ethylene and one alpha-olefin having 3 to 8 carbon atoms, the first ethylene copolymer having a density of about 0.900 to 0.930 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes and the second ethylene copolymer having a density of 0.931 to about 0.950 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes, and for each 100 parts by weight of the first ethylene copolymer, there are about 15 to about 100 parts by weight of the second ethylene copolymer, and (b) for each 100 parts by weight of component (a), there are about 65 to about 150 parts by weight of a mixture comprising huntite and hydromagnesite in a weight ratio of about 2:1 to about 1:1.Type: GrantFiled: July 27, 1994Date of Patent: June 20, 1995Assignee: Nippon Unicar Company Ltd.Inventors: Takeshi Tachikawa, Katsuhiro Horita
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Patent number: 5413848Abstract: Low thermal conductivity insulation for refrigerators and the like is produced by blowing a resinous foam in an inert (e.g., nitrogen) atmosphere with a mixture of carbon dioxide and a low thermal conductivity inert gas such as krypton or xenon. The foam is then sealed in a gas-impervious enclosure and carbon dioxide is removed therefrom, typically by inclusion in said enclosure of a solid material reacted therewith such as an alkaline reagent. The final partial pressure of the low thermal conductivity gas in the enclosure is in the range of about 20-200 torr, and the total pressure is up to 110% of said partial pressure.Type: GrantFiled: August 1, 1994Date of Patent: May 9, 1995Assignee: General Electric CompanyInventors: Heinz Jaster, William J. Ward, III
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Patent number: 5403865Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.Type: GrantFiled: August 26, 1994Date of Patent: April 4, 1995Assignees: Reedy International Corporation, Genpak CorporationInventors: Michael E. Reedy, Edward W. Rider, Jr.
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Patent number: 5397828Abstract: A biaxially stretched polyester film is disclosed.The biaxially stretched polyester film comprises substantially spherical silica particles of colloidal state having average diameters ranging from approximately 20 nm to approximately 200 nm in amounts ranging from approximately 0.005% to approximately 1.0% by weight based on the total weight of the polyester; and alumina particles having average diameters ranging from approximately 50 nm to approximately 500 nm in amounts ranging from approximately 0.05% to approximately 5.0% by weight, the average diameter of the alumina particles being larger than that of the silica particles.The biaxially stretched film prepared according to the present invention has excellent surface properties such as slip property and abrasion resistance, so that the film may be used for manufacturing final products without scratches and white powders occurring thereon.Type: GrantFiled: June 24, 1994Date of Patent: March 14, 1995Assignee: Cheil Synthetics Inc.Inventors: Dae W. Ihm, Jeong L. Kim, Seung B. Jun
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Patent number: 5393569Abstract: A water-permeable and fire-resistant film and the preparing method thereof is disclosed. The water-permeable and fire-resistant film comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyl oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb203 and Sb205. The surface of the film produced is smooth.Type: GrantFiled: February 14, 1994Date of Patent: February 28, 1995Assignee: China Textile InstituteInventors: Shin-Chuan Yao, Jong-Fu Wu, Kun-Lin Cheng, Chiu-Hsiung Tsai, Farn-Ping Koong, Kun-Lung Chuang, Shu-Lan Yao, Chin-Liu Liu
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Patent number: 5389695Abstract: Low thermal conductivity insulation for refrigerators and the like is produced by blowing a resinous foam in an inert (e.g., nitrogen) atmosphere with a mixture of carbon dioxide and a low thermal conductivity inert gas such as krypton or xenon. The foam is then sealed in a gas-impervious enclosure and carbon dioxide is removed therefrom, typically by inclusion in said enclosure of a solid material reacted therewith such as an alkaline reagent. The final partial pressure of the low thermal conductivity gas in the enclosure is in the range of about 20-200 torr, and the total pressure is up to 110% of said partial pressure.Type: GrantFiled: December 22, 1993Date of Patent: February 14, 1995Assignee: General Electric CompanyInventors: Heinz Jaster, William J. Ward, III
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Patent number: 5376208Abstract: A water-permeable and fire-resistant product and the preparing method thereof is disclosed. The waterpermeable and fire-resistant product is made of a fabric layer and a purous film adhered thereon. The porous film of this invention comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyl oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb2O3 and Sb2O5. The surface of the product produced is smooth.Type: GrantFiled: May 11, 1994Date of Patent: December 27, 1994Assignee: China Textile InstituteInventors: Shin-Chuan Yao, Jong-Fu Wu, Kun-Lin Cheng, Chiu-Hsiung Tsai, Farn-Ping Koong, Kun-Lung Chuang, Shu-Lan Yao, Chin-Liu Liu
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Patent number: 5366675Abstract: A foamable composition useful for rotational molding, is provided. The composition advantageously includes an ethylene vinyl ester copolymer as an additive. The additive beneficially has a higher melt index than the base resin of the composition.Type: GrantFiled: March 2, 1994Date of Patent: November 22, 1994Inventor: Donald G. Needham
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Patent number: 5342857Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.Type: GrantFiled: January 18, 1994Date of Patent: August 30, 1994Assignees: Reedy International Corporation, Genpak CorporationInventors: Michael E. Reedy, Edward W. Rider, Jr.
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Patent number: 5336694Abstract: An expanded polymer product with high distortion temperature, high flame resistance and low smoke toxicity and opacity comprises, in combination:between 18% and 25% of a mixture of at least two isocyanates;between 8% and 11% of a styrene and maleic anhydride mixture;between 19% and 42% of a PVC resin in emulsion form;between 4% and 7% of at least one expanding agent;between 0.5% and 1% of at least one temperature stabilizer;between 16% and 40% of TiO.sub.2.Said product is used particularly in sea, ground and air transport, and in numerous constructional applications in which the materials must combine high technical characteristics with adequate lightness.Type: GrantFiled: November 23, 1992Date of Patent: August 9, 1994Assignee: Prima, S.p.A.Inventor: Leone Lauri
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Patent number: 5328937Abstract: A foam spacer which is usable as a cork substitute in the base cushion layer of a glass spacer. The spacer, which is adapted to replace natural cork spacers is preferably laminated to a tack layer or otherwise adhered to a surface. The spacer is formed from a plasticized foamable resin which includes a quantity of incorporated reinforcing agents.Type: GrantFiled: April 14, 1993Date of Patent: July 12, 1994Assignee: Gaska Tape, Inc.Inventor: Lawrence A. Cascino
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Patent number: 5318837Abstract: Soundproofing materials consisting essentially of zinc oxide whisker particles having a nucleus body and needle crystal portions extending radially from the central body in different plural directions. The materials may comprise a support material for supporting the zinc oxide whisker particles. Such support materials include inorganic materials such as metals, ceramics, glasses, cements, mortars and various fillers in the form of powder, flakes, fibers and the like, and organic materials such as resins, rubbers, waxes and the like. These materials are particularly suitable for sound insulation, sound proofing, vibration damping and vibration insulation.Type: GrantFiled: December 17, 1991Date of Patent: June 7, 1994Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Minoru Yoshinaka, Eizo Asakura, Mitsumasa Oku, Takeshi Hamabe, Motoi Kitano
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Patent number: 5317033Abstract: The present invention concerns a process for producing a synthetic resin foam composed of cells having substantially two sizes, one of the sizes being at most 0.3 mm and the other size as being 0.4 to 1 mm, comprising the steps of:forming a mixture of one or more of a water-absorbent high molecular compound, a cell-controlling agent, a synthetic resin, and water; melting the mixture with heating; incorporating a volatile type foaming agent into the mixture under pressure; and extruding the mixture into a lower pressure space to form a foam.Type: GrantFiled: January 14, 1993Date of Patent: May 31, 1994Inventors: Shigeru Motani, Tadayuki Saito, Takahiro Hayashi
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Patent number: 5317044Abstract: Compositions for producing foamed products which include additives and blowing agents which cause the surface treatment additives to migrate to the surfaces of foamed products. The products produced from the compositions require less additives because the incorporated additives are concentrated at the surfaces thereof.Type: GrantFiled: June 11, 1991Date of Patent: May 31, 1994Assignee: J. M. Huber CorporationInventors: Gerry Mooney, Rod A. Garcia, Michael E. Tarquini, John A. Kosin
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Patent number: 5314925Abstract: A process for producing structural aromatic polycarbonate thermoplastic foam is provided which involves gas expansion of a melted aromatic polycarbonate thermoplastic resin composition containing an amount of a polytetrafluoroethylene nucleating agent. The thermoplastic resin compositions provided exhibit an improved uniformity of cell structure in the resultant structural thermoplastic foam as a result of the incorporation of the polytetrafluoroethylene nucleating agent. The process and compositions are useful in the production of structural thermoplastic foam articles.Type: GrantFiled: December 3, 1992Date of Patent: May 24, 1994Assignee: General Electric CompanyInventors: Ann M. Burnell, Albin P. Berzinis, Timothy M. Conroy, Kim G. Balfour
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Patent number: 5314420Abstract: A superabsorbent polymer having improved absorption under pressure and fast absorption rate is obtained by first providing a solution containing carboxylic acid monomers or water soluble salts thereof, and a crosslinking agent. A carbonate blowing agent and a polymerization initiator are added, individually or in combination, to the solution to form a carbonated monomer solution. A polymerization initiator is then added to the carbonated monomer solution which is then polymerized at temperatures ranging from about 0.degree. C. to about 130.degree. C., forming a microcellular hydrogel. The microcellular hydrogel is chopped or ground into gel pieces having a particle diameter ranging from about 0.1 mm to about 5.0 cm. The gel pieces are dried at temperatures ranging from about 85.degree. C. to about 210.degree. C., and are then ground to form a polymer having a particle size of from about 0.05 mm to about 5.0 mm. A mixture is formed from 100 parts by weight of the polymer and about 0.Type: GrantFiled: September 17, 1993Date of Patent: May 24, 1994Assignee: Nalco Chemical CompanyInventors: Scott J. Smith, Eric J. Lind
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Patent number: 5306736Abstract: Compositions for producing foamed products which include additives and blowing agents which cause the surface treatment additives to migrate to the surfaces of foamed products. The products produced from the compositions require less additives because the incorporated additives are concentrated at the surfaces thereof.Type: GrantFiled: July 31, 1992Date of Patent: April 26, 1994Assignee: J. M. Huber CorporationInventors: Gerry Mooney, Rod A. Garcia, Michael E. Tarquini, John A. Kosin
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Patent number: 5302624Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.Type: GrantFiled: May 14, 1993Date of Patent: April 12, 1994Inventors: Michael E. Reedy, Edward W. Rider, Jr.
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Patent number: 5302625Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.Type: GrantFiled: May 27, 1993Date of Patent: April 12, 1994Assignee: Darlene May ParisInventor: Franklin A. Paris, deceased
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Patent number: 5300543Abstract: A thermoplastic molding composition suitable for the preparation of foam is disclosed. The composition comprises a thermoplastic resinous component and a foaming agent which includes A) (i) 0.01 to 4.8% alumina hydrate (aluminum hydroxide) in combination with (ii) 0.01 to 4.8% of an acidic additive or B) 0.01 to 4.8% of the reaction product of said (i) and said (ii), the percentages being relative to the weight of the composition to be foamed. The invention is based on the finding that the foaming of the composition does not lead to any significant reduction in molecular weight of the resinous component or to troublesome discoloration of the foam, even during its re-extrusion.Type: GrantFiled: September 28, 1993Date of Patent: April 5, 1994Assignee: Bayer AktiengesellschaftInventors: Wolfgang Ebert, Jurgen Kirsch, Burkhard Kohler, Wolfgang Beer, Siegfried Anders, Rolf Dhein
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Patent number: 5288764Abstract: Disclosed is a process for obtaining polyester articles, including foamed articles, containing low levels of extractable branching agent. The process comprises: (1) forming a molten mixture comprising (i) a major amount of a first resin composition comprising polyester and from 0 up to about 1 wt. % of a compound capable of branching the polyester, and (ii) a minor amount of a second polyester resin composition comprising at least about 50 wt. % polyester resin and greater than about 2 wt. % of a compound capable of branching the polyester, wherein the relative amounts of (i) and (ii) are such that said molten mixture comprises from about 0.1 wt. % to about 1 wt. % of said branching compound; (2) adding a blowing agent to the molten mixture; and (3) extruding the resultant mixture to obtain a foam. The invention is also directed to the second composition used in the above process, and foamed polyester articles obtained from the process.Type: GrantFiled: January 29, 1993Date of Patent: February 22, 1994Assignee: Amoco CorporationInventors: George E. Rotter, John L. Melquist, Weilong Chiang, Boh C. Tsai, John J. Kelly
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Patent number: 5274006Abstract: The present invention provides a foamable epoxy resin composition (A) 100 parts by weight of a liquid epoxy resin (B) 0.5-20 parts by weight of a latent curing agent, (C) 0.5-15 parts by weight of a foaming agent having a decomposition temperature of 100.degree.-220.degree. C., (D) 0.05-5 parts by weight of a surface active agent and (E) 10-200 parts by weight of a rubbery elastomer or a powdery halogen-free thermoplastic resin of 150 .mu.m or less in average particle diameter, which composition has a melt viscosity of 2.5.times.10.sup.3 -5.times.10.sup.4 dPa.multidot.s at the decomposition temperature of said foaming agent. The composition can provide a foamed material of rigidity and good heat resistance, having an expansion ratio of 5 times or more and a dense cell structure of 0.5 mm or less in average cell diameter.Type: GrantFiled: February 18, 1992Date of Patent: December 28, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Yutaka Kagoshima, Toshio Nagase, Takamitu Mikuni, Takeo Kobayashi
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Patent number: 5272182Abstract: The present invention includes an improved blowing agent concentrate, comprising:(a) a vinyl aromatic polymer;(b) a preformed blend of a styrene/diene block copolymer and a hydrocarbon rubber extending oil; and(c) at least one blowing agent.The blowing agent concentrate is utilized to prepare foamable materials based on a variety of thermoplastic organic polymers. The foamable materials can in turn be molded into a variety of thermoplastic structures.Type: GrantFiled: December 3, 1992Date of Patent: December 21, 1993Assignee: General Electric CompanyInventor: Ann M. Burnell
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Patent number: 5260345Abstract: Disclosed are absorbent foam materials suitable for use as or in the absorbent cores of absorbent articles, such as diapers which absorb and retain aqueous body fluids. Such foam materials comprise hydrophilic, flexible open-celled structures which are preferably prepared by polymerizing high internal phase (HIPE) water-in-oil emulsions. Such foam materials have a pore volume of from about 12 to 100 mL/g, and a capillary suction specific surface area of from about 0.5 to 5.0 m.sup.2 /g. These materials also exhibit a resistance to compression deflection such that a confining pressure of 5.1 kPa produces after 15 minutes a strain of from about 5% to 95% compression when the material is saturated at 37.degree. C. to its free absorbent capacity with synthetic urine.Type: GrantFiled: August 12, 1991Date of Patent: November 9, 1993Assignee: The Procter & Gamble CompanyInventors: Thomas A. DesMarais, Keith J. Stone, Hugh A. Thompson, Gerald A. Young, Gary D. LaVon, John C. Dyer
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Patent number: 5252618Abstract: Compositions for producing foamed products which include filler and/or pigment additives and blowing agents which enhance the strength of weld lines which are produced when the compositions are molded. The products produced from the compositions have weld line that demonstrate superior strengths as compared to similar foamed products which do not utilized the particular blowing agents.Type: GrantFiled: April 22, 1991Date of Patent: October 12, 1993Assignee: J. M. Huber CorporationInventors: Rod A. Garcia, John A. Kosin, Gerry Mooney, Michael E. Tarquini
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Patent number: 5250224Abstract: A stabilized powdered endothermic blowing agent which is a mixture of a polycarboxylic acid and an inorganic carbonate, the polycarboxylic acid and inorganic carbonate each having been surface treated with a component which prevents water from being absorbed thereby The blowing agent is incorporated into a polymeric concentrate used for producing foamed products.Type: GrantFiled: March 30, 1992Date of Patent: October 5, 1993Assignee: J. M. Huber CorporationInventors: Satish K. Wason, Gerry Mooney, Claude R. Andrews, Michael E. Tarouini, John A. Kosin, Rod A. Garcia
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Patent number: 5246625Abstract: Storage-stable 141b prepared by contacting 141b with alumina at temperatures of about 0-100 degrees Centigrade, compositions containing the thus treated 141b, and uses thereof for the production of polyurethane and polyisocyanurate foams.Type: GrantFiled: March 22, 1993Date of Patent: September 21, 1993Assignee: EH Atochem North America, Inc.Inventors: Richard M. Crooker, Maher Y. Elsheikh
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Patent number: 5246626Abstract: Storage-stable 141b prepared by contacting 141b with alumina at temperatures of about 0-100 degrees Centigrade, compositions containing the thus treated 141b, and uses thereof for the production of polyurethane and polyisocyanurate foams.Type: GrantFiled: March 22, 1993Date of Patent: September 21, 1993Assignee: Elf Atochem North America, Inc.Inventors: Richard M. Crooker, Maher Y. Elsheikh
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Patent number: 5246973Abstract: The introduction of a foamable silicone rubber composition that evolves neither toxic gas nor hydrogen, that does not suffer from inhibition of its cure to give silicone rubber, and that cures to give a silicone rubber foam containing uniform microcells. The foamable silicone rubber composition comprises:(A) 100 weight parts thermosetting liquid silicone rubber composition, and(B) 0.1 to 30 weight parts thermally expansible hollow plastic microparticles.Type: GrantFiled: January 27, 1993Date of Patent: September 21, 1993Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Akito Nakamura, Yuichi Tsuji
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Patent number: 5240765Abstract: A silicone rubber composition comprising an organopolysiloxane and a curing agent is improved by adding a foaming agent in an amount of 0.1 to 10 parts by weight per 100 parts by weight of the organopolysiloxane. The composition is heat curable into silicone rubber films or coatings which are substantially unfoamed and tack-free on a surface.Type: GrantFiled: July 10, 1992Date of Patent: August 31, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaharu Takahashi, Kazuma Momii
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Patent number: 5236963Abstract: This invention relates to polymeric compositions capable of being converted into oriented microporous films having microvoid cells, interconnecting pores between the cells, and improved elongation, softness and tear strength, comprising an ethylene-propylene block copolymer having an ethylene content of about 10 to about 50 wt %, a low flexural modulus propylene-based polymer, a propylene homopolymer or copolymer having up to about 10 wt % of a comonomer of ethylene or an .alpha.-olefin of 4 to 8 carbon atoms, an inorganic filler such as calcium carbonate, a beta-spherulite nucleating agent, and optionally, a low molecular weight polypropylene and to microporous films formed from such compositions.Type: GrantFiled: December 30, 1992Date of Patent: August 17, 1993Assignee: Amoco CorporationInventors: Philip Jacoby, William T. Tapp
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Patent number: 5234963Abstract: The present invention is directed to the process and apparatus for compounding and pelletizing of chemical foaming agents in a high melt resin carrier and producing unique, uniform encapsulated and pelletized chemical foaming concentrates. More specifically, the present invention is directed to the compounding, encapsulating and pelletizing in a high melt resin carrier a highly loaded concentration (5 to 70 wt %) of foaming agents which include an endothermic foaming agent, an exothermic foaming agent or hybrid combinations of these two such that when incorporated into a thermoplastic resin to produce a foamed product will chemically react to form a mixture of carbon dioxide, nitrogen or hydrogen as the active foaming agent.Type: GrantFiled: November 10, 1992Date of Patent: August 10, 1993Assignee: Gaia ResearchInventors: Rodrigo A. Garcia, Joseph G. Gho
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Patent number: 5232955Abstract: The invention relates to a process for producing a highstrength a furan stone with high permeability and filtering effect mainly for protecting deep-drilled wells yielding mineral oil, natural gas and water against getting choked by sand. A mixture comprising an artificial resin as a binding material containing a catalyzer for controlling duration of binding and pumpability and an assorted granular material of high-strength forming the skeleton and salt filling and increasing pore spaces is homogenized and pumped into the corresponding producing section of the well into the area to be protected. After hardening of the mixture salt is dissolved from the obtained artificial stone and a filtering effect is achieved without binding the grains of the reservoir rock. Due to the mechanical characteristics and controlled porosity of the obtained artificial stone rock-parts, mainly sand delivered by the yielded fluidum into the well will be retained.Type: GrantFiled: December 16, 1991Date of Patent: August 3, 1993Assignees: Mol Magyar Olaj Es Gazipari Reszvenytarsasag, Koolajkutato VallalatInventors: Tibor Csabai, Miklos Magyar, Istvan Munkacsi, Mihaly Kun, Tibor Plajner, Ambrus Andristyak, Cecilia Fuzes nee Takacs, Istvan Balazs
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Patent number: 5225315Abstract: A water-soluble coating or other deposit is produced from a formulation that is comprised of a curable liquid substance and a dispersed particulate effervescing agent. The formulation is particularly useful as a solder resist in the manufacture of PCBs, and the preferred composition contains n-vinyl-2-pyrrolidone, N,N-dimethylacrylamide, and polyvinylpyrrolidone.Type: GrantFiled: September 19, 1991Date of Patent: July 6, 1993Assignee: Dymax CorporationInventors: Gary V. Grosclaude, Andrew G. Bachmann
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Patent number: 5225107Abstract: The invention relates to new nucleating agents for the preparation of directly gassed thermoplastic foams. The new agents comprise a combination of citric acid, the salts or esters thereof and carbonate or bicarbonate and talc.Type: GrantFiled: September 23, 1992Date of Patent: July 6, 1993Assignee: Boehringer Ingelheim GmbHInventors: Gunther Kretzschmann, Dieter Scholz, Karl-Heinz Hilgert
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Patent number: 5225452Abstract: A foam forming composition comprises (a) one or more polysiloxanes having not less than three alkylhydrogen siloxane units per molecule, (b) one or more polysiloxanes having not less than two silicon-bonded hydroxyl group per molecule, (c) at least one liquid organic titanium compound and (d) a catalyst. Reaction between the organic titanate (e.g. tetraisopropyltitanate) and the hydroxy functional polysiloxane rapidly increases viscosity of the mixture to restrict flow of the composition as it cures to form a foam within 240 seconds of mixing. A vinyl polysiloxane may be incorporated.Type: GrantFiled: December 9, 1992Date of Patent: July 6, 1993Assignee: Dow Corning GmbHInventors: Andre R. L. Colas, Heinz Mueller
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Patent number: 5218006Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.Type: GrantFiled: June 1, 1992Date of Patent: June 8, 1993Inventors: Michael E. Reedy, Edward W. Rider, Jr.
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Patent number: 5216037Abstract: A room temperature vulcanizable, foamable polysiloxane composition is described, which comprises:(A) a specific type of .alpha., .omega.-dihydroxyorganopolysiloxane which has a surface tension of not lower than 22 dynes/cm at 25.degree. C.;(B) a specific type of organopolyhydroxypolysiloxane;(C) a polyorganohydrogensiloxane which has at least two units of the following general formula in one moleculeR.sup.5.sub.a H.sub.b SiO.sub.(4-(a+b))/2wherein R.sup.5 represents a monovalent hydrocarbon group except for aliphatic unsaturated hydrocarbon group, a is an integer of 0 to 2, and b is an integer of from 0 to 3 provided that the total of a+b is an integer of from 1 to 3;(D) an unsubstituted or substituted alcohol having from 1 to 12 carbon atoms; and(E) a platinum catalyst.The composition has a high degree of foaming and the foamed product obtained from the composition has good foaming stability and good tensile strength.Type: GrantFiled: June 24, 1992Date of Patent: June 1, 1993Assignee: Shin-Etsu Chemical Co, Ltd.Inventors: Kei Miyoshi, Masatoshi Arai
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Patent number: 5210107Abstract: A flexible foamed liquid crystal polymer film or sheet having uniformly small cells or bubbles. The foam cells are essentially spherical and have mean diameters less than or equal to approximately 250 microns. The cell size distribution is relatively small. The foamed sheet is made by extruding the polymer through a die under pressure at a temperature near or below the polymer's melting point; a gas or chemical blowing agent is extruded with the polymer to produce foaming as the polymer exits the die.Type: GrantFiled: January 17, 1991Date of Patent: May 11, 1993Assignee: Hoechst Celanese Corp.Inventors: Randy D. Jester, Detlef K. M. Frank
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Patent number: 5187203Abstract: A composition and foam insulation for copper tubing is described herein which is formulated to retard copper oxidation and eliminate or reduce stress corrosion in the copper tubing. The copper compatible, elastomeric foam insulation is made from a composition comprising 100 parts by weight of rubber, vinyl chloride polymer at about 15 to about 85 pphr, a plasticizer selected from the group consisting of an alkyl phosphate ester and an oxyalkyl phosphate ester at about 10 to about 100 pphr, a fire retardant in an amount of at least about 100 pphr, a stabilizer in an amount effective to prevent degradation of the rubber and vinyl chloride polymer, a preservative at from about 0.1 to about 10 pphr, and a lubricant at about 10 to about 85 pphr, wherein the composition and foamed product contains no more than about 5 parts of free phenol per million.Type: GrantFiled: October 23, 1991Date of Patent: February 16, 1993Assignee: Armstrong World Industries, Inc.Inventors: Ronald S. Lenox, Kim S. Boyd, William S. Vought, Jr.
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Patent number: 5174934Abstract: Processes using high temperature thermoplastic polymers in the in-situ fabrication in the formation of foamed composite sandwich or foam articles often result in weak unsound products which may be avoided by utilizing a high temperature thermoplastic in powder form (22), a blowing agent having a high decomposition temperature (24), and, if desired, reinforcers and/or fillers (28), admixing the thermoplastic, blowing agent and reinforcer and fillers (30), placing the admixture in a mold and, if forming a composite structure, in abutment with at least one skin (34), compacting the contents of the mold (37), and applying sufficient heat and/or pressure to the mold and its contents to melt the thermoplastic and generate gas within said mixture by decomposition of the blowing agent (38). Also, an activator may be included with the blowing agent which promotes the production of gas (26).Type: GrantFiled: January 10, 1991Date of Patent: December 29, 1992Assignee: Sundstrand CorporationInventor: Hossein Saatchi
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Patent number: 5175194Abstract: A flame retardant composition and process which is particularly useful for rebonded foam products. The composition of the present invention includes a solid component of magnesium sulfate, boric acid, decabromodiphenylethylene oxide (DECA) and antimony trioxide and a liquid component of halogenated phosphorous. The present invention is based upon the discovery of the synergism between boric acid and DECA. The process, according to the present invention, includes the steps of forming a dispersion of the solid portion of the flame retardant composition along with a small amount of water based adhesive to a mass of foam chips. The treated chips are then dried to permit handling and storage. The dried foam chips subsequently are mixed with a conventional urethane prepolymer binder and the liquid halogenated phosphorous flame retardant compound. After mixing the foam mass is transferred to molds and steamed to allow the binder to cure.Type: GrantFiled: May 11, 1992Date of Patent: December 29, 1992Assignee: Triad-Fabco, Inc.Inventors: Robert W. Ward, Rogelio Tornero, Freeman J. Henderson
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Patent number: 5168104Abstract: A method to prepare uniform populations of macroscopic beads containing pores of at least 0.1 microns diameter is described. The beads consist essentially of a copolymer of a monoethylenically unsaturated monomer and a crosslinking polyethylenically unsaturated monomer, said resulting copolymer optionally being derivatized with functional groups, linking moieties, and/or affinity ligands. The macroporous beads are obtained by utilizing, as porogen in the polymerization reaction, porous inorganic particles which have been preabsorbed with a blowing agent. The blowing agent is not activated until after the polymerization takes place; when the blowing agent is activated, the organic polymer which isolates the inorganic porogen particles from each other in the bead is destroyed. Upon subsequent dissolution of the inorganic porogen, a network of pores throughout the organic copolymer-formed particle is formed. The resulting beads are useful in a variety of chromatographic, analytical and biomedical techniques.Type: GrantFiled: September 13, 1991Date of Patent: December 1, 1992Assignee: Chembiomed, Ltd.Inventors: Nai-Hong Li, M. Abdul Mazid
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Patent number: 5162280Abstract: A storage stable aqueous dispersion useful in the curing of unsaturated polyester resins and the suspension polymerization of vinyl monomers containing an aromatic diacyl peroxide, an alkylene glycol and dispersion-stabilizing amounts of magnesium aluminum silicate and a cellulose ether compound is disclosed. Also disclosed are the curing of polyester resins and the suspension polymerization of vinyl monomers using the dispersion.Type: GrantFiled: October 11, 1991Date of Patent: November 10, 1992Assignee: Witco CorporationInventor: Lawrence A. Bock